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a
University of S~
ao Paulo, P.O. Box 23, 13635-900 Pirassununga, SP, Brazil
b
CSIRO Forestry and Forest Products, Private Bag 10, Clayton South MDC, Vic. 3169, Australia
c
ASSEDO Pty Ltd., 75 Sandringham Road, Sandringham, Vic. 3191, Australia
Abstract
This project evaluated the performance of thin fibre-cement elements produced from alternative raw materials using the Hat-
schek process, with a view to their use in low-cost housing. Sisal and banana fibres were prepared using mechanical and kraft
pulping procedures while residual Eucalyptus grandis pulp was obtained from a commercial pulp mill. Granulated blast furnace slag
(BFS) was used as the major component of an alternative hydraulic binder and ordinary Portland cement as a control. Composites
were prepared using a slurry vacuum de-watering process, pressing and air-curing. At fibre contents of 8–12% by mass, moduli of
rupture (MOR) up to 23 MPa and fracture toughness (FT) values in the range of 0.6–1.7 kJ/m2 were obtained at 28 days. After 12
months of exposure under temperate and tropical conditions, the MOR of the BFS-based composites had decreased to values in the
range of 6.6–10.1 MPa. FT values remained stable or even increased with the weathering exposure. The results indicate that the
mechanical performance of the composites being studied is currently satisfactory, but further optimisation of formulation and
processing parameters should be investigated.
Ó 2002 Elsevier Science Ltd. All rights reserved.
Keywords: Fibre-cement; Construction materials; Blast furnace slag; Eucalyptus grandis pulp; Sisal pulp; Banana pulp; Microstructure
0958-9465/02/$ - see front matter Ó 2002 Elsevier Science Ltd. All rights reserved.
doi:10.1016/S0958-9465(02)00071-9
586 H. Savastano Jr et al. / Cement & Concrete Composites 25 (2003) 585–592
ratory environment of 23 2 °C and 50 5% relative while the exposure of the remaining samples commenced
humidity prior to mechanical and physical testing. at both sites in July 1999.
At a total age of 13 months, test specimens were cut
as described in the section on test methods and stored in
laboratory conditions for 7 days to achieve equilibrium
4. Test methods
moisture content prior to mechanical testing. Table 2
lists the main long term climate averages for the Aus-
A three point bend configuration was employed in the
tralian and Brazilian exposure site.
determination of modulus of rupture (MOR), fracture
toughness (FT) and modulus of elasticity (MOE). A
span of 100 mm and a deflection rate of 0.5 mm/min
6. Results and discussion
were used for all tests in an Instron model 1185 universal
testing machine. Fracture energy was calculated by in-
Table 3 summarises the main mechanical and physi-
tegration of the load–deflection curve to the point cor-
cal properties of BFS and OPC matrices with different
responding to a reduction in load carrying capacity to
fibre types and contents when tested at age 28 days.
50% of the maximum observed. For the purpose of this
Figs. 1–4 compare the range of properties measured at
study, the FT was measured as the fracture energy
each fibre content with those of corresponding com-
divided by specimen width and depth at the failure lo-
posites after aging. Table 4 details the properties of
cation. Nine flexural specimens were tested for each
composites after storage in a controlled environment or
formulation and condition of exposure. The mechanical
exposure to weathering in temperate and tropical con-
test procedures employed are described in greater detail
ditions for 1 year.
by Savastano et al. [9].
Water absorption (WA) values were obtained from
6.1. Composites based on clinker free binders
six tested flexural specimens following the procedures
specified in ASTM C 948-81.
The processing behaviour of BFS-based matrices in
Fracture surfaces of composites were analysed using
slurry de-watered composite production was akin to
a Philips XL30 field emission gun scanning electron
that of OPC. The addition of 4% and 8% fibre provided
microscope (SEM). To facilitate fibre observation the
significant improvements in flexural strengths which
images were taken after tilting the samples 75° in rela-
were more than doubled at the higher loading (Fig. 1).
tion to the horizontal plane. Observation procedures
The MOR and FT reached by OPC reinforced with 8%
were similar to those employed by Coutts and Kightly
of waste fibres were inside the range of corresponding
[14].
BFS-based composites (Figs. 1 and 2), confirming
the acceptable performance of the alternative binder in
fibre-cement products.
5. Weathering conditions At fibre loadings of 4% and 8% by mass, composites
based on BFS 6G2L exhibited relatively low strengths,
To determine the effect of weathering on the prop- in the region of 13.1–16.8 MPa. The poor performance
erties of the composites, some of the prepared samples of composites based on this formulation was probably a
were exposed to temperate and tropical weather condi- result of the lower total activator content failing to
tions in Melbourne, Australia, and Pirassununga, Bra- promote sufficient matrix strength development to allow
zil, respectively. The samples were exposed 28 days after effective stress transfer to the reinforcement.
manufacture in racks inclined 45° and facing north in As previously observed in the case of wood fibre
Melbourne (latitude 37°490 S) and Pirassununga (latitude reinforced OPC [9,15], FT was the property most
21°590 S). The exposure in Melbourne of composites re- improved by the inclusion of reinforcement as high-
inforced with E. grandis pulp commenced in April 1999, lighted in Fig. 2. Warden et al. [16] previously reported
Table 2
Climate averages
Exposure site Temperature (°C) Relative humidity (%) Average rainfall (mm/year)
Ave max/month Ave min/month Ave max/month Ave min/month
Melbourne, Vic, AUa 25.8/Jan 5.9/July 82/ June 60/Jan–Dec 654
Pirassununga, SP, BRb 30.1/Jan–Feb 9.5/July 77/Jan–Feb 63/Aug 1363
a
Source: Bureau of Meteorology, Australia.
b
Source: Air Force Academy, Defence Ministry, Brazil.
588 H. Savastano Jr et al. / Cement & Concrete Composites 25 (2003) 585–592
Table 3
Mechanical and physical properties of composites at 28 daysa
Fibre Binder MOR (MPa) FT (kJ/m2 ) MOE (GPa) WA (% by mass)
Type Content (% by mass)
Nil – BFS 6G2L 8.1 2.2 0.03 0.01 11.6 1.7 17.6 0.9
Waste E. grandis kraft 4 BFS 10G2L 14.3 0.9 0.25 0.02 8.9 1.1 23.9 1.2
8 18.0 1.4 0.75 0.11 6.6 0.6 28.0 1.4
12 18.2 2.8 1.25 0.20 5.0 0.6 32.3 1.7
8 OPC 21.4 0.9 0.82 0.11 11.4 0.9 20.7 0.7
By-product sisal kraft 4 BFS 6G2L 13.1 0.4 0.53 0.12 7.7 0.7 26.6 0.5
8 16.8 1.7 1.41 0.22 6.1 0.5 29.0 1.0
12 14.7 2.0 1.68 0.22 4.3 0.4 33.1 1.3
By-product sisal 4 BFS 10G2L 15.3 0.9 0.30 0.03 8.4 0.5 26.0 0.4
CTMP 8 18.6 0.6 0.82 0.21 6.5 0.5 30.0 0.7
12 10.6 1.4 1.60 0.28 3.0 0.3 36.8 0.7
Banana beaten kraft 4 BFS 10G2L 15.5 1.4 0.24 0.03 7.7 0.9 25.2 0.3
8 21.8 1.2 0.59 0.06 6.7 0.6 27.2 0.6
12 22.8 1.6 1.74 0.31 4.3 0.3 29.3 0.5
Banana screened 4 BFS 10G2L 17.7 0.4 0.32 0.05 8.5 0.6 26.6 0.5
CTMP 8 21.0 1.1 0.76 0.12 6.7 0.5 30.4 1.2
12 Incomplete setting of binder
8 OPC 21.5 1.8 0.60 0.09 10.0 0.6 23.0 1.3
a
single standard deviations of the means indicated.
Fig. 1. Variation in MOR with matrix type and fibre content in the Fig. 2. Variation in FT with matrix type and fibre content in the short
short term, and with condition of exposure (laboratory and tropical term, and with condition of exposure (laboratory and tropical
weathering) in the long term. weathering) in the long term.
toughness values in excess of 1.7 kJ/m2 at a Pinus radiata and 12% fibre contents. It is thought that lower matrix
fibre content of 12%, representing at least a 40-fold strength relative to that of the fibre–matrix bond may
improvement over neat matrix values. Table 3 shows have led to an increased contribution to energy dissi-
that BFS 6G2L-based composites developed consider- pation through microcracking processes in the vicinity
able toughness, in the range of 1.41–1.68 kJ/m2 at 8% of fibre surfaces.
H. Savastano Jr et al. / Cement & Concrete Composites 25 (2003) 585–592 589
Table 4
Mechanical and physical properties of BFS 10G2L-based composites at 13 monthsa
Fibre Exposure condition MOR (MPa) FT (kJ/m2 ) MOE (GPa) WA (% by mass)
Type Content (% by mass)
Waste E. grandis kraft 12 Lab. 12.6 0.8 1.35 0.21 4.1 0.3 30.9 0.4
Vic., AU 8.6 0.7 1.14 0.16 2.4 0.3 33.0 1.6
SP, BR 6.6 1.1 1.17 0.34 1.9 0.3 36.6 1.1
By-product sisal CTMP 8 Lab. 13.1 1.1 1.43 0.25 4.7 0.3 30.8 0.6
Vic., AU 10.1 1.3 1.16 0.19 3.8 0.6 30.4 1.3
SP, BR 7.7 1.7 1.01 0.27 3.5 0.8 33.4 1.7
Banana CTMP 8 Lab. 12.8 1.4 1.10 0.18 4.8 0.3 31.3 0.3
Vic., AU 8.8 1.0 1.05 0.17 3.2 0.5 33.8 1.4
SP, BR 8.6 0.7 0.98 0.12 3.6 0.3 33.0 1.1
a
single standard deviations of the means indicated.
590 H. Savastano Jr et al. / Cement & Concrete Composites 25 (2003) 585–592
best performance in terms of flexural strength in BFS fibre content the E. grandis reinforced material was
matrices at pulp loadings of 8% and 12%. These mate- more dense and stiffer, probably due to the smaller fibre
rials possessed strengths of approximately 22 MPa dimensions allowing better consolidation at this loading.
(Table 3 and Fig. 1), similar to those of the correspond- Greater fibre compliance might also be expected as a
ing OPC reference composites. Chemical pulps are, result of lignin removal during chemical pulping.
however, expensive and mill capital costs demand un- The results of this work represent a significant im-
acceptable investment levels. Mechanical pulps, in which provement over those previously reported by Savastano
most of the original lignin is retained, can provide ade- et al. [21]. In the earlier study, which used a dough
quate reinforcement in air-cured wood fibre-cement mixing process for composite preparation, MOR values
products [20]. These pulps are cheaper to produce and of less than 5 MPa were reported for BFS 10G2L-based
smaller mills can be operated viably at lower outputs, mortars reinforced with waste E. grandis pulp.
with less capital outlay and with reduced effluent prob-
lems.
The range of strength and FT values exhibited by 6.3. The weathering effect
BFS-based composites reinforced with CTMPs of sisal
and banana are shown in Table 3. Mean strengths at a Fig. 1 shows one year of external exposure to tropical
fibre content of 8% by mass were between 19 and 21 weather resulted in a considerable reduction in strength,
MPa. This figure compares favourably with the strengths which had fallen to 6.6 MPa in the case of the 12% E.
obtained for air-cured OPC reinforced with P. radiata grandis formulation exposed in Brazil. The loss in me-
CTMP [20] or kraft pulped banana fibre [9,10]. The chanical strength of composites subjected to either nat-
mechanical behaviour of BFS-based composites dropped ural weathering or ageing in the controlled environment
drastically at the 12% content of the waste-derived ba- is mainly attributable to matrix carbonation. Such a
nana and sisal CTMPs. The substantial amount of lignin mechanism [17] consumes calcium ions from ettringite
and extractives remaining in the fibres may have led to and from the calcium hydroxide occasionally present in
disruption of matrix hydration and incomplete setting of BFS cement, and simultaneously lowers the Ca/Si ratio
composites at higher loadings of banana CTMP. of the calcium silicate hydrate as discussed by Taylor
BFS incorporating 12% of waste E. grandis kraft fibre [22]. Qualitative evaluation using an indicator solution
exhibited a FT value of 1.25 kJ/m2 , considerably lower of 2% phenolphthalein in anhydrous ethanol revealed
than the values for composites with the same loading of that the aged composites were completely carbonated.
sisal or banana pulp (Table 3). The short length of the The greater severity of a tropical environment on
hardwood pulps (Table 1) is recognised as the main composite properties can be attributed to a subsequent
reason for the low energy absorption during failure. leaching under the action of rainwater (Table 2) and to
Fibre pullout is limited at the post-cracking stage, and is the propagation of microcracks generated by the cyclic
confirmed by the image of the fracture surface in Fig. 5. action of temperature and moisture. WA values support
MOE and the physical properties of composites such a supposition (Tables 3 and 4). After 13 months of
containing the five different types of waste pulps were external weathering the WA of composites with 12% E.
similar at the several fibre loadings (Table 3). At 4% grandis kraft and 8% sisal or banana CTMP in BFS
10G2L reached 37% and 33% by mass respectively, ex-
ceeding their values at 28 days and after long term
storage in a controlled environment.
MOE dropped to between 1.9 and 4.1 GPa after 13
months weathering. 12% E. grandis in BFS was again
the worst performer (Fig. 3 and Table 4).
Fig. 2 and Table 4 show that, after a period of
weathering or laboratory ageing, composites demon-
strated FT values similar to or even higher than those at
28 days. 8% banana CTMP in BFS exposed in any of the
environments possessed a toughness of about 1.0 kJ/m2 ,
which corresponds to an increase of more than 30% in
comparison with the short term value. The improve-
ments in ductility can be linked to the losses in MOR
and MOE, confirming the expected compromise be-
tween strength and ductility in such composites.
Fig. 5. SEM image of the fracture surface of residual E. grandis kraft FT values in the range of 1.0–1.2 kJ/m2 after a year of
pulp in BFS 10G2L. Hydration age: 72 days. weathering indicate that the integrity of the fibres within
H. Savastano Jr et al. / Cement & Concrete Composites 25 (2003) 585–592 591
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