Marks: 70 Volume- 1 Timing:-21/2 Hours

Date: 25th Aug 2019 Class-XII Chemistry (Paper-1&2)

Note:
i. All questions are compulsory.
ii. Draw neat, labelled diagrams wherever necessary.

Section A: Select and write the most appropriate answer from the given alternative for
Q. No.1 to 4 of multiple choice type questions carrying one mark each and Q.No.5 to 8 are
very short answer type of questions carrying one mark each.
Section B: contains Q. No. 9 to 15 of short answer-I type questions carrying two marks each. Internal choice
is provided to only one question.
Section C: contains Q. No. 16 to 26 of short answer-II type of questions carrying three marks each. Internal
choice is provided to only one question
Section D: contains Q. No. 27 to 29 of long answer type of questions carrying five marks each.

SECTION A
𝑟+
Q.1. An ionic crystal lattice has 𝑟 − radius ratio of 0.320, its coordination number is _______.
(A) 3 (B) 4 (C) 6 (D) 8
Q.2. The chemical formula of willemite is _______.
(A) ZnS (B) ZnCO3 (C) ZnO (D) Zn2SiO4
Q.3. Identify ‘A’ in the following reaction:

(A) 2-Bromo-2-methylbutane
(B) 1-Bromo-2,2-dimethylpropane
(C) 1-Bromo-3-methylbutane
(D) 1-Bromo-2-methylpropane
Q.4. The preparation of alkyl fluoride from alkyl chloride, in presence of metallic fluorides is known as _______.
(A) Williamson’s reaction (B) Finkelstein reaction
(C) Swarts reaction (D) Wurtz reaction
Q.5. Define the term flux.
Q.6. How is ethyl bromide prepared from ethyl alcohol.
Q.7. What is a Grignard reagent?
Q.8. What is the ratio of octahedral holes to the number of anions in hexagonal closed packed structure?

SECTION B

Q.9. Iron (Z=26) is strongly ferromagnetic. Explain.

Q.10. Which are the various step involved in the extraction of pure metals from their ores.
Q.11 Draw structural formula and write the IUPAC name of DDT.
Q.12. An atom C and D from fcc crystalline structure. Atom C is present at the corners of the cube and D is at the
face centres of the cube. What is the formula of the compound?
Q.13. Draw neat labeled diagram of Bessemer converter.

OR
State and explain Markownikoff’s rule.
Q.14. Identify A and B for the reaction given below:

Q.15. How will you convert the following?

1) Chlorobenzene to cyanobenzene (1)
2) Chlorobenzene into diphenyl (1)

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 SECTION C

Q.16. Define Anisotropy. Distinguish between crystalline solids and amorphous solids.
Q.17. i) Write the name and formula of any one ore of iron. (1)
ii) Write the reaction involved in the zone of reduction in blast furnace during extractions of iron. (1)
Q.18. Explain the optical activity of lactic acid.
Q.19. Write the product of following reaction:

Q.20. Silver Crystallises in FCC structure. If density of silver is 10.51 gcm-3, calculate volume of unit cell.
[Atomic mass of silver (Ag) =108 gm-1]
Q.21. i) What is an Ellingham diagram? (1)
ii) Write the formula of copper pyrites and bauxite (2)
Q.22. Write the preparation of isopropyl chloride using the following reagents:
i) PCl3 ii) PCl5 iii) SOCl2
Q.23. i) What is the role of CaF2 in the metallurgy of aluminium? (1)
ii) Write the chemical reaction involved in van Arkel method for refining of (2)
(a) titanium
(b) zirconium
Q.24. Distinguish between SN1 reaction and SN2 reaction.

OR
Write the IUPAC of following:

Q.25. Calculate packing efficiency in the body centre cubic structure.

Q.26. Define the following terms:
1) Metallurgy
2) Calcinations
3) Smelting
SECTION D

Q.27. Discuss SN2 mechanism of methyl bromide using aqueous KOH. Draw energy profile diagram.
Identify A, B in the reaction given below:

OR
Write a note on:
1) Friedel Craft’s Reaction 2) Wurtz reaction

Q.28. Define Co-ordination number.

Determine the density of Cesium chloride which crystallizes in BCC type structure with the edge
length 412.1 pm. The atomic masses of Cs and Cl are 133 and 35.5 respectively. Predict the
Co-ordination No. of Cs+ ion if 𝑟𝐶𝑠+ = 1.69 and 𝑟𝐶𝑙 − = 1.81
Q.29. Draw neat well labelled diagram of electrolytic cell for the extraction of aluminium.
Describe magnetic separation.

“All the best”

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