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M. W. Hitzman
• The deposit is centered on a number of subvolcanic dacitic porphyry stocks (7.1 - 6.8 Ma)
intruding co-genetic andesite wallrocks (9 - 6.7 Ma).
• The deposit contains 605 million tons with an average grade of 0.54% Cu and 0.64 g/t Au. Was
brought into production in 1997 as Argentina’s first major metal mine.
• The deposit is upright and little deformed making it a “classic” example of a porphyry copper.
M. W. Hitzman
Page 1
Bajo de la Alumbrera, Argentina
Surface Geology
The deposit is centered on a
number of subvolcanic dacitic
porphyry stocks (7.1 - 6.8 Ma)
intruding co-genetic andesite
wallrocks (9 - 6.7 Ma).
M. W. Hitzman
Deposit consists of a swarm of near-vertical dikes and small stocks. The major
intrusions appear to be the P2 and Early P3 intrusions which are syn-alteration and
mineralization. Depth of emplacement is not known, but porphyritic textures suggest
M. W. Hitzman
relatively shallow (2.5 km) subvolcanic environment.
Page 2
The deposit displays a classic
bull's-eye alteration pattern:
Bajo de la Alumbrera, Argentina
• Potassic – Surface Alteration
– A core of strong potassic
alteration (Ksp replacement
and intense qtz-magnetite Propylitic
veining).
– Surrounded by a zone of
moderate to weak Ksp-biotite
replacement of wallrocks
with magnetite veins. This
zone grades out into a more
weakly developed zone of
secondary biotite.
• Propylitic
– Chlorite-epidote-albite-
calcite alteration (dominantly
in andesite wallrocks).
Sulfide content is low and
consists of pyrite with trace
molybdenite, sphalerite,
galena (note metal zoning).
• Sericitic -
– Chloritization (then
sericitization) of biotite and (from Ulrich and Heinrich, 2001, Econ Geol., p. 1727;
replacement of plagioclase Map derived from unpub work of J.M. Proffett)
and Ksp by sericite-calcite-
(kaolinite). Zone contains
1-10% pyrite. Dated at 6.75
Ma (approx. 300,000 yrs after
intrusion of P2 Porphyry). work of J.M. Proffett, EG, 2003
M. W. Hitzman
Vertical “pipe” of potassic alteration, partially enclosed in downward tapering funnel of sericitic
alteration (“late fld destructive”) which cuts and replaces potassic assemblages. Propylitic alteration
(chl-epid) extends outward from the sericitic zone for up to 1 km - probably formed dominantly during
potassic alteration. Note that late and post-mineral porphyries display very weak secondary biotite (this
M. W. Hitzman
is after sericitic event).
Page 3
Bajo de la Alumbrera,
Argentina
M. W. Hitzman
Bajo de la Alumbrera,
Argentina Ore
Metal Zonation shell
• The deposit displays a
classic metal zonation
pattern with “high” grade
copper and gold forming a
shell within the outer portion
of the potassic zone,
surrounding a relatively
barren core of Kspar-mgt (but
a caution… intrusions tend to
be concentric, so late, post-
mineral intrusions may
destroy early-formed
mineralization).
• Some mineralization,
especially gold, extends into
the sericitic alteration zone,
although this occurrence
largely reflects the late
overprinting of potassic by
sericitic alteration.
(from Ulrich and Heinrich, 2001, Econ Geol, p. 1732) M. W. Hitzman
Page 4
Bajo de la Alumbrera -
Why is it Important?
M. W. Hitzman
Yerington, Nevada
Prof. Marco Einaudi (Stanford Univ.) with skarn mineral phase diagrams on skarn
outcrops. M. W. Hitzman
Page 5
Yerington, NV.
Yerington,
Nevada
Page 6
(from Dilles and Einaudi, 1992, Econ
Yerington, Nevada - Geol., p. 1967)
Ann-Mason area
Surface Geology
• The Ann-Mason deposit
represents a tilted slice of crust
from the top of the Yerington
batholith upwards for
approximately 4 km.
Yerington, Nevada -
Ann-Mason area
Early Hydrothermal Alteration
M. W. Hitzman
(from Dilles and Einaudi, 1992, Econ Geol., p. 1968)
Page 7
Yerington, Nevada -
Ann-Mason area
Main Stage (Potassic)
Hydrothermal Alteration
Yerington, Nevada -
Ann-Mason area
Late Stage Hydrothermal
Alteration Sericitic
Page 8
Yerington, Nevada -
Ann-Mason area
Hypogene Sulfide
Distribution increasing
pyrite
upwards
• Hypogene sulfides in the
copper orebody
associated with potassic
alteration consist of 0.01
- 1 % of rock and are cpy
> py or cpy = py. Ann-Mason
Deposit
(at depth)
• The majority of sulfide is
pyrite and occurs in the
sericitic alteration zone
with the highest volumes
of pyrite (>5% of rock) in
the uppermost portions.
Yerington, Nevada -
Ann-Mason area
Copper Geochemistry
(Surface)
• Highest rock and soil Ann-Mason
geochemistry is in the area Deposit
of the buried Ann-Mason (at depth)
deposit. The higher grade
“tail” to the south is a
drainage-related anomaly -
it is on Tertiary volcanics
and does not reflect
bedrock copper grades.
Page 9
Yerington, Nevada - Geological Reconstruction
Ann Mason
MacArthur
Yerington batholith
(from Dilles et al., 2000, Soc Econ Geol, Guidebook Series vol 32, p.57)
North - south geological cross section through the Yerington batholith showing
the position of porphyry copper centers (Ann-Mason, MacArthur) associated with
granite cupolas at about 4 km depth. Also shows how the granite has largely
stopped its way upward in the same position as the Yerington quartz
monzodiorite batholith. M. W. Hitzman
(from Dilles et al., 2000, Soc Econ Geol, Guidebook Series vol 32, p.59)
North - south geological cross section through the Yerington batholith showing the
position of alteration zones.
M. W. Hitzman
Page 10
Yerington, Nevada -
Why is it Important? What is Different about this System?
• The Yerington district is important because of its structural geometry - it allows us to view
a cross-section of a porphyry system.
• The district contains several porphyry copper centers which show the expected early (main
stage) potassic-propylitic alteration (with hypogene copper mineralization in the potassic
zone) and an overlying (and later) sericitic alteration zone.
• However, the porphyry copper deposits (especially the Ann-Mason / Yerington system) also
contains early sodic calcic alteration and later sodic alteration.
– Sodic-calcic alteration was due to prograding, saline, non-magmatic fluids (probably derived
from adjacent evaporites in the Jurassic section) that flowed into the batholith at least 3 km
at depths of 4-6 km. As these fluids were heated they altered Ksp to oligoclase and leached
Fe and Cu from approximately 103 km of quartz monzodiorite. In the dike swarm, these fluids
mixed with magmatic fluids and probably contributed significant K, Fe, and Cu to the ore
zone.
– The later sodic alteration was due to entrainment of saline meteoric water into the warmer
thermal anomaly along the dike swarm. These fluids exchanged sodium for potassium
(alteration of Ksp to oligoclase) and leached copper from sulfides. As they cooled and
became more acidic as they rose, the caused widespread sericitic alteration.
• The prevalence of sodic alteration at Yerington is probably due to the character of the
wallrocks (containing evaporites). The alteration seen in this system gives us important
clues about other types of ore forming systems - the iron oxide-Cu-Au systems (IOCG).
M. W. Hitzman
Chuquicamata, Chile
• Chuquicamata is the world’s
largest known copper orebody.
• Chuquicamata is certainly a
porphyry copper deposit;
however, it shows some unusual
features which may help
account for its enormous size. M. W. Hitzman
Page 11
Chuquicamata, Chile
• The Chuqui orebody occurs within
the Oligocene Chuqui Porphyry
complex (35-33 Ma) to the east of the
West Fault strike-slip fault zone. The
unmineralized Fortuna Complex
(same age as Chuqui porphyry)
occurs to the west of the fault.
• The Chuqui Complex consists of the
East, Fine Texture, West, and Banco
porphyries.
• The Chuquicamata district comprises
ore deposits strung out over 30 km
along the West Fault from MM (Mansa
Mine) in the south to Radomiro Tomic
on the north.
M. W. Hitzman
Chuquicamata, Chile
• The Chuqui pit is bisected by the
West Fault. Rocks to the east are
mineralized, while those to the west
are largely barren.
Page 12
Chuquicamata Alteration - Map View
• Early Stage:
– Potassic alteration affects all porphyries. It comprises partial
Kspar and albite replacement of plagioclase and more pervasive
biotite replacement of hornblende. Potassic alteration is
accompanied by quartz-Kspar veinlets with very minor
chalcopyrite-bornite.
– Fine-grained quartz-Kspar alteration, with destruction of biotite,
occurs parallel to the Banco porphyry dikes. This alteration
accompanies strong cataclastic deformation. Sulfides are
abundant only where there is intense crackle brecciation.
– Propylitic alteration (chloritic on map) extends east of the
potassic zone and overprints hydrothermal biotite.
– Potassically altered rocks are cut by quartz-molybdenite veins.
• Main Stage
– This period formed quartz-sericite alteration and sulfide-rich
veins. On the western side of the body, adjacent to the fault, this
alteration has obliterated earlier assemblages and igneous
textures.
– Sulfide veins contain pyrite with varying amounts of quartz,
chalcopyrite, bornite, covellite, chalcocite, enargite, tennantite,
and sphalerite. These veins have well developed sericitic halos.
– Most copper production has come from this alteration type.
Chuquicamata Alteration -
Cross Section
• Early Stage:
– Potassic alteration forms a
linear zone parallel to the West
fault and extends to depth.
– Propylitic alteration occurs to
the east.
• Main Stage
– This alteration type occurs
along the West fault and also
extends to depth (at least 800m),
associated with sericite stage;
evolution from intermediate to
high sulfidation states (cpy to
en).
[see discussion of Butte, MT in next lecture]
Page 13
Chuquicamata, Chile
Sulfide Distribution -
Map View
• Early Stage:
– Dominantly chalcopyrite-bornite with
potassic alteration.
• Main Stage:
– Complex mixture of sulfide types. Laterally
zoned from chalcopyrite-rich to east to
chalcocite and chalcocite-covellite to
enargite to west along West fault.
from Ossandon et al.,
2001, Econ Geol., p. 259
M. W. Hitzman
Chuquicamata, Chile
Sulfide Distribution -
Cross Section
• Early Stage:
– Dominantly chalcopyrite-bornite with
potassic alteration. Note bornite “core”
within the potassic zone perhaps
indicating the center of this system.
• Main Stage
– Complex mixture of sulfide types.
Laterally and vertically zoned. Laterally
zoned from chalcopyrite-rich to east to
chalcocite and digenite-covellite along
West fault. Vertically zoned from
chalcocite-rich above to digenite below.
– Enargite appears to cross-cut other sulfide
zones - late Butte-type veins.
• Supergene Mineralization
– The deposit originally contained a leached
cap and a copper oxide orebody. These
have been largely mined out.
– The chalcocite zones (in both sericite over
potassic and in potassic) are largely
secondary (supergene). This is the largest
known supergene enriched body in the
world. from Ossandon et al.,
2001, Econ Geol., p. 260
M. W. Hitzman
Page 14
Chuquicamata, Chile
Metal Distribution
M. W. Hitzman
Page 15
Chuquicamata, Chile - Why is this Deposit Unusual?
• The position of Chuqui within a major, long-lived, dynamic regional fault zone
which focused hydrothermal activity over several million years is probably the
reason for its unusual size and grade.
• The early potassic system veins contain relatively low amounts of copper. Has the
copper from the early system been leached and fixed in the Main stage system?
(also postulated for Butte).
• Chuqui lacks the hydrothermal breccias that characterize many porphyry copper
deposits. This may be due to the pervasive shattering of rocks from faulting at all
stages of development of the orebody which would have prevented the buildup of
extensive fluid pressure required for hydrothermal brecciation.
• Where is the other half of Chuqui? This has intrigued geologists for decades.
Regional mapping indicates approximately 35 km of sinistral offset along the West
fault. There is a question about how much of this offset had occurred by each
period of mineralization.
M. W. Hitzman
M. W. Hitzman
Page 16
• The Far Southeast
porphyry deposit is
gold rich (105 Mt at Far Southeast - Lepanto, Philippines
0.86% Cu and 2.02 g/t
Au).
• Mineralization is
associated with a
series of quartz diorite
porphyry dikes. These
dikes are typically 50 -
150 m wide and trend
NW, parallel to the
Lepanto fault.
• Lepanto is a high
sulfidation (HS)
epithermal deposit that
contains a significant
zone of hypogene from Hedenquist et al., 1998, p. 374
advanced argillic
alteration above a • The world-class Lepanto epithermal Cu-Au
potassic zone of deposit has been shown to be linked genetically
alteration. to the Far Southeast porphyry deposit. M. W. Hitzman
Page 17
Far Southeast (FSE) - Lepanto, Philippines
Lepanto
Flts.
• The Far Southeast porphyry deposit occurs as a vertically oriented system associated with a
dike swarm of quartz diorite.
• The Far Southeast porphyry is cut by post-mineral breccia pipes.
• The Lepanto deposit occurs along the Lepanto fault. It is located above and to the northwest
of the Far Southeast porphyry.
• The Lepanto deposit is localized along the contact between basement metavolcanic rocks and
unconformably overlying Pliocene volcanic rocks - just older than the intrusions responsible
for porphyry mineralization.
M. W. Hitzman
• The Far Southeast porphyry deposit displays a potassically altered (biotitic alteration) core
associated with copper-gold mineralization. It is cut by a zone of chlorite-sericite (which
contains higher Cu grades than the potassic zone) which is overlain by an advanced argillic
assemblage of pyrophyllite-diaspore-kandite (kaolinite-dickite), same age as potassic.
• The advanced argillic zone of quartz-alunite alteration is cored by leached residual quartz
which hosts the Lepanto epithermal (high sulfidation) Cu-Au deposit.
• The Lepanto deposit itself is closely associated with the Lepanto fault (70% ore in fault
breccia), as well as in a zone that mushrooms out along the basement-pyroclastic contact.
M. W. Hitzman
Page 18
Lepanto
Cross Section
M. W. Hitzman
Page 19
Far Southeast - Lepanto
How do we know the two are genetically related?
from Hedenquist et al.,1998, p. 385
Low
Med
High
Temps
Page 20
Far Southeast-Lepanto -
Why is it Important?
M. W. Hitzman
Page 21