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S1041406F1
S104/B
EXPLORING SCIENCE
This examination consists of THREE Parts (A, B and C), all of which
should be attempted. For each Part, the following table indicates the
type of question, the choice of question (if any), the recommended
allocation of your time and the proportion of marks awarded.
You are provided with a computer marked examination (CME) form for
Part A, graph paper and an answer book. Answer the Part B question
and each of your chosen two Part C questions in the answer book
together with graph paper where required. Additional answer books and
graph paper are available from the invigilator if required.
A list of standard equations and constants is provided with this
examination paper as a separate insert.
(1) You will find one CME form provided with this paper. The invigilator has a
supply of spare forms if you should need any.
(2) You should use an HB pencil to make entries on the CME form. If you make
any smudges or other spurious marks on the form which you cannot cancel
out clearly, you should ask the invigilator for a new form, and transfer your
entries to it.
(3) If you do not wish to answer a question, pencil across the ‘don’t know’ cell
(‘?’).
(4) If you think that the question is unsound in any way, pencil across the
‘unsound’ cell (‘U’), in addition to pencilling across either an answer cell or
the ‘don’t know’ cell.
(5) For each question you must pencil across either a single answer cell or the
‘don’t know’ cell.
(6) We suggest that in the first instance, you answer by pencilling across the
facsimile CME rows reproduced opposite. Check your answers before
transferring them to your CME form.
(7) You should note that NO ADDITIONAL TIME will be allowed at the end of
the three-hour period for transferring your marks to the CME form. Time for
this is included in the 1 hour 20 minutes for Part A.
(8) On Part 1 of the CME form you must write in your personal identifier (NOT
the examination number) and the ‘assignment number’ for this examination
(S104 81). You should also pencil across the cells in the two blocks in Part 1
of the CME form corresponding to your personal identifier and assignment
number given above. We suggest that you check that Part 1 of the CME
form has been completed correctly before moving on to Part B of the
examination paper.
(9) Failure to follow the above instructions may mean that we shall not be able
to award you a mark for this Part of the examination.
Note
You may use a page at the back of any of your answer books for any rough work
required in Part A. Please note that this rough work will not be considered by the
examiners.
Question 1 Table 1 shows the rainfall as measured at a location in Durham, England (UK),
over a 6-month period in 2011.
Table 1 For use with Q1.
Year April May June July Aug Sept
Rainfall / mm 7.2 40.0 48.4 65.6 125.0 28.4
To two significant figures, by how much did carbon emissions rise between 1975
and 2000?
KEY for Q3
A 53%
B 51%
C 66%
D 68%
E 57%
Component Proportion of
Number of
total number of
molecules/m−3
molecules/%
nitrogen 2.0 × 1025 77.6
24
oxygen 5.4 × 10 20.9
23
argon 2.4 × 10 0.93
23
water vapour 1.3 × 10 0.5
21
carbon dioxide 9.7 × 10 3.8 × 10−2
Table 3 shows that the proportion of CO2 molecules in the air is 3.8 × 10−2 % of
the total number of molecules in the air.
Which one of A–E below correctly expresses this proportion in parts per million
(ppm)?
KEY for Q4
A 3800
B 38
C 97
D 380
E 970
Question 5 The equation for the volume of a cylinder of radius r and height h is given by:
V πr 2 h
Which one of the following is the correct rearrangement of this equation to make
r the subject?
KEY for Q5
V2
A r=
πh
V
B r=
πh
V
C r
πh
D r = V 2 πh
E r = Vπh
Question 7 In the final stage of the proton–proton chain which powers stars such as our Sun,
two 23 He nuclei fuse together to produce two protons and which other product?
KEY for Q7
A one 23 He nucleus
B one 42 He nucleus
E one 53 Be nucleus
Question 9 Which one of the following combinations of quarks and antiquarks forms a
hadron?
KEY for Q9
A one quark and one antiquark
B three antiquarks and a quark
C two quarks and two antiquarks
D two quarks and an antiquark
E three quarks and an antiquark
Question 11 Which one of the following, to the nearest whole number, is the relative molecular
mass for paracetamol, which has a chemical formula of C8H9NO2?
Question 12 Which one of the following best describes the functional groups found in the
molecule in Figure 2? Note: For the purpose of this question, the benzene ring
should not be considered as a functional group.
O
C
H3C NH
CH2
Cl
Time/h 0 2 4 6 8 10
Mass of 37 °C 0.1 1 3 8 10 11
bacterial 4 °C 0.1 0.1 0.3 0.8 1.2 1.8
growth/µg
Question 17 Haemophilia is a human blood clotting disorder that is associated with an allele
found on the X chromosome. The defective allele Xh is recessive whereas the
allele that produces healthy clotting factors is dominant XH.
Which one of the following genotypes would not be a possible outcome in the
children of a man without haemophilia and a woman who is a carrier?
KEY for Q17
A XHXH
B XHXh
C XHY
D XhYH
E XhY
70 70
60 60
mass/%
mass/%
50 50
40 40
30 30
20 20
10 10
0 0
128 64 32 16 8 4 2 0.20 0.18 0.16 0.14 0.12 0.10 0.08 0.06
grain size/mm grain size/mm
90 90
C D
80 80
70 70
60 60
mass/%
mass/%
50 50
40 40
30 30
20 20
10 10
0 0
0.128 0.064 0.032 0.016 0.008 0.004 0.002 8 4 2 1 0.50 0.25 0.12
grain size/mm grain size/mm
90
E
80
70
60
mass/%
50
40
30
20
10
0
7.0 6.5 6.0 5.5 5.0 4.5 4.0
grain size/mm
temperature/°C
0 200 400 600 800
0 0
5
2
10
high
LOW GRADE
pressure/ 108 Pa
geothermal
4 gradient
depth/km
15
20
6
typical 25
geothermal
8 gradient M
HIGH GRADE 30
low
geothermal
gradient
10 35
key
contact metamorphism
regional metamorphism
100
S mica
AL
proportion of minerals
pyroxene R
NE amphibole
75 MI
by volume/%
IC
M AF
50
olivine alkali
plagioclase FELS feldspar
feldspar IC MIN
25 ERA
LS
quartz
0
increasing Si, Na, K
Question 21 A zircon isolated from a volcanic ash layer has a 207Pb/235U ratio of 3
corresponding to 2 half lives of 235U. Given the half-life of 235U is 7.040 × 108
years, estimate the age of the volcanic ash, in Ma.
KEY for Q21
A 352 Ma
B 1408 Ma
C 2112 Ma
D 1056 Ma
E 2816 Ma
Question 23 Figure 6 shows the radial speed (the magnitude of the radial velocity) of a star, as
calculated from Doppler shifts over a period of time. The data indicate that there
might be a planet orbiting the star because the radial speed seems to be varying
periodically. What is the orbital period of the planet?
24.120
24.100
24.080
Vr /km s−1
24.060
24.040
24.020
24.000
0 40 80 120 160 200 240
time/days
Question 25 Table 5 gives the mass (relative to the mass of the Earth, ME), orbital radii and
orientation of five extrasolar planets A–E orbiting similar stars in five different
systems at similar distances from the Earth. Which one of the planets is most
likely to be detected using the planetary transit technique?
(a) Plot these data on a graph, plotting Quantity A on the x-axis. You should
label the axes of your graph and give your graph an appropriate title.
(4 marks)
(b) Draw a best-fit straight line through your plotted data (you should use a
ruler).
(1 mark)
(c) From your completed graph, determine the values for
(i) the gradient and
(ii) the intercept of your best-fit straight line.
Include the units for both and give your answers in scientific notation and to
two significant figures. Indicate on your graph how you have determined the
gradient and intercept values but give any calculations in the exam answer
book.
(5 marks)
(d) Give the equation for your straight line graph using the values for the
gradient and intercept you determined in (c).
(1 mark)
Question 27 (a) Describe the energy transfers and conversions that take place in the
following scenario. A child:
(i) winds up a clockwork car which, when released,
(ii) first drives across a table at a constant velocity and
(iii) then slows gradually to a stop.
(Guideline: up to 150 words.)
(8 marks)
(b) A light emitting diode (LED) has a power output of 60 mW. If a grain of rice
with a mass of 0.03 g were converted fully to energy, for how many years
would the energy released power the LED? You can assume there are
3.16 × 107 seconds in a year. Give your answer to two significant figures and
in scientific notation.
(6 marks)
(c) A laser radiates light at 630 nm. If this laser’s energy output is 100 mJ s−1
how many photons does it emit every second? Give your answer to two
significant figures and in scientific notation.
(6 marks)
[I2 ] [Cl2 ]
K=
[ICl]2
What is the concentration of ICl in the vessel? Give your answer to the
appropriate number of significant figures.
(iii) What would be the effect of adding more ICl to the reaction in part (i)?
Explain your reasoning.
(9 marks)
(i) Sketch a copy of Compound 1 and highlight the chiral carbon with an
asterisk (*). Explain your selection. (Guideline: one or two sentences.)
(ii) In the presence of a suitable catalyst, Compound 1 will react with pure
hydrogen gas (H2). Draw the structure of the major product and name
its functional group.
(iii) Name the type of reaction that is described in (b)(ii).
(iv) The reaction in (b)(ii) will not proceed at 25 °C and 1 atmosphere
unless a catalyst is present. Explain the role of the catalyst in this
reaction. (Guideline: two or three sentences.)
(7 marks)
(c) At 25 °C sodium metal reacts with water via the following reaction to
produce aqueous sodium hydroxide and hydrogen gas.
(b) In a particular woodland ecosystem, of the 1.0 × 1010 kJ ha−1 y−1 of energy
entering the system from the Sun, only 1.9 × 102 kJ ha−1 y−1 ends up as
biomass in the highest carnivore, a secondary consumer.
(i) Express this biomass as a percentage of the incident solar energy.
(ii) Explain where most of the energy has gone and why there are
progressively fewer organisms as you move from herbivore level to
highest carnivore level within an ecosystem.
(5 marks)
(c) (i) Name and describe the two processes that lead to the recombination of
alleles during meiosis (Guideline: three or four sentences.)
(ii) What type of cell is produced as a result of meiosis?
(5 marks)
M J A
B
E
I
N S
10 m
1 km
tion C
p osi
a com e, C
a
agm g, F
m gM
ng e in eas
in
r
cha dec
N a, K
Si,
ng
reasi
inc
A B
accumulated
crystals
accumulated
crystals
cooling
Useful constants
magnitude of the acceleration due to g = 9.8 m s−2
gravity on Earth
Newton’s universal gravitational G = 6.7 × 10−11 N m2 kg−2
constant
Coulomb’s law, constant of ke = 9.0 × 109 N m2 C−2
proportionality
Avogadro constant = 6.02 × 1023 mol−1
Hubble constant = 70 km s−1 Mpc−1
Planck’s constant h = 6.63 × 10−34 J s
speed of light c = 3.0 × 108 m s-1
charge of proton +e = 1.6 × 10−19 C
charge of electron −e = −1.6 × 10−19 C
mass of proton = 1.7 × 10−27 kg
mass of neutron = 1.7 × 10−27 kg
mass of electron = 9.3 × 10−31 kg
astronomical unit AU = 1.5 × 1011 m
y = mx + c
4 3
volume of a sphere V = πr
3
area of a circle = πr 2
1
Ek = mv 2
2
continued overleaf
m
ρ=
V
F =
ma
q = mcΔT
q = Lv m
q = Lf m
ΔV = RI
P = IΔV
v = fλ
Δλ
z=
λ0
v = z×c
v = H0 × r
⎛ [H + (aq)] ⎞
pH = −1og ⎜ −3 ⎟
⎝ mol dm ⎠
E = mc 2
separation distance
speed of separation =
elapsed time
rstar m
= planet
rplanet mstar
rise
gradient =
run
−13.60
En = Z 2 × eV
n2
Eph = hf
L
F=
4πr 2
Q1Q2
Fe = − ke
r
2
m1m2
Fg = G
r2
mass of substance
number of moles of a substance =
molar mass of substance
GPP = NPP + R
2
Periodic Table of the Elements
1.01
23.0
6.94
85.5
39.1
223
133
Na
Rb
Fr
Cs
19
87
55
11
37
Li
H
K
1
francium caesium rubidium potassium sodium lithium hydrogen
87.6
24.3
40.1
9.01
137
226
Mg
Ra
Ba
Be
Ca
Sr
88
56
38
12
20
4
227
139
Ac
La
89
57
radium barium strontium calcium magnesium beryllium
actinium lanthanum
88.9
45.0
Ce
232
140
262
103
175
Th
Sc
Lu
Lr
90
58
71
39
21
Y
thorium cerium lawrencium lutetium yttrium scandium
91.2
47.9
231
141
Pa
104
178
Pr
Hf
91
59
Zr
72
40
22
Ti
protactinium praseodymium hafnium zirconium titanium
92.9
50.9
Nd
Nb
238
144
105
181
Ta
92
60
73
41
23
U
V
uranium neodymium tantalum niobium vanadium
Pm
52.0
Np
237
145
95.9
106
184
Mo
Cr
W
93
61
74
24
42
neptunium promethium tungsten molybdenum chromium
Sm
244
150
98.9
54.9
Mn
Pu
Re
107
186
94
62
Tc
75
43
25
plutonium samarium rhenium technetium manganese
55.8
Am
152
108
190
101
Os
Ru
243
Eu
Fe
95
63
76
44
26
americium europium osmium ruthenium iron
Cm
58.9
Gd
Rh
Co
247
157
109
192
103
96
64
77
45
27
Ir
106
Pd
159
247
Tb
Bk
Pt
78
46
65
Ni
97
28
108
Au
Ag
251
163
Dy
Cu
Cf
79
47
98
66
29
165
Ho
Cd
112
Es
Zn
Hg
201
99
67
30
48
80
27.0
Fm
204
Ga
167
115
257
100
Er
81
49
Al
68
Tl
In
31
13
B
5
72.6
28.1
169
207
119
258
101
Ge
Pb
Sn
82
50
Si
69
32
14
C
6
31.0
173
122
No
209
Yb
Sb
259
102
As
70
51
Bi
83
33
15
N
P
16.0
32.1
128
209
Po
Se
Te
84
52
34
16
O
S
35.5
127
210
53
Br
At
Cl
85
35
17
F
I
39.9
20.2
222
131
Rn
He
Xe
Ne
Kr
Ar
86
54
36
18
10