15.4. Specific surface area from BET data.

The following data were obtained in a BET apparatus for

adsorption equilibrium of N2 on silica gel (SG) at -195.8C. Estimate Sg in m2 /g of silica gel. How
does your value compare with that in Table 15.2?

Solucion
𝑃 1 (𝑐 − 1) 𝑃
= + ( )
𝑣(𝑃0 − 𝑃) 𝑣𝑚 𝐶 𝑣𝑚 𝐶 𝑃0

Y b m x

datos valor unidades

p°= 760 mmHg
t= -195.8 °c
ρL= 0.808 g/cm^3
NA= 6.023E+23
PM= 28

a condiciones STP
vel. Gas= 22.4 m^3/gmol
22400 Cm^3/gmol

Isoterma de launguir

p(torr) v (cm^3 stp/g sg) x y

6 6.1 0.01184211 0.00196459
24.8 12.7 0.03263158 0.00265609
14.3 17 0.01881579 0.00112804
230.3 19.7 0.30302632 0.02206977
285.1 21.5 0.37513158 0.02792265
320.3 23 0.42144737 0.03167179
430 27.7 0.56578947 0.04704081
505 33.5 0.66447368 0.05911618
 0.07

0.06
y = 0.0846x - 0.0012
R² = 0.9873
0.05

0.04

0.03
y

0.02

0.01

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
-0.01
x

1
0.001 0.01 0.1 1

y = 0.0846x - 0.0012 0.1

R² = 0.9873

0.01
y

0.001

0.0001

0.00001
x

(𝑐−1) 1
=0.0844 =-0.0011
𝑣𝑚 𝐶 𝑣𝑚 𝐶

Resolviendo por un sistema de 2x2 obtenemos:

Vm = 12.0048
C= -49.6
2
𝑃𝑀 2/3 28 3
𝛼 = 1.091 ( ) = 1.091 ( ) = 1.63154E − 15
𝑁𝐴∗𝜌𝐿 6.023∗1023 ∗0.808

𝛼∗𝑣𝑚∗𝑁𝐴 1.63154E−15∗12.0048∗6.023∗10^23
𝑠𝑔 = 𝑣
= 22400
=526643.1025 cm^2/g sg
 Nax – absorvente

Tetrametilbenceno - adsorbato
1
( ) 𝑥
𝑞 = 𝑘𝑃 𝑛 ;𝑞 =
𝑚

𝟏
𝐥𝐨𝐠(𝒒) = 𝐥𝐨𝐠(𝒌) + 𝐥𝐨𝐠(𝑷)
𝒏
y b m x

si el peso molecular del tetrametil benceno es 134.2

q(mol/g)=q%/(100-q%)
q (%w) p (torr) P (atm) q (g/g) q (mol/g) log(q ) log (p) q_recal %e
- -
7 0.012 1.57895E-05 0.07526882 0.00056087 3.25113742
4.80163217 0.00064356 14.74357808
- -
9.1 0.027 3.55263E-05 0.10011001 0.00074598 3.12727501
4.44944965 0.00076621 2.711821351
- -
10.3 0.043 5.6579E-05 0.1148272 0.00085564 3.06770773
4.24734496 0.00084687 1.02491645
- -
10.8 0.07 9.21053E-05 0.12107623 0.00090221 3.04469361
4.03571538 0.00094046 4.239730815
-
11.1 0.094 0.000123684 0.12485939 0.0009304 -3.0313313 3.90768556 0.00100203 7.698629649
- -
11.5 0.147 0.000193421 0.1299435 0.00096828 3.01399795 3.71349608 0.00110319 13.93233101
%et= 7.391834558
 -2.95
-6 -5 -4 -3 -2 -1 0
-3

y = 0.2151x - 2.1877
-3.05
R² = 0.9166

-3.1
y

-3.15

-3.2

-3.25

-3.3
x

Con los valores de la pendiente obtenemos el modelo

log(𝑞) = −2.1877 + 0.2151 log(𝑃)

𝑞 = 0.006941𝑃0.2151

isoterma de languir
𝑞0 ∗𝑘∗𝑃
𝑞= 1+𝑘∗𝑃
linealizando y multiplicando por P
𝑃 1 1
= + 𝑃
𝑞 𝑞0 ∗ 𝑘 𝑞0

y b m x

q (%w) p (torr) P (atm) q (g/g) q (mol/g) p/q q_nueva %e

7 0.012 1.57895E-05 0.07526882 0.00056087 0.02815174 0.00056419 0.59125891
9.1 0.027 3.55263E-05 0.10011001 0.00074598 0.04762394 0.00075437 1.125061
10.3 0.043 5.6579E-05 0.1148272 0.00085564 0.06612456 0.00083851 2.00255783
10.8 0.07 9.21053E-05 0.12107623 0.00090221 0.10208883 0.00090415 0.21490957
11.1 0.094 0.000123684 0.12485939 0.0009304 0.13293696 0.00093387 0.37338052
11.5 0.147 0.000193421 0.1299435 0.00096828 0.19975693 0.00103281 6.66462906

%et= 1.82863282
 0.14
y = 971.13x + 0.0125
0.12 R² = 0.9997

0.1

0.08
y

0.06

0.04

0.02

0
0 0.00002 0.00004 0.00006 0.00008 0.0001 0.00012 0.00014
x

m= 968.13 q0= 0.00103292

b= 0.0127 K= 76230.7087

0.00103292 ∗ 76230.7087 ∗ 𝑃
𝑞=
1 + 76230.7087 ∗ 𝑃

conclusión

con base a los porcentajes de error podemos decir que se ajusta mejor el modelo de languir