CHEMISTRY PAPER – 1st YEAR – FLP 2 - CHAPTER # 6 to 11

Time: 20 Min. PAPER OBJECTIVE Marks: 17

Sr. Questions (A) (B) (C) (D)

No.
1. The number of bonds in nitrogen One Sigma and One Sigma and Three Sigma Three pi bonds.
molecule is one pi two pi
2. Which of the following molecules NH₃ CHCl₃ H₂O BF₃
has zero dipole moment
3. The total heat contents of a system Enthalpy Temperature Internal energy Free energy
is called
4. Which statement about the The value of Kp The value of Kp Adding V2O5 The value of Kp is
following equilibrium is correct falls with a rise in falls with catalyst increase equal to Kc
2SO2(g) + O2(g) 2SO3(g)H = -188.33kJmol-1 temperature increasing the equilibrium
pressure yield of sulphur
trioxide
5. Which solution has the highest 5.85% solution of 18.0% solution of 6.0% solution of All have the same
boiling point? NaCl glucose urea boiling point
6. The electrode potential of SHE is 0.1 V 0.20V 0.02 V 0.0 Volts
7. The electrolyte used in fuel cells is NaOH Ca(OH)₂ PbO₂ KOH
8. The cloudiness of aqueous solution Adding BiCl₃ Adding H₂O Adding HCl Removing BiOCl
of BiCl₃ decreases by
9. If the salt bridge is not used Decrease rapidly Decrease slowly Does not change Drops to zero
between two cells then the voltage
10. Decomposition of nitrogen penta Zero First Second Third
oxide has order of reaction.
11. At constant volume, qv is equal to ∆E ∆H ∆V ∆P
12. In case of gases, Kc is replace by Ka Kb Kp Kw
13. When a reaction proceeds in Fastest step Slowest step Molecularity of all Order of different
sequence of steps, the overall rate is steps step
determined by
14. One calorie is equivalent to 0.41884 J 41.84 J 4.184 J 418.4 J
15. The pH of 10ˉ³ mole dmˉ³ of an 3.0 2.7 2.0 1.5
aqueous solution of H₂SO4 is
16. IN H2O2 the oxidation state of 1+ –1 +2 –2
oxygen is
17. The unit of the rate constant is the 1st order 2nd order 3rd order Zero order
same as that of the rate of reaction
in
 CHEMISTRY PAPER – 1st YEAR – FLP 2 - CHAPTER # 6 to 11
Time: 2:40 Hrs PAPER SUBJECTIVE Marks: 68
Note: It is compulsory to attempt any (8 – 8) parts each from Q. No. 2 and Q. No. 3 and attempt any (6) parts
from Q. No. 4. Attempt any (3) questions from Part – II. Write same Question No. and its Part No. as given
in the question paper. Make Diagram where necessary.

PART - I

Q. No. 2.
(i) State Hess’s law. Give its mathematical form.
(ii) State first law of thermodynamics. Give its mathematical form.
(iii) Why heat of sublimation is greater than heat of vaopurization?
(iv) Define activation energy and activated complex?
(v) Differentiate between continuous and discontinuous solubility curve?
(vi) Justify chemical equilibrium is dynamic in nature?
(vii) What is homogeneous and heterogeneous catalysis?
(viii) What are the applications of colligative properties?
Q. No. 3.
(i) What is Henderson’ equation?
(ii) What are conjugate solution and critical solution temperature?
(iii) Boiling points of the solvents increase due to the presence of solutes. Why?
(iv) Write two applications of electrochemical series.
(v) What is function of salt bridge?
(vi) Why sigma bond is stronger than Pi bond?
(vii) The dipole moments of CO2 and CS2 are zero, but that of SO2 is 1.61D.
(viii) Why the atomic radii increase from top to bottom in a group?
Q. No. 4.
(i) Why 2nd electron affinity for all the elements is positive?
(ii) State Le-Chatelier’s principle?
(iii) Explain that burning of a candle is a spontaneous process?
(iv) Define standard enthalpy of atomization?
(v) What is meant by buffer capacity?
(vi) Differentiate between ideal and non-ideal solution?

PART - II

Q. No. 5.
(a) How does Arrhenius equation help us to calculate the energy of activation of a reaction? (4)
(b) The solubility product of Ag2CrO4 is 2.6 x 10-2 at 250C. Calculate the solubility of the compound. (4)
Q. No. 6.
(a) Define dipole moment. How does it help to find out the shapes of molecules? (4)
(b) Prove that H = qp. (4)
Q. No. 7.
(a) Balance the following equation by oxidation number method. (4)
Br2 + NaOH ⎯⎯ → NaBr + NaBrO3 + H2O
(b) Differentiate between hydrolysis and hydration. (4)

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