Unit-V

General principles and process of Isolation of Elements

Remembering

Q.1.Match column I with II

1. Collectors a. Pine oil

2. Stabilizer b. NaCN
c. Cresol
Ans.1(a) 2(c)

Q.2.Match the metal with correct refining process:

1.Tin a. Distillation
2.Mercury b. Liquation
c. Mond’s Process
Ans.1(b) 2(a)

Q.3.Match the name of ore with correct formula:

1.Malachite a. Cu2O
2.Cuprite b. Cu2S
c. CuCO3.Cu(OH)2
Ans.1(c) 2(a)

Understanding:

Q.4.Match the process in column I with appropriate ore:

1.Roasting a. Carbonate ore

2.Calcination b. Sulphite ore
c. Sulphide ore
d. Both a and b
Ans.1(c) 2(a)

Q.5. Match column I with II in electrolytic refining of Copper,the electrode used are:

1.Cathode a. pure copper

2.Anode b. Graphite
c. impure copper
Ans.1(a) 2(c)

Q.6.Match the composition of the alloys in column I and II:

1.german silver a.Alloy of copper and zinc

2.Brass b.Alloy of zinc, nickel& copper
c. Alloy of copper and tin
Ans.1(b) 2(a)
Q.7.Match the nature of substance given in column I with column II:

1.Calcium oxide a. Neutral flux

2.Silica b. Basic flux
c. Acidic flux
Ans.1(b) 2(c)

Q.8.Match column I with II:

1.Zincite a. Sulphide ore of zinc

2.Calamine b. carbonate ore of zinc
c. Oxide ore of zinc
Ans.1(c) 2(b)

Q.9.Match column I with II in reference to electrolytic refining: of copper

1.Anode a. Thin strip of pure copper

2.Cathode b. Aqueous ZnSO4
3.Electrolyte c. Aqueous CuSO4
4.Anode mud d. Ag and Au
e. Impure Copper
Ans.1(e) 2(a) 3(c) 4(d)

Q.10.Match the pair of elements with appropriate process:

1.Zn and Hg a.Zone refining

2.Ge and Si b. Electrolytic refining
3.Zr and Ti c. Distillation
4.Zn and Cu d. Van Arkel
Ans. 1-c,2-a,3-d,4-b

Application:

Q.11.Match column I with the gas evolved in column II:

1.Blister Copper a. CO2 gas

2.Mond’s process b. CO gas
c. SO3 gas
d. SO2 gas
Ans.1(d) 2(b)

Q.12.Match column I with appropriate process in column II:

1.Bauxite Alumina a. Refining

2.Zirconium/iodide gas Zirconium b. Roasting
c. Leaching
Ans.1(c) 2(a)

Q.13.Match the process of column I with column II:

1.Oxidation of metal a. Electrolyte

2.Reduction of metal ion b. Cathode
c. Anode
Ans.1(c) 2(b)
Q.14. Match the property of metal in column I with process in column II:

1.Metals with low boiling point a. Zone refining

2.Metals with low melting point b. liquation
c. Distillation
Ans.1(c) 2(b)

Evaluation & Analysing:

Q.15.Match the following:

Column I Column II
1. Basic flux a. FeSiO3
2. Soluble complex b. CO
3. Slag c. CaO
4. Reducing agent d. Na[Au(CN)2
Ans.1(c) 2(d) 3(a) 4(b)

Q.16.Match column I and II:

1.Vapour phase refining a.Carbonate ore to oxide

2.Roasting b.sulphide ore to oxide
c.Impure metal to metal
Ans.1(c) 2(b)

Q.17.Match reactions in column I with correct process:

1.Cu2+ + H2 Cu +2H+ a.Mond’s process

2.Ni + 4CO Ni(CO)4 b. Van-Arkel method
c. Hydro metallurgy
Ans.1(c) 2(a)

Q.18.Match the metal in column I with column II:

1.Ni a. Van Arkel method

2.Zr b. Mond’s process
c. Zone refining

Ans.1(b) 2(a)

Q.19.Match the ore with column II:

1.Zincite a. Sulphide ore of mercury

2.Calamine b. Carbonate ore of Zinc
c. Oxide ore of Zinc
d. Oxide ore of Copper
Ans.1(c) 2(b)

Q.20.Match the following process with the product formed:

1.Electrolysis of brine a. Al + CO2

2.Hall-Heroult process b. Cu2O +SO2
c. NaOH + H2+Cl2
Ans.1(c) 2(a)
Q.21. Match the following properties with concentration process in column II:

1.Difference in gravities of ore and gangue a. Leaching

2.Difference in solubility of ore and gangue in b.Froth flotation
any suitable solvent
c.Hydraulic washing
Ans.1(c) 2(a)

Q.22.Match column I with column II:

1.Purest form of commercial iron a.Pig iron

2.Iron with about 4% carbon content b.Wrought iron
c.Cast iron
Ans.1(b) 2(a)

Q.23. Match column I with column II:

1.Electrolytic Reduction a. Copper

2.Reduction with carbon b. Aluminium
c. Mercury
d. Iron
Ans.1(b) 2(d)

Q.24. Match the zone in column I with reaction in column II:

1. Upper zone of blast furnace a.CaCO3 CaO + CO2

2. Lower zone of blast furnace b.CO2+C 2CO
c.Fe3O4+4CO 3Fe+4CO2
Ans.1(c) 2(b)

Q.25. Match column I with column II:

a. Calcination
1.2ZnS+3O2 2ZnO+2SO2

b. Leaching
2. Fe2O3.xH2O Fe2O3+xH2O
c.Zone refining
d.Roasting

Ans 1-d , 2-a