1. what volume would be occupied by this quantity?

(1
Of the following name/symbol combinations of gallon = 3.7854 liters)
elements, which one is WRONG? (a) 7.646 x 1011 liters
(a) uranium/U (b) 8.388 x 109 liters
(b) sulfur/S (c) 1.287 x 109 liters
(c) nitrogen/N (d) 5.336 x 1010 liters
(d) potassium/K (e) 4.870 x 109 liters
(e) iron/I 9.
2. Identify the INCORRECT statement.
Of the following symbol/name combinations of (a) Helium in a balloon: an element
elements, which one is WRONG? (b) Paint: a mixture
(a) C/carbon (c) Tap water: a compound
(b) B/barium (d) Mercury in a barometer; an element
(c) F/fluorine 10.
(d) N/nitrogen An unused flashbulb contains magnesium and
(e) U/uranium oxygen. After use, the contents are changed to
3. magnesium oxide but the total mass does not
The chemical symbol for manganese is change. This observation can best be explained by
(a) Mn the
(b) Mo (a) Law of Constant Composition.
(c) Ma (b) Law of Multiple Proportions.
(d) Ga (c) Avogadro's Law.
(e) Mg (d) Law of Conservation of Mass.
4. 11.
The number 0.005436 has how many significant Which answer includes all the following that
figures? are chemical changes and not physical changes?
(a) 7 I. freezing of water
(b) 3 II. rusting of iron
(c) 4 III. dropping a piece of iron into hydrochloric acid
(d) 5 (H2 is produced)
(e) 6 IV. burning a piece of wood
5. V. emission of light by a kerosene oil lamp
The number 10.00 has how many significant figures? (a) III and IV
(a) 1 (b) II and V
(b) 2 (c) I, II, III, IV, and V
(c) 3 (d) II, III, and V
(d) 4 (e) II, III, IV, and V
(e) 5 12.
6. Which response lists all of the following properties of
What is the volume of a 2.50 gram block of metal sulfur that are physical properties and not other
whose density is 6.72 grams per cubic centimeter? properties?
(a) 16.8 cubic centimeters I. It reacts with hydrogen when heated.
(b) 2.69 cubic centimeters II. It is a yellow solid at room temperature.
(c) 0.0595 cubic centimeters III. It is soluble in carbon disulfide.
(d) 0.372 cubic centimeters IV. Its density is 2.97 g/cubic centimeter
(e) 1.60 cubic centimeters V. It melts at 112 degrees C.
7. (a) II, III, IV, and V
A cube of 1.2 inches on the side has a mass of 36 (b) II, IV, and V
grams. What is the density in g/cm3? (c) I
(a) 21 (d) II, III, and IV
(b) 2.2 (e) III, IV, and V
(c) 30.
(d) 1.3 13.
(e) 14 The formula weight of the compound, Al2(SO4)3
8. 18H2O is:
Nitric acid is a very important industrial chemical: (a) 394.4 g
1.612 x 1010 pounds of it were produced in 1992. If (b) 666.4 g
the density of nitric acid is 12.53 pounds/gallon, (c) 110,900 g
 (d) 466.8 g Which one of the samples has the largest mass?
(e) 561.2 g (a) 1 mol of CO2(g)
14. (b) 1 mol of UF6(g)
The weight of a millimole of (NH4)2HPO4 is: (c) 1 mol of CH3COCH3(l)
(a) 132 g (d) 1 mol of He(g)
(b) 114 g (e) all have the same mass
(c) 1.14 x 10-3 g 22.
(d) 0.132 g Which of the following statements is(are) FALSE?
(e) 6.02 x 1020 g 1. The percent by mass of each element in a
15. compound depends on the amount of the
How many moles of alanine, C3H7NO2, are there in compound.
159 g of alanine? 2. The mass of each element in a compound depends
(a) 1.42 x 104 on the amount of the compound.
(b) 1.78 3. The percent by mass of each element in a
(c) 0.992 compound depends on the amount of element
(d) 0.560 present in the compound.
(e) 3.31 (a) 2 and 3
16. (b) 1 only
How many atoms are in one mole of CH3OH? (c) 1 and 2
(a) 6 (d) 1, 2 and 3
(b) 6.0 x 1023 (e) another combination
(c) 12.0 x 1023 23.
(d) 3.6 x 1024 Guanidin, HNC(NH2)2, is a fertilizer. To three
(e) 3 significant figures, what is the percent by mass of
17. nitrogen in the fertilizer?
The mass in grams of 2.6 x 1022 chlorine atoms is: (a) 45.2%
(a) 4.4 (b) 49.4%
(b) 11 (c) 54.8%
(c) 0.76 (d) 65.1%
(d) 1.5 (e) 71.1%
(e) 3.2 24.
18. Calculate the percent, by weight, of carbon in 154 g
How many aluminum atoms are there in 3.50 grams of C4H8O3?
of Al2O3? (a) 46%
(a) 4.13 x 1022 (b) 31%
(b) 4.90 x 1022 (c) 72%
(c) 2.07 x 1022 (d) 27%
(d) 1.68 x 1022 (e) 55%
(e) 2.45 x 1022 25.
19. Analysis of a sample of a covalent compound showed
Which one of the samples contains the most atoms? that it contained 14.4% hydrogen and 85.6% carbon
(a) 1 mol of CO2(g) by mass. What is the empirical formula for the
(b) 1 mol of UF6(g) compound?
(c) 1 mol of CH3COCH3(l) (a) CH
(d) 1 mol of He(g) (b) CH2
(e) all contain the same number of atoms (c) CH3
(d) C2H3
20. (e) none of these
Which one of the samples contains the 26.
most molecules? An oxide of lead contains 90.65% Pb, by weight. The
(a) 1 mol of CO2(g) empirical formula is:
(b) 1 mol of UF6(g) (a) Pb
(c) 1 mol of CH3COCH3(l) (b) PbO
(d) 1 mol of He(g) (c) Pb3O4
(e) all contain the same number of molecules (d) Pb2O3
(e) PbO2

27.
21.
 A 0.500 g sample of a compound containing only (c) 3
antimony and oxygen was found to contain 0.418 g (d) 7
of antimony and 0.082 g of oxygen. What is the (e) 5
simplest formula for the compound? 33.
(a) SbO When iron pyrite (FeS2) is heated in air, the process
(b) SbO2 known as "roasting" forms sulfur dioxide and iron(III)
(c) Sb3O4 oxide. When the equation for this process is
(d) Sb2O5 completed and balanced, using the smallest whole
(e) Sb2O3 number coefficients, what is the coefficient for "O2"?
28. ___ FeS2 + ___ O2 ___ SO2 + ___ Fe2O3
A compound contains, by mass, 40.0% carbon, 6.71%
hydrogen, and 53.3% oxygen. A 0.320 mole sample (a) 2
of this compound weighs 28.8 g. The molecular (b) 4
formula of this compound is: (c) 7
(a) C2H4O2 (d) 8
(b) C3H6O3 (e) 11
(c) C2H4O 34.
(d) CH2O How many moles of KBrO3 are required to prepare
(e) C4H7O2 0.0700 moles of Br2 according to the reaction:
29. KBrO3 + 5KBr + 6HNO3 6KNO3 + 3Br2 + 3H2O
What mass of cerussite, PbCO3, would contain 35.0
grams of lead? (a) 0.210
(a) 27.1 g (b) 0.0732
(b) 45.1 g (c) 0.0704
(c) 42.4 g (d) 0.220
(d) 35.6 g (e) 0.0233
(e) 51.7 g 35.
30. Which of the following statements is FALSE for the
Balance the following equation with the smallest chemical equation given below in which nitrogen gas
whole number coefficients. Choose the answer that reacts with hydrogen gas to form ammonia gas
is the sum of the coefficients in the balanced assuming the reaction goes to completion?
equation. Do not forget coefficients of "one." N2 + 3H2 2NH3
PtCl4 + XeF2 PtF6 + ClF + Xe (a) The reaction of one mole of H2 will produce 2/3
moles of NH3.
(a) 16 (b) One mole of N2 will produce two moles of NH3.
(b) 22 (c) One molecule of nitrogen requires three
(c) 24 molecules of hydrogen for complete reaction.
(d) 26 (d) The reaction of 14 g of nitrogen produces 17 g of
(e) 32 ammonia.
31. (e) The reaction of three moles of hydrogen gas will
Balance the following equation with the smallest produce 17 g of ammonia.
whole number coefficients. Choose the answer that 36.
is the sum of the coefficients in the balanced Calcium carbide, CaC2, is an important preliminary
equation. Do not forget coefficients of "one." chemical for industries producing synthetic fabrics
Cr2(SO4)3 + RbOH Cr(OH)3 + Rb2SO4 and plastics. CaC2 may be produced by heating
calcium oxide with coke:
(a) 10 CaO + 3C CaC2 + CO
(b) 12
(c) 13 What is the amount of CaC2 which can be produced
(d) 14 from the reaction of excess calcium oxide and 10.2 g
(e) 15 of carbon? (Assume 100% efficiency of reaction for
32. purposes of this problem.)
Balance the following equation using minimum (a) 18.1 g
integral coefficients: (b) 28.4 g
NH3 + O2 NO2 + H2O (c) 20.8 g
(d) 19.8 g
The stoichiometric coefficient for oxygen gas O2 is: (e) 27.2 g
(a) 1 37.
(b) 4
 Calculate the mass of hydrogen formed when 25 (b) has the smallest molar mass (formula weight).
grams of aluminum reacts with excess hydrochloric (c) has the smallest coefficient.
acid. (d) is consumed completely.
2Al + 6HCl Al2Cl6 + 3H2 (e) is in excess.
42.
(a) 0.41 g If 5.0 g of each reactant were used for the the
(b) 1.2 g following process, the limiting reactant would be:
(c) 1.8 g 2KMnO4 +5Hg2Cl2 + 16HCl 10HgCl2 + 2MnCl2 +
(d) 2.8 g 2KCl + 8H2O
(e) 0.92 g
38. (a) KMnO4
When 12 g of methanol (CH3OH) was treated with (b) HCl
excess oxidizing agent (MnO4-), 14 g of formic acid (c) H2O
(HCOOH) was obtained. Using the following chemical (d) Hg2Cl2
equation, calculate the percent yield. (The reaction is (e) HgCl2
much more complex than this; please ignore the fact 43.
that the charges do not balance.) What mass of ZnCl2 can be prepared from the
3CH3OH + 4MnO4- 3HCOOH + 4MnO2 reaction of 3.27 grams of zinc with 3.30 grams of
(a) 100% HCl?
(b) 92% Zn +2HCl ZnCl2 + H2
(c) 82%
(d) 70% (a) 6.89 g
(e) 55% (b) 6.82 g
39. (c) 6.46 g
A commercially valuable paint and adhesive stripper, (d) 6.17 g
dimethyl sulfoxide (DMSO), (CH3)2SO, can be (e) 6.02 g
prepared by the reaction of oxygen with dimethyl 44.
sulfide, (CH3)2S, using a ratio of one mole oxygen to How many grams of NH3 can be prepared from 77.3
two moles of the sulfide: grams of N2 and 14.2 grams of H2? (Hint: Write and
O2 + 2(CH3)2S 2(CH3)2SO balance the equation first.)
(a) 93.9 g
If this process is 83% efficient, how many grams of (b) 79.7 g
DMSO could be produced from 65 g of dimethyl (c) 47.0 g
sulfide and excess O2? (d) 120.0 g
(a) 68 g (e) 13.3 g
(b) 75 g 45.
(c) 83 g Silicon carbide, an abrasive, is made by the reaction
(d) 51 g of silicon dioxide with graphite.
(e) 47 g SiO2 +3C SiC + 2CO
40.
The formation of ethyl alcohol (C2H5OH) by the If 100 g of SiO2 and 100 g of C are reacted as far as
fermentation of glucose (C6H12O6) may be possible, which one of the following statements will
represented by: be correct?
C6H12O6 2C2H5OH + 2CO2 (a) 111 g of SiO2 will be left over.
If a particular glucose fermentation process is 87.0% (b) 44 g of SiO2 will be left over.
efficient, how many grams of glucose would be (c) 82 g of C will be left over.
required for the production of 51.0 g of ethyl alcohol (d) 40 g of C will be left over.
(C2H5OH)? (e) Both reactants will be consumed completely, with
(a) 68.3 g none of either left over.
(b) 75.1 g 46.
(c) 115 g Calculate the mass of 6.00% NiSO4 solution that
(d) 229 g contains 40.0 g of NiSO4?
(e) 167 g (a) 667 g
(b) 540 g
(c) 743 g
41. (d) 329 g
The limiting reagent in a chemical reaction is one (e) none of these
that: 47.
(a) has the largest molar mass (formula weight).
 How many grams of water are contained in 75.0 out and balance the equation. Is this a limiting
grams of a 6.10% aqueous solution of K3PO4? reagent problem? )
(a) 75.0 g (a) 5.4 g
(b) 73.2 g (b) 0.92 g
(c) 70.4 g (c) 2.6 g
(d) 68.1 g (d) 1.9 g
(e) 62.8 g (e) 530 g
48. 54.
The mass (in grams) of FeSO4 7H2O required for What alkaline earth metal is located in period 3?
preparation of 125 mL of 0.90 M solution is: (a) Li
(a) 16 g (b) Na
(b) 25 g (c) Ca
(c) 13 g (d) Mg
(d) 31 g (e) Sr
(e) 43 g 55.
49. Which of the following is classified as a metal?
What is the molarity of phosphoric acid in a solution (a) Ge
labeled 20.0% phosphoric acid (H3PO4) by weight (b) As
with a density = 1.12 g/mL? (c) F
(a) 0.98 M (d) V
(b) 2.3 M (e) Ar
(c) 2.7 M 56.
(d) 3.0 M Which of the following is a weak acid?
(e) 3.6 M (a) H2SO4
50. (b) HClO3
How many mL of 17 M NH3 must be diluted to 500.0 (c) HF
mL to make a 0.75 M solution? (d) HCl
(a) 13 mL (e) HNO3
(b) 22 mL 57.
(c) 39 mL Which one of the following is likely to be the most
(d) 73 mL soluble base?
(e) none of these (a) Ca(OH)2
51. (b) Cu(OH)2
How many grams of Ag2CO3 are required to react (c) Ga(OH)3
with 28.5 mL of 1.00 M NaOH solution? (d) Zn(OH)2
Ag2CO3 +2NaOH Ag2O + Na2CO3 + H2O (e) Zr(OH)3
(a) 7.87 g 58.
(b) 3.93 g Which one of the following statements is TRUE?
(c) 15.7 g (a) One mole of any acid will ionize completely in
(d) 10.8 g aqueous solution to produce one mole of H+ ions.
(e) 8.16 g (b) Solutions of weak acids always have lower
52. concentrations of H+ than solutions of strong acids.
How many milliliters of 0.200 M NH4OH are needed (c) There are several common acids that are
to react with 12.0 mL of 0.550 M FeCl 3? insoluble.
FeCl3 + 3NH4OH Fe(OH)3 + 3NH4Cl (d) All of the IA and IIA metal hydroxides are soluble.
(e) All weak acids are insoluble.
(a) 99.0 mL 59.
(b) 33.0 mL Consider the following reaction:
(c) 8.25 mL NH3(g) + H2O(l) NH4+(aq) + OH-(aq)
(d) 68.8 mL Which one of the following statements is false?
(e) 132 mL (a) The double arrows indicate that ammonia, NH3, is
53. only very slightly soluble in water.
When 250. mL of a 0.15 M solution of ammonium (b) The reaction is reversible.
sulfide (NH4)2S is poured into 120. mL of a 0.053 M (c) When ammonia is added to water, NH4+ and
solution of cadmium sulfate CdSO4, how many grams OH- ions are produced in a 1:1 ratio.
of a yellow precipitate of cadmium sulfide CdS are (d) When solutions of NH4Cl and NaOH are mixed,
formed? The other product is (NH4)2SO4. (Hint: Write some ammonia is produced.
(e) Ammonia is considered to be a weak base.
60. (e) CH3COOH(aq) + OH-(aq) CH3COO-(aq) +
Which one of the following salts is insoluble? H2O(l)
(a) NH4Cl 66.
(b) Ca(NO3)2 What is the net ionic equation for the acid-base
(c) BaCO3 reaction that occurs when nitric acid is added to
(d) Na2S copper(II) hydroxide?
(e) Zn(CH3COO)2 (a) H+(aq) + OH-(aq) H2O(l)
61. (b) 2H+(aq) + Cu(OH)2(s) Cu2+(aq) + 2H2O(l)
What salt is formed in the following acid/base (c) 2HNO3(aq) +Cu(OH)2(s) Cu(NO3)2(s) + 2H2O(l)
reaction? (d) 2H+(aq) + 2NO3-(aq) + Cu2+(aq) + 2OH-(aq)
HClO3 + Ba(OH)2 Cu(NO3)2(s) + 2H2O(l)
(a) BaCl2 (e) 2H+(aq) + 2NO3-(aq) + Cu2+(aq) + 2OH-(aq)
(b) ClOBa Cu2+(aq) + 2NO3-(aq) + 2H2O(l)
(c) H2O 67.
(d) BaClO3 Which of the following statements is FALSE given the
(e) Ba(ClO3)2 following net ionic equation?
62. H3PO4(aq) + 3OH-(aq) PO43-(aq) + 3H2O(l)
The precipitate formed when barium chloride is (a) If all the water evaporated away, the salt
treated with sulfuric acid is _______ . remaining could possibly be Na3PO4.
(a) BaS2O4 (b) The acid, H3PO4, is a weak electrolyte.
(b) BaSO3 (c) The base involved must be a strong soluble base.
(c) BaSO2 (d) This is classified as a neutralization reaction.
(d) BaSO4 (e)This could be the net ionic equation for
(e) BaS H3PO4 reacting with Al(OH)3.
63. 68.
The spectator ion(s) in the following reaction is/are: Which of the following statements is FALSE given the
Na2CO3(aq) + Ba(NO3)2(aq) BaCO3(s) + following net ionic equation?
2NaNO3(aq) 2H+(aq) + Cu(OH)2(s) Cu2+(aq) + 2H2O(l)
(a) Na+ and Ba2+ (a) If all the water evaporated away, the salt
(b) Ba2+ and CO32- remaining could possibly be CuS.
(c) CO32- and NO3- (b) The acid involved must be a strong electrolyte.
(d) Na+ only (c) The base, Cu(OH)2, is an insoluble base.
(e) Na+ and NO3- (d) This could be the net ionic equation for
64. HNO3 reacting with Cu(OH)2.
Which one of the following statements is FALSE? (e) This is classified as a neutralization reaction.
(a) For the reaction of a strong acid with a strong 69.
soluble base, the net ionic equation is always Determine the oxidation number of carbon in K2CO3.
H+ + OH- H2O (a) 0
(b) "Spectator ions" appear in the total ionic (b) +2
equation for a reaction, but not in the net ionic (c) +4
equation. (d) -2
(c) HF, HCl, and HNO3 are all examples of strong (e) some other value
acids. 70.
(d) Titration is a process which can be used to Which assignment of oxidation number
determine the concentration of a solution. is INCORRECT for the blinking element?
(e) In a neutralization reaction, an acid reacts with (a) K2Cr2O7; +6
base to produce a salt and H2O. (b) NH3; +3
65. (c) H2PO2-; +1
What is the net ionic equation for the acid-base (d) SeO32-; +4
reaction that occurs when acetic acid and potassium (e) Cu(NO3)2; +2
hydroxide solutions are mixed? 71.
(a) H+(aq) + OH-(aq) H2O(l) Consider the following reaction:
(b) H+(aq) + KOH(s) K+(aq) + H2O(l) 4NH3 + 5O2 4NO + 6H2O
(c) CH3COOH(aq) + KOH(s) KCH3COO(aq) + The element being oxidized and the oxidizing agent
H2O(l) are:
(d) CH3COO-(aq) + H+(aq) + K+(aq) + OH-(aq) K+ (a) N and NH3
-
(aq) + CH3COO (aq) + H2O(l) (b) N and O2
(c) O and NH3
 (d) O and O2 (a) different numbers of protons.
(e) H and NH3 (b) equal numbers of neutrons.
72. (c) the same number of electrons.
Given that the Activity Series is: Na>Mg>Cu>Ag>Au, (d) the same mass numbers.
which one of the following answers represents the (e) the same masses.
ions that would not be displaced from aqueous 79.
solution (reduced) by metallic magnesium? What is the atomic weight of a hypothetical element
(a) Na+ consisting of two isotopes, one with mass = 64.23
(b) Cu2+ amu (26.0%), and one with mass = 65.32 amu?
(c) Cu2+ and Au+ (a) 65.3 amu
(d) Cu2+, Ag+ and Au+ (b) 64.4 amu
(e) Na+, Cu2+, Ag+ and Au+ (c) 64.9 amu
73. (d) 65.0 amu
Which name/formula combination is WRONG? (e) 64.8 amu
(a) phosphorous acid / H3PO4 80.
(b) nitrogen oxide / NO Naturally occurring rubidium consists of just two
(c) acetate ion / CH3COO- isotopes. One of the isotopes consists of atoms
(d) sodium chromate / Na2CrO4 having a mass of 84.912 amu; the other of 86.901
(e) calcium hypobromite / Ca(BrO)2 amu. What is the percent natural abundance of the
74. heavier isotope?
Which name/formula combination is WRONG? (a) 15%
(a) chlorous acid / HClO2 (b) 28%
(b) dinitrogen tetroxide / N2O4 (c) 37%
(c) ammonium nitrate / NH4NO3 (d) 72%
(d) copper(II) periodate / CuIO4 (e) 85%
(e) potassium permanganate / KMnO4 81.
75. What is the frequency of light having a wavelength of
Which of the following has a positive charge? 4.50 x 10-6 cm?
(a) proton (a) 2.84 x 10-12 s-1
(b) neutron (b) 2.10 x 104 s-1
(c) anion (c) 4.29 x 1014 s-1
(d) electron (d) 1.06 x 1022 s-1
(e) atom (e) 6.67 x 1015 s-1
76. 82.
Rutherford carried out experiments in which a beam The emission spectrum of gold shows a line of
of alpha particles was directed at a thin piece of wavelength 2.676 x 10-7 m. How much energy is
metal foil. From these experiments he concluded emitted as the excited electron falls to the lower
that: energy level?
(a) electrons are massive particles. (a) 7.43 x 10-19 J
(b) the positively charged parts of atoms are moving (b) 5.30 x 10-20 J
about with a velocity approaching the speed of light. (c) 6.05 x 10-19 J
(c) the positively charged parts of atoms are (d) 3.60 x 10-20 J
extremely small and extremely heavy particles. (e) 5.16 x 10-20 J
(d) the diameter of an electron is approximately 83.
equal to that of the nucleus. Which of the responses contains all the statements
(e) electrons travel in circular orbits around the that are consistent with the Bohr theory of the atom
nucleus. (and no others)?
77. (1) An electron can remain in a particular orbit as
Consider the species 72Zn, 75As and 74Ge. These long as it continually absorbs radiation of a definite
species have: frequency.
(a) the same number of electrons. (2) The lowest energy orbits are those closest to the
(b) the same number of protons. nucleus.
(c) the same number of neutrons. (3) An electron can jump from the K shell (n = 1
(d) the same number of protons and neutrons. major energy level) to the M shell (n = 3 major
(e) the same mass number. energy level) by emitting radiation of a definite
frequency.
78. (a) 1,2,3
The neutral atoms of all of the isotopes of the same (b) 2 only
element have (c) 3 only
 (d) 1,2 (c) [Kr] 4s1 3d8
(e) 2,3 (d) [Kr] 4s2 3d8
84. (e) [Ar] 4s2 3d8
The Heisenberg Principle states that _____________. 90.
(a) no two electrons in the same atom can have the The outer electronic configuration
same set of four quantum numbers. ns2np4 corresponds to which one of the following
(b) two atoms of the same element must have the elements in its ground state?
same number of protons. (a) As
(c) it is impossible to determine accurately both the (b) Ca
position and momentum of an electron (c) Cr
simultaneously. (d) Br
(d) electrons of atoms in their ground states enter (e) S
energetically equivalent sets of orbitals singly before 91.
they pair up in any orbital of the set. In the ground state of a cobalt atom there are _____
(e) charged atoms (ions) must generate a magnetic unpaired electrons and the atom is _____.
field when they are in motion. (a) 3, paramagnetic
85. (b) 5, paramagnetic
Which statement about the four quantum numbers (c) 2, diamagnetic
which describe electrons in atoms is incorrect? (d) 0, diamagnetic
(a) n = principal quantum number, n = 1, 2, 3, ...... (e) 2, paramagnetic
(b) l = subsidiary (or azimuthal) quantum number, l = 92.
1, 2, 3, ... , (n+1) Which one of the following sets of quantum
(c) ml = magnetic quantum number, ml = (-l), .... , numbers could be those of the distinguishing (last)
0, .... , (+l) electron of Mo?
(d) ms = spin quantum number, ms = +1/2 or -1/2. (a) n = 4, l = 0, ml = 0, ms = +1/2
(e) The magnetic quantum number is related to the (b) n = 5, l = 1, ml = 9, ms = -1/2
orientation of atomic orbitals in space. (c) n = 4, l = 2, ml = -1, ms = +1/2
86. (d) n = 5, l = 2, ml = +2, ms = -1/2
Which atomic orbital is spherical in shape? (Note: (e) n = 3, l = 2, ml = 0, ms = +1/2
you should know and be able to recognize the 93.
shapes of the s orbital, px, py, and pz orbitals, and dxy, How many p electrons are there in an atom of
dyz, dxz, dx2-y2 and dz2 orbitals.) rubidium?
(a) 2s (a) 12
(b) 3p (b) 18
(c) 3d (c) 24
(d) 4f (d) 9
(e) they are all spherical (e) 6
87. 94.
The maximum number of electrons that can be A neutral atom of an element has 2 electrons in the
accommodated in a sublevel for which l = 3 is: first energy level, 8 in the second energy level and 8
(a) 2 in the third energy level. This information
(b) 10 does not necessarily tell us:
(c) 6 (a) the atomic number of the element.
(d) 14 (b) anything about the element's chemical
(e) 8 properties.
88. (c) the total number of electrons in s orbitals.
The ground state electron configuration for arsenic (d) the total number of electrons in p orbitals.
is: (e) the number of neutrons in the nucleus of an
(a) [Ar] 4s2 4p13 atom of the element.
(b) [Kr] 4s2 4p1 95.
(c) 1s2 2s2 2p6 3s2 3p6 3d12 4s2 4p1 The atom having the valence-shell configuration
(d) 1s2 2s2 2p6 3s2 3p6 4s2 3d8 4p5 4s2 4p5 would be in:
(e) 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3 (a) Group VIA and Period 5
(b) Group IVB and Period 4
89. (c) Group VIB and Period 7
Which of the following electron configurations is (d) Group VIIA and Period 4
correct for nickel? (e) Group VIIB and Period 4
(a) [Ar] 4s1 3d8 96.
(b) [Kr] 4s1 4d8
 Select the term best describing the series of Which of the following elements has the greatest
elements: Mn, Fe, Co, Ni, Cu. attraction for electrons in a covalent bond?
(a) d-transition metals (a) Ge
(b) representative elements (b) As
(c) metalloids (c) Se
(d) alkaline earth metals (d) Br
(e) halogens (e) Bi
97. 104.
Which element has the largest atomic radius? Which statement is wrong?
(a) Li (a) The atomic weight of carbon is about 12.
(b) Na (b) The most stable ion of lithium is Li+.
(c) Rb (c) A phosphorus atom is larger than an antimony
(d) F atom.
(e) I (d) The radius of a sodium atom is larger than that of
98. a sodium cation.
Which of the following terms accurately describes (e) Oxygen has a less negative electron affinity than
the energy associated with the process: fluorine.
Li(g) Li+(g) + e- 105.
(a) electron affinity All of the following properties of the alkaline earth
(b) binding energy metals increase going down the group except
(c) ionization energy (a) atomic radius
(d) electronegativity (b) first ionization energy
(e) none of these (c) ionic radius
99. (d) atomic mass
The species that contains 24 protons, 26 neutrons (e) atomic volume
and 22 electrons would be represented by the 106.
symbol: Which of the following is an ionic hydride?
(a) 50V3+ (a) PH3
(b) 26Cr2+ (b) H2S
(c) 50Cr2+ (c) HI
(d) 50Mn2+ (d) KH
(e) none of these (e) CH4
100. 107.
Which element has the lowest first ionization Which of the following is the most basic oxide?
energy? (a) N2O3
(a) He (b) N2O5
(b) Ne (c) P4O6
(c) Ar (d) P4O10
(d) Kr (e) Bi2O5
(e) Xe
101.
Which element has the highest first ionization
energy? (Note: this is an exception to the general
trend - see notes- you may be responsible for this.)
(a) Be
(b) B
(c) C
(d) N
(e) O
102.
Which of these isoelectronic species has
the smallest radius?
(a) Br-
(b) Sr2+
(c) Rb+
(d) Se2-
(e) They are all the same size because they have the
same number of electrons.
103.
ANSWER KEY 58. B
59. A
1. E 60. C
2. B 61. E
3. A 62. D
4. C 63. E
5. D 64. C
6. D 65. E
7. D 66. B
8. E 67. E
9. C 68. A
10. D 69. C
11. E 70. B
12. A 71. B
13. B 72. A
14. D 73. A
15. B 74. D
16. D 75. A
17. D 76. C
18. A 77. C
19. C 78. C
20. E 79. D
21. B 80. B
22. B 81. E
23. E 82. A
24. A 83. B
25. B 84. C
26. C 85. B
27. E 86. A
28. B 87. D
29. B 88. E
30. A 89. E
31. B 90. E
32. D 91. A
33. E 92. C
34. E 93. B
35. E 94. E
36. A 95. D
37. D 96. A
38. C 97. C
39. A 98. C
40. C 99. C
41. D 100. E
42. D 101. D
43. D 102. B
44. B 103. D
45. D 104. C
46. A 105. B
47. C 106. D
48. D 107. E
49. B
50. B
51. B
52. A
53. B
54. D
55. D
56. C
57. A