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P R A C T I C E T E S T
When properly balanced, the equation indicates that ___ mole(s) of O2 are required for
each mole of CH3CHO.
a) 1 c) 2.5
b) 2 d) 3
When properly balanced, the equation indicates that ___ moles of O2 are required for each
mole of C3H8.
a) 3 b) 3.5 c) 5 d) 8
5. What is the total mass of products formed when 16 grams of CH4 is burned with excess
oxygen?
a) 80 g c) 36 g
b) 44 g d) 32 g
6. Calculate the mass of hydrogen formed when 25 g of aluminum reacts with excess
hydrochloric acid.
2Al + 6HCl → 2 AlCl3 + 3 H2
7. How many grams of the mixed oxide, Fe3O4, are formed when 6.00 g of O2 react with Fe
according to
3Fe + 2O2 → Fe3O4
a) 43.4 c) 174
b) 86.8 d) 21.7
9. How many grams of nitric acid, HNO3, can be prepared from the reaction of 92.0 g of NO2
with 36.0 g H2O?
3NO2 + H2O → 2HNO3 + NO
a) 64 c) 84
b) 76 d) 116
11. How many grams of H2O will be formed when 16.0 g H2 is allowed to react with 16.0 g
O2 according to
2H2 + O2 → 2H2O?
a) 18.0 g c) 9.00 g
b) 144 g d) 32.0 g
12. When 8.00 g of H2 reacts with 32.0 g of O2 in an explosion, 2H2 + O2 → 2H2O, the final
gas mixture will contain:
a) H2, H2O, and O2 c) O2 and H2O only
b) H2 and H2O only d) H2 and O2 only
13. 1.056 g of metal carbonate, containing an unknown metal, M, were heated to give the metal
oxide and 0.376 g CO2.
MCO3(s) + heat → MO(s) + CO2(g)
What is the identity of the metal M?
a) Mg c) Zn
b) Cu d) Ba
When properly balanced, the equation indicates that ___ mole(s) of O2 are required for
each mole of CH3CHO.
a) 1 c) 2.5
b) 2 d) 3
When properly balanced, the equation indicates that ___ moles of O2 are required for each
mole of C3H8.
a) 3 b) 3.5 c) 5 d) 8
5. What is the total mass of products formed when 16 grams of CH4 is burned with excess
oxygen?
a) 80 g c) 36 g
b) 44 g d) 32 g
6. Calculate the mass of hydrogen formed when 25 g of aluminum reacts with excess
hydrochloric acid.
2Al + 6HCl → 2 AlCl3 + 3 H2
7. How many grams of the mixed oxide, Fe3O4, are formed when 6.00 g of O2 react with Fe
according to
3Fe + 2O2 → Fe3O4
a) 43.4 c) 174
b) 86.8 d) 21.7
9. How many grams of nitric acid, HNO3, can be prepared from the reaction of 92.0 g of NO2
with 36.0 g H2O?
3NO2 + H2O → 2HNO3 + NO
a) 64 c) 84
b) 76 d) 116
11. How many grams of H2O will be formed when 16.0 g H2 is allowed to react with 16.0 g
O2 according to
2H2 + O2 → 2H2O?
a) 18.0 g c) 9.00 g
b) 144 g d) 32.0 g
12. When 8.00 g of H2 reacts with 32.0 g of O2 in an explosion, 2H2 + O2 → 2H2O, the final
gas mixture will contain:
a) H2, H2O, and O2 c) O2 and H2O only
b) H2 and H2O only d) H2 and O2 only
13. 1.056 g of metal carbonate, containing an unknown metal, M, were heated to give the metal
oxide and 0.376 g CO2.
MCO3(s) + heat → MO(s) + CO2(g)
What is the identity of the metal M?
a) Mg c) Zn
b) Cu d) Ba
reaksi ΔH
Mg(s) + 2 HCl(aq) → MgCl2(aq) + H2(g) -467 kJ/mol
22. Karbon bereaksi dengan oksigen berdasarkan reaksi berikut 2C(s) + O2(g) → 2CO(g)
ΔH = -220 kJ
Pernyataan mana yang benar ?
1. reaksi adalah eksotermik.
2. pembakaran 0.50 mol karbon menghasilkan 55 kJ energy panas
(A) hanya 1 (C) 1 dan 2
(B) hanya 2 (D) bukan 1 atau 2
25. 1.0 g sample A pada 100 °C ditambahkan kedalam 100 ml H2O pada 25 °C. Menggunakan
100 mL H2O terpisah lainnya, prosedur diulang dengan sampel B dengan sampel C.
Bagaimana temperatur akhir dari air ?
Sampel Panas spesifik
A 0.60 J g-1 °C-1
B 0.40 J g-1 °C-1
C 0.20 J g-1 °C-1
(A) Tc > Tb > Ta (C) Ta > Tb > Tc
(B) Tb > Ta > Tc (D) Ta = Tb = Tc
19. 30.0 mL air pada 10 °C dicampur dengan 50.0 mL air pada 60 °C. Berapa temperature akhir
dari campuran ?
(A) 31 °C (C) 41 °C
(B) 35 °C (D) 46 °C
25. Ketika Na2S2O3 . 3H2O dilarutkan dalam air, larutan menjadi dingin. Diagram mana yang
merepresentasikan kejadian dalam larutan tersebut ?
23. Use the standard enthalpies of formation in the table to calculate ΔH° for this reaction:
2 CrO42¯(aq) + 2 H+(aq) → Cr2O72¯(aq) + H2O(l)
Substance ΔH°f, kJ mol¯1
CrO42¯(aq) - 881.2
2
Cr2O7 ¯(aq) - 1490.3
+
H (aq) 0
H2O(l) - 285.8
(A) 272.1 kJ (C) -13.7 kJ
(B) 13.7 kJ (D) -272.1 kJ
NChO 1995
21. For which of these processes is the sign of the enthalpy change different from the others?
(A) Al2O3(s) → 2 Al(s) + 3/2 O2(g)
(B) H2O(s) → H2O(l)
(C) Cl2(g) → 2Cl(g)
(D) Cl(g) + e¯ → Cl¯(g)
22. The standard enthalpy of formation (ΔH°) for nitrogen(IV) oxide is the enthalpy change for
the reaction
(A) N(g) + 2O(g) → NO2(g)
(B) ½ N2(g) + O2(g) → NO2(g)
(C) ½ N2O4(g) → NO2(g)
(D) NO(g) + ½ O2 → NO2(g)
NChO 1994
24. A student mixes 100 mL of 0.50 M NaOH with 100 mL of 0.50 M HCl in a styrofoam cup
and observes a temperature increase of ΔT1. When she repeats this experiment using 200mL
of each solution, she observes a temperature change of ΔT2. If no heat is lost to the
surroundings or absorbed by the styrofoam cup, what is true about ΔT1 and Δ T2?
(A) ΔT2 = ΔT1 (C) ΔT2 = 2 ΔT1
(B) ΔT2 = 0.5 ΔT1 (D) ΔT2 = 4 ΔT1
NChO 1993
13. Which process or reaction has a positive ΔH?
(A) H2O(l) → H2O(s)
(B) 2CH3OH(l) + 3O2(g) → 2CO2(g) + 4H2O(l)
(C) CO2(s) → CO2(g)
(D) 2 Na(s) + Cl2(g) → 2 NaCl (s)
37. What is the order of concentration of the ions and molecules in a nitrous acid solution?
Nitrous acid, HNO2, is a weak acid.
(A) H3O+ = NO2¯ > HNO2 > OH¯
(B) H3O+ = NO2¯ = HNO2 = OH¯
(C) HNO2 > H3O+ = NO2¯ > OH¯
(D) HNO2 > NO2¯ > H3O+ > OH¯
NChO 1998
33. A water solution of sodium carbonate, Na2CO3, has a pH greater than 7 because
(A) it contains more carbonate ions than water molecules.
(B) it contains more sodium ions than carbonate ions.
(C) sodium ions react with water.
(D) carbonate ions react with water.
NChO 1997
34. Which acid reacts with NaOH to form sodium hypochlorite (the ingredient in household
bleach)?
(A) HOCl (C) HOClO2
(B) HOClO (D) HOClO3
37. Normal rain water has a pH of 5.6. This is best explained by the presence of
(A) nitrogen oxides.
(B) carbon dioxide.
(C) sulfur oxides.
(D) particulates.
38. In a 0.050 M solution of a weak monoprotic acid, [H+]= 1.8 x 10¯3. What is its Ka?
(A) 3.6 x 10¯2 (C) 6.7 x 10¯5
(B) 9.0 x 10¯5 (D) 1.6 x 10¯7
NChO 1996
34. According to the Brønsted-Lowry definition, a base is a substance that
(A) increases the hydroxide ion concentration in water.
(B) can react with water to form OH¯ ions.
(C) can donate an electron pair to form a covalent bond.
(D) can accept a proton from an acid.
37. These acids are listed in order of decreasing acid strength in water.
HI > HNO2 > CH3COOH > HCN
According to the Brønsted-Lowry theory, which anion is the weakest base?
(A) I¯ (C) CH3COO¯
(B) NO2¯ (D) CN¯
39. Which of these salts will give a basic solution when added to water?
(A) NH4NO3 (C) Ca(NO3)2
(B) NH4C2H3O2 (D) Ca(C2H3O2)2
NChO 1995
2. When sodium oxide, Na2O, is added to water, the major products expected are
(A) Na+ and OH¯ ions
(B) Na+ ions and H2O
(C) Na+ and O2¯ ions
(D) Na+ and OH¯ ions, and O2 gas
36. At 0 °C the ion product constant of water, Kw, is 1.2 x 10¯15. The pH of pure water at this
temperature is
(A) 6.88 (C) 7.46
(B) 7.00 (D) 7.56
41. The sodium salt, NaA, of a weak acid is dissolved in water and no other substance is added.
Which of the following statements is corrected?
(A) [H+] = [A¯] (C) [A¯] = [OH¯]
+
(B) [H ] = [OH¯] (D) [HA] = [OH¯]
42. Which of these ions is predicted to produce the most acidic solution when dissolved in H2O?
(A) K+ (C) Co2+
(B) Ba2+ (D) Fe3+
43. When 0.10 M solutions of the solutes; HClO4, NH4Br, KOH, KCN, are arranged in order in
increasing [H+], the correct order is
(A) KOH < KCN < NH4Br < HClO4
(B) KCN < KOH < HClO4 < NH4Br
(C) HClO4 < NH4Br < KCN < KOH
(D) NH4Br < HClO4 < KOH < KCN
1985
43. The chemical reaction taking place in a dry cell may be written
Zn(s) + 2H+(aq) + 2MnO2(s)
→ Zn2+(aq) + 2MnO(OH).
The battery is to be discarded after 2.00 g of zinc is converted to Zn2+(aq). If 0.0100
amperes of current is continuously drawn, for how many seconds can the battery operate?
a) [(65.4) (0.0100)] ÷ [(2) (96,500)]
b) [(2) (96,500)] ÷ [(0.0100) (65.4)]
c) [(2) (65.4) (96,500)] ÷ (0.0100)
d) [(2.00) (2) (96,500)] ÷ [(65.4) (0.0100)]
48. A current of 10.0 amperes flows for 2.00 hours through an electrolytic cell containing a
molten salt of metal x. This results in the decomposition of 0.250 mole of metal x at the
cathode. The oxidation state of x in the molten salt is
a) 1+ b) 2+ c) 3+ d) 4+
50. The free energy change for the chemical reaction that occurs in a voltaic cell when it is
discharging and producing an electric current must be
a) positive b) negative
c) zero d) unpredictable
1988
34. In the reaction
SO2 + 2 H2S → 3 S + 2 H2O
a) sulfur is oxidized and hydrogen is reduced
b) sulfur is reduced and there is no oxidation
c) sulfur is reduced and hydrogen is oxidized
d) sulfur is both reduced and oxidized
35. Which group among the representative (main-group) elements contains the most powerful
oxidizing agent?
a) group I b) group III
c) group VI d) group VII
37. Which ion, in solution, can be oxidized by appropriate chemical means but also can be
reduced by a different chemical reaction?
a) Fe2+ b) F¯
2
c) CO3 ¯ d) NO3¯
1989
49. Zinc reacts with dilute acid to produce H2 and Zn2+ but silver does not liberate hydrogen
from an acid. This information enables one to predict that
a) H2(g) + Zn2+(aq) → 2H+(aq) + Zn(s)
b) 2 Ag(s) + Zn2+(aq) → 2Ag+(aq) + Zn(s)
c) 2 Ag+(aq) + Zn(s) → 2Ag(s) + Zn2+(aq)
d) 2 Ag(s) + 2H+(aq) → H2(g) + 2 Ag+(aq)
50. In the electroplating of silver from cyanide solution the cathode reaction is
Ag(CN)2¯ (aq) + e- → Ag(s) + 2CN¯ (aq)
How many grams of silver should be deposited by a current of 4.50 amperes in 28.0
minutes?
a) 0.141 g b) 4.23 g
c) 8.45 g d) 12.53 g
19. What is the potential in volts for the spontaneous reaction between the Ag/Ag2+ and Zn/Zn2+
half-cells?
Zn2+ + 2e¯ → Zn E° = -0.763V
Ag+ + 1e¯ → Ag E° = 0.799V
a) -2.361 b) -1.562
c) 1.562 d) 2.361
1991
47. Given the standard reduction potentials,
Cr3+ + 3e¯ → Cr -0.74 V
Pb2+ + 2e¯ → Pb -0.13 V
what is the standard potential, E°, for the following reaction?
2 Cr + 3 Pb2+ → 2 Cr3+ + 3 Pb
a) 0.61 V b) 0.87 V
c) 1.09 V d) 1.87 V
Half-cell reaction E°
Cu2+ (aq) + 2e¯ → Cu(s) -0.25 V
Ni2+ (aq) + 2e¯ → Ni(s) +0.34 V
65. When two half-cells are connected using a salt bridge,
a) a galvanic cell will result in which Cu is the cathode
b) a galvanic cell will result in which Cu is the anode
c) an electrolytic cell will result in which Ni is the cathode
d) an electrolytic cell will result in which Ni is the anode
59. A spoon is made the cathode in an electroplating apparatus containing a AgNO3 solution.
How many grams of Ag will be plated on the spoon if a current of 2.00 A is passed through
the apparatus for 1.90 min.?
a) 0.255 g b) 0.150 g
c) 0.128 g d) 0.0638 g
1993
67. How many grams of cobalt metal will be deposited when a solution of cobalt(II) chloride is
electrolyzed with a current of 10. amperes for 109 minutes?
a) 0.66 b) 4.0
c) 20 d) 40
Reduction Potentials
Pb2+ + 2e¯ → Pb -0.13 V
Al3+ + 3e¯ → Al -1.68 V
a) 2.97V b) 1.55V
c) -1.81V d) -2.97V
1994
46. If solid nickel metal were added to separate aqueous solutions each containing 1M
concentrations of Ag+, Cd2+, and Sn2+ ions, how many metals would plate out, based on the
given standard reaction potentials?
Standard Reduction Potentials
Ag+/Ag 0.799 V
2+
Sn /Sn -0.141 V
2+
Ni /Ni -0.236 V
2+
Cd /Cd -0.400 V
a) zero b) one
c) two d) three
48. Solutions of Ag+, Cu2+, Fe3+ and Ti4+ are electrolyzed with a constant current until 0.10 mol
of metal is deposited. Which will require the greatest length of time?
a) Ag+ b) Cu2+
c) Fe3+ d) Ti4+
1997
43. What is the function of H2O2 in this reaction?
6H+ + 2MnO4¯ + 5H2O2 → 2Mn2+ + 5O2 + 8H2O
a) catalyst b) reducing agent
c) oxidizing agent d) inhibitor
44. How much hydrogen is produced from the electrolysis of water in the same time that 2.2 L
of oxygen is formed?
a) 0.14 L b) 1.1 L
c) 2.2 L d) 4.4 L
45. Which of these changes will cause the value of the potential for this half-reaction to be less
negative? (E° = -0.28 V for the reaction.)
Co2+(aq) + 2 e¯ → Co(s)
a) increasing the amount of solid Co
b) decreasing the amount of solid Co
1998
40. For this reaction, E°cell = 0.79 V.
6I¯(aq) + Cr2O72¯(aq) + 14H+
→ 3I2 (aq) + 2Cr3+(aq) + 7H2O(aq)
Given that the standard reduction potential for
Cr2O72¯(aq) → 2Cr3+ (aq) is 1.33 V, what is E°red for I2(aq)?
a) +0.54 V b) -0.54 V
c) +0.18 V d) -0.18 V
41. What is the product formed at the anode in the electrolysis of 1.0 M NaNO3(aq)?
a) H2(g) b) NO2(g)
c) O2(g) d) Na(s)
1. Which of the following does NOT influence the speed of a chemical reaction?
a) concentration of reactants
b) nature of reactants
c) temperature
d) presence of a catalyst
e) none of these
2. What would cause the change in the kinetic energy diagrams as shown?
KE KE
a) increasing the ΔH
b) decreasing the temperature
c) increasing the surface area
d) addition of a catalyst
e) increasing the concentration of reactant
3. Diketahui diagram waktu vs konsentrasi untuk reaksi A → B. Berapa laju dari B setelah 20
detik reaksi berjalan?
5. A reaction has the rate law Rate = k[A]2[B]. What is the overall order of the reaction?
a) 0 b) 2 c) 1 d) 4 e) 3
6. What are the correct units for a second order rate constant?
a) mol/L⋅s d) L2/mol2⋅s
b) 1/s e) mol2/L2⋅s
c) L/mol⋅s
7. The reaction I- + OCl- → IO- + Cl- is first order with respect to I- and first order with
respect to OCl-. The rate constant is 6.1 x 10-2 L/mol⋅s. What is the rate of reaction when
[I-] = 0.10 M and [OCl-] = 0.20 M?
a) 2.4 x 10-4 M/s d) 1.2 x 10-4 M/s
b) 1.2 x 10-3 M/s e) 2.4 x 10-5 M/s
c) 6.1 x 10-3 M/s
8. Sebuah reaksi dan hokum laju reaksi diberikan dibawah ini. Jika [C4H6] = 2.0 M, lajunya
adalah 0.106 M/s. Berapa laju [C4H6] = 4.0 M?
2 C4H6 → C8H12 Rate = k[C4H6]2
a) 0.053 M/s d) 0.424 M/s
b) 0.212 M/s e) 0.022 M/s
c) 0.106 M/s
11. The acid catalyzed decomposition of hydrogen peroxide is a first order reaction with the rate
constant given below. For an experiment in which the starting concentration of hydrogen
peroxide is 0.110 M, what is the concentration of H2O2 450 minutes after the reaction
begins?
2H2O2 → 2H2O + O2 k=1.33 x 10-4 min-1
a) 0.0961 M d) 0.00658 M
b) 0.104 M e) 0.0156 M
c) 0.117 M
12. What is the rate constant for a first order reaction for which the half-life is 85.0 sec?
a) 0.00814 sec-1 d) 0.0118 sec-1
b) 4.44 sec-1 e) 58.9 sec-1
c) 0.170 sec-1
13. What fraction of a reactant remains after 3 half-lives of a first order reaction?
a) 1/2 d) 1/8
b) 1/3 e) 1/12
c) 1/6
14. Asumsikan reaksi terjadi dengan mekanisme seperti dibawa ini. Apa hokum laju untuk
reaksi tersebut ?
A+B↔C Cepat
C→D Lambat
a) Rate = k[A][B][C]
b) Rate = k[A]2
c) Rate = k[A][B]
d) Rate = k[A][B]/[D]
15. According to collision theory, which of the following factors does NOT influence the rate of
reaction?
a) collision frequency
b) collision energy
c) collision orientation
d) collision rebound direction
e) none of these
16. What distance corresponds to the activation energy for the reaction of X to Y?
a) a d) d
b) b e) e
c) c
17. At what point on the potential energy diagram given below does the transition state
(activated complex) occur?
a) a d) d
b) b e) e
c) c
20. In the reaction, H2 + Br2 → 2HBr, the step Br• + H2 → HBr + H• is what step?
a) initiation d) propagation
b) completion e) termination
c) inhibition
21. In the reaction, H2 + Br2 → 2HBr, the step Br• + Br• → Br2 is what step?
a) initiation d) propagation
b) completion e) termination
c) inhibition