Adv PDF

Sri Chaitanya IIT Academy., India.
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Jr. Super60-I (Incoming) Dt: 05-06-17
Time: 07:30 AM to 10:30 AM WTA-6 Max.Marks: 240
Name of the Student: ___________________ H.T. NO:
05-06-17_Jr.Super60-I (Incoming)_WTA-6_(2015-P2)Weekend Syllabus

PHYSICS: Kinematics: Motion in 1D, Uniform motion, uniform accelerated motion,
motion under gravity and related graphs (60%)
Integration & its application, Complete vectors (Introduction to physical quantities
like Position Vectors , displacement Vectors ,Velocity Vector ,acceleraction Vector
and mathematical relation between them) (30%)
Cumulative syllabus covered till now (10%)
CHEMISTRY: Thermodynamics: Terms involved in thermodynamics - System &
Surrounding, Extensive and Intensive Properties, Path and State function, types of
processes,First law of thermodynamics , Reversible and irrevesible processes; Work -
expressions for reversible, irreversible isothermal and adiabatic processes, Heat and
Heat capacity, Thermochemistry: Enthalpy (60%) Gaseous State: Measurable
properties of gases; Gas Laws - Ideal gas equation, Dalton's Law of Partial pressure:
Graham's Law of diffusion, Kinetic theory of gases; Distribution of molecular
velocities; Kinetic energy, Non ideality of gases; vander Waal's equaiton of state,
Compressibility factor; liquifaction of gases & Critical state (30%) Cumulative
syllabus (10%)
MATHS: Measurement of Angles, Trigonometric Ratios & Identities, T- Ratio of
Compound angle, Multiple, sub-multiple angles & some special angles (30%);
Transformation formulae, Conditional Identities, Graphs of Trigonometric Functions,
Periodicity and extreme values (60%); Cumulative(10%)
Sri Chaitanya IIT Academy 05-06-17_Jr.Super60-I (Incoming)_JEE-Adv_(2015_P2)_WTA-6_Q'P
JEE-ADVANCE-2015-P2-Model
Time: 3:00 Hours IMPORTANT INSTRUCTIONS Max Marks: 240
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type 4 0 8 32
Sec – II(Q.N : 9 – 16) Questions with Multiple Correct Choice 4 -2 8 32
Questions with Comprehension Type
Sec – III(Q.N : 17 – 20) 4 -2 4 16
(2 Comprehensions – 2 + 2 = 4Q)
Total 20 80
CHEMISTRY:
Sec – III(Q.N : 37 – 40) 4 -2 4 16
Total 20 80
MATHEMATICS:
Sec – III(Q.N : 57 – 60) 4 -2 4 16
Total 20 80
Jr. Super60-I_ADV space for rough work Page 2
PHYSICS Max Marks: 80
SECTION – I
(INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer, 0 if not attempted and 0 in all other cases.
1. A particle moving in a straight line covers half the distance with speed of 3 m/s. The
other half of the distance is covered in two equal time intervals with speeds of
4.5 m/s and 7.5 m/s, respectively. Find the average speed of the particle during this
motion.
2 A ball is thrown vertically upwards from the foot of a tower. The ball crosses the top
of tower twice after an interval of 4 seconds and the ball reaches ground after 8
seconds from the start, If the height of tower in meters is H, Then the value of [H/10]
will be? (take g = 10 m/s2 )
3 Two men P & Q are standing at corners A & B of square ABCD of side 8 m. They
start moving along the tank with constant speed 2m/s and 10 m/s respectively. The
time when they will meet for the first time, in seconds is -
10 m/s C
B
2 m/s
A D

4 At the moment t = 0, a particle leaves the origin and moves in the positive direction of
the x-axis. Its velocity varies with time as
t
v = v0 1 where v0 = 10 cm/sec. The particle will be at the distance of 10 cm from
5
the origin at three different instants T1 , T2 and T3 [ T3 >T2 >T1 ] .If the value of
X Y
[T3-T2 ] is of the form where X and Y are some numbers and Y< X. then
2
the value of [ X-Y ]/ 10 will be ?
5 An insect moves with a constant speed v from one corner of a room to other corner
which is opposite of the first corner along the largest diagonal of room. If the insect
can not fly and has to crawl on the faces of room and dimensions of room is
4 × 2 × 1m, the minimum time in which the insect can reach the opposite corner by
crawling is T, if máximum posible speed of crawling is 1 m/s for the insect , then the
value of T will be?
6. Consider a straight line passing through two points A and B. Position vectors of point
A and B are given by rA and rB respectively. There is another point C with position
vector rC . If a perpendicular is dropped on the line passing through A and B from the

point C. Then foot of perpendicular on straight line is given by point D with a position
vector rD x0î y0 ˆj z0 kˆ if
rA 4î 7 ˆj kˆ
rB 3î 5 ˆj 3kˆ
rC î 3kˆ
Then the value of x0 z0 y0 will be?
7. A right circular cone with radius R and height H contains a liquid which evaporates at
a rate proportional to its surface area in contact with air (proportionality constant
k > 0). Initially cone is completely filled with liquid. If all the liquid gets evaporated
after a time of T0 . If H 20 , K 5 , then the value of T0 will be?

8. If A, B, C and D are any four points in the space. The value of expression
AB CD BC AD CA BD is N times the area of triangle ABC. Then the value
of N will be?
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
9. Choose the Incorrect options for the situation given below:
For a particle moving along a straight line, the position x depends on time t as
x = t3 + t2 + t + . The ratio of its initial acceleration to its initial velocity depends
-
A) only on and B) only on and
C) only on and D) only on
10 If it is given that the velocity of a body is constant during its motion, then what
predictions can be made based on the information given , here |x| represents the
positive value of x .
A) |Instantaneous Velocity vector| = Instantaneous speed
B) |Average velocity vector| = Instantaneous speed
C) Instantaneous Velocity vector = average velocity vector
D) Instantaneous Speed = average speed

11 A train accelerates in a straight line from rest for time t1, at a constant acceleration
for distance x. Then it decelerates to rest at constant retardation in time t2 for
distance y. Then choose the correct options -
x t x t
A) = B) = 1 C) = 1 D) x = y
y t2 y t2
12 A particle of mass m moves on the x-axis as follows: it starts from rest at t = 0 from the
point x = 0, and comes to rest at t = 1 at the point x = 1. No other information is available
about its motion at intermediate times (0 < t < 1). If denotes the instantaneous
acceleration of the particle, then -
A) cannot remain positive for all t in the interval 0 < t < 1
B) cannot exceed 2 at any point or points in its path
C) must be > 4 at some point or points in its path
D) must change sign during the motion, but no other assertion can be made with the
information given
13 A particle moves in a straight line with an acceleration-time ( a–t )curve shown in
figure. It is given that The particle starts from origin and it is at rest at t=0 i.e. initial
position and velocity are zero . Choose the correct options .

a(m/s2)
4
2 10
0 t(s)
–2
A) The time at which the particle comes to rest again is 10 sec
B) Velocity of particle at t = 2 sec is 8 m/s
C) Distance travelled by particle before coming to rest is almost close/equal
to 29.36 m
D) Displacement of the particle before coming to rest is almost close/equal
to 29.36 m
14 A particle moving in a straight line with an initial velocity v0 and retardation v, where
v is its velocity at any time t and " " is a positive constant with proper dimensions.
Assume this retardation is continuously acting and is defined at all t >0. Then choose the
correct options regarding the situation described above . Assume standard SI units for
all physical quantities if you need .
A) The particle will cover a total distance v0/ approximately.
B) The particle will come to rest after a time 1 /
C) The particle will continue to move for a very long time
D) The velocity of the particle will become v0/2 after a time 1/

15 For a particle moving in straight line .The position (x) of a particle depends on time
(t) as: x = t2 – t3 . Then choose the correct options regarding the motion of the
particle.
A) The particle will return to its starting point after time
B) The particle will come to rest after time 2 /3
C) The initial velocity of the particle was zero but its initial acceleration was not zero.
D) No net force will act on the particle at t = /3
16 At t = 0, a particle is at a point P whose position vector is r = x î + y ĵ + z k̂ and starts
with velocity v = vx î + vy ĵ + vz k̂ . If point O is at r = 0, It is given that the particle is
always moving towards point O, i.e. particle is always moving along the line joining
origin and point P. Then choose the possible combinations of x, y, z, vx, vy, vz for
which particle can always move towards origin O.
vx v y vz vx v v
A) = = B) . y . z <0
x y z x y z
vx vy
C) xvx + yvy + zvz < 0 D) . >0
x y
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
correct.Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 17 & 18
A particle is moving on a regular hexagon of side 'a' with constant speed 'u' as shown
in figure. At each corner there is an agent who is changing the direction of velocity ,
choose the most appropriate answer for the information given .
D
vD vC
E C
vB
F B
vA
A
17 Magnitude of average acceleration between A to B will be? Consider the time instants
for average when particle just leaves A and just crosses B.
3 u2 u2 u2 3 u2
A) B) C) D)
a a 2a 2a
18 Magnitude of average acceleration between A to C will be? Consider the time instants
for average when particle just leaves A and just crosses C.
3 u2 3 u2 u2 2u2
A) B) C) D)
2a a a a
Paragraph for Question Nos. 19 & 20
acceleration “a” of a particle moving in a straight line can be related to velocity v ,
displacement x and time t by the given relation .
d2 x
a =v dv = dv
=
dx dt dt 2
by using the above relation of acceleration we can obtain the expression of different
combinations of a, v, x and t.
19 Acceleration of a particle is given by a = (2x + 1) and at x = 0, v = 0. The velocity of
particle at x = x is -
A) 2x2 + 1 B) x2 + 1 C) 2( x 2 x) D) None of these
20 Acceleration of a particle is given by a = (2v + 1) m/s2 and at t = 0, v = 0. The velocity
of particle at t = t is -
e2 t – 1 e 2t
A) B) C) e2t –1 D) v + 1
2 2

CHEMISTRY Max Marks: 80
SECTION – I
21. How many of the following are state function
Reversible work, Irreversible work, Internal energy (u) , Enthalpy(H), Heat, Entropy
(S), Free energy (G)
22. How many of the following are intensive property
E.M.F of cell, Molarity of Solution, Pressure, Enthalpy, Density of gas, Temperature,
Internal energy
23. In the following P-V diagram what is amount of heat is absorbed (in L atm , in
complete cyclic process) if 1 mole monoatomic gas is taken through the process
4atm
2atm
2L 6L V
24. In a constant volume calorimetry 3.5g of C2 H 4 was burnt in excess of oxygen at 298
K. The temperature of the calorimetry was found to increase from 298 k to 298.9 K
due to the combustion process. Given that the heat capacity of the calorimetry is
2.5 kJ K-1 if the approximate numerical value of heat transfer at constant pressure is
X kJ mol-1 then find the value of (X – 10)
25. Calculate the change in pressure (in atm) when 2 mole of NO and 16 g O2 in a 6.25
litre originally at 27°C react to produce the maximum quantity of NO2 possible
according to the equation
2NO(g) + O2 (g) 2NO2 (g)
1
(Take R lt atm/mol K)
12
26.
air Patm 76cm of Hg
10 cm
19 cm of Hg
If above tube is held vertically with open end upward then what is the length (in cm)
of air column Temperature is constant.

27. Calculate work done in chemical reaction (in kcal)
A(s) + 3B(g) C(l) at 227ºC at 1 atm in closed vessel (volume changes).
28. An ideal gas is going under adiabatic free expansion process from state 1 to state 2
then how many of the following is/ are ture
(i) q =0 (ii) W= 0 (iii) u 0 (iv) H 0
1 1
(v) T1 T2 (vi) TV
1 1 T2V2 (vii) T2 T1
SECTION – II
29. An ideal gas is taken through following process, If symbols have usual meaning
then which is/are true relation(s)
A) u1 3 u1 2 u2 3 B) W1 3 W1 2 W2 3
C) W1 2 3 W1 2 W2 3 D) H1 3 H1 2 H2 3

30. 1 mole H 2O s is converted to H 2O l at 1 bar pressure and constant temperature of
00C, by supplying heat, then which is/are NOT true
A) W=0 B) u 0
C) H 0 D) Change in K.E. of water molecules 0
31. In which of the following cases standard enthalpy of formation is zero at 25

A) Na(s) B) Cl2(g)
C) Br2(g) D) C (Diamond)
32. According to the kinetic theory of gases.
A) the pressure exerted by a gas increases with the incrcease in mean square speed of
the molecules.
B) the pressure exerted by a gas increases with the incrcease in root mean square
speed of the molecules
C) the root mean square speed is inversely proportional to the temperature.
D) the mean translational kinetic energy of the molecule is directly proportional to

the absolute temperature.

33. Select correct statement(s):
A) we can condense vapour simply by applying pressure
B) to liquify a gas one must lower the temperature (lesser than or equal to Tc) and
also apply pressure
C) at Tc, there is no distinction between liquid and vapour state, hence density of the
liquid is nearly equal to density of the vapour
D) Liquification of gas is possible below Boyle’s temperature
34. Which is/are true when 1 mole of an ideal gas is taken from the process 1 3
P
T2 T
A) W1 = - RT2 ln P2/P3
B) Process involves isochoric process followed by isothermal process
C) Process involves isobaric process, followed by isothermal process
D) During 1 2 heating takes place and then temperature is constant

35. Which of the following is/are correct ?
A) H U (PV) when P and V both changes
B) H U P V when volume is constant
C) H U V P when volume is constant
D) H U for the reaction 2HI(g) H2(g) + I2(g)
36. One mole of an ideal gas Cvm 5 2 R at 300 K and 5atm is expanded adiabatically to
a final pressure of 2 atm against a constant pressure of 2atm. Then which is/are true
A) Final temperature of the gas is approx 251.4K
B) Final temperature of the gas is 270 K
C) PV
1 1 P2V2 is valid for the process
D) If the process is carried out in infinite steps then final temperature will be less than
the temperature observed is above process

SECTION – III
(PARAGRAPH TYPE)
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
correct.Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
Paragraph for Question Nos. 37 to 38
A gas expand from (10 atm, 3dm3 ) to (6atm, 5dm3 ) against a constant pressure of
3atm isothermally, the work done during the expansion process is used to heat 10
mole of water at temperature 290K. (Specific heat of water = 4.2J g-1 k-1)
1 Latm 101.3 J
37. Which is/are true for the above gas expansion process
A) H 0 B) u 0 C) W 607.85 J D) W 1215.6 J
38. Which is/are true for the above processes

A) Final temperature of water is approximately 290.81 k
B) Final temperature of water is approximately 296.3 k
C) If above gas expansion is carried out reversibly then magnitude of work is more
D) If above gas expansion is carried out reversible then magnitude of work is less
A gas undergoes dissociation as A4 (g) 4A (g) in a closed rigid container having
volume 22.4 litres at constant temperature of 273 K. The initial moles of A4 taken
before dissociation is 1. Molecular diameter of A4 is 3 times of A, then
39. Identify true statement (s) (assume ideal behavior of the gas)
A) The total pressure (in atm) after 50% completion of the reaction
(assuming ideal behaviour) is 2.5atm
B) R.M.S speed of A4 is less than R.M.S speed of A
C) Mean free path of A4 and A are same
D) Average translational kinetic energy of molecules before and after dissociation of
A4 is same
40. If the gases are not ideal & at the beginning total pressure observed is less than 1 atm
before dissociation and total pressure after 100% dissociation is found to be more
than 4 atm, then (assume all other parameters to be same )
A) compressibility factor of A4 > 1
B) compressibility factor of A4 < 1
C) Repulsive force dominates in A under this condition
D) compressibility factor of A > 1

MATHS Max Marks: 80
SECTION – I
2
41. If , then the value of tan tan 2 tan 2 tan 4 tan 4 tan is k, where k
7
1 1
42. If 2sin cos where n ,n Z 3 ___
2sin 2 1 2sin 2 1
43. If m sin cos tan cot sec cos ec and
n sin cos tan cot sec cos ec
Then (for acute ) m n 2 m n ____
44. If tan 11.25o n 2 2 1 2 where n N , then n = ___
1
2 4 8
45. 7 sin sin sin __
7 7 7
2 a 2
46. If tan 250 4sin 250 , then a = .......
6 2 2

2 4 5 7 8
47. Sin2 sin 2 sin 2 sin 2 sin 2 sin 2 = ………
18 18 18 18 18 18
48. If 3 sinx 12 cosy 15 sinz 5 siny 4 cosx 8 cosz 35 then

sinx coty 8 tanz 12
SECTION – II
49. sin 3 cos 6 x x 2 11, 0 4 , x R holds for
A) no values of x and
B) One value of x and two values of
C) Two values of x and two values of
D) Two pairs of values of ( x, )
50. Let f n ( ) tan (1 sec )(1 sec 2 )...(1 sec 2 n ) , then R

2
A) f 2 1 B) f3 1
16 32
C) f 4 1 D) f5 1
64 128

51. If x sec tan and y cosec cot then R
y 1 y 1 1 x
A) x B) x C) y D) xy x y 1 0
y 1 y 1 1 x
3
52. If cos cos cos then , , R
2
A) cos 0 B) sin 0
C) cos sin 0 D) cos sin 0
53. Which of the following is false?

A) 3 tan10o 4sin10o 2 B) tan 20o 4sin 20o 3
C) sec 40o 3 cos ec 40 o 4 D) 3 1 tan 5o 4 2 sin 5o 3
6 4 2
cos 6cos15cos 10
54. If 5 5 5
3
1 5cos 10 cos
5 5
24 16 8
cos 6 cos
15cos 10
5 5 5 then
12 4
1 5cos 10cos
5 5
5 1 5 1
A) B) C) D)
2 4

cos 7 x cos8 x
55. If cos ax cos bx , where a, b are positive integers, then x R
1 2cos 5 x
A) a2 + b2 = 13 B) a2 – b 2 = 5 C) a + b = 5 D) |a – b| = 1
56. The system of equations sinx cosy = a2 and siny cosx = a has a solution x, y R ,
if a =
2 2 1 1
A) B) C) D)
5 1 5 1 5 1 5 1
SECTION – III
(PARAGRAPH TYPE)
Paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONE OR MORE is/are
Correct. Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
3 5
If cos , cos , cos are the roots of the equation 8 x3 4 x 2 4 x 1 0
7 7 7
3 5
57. The equation whose roots are tan 2 , tan 2 , tan 2 is
7 7 7
A) x 3 35 x 2 7 x 21 0 B) x 3 35 x 2 21x 7 0
C) x 3 21x 2 35 x 7 0 D) x 3 21x 2 7 x 35 0
3 2r 1 3 2r 1
58. The value of tan 2 cot 2 is
r 1 7 r 1 7
A) 15 B) 105 C) 21 D) 147
0 0 0
1 1 1
To find the values of trigonometric functions w.r.to angles 7 ,82 ,90 , 27 0 ,52
2 2 2
A A A A
etc… use the results 1 sin A cos sin , 1 sin A cos sin
2 2 2 2
cos ec2 A cot 2 A tan A , cos ec2 A cot 2 A cot A

0
59. The values of 4 sin 27 =
A) 5 5 3 5 B) 5 5 3 5
C) 5 5 3 5 D) None
0
1
60. The values of 4 cos 360 cot 7 =
2
A) 6 3 4 2 1 5
B) 1 2 3 4 5 6
C) 1 2 3 4 5 6
D) 6 1 5 2 3 2

Sri Chaitanya IIT Academy., India.
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Jr. Super60-I (Incoming) 2015-P2 Dt: 05-06-17
Time: 07:30 AM to 10:30 AM WTA-6 Max.Marks: 240
KEY SHEET
PHYSICS
1 4 2 6 3 3 4 8 5 5
6 5 7 4 8 4 9 ACD 10 ABCD
11 ABC 12 AC 13 ABCD 14 AC 15 ABCD
16 ABCD 17 B 18 A 19 C 20 A
CHEMISTRY
21 4 22 5 23 8 24 8 25 2
26 8 27 3 28 5 29 ACD 30 ABC
31 AB 32 ABD 33 ABC 34 ABD 35 AC
36 AD 37 ABC 38 AC 39 ABD 40 BCD
MATHS
41 7 42 2 43 8 44 4 45 2
46 6 47 3 48 6 49 BD 50 ABCD
51 BCD 52 ABD 53 ABCD 54 BC 55 ACD
56 ABCD 57 C 58 B 59 B 60 C
Sri Chaitanya IIT Academy 05-06-17_Jr.Super60-I(Incoming)_JEE-Adv_(2015_P2)_WTA-6_Key&Sol’s
SOLUTIONS
PHYSICS
2 v 0 ( v1 v 2 )
1. vavg =
2 v 0 v1 v 2
2 3(4.5 7.5)
= m/s
6 4.5 7.5
6 12
= m / s = 4m/s
18
2. h = ut – 1 gt2
2
or gt2 – 2ut + 2h = 0
2h 2u
t1t2 = and t1 + t2 = =T
g g
(t2 – t1)2 = (t1 + t2)2 – 4t1t2

2h
16 = 64 – 4 × h = 60 m
g
3.
dx v0 t
4. = v0 –
dt 5
2
x= v0t – v 0 t
10
where x can be either +10 or –10.
10 60
10t – t2 = 10 t=
2
2 10 140
10t – t = –10 t=
2
10 60
for 2nd event, t =
2
rd 10 140
and for 3 event, t =
2
5.
6.
H
7. T0 4
K
8. N=4
9.
x = t3 + t2 + t +
v = dx = 3 t2 + 2 t +
dt
(vini)t = 0 =
dv
a= =6 t+2
dt
(aini)t = 0 = 2
Jr. Super60-I_Advanced Page 2

a ini 2
= =
v ini
10.
11.
12. consider v-t graph and apply condition of area and slope .
13. Area under a-t curve :
v = Area 1 = 2 × 4 = 8
v–u=8
v = u + 8 = 0 + 8 = 8 m/s
1
v – v = Area 2 = 8 2 = – 8 m/s
2
v =v–8=8–8=0
final velocity is zero at t = 10 sec
14
S = 0 + 8 [10 – 1] + ( 8) 10
3
16
=8×9+ 8
3
16
=8 9
3
11
=8×
3
= 8 × 3.666
= 8 × 3.67
S = 29.36 m
dv
14. v = – v
dx
0 x0
or v0
dv
0
dx
or x0 = v0/
dv v dv t
=– v or dt
dt v0 v 0
or v = v0 e– v = 0 for t
15. x = t2 – t3
for x = 0, t2 – t3 = 0
t= .
dx
= 2 t – 3 t2
dt
Particle at rest v = 0

2
2 t–3 t =0
2
t=
3
d2x
=2 –6 t
dt 2
at t = 0 a=2 , at t = 0, v = 0
for no net force, (a = 0)
2 – 6 t = 0, t= .
3
16. If body is always moving towards origin then,

v is antiparallel to r .
17.
18.
19. a = 2x + 1
dv
v = 2x + 1]
dx
v dv = ( 2 x 1 ) dx
v2
= x2 + x
2
v2 = 2(x2 + x)
v= 2( x 2 x )
20. a = (2v + 1)
dv
= 2v + 1
dt
v t
dv
= dt
2v 1
0 0
1
log (2v + 1) = t
2
log (2v + 1) = 2t
2v + 1 = e2t ; v = (e2t –1)/2
CHEMISTRY
21. All type of work and heat is path function.
23. Work = Area
= -8 L atm
As u 0 , cyclic process

q=-w =8 L atm
25. 2NO(g) +O2 (g) 2NO2 (g)
moles 2 0.5 0
2 – 2 × 0.5 0 2 × 0.5
26. P1=76 cm, V1= 10×A
P2= (76+19)=95 cm
V2=?
P1V1=P2V 2
76×10=95×x
x=8cm
3 2 500
27. W= ngRT 3
1000
28. In adiabatic process q =0

For free expansion, Pext = 0
W Pext dv 0
From Ist Law u 0
H 0
T1 T2
30. H 2O s H 2O e
S v 0 S H2 O e S H2O s
Hence W 0
Heat given to the system is used to increase potential energy
u H 0
K.E. of molecules remain same
36. q=0, it is irreversible adiabatic process hence PVr = constant is not valid
- Pext (V2-V1) = n ncv T2 T1
nRT2 nRT1 5
- Pext n R T2 T1
P2 P1 2
T2 300 5
- 2 T2 300
2 5 2

600 5
T2 T2 750
5 2
7T2 650
750
2 5
= 880
1760
T2 251.4 K
7
37. W =-Pext (V 2-V1)
= -3(5-3)
=-6 atm
=-6 101.3 = -607.8J
As process is isothermal hence
u H 0
W nC T
607.8 10 4.2 18 T
T 0.8
Tf 290.8 K
In reversible expansion work done by the gas is more than irreversible expansion
MATHS
41. cos A B C cos A cos B cos C 1 TanATanB
put A ,B 2 ,C 4
2 sin 2 sin 2 2
42. 3
4sin 2 sin 2 2 sin 2 sin 2 1
8sin 2 2
3 2 2
4 sin sin 8sin 2 1
6 4sin 2 1
2 2
2
20sin 4 8sin 1
sin cos 1
43. m n 2 2 sin cos 1 ,m n 2
sin cos
1 2sin cos 1
m n 2 m n 4 8
sin cos

44. cos ec 2 cot 2 Tan
2 4 8 1 2 4 8
45. Put x cos cos cos , y sin sin sin
7 7 7 2 7 7 7
7
x2 y2 2 y
2
2
46. 2 sin150
6 2
2sin150 cos 250 4sin 250 cos 250 cos10 0 cos 400 2sin 50 0
= 2 cos150
cos 250 cos 250
47. Sin 2 cos 2 1
48. 4 cos x 3sin x 12 cos y 5sin y 15sin z 8cos z 35
4 cos x 3sin x 5,12cos y 5sin y 13 and 15sin z 8 cos z 17
3 12 15
cos x , cot y , tan z
5 5 8
2
49. 2sin 2 x 3
3
3 7
x 3, ,
3 2 2
sin 2n
50. cos cos 2 cos 22 cos 2 n 1
fn Tan 2n
2 n sin
51. Conceptual
3 2 2
52. cos cos sin 0
2
cos 0 & sin 0
53. Conceptual
6 4 2
54. cos 6 cos 15cos 10 2 cos cos 5 2 cos 3 cos 10 2 cos 2
5 5 5 5 5 5 5
3
2 cos 1 5cos 10cos
5 5 5
5 1
2 cos
5 2
4
Similarly, 2 cos 2 cos
5 5

15 x x 15 x 5x x
2sin sin 2sin sin sin
55. 2 2 = 2 2 2
2 5x 15 x
1 2 1 2sin sin
2 2
cos 2 x cos3 x
56. sin x y a 2 a , sin x y a2 a
1 a 2 a 1& 1 a 2 a 1
1 5 5 1
a
2 2
1 1
57,58. Put y 1 x
x2 y 1
8 x3 4 x 2 4 x 1 0 y 3 21y 2 35 y 7 0
59, 60. Conceptual

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Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

Name of the Student: ___________________ H.T. NO:

05-06-17_Jr.Super60-I (Incoming)_WTA-6_(2015-P2)Weekend Syllabus

Jr. Super60-I_ADV space for rough work Page 3

Jr. Super60-I_ADV space for rough work Page 4

Then the value of x0 z0 y0 will be?

Jr. Super60-I_ADV space for rough work Page 5

Jr. Super60-I_ADV space for rough work Page 6

C) must be > 4 at some point or points in its path

13 A particle moves in a straight line with an acceleration-time ( a–t )curve shown in

position and velocity are zero . Choose the correct options .

Jr. Super60-I_ADV space for rough work Page 8

16 At t = 0, a particle is at a point P whose position vector is r = x î + y ĵ + z k̂ and starts

with velocity v = vx î + vy ĵ + vz k̂ . If point O is at r = 0, It is given that the particle is

which particle can always move towards origin O.

Jr. Super60-I_ADV space for rough work Page 11

air Patm 76cm of Hg

Jr. Super60-I_ADV space for rough work Page 13

Jr. Super60-I_ADV space for rough work Page 14

00C, by supplying heat, then which is/are NOT true

C) H 0 D) Change in K.E. of water molecules 0

31. In which of the following cases standard enthalpy of formation is zero at 25

speed of the molecules

C) the root mean square speed is inversely proportional to the temperature.

D) the mean translational kinetic energy of the molecule is directly proportional to

Jr. Super60-I_ADV space for rough work Page 15

Jr. Super60-I_ADV space for rough work Page 16

A) H U (PV) when P and V both changes

B) H U P V when volume is constant

C) H U V P when volume is constant

D) H U for the reaction 2HI(g) H2(g) + I2(g)

A) Final temperature of the gas is approx 251.4K

B) Final temperature of the gas is 270 K

the temperature observed is above process

Jr. Super60-I_ADV space for rough work Page 17

38. Which is/are true for the above processes

B) Final temperature of water is approximately 296.3 k

Jr. Super60-I_ADV space for rough work Page 19

43. If m sin cos tan cot sec cos ec and

n sin cos tan cot sec cos ec

Then (for acute ) m n 2 m n ____

44. If tan 11.25o n 2 2 1 2 where n N , then n = ___

Jr. Super60-I_ADV space for rough work Page 20

48. If 3 sinx 12 cosy 15 sinz 5 siny 4 cosx 8 cosz 35 then

50. Let f n ( ) tan (1 sec )(1 sec 2 )...(1 sec 2 n ) , then R

Jr. Super60-I_ADV space for rough work Page 21

C) cos sin 0 D) cos sin 0

53. Which of the following is false?

C) sec 40o 3 cos ec 40 o 4 D) 3 1 tan 5o 4 2 sin 5o 3

Jr. Super60-I_ADV space for rough work Page 22

cos ec2 A cot 2 A tan A , cos ec2 A cot 2 A cot A

Jr. Super60-I_ADV space for rough work Page 24

11 ABC 12 AC 13 ABCD 14 AC 15 ABCD

31 AB 32 ABD 33 ABC 34 ABD 35 AC

36 AD 37 ABC 38 AC 39 ABD 40 BCD

51 BCD 52 ABD 53 ABCD 54 BC 55 ACD

(t2 – t1)2 = (t1 + t2)2 – 4t1t2

Jr. Super60-I_Advanced Page 2

Jr. Super60-I_Advanced Page 3

16. If body is always moving towards origin then,

Jr. Super60-I_Advanced Page 4

28. In adiabatic process q =0