1

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 2

PART – A
1. The sum of a two digit number and the number obtained by reversing its digit is a square number. How many
such numbers are there ?
(a) 6 (b) 8 (c) 12 (d) 15
2. If in a certain code language ‘INDIA’ is coded as ‘OJEBJ’ and ‘DELHI’ is coded as ‘FEMJI’, then in the same
language code for ‘TAKEN’ is
(a) UZJOF (b) BULOF (c) BUJOF (d) BULFO
3. Study the information carefully to answer the question below: A, B, C, D, E and F six persons live on six
different floors of a six storey building ground floor is numbered as one, first floor as two and six on on the top
most floor during six. A, B, C lives in even floors while D, E, F lives in odd floors none of F, B, A, D lives in top
most floor B lives in the lowest floor among the even floors. E lives above A and D lives above F. Who lives
between A and B ?
(a) D (b) C (c) E (d) F
4. In the series given below follows a certain pattern. What should come following the same pattern in place of
question mark (?) ?
3 7 23 95 ?
(a) 380 (b) 479 (c) 514 (d) 461
5. Pointing to a photograph of Ram, a lady says, “He is the father of the son of my mother’s only daughter”. How
is Ram related to the lady ?
(a) Brother (b) Husband (c) Uncle (d) Brother-in-law
6. A courier boy starts delivering letters 3 km southwards and then turns right. He covers 4 km on this road and
again turns right. He delivers letters for 3 km and completes his daily beat. Then he turns left for lunch at home,
which is 5 km away. How far he has to travel to reach the post office after lunch?
(a) 15 km (b) 10 km (c) 9 km (d) 8 km
7. The sweet cola company prepares drinks of three different flavours –X, Y and Z. The production of the three
flavours over a period of six years has been expressed in the bar-graph provided below. Study the graph and
answer the question based on it. Production of three different flavour of soft-drinks X, Y, Z by the company
over the years (in lakh bottles)
X Y z

60 60 60 60 60
55 55 55 55
50 50 50 50 50
50
45 45 45
40 40
40

30

20

10

0
1995 1996 1997 1998 1999 2000
For which of the following years the percentage of rise/fall in production from the previous year is the maximum
for the flavour Y ?
(a) 1996 (b) 1997 (c) 1998 (d) 2000
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8. In an job interview A and B appear for two vacancies in the same post. The probability of A’s selection is 1/7
and the probability that B doesn’t get selected is 4/5. What is the probability that only one of them is selected?
(a) 2/5 (b) 1/10 (c) 2/7 (d) 3/20
1 1 1
9.   is equal to
log a bc  1 log b ac  1 log c ab  1
(a) abc (b) a  b  c (c) 1 (d) 0
1
10. As price of apple reduced by 6 % , Amit was able to buy 1 kg more apple for Rs.120. Find the reduced rate
4
of apple per kg ?
(a) 8 (b) 7.5 (c) 15 (d) 10
11. Directions: In the question below is given few statements followed by the conclusions numbered accordingly.
You have to take the given statements to be true even if they seem to be at variance from commonly known
facts and then decide which of the given conclusions logically follows from the statements disregarding com-
monly known facts.
Statements: Conclusions:
I. Some A are B 1. Some D are not C
II. No B are C 2. Some D are C
III. All B are D
(a) Only 1 follows (b) Only 2 follows (c) Both 1 & 2 follows (d) None follows
12. In the series given below follows a certain pattern. What should come following the same pattern in place of
question mark (?) ?
CX IR OL UF ?
(a) AB (b) ZB (c) AZ (d) AY
13. Below is given a square of side 10 cm and each time mid points of the adjacent sides are connected and formed
a new square and it is repeated as much time as possible. What is the total area of all the squares formed ?

(a) 300 cm2 (b) 400 cm2 (c) 200 cm2 (d) 320 cm2
14. A man standing at a point P is watching the top of a tower, which makes an angle of elevation of 30º with the
man’s eye. The man walks some distance towards the tower to watch its top and the angle of elevation
becomes 60º. What is the distance between the base of the tower and the point P ?
(a) 4 3 units (b) 8 units (c) Data inadequate (d) None of these
15. In a 100 m race A beats B by 10 m and C by 12 m. In race of 180 m, B will beat C by how much metre ?
(a) 6 (b) 4 (c) 8 (d) 10
16. At what time between 5 a.m. and 6 a.m., the minute hand and hour hand of a clock would coincide ?
(a) 5 : 27 : 16 a.m. (b) 5 : 38 : 12 a.m. (c) 5 : 35 : 10 a.m. (d) 5 : 25 : 20 a.m.
17. Total number of triangles in the figure given below is

(a) 20 (b) 18 (c) 24 (d) 25

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18. A solid is in the form of a cylinder with hemispherical ends. The total height of the solid is 19 cm and the
diameter of the cylinder is 7 cm. Find the total surface area of the solid ?
E

D H C

19 cm

A G B

F
(a) 398.75 cm3 (b) 418 cm3 (c) 444 cm2 (d) 412 cm2
19. A completes 2/3 of a certain job in 6 days. B can complete 1/3 of the same job in 8 days and C can complete
3/4 of the work in 12 days. All of them work together for 4 days and then A and C quit. How long will it take
for B to complete the remaining work alone?
(a) 3.8 days (b) 3.33 days (c) 2.22 days (d) 4.3 days
20. In the Botanical garden in Kolkata, there are three watchmen meant to protect the fruits in the campus. How-
ever, one day a thief got in without being noticed and stole some fruits. On the way out however, he was
confronted by the three watchmen, the first two of whom asked him to part with 1/3rd of the fruits and one
more. The last asked him to part with 1/5th of the fruits and 4 more. As a result he had no fruits left. What was
the number of fruits he had stolen?
(a) 12 (b) 13 (c) 15 (d) None of these

PART – B
21. The molarity of 16% aqueous methanol solution by volume is (Density of solution = 0.9 gmL–1)
(a) 2.232 M (b) 2.124 M (c) 1.875 M (d) 1.435 M
22. The probability of formation of linkage between monomer A and B is 0.2. If the total number of
chain in a sample is 10 4, the number of repeating units in a sample is
(a) 1.25×10 –4 (b) 1.25 (c) 1.25×10 4 (d) 8×10 3
23. Two moles of monoatomic gas and diatomic gas compressed from volume V1 to V2 adiabatically. If the
initial temperature is same, then the change in temperature will be observed more for
(a) Monoatomic gas (b) Diatomic gas
(c) Both show same change (d) Cannot be predicted.

24. The change in volume of a gas at constant temperature is related to change in pressure as
(a) Inversely proportional to change in pressure
(b) Directly proportional to change in pressure
(c) Do not have any effect on volume
(d) Cannot be predicted

 dˆ dˆ 
25. The value of the commutator Bracket  , xˆ  is
 dx dx 

d̂
(a) x̂ (b) 1 (c) (d) –1
dx

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26. The major product (P) formed in the following reaction is
H3C CH3

OMOM
LiO Heat
H3C
(P)

H3C

OTBDMS
OTBDMS OTBDMS
MOMO MOMO
CH3 CH3

(a) H3C (b) H3C

H O H O
H3C CH3 H3C CH3

O
OTBDMS
O
H3C CH3 CH3

(c) H3C (d) H3C

H O O
H3C H
H3C CH3

27. If repulsion terms in the Hamiltonian of Lithium (Li) are neglected then its ground state energy is given
by
221 121 81 35
(a)  Hartree (b)  Hartree (c)  Hartree (d)  Hartree
8 9 8 8
28. The major product (P) formed in the following reaction is
O
PhCO2Ag
N2 (P)
Et3N
NHTs

O Ts

O N
(a) (b) O N (c) (d) N
N Ts N N
Ts Ts

K
29. For a 0.2 M solution of ZnCl2. The value of K is (where K is rate constant)
0

(a) 1.2 (b) 2.3 (c) 3.4 (d) 4.6

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30. The major product (P) is
OH

Br

MeO O t
BuOK (2.5 equiv.)
(P)
140ºC
then workup

OH

OH

MeO O

(a) (b)

MeO O

OH

OH OH

Br
(c) (d) MeO

MeO O

31. Match the coordination number given in Column-I with their crystal structures given in Column-II:
Column – I Column – II
(A) 4 (I) face centered cubic structure
(B) 6 (II) diamond cubic structure
(C) 8 (III) body-centered cubic structure
(D) 12 (IV) simple cubic structure
The correct match is
(a) A-II, B-IV, C-I, D-III (b) A-II, B-III, C-IV, D-I
(c) A-II, B-IV, C-III, D-I (d) A-II, B-I, C-III, D-IV
32. How many isomers will be possible if we replace five chlorine atoms of PCl5 with five different groups (R1 to
R5) as shown below?
Cl R1

Cl R2
Cl P R5 P
Cl R3
Cl R4
(a) 5 (b) 12 (c) 20 (d) 16

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33. What will be desired resolution of mass spectrometer to separate close mass signals at m/z 200.1234 and
200.1345.
(a) 28000 (b) 38000 (c) 18000 (d) 48000
34. The NMR involves use of radiofrequency while the ESR involves microwave frequency source. Which is the
correct reason for the same.
(a) Difference in the spin number of proton and electron
(b) Difference in relaxation time of proton and electron
(c) Difference in the magnetic properties of proton and electron
(d) Difference in the mass of proton and electron.
35. The major product (P) formed in the following reaction is
Me Me

Me
OH
NaNO2/HCl
(P)
hv

Me Me
H3C NO Me
Me Me Me Me
Me
OH
Me
(a) (b) (c) CHO (d) CHO
ON

NO

36.

Which of the following option is correct regarding the transport number of chloride t in HCl and NaCl?  
(a) t   HCl   t   NaCl  (b) t   NaCl   t   HCl 

(c) t   NaCl   t   HCl  (d) t   NaCl   t   HCl 

37. What will be the equilibrium constant of the following reaction at 298K
2Fe3  Sn 2 
 2Fe 2  Sn 4

E0  0.771 V E0  0.150 V
Fe3 |Fe 2  Sn 2 |Sn 4

(a) 1021 (b) 1031 (c) 1041 (d) None of these

38. Which of the following properties/phenomenon is not associated with sugar chemistry
(a) Edward-demieux effect (b) Van-style estimation
(c) Lobry de-Bruyn-van Epenstein conversion (d) Mutarotation
39. The correct statement about the following species is

N H O

(A) (B)
(a) Both (A) and (B) are aromatic (b) (A) is aromatic and (B) is not aromatic
(c) (B) is aromatic, while (A) is not aromatic (d) Both (A) and (B) are not aromatic

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40. The major products (A) and (B) respectively are
COOMe COOMe

 
(A) ; (B)

OCOMe OCOMe

, ,
(a) (b)
OCOMe OCOMe OCOMe OCOMe

COOMe COOMe COOMe COOMe

, ,
(c) (d)

41. The correct absolute configuration of compound (P), (Q), (R) and (S) are respectively,
HOOC
OMe

Ph
C CH
(P) (Q)
Me3C CMe2CMe3
MeO O2N

H Br

Me C Me
(R) C C C C C C (S)
H H H H

(a) R, S, S, S (b) S, R, R, S (c) S, R, S, S (d) R, S, S, R

42. The correct order of bond dissociation energies for the indicated C-H bonds in the given compound is

H
4 H
1

H H 2
3

(a) 4 > 3 > 2 > 1 (b) 3 > 2 > 1 > 4 (c) 3 > 2 > 4 > 1 (d) 1 > 4 > 2 > 3
43. The fundamental and first overtone transition of CO molecule are centered at 2076 cm–1 and 3150 cm–1
respectively. The equilibrium vibration frequency and anharmonicity constant is
(a) 2176 cm–1, 0.25 (b) 3150 cm–1, 0.16 (c) 3078 cm–1, 0.163 (d) 2570 cm–1, 0.32

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44. What is the species generating when [Co(NH3)6]Cl3 reacts with moist Ag2O ?
(a) Co(OH)3.5NH3 (b) Co(OH)3.6NH3
(c) Co 2O 3 (d) NH4OH
45. Consider the following statements :
Statement-I : Paramagnetism in the diamagnetic substance is independent of temperature.
Statement-II : In the substances which have only paired electrons, the energy of HOMO is very close to
LUMO and electrons can be promoted spontaneously from HOMO to LUMO due to their thermal motion.
(a) Both statements are correct and statement-II is the correct explanation of statement-I.
(b) Both statements are correct and statement-II is not the correct explanation of statement-I.
(c) Only statement-I is correct.
(d) Only statement-II is correct.
46. In H C C H , the (C–H) species can be replaced by
(a) Cp(CO)2Mo (b) Mo(CO)5 (c) Fe(CO)4 (d) [PtCl3]–

47. (CH3)3Sn + Mn (CO)5Br (X)
Stable (18e–)

The complex(X) obey the 18 electron rule and no M-M bond has been found and also a colorless gas evolved.
Identify the complex(X)

(a) (CO)5Mn (b) (c) (d)

Mn Mn
Mn
OC CO Br CO OC Br
CO CO CO

48. Consider the following species :

N
N P CH3
CH2CH2CH3 O
Ph CH2CH2CH3
Ph C
CH3 CH2CH3 Ph Ph
(A) (B) (C)
The correct order of energy barrier to inversion of following species is :
(a) B < A < C (b) A < B < C (c) C < A < B (d) A < C < B
49. Consider the following reactions
(A) NOCl  AgNO3   (B) NOCl  liq. N 2O4  
(C) NOCl  BrF3 (liq.)   (D) NaNO3  N 2O4  
Reaction will not give [NO]+ as a major product is/are
(a) A and B (b) A and D (c) B and C (d) A only
50. Vitamin B12 react with CH3-THF to give the product P. The oxidation state of metal present in product P is
(a) One (I) (b) Two (II) (c) Three (III) (d) Four (IV)
51. Anhydrous hydrogen fluoride is prepared by the action of concentrated sulfuric acid on
(a) BeF2 (b) MgF2 (c) CaF2 (d) BaF2

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52. Silicon tetrachloride reacts with LiAlH4( 1 : 1 ratio) to give
(a) SiH2Cl2 + LiAlCl4 (b) SiH4 + LiH + AlCl3
(c) SiHCl3 + LiH + AlCl3 (d) SiH4 + LiAlCl4
53. The ground state forms of Gd3+ and Eu3+ respectively are:
7
(a) F0 and 8S7/2 (b) 8 S7/2 and 7 F0 (c) 2
F5/2 and 5 I4 (d) 7 F6 and 2 F7/ 2

54. The spectroscopic term symbols for ground state electronic configuration of carbon (2s2 2p2) are:
3
(a) F, 1D, 1S (b) 3 D, 3 P, 3S, 1D, 1P, 1S
(c) 3 P, 1D, 1S (d) 3 F, 3 P, 1D, 1S
55. The geometric cross-section (in barn) of a nucleus having mass number A = 64, ro  1.4  1015 m approximately
is
(a) 0.98 barn (b) 0.31 barn (c) 0.70 barn (d) 1.96 barn
56. The major product in the following reaction is
O
nC H (S)-BINAL-H
3 7

OH OH
nC H nC H
(a) 3 7 , by Re face attack (b) 3 7 , by Si face attack

OH OH
nC H nC H
(c) 3 7 , by Re face attack (d) 3 7 , by Si face attack

57. The correct order of relative rates of solvolysis for the compounds (I-III) is
Br Br
(CH3)3CBr

I II III
(a) I > II > III (b) I > III > II (b) III > II > I (d) III > I > II
58. The major product formed in the following reaction is
DCl
(A)

Cl
D Cl Cl
(a) (b) (c) (d)
Cl D D D

Tx
59. A certain system of non-interacting particle has the single particle partition function f  B , where B is
V
some constant. The average energy per particle will be
(a) k BT / B (b) k BT / x (c) Bk BT (d) xk BT

60. In milk at 37ºC, Lactobacillus acidophilus has a generation time of 75 minutes. The population relative to
the initial value at 150 minutes is
(a) 4.0 (b) 2.25 (c) 2.0 (d) 1.75

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PART – C
61. 250 mL of x M solution and 500 mL of y M solution are mixed and diluted to 2L to produce a final
concentration of 1.6 M.
If x : y  5 : 4 , then the value of x and y are
(a) x = 4.93 M, y = 3.94 M (b) x = 3.94 M, y = 4.93 M
(c) x = 2.54 M, y = 1.34 M (d) x = 1.34 M, y = 2.54 M
62. The enthalpy of adsorption is –40 kJmol–1 . The preexponential factor is 10 –5 s –1 . The average
residence time of an adsorbate at 300K is
(a) 10 –10 s (b) 10 –12 s (c) 10 –8 s (d) 10 –6 s
4 1 5 1
63. For liquid water at 25ºC,   2.07  10 K and   4.53  10 atm . The density of water is 1.00
gcm–3 . One mol of water is compressed isothermally from 1 atm to 1000 atm. The value of


S JK 1mol 1 is 
(a) –0.562 (b) –0.47 (c) –0.37 (d) –0.23
1
64. If the equation of state for a ga with internal energy U is PV  U , then the equation for an adiabatic
3
process is
(a) PV 1/3  constant (b) PV 5/3  constant (c) PV 4/3  constant (d) PV 7/3  constant
65. The percentage transmittance (T) can be related to the absorbance (A) as
(a) % T = 2–log A (b) A = 2–log % T
(c) A = log % T–2 (d) % T = log A –2

66. For a two electron system which is/are wavefunction can be written in the form of their product of
space part and its spin part

1 1 1 2  1 1 1 1 2 1

(a) (b)
2 1  2  2   2  2 1  2  2  2 

1  1   1 2   1   1 

(c)   2   2     2   2  (d) All of these
1      2     
67. The ground state energy of 5 identical spin-½ particles which are subject to a one-dimensional half
harmonic oscillator potential of frequency v, is
3 15 13 31
(a) hv (b) hv (c) hv (d) hv
2 2 2 2
68. An energy eigenstate of the hydrogen atom has the wave function,
3/2
1  1    r 
 nm  r , ,      sin  cos  exp     i  
81   a0    3a0 

where a0 is the Bohr radius. The principal (n), azimuthal    and magnetic (m) quantum numbers
corresponding to this wave function are
(a) n  3,   2, m  1 (b) n  2,   1, m  1 (c) n  3,   2, m  1 (d) n  2,   1, m  1

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69. A particle is located in a three-dimensional cubic well of width L with impenetrable walls. The degeneracy
of the fourth level is given by
(a) 1 (b) 2 (c) 3 (d) 4
70. In a cubic crystal, the (1 1 1), (2 0 0), (2 2 0) and (3 1 1) reflections are observed but not the (1 0 0),
(1 1 0) and (2 1 0) reflections. For this cubic crystal, the correct statements from the following are:
(A) The angle between planes (2 0 0) and (2 2 0) is 45o.
(B) The ratio of interplanar spacings of planes (2 0 0) and (2 2 0) is 2
(C) The lattice of the crystal is face-centered cubic.
3
(D) The fraction of volume occupied by atoms in the crystal is
8
(a) A, B and D (b) A and D (c) B, C and D (d) A, B and C
71. Incorrect statement about NMR of 3, 4-dimethoxy-benzylalcohol.
(a) Nine signals in 13C NMR
(b) Seven signals in 1H NMR
(c) Doublet in H NMR with J = 1.5 Hz
(d) Total three doublet signals, each of one hydrogen in 1H NMR
72. The correct number of lines expected in the proton and fluorine NMR spectrum of 1,2-difluoroethane at 30
degC.
(a) Four and six (b) Four and nine (c) Six and nine (d) Five and eight
73. Which of the following statement defines the Mössbauer effect.
(a) Nuclear transitions using gamma radiation
(b) Emission of gamma photon and absorption for nuclear transitions
(c) Recoil less Emission of gamma photon and absorption for nuclear transitions
(d) Recoil less Emission and resonant absorption gamma photon for nuclear transitions
74. Which of the following is the incorrect statement about the spectral activity of four molecules (P to S given in the
below table.

P-molecule Q-molecule R-molecule S-molecule

Pure rotational microwave spectrum Inactive Inactive Inactive Active
Pure rotational Raman spectrum Inactive Active Active Active
Vibration IR spectrum Active Active Inactive Active
Vibration Raman spectrum Active Active Inactive Active

(a) Example of P-molecule is CH 4 (b) Example of Q-molecule is CO 2

(c) Example of R-molecule is acetylene (d) Example of S-molecule is CO
75. The major products (A) and (B) are formed with appropriate conditions

(A) hv  (B)

COOEt

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 13

A B
H

(a)
Con
Con
N
H H H
N CO2Et

CO2Et

(b)
Dis Dis

H N
H N
H
CO2Et
CO2Et

H
(c)
Dis Dis

H N
H N
H
CO2Et
CO2Et

H
(d)
Con Con

H N
H N
H
CO2Et
CO2Et

76. The major product (P) formed in the following reaction

(i) H2O2, NaOH

CO2Me (P)
(ii) TsNH.NH2
(iii) Base

H O CO2Me
(a) (b)
H
O
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 14

O
CO2Me O
CO2Me
(c) (d)

N NH Ts
77. The major product (P) formed in the following reaction is
O
EtO2C MeS
Me
(i) –70ºC
(P)
(ii) Et3N, –70ºC
NHCl (iii) H2, Ni, EtOH, r.t.

Me

EtO2C EtO2C

(a) (b) Me
N N

H H

EtO2C Me EtO2C Me

(c) O (d)
O
NH2 N

H
78. The major product (P) formed in the following reaction is
I

(i) LDA, THF, –78ºC, then DMF

(P)
(ii) HSCH2CO2Me, K2CO3, DMF, r.t.

I
S

EtO2C

(a) (b)

S F

CO2Me

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 15

I
I

(c) CO2Me (d)

CO2Me
S
S

79. The value of Debye screening length is found to be 9.6 nm for a 0.001 M solution of BeCl2. The value of
Debye screening length for 0.1 M BeCl2 is
(a) 1.57 nm (b) 2.90 nm (c) 1.06 nm (d) 0.96 nm
80. In a solution of LiBr, the mobility of anion is 7.5×10–2 m2s–1v–1. The ratio of velocity of cation and
anion is 2 : 4. The molar conductance of Li+ is
(a) 3.7516 Sm2mol–1 (b) 3618.75 Sm2mol–1
(c) 4618.90 Sm2mol–1 (d) 9750.70 Sm2mol–1
81. The correct order of migration of the following amino acids towards the cathode, when separated by
electrophoresis in a solution of pH 7.3 is
Isoelectric Point
(I) Lysine 9.87
(II) Alanine 6.02
(III) Aspartate 5.95
(a) I > III > II (b) III > II > I (c) I > II > III (d) II > III > I
82. Which of the following statement is TRUE regarding transcription and translation
(a) During transcription a m-RNA molecule is created from DNA molecule
(b) Translation takes place in the nucleus, while transcription takes place in the cytoplarm
(c) During protein synthesis, translation occur prior to transcription
(d) During translation a DNA sequence is used to synthesize an Amino acid sequence.
83. Match the following:
Column-I Column-II
(P) CO 2 , HBr (M) IA  IB  IC
(Q) BCl3 , CH3Cl (N) IB  IC  IA , IA  0
(R) H 2O, CH 2  CHCl (O) IB  IC  IA , IA  0
(S) CH 4 , SF6 (Z) IA  IB  IC
The correct match is
(a) P Z, Q  O, R  M, S  N (b) P N, Q  Z, R  O, S  M
(c) P O, Q  N, R  Z, S  M (d) P M, Q  O, R  N, S  Z
84. The rotational partition function of D2 is
BhcJ  J 1 BhcJ  J 1
 
1 k BT 3 k BT
(a)   2 J  1 e    2 J  1 e
4 J 0,2,4 4 J 1,3,5...

BhcJ  J 1 BhcJ  J 1

 
2 k BT 1 k BT
(b)   2 J  1 e    2 J  1 e
3 J 0,2,4,6 3 J 1,3,5...

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BhcJ  J 1 BhcJ  J 1

 
k BT k BT
(c) 6   2 J  1 e 3   2 J  1 e
J 0, 2,4,6 J 1,3,5...

BhcJ  J 1 BhcJ  J 1

 
2 k BT 3 k BT
(d)  
3 J 0,2,4,6
2 J  1 e   
4 J 1,3,5...
2 J  1 e

85. The stability constants for the first row M2+ complexes of the strong -acceptor ligands o-phenanthroline and
bipyridine follow the order:
(a) Mn 2   Fe 2   Co 2   Ni 2   Cu 2 (b) Mn 2  Fe 2  Co 2   Ni 2   Cu 2 
(c) Mn 2  Fe 2  Co 2   Ni 2   Cu 2  (d) Mn 2   Fe 2   Ni 2   Co 2   Cu 2

86. Select the incorrect statement among the following:

(a) Two solutions of Ni2+ are blue and green: Aqueous solution of Ni(NO3)2 is blue and the colour of [Ni(NH3)6]2+
is green.
(b) The wavelength of LMCT decreases in the order: FeO24  MnO34  CrO 44  RuO 24 .
2 3 4 2
(c) Increasing order of metal-oxygen bond length: FeO 4  MnO 4  CrO 4  RuO 4 .
(d) [Fe(S2CNEt 2 )3 ] exhibits high spin-low spin equilibrium.
87. Consider the following statements
(A) Rate of water exchange : Cu 2  Ti3  Be2  Co3
(B) Rateof electron transfer from outer sphere toinner sphere mechanism : Cr 2  / Co3  Cr 2  / Ru 3  V2 / Co3
(C) Order of lattice energy : Co2  Cu 2  V2  Cr 2
(D) Order of lability : [AlF6 ]3  [SiF6 ]2  [PF6 ]
The correct statements are :
(a) A, C and D (b) B and C (c) A and D (d) All of these.
88. The incorrect statement regarding the theories for metal ligand bonding in complexes is :
(a) According to VBT, the magnetic moment can help in ascertaining type of complex : inner orbital complex
or outer orbital complex.
(b) CFT explains the thermodynamic and kinetic aspects of the complexes.
(c) CFT not only considered -bonding in complexes but also the covalent character in transition
metal complexes.
(d) VBT fails to explain the distortion in some octahedral complexes.

89. The geometries of [NiCl2 (Py)2 ] and [NiBr(diars) 2 ] respectively

(a) Tetrahedral, TBP (b) Tetrahedral, square pyramidal
(c) Octahedral, TBP (d) Octahedral, square pyramidal

90. Arrange the C  O frequencies of A  D complex in increasing order :

IrCl(CO)(PPh 3 ) 2 IrCl(CO)(PMe3 ) 2
(A) (B)
IrMe(CO)(PMe3 )2 IrPh(CO)(PMe3 ) 2
(C) (D)
(a) A < B < D < C (b) C < D < B < A
(c) C < D < A < B (d) B < A < C < D

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 
91. CpFe(CO)2  C5 H 5 Br
 A 
18e
 B  CO
18e

Identify the product (A) and (B) in the above synthetic transformation is

(a) (A)  ( 5Cp)( 1Cp)Fe(CO) 2  and B  ( 3Cp)2 Fe(CO) 2 

(b) (A)  ( 5Cp)2 Fe  and B  ( 3Cp)( 1Cp)Fe(CO)3 

(c) (A)  ( 5Cp)( 1Cp)Fe(CO)2  and B  ( 5Cp) 2 Fe 

(d) (A)  CpFe(CO) 2 (Br) and B  Cp 2 Fe2 Br2 

R
R
H
R
R
92. M + M M

R
R (Y)

R R
(X)

Product (X) and (Y) are formed by

(a) X by oxidative addition and Y by reductive elimination
(b) X and Y both by reductive elimination
(c) X by reductive elimination and Y by migratory insertion
(d) X by reductive elimination and Y by  elimination.

93.
Ni(0) Ni
(X)

(Z) (Y)
PR3

Ni

In the above oligomerization of butadiene in presence of Ni(0). The major steps involved (X), (Y) and (Z)
respectively are
(a) Oxidative coupling, alkene co-ordination followed by reductive elimination.
(b) Alkene co-ordination, oxidative coupling followed by reductive elimination.
(c) Oxidative coupling followed by migratory insertion twice
(d) Oxidative coupling,  elimination followed by migratory insertion.
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94. Consider the following statements:
(A) TeI62 and SbBr63 have perfect octahedral structure.

(B) Al2Sb126 and GaH 4Cl2 show 3centred-4 electron bonding.
(C) Sb(C3H5)5 and [CdCl5]3– have same geometry around the central atom.
(D) CN– and N 3 display properties analogous to single halogen atoms.
The correct statements are :
(a) A and D (b) A, B and D (c) B and C (d) All of these
95. Which of the following sequences are correct for the mentioned properties?
(A) MnO24  CrO24   MoO24  [Order of oxidising power]
(B) HgF2  HgCl2  HgBr2  HgI2 [Order of solubility]
(C) BeCl2  BF3  NO2  OCl2  NH 3  PH 3 [Order of bond angle]
(D) B(NR 2 )3  HB(NR 2 )2  H 2 B  NR 2 [Order of bond length]
(a) A, B and C (b) B, C and D (c) A and C (d) All of the above
96. Consider the following statements :
(A) HClO4 will behave as an amphoteric substance in liquid HF.
(B) H2SO4 will behave as a base in liquid HF.
 H 2SO3F  SO3 F .
(C) Liquid fluorosulfuric acid undergoes autoionisation as 2HSO3 F 
(D) HNO3 will act as base in H2SO4.
Correct statements are :
(a) B and D (b) B, C and D (c) A and C (d) All of these
97. Match the metalloproteins in Column A with their function in Column B:
Column–A Column–B
I. Oxidoreductase (A) Ionophore
II. Plastocyanin (B) Conversion of ribonucleotide to deoxyribonucleotide
III. Valinomycin (C) Epoxidation of alkene
IV. Coenzyme Vit B12 (D) Mobilization of Fe3+ ion.
(E) Electron transfer
(F) Oxygen transport
(a) I–E; II–E; III–A; IV–B (b) I–D; II–E; III–A; IV–B
(c) I–D; II–F; III–E; IV–C (d) I–B; II–F; III–D; IV–C
98. Nature has chosen Zn(II) ion at the active site of many hydrolytic enzyme. Among the following statements with
respect to Zn containing metalloenzyme.
(A) In catalytic hydration of CO2 by carbonic anhydrase, CO2 first interacts with water of the active site of
enzyme then with Zn
(B) Zn2+ ion is more acidic in carbonic anhydrase than in carboxypeptidase.
(C) Zn in carboxypeptidase is coordinated by three histidine residue and water molecule
(D) In peptide bond cleavage, carboxypeptidase enzyme acts more selectively when N-terminal side has
aliphatic or aromatic substituents.
The incorrect statements are
(a) A and B (b) B and D (c) A, B and C (d) A, C and D
99. Consider the following reactions :
(A) B2 H 6  2Me3 N 
 2Me3 NBH 3
230  C
(B) 3NH 4Cl  3LiBH 4   B3 N 3 H 6  3LiCl  9H 2
(C) 4PCl5  4NH4Cl 
 (NPCl2 )4  16HCl
(D) XeF4  4NO   Xe  4NOF
Correct reactions are :
(a) B, C and D (b) A and C (c) A and B (d) All of these
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100. Consider the following options for the mentioned property.
(A) F > Ne > O > N [Third ionisation energy order]
(B) Al > Ga > In > Tl > B [Electron affinity order]
(C) M gO > A l 2O3 > SiO2 > SO3 [Order of basic character]
(D) P < Si < Be < Mg < Na [Order of metallic character]
The correct statements are
(a) A, C and D (b) B and C (c) A and D (d) All of the above
101. Among the following statements:
(A) The coordination environment of Nd3+ in [Nd(CO3)4(OH2)]5– is five
(B) In electronic spectra of lanthanoid, absorption due to f-f transition are sharp but bands due to 4f-5d
transition are broad
(C) The calculated magnetic moment of Eu3+ at room temperature is higher than the observed magnetic moment.
The incorrect statements are :
(a) A and B (b) B and C (c) A and C (d) A, B and C
102. The Q-value of Na 23 ( n,α)F20 reaction is –5.4 MeV. The threshold energy of the neutrons for this reaction is
(Given: mass of neutron = 1.00866 amu and mass of Na23 = 22.99097)
(a) 5.4 MeV (b) 5.64 MeV (c) 5.18 MeV (d) 6.34 MeV

103. HgO  4I   H 2O  HgI 42   2OH 

A 0.217 g sample of HgO (molar mass = 217 g) reacts with excess iodide ions according to the reaction shown
above. Titration of the resulting solution requires how many mL of 0.10 M HCl to reach equivalence point?
(a) 1.0 mL (b) 10 mL (c) 20 mL (d) 100 mL
104. The ratio of population of first populated excited state with respect to populated ground state for
O 2 molecule is 2.2 (consider the degeneracy of both the state). The rotational constant for the
molecule is (Given: k BT = 200 cm–1)
(a) 31 cm–1 (b) 1.176 cm–1 (c) 27.36 cm–1 (d) zero
105. The major product (P) formed in the following reaction is

NBn2 O

H OCH3
H3C
workup
(P)

CH3 O

NBn2 NBn2

O OCH3
(a) H3C COOCH3 (b) H3C
CH3 OH CH3 OH

NBn2 NBn2

O OCH3
(c) H3C (d) H3C COOCH3

CH3 OH CH3 OH

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106. Select the correct option regarding compounds (A–H) is
CH3 Br CH3 Cl

NO2 Cl NO2 Br
(A) (B)
CH3

CH3

H3C
H3C (D)
(C)

Br Me H H

H Br

H Me
(E) (F)

Br CH3
OH
Br

HOOC OH H3C COOH

(G) (H)
(I) (A) and (B) are Homomers.
(II) (C) and (D) are configurational isomers
(III) (E) and (F) are diastereoisomers
(IV) (G) and (H) are enantiomers
(V) (C) and (D) are conformational isomers
(VI) (E) and (F) are conformational isomers
(VII) (G) and (H) are diastereoisomers
(a) I, II, III, IV (b) I, V, VI, VII (c) II, III, VI, VII (d) I, IV, V, VI
107. The major product (P) formed in the following reaction
O

2 mol%
(P)
Me O N2 Cu[CH(COCF3)2]2
CH2Cl2
Reflux
O

Me
(a) (b) O
Me O O

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O O
Me

(c) Me O (d)
O

108. The major product (P) and (Q) are formed from the reactant (A) and (B), respectively,

Ph Ph

H H
O O

hv hv
(P) (B) (Q)
(A) (CH3)2CHOH
(CH3)2CHOH

H H

O
Ph
(a) P = Q=
Ph
OH

O Ph
(b) P = Q=
Ph OH

O
(c) P = Q =
Ph

Ph
(d) P = Q =
OH
109. The major products A and B formed in the following reaction sequence are
O Br (CH2)9OH
BH
O
C3H7C CH A B
Pd(PPh3)4
THF, reflux

C3H7 B O
O
(a) A= (CH2)9OH
B= C3H7

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 22

C3H7 B O
O
(b) A= (CH2)9OH
B= C H
3 7

C3H7

B O (CH2)9OH
(c) A= O B= C H
3 7

C3H7
C3H7
B O (CH2)9OH
(d) A= O B=

110. The major product formed in the following reaction sequence is

O N
i) nBuLi, -78C
Br

CHO
ii)

iii) HCl

O O
O O O N O N
Cl Cl
(a) (b) (c) (d) Br

111. The major product A formed in the following reaction sequence is

i) KOH, H2O, DMSO

Cl A
ii) NH2OH-HCl
CN iii) BF3-Et2O

NC NC

(a) N O
(b) NH (c) (d)
H O
112. The major product formed in the following reaction sequence is
Br
Me i) Li, THF

ii) TMS-Cl
ii) MeCOCl-AlCl3

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 23

TMS
Me O O TMS Me
Me
Me Me
(a) (b) Me (c) Me (d) Me
O O
113. The major product formed in the following reaction sequence are
thexyl-BH2 i) CO-H2O
A B
ii) H2O2 -OH-

H thexyl O
H
B
(a) A = B=
H H
H thexyl O
H
B
(b) A = B=
H H

(c) A = thexyl B=
B
H CHO

(d) A = thexyl B=
B OH
H
O
2 2 3
114. If Z  4T X and 0.2% error is incurred for T and 0.1% error is incurred for X. The percentage error
involved in Z will be
(a) 0.60 (b) 0.50 (c) 0.35 (d) 0.25
115. The major product (P) formed in the following reaction is
(i) H2
(P)
Lindlar catalyst
(ii) 
HO OH

H OH H OH

(a) (b)
OH OH
H H

H
OH H OH

(c) (d)
OH
H
H
OH

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116. The major product (B) formed in the following reaction is
(i) OsO4 F–
H3C OTBDMS (A) (B)
(ii) SOCl2 H+
(iii) RuCl3, NaIO4
Cl OH
O
HO H3C OH H3C Cl O
(a) (b) (c) (d) H3C OH
CH3
OH OH
117. The major product (P) formed in the following reaction is
H

(CF3CO)2O
(P)
N Me
S

O O
H
H

O SMe
(a) O (b) N
N S
O Me
O

H H
OH OH

(c) N (d) N

O O
118. For trans N 2F2 molecule the dxy orbital belongs to which irreducible representation (take h to be the xy
plane and C2 axis along with the z-axis)
(a) Ag (b) Bg (c) Au (d) Bu
119. Which of the following integral will be non-zero for D2d point group.
D2 d E 2 S4 C2 2C2 2 d
A1 1 1 1 1 1 x2  y 2 , z2
A2 1 1 1 1  1 Rz
B1 1 1 1 1 1 x2  y 2
B2 1 1 1 1 1 z xy
E 2 0 2 0 0 ( xz, yz )
( x, y ); ( Rx , Ry )

(a)  d x2  y2  z  d xy d (b)  d z2  z  d xy d (c) both (a) and (b)(d) None of these

120. The radius of an adsorbate molecule is 4.9 nm. If the radius of an adsorbent molecule is 25 µm, the number
of adsorbate molecule is approximately
(a) 105 (b) 106 (c) 107 (d) 108

All t he Best for CSIR-NET “16t h June 2019” Exam

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 25
Space for rough work

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 26

CSIR-UGC-NET/JRF | GATE CHEMISTRY

CHEMICAL SCIENCES Date : 10-06-2019

TEST SERIES-E

ANSWER KEY [FULL LENGTH TEST - 2 ]

PART-A

1. (b) 2. (b) 3. (a) 4. (b) 5. (b) 6. (c) 7. (b)

8. (c) 9. (c) 10. (b) 11. (a) 12. (c) 13. (c) 14. (c)

15. (b) 16. (a) 17. (c) 18. (b) 19. (b) 20. (c)

PART-B

21. (c) 22. (c) 23. (a) 24. (b) 25. (c) 26. (a) 27. (c)
28. (c) 29. (d) 30. (b) 31. (c) 32. (c) 33. (c) 34. (c)
35. (c) 36. (b) 37. (a) 38. (b) 39. (b) 40. (c) 41. (d)
42. (c) 43. (c) 44. (b) 45. (a) 46. (a) 47. (b) 48. (b)
49. (b) 50. (c) 51. (c) 52. (d) 53. (b) 54. (c) 55. (a)
56. (a) 57. (b) 58. (c) 59. (d) 60. (a)

PART-C

61. (a) 62. (b) 63. (c) 64. (c) 65. (b) 66. (c) 67. (d)
68. (c) 69. (c) 70. (d) 71. (d) 72. (b) 73. (d) 74. (c)
75. (c) 76. (b) 77. (b) 78. (c) 79. (d) 80. (b) 81. (c)
82. (a) 83. (c) 84. (b) 85. (b) 86. (a) 87. (a) 88. (c)
89. (d) 90. (b) 91. (c) 92. (d) 93. (b) 94. (b) 95. (d)
96. (d) 97. (a) 98. (d) 99. (d) 100. (a) 101. (c) 102. (b)
103. (c) 104. (b) 105. (d) 106. (b) 107. (c) 108. (b) 109. (d)
110. (a) 111. (c) 112. (a) 113. (b) 114. (c) 115. (c) 116. (a)
117. (b) 118. (a) 119. (b) 120. (d)

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