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Electrons in Atoms
Bohr atomic model- electrons can have only specific values of energy- can revolve in only discrete orbitals
Wave mechanical model is accepted
quantum numbers- size, shape, and spatial orientation and spin
Pauli exclusion principle
ground state
stable electron configurations
electropositive and electronegative
Imperfections in solids
Why study of effects is important??
Point- vacancy , self interstitial
Linear defects- edge, screw dislocation , burgers defects
Interfacial defects-external, grain, stacking faults, twin , twist ,tilt etc.
Microscopic detection – optical, scanning probe, electron
Phase Diagrams
Solid solution, componenets, system
Solubility limit, ex- sugar solution, solubility diagram, phase- boundaries, chemical physical or bothhases
Microstructure, phase equilibria-constancy of phase prop, metastable structures
Phase dia- 3 factors , urnary dia, phase dia for h20
Binary Phase Diagrams-pre held constant, cu-ni alloy, 3 phases, isomorphous systems
α,β, solidus line, liquidus line
INTERPRETATION OF PHASE DIAGRAMS- phases present , composition of phases, phase amounts
DEVELOPMENT OF MICROSTRUCTURE IN ISOMORPHOUS ALLOYS on solidification under equilibrium cooling and non
equilibrium cooling