SCIENCE ENTRANCE ACADEMY

II PUC CHEMISTRY (34)

Date: 12-10-2019
Time: 3.00hrs IV PREPARATORY EXAMINATION
Max. Marks: 100
Instructions: 1. The question paper has four parts: A, B, C and D. All parts are compulsory.
2. Write balanced chemical equations and draw labeled diagrams wherever required.
3. Use log tables and simple calculations if necessary.(Use of scientific calculator is not allowed.)
PART-A
I. Answer ALL the following. (Each question carries 1 mark) 10x1=10
1. What happens to the total volume when ethanol and water are mixed?
2. Mention the SI unit of Ebullioscopic constant.
3. How many Faradays of electricity are required to discharge 1 mole of calcium from molten
CaCl2?
4. By how many times does the t1/2 of zero order reaction increase if the initial concentration of the
reactant is doubled?
5. Name the catalyst that catalyses the decomposition of KClO3 into KCl and O2
6. What is the function of aniline in froath floatation method?
7. Name the noble gas which is used in Magnetic Resonance Imaging system.
8. Grignard reagents should be prepared under anhydrous conditions. Why?
9. Why aromatic carboxylic acids do not undergo Friedel-Crafts reaction?
10. Glucose on oxidation with Br2/ water gives gluconic acid. What does this reaction indicate about
the structure of glucose?
PART-B
II . Answer ALL the following. (Each question carries two marks.) 8×2= 16
11. Atoms of element B form hcp lattice and those of element A occupy 2/3 rd of tetrahedral voids.
What is the formula of the compound formed by these elements A and B?
12. Write chemical formula of rust. What is the overall electrochemical reaction taking place during
rusting?
13. The electrical resistance of a column of 0.05 mol/L NaOH solutions of diameter 1cm and length
50cm is 5.55 x 103 ohm. Calculate its resistivity.
14. What happens when acidified KMnO4 reacts with oxalic acid? Write ionic equation.
15. Explain with chemical equation, why tert-butyl ether cannot be prepared by Williamson’s
synthesis using tert-butyl halide?
16. A carboxylic acid is treated with alcohol in presence of conc. H2SO4. Name the reaction. Give
its general equation.
17. What are agonists and antagonists?
18. Name two α amino acids which form a dipeptide which is 100 times sweeter than cane sugar.
PART –C
III Answer any ALL of the following. (Each question carries 3 marks) 8× 3=24
19. How do you extract iron from roasted haematite ore? Explain with diagram.
20. In the manufacture of ammonia by Haber’s process;
(a) Write the balanced chemical equation
(b) Name the promotor used
(c) Draw the flow chart [1+1+1]
21. Give one example each to show that concentrated sulphuric acid is
(a) A dehydrating agent
(b) An oxidizing agent for metals
(c) An oxidizing agent for non metal [1+1+1]
22. (a) Explain bleaching action of chlorine.
(b) What is the basicity of Phosphonic acid? [2+1]
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 23. How is potassium permanganate prepared from MnO2? (non commercial method)
24. Name the elements of 3d series:
(a) Having positive value of M2+/M standard electrode potential
(b) Showing highest oxidation state.
(c) Colourless in +2 oxidation state. [1+1+1]
25. (a) Explain linkage isomerism with an example.
(b) Give the IUPAC name of K[Cr(NH3)2(CO3)2] [2 +1]
26. Explain the hybridization, geometry and magnetic property of [CoF6]3-
PART-D
IV. Answer any FOUR of the following.(Each question carries 5 marks) 5x4=20
27. (a) Calculate the packing efficiency in hexagonal close packing arrangement.
(b) Give reason: Rock salt some time appears yellow in colour. [3+2]
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28. (a) 200 cm of aqueous solution of a protein contains 1.26 g of protein. The osmotic pressure of
such a solution at 300K is found to be 2.57x10-3bar. Calculate the molar mass of protein.
(b) Write any two characteristics of non ideal solution. [3+2]
29. (a) In the given Galvanic cell: Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) ; Identify:
i. Which of the electrode is negatively charged?
ii. The carriers of the current in the cell.
iii. Individual reaction at each electrode.
(b) Mention any two factors which affects electronic conductance. [3+2]
30. (a) Derive integrated rate equation for the velocity constant of a zero order reaction. [3+2]
(b) Explain the effect of positive catalysts on the rate of the reaction with the help of graph.
31. (a) Explain the following terms
i) Zeta potential
ii) Kraft temperature
iii) Selectivity of catalyst
(b) What is the change in enthalpy and entropy during adsorption of gas on solid? [3+2]
V. Answer ALL the following. (Each question carries 5 marks) 6×5=30
32. (i) Explain SN2 mechanism with equation
(ii) What are allylic halides? Give one example.
(iii) What are freons? [2+2+1]
33. (a)Explain the preparation of propanol from propene by hydroboration oxidation reaction.
(b)Name the conjugated diketone formed, when phenol is heated with chromic acid? Write the
chemical reaction.
(c) Give the IUPAC name of product formed when t-butyl alcohol is heated with copper at
573K. [2+2+1]
34. (a) Explain the mechanism of addition of HCN to aldehyde.
(b) Write equation for
(i) The formation of oxime from carbonyl compounds.
(ii) The reaction between carboxylic acid and PCl5. [3+2]
35. (a) Explain how Hinsberg’s reagent is used to distinguish the primary, secondary and tertiary
amines.
(b) Write chemical equation for a coupling reaction of diazonium salt with phenol [3+2]
36. (a) Write the Haworth’s structure of lactose.
(b) What are reducing sugars? Why sucrose is not a reducing sugar?
(c) Give an example for fibrous protein. [2+2+1]
37. (a) Name the polymer used in laminated sheets and give the name of monomeric units involved
in its formation.
(b)Which type of biomolecules has some structural similarity with synthetic polyamides?
What is the similarity? [3 +2]

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