Excited States In Organic Chemistry

J. A Barltrop J. D Coyle

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The excited state thus produced is formed in a very short time i.e. of the order of 10-15 seconds. In accordance with Franck-Condon
principle, during electronic excitation the atoms of the molecule do not move. Similarly, at ordinary temperatures, organic molecules
are in a constant state of vibrations, each bond having its characteristic stretching and bending frequencies. When infrared light
radiations between 4000-400 cm-1 (the region most concerned to an organic chemist) are passed through a sample of an organic
compound, some of these radiations are absorbed by the sample and are converted into energy of molecular vibrations.