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Outline
• Stages of Oil Recovery
• EOR recovery concepts
• EOR and heavy oil
• Chemical EOR for heavy oil
• Chemical EOR methods
• Injectivity issues - major limitations in heavy oil
• Good recovery at adverse mobility ratio
• Field cases- chemical EOR projects in heavy oil
field and lessons learnt
• Summarized concerns and possible solutions
Stages of oil recovery
Recovery Mechanisms
Natural Drives
Gravity Drainage Water Drive Gas Cap Drive Solution gas Drive
High Performance
systems and
optimization can
expand the limit
Above Figure shows an oil blob being displaced by water at the pore scale in a reservoir. The blob
has encountered a constriction at a pore throat. Obviously, in order for the oil blob to pass through
the constriction and be produced, a sufficiently high pressure gradient must be applied across the
blob. If such a pressure gradient cannot be generated by the water injection, then the blob will be
trapped as residual oil. Pressure gradient required to mobilize the oil blob is given. The objective of
this exercise is to determine whether or not such gradients can be created under normal oilfield flow
conditions. Here are additional facts about the problem.
Question 1 Question 2
Most of Canadian ASP pilots for heavy oil are designed to serve
the 1st purpose (Delamaide et al. 2014)
Phase Behavior Studies
▪ Phase behavior experiments gives an idea about the ability of chemical slugs to provide ultra-
low IFT without performing IFT experiments. IFT experiments are expensive
▪ There exists the optimal salinity and surfactant concentration at which low IFT can be attained
for the specific system (Surfactant, salts, oil)
▪ Three types of phase behavior (when adding surfactant to water-oil system) exists
1. Winsor Type I : forms oil – in – water microemulsions in the water phase
2. Winsor Type 2 :forms water – in – oil microemulsions in the oil phase
3. Winsor Type 3 :forms microemulsions in the separate phase between oil and water. it is a
continuous phase (Ideal for ultra-low IFT)
Type 3 gives
Ultra-low IFT
Phase behavior of ASP slugs with heavy oil
For 1% surfactant ASP slug with For 1% surfactant ASP slug with varying
varying salinity : Phase behavior salinity : IFT by Spinning drop
• ASP slugs are usually carried out in softened water (low concentration of divalent Ca2+
and Mg 2+). But connate water has significant amount of divalent ions
• At high pH (Around 9), Magnesium can bridge the colloidal silicate particles and forms
an amorphous magnesium silicate scale
• At high pH (Around 9), Calcium forms calcium carbonate which provides nuclei for the
formation of silicate scale
• This affects production and injection tubulars and slows down the efficiency of the
pumps.
• It also leads to the formation damage which eventually reduces the injectivity of the
process
ASP flooding- Scaling Monitoring and
Prevention
Steel coupons installed at well head gives the
intent of shale deposition
Stage 1: No deposit
Stage 2: Filmy
Stage 3: Light scale
Stage 4: loose scale
Stage 5: Scale and
Scale 6: Heavy scale
Accordingly, inhibition measures can be
taken
As the ASP slugs gets propagated in the reservoir, produced fluid will have various pH,
concentrations of silicate, magnesium and calcium
Prevention:
1. Mechanical inhibition
2. Chemical inhibition
ASP slugs are avoided in carbonate formation as the alkali loses its alkalinity
and induces the permeability damage due to precipitation of CaC03
ASP flooding- Recovery Mechanisms in
heavy oil
• ASP reduces the IFT and increase the capillary
number
• However for viscous oil, sweep efficiency is
more important
• Under low IFT, oil and water can mix and lead
to formation of oil-in-water (O/W) emulsions.
In the presence of salts, water-in-oil (W/O)
emulsions are expected to be formed.
• Both the emulsions provides an additional
viscous force that increases the sweep
efficiency (needed for heavy oil recovery)
Polymer flooding
➢ Involves the injection of polymeric solutions as the displacing fluid to
increase the sweep efficiency.
➢ Polymer flooding provides favorable mobility ratio by increasing the
viscosity of the water and decreasing the permeability of water. It avoids
fingering to increase the sweep efficiency (mainly applicable in heavy oil
recovery)
➢ Polymer flooding also can be used for conformance control applications in
fractured and channeled reservoirs
Polymer flooding – Rheological behavior
➢ Two major types of polymer are Xanthan gum and Hydrolyzed
polyacrylamide (HPAM)
➢ Xanthan gum is a purely viscous polymer and HPAM is viscoelastic
polymer. (HPAM is mostly preferred for heavy oil applications)
➢ Rheology of viscous and viscoelastic polymers differs significantly
Delshad et al. 2008 UVM model requires core flood data for
Carreau model based on rheological data
extracting the extensional parameter
alone
Numerical Problem: Polymer flood- Injectivity
1. Calculate the injectivity of viscoelastic polymeric solutions using
carreau model, UVM model and true apparent viscosity from the
figure in the previous page.
a. Assume the shear rate of 1000/s = velocity of 100 ft/day. This is the
rate around the wellbore. Use the core dimensions - core length- 12 cm ,
diameter= 1.5 cm
2. Using the three different core injectivity results , calculate how much
would be safe injection pressure that can be generated by the polymer
solutions in the reservoirs if the depth is 2000 ft and fracture gradient is
0.7 psi/ft.
3. Compare the three results.
3. Explain, what will happen if you go with the carreau model and UVM?
4. What difficulty would be there with UVM model in terms of field
applications?
Rheological Measurements in Lab- Shear and Extensional rheometer
Rotational rheometer
Features
1. Can measure both shear and
extensional properties
2. Proprietary viscoelastic model
(Patent submitted) is developed
Extensional rheometer using shear and extensional
parameters
Fractional Flow curve: Effect on heavy oil
and Polymer flood
Case 1 – End point mobility ratio – 3
(Water flood in light oil reservoir : Displacing fluid viscosity is 1 cP and Displaced oil viscosity- 10 cP)
Case 2 – End point mobility ratio - 60
(Water flood in heavy oil reservoir : Displacing fluid viscosity is 1 cP and Displaced oil viscosity- 100 cP)
Case 3 – End point mobility ratio – 0.03
(Polymer flood in light oil reservoir : Displacing fluid viscosity is 1 00 cP and Displaced oil viscosity- 10 cP)
Case 2
Water flow is high even at low saturation. Means less oil is in flowing
(So more Fingering, less stable front).
This is the case with 100 cP oil itself.
Case 1
Water flow is nominal even at low saturation.
(So not much Fingering, stable front than case 2)
Case 3 (Best)
Water flow is low even at high saturation. Means more oil is
flowing.
(So no Fingering, very stable front)
Fractional Flow curve: Effect on heavy oil
and Polymer flood
Case 1 – End point mobility ratio – 3
(Water flood in light oil reservoir : Displacing fluid viscosity is 1 cP and Displaced oil viscosity- 10 cP)
Case 2 – End point mobility ratio - 60
(Water flood in heavy oil reservoir : Displacing fluid viscosity is 1 cP and Displaced oil viscosity- 100 cP)
Case 3 – End point mobility ratio – 0.03
(Polymer flood in light oil reservoir : Displacing fluid viscosity is 1 00 cP and Displaced oil viscosity- 10 cP)
Case 2
Water saturation front is lowest . Lots of oil need to be recovered in this
Fingering displacement.
(Almost reached the producer and early break through).
This is the case with 100 cP oil itself.
Case 1
Water saturation front is higher than case 2.
(better than case 2)
Case 3 (Best)
Water saturation front is highest. Almost reached the residual oil
saturation. Piston like displacement.
(The front is still a long way from reaching the producer)
Fractional Flow curve: Effect on heavy oil
and Polymer flood
Case 1 – End point mobility ratio – 3
(Water flood in light oil reservoir : Displacing fluid viscosity is 1 cP and Displaced oil viscosity- 10 cP)
Case 2 – End point mobility ratio - 60
(Water flood in heavy oil reservoir : Displacing fluid viscosity is 1 cP and Displaced oil viscosity- 100 cP)
Case 3 – End point mobility ratio – 0.03
(Polymer flood in light oil reservoir : Displacing fluid viscosity is 1 00 cP and Displaced oil viscosity- 10 cP)
Case 2
Break through recovery is less. Need more pore volume of injection to increase
the recovery
This is the case with 100 cP oil itself.
Case 1
Break through recovery is higher than case 2.
(better than case 2)
Case 3 (Best)
Reached residual oil recovery even during break through.
(Recovered the maximum recoverable oil in short time. Profitable
project if polymer is added to water)
?
Can Polymer flood recover more than
residual oil limit ?
Yes if the polymer is viscoelastic
Polymer flooding- Issues
1. Most of the polymers are susceptible to
mechanical degradation. This will makes the
polymer ineffective to sweep the oil in
farthest part of the reservoirs
2. Injectivity becomes an issue when applied at
high concentration for heavy oil recovery
(due to shear thickening)
3. Most of the polymers fails to make provide
the required viscosity needed for mobility
control in heavy oil recovery applications
4. Quantification of viscoelastic effects , a major
challenge in chemical EOR industry
Why Injectivity is crucial for heavy oil
reservoirs ?
• Injectivity is the measurement of ease with
which the fluid can be injected into the
reservoir (Hyne 1994)
(Seright 2010)
(Seright 2010)
CHEMICAL EOR in Heavy oil reservoirs: The case
studies
Barmer Basin
Polymer flood Case Study – 1 (Bohai Field,
China)
Bohai field – Rock and Fluid Properties
Porosity- 28 to 35%; Average Permeability – 2600 mD ; Thickness – 61.5 m ;
Depth – 1300 to 1600 m; Reservoir temperature - 65Oil viscosity – 240 cP;
Polymer viscosity – 80 cP; Formation – sandstone (poorly consolidated)
• The pool was discovered in 1986 and over all primary recovery factor (using
both vertical and horizontal wells) is 4%. Low thickness, high oil viscosity and
high water cut are reasons
• Water flooding was initiated in 2006 (1 injector and 2 producers) with
horizontal wells. Break through was quick and oil rates dropped suddenly.
This is attributed to the mobile water presence and heterogeneity
• Polymer flood was started in Nov 2008 ( 2 injectors and 3 producers) with
horizontal wells. Oil production was good for a first few months. Then water
cut increased drastically. Recovery from the central well was 13%.
Key lessons from Mooney : Presence of High Mobile water
Presence of high
mobile water
indeed results in
early break
through (in
mooney and
pelican lake
region)
Rates increased
Rates increased from 9 BOPD to 364
from 18 bopd to BOPD in central
232 bopd well
Rates increased
from 9 BOPD to
364 BOPD
Expansion of Polymer flood projects in
Pelican Lake following its initial success