DELHI PUBLIC SCHOOL NUMALIGARH

WINTER HOLIDAY REVISION WORK 2018-19

CLASS –XI(SCIENCE)
TOPICS- (I) REDOX REACTIONS
(II) SOME BASIC CONCEPTS IN ORGANIC CHEMISTRY+ HYDROCARBONS
(III) PERIODIC CLASSIFICATION OF ELEMENTS.
(IV) CHEMIC AL BONDING AND MOLECULAR STRUCTURE.
(V) STATES OF MATTER.
(VI) THERMODYNAMICS.
GENERAL INSTRUCTIONS-
All answers have to be written in Assignment notebook and submitted on the school reopening day after
the WINTER vacation.

1.Write the IUPAC name of the following:-

(a) (CH3)3CCH2OH
(b) (CH3)2C(C2H5)2
(c ) CH3—C—CH –CH –COOH
II I I
O CH3 NH2
(d) Br-CH2-C(CH3)2-CH2-CH= CH – CH(OH)-COOH
(e)(CH3)2CH=CH-CH2Cl
2. Draw all the possible position and chain isomers of Hexyne.
3. Write the complete structural formula and bond line formula of the following:-
(a) 3,4-Dimethylhept-3-ene.
(b) 2,4-dinitrochlorobenzene.
(c ) 4-methylhexen-3-en-2-one.
(d) 2-ethyl-3-hydroxy-2-methyl propanal.
(e)3-phenylprop-2-en-1-oic acid.
(f) 3,3- diethyl-5-isopropyl-4- methyl octane.
(g) 1-methyl-3-propyl cyclohexane
(h) 2-cyclohexyl propanal.
4. Why fluorine does not show any disproportion reaction?
5.Balance the following by ion electron method/also by oxidation number method.
(a) MnO4- + Cl- ----------- Mn2+ + Cl2(acidic medium)
(b) Cr2O72- + SO2 -------- Cr3+ + SO42-( acidic medium)
6.Identify the strongest and weakest reducing agent from the electrochemical series.
Zn, Cu, Ag, Na, Sn.
7. Explain the following effects with suitable examples-
(i) +I effect and –I effect.
(ii). +R effect and –R effect.
(iii) + E effect and –E effect.
(iv) Hyperconjugation.
8. Discuss the different types of isomerism in organic compounds with suitable examples.
9. Draw the resonance structures of
(i) phenol.
(ii) benzoic acid.
10. What are Electrophiles and nucleophiles. Give three examples of each.
11. Distinguish between homolytic and heterolytic fission with suitable examples.
12. Define oxidation and reduction in terms of oxidation number.
13. Explain the constriction and working of Daniel cell with proper diagram.
14. Different between emf and potential difference.
15. What is standard reduction potential. Depict the electrochemical cell and the redox reaction that would
takes place by connecting potassium electrode and silver electrode.
EOK+/K = -2.93V and EOAg+/Ag = 0.80V.Calculate also the emf of the cell.

16. Discuss the stability of 10carbocations and 20 carbocations and 30 carbocation.

17. Draw the hyperconjugation structures of a 2o carbocation.
18. Write correctly balanced equation for the following redox reaqction using half reaction method-
Bi(s) + NO3- + H+ ----------- NO2 + Bi3+ + H2O
19. Make a mind mapping of all the important topic of the chapter redox reaction.
20. What is the basic difference in the approach between Mendeleev’s periodic table and modern periodic
table.
21. Explain the following-
(i) Cl has a higher electron gain enthalpy than F.
(ii)Size of anion is larger than corresponding atom.
(iii)First I.E of Na is lower than Mg but second I.E is higher than Mg.
22. An atom of element has atomic number 52. To which block it belongs. Predict also its group and period
in the periodic table.
23. An element X belongs to the third period of the p-block. It has 7 electrons in the outermost shell. Write
its (i) electronic configuration,
(ii) valency
(iii)Formula of its oxide and hydrides.
24. What is shielding effect. How does shielding affect the atomic properties like-
(i) Ionisation enthalpy (ii) electron gain enthalpy.
25. Account for the fact that (i) the 6th period of the periodic table has 32 elements.
(ii) The position of hydrogen is anomalous in the periodic table.
26. The increasing order of reactivity among the group 1 elements is Li ‹ Na ‹K‹ Rb‹ Cs where as
among group 17 elements is F› Cl › Br › I. Explain.
27. Discuss the variation in size of the isoelectronic species :-
O2- F- Mg2+ Na+.
28. Which has a higher ionization enthalpy- N or O. Explain.
29. On the basis of M.O theory predict the magnetic character and calculate the bond order in O2
30. What is an isotherm? Why do gases deviate from ideal behavior?
31. What volume of air will be expelled from a vessel containing 400cm3 at 70C when it is heated to 270C at
the same pressure?
32.Write the hybridization involved in the molecules with the following shapes.
(i) see-saw (ii) square planer (iii) trigonal planer (iv) octahedral
33.Why is the gas constant ‘R’ called universal gas constant. Derive its value in S.I unit.
34. On the basis of hybridization concept explain the formation of the following molecules:-
(i) NH3 (ii) CO2
35.Calculate the volume occupied by8.8g of CO2 at 31.10C and 1bar pressure.
(R= 0.083barL/K/mol)
36.A vessel of 120ml capacity contains a certain amount of gas at 350C and 1.2 bar pressure. The gas is
transferred to another vessel of volume 180ml at 350C. What would be the pressure.
37. 250ml of nitrogen maintained at 720mm pressure and 380ml of oxygen maintained at 650mm pressure
are put together in 1L flask. If the temperature is kept constant what will be the final pressure of the mixture.
38. Write short notes on(i) Ozonolysis(ii) Markovnikov’s rule(iii) Friedal Crafts alkylation.(iv) Wurtz
reaction
39. Write the mechanism involved in the following reactions
(i) Chlorination of methane.
(ii) Nitration of benzene.
40. Convert the following (i) Ethyl chloride to ethanol.
(ii) Ethyl chloride to ethene.
(iii) Propene to 1-bromo propane
(iv)Ethene to ethane-1,2-diol.
41.What is absolute zero?
42.State Dalton’s law of partial pressure.
43.State Hess’s Law of constant heat summation.
44.What is an adiabatic process?
45Define viscosity.
46Derive the ideal gas equation.
47Why do gases deviate from ideal behaviour? Which postulates of kinetic molecular theory of gases do not
hold true under all conditions of temperature and pressure?
48 What volume of air will be expelled from a vessel containing 400cm3 at 70C when it is heated to 270C at
the same pressure?
49 Define vapour pressure. Which has a higher boiling point- Ethyl alcohol or water? Explain with reference
to their vapour pressure..
50A Ne-O2 mixture contains 70.6g O2 and 167.5g neon. If pressure of the mixture of gases in the cylinder is
25 bar what is the partial pressure of the individual gases.(RAM of O=16,Ne=20)
51Calculate the volume occupied by8.8g of CO2 at 31.10C and 1bar pressure.
(R= 0.083barL/K/mol)
52.Derive the relation between Cp and Cv for an ideal gas.
53.State the First law of thermodynamics and derive the mathematical relation.
54.The standard enthalpy of formation of CO(g), CO2(g), N2O(g) and N2O4(g) are -110,
-393, 81 and 9.7KJ/mol respectively. Find the enthalpy of the reaction:
N2O4(g) + 3CO(g) → N2O(g) + 3CO2(g)
55.The change in internal energy for the following reaction at 298K is -742.7KJ.
NH2CN(g) + 3/2 O2 (g) → N2(g) + CO2(g) + H2O(l)
Calculate the enthalpy change for the reaction at 298K.
56. Define critical temperature. Critical temperature for CO2 and CH4 are 31.10C and
-81.90C.Which has stronger intermolecular forces and why?

57. 250ml of nitrogen maintained at 720mm pressure and 380ml of oxygen maintained at
650mm pressure are put together in 1L flask. If the temperature is kept constant what
will be the final pressure of the mixture.

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