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Table of Contents
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Table of Contents
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Table of Contents
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Section 1 General Information
1.1 Disclaimer
The information in this manual has been carefully checked and is believed to be accurate.
However, Hach Lange assumes no responsibility for any inaccuracies that may be contained in
this manual. In no event will Hach Lange be liable for direct, indirect, special, incidental, or
consequential damages resulting from any defect or omission in this manual, even if advised of
the possibility of such damages. In the interest of continued product development, Hach Lange
reserves the right to make improvements in this manual and the products it describes at any
time, without notice or obligation.
Copyright © 2009 by Hach Lange. All rights reserved. No part of the contents of this manual
may be reproduced or transmitted in any form or by any means without the written permission of
Hach Lange.
WARNING
A warning is used to indicate a condition which, if not met, could cause serious personal
injury and/or death. Do not move beyond a warning until all conditions have been met
CAUTION
A caution is used to indicate a condition which, if not met, could cause minor or
moderate personal injury and/or damage to the equipment. Do not move beyond a
caution until all conditions have been met.
Note: A note is used to indicate important information or instructions that should be considered
before operating the equipment.
WARNING
In accordance with safety standards, it must be possible to disconnect the power supply
of the analyzer in its immediate vicinity.
WARNING
The installation of the analyzer should be performed exclusively by personnel
specialized and authorized to work on electrical installations, in accordance with relevant
local regulations.
5
General Information
This symbol, when noted on a product enclosure or barrier, indicates that a risk of electrical
shock and/or electrocution exists and indicates that only individuals qualified to work with
hazardous voltages should open the enclosure or remove the barrier.
This symbol, when noted on the product, indicates that the marked item can be hot and should
not be touched without care.
This symbol, when noted on the product, indicates the presence of devices sensitive to
electrostatic discharge and indicates that care must be taken to prevent damage to them.
This symbol, when noted on the product, identifies a risk of chemical harm and indicates that
only individuals qualified and trained to work with chemicals should handle chemicals or perform
maintenance on chemical delivery systems associated with the equipment.
This symbol, if noted on the product, indicates the need for protective eye wear.
This symbol, when noted on the product, identifies the location of the connection for protective
earth (ground).
Electrical equipment marked with this symbol may not be disposed of in European public
disposal systems. In conformity with European local and national regulations, European
electrical equipment users must now return old or end-of-life equipment to the manufacturer for
disposal at no charge to the user.
Products marked with this symbol indicates that the product contains toxic or hazardous
substances or elements. The number inside the symbol indicates the environmental protection
use period in years.
6
General Information
ENGLISH
Electrical equipment marked with this symbol may not be disposed of in
European public disposal systems after 12 August 2005. In conformity with
European local and national regulations (EU Directive 2002/96/EC), European
electrical equipment users must now return old or end-of-life equipment to the
manufacturer for disposal at no charge to the user.
Note: For return for recycling, please contact the equipment
manufacturer or supplier for instructions on how to return end-of-life
equipment for proper disposal.
DEUTSCH
Elektrogeräte, die mit diesem Symbol gekennzeichnet sind, dürfen in Europa nach dem 12.
August 2005 nicht mehr über die öffentliche Abfallentsorgung entsorgt werden. In
Übereinstimmung mit lokalen und nationalen europäischen Bestimmungen (EU-Richtlinie
2002/96/EC), müssen Benutzer von Elektrogeräten in Europa ab diesem Zeitpunkt alte bzw. zu
verschrottende Geräte zur Entsorgung kostenfrei an den Hersteller zurückgeben.
Hinweis: Bitte wenden Sie sich an den Hersteller bzw. an den Händler, von dem Sie das Gerät
bezogen haben, um Informationen zur Rückgabe des Altgeräts zur ordnungsgemäßen
Entsorgung zu erhalten.
FRANCAIS
A partir du 12 août 2005, il est interdit de mettre au rebut le matériel électrique marqué de ce
symbole par les voies habituelles de déchetterie publique. Conformément à la réglementation
européenne (directive UE 2002/96/EC), les utilisateurs de matériel électrique en Europe doivent
désormais retourner le matériel usé ou périmé au fabricant pour élimination, sans frais pour
l'utilisateur.
Remarque: Veuillez vous adresser au fabricant ou au fournisseur du matériel pour les
instructions de retour du matériel usé ou périmé aux fins d'élimination conforme.
ITALIANO
Le apparecchiature elettriche con apposto questo simbolo non possono essere smaltite nelle
discariche pubbliche europee successivamente al 12 agosto 2005. In conformità alle normative
europee locali e nazionali (Direttiva UE 2002/96/EC), gli utilizzatori europei di apparecchiature
elettriche devono restituire al produttore le apparecchiature vecchie o a fine vita per lo
smaltimento senza alcun costo a carico dell’utilizzatore.
Nota: Per conoscere le modalità di restituzione delle apparecchiature a fine vita da riciclare,
contattare il produttore o il fornitore dell’apparecchiatura per un corretto smaltimento.
DANSK
Elektriske apparater, der er mærket med dette symbol, må ikke bortskaffes i europæiske offentlige
affaldssystemer efter den 12. august 2005. I henhold til europæiske lokale og nationale regler
(EU-direktiv 2002/96/EF) skal europæiske brugere af elektriske apparater nu returnere gamle eller
udtjente apparater til producenten med henblik på bortskaffelse uden omkostninger for brugeren.
Bemærk: I forbindelse med returnering til genbrug skal du kontakte producenten eller
leverandøren af apparatet for at få instruktioner om, hvordan udtjente apparater bortskaffes
korrekt.
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General Information
SVENSKA
Elektronikutrustning som är märkt med denna symbol kanske inte kan lämnas in på europeiska
offentliga sopstationer efter 2005-08-12. Enligt europeiska lokala och nationella föreskrifter
(EU-direktiv 2002/96/EC) måste användare av elektronikutrustning i Europa nu återlämna gammal
eller utrangerad utrustning till tillverkaren för kassering utan kostnad för användaren.
Obs! Om du ska återlämna utrustning för återvinning ska du kontakta tillverkaren av utrustningen
eller återförsäljaren för att få anvisningar om hur du återlämnar kasserad utrustning för att den ska
bortskaffas på rätt sätt.
ESPANOL
A partir del 12 de agosto de 2005, los equipos eléctricos que lleven este símbolo no deberán ser
desechados en los puntos limpios europeos. De conformidad con las normativas europeas
locales y nacionales (Directiva de la UE 2002/96/EC), a partir de esa fecha, los usuarios
europeos de equipos eléctricos deberán devolver los equipos usados u obsoletos al fabricante de
los mismos para su reciclado, sin coste alguno para el usuario.
Nota: Sírvase ponerse en contacto con el fabricante o proveedor de los equipos para solicitar
instrucciones sobre cómo devolver los equipos obsoletos para su correcto reciclado.
NEDERLANDS
Elektrische apparatuur die is voorzien van dit symbool mag na 12 augustus 2005 niet meer
worden afgevoerd naar Europese openbare afvalsystemen. Conform Europese lokale en
nationale wetgegeving (EU-richtlijn 2002/96/EC) dienen gebruikers van elektrische apparaten
voortaan hun oude of afgedankte apparatuur kosteloos voor recycling of vernietiging naar de
producent terug te brengen.
Nota: Als u apparatuur voor recycling terugbrengt, moet u contact opnemen met de producent of
leverancier voor instructies voor het terugbrengen van de afgedankte apparatuur voor een juiste
verwerking.
POLSKI
Sprzęt elektryczny oznaczony takim symbolem nie może być likwidowany w europejskich
systemach utylizacji po dniu 12 sierpnia 2005. Zgodnie z europejskimi, lokalnymi i państwowymi
przepisami prawa (Dyrektywa Unii Europejskiej 2002/96/EC), użytkownicy sprzętu elektrycznego
w Europie muszą obecie przekazywać Producentowi stary sprzęt lub sprzęt po okresie
użytkowania do bezpłatnej utylizacji.
Uwaga: Aby przekazać sprzęt do recyklingu, należy zwrócić się do producenta lub dostawcy
sprzętu w celu uzyskania instrukcji dotyczących procedur przekazywania do utylizacji sprzętu po
okresie użytkownia.
PORTUGUES
Qualquer equipamento eléctrico que ostente este símbolo não poderá ser eliminado através dos
sistemas públicos europeus de tratamento de resíduos sólidos a partir de 12 de Agosto de 2005.
De acordo com as normas locais e europeias (Directiva Europeia 2002/96/EC), os utilizadores
europeus de equipamentos eléctricos deverão agora devolver os seus equipamentos velhos ou
em fim de vida ao produtor para o respectivo tratamento sem quaisquer custos para o utilizador.
Nota: No que toca à devolução para reciclagem, por favor, contacte o produtor ou fornecedor do
equipamento para instruções de devolução de equipamento em fim de vida para a sua correcta
eliminação.
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General Information
Hach Lange is committed to ensuring that the risk of any environmental damage or pollution
caused by any of its products is minimized as far as possible. The European Waste Electrical
and Electronic Equipment (WEEE) Directive (2002/96/EC) that came into force on August 13
2005 aims to reduce the waste arising from electrical and electronic equipment; and improve the
environmental performance of all those involved in the life cycle of electrical and electronic
equipment.
In conformity with European local and national regulations (EU Directive 2002/96/EC stated
above), electrical equipment marked with the above symbol may not be disposed of in
European public disposal systems after 12 August 2005.
Hach Lange will offer to take back (free of charge to the customer) any old, unserviceable or
redundant analyzers and systems which carry the above symbol, and which were originally
supplied by Hach Lange. Hach Lange will then be responsible for the disposal of this
equipment.
In addition, Hach Lange will offer to take back (at cost to the customer) any old, unserviceable
or redundant analyzers and systems which do not carry the above symbol, but which were
originally supplied by Hach Lange. Hach Lange will then be responsible for the disposal of this
equipment.
Should you wish to arrange for the disposal of any piece of equipment originally supplied by
Hach Lange, please contact your supplier or our After Sales Service department in Geneva for
instructions on how to return this equipment for proper disposal.
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General Information
Transmitter box X
CPU PCB
O O
(with battery)
Power PCB O O
RS 485 O
Profibus O
PCB CAN O
PCB Measure O
PCB Pumps O
PCB Mixer O
PCB Channel O
O:
X:
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Section 2 Specifications
Sample
Number of channels 1-6
Measurement cycle < 10 min / channel
Sample pressure 0.2 to 6 bar (3 to 87 psi)
Temperature 5 - 50°C (41 - 122°F)
Minimum 5L / hour
Sample flow
Maximum 30L / hour
Connections
Simple fittings for 6 mm O.D. tubing or ¼" O.D. in PE-low density.
Sample input
¼" OD in PHED-PTFE-SS as option
Sample output Barbed stem for 12 mm (½" I.D.) hose
Conditions of use
Ambient temperature 5 to + 45°C (41 to 113°F)
Power supply voltage fluctuation ± 10%
Overvoltage category 2 (according to standard EN 61010-1)
Degree of pollution 2 (according to CEI 664)
Altitude ≤ 2000 m
Relative humidity 10 to 80%
Measurement category Cat II, Class 1 (overvoltage < 1500V)
Weight
Panel analyzer without canister 13 kg
Cabinet analyzer without canister 65 kg
Full canisters 8 kg
Standards
EMC EN 61326-1 (1997) & A1 (1998) & A2 (2001) & A3 (2004)
European safety standards IEC 61010-1 (2001) & EN 61010-1 (2001)
Certified to UL & CSA safety standards, with cETLus mark
UL & CSA agreement
(Control Number: 3164002)
Safety of Electrical Equipment for Measurement, Control and Laboratory use;
UL & CSA standards UL61010-1, Issued: 2004/07/12, Ed.2 Rev: 2005/07/22 and CAN/CSA C22.2
No. 61010-1, Issued: 2004/07/12
Analysis
Value measured Dissolved SiO2
Cycle time Approximately 10 minutes per channel
Measurement range (2 versions) 0 - 1000 ppb 0 - 5000 ppb
Repeatability ± 2% or ± 0.5 ppb ± 2% or ± 2 ppb
Detection limit 0.5 ppb 2 ppb
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Specifications
Inputs / Outputs
Number 8
Functions 6 threshold alarms / lack of sample / active channel
Alarms 1 system alarm
1 warning alarms
Cut-off power 30 VDC, 0.5 A maximum
Number 12
Logical inputs Remote alarm clearance
By-pass measurement for a channel
Serial input interface RS 485, Modbus communication protocol
Number 8
4/20 mA or 0/20 mA programmable
Outputs 4 / 20 mA
Galvanically insulated
Maximum charge of 800 ohms
Materials and protection
Transmitter Aluminium with polyester paint
Panels and other boxes Polystyrene
Protection transmitter box IP 65
Protection cabinet (optional) IP 54
Cabinet front door Plexiglas
Maintenance
Calibration Chemical zero, slope with calibration solution
No particular maintenance is necessary
Maintenance
Cleaning can be done with a soft non-aggressive cloth
Reagent consumption Approximately 1L per month and per reagent
Calibration solution consumption Approximately 200 ml / calibration
Time safeguard lithium battery CR 1220 (3 V)
Transmitter
Programming by menu
Concentration of 6 samples
Analyzer status
Display Alarms
Trend curves
Concentration historic
Calibration parameters historic (date, slope and offset)
Mains power supply
100 - 240 VAC 50 - 60 Hz
Mains Automatic switching
Max. consumption: 80 VA
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Section 3 Analyzer Overview
3.1 Operation
The 9210 can analyze up to six different samples. The sample to be analyzed circulates in a
fast loop permitting rapid renewal of the sample. Adjustment of the flow is carried out with the
help of a needle valve (2). At the beginning of the analysis, the sample is introduced into the
measuring cell (4) with the use of a solenoid valve (5).
The reagents R1M and R1A are first added using two of the reagent pumps (9). The silica
contained in the sample then reacts with the molybdate and forms the silicomolybdic complex.
The reaction will take up to 5 minutes.
Oxalic acid is then added using a reagent pump (9) to avoid phosphate interference and to
intensify the color.
The silicomolybdic complex is reduced to a blue molybdenum complex by means of ferrous
ions. A photometric measurement is carried out at the end of the reaction.
13
Analyzer Overview
3.2 Calibration
In order to ensure accurate measurements, the analyzer should be calibrated periodically. The
zero is achieved chemically and internally in the analyzer. The system slope is controlled by
comparison to a standard solution of known concentration. Further information regarding
calibrations can be found in the section entitled Calibration on page 51.
3.4 Maintenance
To ensure a high degree of accuracy is maintained by the analyzer, it is recommended to
perform a specific maintenance procedure once a year. All replacement parts and fittings are
available by purchasing the maintenance kit 09120=A=8000 which contains enough parts and
fittings for two years.
Full details on this procedure and the contents of the maintenance kit can be found in Yearly
maintenance on page 60.
14
Analyzer Overview
3.5 Presentation
3.5.1 Front panel
15
Analyzer Overview
16
Section 4 Installation
WARNING
The analyzer should only be assembled by qualified staff. Mains power should only be
connected once installation has been completed and checked.
17
Installation
A. Mains power supply cable gland, drilled ∅ 11 (5 to 10mm), 100…240V, 50-60Hz, 25VA
B. Field bus cable gland, drilled ∅ 13 (6 to 12mm)
C. 5 to 7 mm cable gland
• Alarm signals: 30V, 0.5A max.
• Logic inputs: Cutoff on channels 1 to 6, acknowledgement of alarm signals
• Analog outputs: 0-20 mA or 4-20 mA
D. Sample inlets, (channels 1 to 6), QR coupling for semi-rigid tubing ∅ 6mm, 5 to 50°C
(40° to 120°F), P 0.2 to 6 bar (3 to 87 PSI)
E. Drain tube: silicon tubing ∅ 12 x 17mm, at atmospheric pressure
18
Installation
19
Installation
Ensure the position of the canister holder does not exceed the maximum and minimum
distances from the bottom of the analyzer that are given in Figure 6 above.
20
Installation
At this stage of the installation, make sure that the flow valves (2) are all closed.
Connect the tubes by inserting into the quick release connections found under the sampling
block as illustrated in Figure 8 below.
21
Installation
The electrical installation should be carried out by duly qualified personnel. A supply voltage of
100-240 VAC is acceptable without changing the configuration. The power supply terminals can
be removed from their housing to make connection easier.
For safety reasons, it is imperative to respect the following:
• Use a three-wire power lead (live + neutral + earth) for supplying the required power.
• The analyzer should be connected to the mains via a circuit-breaker or fuse whose value
should be less or equal to 20 A. It should be located in the proximity and be identified.
This connection should cut-off the live and neutral when electrical problems occur or
when the user wishes to intervene inside the analyzer. However, the earth conductor
should always be connected.
22
Installation
The following procedure outlines the steps required to connect power to the analyzer. The main
cabinet should be open with access to the interior:
23
Installation
24
Installation
25
Installation
CPU board with JBUS/MODBUS option - - - - - CPU board with PROFIBUS option
26
Installation
This will reveal the I/O board as illustrated in Figure 10 (which shows connections already in
place).
27
Installation
Before using any of the cable glands, perforate first with a screwdriver. To ensure a good seal,
the external diameter of the cables should be between 5 and 7 mm.
For information on the connections available refer to Table 1.
CAUTION
The relay outputs can only supply power in very low safety voltage (30 VAC or 42.4 VDC
maximum) and limited to 0.5 A.
The nomenclature given in the connections column of Table 1 below, refers to the same
nomenclature that is printed on the I/O board against each available connection.
Note: Dry relays are used for all the following logical inputs. At best, provide 1 dry circuit (no voltage)
which will be closed to launch an action.
By-pass sample measurement (channels 1 - 6)
In1 to In6 For input In1, use terminals " in " and " - "
Terminals " + " and " out " are not used
5 VDC 5 mA
In7 to In10 Not used
In11 Remote acknowledgment of alarms
In12 Level sample detector
When all I/O connections have been made, put the cover back on the local controller box and
secure in place with the 4 screws.
28
Installation
WARNING
Read the Material Safety Data Sheets (MSDS) on page 77 and wear protective goggles
and clothes before using chemical products.
• Rinse a 2 liter volumetric flask three times with ultra pure water
• Fill two-thirds of the flask with ultra pure water which has less than 5 ppb of SiO2
• Stirring continuously for about 5 minutes, gently dissolve 110g of the sodium dihydrate
molybdate in the water. The turbidity of the solution should be very low
• Top up the solution to 2 liters with additional ultra pure water, and transfer the solution to
the canister labelled R1M
• Rinse a 2 liter volumetric flask three times with ultra pure water
• Fill two-thirds of the flask with ultra pure water which has less than 5 ppb of SiO2
• Stirring continuously for about 5 minutes, gently pour 300mL of nitric acid into the water.
The solution should be clear
• Top up the solution to 2 liters with additional ultra pure water, and transfer the solution to
the canister labelled R1A
• Rinse a 2 liter volumetric flask three times with ultra pure water
• Fill two-thirds of the flask with ultra pure water which has less than 5 ppb of SiO2
• Stirring continuously for about 5 minutes, gently dissolve 80g of oxalic acid in the water
• Top up the solution to 2 liters with additional ultra pure water, and transfer the solution to
the canister labelled R2
29
Installation
• Rinse a 2 liter volumetric flask three times with ultra pure water
• Fill two-thirds of the flask with ultra pure water which has less than 5 ppb of SiO2
• Stirring continuously, gently pour 25mL of sulfuric acid into the water
• Stirring continuously, gently add 40g of ammonium-iron(II) sulfate hexahydrate to the
solution
• Top up the solution to 2 liters with additional ultra pure water, and transfer the solution to
the canister labelled R3
Given that the demineralized water may often have a non-zero silica content, use of one two
methods for determining the nominal silica values of the final calibration solution. On
completion, transfer 2 liters of the solution to the calibration canister labelled CAL.
Note: It is recommended to use demineralized water with a silica content of no more than 5 ppb when
diluting the concentrated solution.
Method 1:
Determine the silica content of the demineralized water by using a laboratory measurement
technique (e.g. Hach Lange laboratory photometer), or by using the grab sample mode of an
accurately calibrated POLYMETRON 9210 if available on site. The concentration value can then
be added to the values in the above table, giving the following revised table when (for example)
using demineralized water with a silica content of 5 ppb (which equates to 2.33 ppb Si):
30
Installation
Method 2:
Prepare the final calibration solution by diluting the concentrated solution (at 21.39 mg/liters)
with demineralized water. Then determine the exact silica concentration value of this solution by
using a laboratory measurement technique (e.g. Hach Lange laboratory photometer) or by using
the grab sample mode of an accurately calibrated POLYMETRON 9210 if available on site.
Screw the cap on each canister so that the weight is resting at the bottom of the canister. Put
the canister in the canister holder with the cap towards the exterior as shown in Figure 11
below.
The canister on the far right of the illustration is the calibration solution. This has a thicker tube
compared to the reagents. Ensure that the cap has also been securely screwed on to this
canister.
At this stage, the analyzer doors can now be closed and locked as access to the interior of the
analyzer is no longer required.
31
Installation
32
Section 5 Operating Instructions
• The Esc key cancels data input or goes back to the previous screen.
• The Enter key validates the input and goes on to the next step.
• The Up Arrow keys select the option displayed immediately above them on the screen.
Note: If you do not use the keyboard for at least 10 minutes, the analyzer returns to the measure mode
except during the calibration and maintenance options. An access code may be required for the calibration,
programming and service menus (see Code on page 38).
33
Operating Instructions
34
Operating Instructions
In the illustration above, the symbol “.../...” is displayed in the bottom right. This indicates that
there are more options available in this menu than those currently displayed. As you scroll down
the other menu options will become visible in a rolling menu.
The first option in the menu will always be highlighted by default. To scroll to the required option,
press the Up Arrow function key under the Select option.
Note: Scrolling past the last item in the list will take you back to the first item. It is not possible to scroll
upwards through any list.
Detailed information on all the menu options is available throughout in this manual.
35
Operating Instructions
36
Section 6 System Setup
Before attempting to setup the analyzer, ensure you have read and understood how to enter
and change data fields as described in the section entitled Data Entry on page 33.
6.1.1 Time
37
System Setup
6.1.2 Display
6.1.2.1 Customize
6.1.3 Code
38
System Setup
This option allows you to reload all the factory set default
values (see Default Configuration on page 73 for a complete
listing).
6.1.6 mA adjustments
Use the " - " and " + " keys to make minor adjustments to the
values on the 4 mA outputs.
Validate (press Enter) will move you to the 20 mA outputs
screen.
Adjust the 20 mA value in the same way and then press Enter
to complete the adjustment process and return to the screen
to select the next output to adjust.
39
System Setup
6.1.7 Factory
40
Section 7 User Setup
Before attempting to setup the analyzer, ensure you have read and understood how to enter
and change data fields as described in the section entitled Data Entry on page 33.
The user setup process consists of accessing five sub-menus from the main menu:
• MEASURE
• ALARMS
• mA OUTPUTS
• RS485
• SEQUENCE
41
User Setup
7.1.3 Historic
42
User Setup
The READ option lets you view the data as defined by the
parameters set in the programming option.
Use the key to scroll through the list of stored data
which displays the date and time of the measurement, the
channel number, and the measured concentration value.
This option displays the parameters for the primary and last
calibrations, and the last measurement.
The information given can be used for diagnostic purposes if
the analyzer appears to be giving incorrect measurements.
43
User Setup
7.2.1 Alarms 1 to 6
Value Description
LIMIT XXXX Define the concentration limit when the alarm is triggered
DIRECTION Up Trigger the alarm when the measurement is above the limit
Down Trigger the alarm when the measurement is below the limit
HYSTERESIS nn% Hysteresis percentage
If MODE = Limit
• Define the channel for which alarm 2 will be triggered
• Define the limit value.
• Define if the alarm is triggered when concentration goes
above (Up) or below (Down) the limit.
• Set the hysteresis percentage.
• Define the relay type (normally open or normally closed)
44
User Setup
Value Description
ACCEPT When the alarm is triggered, it can only be turned off by pressing
Manual
the Enter function key
When the alarm is triggered, it will turn itself off when the reason
Auto
for the alarm is no longer valid
RELAY N.O. Normally open
N.C. Normally closed
Value Description
Note: The system alarm can only be acknowledged manually, either by holding down the Enter key or,
remotely, by using the digital input, In11 on the I/O card (see Figure 10 on page 27).
45
User Setup
• Warning: the analyzer displays a warning on the screen and locks the warning relay.
• System: the analyzer locks the system alarm relay, displays a message and stops.
46
User Setup
7.3.1 Affect
Select the AFFECT option and then each output (1-6) in turn.
Description
AFFECT Define the measurement channel (1-6). The measurement on this channel will be
carried over the selected analog output
TYPE Define the analog output scale (0-20 or 4-20 mA)
MIDDLE Value corresponding to the mid-point of the scale (only available in dual mode)
47
User Setup
The following graph indicates the result of the 4-20 current in relation to the type, and the first,
middle and end value of the scale.
This option lets you program the status of analog output 7 for
the following special events:
• Maintenance
• Calibration
• Grab sample analysis
• System alarm
• Warning alarm
Use the Select function to choose the event for which analog
output 7 is to be assigned.
Note: In the case of a system alarm, all the analog outputs (1 to 7) are set to the preset value defined in the
SYSTEM ALARM option.
48
User Setup
7.3.3 Test
7.4 RS485
Description
BAUD Transmission speed in bauds (300, 600 1200, 2400, 4800, 9600)
STOP BIT 1 or 2
SWAP WORD Lets you reverse the send order of the data
49
User Setup
7.5 Sequence
7.5.2 Sequence
50
Section 8 Calibration
Before attempting to setup the analyzer, ensure you have read and understood how to enter
and change data fields as described in the section entitled Data Entry on page 33.
For continued accurate measurements, the analyzer should be calibrated on a regular basis.
Calibrations allow the adjustment of:
• ZERO of the system
• SLOPE of the system
• Both ZERO and SLOPE of the system
The ZERO calibration is performed chemically by the analyzer. In order to avoid the use of
water free of SiO2, the analyzer carries out a measurement without a colorimetric reaction. The
slope of the system is then calibrated with a standard solution of known concentration of SiO2.
Three types of calibration are available:
• Primary
• Manual
• Automatic
In addition, the CALIBRATION menu also gives access to the current calibration parameters
and a history of previous calibration results.
51
Calibration
Sample minimum
Recommended frequency
concentration
< 5 ppb 24 hours
5 < x < 50 ppb 48 hours
> 50 ppb > 72 hours
52
Calibration
A primary calibration is carried out at the factory and is used as a reference for all following
calibrations.
In general, this type of calibration does not need to be repeated unless important changes
have been made to the analyzer.
Important Note: If you feel that a primary calibration is required, please discuss this with your
Hach Lange representative for advice and assistance before performing this type of calibration
on your analyzer.
The primary calibration sets the slope and zero references. All results of further manual or
automatic calibrations will be compared to the zero and slope references set by this
calibration. Large differences will signify an error in the calibration and will be highlighted with
an error message.
The calibration of the slope is defined first, followed by the zero.
Press Esc to abort the calibration and return to the CALIBRATION menu.
The calibration is made in the following stages:
• Sample preparation
• Conditioning
• Measurement
• Rinse
53
Calibration
8.1.4 Parameters
8.1.5 Historic
54
Calibration
Zone ok
Normal variations compared to the reference values. The new parameters are acceptable.
In automatic mode, the analyzer returns to its measurement cycle. In manual mode, validate
with OK and restart the analyzer (Start function key).
S: XXXXX DD:MM:YY - Slope
O: XXXXX DD:MM:YY - Offset
C: XXXXX DD:MM:YY - Concentration of the sample solution just measured, calculated using
the calibration values from the Last calibration.
Confirmation zone
Abnormal variations compared to the reference values. The new parameters can be accepted
but a warning is displayed and confirmation is required.
In automatic mode, the analyzer does not take the new parameters, but returns to
measurement mode with the previous parameters. In manual mode, you must confirm (Conf)
or cancel (Cancel) to accept or reject the new parameters.
Note: In automatic mode, where the calibration lies within the confirmation zone, the analyzer takes one
measurement and then recalibrates. After 3 successive invalid calibrations, the analyzer waits for the next
programmed date before attempting another calibration.
Rejection zone
Parameters are abnormal. There is a basic problem such as an invalid calibration solution
preparation being used.
In automatic mode, the analyzer stops and triggers a system alarm. In manual mode, you can
Cancel (return to measurement mode with the previous parameters) or Restart the
calibration.
55
Calibration
56
Section 9 Maintenance
9.1 General
Periodic maintenance will ensure accurate and consistent analysis results. Verify the level of the
calibration and reagent solutions on a regular basis and refill if necessary.
57
Maintenance
58
Maintenance
WARNING
There is a risk of explosion if the replacement battery does not correspond to the correct
model as indicated above. Do not throw away used batteries, but send them to a local
recycling center.
Replacement fuses are supplied with the analyzer and these must be used to replace faulty or
blown fuses. If for any reason these replacements are not available, only the following
alternatives should be used:
• JDYX2, LITEFUSE, type 213, rated 2 AT, 250 VAC
• JDYX2, SIBA, Type 179120, rated 2 AT, 250 VAC
• JDYX2, SCHURTER, Type FST, rated 2 AT, 250 VAC
If there is any difficulty in obtaining these replacement fuses, please contact your local Hach
Lange representative for advice and assistance.
59
Maintenance
1. Ensure that adequate warning has been given to all personnel that are involved in any
way with the analyzer, that maintenance will be carried out on a pre-defined date/time.
2. Shut down the analyzer as follows:
a. Stop the analyzer measuring process by pressing the Stop function key
b. Press the Menu function key and select the MAINTENANCE option
c. Select the EXTENDED STOP option
d. Fill a beaker with 250 mL of demineralized water
e. Open the analyzer to gain access to the reagent and calibration solution canisters
f. Unscrew the caps on the 4 reagent canisters, remove the tube guides from the
canisters and place them in the beaker of demineralized water
g. Unscrew the cap on the calibration solution canister, remove the tube guide from
the canister and place it in a second (empty) beaker. Do not put it in the beaker of
demineralized water containing the reagent tube guides
h. Press OK to start the rinsing process
i. On completion press Esc to exit the process. The measuring cell and reagent
tubes will now be rinsed and empty
j. Disconnect the analyzer from the power source
3. With the analyzer still open, remove the 4 screws holding the pump box cover in place
(item no. 8 in Figure 3 on page 16) and set to one side.
Note: The pump connections are described on the pump box cover. Each pump has an inlet tubing
(from the canister to the pump) and an outlet tubing (from the pump to the measuring cell). The
outlet tubing is also referred to as the injector.
4. Prepare 4 of the injectors (part no. 09210=A=4362 from the maintenance kit). The
process is slightly different depending on the analyzer model in use (sulfuric acid or nitric
acid chemistry).
9120 analyzer with sulfuric acid chemistry:
a. The injector is supplied with the ferrule and fitting nut attached. These are not
required, so cut the tubing immediately after the ferule (90° angle) and discard the
ferrule and nut. Do this on all 4 injectors
9120 analyzer with nitric acid chemistry:
a. No action is required and the tubing injectors should be used as supplied in the
maintenance kit
60
Maintenance
5. Prepare the inlet tubing (part no. 590=050=060 from the maintenance kit). Again, the
process is slightly different depending on the analyzer model in use (sulfuric acid or nitric
acid chemistry).
9120 analyzer with sulfuric acid chemistry:
a. Cut 4 lengths of tubing of 90 cm each and proceed to the step 6
9120 analyzer with nitric acid chemistry:
a. Using a scalpel, cut one end of the tubing to form a point approximately 30mm
long, to enable the tube to be passed through the ferrule:
WARNING
Always take care when using scalpels. Always make tube cuts away from the body
and keep fingers away from the blade.
b. Slide the fitting nut onto the tube. Slide the ferrule over the pointed end and onto
the tube as far as possible without forcing it, and ensuring the PTFE seal is facing
towards the pointed end of the tube:
c. With the aid of long-nosed pliers or similar, pull the pointed tube end through the
ferrule until the PTFE sealing surface has reached the uncut section of the tube.
Keeping the ferrule as perpendicular as possible to the tube will ensure the best
results. Rotate the ferrule around the tube 3 or 4 times to seat the ferrule on the
tube correctly:
d. Using a scalpel, cut the pointed tube end as close to the ferrule as possible,
ensuring the end of the ferrule is not cut:
61
Maintenance
Apply the following procedure for one reagent, then repeat for each reagent in turn. For
easier access, start with the reagent pump on the far left (closest to the calibration
pump).
a. Locate the inlet port (nearest to you) and outlet port (farthest from you) of the
pump. Be aware that there is an additional port on each pump between the inlet
and outlet ports but which is not to be used. Disconnect the inlet tubing and the
injector tubing from the pump. Pull the injector tubing out of its position in the
photometric cell (item no. 5 in Figure 2 on page 15) and discard it
b. Mount the newly prepared injector on the outlet port of the pump and screw in
place. Slide the other end of the tubing through the panel cut-out at the front but
do not yet connect to the photometric cell
c. Mount the newly prepared inlet tubing on the inlet port of the pump and screw in
place
d. Retrieve the old inlet tubing and the tube guide from the beaker of water
e. Unscrew the plastic fitting from the weight (position 1 in the illustration below) and
put the weight to one side on a clean tissue
f. Once the weight is removed, pull all the old reagent tubing out of the tube guide
and discard
g. Slide the newly prepared reagent tubing through tube guide
h. Place a new fitting (part no. 589=010=015 from the maintenance kit) on the end of
the tubing and screw into the weight
i. Take the same sticker as the original one (part no. 625=065=025 from the
maintenance kit) and place it around the reagent tube approximately 10cm from
the tube guide
j. Place the tube guide assembly back in its canister and screw down securely
k. Repeat these steps for the next reagent pump until all four have been completed
7. Change the magnetic stirrer in the photometer cell by first removing the 4 screws from
the photometric cell cover. Put the screws to one side. Lift off the cap and then remove
the old magnetic stirrer in the bottom of the cell.
Take a new stirrer (226=003=013 from the maintenance kit) and place in position at the
bottom of the cell.
Replace the photometric cell cover and secure with the 4 screws.
8. Place the ends of the injectors into the top of the photometric cell as far as they will go
without forcing them.
62
Maintenance
9. Re-connect power to the analyzer. Once the measurement screen is displayed, select
the Menu option and then MAINTENANCE. Then select the REAGENTS REFILL option
and then the TUBES PRIMING option. This will purge and refill the new calibration and
reagent tubing, and will take about 20 minutes to complete.
At the end of the process press Esc to return to the menu at which stage the new
reagent tubes should be full of reagent.
10. Return to the measurement screen and press the Start function key to begin
measurements. Leave the analyzer to run for a period of two hours after which the
measurements will have stabilized.
11. Once stable, press the Stop function key to stop measurements. Then select the Menu
option and then CALIBRATION. Perform a manual ZERO+SLOPE calibration.
After a successful calibration the analyzer is ready to resume measurements. Return to
the measurement screen and press the Start function key.
63
Maintenance
9.7 Startup
This option is used after the analyzer has not been used for
an extended period of time, or when starting the analyzer for
the very first time.
Using a screwdriver, set the flow rate for the first sample using
the adjustment screws on the front panel (item 4 in Figure 2
on page 15). Regulate the flow (between 5 and 30 L/hour) to
ensure a slight overflow into the overflow vessel.
Note: Do not completely unscrew the adjustment screw as it has no
stop and may provoke a sample leak.
The analyzer monitors the reagent and calibration solution consumption. Messages are
displayed when the solution levels are low.
64
Maintenance
65
Maintenance
66
Maintenance
9.15 Relays
67
Maintenance
1. Place the tube in the cutter with the cutting wheel on the mark.
2. Tighten the tool a quarter of a turn.
3. Rotate the tool around the tube and check a small groove has been cut all round the tube.
4. Remove the tube from the cutter.
68
Section 10 Troubleshooting
69
Troubleshooting
70
Section 11 Spare Parts
Accessories
09125=A=1485 Kit for Profibus DP with board for 91xx / 92xx and Operator Manual
09125=A=2485 Optional RS485 JBUS/MODBUS for transmitters model 91XX after February 2004 (CPU-ph2) or 92XX
after June 2006 (CPU-ph2): board + instruction manual (5 languages)
09210=A=8000 2 years spare part kit 921X (all ranges). Includes items and quantities below
8 x 589=010=015 Fitting for 1.5mm I.D tubing - 10/32 UNF thread
8 x 590=050=060 Polyethylene tubing 1.6 x 3.2mm (per meter)
8 x 625=065=025 Printed stickers for tubing identification
1 x 09210=A=8050 Kit of (8) ferrules, (8) nuts
8 x 09210=A=4362 Injectors
2 x 226=003=013 Teflon coated magnetic stirrer (for 921X analyzers)
0.5 x 151400,22387 PE tubing 6 x 8mm (per meter)
1.0 x 151575,00006 PE tubing 4 x 6mm (per meter)
09210=A=8012 9210-ph2 Analyzer tech spare part kit. Includes items and quantities below:
1 x 09210=A=0250 Sample level sensor for 921X
1 x 09210=C=7010 9210 set of dry chemicals for 50 days operation
1 x 09210=A=8072 Kit of 5 empty canisters w/caps & stickers for 9210-ph2 silica
1 x 689=118=008 Sampling solenoid valve, NPS 0.8 (0.2 - 6 bars)
1 x 689=118=024 Sampling electrovalve (overflow vessel)
1 x 695=004=004 Calibration / flush pump
1 x 09210=A=8040 micro-dosing diaphragm self-priming pump
09210=A=8072 Kit of 5 canisters w/caps & stickers for 9210-ph2 silica (for dry chemicals see 09210=C=7010)
09210=C=7010 9210 set of dry chemicals for 50 days operation (applicable for all 9210 generation)
G-MC-9210 GOLD-Contract, Maintenance & Calibration, Analyzer Silica (SiO2), 9210
P-MC-9210 PLATINUM-Contract, Maintenance & Calibration, Analyzer Silica (SiO2), 9210
S-MC-9210 SILVER-Contract, Maintenance & Calibration, Analyzer Silica (SiO2), 9210
MC-9210 Maintenance & Calibration, Silica (SiO2) analyzer, 9095/9097/9210
Spare parts in contact with sample
09210=A=0100 0.5 - 6 bars adaptation kit for 6 solenoid sample valves
09210=A=0105 Sampling flow-rate adjustment screw (w/ its O-ring)
09210=A=0110 Metric to imperial conversion assembly (for one channel) from connector 6 mm O.D. to 1/4'' O.D. acetal
09210=A=0111 921X sample valve kit (uneven to even number)
09210=A=0121 Complete 1 channel block for 921X
09210=A=0122 Complete 2 channels block for 921X
09210=A=0143 Complete 3 channels block for 921X
09210=A=0144 Complete 4 channels block for 921X
09210=A=0165 Complete 5 channels block for 921X
09210=A=0166 Complete 6 channels block for 921X
09210=A=0250 Sample level sensor for 921X
356099,05040 Viton O-ring 4 x 1 mm of the sampling flow-rate adjustment screw.
356099,35380 Viton O-ring 38 x 2 mm (around level detector)
359110,52012 Tubing silicone 12 x 17 mm (per meter) - from 8810 vessel or 921x, 924x column to drain -
689=118=008 Solenoid valve (24CC, 2/2way) as per 9210&9211 sample blocks [NPS 0.8 (0.2 - 6 bars)]. Delivered with
one connector P/N 350=005=377. For mounting, see special torx screw driver at P/N 820=000=006
689=118=016 Solenoid valve (24CC, 2/2way, NPS 1.6 (0.2 - 2 bars)). Delivered with one connector P/N 350=005=377.
For mounting, see special torx screw driver at P/N 820=000=006
689=118=024 Solenoid valve (24CC, 2/2way) as per 9210&9211 overflow vessel (AKA transfer valve). For connector,
see P/N 350=005=377. For mounting, see special torx screw driver at P/N 820=000=006
Spare parts in contact with cell or electrodes
09097=C=0560 Heating element
09210=A=0300 Complete photometer cell for 921X
09210=A=0400 Complete mixer for 921X analyzers
09210=A=0500 Hollow fiber for 921X
71
Spare Parts
72
Section 12 Default Configuration
User configuration
CALIBRATION / PROGRAMMING
Offset interval 24 hours 1 - 999 hours
Cal. sol 214 ppb ppb / ppm
Auto. cal No Yes / No
Base Day Day / Hour
Week SMTWTFS SMTWTFS
Hour 15:00:00 24 Hour clock
MAINTENANCE / REAGENTS REFILL / ADJUST VOLUMES
Reagent 1 2.00 L 0-5L
Reagent 2 2.00 L 0-5L
Reagent 3 2.00 L 0-5L
Calibration solution 2.00 L 0-5L
MEASURE / MEASURING MODE
Cycle In loop Interval / In loop
Interval 15 mins 1 - 999 mins
ALARMS / ALARM 1
Limit
Mode Limit Active channel
Level sample
Affect Channel 1 Channel 1-6
Limit 1000 ppb
Direction Up Up / Down
Hysteresis 0% 0 - 10%
Relay N.O. N.O. / N.C.
ALARMS / ALARM 2
Limit
Mode Limit Active channel
Level sample
Affect Channel 2 Channel 1-6
Limit 1000 ppb
Direction Up Up / Down
Hysteresis 0% 0 - 10%
Relay N.O. N.O. / N.C.
ALARMS / ALARM 3
Limit
Mode Limit Active channel
Level sample
Affect Channel 3 Channel 1-6
Limit 1000 ppb
Direction Up Up / Down
Hysteresis 0% 0 - 10%
Relay N.O. N.O. / N.C.
73
Default Configuration
User configuration
ALARMS / ALARM 4
Limit
Mode Limit Active channel
Level sample
Affect Channel 4 Channel 1-6
Limit 1000 ppb
Direction Up Up / Down
Hysteresis 0% 0 - 10%
Relay N.O. N.O. / N.C.
ALARMS / ALARM 5
Limit
Mode Limit Active channel
Level sample
Affect Channel 5 Channel 1-6
Limit 1000 ppb
Direction Up Up / Down
Hysteresis 0% 0 - 10%
Relay N.O. N.O. / N.C.
ALARMS / ALARM 6
Limit
Mode Limit Active channel
Level sample
Affect Channel 6 Channel 1-6
Limit 1000 ppb
Direction Up Up / Down
Hysteresis 0% 0 - 10%
Relay N.O. N.O. / N.C.
ALARMS / WARNING ALARM
Alarm Yes Yes / No
Accept Manual Manual / Auto.
Relay N.O. N.O. / N.C.
ALARMS / SYSTEM ALARM
Alarm Yes Yes / No
Relay N.O. N.O. / N.C.
mA OUTPUTS / AFFECT / OUTPUT 1
Affect Channel 1 Channel 1 - 6
Type 0-20 mA 0/20 mA / 4/20 mA
Mode Linear Linear / dual
Low 0 ppb
Middle 100 ppb
Up 1000 ppb
74
Default Configuration
User configuration
75
Default Configuration
User configuration
76
Section 13 Material Safety Data Sheets (MSDS)
Name:
OXALIC ACID 1. dihydrate Formula: 1. (COOH)2. 2H2O
2. anhydrous Formula: 2. (COOH)2.
CAS N°144-62-7
PHYSICAL PROPERTIES
MELTING POINT 1. 101°C
2. 190 °C
SOLUBILITY IN WATER About 14%
FIRE AND EXPLOSION HAZARD Decomposition products include carbon monoxide (highly flammable and toxic) and
carbon dioxide.
HEALTH HAZARD Classification of risk - Harmful
Harmful in contact with skin
Harmful if swallowed
Harmful if inhaled
Minimum lethal dose (LD50) = 275 mg/Kg
SAFETY PRECAUTIONS
EYES Wash thoroughly with water; obtain medical attention
LUNGS Remove from exposure, rest and keep warm; obtain medical attention
INGESTION Wash out thoroughly with water; give plenty of water to drink; obtain medical
attention
CHEMICAL HAZARDS AND STABILITY
STABILITY Stable
SPECIAL HAZARDS Mixtures with sodium chlorite can explode with the addition of water.
WASTE DISPOSAL Dissolve or mix the material with a combustible solvent and burn in a chemical
incinerator equipped with an after burner and scrubber. Dispose in a safe manner
consistent with Local Authority chemical waste regulations. For guidelines on
disposal consult the requirements of the Control of Pollution Act (1974) and the
Control of Pollution (Special Wastes) Regulations (1980 S1 1709).
PROTECTIVE MEASURES
RESPIRATOR Dust mask or positive pressure hood - if handling large quantities.
GLOVES Rubber or plastic
EYE PROTECTION Goggles
SPILLAGE HANDLING
SMALL SPILLAGE Mop up with plenty of water and run to waste, diluting with running water.
LARGE SPILLAGE Transfer to salvage canister and treat residue as for small spillage.
The information on this sheet is believed to be correct at the time of printing. The details should be reviewed periodically and
should be checked for special uses.
77
Material Safety Data Sheets (MSDS)
Name:
SULPHURIC ACID Formula: H2 SO4
Hazard class: 8 UN N°: 1830
CAS N° 7664-93-9
PHYSICAL PROPERTIES
MELTING POINT 10 °C
BOILING POINT 330°C
SPECIFIC GRAVITY 1,8
MISCIBLE WITH WATER
FIRE AND EXPLOSION HAZARD May evolve toxic fumes in a fire.
HEALTH HAZARD Classification of risk - Corrosive.
Causes severe burns to eyes and skin.
If ingested causes severe internal irritation and damage.
Dilute acid irritates the eyes and skin and can cause burns and dermatitis.
Minimum lethal dose, D50 = 2140 mg/Kg, via oral route.
Occupational exposure standard, long term exposure limit (8 hours TWA) mg-3
Keep out of reach of children.
SAFETY PRECAUTIONS-FIRST AID
EYES Wash immediately and thoroughly with plenty of water for at least 10 minutes.
Obtain medical attention.
LUNGS Remove from exposure, rest and keep warm, or if exposure has been great, obtain
medical attention.
MOUTH Wash out mouth thoroughly with water; give plenty of water to drink; obtain medical
attention.
SKIN Drench the skin thoroughly with water and give plenty of water to drink. Obtain
medical attention.
CHEMICAL HAZARDS AND STABILITY
Reacts vigorously with evolution of heat. Never add water to this product.
Will react violently with the following:
• Acetonitrile.
• Perchlorates.
• Nitro-organic compounds.
• Alkali metals.
• Potassium permanganate
• Metal halogenates.
Avoid contact with bases.
PROTECTIVE MEASURES
Wear chemical-resistant gloves (nitrile), safety goggles or face shield and use fume
cupboard. For large quantities use approved breathing apparatus, plastic apron and
sleeves and wear boots.
Ensure that safety shower and eye bath are available in the locality.
SPILLAGE HANDLING Wear appropriate protective clothing.
Cover the spillage with soda ash. If local regulations permit, cautiously add plenty
of water and mop up while diluting with more water and run to waste. Wash site of
spillage thoroughly with water. Otherwise cover with dry lime, sand or soda ash and
place in covered canisters. Arrange removal by disposal company. Ventilate area
and wash spill site with water after material removal is complete.
If material has entered drains it may be necessary to inform the Local Authorities.
78
Material Safety Data Sheets (MSDS)
WASTE DISPOSAL
Dispose in safe manner consistent with Local Authority chemical waste regulation.
For guidelines on disposal consult the requirements of the Control Pollution Act
(1974) and the Control of Pollution (special wastes) Regulations (1980 SI 1709).
The information on this sheet is believed to be correct at the time of printing. The details should be reviewed periodically and
should be checked for special uses.
79
Material Safety Data Sheets (MSDS)
80
Material Safety Data Sheets (MSDS)
81
Material Safety Data Sheets (MSDS)
82
Material Safety Data Sheets (MSDS)
REGULATORY INFORMATION
LABELLING TO EEC DIRECTIVES EU-no: 007.004.00.1
EINECS/ELINCS-no: 231-714-2
HAZARDOUS PRODUCT IDENTIFICATION C Corrosive
" R " Phrases R35 Causes burns
" S " Phrases S26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice
S36 Wear suitable protective clothing
S45 In case of accident or if you feel unwell, seek medical advice
(show the label where possible)
X1 Reserved for industrial and professional use.
X11 Keep in a cool place, protect against sunlight.
OTHER INFORMATION
NFPA RATINGS Health: 3
Flammability: 0
Reactivity: 0
Other: Oxidizer
LABEL HAZARD WARNING POISON! DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY
CAUSE FIRE. CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY
TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE LUNG
AND TOOTH DAMAGE.
LABEL PRECAUTIONS Do not get in eyes, on skin, or on clothing.
Do not breathe vapor or mist.
Use only with adequate ventilation.
Wash thoroughly after handling.
Keep from contact with clothing and other combustible materials.
Do not store near combustible materials.
Store in a tightly closed container.
Remove and wash contaminated clothing promptly.
LABEL FIRST AID In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed,
DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to
an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. In all cases get medical attention immediately.
PRODUCT USE Laboratory Reagent.
The information in this sheet is believed to be correct at the time of printing. The details should be reviewed periodically and
should be checked for special uses.
83
Material Safety Data Sheets (MSDS)
84
Material Safety Data Sheets (MSDS)
85
Material Safety Data Sheets (MSDS)
86
Material Safety Data Sheets (MSDS)
REGULATORY INFORMATION
LABELLING TO EEC DIRECTIVES EU-no: 007.001.01.2
HAZARDOUS PRODUCT IDENTIFICATION C Corrosive
" R " Phrases R34, R50 Causes burns. Very toxic to aquatic organisms
" S " Phrases S26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice
S36/37/39 Wear suitable protective clothing, gloves, and eye/face
protection
S45 In case of accident or if you feel unwell, seek medical advice
(show the label where possible)
S61 Avoid release to the environment
OTHER INFORMATION
NFPA RATINGS Health: 3
Flammability: 1
Reactivity: 0
LABEL HAZARD WARNING POISON! DANGER! CORROSIVE. MAY BE FATAL IF SWALLOWED OR INHALED. MIST
AND VAPOR CAUSE BURNS TO EVERY AREA OF CONTACT.
LABEL PRECAUTIONS Do not get in eyes, on skin, or on clothing.
Do not breathe vapor or mist.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
LABEL FIRST AID If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give
anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately
flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse. IMMEDIATE ACTION IS ESSENTIAL FOR
EYE EXPOSURES. In all cases call a physician immediately.
PRODUCT USE Laboratory Reagent.
The information in this sheet is believed to be correct at the time of printing. The details should be reviewed periodically and
should be checked for special uses.
87
Material Safety Data Sheets (MSDS)
Name:
SODIUM HEXAFLUOROSILICATE (sodium fluorosilicate, disodium hexafluorosilicate disodique)
Formula: Na2SiF6
Hazard class: 6.1 No. UN: 2674
CAS N° 16893-85-9
PHYSICAL PROPERTIES
White granular powder
Density (20 °C) approx. 2,7 g cm-3
Slightly soluble in water (6g 1-1 to 20°C)
FIRE AND EXPLOSION HAZARD When heated to decomposition it may emit hydrogen fluoride.
HEALTH HAZARD Classification of risk - toxic.
Avoid contact with skin.
Avoid contact with eyes.
Keep locked up.
Keep out of reach of children.
Toxic by ingestion and skin contact
Toxic by inhalation
Irritating to skin and eyes, may cause damage if exposure is prolonged.
Occupational exposure standard, long term exposure limit (8h TWA) 2,5 mg m-3
SAFETY PRECAUTIONS - FIRST AID If the casualty feels unwell, seek medical advice and show label where possible.
EYES Rinse immediately and thoroughly with water for at least 10 minutes. Obtain
medical attention.
LUNGS Remove from exposure, rest and keep warm. In severe cases, or if exposure has
been great obtain medical attention.
MOUTH Wash out mouth thoroughly with water and give plenty of water to drink. Obtain
medical attention.
SKIN Wash skin thoroughly with water and give plenty of water to drink. Obtain medical
attention.
CHEMICAL HAZARD AND STABILITY Contact with acids liberates toxic gas.
PROTECTIVE MEASURES (as appropriate to quantity handled)
RESPIRATOR Dust respirator.
VENTILATION Extraction hood.
GLOVES Rubber or plastic.
EYE PROTECTION Goggles or face shield.
OTHERS MEASURES Plastic apron, sleeves, boots - if handling large quantities.
SPILLAGE HANDLING
PRECAUTIONS Wear appropriate protective clothing.
Mix with sand, transfer carefully to canister and arrange removal by disposal
company. Wash site of spillage thoroughly with water and detergent.
For large spillages liquids should be contained with sand or earth and both liquids
and solids transferred to salvage canisters. Any residues should be treated as for
small spillages.
If material has entered surface drains it may be necessary to inform Local
Authorities, including fire services flammable.
WASTE DISPOSAL Dispose in safe manner consistent with Local Authorities or national chemical
Waste Regulation. For guidelines for disposal in the UK consult the requirements of
the Control of Pollution (special wastes) regulations (1980 SI 1709).
The information in this sheet is believed to be correct at the time of printing. The details should be reviewed periodically and
should be checked for special uses.
88
Material Safety Data Sheets (MSDS)
PRODUCT IDENTIFICATION
PRODUCT NAME FERROUS AMMONIUM SULPHATE HEXAHYDRATE
CAS No. (CE) 7783-85-9 233-151-8
FORMULA (NH4)2Fe(SO4)2, 6H2O
MOLECULAR WEIGHT 392,14 AMU
ALTERNATIVE NAMES Ferrous ammonium sulfate hexahydrate
Ammonium ferrous sulfate, hexahydrate
Iron ammonium sulfate hydrate
Sulfuric acid, ammonium iron (2+) salt, hexahydrate
PHYSICAL PROPERTIES
FORM Solid
COULOUR Greenish blue
ODOUR Nil
MELTING POINT 100°C
DENSITY 1.86 g/cm3
FIRE AND EXPLOSION HAZARD Non-combustible.
Likelihood of dangerous vapors being given off if close to a fire.
In fire situations it may form nitrogen oxides and sulphur oxides.
HEALTH RISKS
SPECIFIC ENVIRONMENTAL AND
Irritant for the eyes, respiratory tract and skin.
HEALTH HAZARDS
SAFETY MEASURES
EYES - SKIN Flush copiously with water.
Remove any contaminated clothing
RESPIRATORY TRACT Avoid continued exposure, breathe in fresh air; seek medical attention.
IF SWALLOWED Drink plenty of water, provoke vomiting, and seek medical advice.
CHEMICAL RISKS AND STABILITY
STABILITY Conditions to avoid - high temperatures
CONDITIONS TO AVOID Sensitive to air, sensitive to light.
PRODUCTS TO AVOID Powerful oxidizing agents and acids.
DANGEROUS DECOMPOSITION Iron oxides
PRODUCTS Ammonia
Sulphur oxides
PREVENTIVE MEASURES
HANDLING Safe Handling Instructions: Do not breathe the dust. Avoid contact with the eyes,
skin or clothing. Avoid prolonged or repeated exposures.
EXPOSURE LIMITS UK:
Source - category - value
OEL - LTEL - 1 mg (Fe)/m3
OEL - STEL - 2 mg (Fe)/m3
BREATHING EQUIPMENT Use dust-masks or over-pressure breathing gear if dust formation is likely.
GLOVES Essential.
Wear chemical resistant gloves (nitrile rubber, NBR).
EYE PROTECTION Protective glasses/goggles are essential.
OTHER Wear protective clothing and work in a well-ventilated area.
Remove any contaminated clothing and wash hands thoroughly after working with
the product.
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Material Safety Data Sheets (MSDS)
DISPOSAL MEASURES
Contact a specialist waste disposal organization where disposal of this product is
required. Dissolve, or mix, the product with a combustible solvent and burn in a
chemical incinerator fitted with post-combustion and scrubber systems. Observe all
applicable local, national and international environmental regulations.
FIRST AID MEASURES
FOLLOWING INHALATION In the event of inhalation, seek clean air. Where breathing has stopped, apply
artificial respiration. Where breathing is difficult, give oxygen.
FOLLOWING CONTACT WITH SKIN In the event of skin contact, wash the skin immediately using soap and plenty of
water.
FOLLOWING CONTACT WITH THE In the event of contact with the eyes, rinse out immediately with plenty of water for
EYE at least 15 minutes.
FOLLOWING INGESTION (IF If swallowed, rinse out the mouth with water if the patient is still conscious. Call
SWALLOWED) medical assistance.
FIRE FIGHTING - EXTINCTION METHODS
SUTABLE EXTINGUISHERS Water spray. Carbon dioxide, dry chemical powder or suitable foam.
SPECIAL RISKS Specific Danger(s): Gives off toxic fumes if burnt.
SPECIAL PROTECTIVE EQUIPMENT Wear individual breathing apparatus and protective clothing to prevent any contact
NEEDED FOR FIRE FIGHTING with the eyes or skin.
The information contained in this document is reviewed at regular intervals and checked for special cases.
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Material Safety Data Sheets (MSDS)
Name:
SODIUM MOLYBDATE DIHYDRATE Formula: Na2MoO4.2H2O
CAS N° 10102-40-6
PHYSICAL PROPERTIES
MELTING POINT 687°C
SOLUBILITY IN WATER 840 g/L
FIRE AND EXPLOSION RISK No information available
HEALTH RISKS Not hazardous according to Directive 67/548/EEC
SECURITY MEASURES
EYES Rinse immediately with plenty of water, keeping the eyelids
open as much as possible
LUNGS In case of inhalation, remove from exposure and move to
fresh air immediately.
INGESTION Drink plenty of water. If feeling unwell seek medical aid
CHEMICAL DANGER AND STABILITY
STABILITY Stable
SPECIFIC RISKS No information available
DISPOSAL Observe all federal, state, and local environmental regulations
for disposal of chemical products
PERSONAL PROTECTION
RESPIRITORY Wear appropriate breathing apparatus due to the formation of
dust
GLOVES Not necessary
EYES Wear appropriate safety goggles
MEASURES TO TAKE IN CASE OF ACCIDENTAL SPILLAGE
PERSONAL Avoid inhalation of any dust
ENVIRONMENT Do not dispose of in any standard waste disposal systems
such as sinks or sewers
CLEANING Vacuum or sweep up material and place into a suitable
disposal container. Avoid generating dusty conditions.
The information listed above must be reviewed periodically and should not be considered a substitute for the MSDS for this
product.
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Material Safety Data Sheets (MSDS)
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Material Safety Data Sheets (MSDS)
93
Material Safety Data Sheets (MSDS)
94
Material Safety Data Sheets (MSDS)
95
Material Safety Data Sheets (MSDS)
13.10Reagent R2
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Material Safety Data Sheets (MSDS)
97
Material Safety Data Sheets (MSDS)
13.11Reagent R3
98
Material Safety Data Sheets (MSDS)
99
Material Safety Data Sheets (MSDS)
100