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IN

Code No. : SY 17

HIGHER SECONDARY
FIRST TERMINAL SECOND YEAR EXAMINATION .2018.2019
CHEMISTRY
Maximum : 60 scores
Time: 2 Hours
HSE II Cool offtime : 15 minutes

General Instructions to Candidates:

. There is a'Cool off time' of 15 minutes in addition to the writing time.
. Use the 'Cool off time' to get familiar with questions and to plan your answers,
. Read the instructions carefully
, Read questions carefully before answering
. Calculations, figures and graphs should be shown in the answer sheet itself.
, Malayalam version of the questions is also provided.
. Giye equations whereyer necessary.
c Electronic devices except non-Programmqble calculators are not allowed in the examination hall.
oilapdrnrfladeoeqs o"rmefiildcnoflBd
. nflrdg?,ab qul@ara?(f .U080 15 Dloilg a,And 6n"n" aaso pornta?a?eoJo.
. al1d at,a'6)aso E-ztJBJ6oh0d
"Jallet@)o"15JaJo Qa0rd6aBd
opoq60ano aatQJaJo ooJe@t(t?aa3a.
. rfldelna,Bnd q%uod UauJoJedqo utat?aemno
o par0o6dBrrd .gv3rostrrna?rn" ryni eefiDJfrDtrd pruufirxo u3a'la6tono.
. a,ffi)ao" a,J1e$a,d, -oil\afinBnd, p)onee,(fi
"g)nD?ot
poraa8"J"101d roarm garlafia?anno.
o 8.atJBJ60Brfi ouangara?ago rnada?algpti.
. @DAtnaJDe@ fiMercm" @0afia'J60u(d aaJSJaaflno.
. EtaJS[oJ^la'cd ae]qlma,Jon a,Jolaaeeeq1ea'fid 5tg?oa'@)e@ aa3 gua'"eptatfla'" g"Le'aonuSo
a1 ea uo ry? od g e an oil aa j u t nd tsl g.
"L "L "L

Question 1 to 5 carry 1 score each. 1 aaooE 5 ooG ofirjlgeEE! ooell callBJfi,Bu0ao3o

Answer all the question. (5r1:5) gorocos93o3o,. crc6rfirilmSo 1 0ut6lr0 oikoro
(5x1:5)
1. From the following solid which is 1. ofirflS3@ oroofiu"oe€oglo8 onlelougleflolo
amorphous ? .{fO?
(Sodium Chloride, diamond, metals, G ow rui a o s & Jo ao ru; alfio, E Et J 6oD od,
"o
glass) oti.lS?e'o)

2. Which of the following concentration 2. ornrflggqororloE nlrm3 olnroro)lo0 nulrol

term is independent of temperature. nileoonrsoorol olnigoo o fiD3oil.rfloo3m
olB€aO?
(Mo I arity, Mas s /Vo lume p erc ent age,
Vo lume p erc ent age, Mo I ality)
( o o J0 J
w7 ufi "J"a) od (D o J a o,
01 p?, o J

afl "J'a) 0d @) 0 ) (D o, A g J g J eil p?)

J. Molecularity of the reaction 3. 2NO+O2---+2NOr.,.0(m [dOflL.rCXdOOmOolOfi0
2NO+Or-+2NOris € a r Eil qJ a el] G] 91 ol c ern

HSE II CHEMISTRY - 1i4

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t Give an example for 4 eDe6r oilcralur'lo el€ glarrurfii

Lyophobic Colloid. 6,Ce pBloOCSmo n{}t9J{0)JO.

)
_is a synthetic Zeolite used for 5 GDo86o€"oog3e,o g oJloruleilmoaeil algco0
convefting alcohols to gasoline. porcorrjl€oAm 6,Jtoil a mleotcooer gl6rn" . .....

uestion 6 to 19 carry 2 score each. 6 seooil 19 ooo Get)BJ61,r,oA€o"2 rD"Gorlr0 oflnDo

nswerjllJlf,L questions "
(11 x2.=22) ogi o o a,l er eo I -ot I fi ,r, d oo" o om 6 o s I (,)3 6.
1 G BJ
e

(11x2--22)
) State Henry's law and give two important 6. o.ofiill rnlolao Lolffu"otoilooaor, p9 fiiloa
application? maoo0 Lol0tm Lotcolo60BEJo o{r9lr0'rJor?
Sea water freezes at lower temperature
7. o,so0, seto, €rruln16dl4 uerom'lcofloilcm
than distilled water but boils at higher €old olle"m ol.lnilelaroE otmleojl€oAm3.
temperature. Give reason. opmlo0 Ooldm ol"lfiilelaro8 oilgor"eer3
o,a)lo ootQJflDJ oJr?5l'Do oiloaoaceer36j.
If 30ml of 0.5M H2SO4 solution is 8. 30m10.5M csogtd H2SO4 enoffiloa)
diluted to 500m1. Calculate the molarity 500 ml €er€o" €mddil6o3maorlr61o8.
of new solution? orAoAolol errfl 4 ercornfl a)Aos ootElcll0l
Or6m€OOOO36i.
I l"'m forNaCl, HCl, CH3 COONa are 9. NaCl, HCl, CIt COONa ooffrfloto3os L.m
126.4,425.9 and 91.0 Scm2 mol-r zJelo ()lOSlOrOo 126.4,425.9, 91.0
respectively. Calculate ).om for Scm2 moli G06rn". .,08100 CH, COOH ocrfl
cH3 cooH L"m OJe[o Or6mO0]€OeOJ.
0. State Faraday's laws of electrolysis. 10. oorG€oDla)eos ooorueooil€mos6fn niloz
on r0 1a au"o'noil€oeo,.
1. Write electrode reactions and cell 11. Al lAP. ll C"" I Cu oe0D ocrueiloel
reaction of the cell? p er6L€lrui LdoilLd ol dolo(n 6o8plo,
A1 lAl3. ll Cu2* | Cu orruodL.lojlL.lotr0oomot3o o093CI')36.
2. Differentiate between order and 12. 6lrdruJd, €alg|€oeeltolgl .,grnrilcuor3os
molecularity? {xJ0lJlclUo r'0) 9eO3O,?
3. Inversion ofcane sugar is a pseudo first 13. oo1mfl00 ol6ruurulcol3os Loloil€enaoo EGJ
order reaction. Give reason? orors 5l0Dlo Slldaxd LoJojlt Jcxdo0mal6rn"
€:3G6rDo Oiltranareer3e.
4. Derive the relation between rate constant 14. or3qjo sldeDd pofll"rcldruolmoroloofl
and halflife period ofzero order
njloeo" rru.o1ooe ot3o, ond nucot3 p3o
reaction? orol er3@ 6Dl filJJo cuJAoildlrrdfl a6);.a,?
5. What is the order of decomposition of 'l 5. sJlglmo po0e6oe,oroiloofl 1.rtoletoluiler3gg
ammonia on the surface of platinum Gn €ar6niloo3os oil.s smorcrloo0 dltdaud
catalyst? Give another example having o0)0or6rn? p€o cld0lJ0'lel3@ ao0lo3
the same order ? pBSoOG6[Do o09e(o36r.
6. What is the difference between 16. cDur€@l.,g6rno, Gl'601td5[Do po] o2a'let3@
adsorption and absorption? Give one o!CI)JJCrUo 5ltGGl gBto0(affi0 (}l1oo
"00o?
example for each n09e(0)36.
7. Explain the selectivity of catalyst using 17. po0€L"rco,6Tr3g3o5 oc5rnlo'Doro
examples ? pB3oo c6rn60Br0 p lcoDallef oiloa n aceo3e. a

t SEII CHEMISTRY - 2/4

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18. a) Arrange the following ions according 18. .,0)) ornrlggq GtaGot36rn3€rog Gnoa)Aos
to the increasing order of efficiency of me,g2OOSOS
rfU"O, m GD €Glo06rn LO,q OOIOE
coagulation ?
16,01O,Cl€O3O,?
cl-, Po43-' SOor- cl-, Po43- SOor-
'
b) Give the name of the rule related to onll) a3egloer L6rsloro6rnoA0ta, 6rxfiuoo55
above arrangement. nilora omrloofl €oJrd' a0pAoa6,.
19. Illustrate the role of depressant in froth 19. oJo?Jotm [olotdommoo]o0 arnlecoleg3ers
floatation method ? udmo gnlooocm cru"rilolo oilooaceer3e
.z

20 to 28 carry 3 score each. 20 0AooA 28 ooo srJlBJd,r,u06o" a3nri nutelr0 ofloro

swer aELZ questions. (7 x 3:21) o0t o o 8,1 et e o7 G -er I BJ fi ,r, d 60" O onD o o a 9 oa6.
A

(7x3:21)
20. Explain the reasons for the following. 20. rolnrilg3ggorol3os 6rloom60nnd ojloanaleo3e.
a) White ZnO becomes yellow on .{r) oorp3om ZnO-am dAst€oesffxls0
heating (2 score) 2 6100) ffilo oojlellora rm3 (2 score)

b) FeO is non stoichiometric and has onil) FeO Glm cra fiDa16,c6rDq1 oloaloi olo0
approximate composition Fe., OnOilOfrfl dCIO,€B(o .€tSO,lmAo_DOo Feo.rrO
nrO
(l score)
r,.Qml5fn". Q score)
).1. An element rvith molarmass 21. o')ollol"-ilflruo2.7 x 10rkg mol-1 gge ao3
2.1 x 70-2 kg mol-r form a cubic unit cell 0Jet6ro, Cuooomloofl mlgo 405pm croa)]$@
with edge length 405 pm. If its density oo3 e.13onflei oA6nilQ onuoE p6rBt6oerme.
is 2.7 x lOrkg m 3. What is the nature of potlofiA rutLmo 2.7 xl}3kgmr onem". pe
cubic unit cell. olA6n lQ' o nuo0 o{ro3 ocoruilele@rocoil o1eo3o.
t2. Derive the edge length, radius relation of 22. b.c.c. .ersmoeos otooloofl mlgo3o, Grg{aotJo
b.c.c. structure. olza'let3 gq 6Dl fiuJo oUoE.slol.riloo3e,.

,,3.
Explain the following concentration 23. ornrjlse@ olQleoou fiDe4il.rfl€oacm olBso.Bd
tems. oilaaoaceer3e.
a) molarity b) molality
"0t)
ootgta?p? millaotgtei)p?
c) molefi'action rnil eslodB?(mo

4. a) State Raoult's Law (l score) 24. "g))oocd nilaurno bJou"@Jjlaoea e score)

b) The value of Vant Hoff factor ' i ' for 6DiD KCI a@ aa?at etJ@)(D?@Jas ul(t{
aqueous KCI solution is close to 2, while ,
&,nJaO" aA\1A,OrO?A1fl, i 01U10 2_ nf
the value of i' for ethanoic acid in @td 5 J (ffiu o, a0 (m J al a 6Dt 0d @1 (D7 a el
benzene is nearly 0.5. Give reason. a0nea7@?o6)" apmt?ol eLtaxtfla4as, i ,

(2 score) zJetJo 0. 5 - rn" onstr aa3oJ6fi): e,Jo6mo

ai)aootaaSe. (2 score)
)s Explain the working of lead storage
25. oelad nu"€0tcos" 6rxl0rjloeos Ldodoomo
battery.
oflrranoceer3e.

,1, What is Tyndall effect ? Write two 26. 1s1o0cu.lo0 [oJlBJoJo opm]oE
"00o?
conditions to takeplace Tyndall effect. 1s1o0ru;roE lnJeJoto mloJsloo3moilm3 gg oeni
CruJo0 -ol GJ6TBtr0 .,gr U3Ol3e.

CHEMISTRY- 3/4
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27. a) Discuss the effect of pressure and 27. n0) otJ(u)e,6oBgJas anoJildan6o?gleU@
temperature on the adsorption of gases @D o? e @.s 6n nra? al o d g aa? m S o a l.L aa? n 3

on solids. (2 score) 2J@ fiufiu1(no ad4 aeJqJa? Q score)

b) What is Freundlich absorption mil) t nod etl+f 6nats@,.,sdn
isotherm (1 score) @0@)Ji) .0mJ(0d ,{)0a)" ? 0 score)

28. Explain leaching of alumina from 28. cmxldoonuglu0 nilrm3o cnelao'lmo3os

bauxite ? eI 4fl sun" oil oa o a reo3e.

Question 29 to 32 carry 4 score each. 29 aAooE 32 (xoo c-cDBJfi,r,ud€o"a rru"celd oflroo

Answer an5[ questions. (3x4-12) .,{P O O e,'l er3 o 3 C ri l BJ fi'ri u0 €6t- o om o o a I e o e o,,
(3x4-12)
29. a) Explain the conductance of solids 29.,,0 godwwsa,gps@nslru-0)(notalad
based on energy bands (3 score) a.t a oJ H d (0)n 600 g J a 5 eJ J eb a) ail aa B il eo J o,

(3 score)
b) What is n-type semiconductors
nLl)n - oasd @ndru dJeJe,6[B(Jd ,,g(n)@d
(1 score) mrnn"
-

30. What is corrosion? Explain the ( I .scrn'e t

mechanism of rusting of iron? 30 €elln0mlUamo o$r0i)lOE

"QfiO?
D cA fix oa GAmjlooAonroiloofl 1e1oroL1 uI
31. a) Reaction of molecularity greater than oLlmozleo3e
three are rare. Give reasons ?(l score) 31. .O) Dl(ml@d e,lsJ@@d BDJgileoeeficlplol@
to-t o)l bJ oJ d ora a 608 0d ot og iltn". 6 ) G 6rD o
b) The rate constant ofa reaction at "09Jop (1 scorel

500k and 700 k are 0.025-1 and 0.07S-t nfl aq bJoi)1.-tordoroaanl6)(fi 500k rnleqo
respectively. Calculate the values of Ea 700 k alaSo g@ (rilao6)" runlatp,anrfi
andA (3 score) @)a)(aDo 0.02s t plo 0.07s-r glo @D6n".
g e bJ a)l bJ oJ d aa n orofl a @ E a opLl a S o
A otrqc,ltro 66iD€ol€0eo. (3 score)

32. a) Explain calcination and roasting with

suitable examples (2 score) 32. n0) e,Jadruleansod, s0tfiu"pl6ot" aT(mloJoa)
. n a s aD gJ E J @ dn o
@a I Bt on G 0u
"(fl
a) ot? (,0 B

b) Explain Hall - Heroult nro..r, ZJAOJA, Q scorel

',,,, (2 score) niT .olcd - oooeil(rd7" toJ@)a)
ai)nnorca3e. (2 score)

Iri

HSE II CHEMISTRY - 4i4