Potassium fluoride, KF

TOXICITY LD50 oral rat:

245 mg/kg

LD50 dermal rat:

> 2000 mg/kg body weight (EPA OPPTS 870.1200: Acute Dermal Toxicity, 24 h, Rat, Male
/ female, Experimental value, Dermal, 14 day(s))

LC50 inhalation rat (mg/l):

1 mg/l air (OECD 403: Acute Inhalation Toxicity, 4 h, Rat, Male / female, Read-across,
Inhalation (dust), 14 day(s))

ATE US (oral):
245 mg/kg body weight

PROPER HANDLING Handling

AND STORAGE Avoid raising dust. Keep away from naked flames/heat. Measure the concentration in
the air regularly. Carry operations in the open/under local exhaust/ventilation or with
respiratory protection. Comply with the legal requirements. Remove contaminated
clothing immediately. Clean contaminated clothing. Thoroughly clean/dry the
installation before use. Do not discharge the waste into the drain. Keep container tightly
closed.

Storage conditions:
Store in a dry area. Keep container in a well-ventilated place. Keep locked up. May be
stored under inert gas. Meet the legal requirements.

FIRST AID First-aid measures after inhalation:

Remove the victim into fresh air. Immediately consult a doctor/medical service.

First-aid measures after skin contact:

Wash immediately with lots of water. Do not apply (chemical) neutralizing agents.
Remove
clothing before washing. Take victim to a doctor if irritation persists.

First-aid measures after eye contact:

Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing.
Take victim to an ophthalmologist if irritation persists.

First-aid measures after ingestion:

Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not
induce vomiting. Immediately consult a doctor/medical service.
Ingestion of large quantities: immediately to hospital.

Ferric chloride, FeCl3

TOXICITY Chronic Effects: Repeated dosage may cause hemosiderosis, including possible
damage to liver and pancreas.

Toxicological Data: Anhydrous Ferric Chloride Solid Oral LD50 (rat) = 450 mg/kg

Carcinogenicity: None of the components of this material are listed as a carcinogen by

IARC,
NTP, OSHA, or ACGIH.
Reproductive Effects: TDLo Rat 1 day (intratesticular) 12976 𝜇𝑔/𝑘𝑔; TDLo Rat 1 day
(intravaginal) 29 mg/kg pre pregnancy continuous.
PROPER HANDLING Handling:
AND STORAGE Store and handle in corrosion-proof materials (and area). Use FRP or PVC pipes. Be
cautious of substance residue in empty containers. Act according to precautions and
warnings
set forth.

Storage conditions:
Store in a tightly closed container. Do not store in metal containers. Fiberglass, plastic, or
rubber-lined tanks may be used for storage. Protect from damage and keep separated
from incompatible substances.

FIRST AID First-aid measures after eye contact:

Immediately flush eyes for 15 minutes with large amounts of water while holding eyelids
apart. Washing within one minute is essential to achieve maximum effectiveness.
Obtain medical attention IMMEDIATELY after flushing.

First-aid measures after skin contact:

Flush skin with water. Remove contaminated clothing; wash before reuse. If irritation is
still present, seek medical attention IMMEDIATELY.

First-aid measures after inhalation:

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Obtain medical attention IMMEDIATELY.

First-aid measures after ingestion:

DO NOT INDUCE VOMITING. Give 1 or 2 glasses of water or milk. Never give anything by
mouth to an unconscious individual. Obtain medical attention IMMEDIATELY.

Silver nitrate, AgNO3

TOXICITY LD50 oral rat:
1173 mg/kg (Rat)

ATE US (oral):
1173 mg/kg body weight

PROPER HANDLING Handling:

AND STORAGE Wash hands and other exposed areas with mild soap and water before eating, drinking
or smoking and when leaving work. Provide good ventilation in process area to prevent
formation of vapor.

Storage conditions:
Keep only in the original container in a cool, well ventilated place away from: Heat
sources, Ignition sources, incompatible materials. Keep container closed when not in
use.

FIRST AID First-aid measures after inhalation:

Allow victim to breathe fresh air. Allow the victim to rest.

First-aid measures after skin contact:

Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention.

First-aid measures after eye contact:

Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

First-aid measures after ingestion:

Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
 Denatured Alcohol
TOXICITY LD50 oral rat:
10740 mg/kg bodyweight (Rat; Experimental value,Rat; Experimental value)

LD50 dermal rabbit:

> 16000 mg/kg (Rabbit)

PROPER HANDLING Handling:

AND STORAGE Comply with the legal requirements. Remove contaminated clothing immediately.
Clean contaminated clothing. Handle uncleaned empty containers as full ones.
Thoroughly clean/dry the installation before use. Do not discharge the waste into the
drain. Do not use compressed air for pumping over. Use spark-/explosionproof
appliances and lighting system. Take precautions against electrostatic charges. Keep
away from naked flames/heat. Keep away from ignition sources/sparks. Observe normal
hygiene standards. Keep container tightly closed. Measure the concentration in the air
regularly. Work under local exhaust/ventilation.

Storage conditions:
Keep container tightly closed. Keep only in the original container in a cool, well
ventilated place away from: Direct sunlight, Heat sources, Ignition sources, incompatible
materials. Keep in fireproof place.

FIRST AID First-aid measures after inhalation:

Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

First-aid measures after skin contact:

Rinse with water. Take victim to a doctor if irritation persists.

First-aid measures after eye contact:

Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to
an ophthalmologist if irritation persists.

First-aid measures after ingestion:

Rinse mouth with water. Do not induce vomiting. Ingestion of large quantities:
immediately to hospital.

SODIUM METAL
TOXICITY LD50/LC50: RTECS: Not available.

Carcinogenicity: Sodium - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop

65.

PROPER HANDLING Handling:

AND STORAGE Wash thoroughly after handling. Remove contaminated clothing and wash before
reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do
not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from
heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Storage conditions:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep away from water.
FIRST AID First-aid measures after inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing

First-aid measures after skin contact:

Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
contaminated clothing before reuse. Brush off loose particles from skin. Immerse in cool
water/wrap with wet bandages

First-aid measures after eye contact:

Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing

First-aid measures after ingestion:

Rinse mouth. DO NOT induce vomiting.

FeSO4 CRYSTALS
TOXICITY Oral LD50 (rat):
319 mg/kg (anhydrous)

LD50 (mouse):
1520 mg/kg

PROPER HANDLING Handling:

AND STORAGE Avoid prolonged or repeated contact with skin, eyes and clothing. Only use in well-
ventilated areas. Keep container tightly closed when not in use. Avoid generating and
inhaling dust.

Storage conditions:
Keep container tightly closed and in a cool, well-ventilated place, away from direct
sunlight and other sources of heat or ignition.

FIRST AID First-aid measures after inhalation:

Remove victim to fresh air. Keep warm and at rest. Employ artificial respiration if
indicated. Seek medical advice if effects persist

First-aid measures after skin contact:

Remove contaminated clothing and wash affected skin with soap and water. If
persistent irritation occurs, obtain medical attention.

First-aid measures after eye contact:

Immediately irrigate with copious quantity of water for at least 15 minutes. Eyelids to be
held open. Seek immediate medical assistance.

First-aid measures after ingestion:

Rinse mouth thoroughly with water immediately. Give plenty of water to drink. Do not
induce vomiting. Seek immediate medical assistance.
 HEXANE
TOXICITY LD50/LC50:
CAS # 110-54-3: Draize test, rabbit, eye: 10 mg mild Inhalation, mouse: LC50 = 150000
mg/m3/2H Inhalation, rat: LC50 = 48000 ppm/4H Inhalation, rat: LC50 = 627000
mg/m3/3M Oral, rat: LD50 = 25 g/kg

Carcinogenicity:
CAS # 110-54-3: Not listed by IARC, NTP, ACGIH, or CA Prop 65

PROPER HANDLING Handling:

AND STORAGE Wash thoroughly after handling. Remove contaminated clothing. Ground and bond
containers when dispensing. Keep container tightly closed. Keep away from heat and
flames. Avoid breathing vapors. Use with adequate ventilation. Empty containers retain
product residue and can be dangerous.

Storage conditions:
Store in cool, dry, well ventilated area away from incompatible materials. Keep away
from sources of ignition and oxidizing materials.

FIRST AID First-aid measures after inhalation:

Remove from exposure area to fresh air immediately. If breathing has stopped, give
artificial respiration. Get medical aid at once.

First-aid measures after skin contact:

Flush skin with plenty of water for 15 minutes. Remove contaminated clothing. Get
medical aid at once.

First-aid measures after eye contact:

Flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower
eyelids. Get medical aid at once.

First-aid measures after ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Hexane may be
aspirated. If vomiting occurs naturally, have victim lean forward. If victim is conscious,
give 2-4 glasses of water. Get medical aid at once.

H2SO4
TOXICITY LD50 oral rat:
2140 mg/kg bodyweight (Rat, Experimental value)

ATE US (oral):
2140 mg/kg bodyweight

Skin corrosion/irritation: Causes severe skin burns and eye damage. pH: < 1

Serious eye damage/irritation:

Causes serious eye damage. pH: < 1

PROPER HANDLING Handling:

AND STORAGE Keep away from naked flames/heat. Measure the concentration in the air regularly.
Carry operations in the open/under local exhaust/ventilation or with respiratory
protection. Comply with the legal requirements. Remove contaminated clothing
immediately. Clean contaminated clothing. Keep the substance free from
contamination. Thoroughly clean/dry the installation before use. Do not discharge the
waste into the drain. Never add water to this product. Never dilute by pouring water to
 the acid. Always add the acid to the water.

Storage conditions:
Store in a dry area. Ventilation at floor level. Keep locked up. Provide for a tub to collect
spills. Unauthorized persons are not admitted. Meet the legal requirements.

FIRST AID First-aid measures after inhalation:

Remove the victim into fresh air. Immediately consult a doctor/medical service.

First-aid measures after skin contact:

Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical)
neutralizing agents. Remove clothing while washing. Do not remove clothing if it sticks to
the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If
burned surface > 10%: take victim to hospital.

First-aid measures after eye contact:

Rinse immediately with plenty of water for 15 minutes. Take victim to an ophthalmologist.
Do not apply neutralizing agents. Remove contact lenses, if present and easy to do.
Continue rinsing.

First-aid measures after ingestion:

Rinse mouth with water. Do not induce vomiting. Do not give activated charcoal.
Immediately consult a doctor/medical service. Ingestion of large quantities: immediately
to hospital. Do not give chemical antidote.

AMMONIA, NH3
TOXICITY Oral: LD50: 350 mg/kg (rat)

PROPER HANDLING Handling:

AND STORAGE Wash hands after handling. Follow good hygiene procedures when handling chemical
materials. Do not drink, smoke, or use personal products when handling chemical
substances. Use only in well ventilated areas. Avoid contact with eyes, skin, and clothing.

Storage conditions:
Provide ventilation for containers. Avoid storage near extreme heat, ignition source or
open flame. Store away from food stuff, oxidizing agents. Store in cool, dry conditions in
well-sealed containers.

FIRST AID First-aid measures after inhalation:

When inhaled, move exposed individual to fresh air. Loosen clothing as necessary and
position individual in a comfortable position. Seek medical assistance if discomfort
persists. Give oxygen if there’s difficulty in breathing.

First-aid measures after skin contact:

If chemical got in contact with the skin, wash affected area with soap and water. Rinse
gently using water for 15-20 minutes. Seek medical assistance if irritation persists.

First-aid measures after eye contact:

If eye contact occurred, protect unexposed eye. Rinse exposed eye/s gently using
water for 15 to 20 minutes. Remove contact lenses if able to do so during rinsing.

First-aid measures after ingestion:

If swallowed, rinse mouth thoroughly. Don’t induce vomiting. Have exposed individual
drink sips of water. If discomfort or vomiting persists, seek medical attention.
 p-chloroaniline
TOXICITY Acute toxicity:
LD50 Oral - Rat - male - 256.0 mg/kg(4-Chloroaniline) LC50 Inhalation - Rat - 4 h - 2,340
mg/m3(4-Chloroaniline) Remarks: Behavioral:Somnolence (general depressed activity).
Lungs, Thorax, or Respiration:Dyspnea. Cyanosis Page 5 of 8 LD50 Dermal - Rat - male -
455.0 mg/kg(4-Chloroaniline)

Skin corrosion/irritation: Skin - Rabbit(4-Chloroaniline)

Result: No skin irritation

Serious eye damage/eye irritation Eyes - Rabbit(4-Chloroaniline)

Result: Mild eye irritation

Carcinogenicity
This product is or contains a component that has been reported to be proba EPA
classification.(4- Chloroaniline) Possible human carcinogen(4-Chloroaniline) (4-
Chloroaniline)

PROPER HANDLING Handling:

AND STORAGE Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure
- obtain special instructions before use. Provide appropriate exhaust ventilation at
places where dust is formed.

Storage conditions:
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

FIRST AID First-aid measures after inhalation:

If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.

First-aid measures after skin contact:

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a
physician.

First-aid measures after eye contact:

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

First-aid measures after ingestion:

Never give anything by mouth to an unconscious person. Rinse mouth with water.
Consult a physician.

Sulfanilic acid, C6H7NO3S

TOXICITY LD50 = 12300 mg/kg (Rat)

Irritation:
Irritating to eyes and skin

Sensitization:
May cause sensitization by skin contact

PROPER HANDLING Handling:

AND STORAGE Wear personal protective equipment. Ensure adequate ventilation. Avoid dust
formation. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation.
 Storage conditions:
Keep containers tightly closed in a dry, cool and well-ventilated place.

FIRST AID First-aid measures after inhalation:

Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention.

First-aid measures after skin contact:

Wash off immediately with plenty of water for at least 15 minutes. Obtain medical
attention

First-aid measures after eye contact:

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Get medical attention.

First-aid measures after ingestion:

Do not induce vomiting. Obtain medical attention.

Chlorobenzene
TOXICITY LD50/LC50:
CAS# 108-90-7:
Inhalation, rat: LC50 = 2965 ppm;
Oral, mouse: LD50 = 2300 mg/kg;
Oral, rabbit: LD50 = 2250 mg/kg;
Oral, rat: LD50 = 1110 mg/kg;

PROPER HANDLING Handling:

AND STORAGE Wash thoroughly after handling. Remove contaminated clothing and wash before
reuse. Use with adequate ventilation. Ground and bond containers when transferring
material. Avoid contact with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks
or open flames.

Storage conditions:
Keep away from sources of ignition. Store in a tightly closed container. Keep from
contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from
incompatible substances.

FIRST AID First-aid measures after inhalation:

Remove from exposure and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.

First-aid measures after skin contact:

Flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing
before reuse.

First-aid measures after eye contact:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid.

First-aid measures after ingestion:

Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
 Sodium nitroprusside, Na2[Fe(CN)5NO]
TOXICITY LD50 oral rat:
99 mg/kg

ATE US (oral):
99 mg/kg body weight

PROPER HANDLING Handling:

AND STORAGE Wash hands and other exposed areas with mild soap and water before eating, drinking
or smoking and when leaving work. Provide good ventilation in process area to prevent
formation of vapor.

Storage conditions:
Keep only in the original container in a cool, well ventilated place away from: Ignition
sources, Heat sources, incompatible materials. Keep container closed when not in use.

FIRST AID First-aid measures after inhalation:

Allow victim to breathe fresh air. Allow the victim to rest.

First-aid measures after skin contact:

Remove affected clothing and wash all exposed skin area with mild soap and water,
followed by warm water rinse.

First-aid measures after eye contact:

Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or
redness persists.

First-aid measures after ingestion:

Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Immediately call a poison center or doctor/physician.

Nitric Acid, HNO3

TOXICITY LD50 oral rat:
≥ 90000 mg/kg

ATE US (oral):
90000 mg/kg body weight

Skin corrosion/irritation: Causes severe skin burns and eye damage.

Serious eye damage/irritation: Causes serious eye damage.

PROPER HANDLING Handling:

AND STORAGE Wash hands and other exposed areas with mild soap and water before eating, drinking
or smoking and when leaving work. Provide good ventilation in process area to prevent
formation of vapor. Do not breathe mist, vapors, spray.

Storage conditions:
Keep only in the original container in a cool, well ventilated place away from:
incompatible materials. Keep container closed when not in use.

FIRST AID First-aid measures after inhalation:

Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a poison center or doctor/physician.
First-aid measures after skin contact:
Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a poison center or doctor/physician.

First-aid measures after eye contact:

Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.

First-aid measures after ingestion:

Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or
doctor/physician.