Geethanjali

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Time : 60 Min Chem : Atomic Structure Marks : 120

61) The number of unpaired electrons in the Fe2 69) The frequency corresponding to transition
ion is n  2 to n = 1 in hydrogen atom is
A) 0 B) 3 A) 40.57  1024 Hz B) 30.57  1014 Hz
C) 4 D) 6
C) 24.66  1014 Hz D) 15.66  1010 Hz
62) The energy of second Bohr orbit of the 70) If wavelength of photon is 2.2 x 10-11 m,
hydrogen atom is -328 kJ mol-1, hence the energy
of fourth Bohr orbit would be h = 6.6  1034 j-s, then momentum of photon is
A) -1312 kJ mol-1 B) -164 kJ mol-1 A) 6.89  1043 kg ms1
C) - 82 kJ mol-1 D) - 41 kJ mol-1 B) 1.452  1044 kg ms1
63) Energy of electron of hydrogen atom in second C) 3.33  1022 kg ms1
Bohr orbit is D) 3  1023 kg ms1
A) 5.44  1019 eV B) 5.44  1019 cal
71) The value of the energy for the first excited
C) 5.44  1019 kJ D) 5.44  1019 J
state of hydrogen atom will be
A)  0.85 eV B)  1.51 eV
64) The postulate of Bohr theory that electrons
jump from one orbit to the other, rather than flow C)  3.40 eV D)  13.6 eV
is according to
A) Heisenberg uncertainty principle. 72) The radius of first Bohr's orbit for hydrogen is
B) the probability expression for electron. 0.53 Å. The radius of third Bohr's orbit would be
C) the wave nature of electron. A) 4.77 Å B) 3.18 Å
D) the quantization concept. C) 1.59 Å D) 0.79 Å
73) The energy of electron in hydrogen atom in its
65) The emission spectrum of hydrogen is found to grounds state is -13.6 eV. The energy of the level
satisfy the expression for the energy change. E corresponding to the quantum number equal to 5
 1 1  is
(in joules) such that E  2.18  10  2  2  J , A) - 0.40 eV B) - 0.54 eV
n 
 1 n2  C) - 0.64 eV D) - 0.85 eV
where n1 = 1, 2, 3,... and n2 = 2, 3, 4,... The
spectral lines correspond to Paschen series are 74) Which of the following is not isoelectronic?
A) n1  2 and n2  3, 3, 5 A) Cl  B) O2
B) n1  1 and n2  3, 4, 5 C) Mg 2 D) Na 
C) n1  3 and n2  4, 5, 6 75) In an element going away from nucleus, the
D) n1  1 and n2  2, 3, 4 energy of particle
A) decreases. B) increases.
66) Splitting of spectral lines under the influence of C) not changing. D) none of these.
magnetic field is called
76) The radius of electron in the first excited state
A) Zeeman effect.
of hydrogen atom is
B) photoelectric effect.
C) stark effect. A) 8 a 0 B) 4 a 0
D) none of these. C) 2a 0 D) a 0

77) Bohr model of an atom could not account for

67) The energy of an electron in nth orbit of
A) fine spectrum.
hydrogen atom is
B) line spectrum of hydrogen.
13.6 13.6
A) eV B) eV C) absorption spectrum.
n n2 D) emission spectrum.
13.6 13.6
C) 3
eV D) eV 78) If change in energy
n n4 8 34
(E)  3  10 J, h  6.64  10 J -s and
68) The number of electrons in one molecule of c  3  108 m /s, then wavelength of the light is
CO2 are
A) 6.36  1018 Å B) 6.64  108 Å
A) 88 B) 66
C) 44 D) 22 C) 6.36  105 Å D) 6.36  103 Å

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 Geethanjali

79) The ratio between kinetic energy and the total A) Be3 (n  2) B) Li2 (n  3)
energy of the electrons of hydrogen atom according
to Bohr's model is C) Li2 (n  2) D) He (n  2)
A) 1 : 2 B) 1 : - 1
C) 1 : 1 D) 2 : 1 90) Rutherford's  -particle scattering experiment
proved that atom has
80) The ionization potential of a hydrogen atom is - A) electrons B) neutron
13.6 eV. What will be the energy of the atom C) nucleus D) orbitals
corresponding to n = 2?
A) - 1.7 eV B) - 2.7 eV
C) - 3.4 eV D) - 6.8 eV

81) If electron falls from n = 3 to n = 2, then

emitted energy is
A) 0.65 eV B) 1.9 eV
C) 10.2 eV D) 12.09 eV

82) The frequency of radiation emitted when the

electron falls from n = 4 to n = 1 in a hydrogen
atom will be (Given ionization energy of H
 2.18  1018 J atom1 and h  6.625  1034 Js )
A) 1.03  1015 s 1 B) 1.54  1015 s 1
C) 2.00  1015 s1 D) 3.08  1015 s1

83) In Bohr's model, atomic radius of the first orbit

is  , the radius of the 3rd orbit, is
A) 9  B) 3 
C)  D)  / 3

84) Which of the following transitions have

minimum wavelength?
A) n2  n1 B) n3  n1
C) n4  n1 D) n4  n2

85) Bohr's radius can have

A) fractional values. B) -ve values.
C) +ve values. D) discrete values.

86) Who modified Bohr's theory by introducing

elliptical orbits for electron path?
A) Somerfield B) Rutherford
C) Thomson D) Hund

87) Nuclei tend to have more neutrons than

protons at high mass numbers because
A) neutrons decrease the binding energy.
B) more neutrons minimize the coulomb repulsion.
C) neutrons have more mass than protons.
D) neutrons are neutral particles.

88) If the atomic weight of an element is 23 times

that of the lightest element and it has 11 protons,
then it contains
A) 11 protons, 11 neutrons, 23 electrons.
B) 11 protons, 12 neutrons, 11 electrons.
C) 11 protons, 11 neutrons, 11 electrons.
D) 11 protons, 23 neutrons, 11 electrons.

89) The radius of which of the following orbit is

same as that of the first Bohr's orbit of hydrogen
atom?

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