Peng-Robinson Equation of State for a Pure Fluid

Professional courtesy from G. Bolaños (School of ChE - Univalle - Colombia)

Properties Intermediate calculations

Substance Tc (K) Pc (MPa) w
Oxido de etileno 469 7.194 0.2 Rg = 8.314
Tr = 0.7103
State Pr = 0.0198
T (K) 333.15 fw = 0.6723
P (MPa) 0.1427
Equation-of-state constants
Three real roots (1 or 2 phase region) a= 1181389.2
Z V Fugacity b= 42.17
cm3/gmol MPa
0.979896 19019.79 0.13988 Coefficients in EOS polynomial: Z3 +
0.015007 291.29 1.13952 alfa = 0.0220
0.002925 56.77 0.47713 beta = 0.0022
Fugacity ratio = 0.29317
A= -0.9978
Vtot (cm3) 1000000 B= 0.0176
M (g/mol) 44.05 C= 0.0000

Peng-Robinson Gases ideales Equation-of-state roots (Thank god

n (mol) 52.5768181576 51.5197960755 Q= 0.10476
m (kg) 2.3160088398 2.2694470171 R= -0.06778
M= -4.8045E-06
V (ecu.gas.ideal) 19410.014716188 cm3

% error 2.0104337218 %

Se consumen 2,32 kg de óxido de etileno.

Three real roots calculation
Comparando el resultado cola ecuacion de gases ideales se tiene un Theta Roots
porcentaje de error de 2,01 % 0.010776 0.979896
te calculations

cm3 MPa/(gmol K) Ideal gas constant

Reduced temperature
Reduced pressure
Accentric factor function

tate constants
MPa cm6/gmol2
cm3/gmol

n EOS polynomial: Z3 + A*Z2 + B*Z + C = 0

tate roots (Thank god Cardano did not die at the stake!)

If M > 0 there is one real root

If M < 0 there are three real roots

ts calculation
Roots
0.015007 0.002925