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RESINS
Description of the process
Industry scale optimization
1,2 2 1
J. P. Silva , J. Carvalho , E. J. G. Azevedo
1 - Instituto Superior Técnico, 2 – Resiquímica, S.A.
ABSTRACT
The present work aims the characterization of the elements of a polyester reactor and the optimization of
Unsaturated Polyester Resins process relating to its polymerization time. It consisted in resolution of
problems, evaluation of inherent relations and compilation of equipments and methods. A detailed flowsheet
and equipment information were elaborated and also an optimization process, consisting on the resolution of
problems and evaluation of equipments and methods.
An experimental method in the laboratory was developed to be adopted at the factory. It leads to a significant
reduction of the amount of time. With the new procedure, the total time of polymerization is reduced in about
1h20min.
Key-words: Unsaturated Polyester Resins, Production Time, Equipment, Set-Point, Maleic Anhydride,
Optimization.
In order to compare the most important factors The flowsheet for the process of unsaturated
witch influence the time production and its polyester resins in the chemical industry
optimization, were studied: glycol losses during Resiquímica, S.A., based on maleic anhydride,
distillation process, Set-Points which establish the phthalic anhydride and glycol (propylene glycol,
inherent distillation phase, and a method that ethylene glycol and diethylene glycol) is shown in
relays to a small modifying parameter to the fabric Figure 1.
method.
1
- Filtration equipment to clean the resin of gel
particles or extraneous matter which would
{
{ contaminate products derived from the resin.
25 lote 10028381
%glicol(v/v)
materials; 15
10
- Facilities for measurement of temperature at key
5
- A separate blending and thinning vessel for Figure 2 – %Glycol losses during distillation phase.
dilution to slightly above specification solids and
final adjustment to within this specification; The loss of glycol during distillation was
determined. The current excess (11%) guarantees
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the required composition according to the inherent 2.4 Vacuum operating system
losses.
Alongside this troubleshooting which is also The application of vacuum in order to minimize
related to the production time, several solutions the time production, therefore, a restructure of the
have been studied and presented as followed. energy integration is required, and can be seen in
Figure 4.
SP=102 ºC
2.2 Inert Gas
UF - Água
Refrig.
(d)
Application of inert gas flow facility, throw the
bottom of the vessel which allows a better mixture
between the raw materials. It increases the
velocity of the polymerisation reaction and the UF - Água
Refrig.
water extraction from the process.
3
is lower for longer times of first stage distillation. Table 1 – Time savings for the Polymerization reaction
with the new method (Test 2).
With this, the trend of optimum temperature in the
Time saved with Test 2
reactor when it must connect to hot utility after
Viscosity (mPa.s)
exothermic is 170 º C in order to lower total time Test 330-354 427-455 503-523
Test 2 Test 1
02:09
330-354 427-455 503-523 [7] PEREIRA, A.F., Estudo de Propriedades
viscosity ranges (mPa.s)
Eléctricas, Mecânicas e Dispersivas de Materiais
Compósitos de Nanofibra de Carbono em Matriz
Figure 5 – Polymerization time for the old and new de Poliéster Insaturado, Lisboa, 2007;
method (Test 2).
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