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JEE Main 2018

Conducted on 08-Apr-2018

Total time 180 mins

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JEE Main 2018 Question Paper
ATTEMPT ONLINE: https://www.exambazaar.com/assessment/jee-main-2018

JEE Main 2018

Duration: 180 mins Max Score: 360

Test Instructions
1. The test is of 3 hours duration
2. The Test Booklet consists of 90 questions. The maximum marks are 360
3. There are three parts in the question paper A, B, C consisting of Chemistry, Mathematics and
Physics having 30 questions in each part of equal weightage. Each question is allotted 4 (four)
marks for correct response
4. ¼ (one-fourth) marks of the total marks allotted to the question will be deducted for indicating
incorrect response of each question. No deduction from the total score will be made if no
response is indicated for an item
5. There is only one correct response for each question.

Te st Se ctions

Se ction Q ue stions Marks


Physics 30 Questions (1 - 30) 120
Mathematics 30 Questions (31 - 60) 120
Chemistry 30 Questions (61 - 90) 120

Color coding for type s of Q ue stions

Code Type of Q ue stion


Single Option Correct Multiple Choice Question
One or More Options Correct Multiple Choice Question with Multiple Answers
Numerical Numerical

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Q. 1 Single Option Correct +4 -1

It is found that if a neutron suffers an elastic collinear collision with deuterium at rest,
fractional loss of its energy is P ; while for its similar collision with carbon nucleus at rest,
fractional loss of energy is P . The values of P and P are respectively:

A. (0, 0)
B. (0, 1)
C. (0.89, 0.28)
D. (0.28, 0.89)

Q. 2 Single Option Correct +4 -1

The mass of a hydrogen molecule is 3.32 X 10⁻²⁷ kg. If 10²³ hydrogen molecules strike, per
second, a fixed wall of area 2 cm² at an angle of 45° to the normal, and rebound elastically
with a speed of 10³ m/s, then the pressure on the wall is nearly :

A. 2.35 x 10² N/m²


B. 4.70 x 10² N/m²
C. 2.35 x 10³ N/m²
D. 4.70 x 10³ N/m²

Q. 3 Single Option Correct +4 -1

A solid sphere of radius r made of a soft material of bulk modulus K is surrounded by a


liquid in a cylindrical container. A massless piston of area a floats on the surface of the
liquid, covering entire cross section of cylindrical container. When a mass m is placed on
the surface of the piston to compress the liquid, the fractional decrement in the radius of
the sphere, (dr/r) is

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A. mg/3Ka
B. mg/Ka
C. Ka/mg
D. Ka/3mg

Q. 4 Single Option Correct +4 -1

Two batteries with e.m.f. 12 V and 13 V are connected in parallel across a load resistor of
10Ω. The internal resistances of the two batteries are 1Ω and 2Ω respectively. The voltage
across the load lies between :

A. 11.4 V and 11.5 V


B. 11.7 V and 11.8 V
C. 11.6 V and 11.7 V
D. 11.5 V and 11.6 V

Q. 5 Single Option Correct +4 -1

A particle is moving in a circular path of radius a under the action of an attractive potential
U = -k/2r². Its total energy is :

A. 0
B. -3/2 k/a²
C. -k/4a²
D. k/2a²

Q. 6 Single Option Correct +4 -1

Two masses m₁ = 5 kg and m₂ = 10 kg, connected by an inextensible string over a


frictionless pulley, are moving as shown in the figure. The coefficient of friction of
horizontal surface is 0.15. The minimum weight m that should be put on top of m₂ to stop
the motion is :

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A. 43.3 kg
B. 10.3 kg
C. 18.3 kg
D. 27.3 kg

Q. 7 Single Option Correct +4 -1

If the series limit frequency of the Lyman series is vₗ, then the series limit frequency of the
Pfund series is :

A. vₗ / 16
B. vₗ / 25
C. 25vₗ
D. 16vₗ

Q. 8 Single Option Correct +4 -1

Unpolarized light of intensity I passes through an ideal polarizer A. Another identical


polarizer B is placed behind A. The intensity of light beyond B is found to be 1/2. Now
another identical polarizer C is placed between A and B. The intensity beyond B is now
found to be I/8. The angle between polarizer A and C is :

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A. 45°
B. 60°
C. 0°
D. 30°

Q. 9 Single Option Correct +4 -1

An electron from various excited states of the hydrogen atom emits radiation to come to
the ground state. Let λₙ, λ be the de Broglie wavelength of the electron in the nᵗʰ state and
the ground state respectively. Let An be the wavelength of the emitted photon in the
transition from the nth state to the ground state. For large n, (A, B are constants)

A. ∧²ₙ ≈ A + Bλ²ₙ
B. ∧²ₙ ≈ λ
C. ∧ₙ ≈ A + B/λ²ₙ
D. ∧ₙ ≈ A + Bλₙ

Q. 10 Single Option Correct +4 -1

The reading of the ammeter for a silicon diode in the circuit given in figure (1)

A. 11.5 mA
B. 13.5 mA
C. 0
D. 15 mA

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Q. 11 Single Option Correct +4 -1

An electron, a proton and an alpha particle having the same kinetic energy are moving in
circular orbits of radii re, rp, rα respectively in a uniform magnetic field B. The relation
between re, rp ,rα is:

A. re < rp < rα
B. re < rα < rp
C. re > rp = rα
D. re < rp = rα

Q. 12 Single Option Correct +4 -1

A parallel plate capacitor of capacitance 90 pF is connected to a battery of emf 20 V. If a


dielectric material of dielectric K = 5/3 is inserted between the plates, the magnitude of the
induced charge will be

A. 2.4 nC
B. 0.9 nC
C. 1.2 nC
D. 0.3 nC

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Q. 13 Single Option Correct +4 -1

For an RLC circuit driven with voltage of amplitude Vm and frequency ωo = 1/√LC the
current exhibits resonance. The quality factor, Q is given by :

A. R/(ωoC)
B. CR/ωo
C. ωoL/R
D. ωoR/L

Q. 14 Single Option Correct +4 -1

A telephonic communication service is working at carrier frequency of 10 GHz. Only 10% of


it is utilized for transmission. How many telephonic channels can be transmitted
simultaneously if each channel requires a bandwidth of 5 kHz ?

A. 2 x 10⁵
B. 2 x 10⁶
C. 2 x 10³
D. 2 x 10⁴

Q. 15 Single Option Correct +4 -1

A granite rod of 60 cm length is clamped at its middle point and is set into longitudinal
vibrations. The density of granite is 2.7 x 10³ kg/m³ and its Young's modulus is 9.27 x 10¹⁰
Pa. What will be the fundamental frequency of the longitudinal vibrations?

A. 10 kHz
B. 7.5 kHz
C. 5 kHz
D. 2.5 kHz

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Q. 16 Single Option Correct +4 -1

Seven identical circular planar disks, each of mass M and radius R are welded symmetrically
as shown in figure (1). The moment of inertia of the arrangement about the axis normal to
the plane and passing through the point Pis :

A. 73/2 MR²
B. 181/2 MR²
C. 19/2 MR²
D. 55/2 MR²

Q. 17 Single Option Correct +4 -1

Three concentric metal shells A, B and C of respective radii a, b and c (a < b < c) have
surface charge densities +σ , -σ and +σ respectively. The potential of shell B is :

A. σ/εo[(b²-c²)/b + a]
B. σ/εo[(b²-c²)/c + a]
C. σ/εo[(a² - b²)/a + c]
D. σ/εo[(a² - b²)/b + c]

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Q. 18 Single Option Correct +4 -1

In a potentiometer experiment, it is found that no current passes through the


galvanometer when the terminals of the cell are connected across 52 cm of the
potentiometer wire. If the cell is shunted by a resistance of 5Ω, a balance is found when the
cell is connected across 40 cm of the wire. Find the internal resistance of the cell.

A. 2Ω
B. 2.5Ω
C. 1Ω
D. 1.5Ω

Q. 19 Single Option Correct +4 -1

An EM wave from air enters a medium. The electric fields are E₁ = E₀₁ x̂cos [2πν (z/c - t)] in
air and E₂ = E₀₂ x̂cos [k (2z - ct)] in the medium where the wave number k and frequency ν
refer to their values in the air. The medium is non-magnetic. If ∈ᵣ₁ and ∈ᵣ₂ refer to relative
permittivities of air and medium respectively, which of the following options is correct?

A. ∈ᵣ₁ / ∈ᵣ₂ = 1/4


B. ∈ᵣ₁ / ∈ᵣ₂ = 1/2
C. ∈ᵣ₁ / ∈ᵣ₂ = 4
D. ∈ᵣ₁ / ∈ᵣ₂ = 2

Q. 20 Single Option Correct +4 -1

The angular width of the central maximum in a single slit diffraction pattern is 60°. The
width of the slit is 1 μm. The slit is illuminated by monochromatic plane waves. If another
slit of same width is made near it, Young's fringes can be observed on a screen placed at a
distance 50 cm from the slits. If the observed fringe width is 1 cm, what is slit separation
distance ?
(i.e. distance between the centres of each slit.)

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A. 75 μm
B. 100 μm
C. 25 μm
D. 50 μm

Q. 21 Single Option Correct +4 -1

A silver atom in a solid oscillates in simple harmonic motion in some direction with a
frequency of 10¹²/sec. What is the force constant of the bonds connecting one atom with
the other ? (Mole wt of silver =108 and Avogadro number = 6.02 x 10²³ gm mole⁻¹)

A. 2.2 N/m
B. 5.5 N/m
C. 6.4 N/m
D. 7.1 N/m

Q. 22 Single Option Correct +4 -1

From a uniform circular disc of radius R and mass 9 M, a small disc of radius R/3 is removed
as shown in the figure (1). The moment of inertia of the remaining disc about an axis
perpendicular to the plane of the disc and passing through centre of disc is :

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A. 10 MR²
B. 37/9 MR²
C. 4 MR²
D. 40/9 MR²

Q. 23 Single Option Correct +4 -1

In a collinear collision, a particle with an initial speed Vo strikes a stationary particle of the
same mass. If the final total kinetic energy is 50% greater than the original kinetic energy,
the magnitude of the relative velocity between the two particles. after collision, is :

A. Vo/2
B. Vo/√2
C. Vo/4
D. √2 Vo

Q. 24 Single Option Correct +4 -1

The dipole moment of a circular loop carrying a current I, is m and the magnetic field at the
centre of the loop is B1. When the dipole moment is doubled by keeping the current
constant, the magnetic field at the centre of the loop is B2. The ratio B1/ B2 is :

A. √2
B. 1/√2
C. 2
D. √3

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Q. 25 Single Option Correct +4 -1

The density of a material in the shape of a cube is determined by measuring three sides of
the cube and its mass. If the relative errors in measuring the mass and length are
respectively 1.5% and 1%, the maximum error in determining the density is:

A. 4.5 %
B. 6%
C. 2.5 %
D. 3.5 %

Q. 26 Single Option Correct +4 -1

On interchanging the resistances, the balance point of a meter bridge shifts to the left by
10cm. The resistance of their series combination is 1kΩ. How much was the resistance on
the left slot before interchanging the resistances ?

A. 550 Ω
B. 910 Ω
C. 990 Ω
D. 505 Ω

Q. 27 Single Option Correct +4 -1

In an a.c. circuit, the instantaneous e.m.f. and current are given by


e = 100 sin 30 t
i = 20 sin (30 t - π/4)
In one cycle of a.c., the average power consumed by the circuit and the wattless current
are, respectively :

A. 50/√2 , 0
B. 50 , 0
C. 50 , 10
D. 1000/√2 , 10

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Q. 28 Single Option Correct +4 -1

All the graphs (1), (2), (3), (4) are intended to represent the same motion. One of them does
it incorrectly. Pick it up.

A. 1
B. 2
C. 3
D. 4

Q. 29 Single Option Correct +4 -1

Two moles of an ideal monoatomic gas occupies a volume V at 27°C. The gas expands
adiabatically to a volume 2 V. Calculate (a) the final temperature of the gas and (b) change
in its internal energy.

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A. (a) 189 K (b) -2.7 kJ


B. (a) 195 K (b) 2.7 kJ
C. (a) 189 K (b) 2.7 kJ
D. (a) 195 K (b) -2.7 kJ

Q. 30 Single Option Correct +4 -1

A particle is moving with a uniform speed in a circular orbit of radius R in a central force
inversely proportional to the nᵗʰ power of R. If the period of rotation of the particle is T,
then :

A. T∝R⁽ⁿ ⁺ ¹⁾/²
B. T∝Rⁿ/²
C. T∝R³/² for any n
D. T∝Rⁿ/² ⁺ ¹

Q. 31 Single Option Correct +4 -1

If the tangent at (1, 7) to the curve x² = y - 6 touches the circle x² + y² + 16x + 12y + c = 0 then
the value c is:

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A. 85
B. 95
C. 195
D. 185

Q. 32 Single Option Correct +4 -1

If L1 is the line of intersection of the planes 2x - 2y + 3z = 0, x - y + z = 0 and L2 is the line of


intersection of the planes x + 2y - z - 3=0, 3x - y + 2z = 0, then the distance of the origin from
the plane, containing the lines L1 and L2, is :

A. 1/2√2
B. 1/√2
C. 1/4√2
D. 1/3√2

Q. 33 Single Option Correct +4 -1

If α, β ∈ C are the distinct roots, of the equation x² - x + 1 = 0, then α¹⁰¹ + β equal to:

A. 1
B. 2
C. -1
D. 0

Q. 34 Single Option Correct +4 -1

Tangents are drawn to the hyperbola 4x² - y² = 36 at the points P and Q. If these tangents
intersect at the point T(0, 3) then the area (in sq. units) of ΔPTQ is :

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A. 60√3
B. 36√5
C. 45√5
D. 54√3

Q. 35 Single Option Correct +4 -1

If the curves y² = 6x, 9x² + by² = 16 intersect each other at right angles, then the value of b is
:

A. 4
B. 9/2
C. 6
D. 7/2

Q. 36 Single Option Correct +4 -1

If the system of linear equations


x + ky + 3z = 0
3x + ky - 2z = 0
2x + 4y - 3z = 0
has a non-zero solution (x, y, z), then xz/y² is equal to:

A. -30
B. 30
C. -10
D. 10

Q. 37 Single Option Correct +4 -1

Let S = {x ∈ R : x≥ 0 and 2|√x - 3| + √x(√x - 6 ) + 6 = 0}. Then S

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A. contains exactly two elements


B. contains exactly four elements
C. is an empty set
D. contains exactly one element.

Q. 38 Single Option Correct +4 -1

If sum of all the solutions of the equation 8 cos x . (cos(π/6 + x) . cos(π/6 - x) - 1/2) = 1 in {0,
π} is kπ, then k is equal to:

A. 8/9
B. 20/9
C. 2/3
D. 13/9

Q. 39 Single Option Correct +4 -1

A bag contains 4 red and .6 black balls. A ball is drawn at random from the bag, its colour is
observedand this ball along with two additional balls of the same colour are returned to
the bag. If now a ball is drawn - at random from the bag, then the probability that this
drawn ball is red, is :

A. 1/5
B. 3/4
C. 3/10
D. 2/5

Q. 40 Single Option Correct +4 -1

Let f(x) = x² + 1/x² and g(x) = x - 1/x, x ∈ R - [-1, 0, 1]. If h(x) = f(x)/g(x), then the local minimum
value of h(x) is:

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A. -2√2
B. 2√2
C. 3
D. -3

Q. 41 Single Option Correct +4 -1

Two sets A and B are as under


A= {(a, b) ∈ R x R : la - 5| < 1 and |b - 5| < 1};
B= {(a, b) ∈ R x R : 4(a - 6)² + 9(b - 5)² ≤ 36}. Then :

A. A ∩ B = Φ (an empty set)


B. neither A ⊂ B nor B ⊂ A
C. B⊂A
D. A⊂B

Q. 42 Single Option Correct +4 -1

The Boolean expression


-(p v q) v (~ p ∧ q) is equivalent to :

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A. q
B. ~q
C. ~p
D. p

Q. 43 Single Option Correct +4 -1

Tangent and normal are drawn at P(16, 16) on the parabola y² = 16x, which intersect the
axis of the parabola at A and B, respectively. If C is the centre of the circle through the
points P, A and B and ∠CPB = θ, then a value of tan θ is :

A. 3
B. 4/3
C. 1/2
D. 2

Q. 44 Single Option Correct +4 -1

Find the value of ordered pair (A, B) in accordance to the matrix given in figure (1)

A. (- 4, 5)
B. (4, 5)
C. (-4, -5)
D. ( - 4, 3)

Q. 45 Single Option Correct +4 -1

The sum of the co-efficients of all odd degree terms in the expansion of the given equation
in figure (1) is:

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A. 1
B. 2
C. -1
D. 0

Q. 46 Single Option Correct +4 -1

Find the value of m in accordance with the following equation given in figure (1) where a₁,
a₂, a₃, ........., a₄₉ is in A.P.

A. 34
B. 33
C. 66
D. 68

Q. 47 Single Option Correct +4 -1

A straight line through a fixed point (2, 3) intersects the coordinate axes at distinct points P
and Q. If 0 is the origin and the rectangle OPRQ is completed, then the locus of R is :

A. 3x + 2y = xy
B. 3x + 2y = 6xy
C. 3x + 2y = 6
D. 2x + 3y = xy

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Q. 48 Single Option Correct +4 -1

Find the value of the equation given in figure (1):

A. 4π
B. π/4
C. π/8
D. π/2

Q. 49 Single Option Correct +4 -1

Let g(x) = cos x², f(x) =√x, and α, β (α < β) be the roots of the quadratic equation 18x² - 9πx +
π² = 0. Then the area (in sq. units) bounded by the curve y = (gof)(x) and the lines x = α, x = β
and y = 0, is:

A. 1/2(√3 - √2)
B. 1/2(√2 - 1)
C. 1/2(√3 - 1)
D. 1/2(√3 + 1)

Q. 50 Single Option Correct +4 -1

For each t € R, let [t] be the greatest integer less than or equal to t. Then find the value of
the given equation:

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A. is equal to 120
B. does not exist (in R).
C. is equal to 0
D. is equal to 15

Q. 51 Single Option Correct +4 -1

Find the standard deviation of the 9 items x₁, x₂, x₃......x₉ in accordance to the given
equation given in figure

A. 2
B. 3
C. 9
D. 4

Q. 52 Single Option Correct +4 -1

The integral ∫(sin²x cos²x)/(sin⁵x + cos³xsin²x + sin³xcos²x + cos⁵x)² dx is equal to:


(where C is a constant of integration)

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A. 1/(1 + cot³x) + C
B. -1/(1 + cot³x) + C
C. 1/3(1 + tan³x) + C
D. -1/3(1 + tan³x) + C

Q. 53 Single Option Correct +4 -1

Let S = (t ∈ R : f(x) = f(x) = |x - π| . (e^|x| - 1) sin|x| is not differentiable at t). Then the set S
is equal to :

A. {π}
B. {0 π}
C. Φ (an empty set)
D. {0}

Q. 54 Single Option Correct +4 -1

Let y = y(x) be the solution of the differential equation


sin x (dy/dx) + y cosx = 4x, x ∈ (0, π). If y(π/2) = 0, then y(π/6) is equal to:

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A. -8/9π^2
B. -4/9π^2
C. 4/9√3π^2
D. -8/9√3π^2

Q. 55 Single Option Correct +4 -1

Refer to figure

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A. 256
B. 84
C. 336
D. 315

Q. 56 Single Option Correct +4 -1

The length of the projection of the line segment joining the points (5, —1, 4) and (4, —1, 3)
on the plane, x + y + z = 7 is :

A. 1/3
B. √2/√3
C. 2/√3
D. 2/3

Q. 57 Single Option Correct +4 -1

PQR is a triangular park with PQ = PR = 200 m. A T.V. tower stands at the mid-point of QR. If
the angles of elevation of the top of the tower at P, Q and R are respectively 45°, 30° and
30°, then the height of the tower (in m) is :

A. 100√3
B. 50√2
C. 100
D. 50

Q. 58 Single Option Correct +4 -1

From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary is to be


selected and arranged in a row of shelf so that the dictionary is always in the middle. The
number of such arrangements is :

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A. at least 500 but less than 750


B. at least 750 but less than 1000
C. at least 1000
D. less than 500

Q. 59 Single Option Correct +4 -1

Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of the series 1²
+ 2.2² + 3² + 2.4² + 5² + 2.6² + ....................... If B - 2A = 100 λ, then λ is equal to:

A. 464
B. 496
C. 232
D. 248

Q. 60 Single Option Correct +4 -1

Let the orthocentre and centroid of triangle be A(-3, 8) and B(3, 3) respectively. If C is the
circumcentre of this triangle, then the radius of the circle having line segment AC as
diameter, is

A. 3(√5/√2)
B. 3√5/2
C. √10
D. 2√10

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Q. 61 Single Option Correct +4 -1

Total number of lone pair of electrons in I₃⁻ ion is :

A. 9
B. 12
C. 3
D. 6

Q. 62 Single Option Correct +4 -1

Which of the following salts is the most basic in aqueous solution ?

A. FeCl₃
B. Pb(CH₃COO)₂
C. AI(CN)₃
D. CH₃COOK

Q. 63 Single Option Correct +4 -1

Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A
reacts with Br₂ to form product B. A and B are respectively (among (1), (2), (3), (4)):

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A. 1
B. 2
C. 3
D. 4

Q. 64 Single Option Correct +4 -1

The increasing order of basicity of the following compounds (among (1), (2), (3), (4)) is :

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A. (b) < (a) < (d) < (c)


B. (d) < (b) < (a) < (c)
C. (a) < (b) < (c) < (d)
D. (b) < (a) < (c) < (d)

Q. 65 Single Option Correct +4 -1

An alkali is titrated against an acid with methyl orange as indicator, which of the following
(given in figure (1)) is a correct combination ?

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A. 1
B. 2
C. 3
D. 4

Q. 66 Single Option Correct +4 -1

The trans-alkenes are formed by the reduction of alkynes with :

A. Na/liq. NH₃
B. Sn - HCl
C. H₂ - Pd/C, BaSO₄
D. NaBH₄

Q. 67 Single Option Correct +4 -1

The ratio of mass percent of C and H of an organic compound (CₓHᵧOz) is 6 : 1. If one


molecule of the above compound (CₓHᵧO ) contains half as much oxygen as required to
burn one molecule of compound CₓHᵧ completely to CO₂ and H₂O. The empirical formula of
compound CₓHᵧO is :

A. C₃H₄O₂
B. C₂H₄O₃
C. C₃H₆O₃
D. C₂H₄O

Q. 68 Single Option Correct +4 -1

Hydrogen peroxide oxidises [Fe(CN)₆]⁴⁻ to [Fe(CN)₆]³⁻ in acidic medium but reduces


[Fe(CN)₆]³⁻ to [Fe(CN)₆]⁴ in alkaline medium. The other products formed are, respectively:

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A. H₂O and (H₂O + O₂)


B. H₂O and (H₂O + OH⁻)
C. (H₂O + O₂) and H₂O
D. (H₂O + O₂) and (H₂O + OH⁻)

Q. 69 Single Option Correct +4 -1

The major product (among (1), (2), (3), (4)) formed in the following reaction is :

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A. 1
B. 2
C. 3
D. 4

Q. 70 Single Option Correct +4 -1

How long (approximate) should water be electrolysed by passing through 100 amperes
current so that the oxygen released can completely burn 27.66 of diborane ?
(Atomic weight of B = 10.8 u)

A. 3.2 hours
B. 1.6 hours
C. 6.4 hours
D. 0.8 hours

Q. 71 Single Option Correct +4 -1

Which of the following lines (figure (1)) correctly show the temperature dependence of
equilibrium constant, K, for an exothermic reaction ?

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A. C and D
B. A and D
C. A and B
D. B and C

Q. 72 Single Option Correct +4 -1

At 518°C, the rate of decomposition of a sample of gaseous acetaldehyde, initially at a


pressure of 363 Torr, was 1.00 Torr s⁻¹ when 5% had reacted and 0.5 Torr s⁻¹ when 33%
had reacted. The order of the reaction is :

A. 1
B. 0
C. 2
D. 3

Q. 73 Single Option Correct +4 -1

Glucose on prolonged heating with HI gives

A. Hexanoic acid
B. 6-iodohexanal
C. n-Hexane
D. 1-Hexene

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Q. 74 Single Option Correct +4 -1

Consider the following reaction and statements


[CO(NH₃)₄Br₂]⁺ + Br⁻ −> [Co(NH₃)₃Br₃] + NH₃
(I) Two isomers are produced if the reactant complex ion is a cis-isomer.
(II) Two isomers are produced if the reactant complex ion is a trans-isomer.
(Ill) Only one isomer is produced if the reactant complex ion is a trans-isomer.
(IV) Only one isomer is produced if the reactant complex ion is a cis-isomer.
The correct statements are :

A. (III) and (IV)


B. (II) and (IV)
C. (I) and (II)
D. (I) and (III)

Q. 75 Single Option Correct +4 -1

The major product (among (1), (2), (3), (4)) of the following reaction is :

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A. 1
B. 2
C. 3
D. 4

Q. 76 Single Option Correct +4 -1

Phenol on treatment with CO₂ in the presence of NaOH followed by acidification produces
compound X as the major product. X on treatment with (CH₃CO)₂O in the presence of
catalytic amount of H₂SO₄ produces :

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A. 1
B. 2
C. 3
D. 4

Q. 77 Single Option Correct +4 -1

An aqueous solution contains an unknown concentration of Ba²⁺. When 50 mL of a 1 M


solution of Na₂SO₄ is added, BaSO₄ just begins to precipitate. The final volume is 500 mL.
The solubility product of BaSO₄ is 1 x 10⁻¹⁰. What is the original concentration of Ba²⁺?

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A. 1.1 x 10⁻⁹ M
B. 1.0 x 10⁻¹⁰ M
C. 5 x 10⁻⁹ M
D. 2 X 10⁻⁹ M

Q. 78 Single Option Correct +4 -1

Which of the following compounds (among (1), (2), (3), (4)) will be suitable for Kjeldahl's
method for nitrogen estimation?

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A. (1)
B. (2)
C. (3)
D. (4)

Q. 79 Single Option Correct +4 -1

When metal 'M' is treated with NaOH, a white gelatinous precipitate 'X' is obtained, which is
soluble in excess of NaOH. Compound 'X' when heated strongly gives an oxide which is
used in chromatography as an adsorbent. The metal 'M' is:

A. Al
B. Fe
C. Zn
D. Ca

Q. 80 Single Option Correct +4 -1

An aqueous solution contains 0.10 M H₂S and 0.20 M HCI. If the equilibrium constants for
the formation of HS⁻ from H₂S is 1.0 x 10⁻⁷ and that of S²⁻ from HS⁻ ions is 1.2 x 10⁻¹³ then
the concentration of S²⁻ ions in aqueous solution is :

A. 6 x 10⁻²¹
B. 5 x10⁻¹⁹
C. 5 x 10⁻⁸
D. 3 x 10⁻²⁰

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Q. 81 Single Option Correct +4 -1

The recommended concentration of fluoride ion in drinking water is up to 1 ppm as


fluoride ion is required to make teeth enamel harder by converting [3Ca₃(PO₄)₂ . Ca(OH)₂]
to

A. [3ca₃(PO₄)₂.CaF₂]
B. [3{Ca(OH)₂} . CaF₂]
C. [CaF₂]
D. [3(CaF₂) . Ca(OH)₂]

Q. 82 Single Option Correct +4 -1

The compound that does not produce nitrogen gas by the thermal decomposition is

A. NH₄NO₂
B. (NH₄)₂SO₄
C. Ba(N₃)₂
D. (NH₄)₂Cr₂O₇

Q. 83 Single Option Correct +4 -1

The predominant form of histamine present in human blood (among (1), (2), (3), (4)) is (pKa,
Histidine - 6.0)

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A. (1)
B. (2)
C. (3)
D. (4)

Q. 84 Single Option Correct +4 -1

The oxidation states of Cr in [Cr(H₂O)₆]Cl₃ , [Cr(C₆H₆)₂], and K₂[Cr(CN)₂(O)₂(O₂)(NH₃)]


respectively are :

A. +3, 0 and +6
B. +3, 0 and +4
C. +3, + 4 and +6
D. +3, +2 and +4

Q. 85 Single Option Correct +4 -1

Which type of 'defect' has the presence of cations in the interstitial site ?

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A. Frenkel defect
B. Metal deficiency defect
C. Schottky defect
D. Vacancy defect

Q. 86 Single Option Correct +4 -1

The combustion of benzene (I) gives CO₂(g) and H₂O(l). Given that heat of combustion of
benzene at constant volume is -3263.9 kJ mol⁻¹ at 25°C; heat of combustion (in kJ mol⁻¹) of
benzene at constant pressure will be :
(R = 8.31.4 JK⁻¹1 mol⁻¹)

A. 3260
B. -3267.6
C. 4152.6
D. -452.46

Q. 87 Single Option Correct +4 -1

Which of the following are Lewis acids ?

A. PH₃ and SiCl₄


B. BCl₃ and AlCl₃
C. PH₃ and BCl₃
D. AlCl₃ and SiCl₄

Q. 88 Single Option Correct +4 -1

Which of the following compounds contain(s) no covalent bond(s)?


KCl, PH₃, O₂, B₂H₆, H₂SO₄

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A. KCl
B. KCl, B₂H₆
C. KCl, B₂H₆, PH₃
D. KCl, H₂SO₄

Q. 89 Single Option Correct +4 -1

For 1 molal aqueous solution of the following compounds, which one, will show the highest
freezing point ?

A. [Co(H₂O)₄Cl₂)Cl . 2H₂O
B. [Co(H₂O)₃Cl₃] . 3H₂O
C. [Co(H₂O)₆]Cl₃
D. [Co(H₂O)₅CI]Cl₂ . H₂O

Q. 90 Single Option Correct +4 -1

According to molecular orbital theory, which of the following will not be a viable molecule?

A. H₂⁻
B. H₂²⁻
C. He₂²⁺
D. He₂⁺

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JEE Main 2018


Answers

1. C 2. C 3. A
4. D 5. A 6. D
7. B 8. A 9. C
10. A 11. D 12. C
13. C 14. A 15. C
16. B 17. D 18. D
19. A 20. C 21. D
22. C 23. D 24. A
25. A 26. A 27. D
28. D 29. A 30. A
31. B 32. D 33. A
34. C 35. B 36. D
37. A 38. D 39. D
40. B 41. D 42. C
43. D 44. A 45. B
46. A 47. A 48. B
49. C 50. A 51. A
52. D 53. C 54. A
55. C 56. B 57. C
58. C 59. D 60. A
61. A 62. D 63. A
64. A 65. A 66. A
67. B 68. A 69. B
70. A 71. C 72. C
73. C 74. D 75. D
76. C 77. A 78. D
79. A 80. D 81. A
82. B 83. B 84. A
85. A 86. B 87. B
88. A 89. B 90. B

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