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FIG1 - Locality map illustrating the distribution of important high-grade hematite ore deposits.
FIG 3 - (A). Illustration of a truncation model of folded Transvaal strata by the lateritised erosion surface on subcontinental scale below the
pre-Gamagara unconformity. (B). Lateral variations along laterite profiles. All laterite profiles illustrated were intersected in drill core depths
of >100 m and are free of modern weathering. The Wolhaarkop profile (note depths below red bed cover rocks) display liesegang and
corestone weathering patterns in saprolite derived from massive lava and diamictite bedrock. Karstic laterites on dolomite bedrock contain
supergene manganese ores at Glosam and iron ore crusts derived from supergene leaching of iron-formation at Sishen, in addition to
Al-rich claystones. Supergene iron ore beds are also sporadic preserved below the unconformity at the base of the overlying Mapedi and
Gamagara red beds, in areas outside of the karstic environment, such as in the vicinity of Hotazel. The red beds contain hematite pebble
conglomerates derived from the iron ore beds and pisolitic laterites. In the Hekpoort profiles the saprolite zone preserves original textures of
the parent basalt but the pallid and upper ferruginous zones have a massive reconstituted fabric.
HYDROTHERMAL DEPOSITS
Type examples of hard high-grade hydrothermal hematite ores
from the Brockman Iron Formation of the Hamersley Group in
Western Australia and the Penge Iron Formation of the Transvaal
Supergroup at Thabazimbi in South Africa (Figure 1) share many
features. The parent iron-formations are of correlative age (in the
order of 2460 - 2480 m.y.) and overly black shales capping
carbonates. In both areas the main orebodies are located near the
base of the iron-formation succession in contact with underlying
black shale. Mineralisation also invariably appears to be
associated with early normal faults (Taylor et al, 2001;
FIG 4 - Schematic diagram illustrating the setting of ancient
Netshiozwi, 2002; Netshiozwi et al, 2002). At Thabazimbi, loss
supergene hematite ores in karstic solution collapse structures
of stratigraphy along the contact between the Penge Iron
at the Sishen deposit, South Africa.
Formation and underlying Malmani dolomite indicates that related to intrusion of the Bushveld Complex at ~2.058 Ga.
mineralisation took place along early low-angle normal lystric However, mineralisation took place prior to deposition of circa
faults that were later rotated to steep dip by thrust deformation 2.0 Ga conglomerates of the unconformably overlying Waterberg
(Figure 5). Similarly, at both Mount Tom Price and Paraburdoo, Group that contain pebbles of iron ore. Mineralisation thus
high-grade iron ores formed along steep normal faults (Taylor et appears to have taken place shortly before 2.0 Ga, very similar to
al, 2001). the age of ore formation in the Hamersley Province recently
Ore formation can be ascribed to leaching of silica (chert) proposed by Taylor et al (2001). Following ore formation,
from iron-formations and recrystallisation of other iron mineral the ores at Thabazimbi have been duplicated by a series of
phases to specularite and martite. There may have been some north-verging post-Waterberg thrust faults. At Paraburdoo, the
mobility of iron in the system, as indicated by the replacement of ores were tilted in southern direction by the post-Wyloo
chert-bands by hematite without significant volume loss. Capricorn orogeny at 1.7 - 1.8 Ga (Taylor et al, 2001).
However, for the most part hematite enrichment can apparently The only significant difference between the two areas appears
be accounted for by leaching of silica, compaction and an to be the depth of post-Gondwana late Mesozoic to Tertiary
increase in porosity (Taylor et al, 2001). weathering. At Thabazimbi, significant weathering to depths of
Shales, dykes and sills in the iron-formations at both 50 m to 100 m along the Late Cretaceous – Early Tertiary
Thabazimbi and in the Hamersley Province appear to exceed an African Land Surface was associated with karstification of the
important control in the localisation of the orebodies (Taylor et underlying dolomites and solution collapse of ore into the karst
al, 2001; Netshiozwi, 2002). Ores are often only developed along cavities. The present day weathering surface appears to have very
one side of dolerite dykes that intruded prior to ore formation. little effect on the ores (Figure 5). In contrast, the depth of
Similarly, impermeable shale beds and dolerite sills appear to weathering in the Hamersley Province is commonly between
have acted as hydrological seals that restricted ore formation. 100 m and 200 m deep (Taylor et al, 2001).
This is illustrated by the observations that high-grade iron ores With reference to the mineralogical composition of the ores it
are only rarely developed above the Whaleback shale in the is important to note that an early phase of magnetite and hematite
Hamersley District, or above a prominent pre-mineralisation mineralisation, intimately associated with metasomatic carbonate
diabase sill in the Penge Iron Formation at Thabazimbi. It is also formation, has been identified at Mount Tom Price (Taylor et al,
important to note that the orebodies are always surrounded by a 2001). Similar carbonate-bearing ores are developed at
halo of oxidised (hematite-rich) iron-formation. This is very well Thabazimbi (Figure 5) (Netshiozwi, 2002). REE patterns in
illustrated at Thabazimbi, where earlier carbonate and silicate hydrothermal ores from Thabazimbi and the Hamersley Province
facies iron-formations have been transformed into hematite-rich differ from those in ancient supergene Sishen-type deposits in
iron-formation in vicinity of the orebodies (Netshiozwi, 2002). that they display slight negative to no Ce anomalies. Overall, the
The age of ore formation in the Hamersley Province and at patterns remain very similar to that in parent iron-formations,
Thabazimbi also appears rather similar. At Thabazimbi, hematite strongly suggesting that no significant preferential concentration
ore replaces contact metamorphic grunerite in the iron-formation or introduction of REE took place during ore formation.
FIG 5 - Schematic cross-section of the Donkerpoort West high-grade hematite orebody at Thabazimbi Mine, South Africa.
Carbon and oxygen isotope signatures of hydrothermal Apart from bring characterised by the abundance of friable
dolomite associated with iron ores at Thabazimbi in comparison (soft) hematite ores in very deep (>100 - 500 m) lateritic
with diagenetic carbonates in the iron-formation protore, indicate weathering profiles (Figures 6, 7 and 8), the supergene-modified
rock-buffered conditions for δC13 and δO18. Sparitic calcite, on iron ores of Brazil and India display many features that are
the other hand, appears to have formed at significantly greater similar to those of less altered hydrothermal iron ore deposits in
fluid-rock ratios with highly depleted δO18 values relative to that Western Australia and at Thabazimbi, South Africa. The friable
of diagenetic carbonates in parent iron-formations (Gutzmer to powdery saprolitic hematite ores, usually composed of
et al, 2002). microplaty hematite, specularite and martite, are invariably
Oxygen isotopic compositions of hematite in the Thabazimbi associated with bodies of hard hematite ore. These hard ores
and Hamersley ores are marked by δO18SMOW values as low as often occur as large tabular bodies in the lower part of the
-7‰. Fluid inclusion studies on carbonates and quartz associated
with hematite ores at Thabazimbi indicate the presence of two
distinct hydrothermal fluids, namely a high-salinity fluid that
resulted in deposition of early dolomite at temperatures around
150 - 160°C, and a low salinity fluid that led to precipitation of
quartz at temperatures of between 120 and 140°C (Netshiozwi,
2002). Fluid inclusions in calcite have compositions ranging in
composition between the two end members in both salinity and
temperature. It is thus suggested that the calcite was deposited
during mixing of the two fluid end members. These results are in
excellent agreement with homogenisation temperatures and
salinities of fluid inclusions from quartz veins associated with
hematite mineralisation at the Mount Tom Price deposit (Taylor
et al, 2001). At 160°C the oxygen isotopic composition of the
hydrothermal fluid from which hematite and calcite precipitated
at Thabazimbi can be estimated at -2‰ (relative to SMOW).
Fluids of such light oxygen composition can only be meteoric
water, ie water-rich fluids of shallow crustal origin that have not
interacted with silicate rocks (Netshiozwi, 2002).
iron-formation successions with smaller, lenticular bodies higher observed that ore formation postdated intrusion and folding of
up in the stratigraphy. In certain cases, tabular orebodies are also dolerite sills. These sills could be related to volcanic activity that
developed below impermeable roof rocks such as dolerite sills, took place around 2.12 Ga (Alkmim and Marshak, 1998) during
lava and/or shale. The hard orebodies are typically surrounded by deposition of the Sabara Group. Dykes that crosscut the ore have
highly porous friable ores and/or friable hematite-rich banded been dated at 1.75 Ga (Alkmim and Marshak, 1998) and iron ore
iron-formation (itabirite) (Figures 6, 7 and 8). The friable formation may thus have taken place during or shortly after a
itabirite (best described as iron-formation saprolite) is widely period of extensional tectonics described by Alkmim and
Marshak (1998). In the Dalli-Rajhara deposits of India excellent
utilised as low-grade ore in the Quadrilátero Ferrífero because
exposures of crosscutting relationships between orebodies and
hematite can easily be concentrated from the closely associated
bedding in intensely folded iron-formation can be observed.
quartz by dense media separation. Near surface, the orebodies Unfortunately the age of folding is not known at present.
are typically capped by a veneer of hydrated goethitic ore below
a cover of laterite and canga that has been incised by streams in
geologically recent times. GENETIC MODEL FOR HYDROTHERMAL ORES
The origin of the highly porous soft ores in the deposits is a AND THEIR SUPERGENE MODIFICATION
matter of contention at present. They have always been Information available at present strongly suggests that all major
considered the result of leaching of silica from banded high-grade hematite iron ore deposits of Western Australia,
iron-formation under deep lateritic weathering conditions Thabazimbi in South Africa, the Quadrilátero Ferrífero and
(Dardenne and Shobbenhaus, 2000). However, in recent years Carajas in Brazil, and eastern and central India are very similar
through deep drilling and mining in Brazil, it has become in character and may thus share a very similar mode of origin.
obvious that banded carbonate-hematite rocks are preserved at Differences between the ores are largely the result of varying
depth below friable hematite ores at Carajas and the Aguas intensities of supergene modification in late Cretaceous to
Claras mine in the Quadrilátero Ferrífero (Figures 6 and 7). Tertiary times, after the breakup of Gondwana.
These rocks obviously developed from the replacement of chert All indications are that primary orebodies owe their origin to
bands in iron-formation by carbonate. Aguas Claras is the best the interaction of iron-formation with a hydrothermal fluid of
example, where original chert bands in the lower part of the Caué meteoric origin at temperatures of not more than 160°C to
Iron Formation have been completely replaced by ferroan 200°C. Ore formation was essentially a process of silica
dolomite. In the deepest levels of this mine there are excellent dissolution and transformation of ferrous iron minerals, including
exposures illustrating how leaching of dolomite from the banded siderite, ankerite and iron silicates into microplaty hematite and
dolomite-hematite rock gives rise to saprolitic friable hematite magnetite, the latter of which was later transformed into martite.
ore (Figure 7). How much of this applies to other deposits in the An early phase of magnetite + carbonate mineralisation is
Quadrilátero Ferrífero is unknown at present, but it is certainly present in some deposits and could have formed at elevated
applicable to the Carajas district, where rather similar temperatures and very low oxygen fugacity under the influence
carbonate-replaced hematite-rich iron-formation has been of an alkaline hydrothermal fluid that carried Ca++ and Mg++, an
intersected in drill core at depth. Another argument in favor of environment also most suitable for the leaching of silica. Cooling
leaching of carbonate rather than silica to form friable ores is the of this hydrothermal fluid would have favored the formation of
fact that large volumes of friable itabirite are preserved close to hematite, a process that does not necessarily require higher
surface in many of the mines in the Quadrilátero Ferrífero and at oxygen fugacity than magnetite formation.
Carajas. At Aguas Claras lenticular bodies of itabirite are A simple system of meteoric fluid circulation along
preserved in soft ore close to surface (Figure 7). Rather than extensional fault-controlled aquifers is envisaged for formation
representing iron-formation corestones in the ore from which of the iron ore deposits. Some faults acted as aquifers for
silica has not been leached, they may well represent pockets of meteoric water recharge and others for discharge. Deep seated
iron-formation that were not affected by carbonate iron ore deposits formed in the vicinity of normal faults that
metasomatism. acted as channels for fluid escape. Meteoric water flow was most
The Indian deposits that we have investigated thus far probably topographically driven with recharge taking place in
(Mukhopadhyay et al, 2002) have only been explored and mined areas of uplift related to either rise of basement domes, like in
to depths of 50 m - 100 m so and there is virtually no information the Quadrilátero Ferrífero, or areas of extensional tectonics. It is
available on the precursor rock for the friable ores. However, in quite possible that lateritic supergene ores formed in areas of
mines around Noamundi, bodies of hard unaltered chert-rich
recharge but because of uplift they would have had a small
iron-formation are commonly preserved in friable saprolitic
hematite ore. Contacts between the friable ores and preservation potential.
iron-formation bodies are sharp and difficult to explain by Following breakup of Gondwanaland the ore deposits were
supergene leaching of silica. Rather, it would appear that the subjected to different degrees of supergene alteration, determined
iron-formation was replaced by hematite and perhaps carbonate by climatic evolution on the various continents, and timing of
prior to lateritic weathering. Similarly, in the Dalli-Rajhara area, exposure of deposits. At present, the deposits are mainly
there are abundant examples of unreplaced hard and friable preserved at high elevations below old lateritised land surfaces.
(saprolitic) siliceous iron-formation bodies preserved in soft These old land surfaces are preserved at high elevations because
hematite ore. fluvial erosion takes place by pediplenation (back-cutting) rather
Massive and laminated hard orebodies are present in both the than peneplenation (down-cutting).
Brazilian and Indian deposits. The massive ores are typically
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