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RECEIVING TERMINALS
Jayanthi Vijay Sarathy, M.E, CEng, MIChemE, Chartered Chemical Engineer, IChemE, UK
Liquefied Natural Gas (LNG) is a cryogenic Typical Design Considerations [3]
mixture of low molecular weight (MW) 1. Single containment tank is either a single
hydrocarbons with its chief component being tank or a tank comprising an inner tank
methane. Its uses cover a gamut of and outer container, designed and
applications from domestic & industrial use, constructed so that only the inner tank is
power generation, to transportation fuel in its required to meet the low temperature
liquid form. LNG is transported in double- ductility requirements for storage of the
hulled ships specifically designed to handle product. A double containment tank is a
low temperatures of the order of -1620C. As of tank designed and constructed so that both
2012, there were 360 ships transporting the inner tank and the outer tank are
more than 220 million metric tons of LNG capable of independently containing the
every year. [1] refrigerated liquid stored.
When LNG is received at most terminals, it is 2. The difference between the double
transferred to insulated storage tanks that containment and full containment is that
are built to specifically hold LNG. These tanks the outer tank of a full containment tank is
can be above or below ground & keep the intended to be capable of both containing
liquid at a low temperature to minimize the refrigerated liquid and of controlled
evaporation & compositional changes due to venting of the vapour resulting from
heat ingress from the ambient. The product leakage after a credible event.
temperature within the tank will remain Among these three types of LNG tanks, the
constant if the pressure is kept constant by full containment type is regarded as the
allowing the boil off gas (BOG) to escape from most advanced type.
the tank. This is known as auto-refrigeration. 3. The inner tank is manufactured with 9%
BOG is collected & used as a fuel source in the nickel steel and the outer tank is composed
facility or on the tanker transporting it. When of reinforced concrete and pre-stressed
natural gas is needed, LNG is warmed enough concrete. The 9% nickel steel is widely
using heat exchangers to vaporize it called re- used as a material for the inner tank since
gasification process, prior to transferring it to it has the strength and toughness enough
the pipeline grid to various users. for cryogenic uses. The inner tank also has
Boil-off gas (BOG) management & assessment a function of preventing LNG from leakage.
of LNG’s thermodynamic properties are key The concrete outer tank is designed to
issues in the technical assessment of LNG resist all the external loads including
storage. Increased vaporization process may seismic load. Insulating materials are
negatively affect the stability and safety of the placed between the inner and outer tank to
stored LNG. For these reasons the rate of preserve the stored LNG.
vaporization (boil off rate) should be 4. The design boil off rate is typically about
precisely determined in storage terminal 0.05 vol%/day & the design vacuum
energy systems. [2]. pressure in the dome is about -0.05 kPag.
Page 1 of 8
5. The roof has a suspended ceiling deck and 3. Radiation plays a role & the emissivity of
a steel lined concrete dome. The steel liner the outer concrete is taken to be 0.9.
installed on the inside surface of the outer 4. The LNG tank’s inner heat transfer
concrete tank provides the gas tightness. coefficient is taken as 35 W/m2.K & the
The boil-off rate is determined by the soil’s heat transfer coefficient is taken as 2
insulation system. W/m2.K.
6. In case of an LNG leakage, liquid may 5. Since no information is available from Ref
impact the outer tank. Accordingly, liquid [2] regarding the maximum operating
tightness must be guaranteed by the liquid level in the LNG tank, the max
corner protection system as well as the operating liquid level (H) is taken to be 2 m
polyurethane foam coating installed on the less than the height of the inner
inside surface of the concrete wall. The containment. This would mean a vapour
concrete outer tank protects the inner tank space is available & the heat transfer
in case of emergency from the outside. through this vapour space is neglected.
7. The base of the tank has a bottom heating 6. Certain insulation material related to the
system (BHS) using ethylene glycol as roof top & tank bottom is not presented in
brine fluid. The bottom heating system is Ref [2], hence the insulation material and
installed in order to avoid frost heave. their concerned thickness is assumed as
8. The roof liner consisting of a 9% Ni steel shown in the next section.
membrane stiffened with rafters in radial 7. Heat transfer due to free convection is
and tangential directions acts as formwork expected. Considering the diameter of the
for the concrete sphere. The steel structure LNG tank to be very large, any section of
is fabricated on the bottom slab and lifted the concrete wall, is assumed to be similar
by air pressure to its final position. Rafters to flow over a vertical flat plate.
and roof liner plates are connected with a
8. The LNG tank outer temperature at the
steel compression ring anchored in the
concrete wall is expected to be less than
concrete roof ring-beam by welding.
the ambient temperature. In calculating the
Case Study & Assumptions free convection, Grashof number is
To demonstrate the BOG Rate calculations, expected to yield a negative value.
the following case study is made based on a However as per Ref [4], Sec. 9.4, Page 568
single containment LNG Tank dimensions & indicates, that irrespective of Ts > T or Ts <
composition given in Ref [2]. In addition, T, where, T is the ambient temperature &
certain assumptions are made for this Ts is the surface temperature, the foregoing
example case study. results to estimate Nusselt number still
1. The ambient temperature is taken to be apply. When Ts < T, free convection still
26.850C & wind velocity is taken to be 36 develops, except that the convection
km/h (10 m/s). The soil temperature is boundary flows downward. Therefore, in
taken as 16.850C. the event of obtaining a negative Grashof
2. For heat transfer computations, the Number based on Ts < T, the absolute
average temperature on the LNG Tank value is taken.
surface is taken to be an average of LNG 9. LNG is stored at cryogenic temperatures
temperature inside the tank and the for significant durations and inevitable
ambient air temperature. heat ingress from the surroundings into
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the storage tank will lead to vaporization. Kay’s Rule of Mixing for the composition
The more volatile components (methane selected and are as follows,
and nitrogen) will vaporize preferentially,
𝑀𝑊𝐿𝑁𝐺 = ∑𝑖=𝑛
𝑖=1 𝑥𝑖 𝑀𝑊𝑖 (1)
resulting in weathering of LNG. If left
unchecked, weathering can render the 𝐿𝑁𝐺 = ∑𝑖=𝑛
𝑖=1 𝑥𝑖 𝑖 (2)
remaining LNG unsellable, because of Where,
regulatory requirements. Furthermore,
MW = Molecular Weight [kg/kmol]
weathering increases the overall tank
= Latent Heat of Vaporization [kJ/kg]
pressure and in order to avoid over-
pressurization some of the generated Table 2. LNG Latent Heat of Vaporization & MW
vapour is removed, as boil-off gas (BOG). Component LNG xi.MWi xi. i
10. The LNG industry is specifically concerned - [kJ/kg] [kg/kmol] [kJ/kg]
in minimizing BOG rates and ensuring that Methane 510.8 14.36 457.3
weathering does not greatly impact the
Ethane 489.3 2.07 33.7
LNG quality. In particular weathering
prediction is used in planning operations, Propane 425.6 1.07 10.3
LNG Tank Design Data To estimate the density of LNG, the specific
For BOG estimation, the following process molar volumes as per Ref [6] page 145, 146,
data for heavy LNG is used [2], (N.B.S. - Technical note 1030 December 1980)
need to be computed as,
Table 1. Heavy LNG Composition
𝑀𝐿𝑁𝐺
Component MW Mol% 𝜌𝐿𝑁𝐺 = (3)
𝐿𝑁𝐺
- [kg/kmol] [%] 𝑥
𝐿𝑁𝐺 = ∑ 𝑥𝑖 𝑖 − [𝐾1 + (𝐾1 − 𝐾1 ) 0.0425
𝑁2
] 𝑥𝐶𝐻4 (4)
Methane [CH4] 16.04 89.52
Where,
Ethane [C2H6] 30.07 6.89
LNG = Density of LNG [kg/m3]
Propane [C3H8] 44.01 2.42
MLNG = Molar Mass of LNG [kg/kmol]
i-Butane [i-C4H10] 58.12 0.62
LNG = LNG molar volume [L/mol]
n-Butane [n-C4H10] 58.12 0.47
Mi = Molar Mass of Component ‘i’ [kg/kmol]
i-Pentane [i-C5H12] 72.15 0.00
xi =Molar fraction of component ‘i’ [-]
n-Pentane [n-C5H12] 72.15 0.00
i = Component molar volumes of ‘i’ at LNG
Nitrogen [N2] 28.01 0.08
Temperature [L/mol]
Total 100.0
K1, K2 = Correction Factors [-]
The LNG molecular weight (MW) and latent
The values of K1, K2 can be obtained from the
heats of vaporization are estimated using
below graphs,
Page 3 of 8
Table 3. LNG Molar Volume
Figure 4. Single Containment LNG Tank Schematic Perlite Insulation [k2] r2 37.80
The various tank insulations are depicted as, Carbon Steel [k3] r3 37.95
Page 5 of 8
Polyurethane Foam [k4] r4 38.55 The above correlation is valid for all ranges of
Reynolds number (Re) and Pr 0.2, where all
9% Nickel Steel [k1] r5 0.20
properties are evaluated at film temperature.
Foam Glass [k6] r6 0.60
It is to be noted that as per [4], Churchill &
Carbon Steel [k7] r7 0.15 Bernstein correlation is reasonable over a
Concrete [k8] r8 0.60 certain range of conditions but for most
engineering calculations, the accuracy is not
Design Methodology
expected to be much better than 20% because
To estimate the heat load, thermal
these are based on more recent results
conductivity and heat transfer coefficients
encompassing a wide range of conditions [4].
determine the amount of heat transferred to 4⁄
5
the cryogenic LNG through the walls of the
1⁄ 1⁄ 5⁄
0.62 × 2.41 × 107 2 0.7293 3 2.41 × 107 8
𝑁𝑢 = 0.3 + 1⁄ [1 + ( ) ]
282000
tank. The modes of heat transfer driven by [1 + (
0.4
)
2⁄
3
]
4
0.7293
temperature differences are conduction
through the tank wall & its various insulation (17)
𝑃𝑟 =
𝐶𝑃,𝑎𝑖𝑟𝜇𝑎𝑖𝑟
=
1.006×0.000019
≈ 0.7293 (14) The radiation mode expressed above is
𝑘𝑎𝑖𝑟 0.0256
written in a manner similar to convection, i.e.,
Based on the assumption that the tank the radiation rate equation is linearized
diameter is large; the flow of air over the tank making the heat rate proportional to the
is approximated to flow over a flat plate. temperature difference rather than to the
Therefore Reynolds number (Re) becomes, difference between two temperatures to the
𝑉𝑎𝑖𝑟 𝐿𝑚𝑎𝑥 𝑂𝑝 𝐿𝑒𝑣𝑒𝑙 10×38 fourth power [2]. Therefore the radiation
𝑅𝑒 = = 0.000016 = 2.41 × 107 (15)
𝛾𝑎𝑖𝑟
heat transfer coefficient (hr) for emissivity of
Nusselt number for forced convection over concrete () taken as 0.9 & Stefan Boltzmann
circular cylinder with cross flow can be Constant () of 5.6710-8 W/m2/K is,
estimated using Churchill and Bernstein ℎ𝑟 = 0.9 × 5.67 × 10−8 (206.25 + 112.5) × (206.252 + 112.52 )(21)
correlation [4]. This equation is valid for all
Or, ℎ𝑟 ≈ 0.9 𝑊/𝑚2 𝐾 (22)
Re.Pr 2 and the correlation is expressed as,
4⁄ Natural/Free Convection
1 1 5⁄ 5
0.62 𝑅𝑒 ⁄2 𝑃𝑟 ⁄3 𝑅𝑒 8 To estimate the heat transfer due to natural
𝑁𝑢 = 0.3 + 1⁄ [1 + (282000 ) ] (16)
2 4
0.4 ⁄3
[1+( ) ]
𝑃𝑟
convection, the correlation by Churchill & Chu
[4] can be used and is of the form,
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2 1⁄
𝑁𝑢𝑐𝑜𝑚𝑏𝑖𝑛𝑒𝑑 = [233574 + 84974 ] 4 (35)
1
0.387 𝑅𝑎 ⁄6
𝑁𝑢 = {0.825 + 8⁄ } (23) 𝑁𝑢𝑐𝑜𝑚𝑏𝑖𝑛𝑒𝑑 = 23,458 (36)
9 27
0.492 ⁄16
[1+( ) ]
𝑃𝑟
Therefore the combined external heat
Where, Rayleigh number (Ra) is the product transfer coefficient, hcomb, is computed as,
of Grashof number (Gr) and Reynolds number ℎ𝑐𝑜𝑚𝑏 = 𝐿 𝑎𝑖𝑟
𝑘 𝑁𝑢𝑐𝑜𝑚𝑏
=
0.0256×23458
≈ 15.8 𝑊/𝑚2 𝐾 (37)
38
(Re) computed as, 𝑀𝑎𝑥𝑂𝑝.𝐿𝑒𝑣𝑒𝑙
The Rayleigh number and Nusselt number is, bottom. For tank wall, the heat load is
computed as,
𝑅𝑎 = 6.75 × 1014 × 0.7293 = 4.93 × 1014 (27)
−2𝜋𝐻𝑚𝑎𝑥 [𝑇𝐿𝑁𝐺 −𝑇𝑠]
2 𝑄𝑊 = (40)
∑ 𝑅1
⁄1
0.387× (4.93×1014 ) 6 Where R1 is the resistances through the tank
𝑁𝑢 = {0.825 + 8⁄ } = 8497(28)
9 27
[1+(
0.492 ⁄16
) ] wall.
0.7293
1 1
𝐴1 = 𝑟 = 37×16.73 = 0.0016 𝑚. 𝐾/𝑊 (41)
Therefore the external free convection heat 𝑜𝑢𝑡 ℎ𝑎𝑖𝑟,𝑜𝑣𝑒𝑟𝑎𝑙𝑙
1 𝑟 1 38.55
forced convection, the condition that is 𝐴5 =
𝑘𝑝𝑜𝑙𝑦
𝑙𝑛 [ 4 ] =
𝑟3 0.029
𝑙𝑛 [
37.95
] = 0.541 𝑚. 𝐾/𝑊 (45)
required to be satisfied is as follows [4],
1 𝑟 +𝑟 1 39.15
𝐴6 = 𝑘 𝑙𝑛 [ 4𝑟 8 ] = 1.8 𝑙𝑛 [38.55] = 0.0086 𝑚. 𝐾/𝑊 (46)
𝐺𝑟 𝑐𝑜𝑛𝑐 4
≪ 1 ; Free convection is negligible (30)
𝑅𝑒 2 1 1
𝐴7 = 𝑟 = 39.15×35 = 0.00073 𝑚. 𝐾/𝑊 (47)
𝑖𝑛 ℎ𝐿𝑁𝐺
𝐺𝑟
≫ 1 ; Forced convection is negligible (31)
𝑅𝑒 2 ∑ 𝑅1 = 𝐴1 + 𝐴2 + 𝐴3 + 𝐴4 + 𝐴5 + 𝐴6 + 𝐴7 (48)
𝐺𝑟
≈ 1 ; Mixed Convection Exists (32) ∑ 𝑅1 = 0.973 𝑚. 𝐾/𝑊 (49)
𝑅𝑒 2
Therefore, checking for mode of convection, The heat load through the tank wall is,
−2𝜋×38×[112.5−206.25]
𝐺𝑟 6.75×1014 𝑄𝑊 = = 23,005 𝑊 (50)
= (2.41×107 )2 = 1.1652 ≈ 1 (33) 0.973
𝑅𝑒 2
The heat load through the Tank bottom is
Therefore the mode of heat transfer is mixed
computed in linear coordinates as,
convection and the combined heat transfer
coefficient is computed as, −𝜋𝑟 2 [𝑇𝐿𝑁𝐺 −𝑇𝑠𝑜𝑖𝑙 ]
𝑄𝐵 = (51)
∑ 𝑅2
1⁄
4 4 4
𝑁𝑢𝑐𝑜𝑚𝑏𝑖𝑛𝑒𝑑 = [𝑁𝑢𝑓𝑟𝑒𝑒 + 𝑁𝑢𝑓𝑜𝑟𝑐𝑒𝑑 ] (34) Where R2 is the tank bottom resistance,
Page 7 of 8
𝐵1 = ℎ
1 1
= 35 = 0.0286 𝑚2 𝐾/𝑊 (52) For the LNG Tank volume of 160,000 m3,
𝐿𝑁𝐺
𝐵𝑂𝐺×100 23494×100
𝑟5 0.2 2
𝐵𝑂𝐺 𝑅𝑎𝑡𝑒 = = ≈ 0.032% (73)
𝑉𝐿𝑁𝐺 ×𝜌𝐿𝑁𝐺 160000×456.5
𝐵2 = 𝑘 = 90.9 = 0.0022 𝑚 𝐾/𝑊 (53)
9% 𝑁𝑖
From the estimated BOG Rate of 0.032 vol%,
𝑟6 0.6 2
𝐵3 = 𝑘 = 0.045 = 13.34 𝑚 𝐾/𝑊 (54) it is lower than the allowable 0.05 vol%/day.
𝑓𝑜𝑎𝑚
𝑟 0.15 References
𝐵4 = 𝑘 7 = 42.6 = 0.0035 𝑚2 𝐾/𝑊 (55)
𝐶𝑆
1. https://ww2.energy.ca.gov/lng/faq.html
𝑟8 0.6 2
𝐵5 = 𝑘 = 1.8 = 0.3334 𝑚 𝐾/𝑊 (56) 2. “Analysis of boil-off rate problem in
𝑐𝑜𝑛𝑐
𝑟6 0.3
London, Repsol S.A, calle de Mendez
𝐶3 = 𝑘 = 0.038 = 7.8947 𝑚2 𝐾/𝑊 (64) Alvaro, 44, 28045, Madrid, Spain
𝑝𝑒𝑟𝑙𝑖𝑡𝑒
∑ 𝑅3 = 𝐶1 + 𝐶2 + 𝐶3 + 𝐶4 + 𝐶5 (67)
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