Feed Streams

Name
61 73A
Vapour Fraction 0.00 0.00
Temperature [C] 35.88 10.40
Pressure [kPa] 3100.00 3100.00
Molar Flow [kgmole/h] 655.40 14635.09
Mass Flow [kg/h] 33745.18 528044.99
Liquid Volume Flow [m3/h] 62.22 1217.68
Mass Density [kg/m3] 525.17 443.83

61
Total molar rate (Kmol/h) 15290.49 0.0428634503
1.5380018712
1.38E-03 4.50E+00 4.50E+00 1.48E-06
1.18E-01 1.43E+00 1.55E+00 9.79E-11
4.38E+01 1.36E+03 1.40E+03 2.03E-05
7.96E+01 5.95E+03 6.03E+03 2.31E-01
1.54E+02 7.03E+03 7.08E+03 9.70E+01
9.19E+01 1.60E+02 1.59E+02 9.26E+01
1.92E+02 1.20E+02 1.34E+02 1.79E+02
2.50E+01 5.58E+00 5.78E+00 2.48E+01
9.68E+00 1.79E+00 1.82E+00 9.66E+00
3.32E+01 4.60E+00 4.61E+00 3.32E+01
2.17E+01 1.34E+00 1.30E+00 2.17E+01
3.73E+00 1.18E-01 1.13E-01 3.74E+00
3.05E-01 3.19E-03 4.03E-03 3.04E-01
1.29E-02 4.26E-06 1.16E-04 1.28E-02
6.66E-14 7.85E-17 3.32E-16 6.64E-14
2.22E-14 1.06E-16 6.32E-17 2.23E-14
8.13E-07 1.72E-06 2.53E-06 1.26E-10
6.55E+02 1.46E+04 1.48E+04 4.62E+02
1.53E+04 1.53E+04
Overhead Outlet Bottom Outlet
62 63
1.00 0.00
48.04 131.28
2900.00 3000.00
14828.79 461.70
534427.14 27363.03 0.3578
1233.03 46.86
58.13 398.34 0.1506

73A
0.9571365497
9.9539009397 11.4919028109

7.6008417391

1021402.1781681 27363.0355
283.7228272689 7.600843194
 Feed Streams
Name
61 73A
CO2 2.10E-06 3.08E-04
Nitrogen 1.80E-04 9.78E-05
Methane 6.68E-02 9.30E-02
Ethane 0.1214856861 4.07E-01
Propane 0.2356064064 4.80E-01
i-Butane 0.140282251 1.09E-02
n-Butane 0.2928887058 8.22E-03
i-Pentane 3.81E-02 3.81E-04
n-Pentane 1.48E-02 1.23E-04
C6* 5.07E-02 3.15E-04
C7* 3.31E-02 9.16E-05
C8* 5.70E-03 8.04E-06
C9* 4.66E-04 2.18E-07
C10* 1.97E-05 2.91E-10
C11* 1.02E-16 5.37E-21
C12* 3.39E-17 7.27E-21
H2S 1.24E-09 1.17E-10
Total 1.00E+00 1.00E+00

Name To Reboiler To Debutaniser

0 0
Vapour
119.355229077 131.2795437496
Pressure [kPa] 3000 3000
Molar Flow [kgmole/h] 18263.0534822 461.7013871945
Mass Flow [kg/h] 1021402.17817 27363.03549724
Std Ideal Liq Vol Flow [m3/h] 1800.0283017 46.8616675011
Molar Enthalpy [kJ/kgmole] -128208.488784 -131149.94607989
Molar Entropy [kJ/kgmole-C] 132.497720012 143.3844375997
Heat Flow [kJ/h] -2341478487.53 -60552112.035567
 Overhead Outlet Bottom Outlet
Total Inlet component fraction
62 63
2.94E-04 3.04E-04 3.22E-09
1.01E-04 1.05E-04 2.12E-13
9.19E-02 9.47E-02 4.39E-08
3.94E-01 0.406586641 5.00E-04
4.70E-01 0.4776431641 2.10E-01
1.64E-02 1.07E-02 0.2005377979
2.04E-02 9.01E-03 0.3866862013
2.00E-03 3.90E-04 5.37E-02
7.50E-04 1.22E-04 2.09E-02
2.47E-03 3.11E-04 7.19E-02
1.50E-03 8.80E-05 4.70E-02
2.52E-04 7.62E-06 8.10E-03
2.02E-05 2.72E-07 6.59E-04
8.45E-07 7.83E-09 2.77E-05
4.36E-18 2.24E-20 1.44E-16
1.46E-18 4.26E-21 4.82E-17
1.66E-10 1.71E-10 2.74E-13
1.00E+00 1.00E+00 1.00E+00

Boilup QREB-T103
1 <empty>
131.2795437496 <empty>
3000 <empty>
17801.3520949698 <empty>
994039.142670892 <empty>
1753.1666341966 <empty>
-117000.668314517 <empty>
160.1834606924 <empty>
-2082770092.01349 198156283.481233
Total Outlet component fraction

2.94E-04
1.01E-04
9.19E-02
3.94E-01
4.70E-01
1.64E-02
2.04E-02
2.00E-03
7.50E-04
2.47E-03
1.50E-03
2.52E-04
2.02E-05
8.45E-07
4.36E-18
1.46E-18
1.66E-10
1.00E+00
(𝑃𝑙𝑎𝑡𝑒 𝑡ℎ𝑖𝑐𝑘𝑛𝑒𝑠𝑠 )/(𝐻𝑜𝑙𝑒 𝐷𝑖𝑎𝑚𝑒𝑡𝑒𝑟)=
Am= either the downcomer area (Ad) or the clearance area under the down
 Parameters Calculations

The light component

The heavy component

operating pressure (Kpa)

Oprating Temperature (K)

Antoine Coeffic

Carbon dioxide
Nitrogen
Methane
Ethane
Propane
i-butane
n-butane
i-pentane
n-pentane
C6
C7
C8
C9
C10
C11
C12
H2S
REFERN

2.1.1 Dew point:

based on the overhead stream (62)

 2.1.2 Bubble point
based on the bottom stream (63)
2.2 minimum number of stages

2.4 Nature of feed

 based on the feed streams

2.5 Minimum reflux ratio

based in distillate stream

2.6 Theoretical number of stages:

 x

2.7 Colunm efficiency

2.8 Actual number of trays

thoertical number of trays

actual number of trays

2.9 Feed point location

 2.10 Plate efficiency

2.11 colunm diamter

The liquid vapour factor (FLV)

2.14 Tray design

Tray type is
the maximum volumeteric liquid rate

Entrainment

un
uf

percentage flooding
FLV
Fractional entranment, ψ
 2.15 Provisional plate Design

Column Diameter, Dc
Column Area, Ac
Downcomer area (%12 of Ac),Ad
Net Area
Active area
Hole Area

To use the Figure below

Weir
length=𝐴𝑑/𝐴𝑐×100

Weir length
 𝐿�/𝐷𝑐

Lw
weir height
Hole diameter
Plate Thickness

2.16 Weep point checking

maxium liquid rate, Lw

mim lquid rate at %70 turn down
Weir height
how =750[𝐿_�/𝜌_(𝑙 𝑙_� ) ]^(2⁄3)Francis weir formula

weir crest, how

weir crest, how, min
how+hw
 from Figure above k2

the minimum design vapour velocity is given by:

�_𝑏=[𝐾_2−0.90(25.4−𝑑_ℎ)]/(𝜌_𝑣 )
^(1/2)

hole diameter, dh, mm

ub

2.17 Height of column

𝐶𝑜𝑙�𝑚𝑛 𝐻𝑒𝑖𝑔ℎ𝑡= (𝑁�𝑚𝑏𝑒𝑟 𝑜𝑓 𝑠𝑎𝑡𝑎𝑔𝑒𝑠−1)(𝑇𝑟𝑎𝑦 𝑠𝑝𝑎𝑐𝑖𝑛𝑔)+(𝑇𝑟𝑎𝑦 𝑠𝑝𝑎𝑐𝑖𝑛𝑔 ×2)+(𝑁�𝑚𝑏𝑒𝑟 𝑜𝑓 𝑠𝑡𝑎𝑔𝑒𝑠 −1)(𝑇ℎ

Plate spacing
Thickness of trays
Number of stages

Column Height

2.18 plate pressure drop

 Maximum vapour velocity through holes

𝐴ℎ/𝐴𝑝=0.9[𝑑ℎ/𝐼𝑝]^2

Hole Diameter, dh
(𝑃𝑙𝑎𝑡𝑒 𝑡ℎ𝑖𝑐𝑘𝑛𝑒𝑠𝑠 )/(𝐻𝑜𝑙𝑒 𝐷𝑖𝑎𝑚𝑒𝑡𝑒𝑟)=

𝐴ℎ/𝐴𝑎=0.10∗100=10
 from the Figure:
Orifice coefficient, C0

�_�
�_L

ℎ𝑑=51[�ℎ/�_� ]^2 𝜌_𝑣/𝜌_𝑙

hd
hr =(12.5× 〖 10 〗
^3)/�_�

hr

ℎ�=ℎ𝑑+(ℎ�+ℎ𝑜�)+ℎ𝑟

hT

2.19 Downcomer design (back-up)

where;
Lwd = Liquid flow rate in downcomer
e downcomer area (Ad) or the clearance area under the downcomer (Aap), whichever smaller

Lwd
Am
 ℎ𝑏<1/2 (𝐼𝑡+ℎ�)

2.20 Residence time

2.21 Perforated area

2.22 Number of holes

2.23 Summary of process design

 Propane
n-butane

3100.00
284.6419028109

Antoine Coefficients*
A
20.5748
12.9392
13.2093
13.6467
13.711
13.5231
13.6632
13.7103
13.8183
13.8216
13.8587
13.9276
13.9521
13.9964
14.039
14.0984
14.069
REFERNCE:https://www.slideshare.net/termoaplicadaunefm/11
Relative voletility ( αab )

DEW Point
xLK
xHK

BUBBLE point
xLK
xHK

Fenske equation

Nm
 Component
Propane
n-butane

2.8355
-0.4314113535

Component
Propane
n-butane

0.4092

0.61
0.1267746741

0.5271367269

63
0.1214679222

63.20
6
11
N Theoritical
N Actual

E0
 The Top stream

The bottom stream

FLV

plate spacing is set to be

therefore from Figure 11.34.

 K1

Therfore,

Uf

Design for %80 flooding at flow rate

maximum voulmetric flow rate (top )

maximum voulmetric flow rate (bottom )

net area required (top)

downcomer area is set be %12 of the colunm cross-sectional area

Net area equired (top)

Threfore

Column diameter (m)

Singal pass
 0.022

1.9943817187
1.595505375

80
0.0196725237
0.175
 1.521788387
1.8188564001
0.218262768
1.6005936321
1.3823308641
0.1382330864

12
 0.75

1.1413412903
50
5
5

7.60
5.3205892174
50
𝑙_� ) ]^(2⁄3)Francis weir formula

49.4159096207
38.9581944293
88.9581944293
 30.9

25.4−𝑑_ℎ)]/(𝜌_𝑣 )

5
18.36
12.54
1.6447284803

𝑔𝑒𝑠−1)(𝑇𝑟𝑎𝑦 𝑠𝑝𝑎𝑐𝑖𝑛𝑔)+(𝑇𝑟𝑎𝑦 𝑠𝑝𝑎𝑐𝑖𝑛𝑔 ×2)+(𝑁�𝑚𝑏𝑒𝑟 𝑜𝑓 𝑠𝑡𝑎𝑔𝑒𝑠 −1)(𝑇ℎ𝑖𝑐𝑘𝑛𝑒𝑠𝑠 𝑜𝑓 𝑝𝑙𝑎𝑡𝑒𝑠)

0.45
0.005
11

5.2374081762
 11.8982258372

�ℎ/��≈
𝐴ℎ/𝐴𝑎

1
 0.84

58.130846535
393.7656836147

31.7447673074

�=ℎ𝑑+(ℎ�+ℎ𝑜�)+ℎ𝑟

ℎ𝑑𝑐=166[𝐿�𝑑/(�_�
𝐴𝑚)]^2

downcomer (Aap), whichever smaller

283.7228272689

393.7656836147

ℎ𝑏=(ℎ�+ℎ𝑜�)+ℎ𝑡+ℎ𝑑𝑐
 𝐴𝑝=ℎ𝑎𝑝×𝑙�

ℎ𝑏<1/2 (𝐼𝑡+ℎ�)
*
B C
3103.39 -0.16
586.72 -6.6
897.84 -7.16
1582.178 -13.7622
1872.46 -25.16
2032.73 -33.15
2154.9 -34.42
2274.15 -37.23
2477.07 -39.94
2697.55 -43.81
2911.32 -56.51
3120.29 -63.63
3291.45 -71.33
3456.8 -76.670
2614.07 -85.450
3774.56 -91.31
1766.69 -26.06
ttps://www.slideshare.net/termoaplicadaunefm/11-tablas-de-antoine

Component Mole Fraction (yi)

CO2 3.04E-04
 Nitrogen 1.05E-04
Methane 9.47E-02
Ethane 4.07E-01
Propane 4.78E-01
i-Butane 1.07E-02
n-Butane 9.01E-03
i-Pentane 3.90E-04
n-Pentane 1.22E-04
C6* 3.11E-04
C7* 8.80E-05
C8* 7.62E-06
C9* 2.72E-07
C10* 7.83E-09
C11* 2.24E-20
C12* 4.26E-21
H2S 1.71E-10
1.00E+00

Component Mole Fraction (xi)

CO2 3.22E-09
Nitrogen 2.12E-13
Methane 4.39E-08
Ethane 5.00E-04
Propane 2.10E-01
i-Butane 2.01E-01
n-Butane 3.87E-01
i-Pentane 5.37E-02
n-Pentane 2.09E-02
C6* 7.19E-02
C7* 4.70E-02
C8* 8.10E-03
C9* 6.59E-04
 C10* 2.77E-05
C11* 1.44E-16
C12* 4.82E-17
H2S 2.74E-13
1.00E+00

4.24E+00

5E-01
9E-03

2E-01
4E-01

3 3E+00
Mole Fraction (xi,f) K-value
4.70E-01 2.325
2.04E-02 0.549

Mole Fraction (xi,d) K-value

4.70E-01 2.325
2.04E-02 0.549
 73A
7.75E-02 cP (mNs/m2)

0.0994877524 cP (mNs/m2)
4.24
63.20 0
 molar flow of the bottom product
molar flow of the overhead product
concentration of the heavy key in the feed
concentration of the light key in the feed product
concentration of the light key in the bottom product (𝑁_𝐹−1)/(𝑁_𝑇−𝑁_𝐹 )
concentration of heavy key in the overhead product =𝑁_𝑟/𝑁_𝑠

the feed stages is

6
11

0.5696509771 56.9650977056
 58.130846535 kg/m3
534427.14 kg/hr

393.7656836147 Kg/m3
27363.03 Kg/hr

0.0196725237

0.45 m
 0.83

1.9943817187 m/s

1.595505375 m/s

2.5537557432 m/s
0.0193029562 m/s

1.6005936321 m2

1.8188564001 m2

1.521788387
m3/s
m
m2
m2
m2
m2
m2 Take %10 os Aa as a fist trial

%
 m
mm
mm
mm

kg/s
kg/s
mm

mm 0.0003813432
mm 0.0052586869
mm 3.9440151945
 m/s

𝑒𝑠𝑠 𝑜𝑓 𝑝𝑙𝑎𝑡𝑒𝑠)

m
m

m
m/s

mm
mm Liquid

mm liquid

kg/s

kg/m^3
 ln (p) P K value
9.6658811221 15770.2592944211 5.087
10.8290144702 50463.9485469186 16.279
9.973629526 21453.2091948794 6.920
7.8058120206 2454.828107934 0.792
6.4948512832 661.725808251 2.325
5.4404143259 230.5376814095 0.810
5.0512440689 156.2166879729 0.549 4.2359482642
4.5185433619 91.7019241306 0.030
3.6954935504 40.2654407095 0.141
2.6206338136 13.7444322325 0.048
1.0971354659 2.9955728017 0.222
-0.1905988857 0.8264640282 0.061
-1.4781219268 0.2280656103 0.000
-2.6250760421 0.0724342488 0.000
0.9157251885 2.4985865413 0.001
-5.4253306679 0.0044036098 0.000
7.2367739981 1389.603867531 0.448

Ki value Dew point (xi=yi/Ki)

25.4717 1E-05
23.5980 4E-06
11.8113 8E-03
2.0047 2E-01
0.6888 7E-01
0.2832 4E-02
0.2098 4E-02
0.1368 3E-03
0.0707 2E-03
0.0294 1E-02
0.0091 1E-02
0.0034 2E-03
0.0013 2E-04
0.0005 1E-05
0.0919 2E-19
0.0001 6E-17
1.3681 1E-10
1.01E+00

Ki value Dew point (yi=xi*Ki)

1.25E+02 4E-07
3.14E+01 7E-12
1.86E+01 8E-07
4.74E+00 2E-03
2.06E+00 4E-01
9.93E-01 2E-01
8.03E-01 3E-01
5.80E-01 3E-02
3.51E-01 7E-03
1.77E-01 1E-02
7.46E-02 4E-03
3.60E-02 3E-04
1.77E-02 1E-05
9.44E-03 3E-07
1.06E-01 2E-17
2.26E-03 1E-19
3.87E+00 1E-12
1.00E+00
Relative volatility (αi)
4.24
1

Relative volatility (αi)

4.24
1
 Rmin/(Rmin+1) 0.2903595906
R/(R+1) 0.3803240222

Nmin/N 0.615 based on Figure 11.18

N 5.159434034 6

From HYSYS
 B 461.70
D 14828.79
2.04E-02
4.70E-01
(𝑁_𝐹−1)/(𝑁_𝑇−𝑁_𝐹 ) 2.10E-01
=𝑁_𝑟/𝑁_𝑠 9.01E-03
-2.75E-02
0.94

6
Temperature [C] at Dew point is 58.40
 ln (p)
Pressure [kPa] 2900.00 11.21003341
Temperature [K] 331.55 11.13362991
10.44152048
8.667975203
Antoine Coefficients* 7.599638663
A B C 6.711002145
Carbon dioxide 20.5748 3103.39 -0.16 6.410818887
Nitrogen 12.9392 586.72 -6.6 5.983506034
Methane 13.2093 897.84 -7.16 5.323838219
Ethane 13.6467 1582.178 -13.7622 4.446643442
Propane 13.711 1872.46 -25.16 3.273621466
i-butane 13.5231 2032.73 -33.15 2.281250343
n-butane 13.6632 2154.9 -34.42 1.303379686
i-pentane 13.7103 2274.15 -37.23 0.433939234
n-pentane 13.8183 2477.07 -39.94 3.417117066
C6 13.8216 2697.55 -43.81 -1.613221712
C7 13.8587 2911.32 -56.51 8.285864709
C8 13.9276 3120.29 -63.63
C9 13.9521 3291.45 -71.33
C10 13.9964 3456.8 -76.670
C11 14.039 2614.07 -85.450
C12 14.0984 3774.56 -91.31
H2S 14.069 1766.69 -26.06
ln (p)
12.83547982
11.45213879
10.93046044
9.56247742
8.730920743
Temperature [C] at Bubble point is 128.00 7.999377174
7.787214943
7.46126175
6.960599493
6.272627033
5.411276602
Pressure [kPa] 3000.00 4.682844134
Temperature [K] 401.15 3.972565709
3.343046943
5.7588656
Antoine Coefficients* 1.916112368
A B C 9.358957077
Carbon dioxide 20.5748 3103.39 -0.16
Nitrogen 12.9392 586.72 -6.6
Methane 13.2093 897.84 -7.16
Ethane 13.6467 1582.178 -13.7622
Propane 13.711 1872.46 -25.16
i-butane 13.5231 2032.73 -33.15
n-butane 13.6632 2154.9 -34.42
i-pentane 13.7103 2274.15 -37.23
n-pentane 13.8183 2477.07 -39.94
C6 13.8216 2697.55 -43.81
C7 13.8587 2911.32 -56.51
C8 13.9276 3120.29 -63.63
C9 13.9521 3291.45 -71.33
C10 13.9964 3456.8 -76.670
C11 14.039 2614.07 -85.450
C12 14.0984 3774.56 -91.31
H2S 14.069 1766.69 -26.06
 P K value
73867.8829355 25.4717
68434.3323274 23.5980
34252.6932404 11.8113
5813.71583037 2.0047
1997.47400371 0.6888
821.393382212 0.2832
608.391681386 0.2098
396.829228903 0.1368
205.169859474 0.0707
85.3400140159 0.0294
26.4067977086 0.0091
9.7889122626 0.0034
3.6817187192 0.0013
1.5433250838 0.0005
30.4814123362 0.0919
0.1992446701 0.0001
3967.3938976 1.3681

P K value
375299.561773 125.0999
94102.3963298 31.3675
55851.9900294 18.6173
14221.0340674 4.7403
6191.42619725 2.0638
2979.1019467 0.9930
2409.59736214 0.8032
1739.34128699 0.5798
1054.26539295 0.3514
529.867530619 0.1766
223.917258444 0.0746
108.077021359 0.0360
53.1206482486 0.0177
28.3052398947 0.0094
316.988533169 0.1057
6.7944925688 0.0023
11602.281943 3.8674
 Thickness calculations
operating presure 30.59 bar
10 above opearting pressure 32.554083 N/mm2
Desing temperature 312 k
desing stress from table 13.2 135 N/mm2
length of column 5.2374082 m
width 1.5217884 m

cylinderical section 73 mm
add corrosion allowance 75 mm