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CHAPTER I
INTRODUCTION
The Philippines population is equivalent to 1.38% of the total world population, this
is 104,096,518 based on the latest update of United Nations last September 13, 2017
disposal is also increasing. According to Castillo (2013), about 35,580 tons of garbage
is generated every day in the Philippines. Proper waste management and disposal is
one of the major problems that the country is currently facing. The government,
particularly the local authorities like barangays, government offices and agencies,
schools, etc. are gradually implementing the program of “segregations schemes” for our
daily waste products as a result of our daily human activities. “Segregation” refers to the
solid waste in order to promote recycling and re-use of resources and to reduce the
volume of waste for collection and disposal (National Solid Waste Management
(NSWM) Strategy, 2016). The total solid waste generated from households, 95% can
still be reused or recycled (43%), or turned into compost (52%) (Castillo, 2013).
effective way to reduce, reuse, and recycle garbage. Biodegradable wastes are those
capable of being slowly broken down into very small parts by natural processes
(Merriam-Webster, n.d.).
Although, there is a wide campaign for this program the amount of waste materials
still increases due to population growth and because of irresponsible garbage disposal.
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People throw their trashes almost anywhere they wanted to. Often times, if not properly
contained, this may have harmful effects on the health of humans. One great example
direct health effects arise from excessive breeding of vermin and agents of disease
such as rats, flies and mosquitoes (Obinna, 2015). In addition, garbage that is disposed
improperly releases methane gas (Boehlke, 2017) that can cause unconsciousness and
even death when exposed for a long period of time (Roman, 2014).
In some places, land pollution is a serious matter that is the result of improper
waste disposal. One contributor in these wastes is the mussel shells. Tons of Philippine
mussel (tahong) also known as Perna viridis are harvested every year and widely
distributed in the Asia-Pacific region that also greatly contributes to the increase of solid
wastes generated in the region (Murico, 2007). According to Othman, et al. (2013), the
Consequently, the researchers have thought of a way to make use of these disposed
mussel shells productively. After some thorough studies, the researchers have agreed
mussel shell is composed of 95% Calcium Carbonate (CaCO3) is one of the main
component for the durability of cement. Shells by products have been applied in
industries (Othman, et al., 2013). The purpose of this study is to make a mid-class
concrete that is less expensive but the quality is the same as the ordinary concrete that
a. Texture
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b. Compressive Strength
a. Texture
b. Compressive Strength
The study aims to investigate the compressive strength of concrete made from
mussel shells (Perna Viridis) that is collected from Pasay City Public Market, Seaside
Dampa Macapagal, and Sineguelasan, Bacoor, Cavite. The collection of mussel shells
materials like the mussel shells. In addition, land pollution caused by improper
waste disposal will be reduced into minimum amount by recycling mussel shells
uplifting their livelihood status. Since remnants like mussel shells can now be
use into useful material or as one of the main ingredient in making concrete
products.
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c. Construction Industry. This study will help improve the quality of construction
cement’s composition, one must know the function of every ingredient present in the
cement. In composing a cement, there must be eight present ingredients which are the
Calcium oxide, Silicon dioxide, Aluminum oxide, Magnesium oxide, Iron oxide, Calcium
sulfate, Sulfur trioxide, and Alkaline. In this study, the researchers will focus on the
diagram, it shows the relation of dependent and independent variable along with the
extraneous variable. The pulverized mussel shells where the calcium carbonate come
from is the main component or ingredient in cement. In this study, the researchers will
replace the cement with calcium carbonate from the mussel shells which will determine
the strength and texture of the concrete in different amount of mussel shells present. In
the concrete making, the pulverized mussel shell is the independent variable, the
strength and texture is the dependent variable and the extraneous variables are the
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Cement
Sand
Pulverized Strength
Water
the mineral calcite and aragonite and is the main component of pearls and
adheres other materials binding them together. Cement is used with fine
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pushed together).
allow the concrete to achieve the desired properties for its intended use.
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CHAPTER II
This chapter presents the literature of the study which served as the framework
thereof. Further, it narrates some related studies that can support the present study.
I. Mussel Shells
One of the main sources of protein for humans is the mussel. According to Lemer,
et al., (2017), Mussel (Mytilida) are a group of bivalves with ancient origins and some of
the most important commercial shellfish worldwide. Perna Viridis, commonly known as
the mussel (tahong), is a bivalve mussel widely distributed in the Asia-Pacific region.
The green mussel shells that greatly contributed to the increase of solid wastes
generated in the region (Murico, 2007). Reusing and recycling mussel shells can reduce
the generated waste disposed prevalent in our country. Mussel shells contain 95% of
calcium carbonate (CaCo3) (Kumar, et al. 2016). According to Kert Wattanaruk, Makul
and Sripattarapravert (2012), the composition of CaCo 3 “is similar to limestone powder
or dust-like stone powder from grinding limestone” CaCo3 is widely used in industries
and mussel shells are a natural source of this, making it a possible alternative to
construction of roads, replacement of industrial lime, ash cements, fertilizer, lime agent,
moisturizers and tiles (Othman, et al., 2013). Reusing and recycling mussel shells can
According to Filho, et al., (2014), the shell act as skeletons for supporting the soft
parts of the molluscs’ body, offer mechanical protection against predators and, in
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terrestrial species, keep abrasive materials (earth and sand) out of the mantle cavity.
The shell is mainly made of calcium carbonate (CaCO3) (Kumar, et al. 2016). According
similar to limestone powder or dust-like stone powder from grinding limestone. CaCO3
is widely used in industries and mussel shells are a natural source of this, making it a
According to Filho, et al. (2012), CaCo3 is the second most abundant mineral
existing in the earth’s crust, exceeded only by quartz. Present day production of CaCO 3
in the world ocean is calculated to be about 5 billion tons per year of which about 3 bt
accumulate in sediments the other 40% is dissolved. Nearly half of the carbonate
sediment accumulates on reefs banks and tropical shelves. Deep sea carbonates
lower productivity and accumulation rates than shallow water carbonate (Milliman,
2011).
Studies indicate that CaCO3 is not entirely an inert admixture, it not only has the
filling effect but is also involved in cement hydration, accelerate the hydration of the
cement and the formation of paste structure. By mixing shell powder with the cement on
one hand the shell can be used reasonably, the impact that caused by hard shell of
shellfish after the death on the marine environment can be reduced. On the other hand
the performance of the cement can be improved (Wang et al., 2012). Mussel shell
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contains 95% of CaCo3 that led researchers to produce shell by-products applied in
favourable in application since the production of shell powder requires intensive energy
to burn and grind the shells as fine as grain powder and the produced CaCo 3 is suitable
skeletal shells. It can be used for building purposes like making bricks, road and
cement.
III. Sand
A. Characteristics
Sand is naturally occurring granular material composed of finely divided rock and
mineral particles. The composition of sand is highly variable, depending on the local
rock sources and conditions, but the most common constituent of sand in inland
continental settings and non-tropical coastal settings is silica (silicon dioxide, or SiO2),
usually in the form of quartz (Verma, 2015). In terms of particle size as used by
geologists, sand particles range in diameter from 0.0625 mm (or 1/16 mm) to 2 mm.
According to Verma, (2015), an individual particle in this range size is termed a sand
grain. Sand grains are between gravel (with particles ranging from 2 mm up to 64 mm)
B. Uses
Sand could be used for building purposes. Aside from water and gravel or stones,
sand is one of the components to make a cement and concrete. The sand used in
concrete are classified as soft or sharp. Soft sand are smooth while the sharp sand are
rough. It is because the soft sand comes from beaches while the rough sand is the
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result of crushing of larger aggregate. The sand used in concrete must be clean sand
because it will weaken the foundation on hardened concrete (Plaehn, n.d). According to
Badjad, et al., (2013), Natural sand, crushing, natural gravels, crushing hard stones
(artificial sand) are fine aggregates that influence the workability and hardened the
concrete. Sand is an essential component because 25% of wet concrete mixture are
made up of sand and it fills the gaps between larger stones (Plaehn, n.d). According to
Engineering Material (2011), it is used as an inert material to give volume in mortar and
if the sand used is well graded or high quality, it provides density. If the sand content
has been increase, the strength of cement mortar also increase (Bu et al, 2017).
The sand has different purposes depending on the situation. The sand acts as
adulterant. It increase the volume of mortar and it can also use in setting to absorb the
carbon dioxide if the building materials used is fat lime. Another is in shrinkage, it
prevents the shrinkage of the mortar and it also increase the strength of the mortar by
variation of its proportion and increases its resistance to crush. Last one is in surface
IV. Cement
Cement plays an important role in the field of industry. It is commonly used in the
construction of building, infrastructure, bridges and road. The materials needed in the
carbonate (Mishra, 2017). And according to Merdes, et al. (2014), portland cement is
one of the most produced chemical product more than 3.6 at 2011 causing an impact to
the environment. In order to maintain the quality of cement, the materials to be used
must possess the ideal composition and the variations remains in its range because
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most of the cements that are being process or produce are cheap and low quality so
Cement production is highly needed in today’s world because of its high demand
for building constructions. According to Polygon, China is the number one producer of
cement in the world. It increase 2.5% cement demand in 2016 after the decrease in
demand in the previous year and it will be slow again due to industrial reorganization
this year While north America is the number one in cement consumption with the
projected growth of more than 7.4 million metric tons this year by CemNet because of
its expansion in the economic growth. The Portland Cement Association predicted that
U.S will increase it cement consumption by 3.1% this year. And lastly, the cement
production will increase about 4.4 billion metric tons in 2020 (Tutmez, 2013).
According to Civiltoday (n.d), cement has only 8 main ingredients and these are
60-65% of lime, 17–25% of silica (SiO2), 3-8% of alumina (Al2O3), 1-3% of magnesia
(MgO), 0.5-6% of iron oxide (Fe2O3), 0.1-0.5% of calcium sulfate (CaSO4), 1-3% sulfur
trioxide (SO3) and 0-1% of alkaline. Each raw materials have different roles or function
inside the cement. Lime is calcium oxide or calcium hydroxide and it helps form
aluminates and silicates of calcium, deficiency of lime weakens the strength of cement
and set quickly and if there is an excessive amount of lime, it makes the cement
unsound, expand and disintegrate and excessive amount of alkaline matter causes
is caused when soluble salts and other water dispersible materials come to the surface
of concrete and mortars (Nasvik, 2005). Sulfur helps in making the sound of cement
while Silica gives strength to cement through the formation dicalcium and tricalcium
silicates, it makes the cement stronger but the setting time is prolong if there is an
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cement because it acts as flux and it lowers the clinkering temperature however, higher
temperature might weaken the cement. Iron oxide and Magnesia gives the cement its
color and hardeness but only iron oxide provides some strength and Calcium Sulfate
helps to quicken the initial setting time of the cement (Biswas, 2013).
today’s generation. It can be used for building purposes such as houses, buildings
B. Testing
because it’s easy to perform and also the desired characteristics and properties of the
concrete are related to its compressive strength. The Compressive Strength of the
concrete is one of the most essential and useful property of concrete. In most structural
Concrete is the widely used material for construction all over the world. It is
produced from different components such as water, cement and other aggregates. For
testing the quality and to measure the performance, 28 day compressive strength test is
required for design and construction code requirements. The test is based on standard
the concrete in order to meet the required and specific strength and the ability to resist
CHAPTER III
METHODOLOGY
control over the factors in there control group and independent variable that may affect
the result of their experiment. The study was carried out with a particular varying
amount of Calcium Carbonate versus the control group which was 0%. In this
experimental research, the independent variable which was the amount of pulverized
mussel shells and the intervening variables, which were the water, gravel and sand,
were monitored.
The collected samples were taken from three different places in order to complete
the 18 kilograms of mussel shells needed by the researchers: Pasay City Public Market
is located at A. Arnaiz Ave. corner Taft Ave., Pasay City, NCR with geographical
coordinates of 14o 32’ 53” N, 120o 59’ 49” E; also in Pasay City are Dad and Mom’s
Family Restaurant, Aling Tonya’s, Kaymig Seafood Grill, and Huey Ying Restaurant in
Pasay City Public Market is operated by the city government and another owned by a
private enterprise. The Public Market is 13,378.47 square meter two-storey structure.
The market is divided into different markets such as the wet market, dry market and
special areas which are for carinderias, ice dealers, rice dealers and groceries. There
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are several stalls selling mussel shells in wet market where some of the vendors are
(Source: http://www.panoramio.com/m/photo/76297187)
probably the largest seafood place in Manila is the Seafood Paluto Restaurant which is
Boulevard in Pasay City, just a few meters away from Manila Bay and fishing ports
around the area. There is a wet market selling fresh sea foods where customers can
choose from and have it cooked on the other side where a row of restaurants are
located such as Dad and Mom’s Family Restaurant, Aling Tonya’s, Kaymig Seafood
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Commission, now Bureau of Fisheries and Aquatic Resources (BFAR). Not far from the
Sineguelasan, a small barangay of Bacoor known for their fish port, mussel and oyster.
The said province is the major producer of mussel shells making them known for
delicacies made out of this (shown in Figure 2). The 80% of the annual production of
mussel sells from four districts of the Province of Cavite is from the 2nd District, City of
Bacoor which has produced 12,569 metric tons of mussel shells. Followed by the 1st
District, Cavite City and Kawit which has produced 2,978.20 metric tons. The livelihood
mussels.
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(Source: http://exploringcavitebyjulz.blogspot.com/2015/04/tahong-at-talaba-mussels-
and-oyster.html?m=1)
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method and it occurs when elements selected for the sample are chosen by the
judgment of the researcher” (Research Methodology, n.d.). The researchers chose this
samples and observations of the resulting data. The researcher’s goals were to have a
rupture. In this study, the researchers used compressive strength machine in order to
determine the durability of concrete made from pulverized mussel shells from the
commercialized concrete. Compressive strength machine tested the maximum load and
stress of the three concrete cylinder samples per percentage set-up from 0%, 5% of
3.5 Procedures
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Series of meetings were held at the Bureau of Research and Standard Office in
Department of Public Works and Highways (DPWH) located in Kamuning, Quezon City
by the researchers and engineers of the said office last September 8 and September
20, 2017. For the approval of the request for cement making and testing of the made
samples would be possible at the said venue. After earning the permission of DPWH,
the researchers collected mussel shells from different places such as, in the different
stalls selling seafoods in Pasay City Public Market; Dad and Mom’s Family Restaurant,
Aling Tonya’s, Kaymig Seafood Grill, and Huey Ying Restaurant in Diosdado Macapagal
The gathered mussel shells were washed and air-dried. The materials used to
conduct the experiment were mortar and pestle and blender for pulverizing the mussel
shells, bistay for filtering to a fine powdered mussel shells, safety gloves, bowls, cylinder
molder, and compressive strength machine. The following procedure was followed and
performed by the researcher. First, the design mix was prepared. It is the ratio of each
component for the three set ups which are (0%) of CaCO3, (5%) of pulverized mussel
shells and (10%) of pulverized mussel shells. Secondly, components were measured
according to their assigned proportion or amount such as the sand or fine aggregates,
gravel or coarse aggregates, cement, pulverized mussel shells and water. Thirdly, each
material was placed in the mixing board and mixed thoroughly. Fourthly, the mixed
components were poured in the cylinder molder and each set-up was tamped 25 times
per layer. After 24 hours the specimens was removed from its molder and cured for 3
days. Lastly, the specimens were broken by the used of compressive strength machine.
The researchers undergo observation process to gain knowledge about the quality
promote values such as trust, good behaviour and fairness. The integrity, reliability and
the validity of research findings rely heavily on adherence to ethical principles. In this
study, the researchers also considered the following ethics such as:
gathering of data.
All statistical computation was done through the aid of Statistical Packages for
The mean of the compressive strength results will be computed per each samples
of concrete, which will be compared to the required strength that was set by the
Department of Public Works and Highways. This will be carried out to determine if the
this, minimum and maximum value of the strength of cement made from mussel shells
were identified.
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CHAPTER IV
This chapter presents the data gathered by the researchers in the experiment,
which includes the ratio or percentage of the cement, water, sand, gravel and pulverized
TABLE 1
ID ID ID
From Table 1, it is shown that there are 3 samples per set-up being subjected into
compressive strength machine for investigating the durability of concrete. And prior to
the table, the calculated mean results for each percentage of pulverized mussel shells
are less than the maximum load of the commercialized concrete which is 98.99 KN
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TABLE 2
Experimental
Deviation
Valid N 3
(listwise)
set-up is illustrated in Table 2. The computed mean and standard deviation for each
set-up is 12.21 MPa; 1.42 (0%), 7.47 MPa; 1.24 (5%) and 6.64; 1.65 MPa (10%).The
table shows that the maximum strength of pulverized mussel shells resulted into lesser
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TABLE 3
Texture
1
0% 2
3
1
5% 2
3
1
10% 2
3
It is highly noticeable that all the surface areas of the performed procedures of
concrete making, the resulted samples of the concrete made from pulverized mussel
shells had smooth surface areas in texture and white grayish in color as compare to
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CHAPTER V
This chapter brings together the results presented on the previous chapter and
includes the recommendations of the researchers and the sources of the researchers to
Summary
each day. The government is making ways to solve the problem regarding the proper
waste management and disposal, such as the program “segregation schemes” to sort
out the different materials that can be recycled and reuse to reduce the volume of
garbage produced. The researchers have thought of a way to help by using wastes
productively, like shells that takes a long time to decay. This study aims to investigate if
there is a difference between the commercial concrete and pulverized mussel shells
Conclusions
1. The researchers find out how effective is the pulverized mussel shells when it is
to the smoothness of the surface areas of the resulted samples has compared to
2. The researchers concluded that the computed mean for each percentage of
pulverized mussel shells from (0 %), (5%) and (10%) for the compressive strength
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3. And this coincides with the idea that the concrete made from pulverized mussel
shells when subjected to the maximum standard of curing days which is 28 days
Recommendation
Based on the findings and conclusions presented, this study puts forward the
following recommendations:
3.)The researchers recommend the use of type 1 cement for cement making as it has
fairly high Tricalcium Silicate C3S - content for good early strength development.
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LIST OF REFERENCES
5 Concrete Facts: Global Cement Production is on the Rise. (n.d.). Retrieved October
cement-production-is-on-the-rise/
8 Main Cement Ingredients & Their Functions. (n.d.). Retrieved October 12, 2017, from
https://civiltoday.com/civil-engineering-materials/cement/10-cement-ingradients-
with-functions
Abinaya, S., & Prasanna venkatesh, S. (2016). An Effect on Oyster Shell Powder’s
doi:10.15680/IJIRSET.2016.0506296
Akande, K. O., Owolabi, T. O., Twaha, S., & Olatunji, S. O. (2014). Performance
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Bacoor City- Marching Band Capital of the Philippines. (2015, September 08). Retrieved
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Barbachi, M., Imad, A., Jeffali, F., Boudjellal, K., & Bouabaz, M. (2017). Physical
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Barbachi.pdf.
Beraldo, A. (2014). Portland Cement Mortar Composite with Partial Sand Replacement
doi:10.4236/ojinm.2014.44007
Biswas, L. (2013, April 17). Cement Ingredients and Their Functions. Retrieved October
Brown, M. E., Kowalewski, M., Neves, R. J., Cherry, D. S., & Schreiber, M. E. (2015).
http://www.fishwild.vt.edu/mussel/PDFfiles/Freshwater_mussel_shells.pdf
Castillo, A. L., & Otoma, S. (2013). Status of Solid Waste Management in the
https://www.jstage.jst.go.jp/article/jsmcwm/24/0/24_677/_pdf.
Retrieved from
http://www.cavite.gov.ph/multimedia%20files/SEPP/2014/13%20SEPP2014_Chap
ter6_Economic.pdf
of-cement-opc/7561/
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https://www.irjet.net/archives/V4/i2/IRJET-V4I2392.pdf.
Hamester, M., Balzer, P., & Becker, D. (2012). Characterization of calcium carbonate
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Mendez, T., Hotza, D., & Repette, W. (2015). NANOPARTICLES IN CEMENT BASED
journals/RAMS/no_14015/06_14015_mendes.pdf
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http://www.panoramio.com/m/photo/76297187
http://www.ijset.net/journal/38.pdf
Naik, T. R., Canpolat, F., & Chun, Y. (2003). LIMESTONE POWDER USE IN CEMENT
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Plaehn, T. (n.d.). The Importance of Sand in Concrete | Hunker. Retrieved October 12,
Regina Rosa Hamester, Michele & Balzer, Palova & Becker, Daniela. (2012).
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http://basharesearch.com/IJASGE/1010202.pdf
Vamsi mohan, U., Nagendra Prasad, ,., & Praveen Kumar Reddy, S. (2015). Studies on
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Verma, Atul. (2015). Evaluation of sea sand and river sand properties and their
comparison. . 10.13140/RG.2.1.4906.6327.
Wanderer, O. A. (2017, August 05). Seaside Dampa Macapagal - Where to eat seafood
http://www.edpuno.com/2017/03/seaside-dampa-macapagal-eat-seafood-
manila.html
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APPENDIX A
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APPENDIX B
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APPENDIX C
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LAB RESULTS
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APPENDIX D
BUDGET
Laboratory
Materials
Transportation
Php 1200
Library Fee
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CURRICULUM VITAE
The researchers are Grade 12 students from Pasay City West High School. They
Academic Track.
ma.charlenehilvano@yahoo.com trias.raquel24@gmail.com
09489545401 09171503567
973- E.P. De Galvan St., Malate, Manila 2742 Park Avenue St., Pasay City
valerieevalena@gmail.com aguirreercolejames@gmail.com
09952324208 09955454805
510 Unit-G Inocencio St., Pasay City Blk 3 Lot 17 Don Carlos Village, Pasay City
jmld928@gmail.com
09158676851
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