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SAFETY

DATA SHEET
ECRF Cold Fusion Black Cement
(CC-ECRF-001, CC-ECRF-002, CC-ECRF-010, CC-ECRF-200)
Date Prepared: Aug 10, 2016

SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


MANUFACTURER/ SUPPLIER ………………… Shaw Almex Fusion Canada
323 Glover Road, Stoney Creek, ON L8E 5M2
Tel: (905) 643-7750 Fax: (905) 643-7788
PRODUCT NAME .................................... ECRF Cold Fusion Black Cement
PRODUCT USES …………………………………… Industrial Adhesive
EMERGENCY PHONE #: ................................ (613) 996-6666 (CANUTEC)

SECTION 02: HAZARDS IDENTIFICATION



HAZARD CLASSIFICATION ……………………… Flammable Liquids — Category 2.
Skin Irritation — Category 2.
Germ Cell Mutagenicity — Category 1B.
Carcinogenicity — Category 1A.
Reproductive Toxicity — Category 1B
Eye Irritation — Category 2A.
Specific Target Organ Toxicity — Category 2, Category 3 (narcotic effects) single exposure.
Aspiration Hazard — Category 1.
SIGNAL WORD ………………………………..…. Danger.
HAZARD STATEMENTS ……………………….. H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed or enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
PRECAUTIONARY STATEMENTS …………. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No Smoking.
P233 Keep container tightly closed.
P240 Ground/ bond container and receiving equipment.
P241 Use explosion-proof equipment: electrical/ ventilating/ lighting.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 A dust/ fume/ gas/ mist/ vapour spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P403+P405+P235 Store locked up in a well-ventilated place. Keep cool.

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SAFETY DATA SHEET
ECRF Cold Fusion Black Cement
(CC-ECRF-001, CC-ECRF-002, CC-ECRF-010, CC-ECRF-200)
Date Prepared: Aug 10, 2016

SECTION 03: COMPOSITION/INFORMATION INGREDIENTS
HAZARDOUS INGREDIENTS CAS# WT %
Ethyl Acetate 141-78-6 10-30
Heptanes 142-82-5 10-30
Toluene 108-88-3 10-30
Acetone 67-64-1 5-10

SECTION 04: FIRST AID MEASURES
EYE CONTACT ……………………………………. Immediately flush with water for a minimum of 20 minutes. Get medical attention.
SKIN CONTACT ………………..................... Remove contaminated clothing. Wash affected area with water and soap. Seek medical attention if
irritation occurs or persists.
INGESTION …………………………………………. Rinse mouth with water. Do not induce vomiting, aspiration hazard. Get immediate medical attention.
INHALATION …………………………………….… If overexposure occurs, remove to fresh air.

SECTION 05: FIRE FIGHTING MEASURES
FLAMMABILITY …………………………………… Extremely flammable.
IF YES, UNDER WHICH CONDITIONS? …. Excessive heat, sparks and open flame.
EXTINGUISHING MEDIA ……………………... Carbon dioxide, dry chemical, foam, water fog.
HAZARDOUS COMBUSTION PRODUCTS . Combustion will result in the usual decomposition products, including oxides of carbon.
SPECIAL PROCEDURES ………………………... Firefighters should wear the usual protective gear; self-contained breathing apparatus.

SECTION 06: ACCIDENTAL RELEASE MEASURES


LEAK/SPILL ………….................................. Eliminate all sources of ignition. Wear a breathing apparatus. Dike area to prevent spreading, absorb
with inert material. Clean with water. Evacuate all non-essential personnel. Put in appropriate
container.

SECTION 07: HANDLING AND STORAGE


HANDLING PROCEDURES AND Avoid skin and eye contact. Maintain good personal hygiene.
Use adequate ventilation. Avoid smoking when material is used.
EQUIPMENT …….....................................
Avoid shock and friction. Avoid breathing vapors. Equipment must be grounded. Keep container
closed.
STORAGE NEEDS …………………………………. Keep away from heat, sparks, and open flames. Store in a dry and well-ventilated area. Keep container
closed.

SECTION 08: EXPOSURE CONTROLS/PERSONAL PROTECTION


INGREDIENTS TWA ACGIH TLV PEL OSHA PEL REL NIOSH
STEL STEL
Ethyl Acetate 400 ppm 400 ppm Not listed Not listed Not Available
Heptanes 400 ppm 500 ppm 500 ppm Not listed 85 ppm (TWA 10 hours) 40 ppm
(8 hours) (CEIL)
Toluene 200 ppm 20 ppm 300 ppm (CEIL) 150 ppm Not available
Acetone 500 ppm 750 ppm Not Listed 1000 ppm 250 ppm

HAND PROTECTION……………………………… A barrier cream. Wear protective gloves (Butyl rubber gloves).
RESPIRATORY PROTECTION………………... Avoid breathing vapours. Wear NIOSH/MSHA approved air supply respirator. Use NIOSH approved
respirator for organic vapours.
EYE PROTECTION………………………………… Safety glasses with side-shields. Splash proof chemical goggles or 8" face shield.
FOOTWEAR PROTECTION…………………… Not applicable.
CLOTHING PROTECTION......................... Wear adequate protective clothes.
OTHER..................................................... Eye wash facility should be close in proximity.
VENTILATION REQUIREMENTS............... Local exhaust at points of emission. Avoid breathing vapours and mists. If general ventilation or local
exhaust is inadequate, persons exposed to mists should wear approved breathing devices.

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SAFETY DATA SHEET
ECRF Cold Fusion Black Cement
(CC-ECRF-001, CC-ECRF-002, CC-ECRF-010, CC-ECRF-200)
Date Prepared: Aug 10, 2016

SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE ….................................... Black liquid.
ODOUR ................................................... Mild solvent odour.
ODOUR THRESHOLD (ppm) ................... Not available.
pH ………………………………………………………… Not applicable.
BOILING POINT …………………………………….. 89°C (192°F).
FLASH POINT (METHOD) ........................ <-18°C (0°F) (Acetone) (TCC).
LOWER EXPLOSIVE LIMIT ……………………. 1.1%.
UPPER EXPLOSIVE LIMIT ……………………... 12.8%.
EVAPORATION RATE …………………………….. 4.4 (BUTYL ACETATE = 1).
VAPOUR PRESSURE (mm Hg) …................ 60 @ 20°C (68°F).
VAPOUR DENSITY (AIR=1) ....................... 3.1.
SPECIFIC GRAVITY ……………………………… 0.82 @ 20°C (68°F).
SOLUBILITY IN WATER (% W/W) ….......... Insoluble.
COEFFICIENT OF WATER/OIL
DISTRIBUTION …………………………………….. Not applicable.
AUTO IGNITION TEMPERATURE …………. Not available.
DECOMPOSITION TEMPERATURE ……….. Not available.
.
VISCOSITY ………………………………………….. Approximately 2000 mPa s @ 20°C (68°F).

SECTION 10: STABILITY AND REACTIVITY


REACTIVITY CONDITIONS? …………………. Keep away from open flames and spark producing equipment. Stable under normal conditions of use
and storage. Avoid build-up of static electricity.
CHEMICAL STABILITY:
YES
NO, WHICH CONDITIONS? …………………. Strong oxidizing agents, strong reducing agents, acids, bases, or unstable chemicals, amines, alcohols,
water.
COMPATABILITY WITH OTHER
SUBSTANCES:
YES
NO, WHICH ONES? ................................ See reactivity conditions.
SENSITIVITY TO STATIC DISCHARGE ….… Not available.
HAZARDOUS PRODUCTS OF Hazardous decomposition is unlikely to occur. Thermal decomposition products may include carbon
DECOMPOSITION ………………………………. monoxide, carbon dioxide, smoke and fumes, hydrocarbon fragments and other undetermined
products.

SECTION 11: TOXICOLOGICAL INFORMATION


INGREDIENTS SKIN (LD50 DERMAL) INGESTION (LD50 ORAL)
Ethyl Acetate >2000 mg/kg (Rabbit) >2000 mg/kg (Rat)
Heptanes >2000 mg/kg (Rabbit) >5000 mg/kg (Rat)
Toluene 12125 mg/kg (Rabbit) 5580 mg/kg (Rat)
Acetone >7426 mg/kg (Guinea Pig) 5800 mg/kg (Rat)

ROUTE OF ENTRY:
Contains materials that can cause irritation to the skin.
SKIN CONTACT........................................
SKIN ABSORPTION ……………………………… May be harmful if absorbed through the skin. May cause dermatitis in sensitive individuals.
EYE CONTACT ………………………………….… Irritation to eyes.
INHALATION ……………………………………… Nose and throat irritation. Vapours may cause respiratory tract irritation, nausea, headache, and
dizziness.
INHALATION, CHRONIC ………………………. Not applicable.
INGESTION …………………………………………. See LD50 dermal and LD50 oral.
EFFECTS OF ACUTE EXPOSURE ……………. Refer to route of entry.

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SAFETY DATA SHEET
ECRF Cold Fusion Black Cement
(CC-ECRF-001, CC-ECRF-002, CC-ECRF-010, CC-ECRF-200)
Date Prepared: Aug 10, 2016

EFFECTS OF CHRONIC EXPOSURE ……….. May cause damage to the central nervous system, respiratory system, lungs, eyes, skin,
gastrointestinal tract, liver, spleen and kidneys.
IRRITANCY OF MATERIAL …………………... Refer to route of entry.
SENSITIZING CAPABILITY OF MATERIAL See effects of acute exposure.
CARCINOGENICITY OF MATERIAL. ……… Not available.
TERATOGENICITY ………………………………. Not available.
MUTAGENICITY …………………………………. Not available.
REPRODUCTIVE EFFECTS ……………………. Not available.
SYNERGISTIC MATERIALS ……………………. Not available.
OTHER ……………………………………………….. This product contains the following chemicals known to the state of California (proposition 65) to
cause cancer or reproductive toxicity - Toluene.

SECTION 12: ECOLOGICAL INFORMATION
BIODEGRADABILITY ENVIRONMENTAL .
TOXICITY TO FISH ………………………………. LC50:
Ethyl Acetate: ((pimephales promelas (fathead minnow)): >100 mg/l 96 hour flow through.
Heptanes: No data available.
Toluene: No data available.
Acetone: ((oncorhynchus mykiss (rainbow trout)): 5540 mg/l static test.
TOXICITY TO AQUATIC INVERTEBRATES .. EC50:
Ethyl Acetate: ((daphnia magna (water flea)): >100 mg/l static test.
Heptanes: No data available.
Toluene: No data available.
Acetone: No data available.
TOXICITY TO ALGAE ……………………………. EC50:
Ethyl Acetate: ((desmodesmus subspicatus (green algae)): >100 mg/l 72 hour static test.
Heptanes: No data available.
Toluene: No data available.
Acetone: ((chlorella pyrenoidosa) (algae)): 3020 mg/l 14 day.
BIOACCUMULATION …………………………... No data available.
MOBILITY IN SOIL ……………………………….. No data available.
OTHER ADVERSE EFFECTS …………………. No data available.

SECTION 13: DISPOSAL CONSIDERATIONS


WASTE DISPOSAL ……………………………... In accordance with municipal, provincial and federal regulations.
Dispose of all product wastes and water rinses in accordance with current local, provincial, and federal
regulations.

SECTION 14: TRANSPORT INFORMATION


T.D.G. CLASSIFICATION ……………………… Adhesives, Class 3, UN1133 Flammable Liquid, Packing Group II
Emergency Response Guide: 128
IATA CLASSIFICATION ………………………... Adhesives, Class 3, UN1133, Packing Group II

SECTION 15: REGULATORY INFORMATION


HAZARD INDEX …………………………………… Health: 2, Flammability: 3, Reactivity: 0
WHMIS (1988) CLASSIFICATION …………, Class B, Division 2, – Flammable Liquid
Class D, Division 2, Subdivision A – Very Toxic Material
Class D, Division 2, Subdivision B – Toxic, Eye and Skin Irritant
OSHA HAZARDS (HCS 1994) ……………….. Hazardous material by definition of hazard communication standard (29 CFR 1910.1200).
SECTION 313: ………………………………………. This product contains the following substances subject to the reporting requirements of section 313 of
Title III of Superfund Amendments and Reauthorization Act of 1986 and CFR part 372: Toluene
(CAS#108-88-3).

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SAFETY DATA SHEET
ECRF Cold Fusion Black Cement
(CC-ECRF-001, CC-ECRF-002, CC-ECRF-010, CC-ECRF-200)
Date Prepared: Aug 10, 2016

SECTION 16: OTHER INFORMATION
This information is furnished without warranty, representation, inducement or license of any kind, except that it is accurate to the best of Shaw
Almex Industries knowledge or is obtained from sources believed by Shaw Almex Industries to be accurate. Shaw Almex Industries makes no
representation and assumes no liability for any direct, incidental or consequential damages resulting from its use or reliance on same. Customers
are encouraged to conduct their own tests.

PREPARED BY: Shaw Almex Industries

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