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condition?
Define liquid crystal polymer with examples. Identify the advantages of applying liquid
crystal polymer in engineering and medical sciences.
Explain the mechanism of conduction in Poly-acetylene.
Explain the energy of an ideal gas change if it is made to expand into vacuum at constant
temperature?
Calculate the change in enthalpy for the following reaction with equilibrium constants, Kp =
50.0 at 448 ºC and 66.9 at 350 ºC, respectively. H2(g) + I2(g) = 2HI(g)
Define partial molar property and deduce the expression for Gibbs free energy?
Define enthalpy and discuss the significance of work function?
Define lyophillic and lyophobic colloids and compare them critically?
Discuss the factors affecting the CMC of surfactants?
State thermodynamic equilibrium and write expression for thermodynamic state equation?
Define free energy, enthalpy, enthalpy and entropy and identify the relation among them?
Explain different types of molecular weight method for polymers? How are they determined
& expressed mathematically?
Discuss the mechanism of free radical polymerization with all steps?
Distinguish intensive and extensive properties with examples?
State the entropy of a perfect crystal at zero temperature and give its significance?
Define polymer? What are the different criteria for classification of polymer
Explicate the factors responsible for altering CMC of surfactant molecules?
(a) Illustrate the significance of partial molar property and discuss its determination by
method of intercepts?
(b) A chemist found that the energy of a system decreases during a specific spontaneous
endothermic change in state. Comment?
(a) Correlate any two factors which alters the rate of reaction?
(b) Construct the following diatomic molecules in the ascending order of their standard
entropies. H2, N2, HF, Cl2, NO
(a) Discuss the significance of third law of thermodynamics and mention two apparent
exceptions?
(b) Distinguish between micelle and reverse micelle
(a) Compare solution and suspension polymerization
(b) Classify polymers with examples?
(a) Deduce the relation between pressure and temperature for the condition of equilibrium
phase boundaries?
(b) Deduce a correlation between the composition in liquid phase and the partial vapour pressures in
the gaseous phase?