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Inductive Effect
 -I effect
C–C–C–C––
EN of G > EN of carbon
–
C – C – C – C– G
–
C – C – C – C– G
 + I effect
C–C–C–C––
EN of G < EN. of Carbon
–
C – C– C– C– G
–
C – C – C – C– G
 +I effect & -I effect
+I Effect = Electron donating group
-I Effect = Electron accepting group
 -I Effect
• NF3+ NR3+ NH3+
 -I Effect
• -CHO -COOH
 -I Effect
• -OR -OH
 -I Effect
–OH –Cl –NH2 –Cl
 Order of –I effect
-NF3+ > -NR3+ > -NH3+ > -NO2 >
–C N > -CHO > -COR > -COOH >
-F >-Cl > -Br > -I > -OR >-OH >
-NH2 > -Ph > -H
 Order of +I effect
– –
–
– C H2 –NH O (+I effect)
 Return Gift
CH2- > NH- > O- > COO- >
3’ alkyl > 2’alkyl > 1’alkyl >normal alkyl
> T > D > H
 Super Example
Compare acidic order
(1) F – CH2 – COOH
(2) NO2 – CH2 – COOH
(3) Cl – CH2 – COOH
(4) NH2– CH2 – COOH
 Super Example
Compare acidic order
CH3 CH3
(3) CH3 – CH2 – OH
CH3– C – OH CH3– C – OH
(4) CH3 – OH
CH3 H
 Super Example
Compare acidic order
1. HClO
2. HClO2
3. HClO3
4. HClO4
 Super Example
Compare acidic order
(1) HCOOH
(2) CH3COOH
 Super Example
Compare acidic order
(1) CH3 – COOH
(2) Cl – CH2 – COOH
(3) OH – CH2 – COOH
 Super Example
Compare acidic order
(1) FCH2 – COOH
(2) ClCH2 – COOH
(3) BrCH2 – COOH
(4) ICH2 – COOH
 Super Example
Compare acidic order
(1) FCH2 – COOH
(2) ClCH2 – COOH
(3) BrCH2 – COOH
(4) I2CH – COOH
 Super Example
Compare acidic order
1. CHF2 – COOH
2. CCl3 – COOH
3. CBr3 – COOH
4. CI3 – COOH
NET Effect of Some – Special Groups
CH2–F
CH2–Cl CH2 — X Net –I effect
CH2–Br
CH2–I +I –I
effect effect

CH2–OH CH2—OH Net +I effect

+I –I
effect effect
 Super Example
Compare acidic order
(1) F – H2C–COOH
(2) CH3COOH
(3) Cl – CH2–COOH
 Super Example
Compare acidic order
(1) CH3 – CH2 – OH
(2) CH3 – NH2
 Resonance
• Delocalization of p electron, within the molecule is
called resonance.
• For resonance conjugation must be there.
(1) p s
(2) p s Q
(3) p s lp
(4) p s
(5) p s p
Super Example
 Super Example
CH2 — CH = CH2
 Super Example
O
QCH – C – H
2