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Table of Contents
“Evaluating the Performance Characteristics of Abrasive
Media” written by Chad Quatman. This article discusses
media selection based on type, size, and shape. 3
“The Importance of Monitoring Abrasive Cleanliness” written
by John Todd. Oil, salt, or rust contamination on an abrasive
may be transferred to the surface during blast cleaning 9
operations and adversely affect long term coating
performance.
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Abrasive blasting is used to prepare a surface for coating by removing rust, mill
scale, or paint and to provide a profile to improve bonding. It sounds simple
enough, however selecting the correct abrasive is a complicated task. Abrasive
media are evaluated for relevant physical attributes for a number of reasons: to
determine if the media meets specification requirements, to determine if it is
detrimental to the health of the user or the environment, and to compare
performance such as productivity and consumption.
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Types of Abrasives
Various abrasive types offer different advantages depending on the intended use.
It is important to understand the differences and to select the appropriate media
for the job. Table 1 lists the different types of abrasive media, ideal uses, and
certain characteristics. Abrasives used for blast cleaning are generally divided into
two categories: expendable and recyclable. Expendable abrasives are highly
friable and breakdown at a relatively high rate, making them too small (and too
dusty) to reuse; while recyclable abrasives can be used multiple times, since their
inherent friability is low.
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media, based on the equipment type and operating parameters, prior to
production work.
The abrasive industry is reasonably competitive. Many projects set forth specific
abrasive requirements to be met prior to approval (prequalification testing).
Abrasive media are often specified by DOTs, facility owners, or military. Abrasives
used on bridges or industrial structures such as tanks often require qualification
according to one of five standards:
Standard tests are listed in each; the abrasive material must meet the minimum
requirements for each test to be included on an approved products list. These
standards include tests such as specific gravity, hardness, water-soluble
contaminants (conductivity), weight change on ignition, oil content, crystalline
silica content, surface profile (yield), particle size distribution (sieve analysis),
soluble and total metals content, friability, radioactivity, size, shape, and
durability. Additional performance tests are non-mandatory unless invoked by the
procurement documents. Health and safety regulations dictate that all abrasive
materials be tested for toxic/hazardous materials that may adversely impact
worker health and/or the environment.
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Note that SSPC-AB2, Cleanliness of Recycled Ferrous Metallic Abrasive, is a
standard for “in-process” abrasive cleanliness and does not contain performance
test requirements; therefore, it is not a “qualification-based” document.
More specifically, a fine abrasive will yield more impacts per volume. The more
particles in the stream, the more work is accomplished in the same amount of
time. When roughening concrete or wood, a hard, expensive abrasive, or a coarse
particle is unnecessary; crushed glass or agricultural abrasives are good choices
for work on relatively soft surfaces. However, when preparing steel for a
protective coating system, there are additional considerations. Many coatings
adhere poorly to hard, flat surfaces, so the abrasive needs to generate a pattern
of indentations that the coating can anchor to (a.k.a. anchor pattern or surface
profile).
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An 80-mesh garnet particle
leaves up to 3.6 mil depth
profile in steel.
1. 177 microns = 7 mils
2. Peak
3. 76.2 microns = 3 mils
4. Valley
For optimal adhesion, the applied coating should completely fill the valleys and
cover the peaks. The deeper the profile, the more anchoring occurs. However, if
the surface profile is too deep, the peaks can protrude beyond the surface of the
coating, causing pinpoint rust. In some cases, the contractor may be required to
go back over the area with a finer abrasive to reduce the surface to specified
profile depth – a costly mistake. The surface profile range is typically established
by the coating manufacturer depending on the total coating system thickness and
service environment. This range often becomes part of the coating specification.
SIZE -The bigger the particle, the deeper indentation it will make, but blast
cleaning with large particles will yield fewer impacts than an equal volume of
smaller particles. Small particles clean faster, provide better coverage, and result
in a more uniform profile; however, if the abrasive is too small the resulting
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surface profile will be too shallow. The most efficient approach is to use the
smallest particle necessary to achieve the desired surface profile. Particle sizes are
commonly classified by mesh sizes, often given as a range, for example: 30/60.
This indicates that 95% of the mix will fall through a 30 mesh but not pass through
the 60.
SHAPE – The shape of the abrasive effects how deeply it cuts into the coating and
underlying substrate. Shapes are classified according to angularity. Angular
particles cut through soft coatings and rust, cleaning faster, and producing
sharper anchor patterns. Rounded particles produce a more even, peened
surface, good for breaking away hard, brittle coatings and mill scale. Sub-rounded
and rounded particles generate comparatively fewer peaks than the angular and
sub-angular abrasives. Peak density is an important consideration for thermal
spray coatings (metalizing) but less significant for liquid-applied coatings.
HARDNESS – Hardness
determines whether an
abrasive particle can etch or
provide an anchor pattern on
a particular-type of substrate.
Surface profile is not only
based on the hardness of the
abrasive but also the hardness of the substrate (i.e., think aluminum versus steel).
The hardness of an abrasive is frequently communicated according to the Mohs’
hardness scale. The scale ranges from 1 to 10, with 1 being the softest (talc) and
10 being the hardest (diamond). Most abrasives that effectively produce an
anchor pattern in mild carbon steel have a Mohs’ hardness of at least 6.0.
DENSITY – The density or specific gravity of an abrasive affects the cleaning rate
and anchor profile produced into the substrate. Density is measured in pounds
per cubic foot. Specific gravity is measured by the density of the particle-relative
to the density of water. An abrasive with a high specific gravity is heavier. When
propelled at the same pressure, a heavier abrasive achieves a deeper anchor
pattern than that from a lighter one. Abrasives with a high specific gravity tend to
be less dusty. Those with a low specific gravity impact the substrate with less
force and are used for light cleaning, polishing, and deburring.
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Other Considerations
Other considerations that can affect productivity include cleaning rate (square
feet/minute), consumption rate (pounds/square foot) and dust generation.
Conclusion
Oil transferred to the substrate can cause film defects (e.g., fish eyes) and
potentially affect adhesion of the primer. Water soluble salts transferred to the
surface can cause accelerated rust back, osmotic blistering, under-film corrosion,
and premature coating failure. Without routine monitoring of abrasive
cleanliness, these contaminants could go unnoticed.
An excerpt from one of the SSPC abrasive blast cleaning standards addressing
abrasive cleanliness is shown below:
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Oil contamination is determined in accordance with
ASTM D7393, Standard Practice for Indicating Oil in
Abrasives. This field test, commonly known as the
vial test, requires that a sample of abrasive be
placed in a clean, sealable container. Tap water is
added to the container so that it is approximately 1
inch above the abrasive. The container is shaken for
about 1 minute and allowed to stand up to 5
minutes. The surface of the water is then visually
examined for any oil droplets or sheen. If oil is
visually evident, the abrasive fails the test. This test
should be conducted at least once per shift (during
blast cleaning operations) and at least 3 tests per
shipment of bulk delivery. This test also reveals
whether the abrasive is excessively dirty. If dust
settles on the surface or water remains cloudy, the overall cleanliness of the
abrasive should be questioned as this could cause impede production.
Water soluble contaminants are the non-visible soluble salts that may be present
on an abrasive. The abrasive is tested in accordance with ASTM D4940, Standard
Test Method for Conductimetric Analysis of Water Soluble Ionic Contamination of
Blast Cleaning Abrasives. According to the SSPC AB standards the conductivity of
the abrasive cannot exceed 1,000 µS/cm (micro-siemens/cm).
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Which abrasive cleanliness standard should be used?
Of the four SSPC abrasive standards, each standard has different requirements
based on the type of media but are identical when it comes to the quality control
tests for oil content and water-soluble contaminants. SSPC-AB 2 requires
additional field and laboratory tests for cleanliness to help ensure the abrasive
recycling equipment is functioning properly and that the abrasive operating mix is
still adequately sized. SSPC-AB 4 requires more frequent testing including at least
three water-soluble contaminants tests at different times during an 8-hour
period.
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“OSHA’s Final Rule on Beryllium: Key Provisions and
Proposed Modifications Affecting the Abrasive Blast
Cleaning Industry”
Introduction
The International Agency for Research on Cancer (IARC) classifies beryllium and
beryllium compounds as carcinogenic to humans, and the Environmental
Protection Agency (EPA) classifies inhaled beryllium as a possible
carcinogen. Despite its toxicity, beryllium is an important material in the
aerospace, electronics, energy, telecommunication, energy, medical and defense
industries due to its physical properties, such as its strength-to-weight ratio. In
the construction (and maritime) industries, worker exposure to respirable
beryllium primarily occurs when slags that contain trace amounts of beryllium
(<0.1 percent weight) are used for abrasive blast cleaning. The Occupational
Safety and Health Administration (OSHA) estimates approximately 11,500
construction and shipyard workers who may conduct abrasive blast cleaning with
slags may be exposed to trace amounts of beryllium. Abrasive blast cleaning
typically produces a large amount of dust, some of which may contain small
(respirable) beryllium particles. Inhaling beryllium may lead to beryllium
sensitization which ultimately puts an individual at risk for developing varying
diseases affecting the lungs, including chronic beryllium disease (CBD), acute
beryllium disease, and lung cancer.
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According to OSHA, despite the known
health dangers related to beryllium
exposure, the permissible exposure limit
(PEL) remained outdated and ineffective
for preventing beryllium-related
diseases for decades. After years of
science supporting the need for an
updated beryllium standard, on January
9th, 2017, OSHA issued a final rule that
established greater protection for
workers exposed to beryllium in general
industry (1910.1024), construction (1926.1124) and shipyards (1915.1024).
The rule applies when materials being used contain greater than 0.1 percent
beryllium by weight. Employers using materials with a lesser beryllium content
are exempt only where the employer has objective data demonstrating that
employee exposure to airborne beryllium will remain below the action level under
any foreseeable conditions. Employers can use objective data, based on industry-
wide surveys or calculations based on the beryllium content in dust, that
represent typical exposures during the employers’ operations, to determine if
they are covered under the standard. The data must reflect workplace conditions
closely resembling or with a higher airborne exposure potential than the
processes, types of material, control methods, work practices, and environmental
conditions in the employer’s current operations.
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provide respiratory protection where exposures are, or can be reasonably be
expected to be, at or above the action level.
▪ The standard requires provisions for respiratory protection and
implementation of a written exposure control plan whenever employees
are, or can reasonably be expected to be, exposed to airborne beryllium at
levels above the TWA PEL or STEL.
▪ The employer must train each employee on beryllium hazards who has, or
can reasonably be expected to have, airborne exposure to or dermal contact
with beryllium.
▪ It requires employers to make medical surveillance available at no cost to
the employee to monitor exposed workers identified with a beryllium-
related disease or who are reasonably expected to be exposed at or above
the action level for more than 30 days per year.
All three standards took effect May 20, 2017 but employers have until March 12,
2018 to comply with most provisions of the rule.
On June 23, 2017, OSHA announced its proposal to revoke certain provisions of
the beryllium rule in the construction and maritime industries. However, the
standard would maintain the requirements for exposure limits. OSHA estimates
that revoking the provisions below (while retaining the lower PEL and STEL for
construction and shipyards) would yield a total annualized cost savings of $10.2
million across these industries.
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Industry organizations such as
the Abrasive Blasting
Manufacturers Alliance
criticized the “overreaching”
beryllium standard and
applauded the proposal to
revoke the ancillary provisions
of the construction and
maritime industries. The
Alliance, which represents
manufacturers of coal slag,
argues there is an important
distinction between beryllium alloy and the mineral form of beryllium, which is
found in trace amounts in abrasive. While the Alliance agrees beryllium alloys
and other processed forms of beryllium have been found to lead to illness, they
argue, that the Alliance is “not aware of a single documented case of beryllium
sensitization or beryllium-related illness associated with coal or copper slag
abrasive production among their employees, or their customers’ employees
working with the products of Alliance members” (82 FR 29182). However,
without a medical surveillance program in place OSHA states that such reports are
not compelling evidence.
The Alliance also stresses the beryllium rule not only affects slag abrasive
manufacturers but the entire abrasive industry. According to the Alliance all blast
cleaning media and blast cleaned surfaces can contain trace amounts of
beryllium. Therefore, due to the dramatic reduction in the beryllium PEL and
action level, all blasters would need to comply with the regulations regardless of
abrasive media.
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Specifically, the agency was looking for “responses, supported by evidence and
reason, to the following questions:”
The request for comment period ended on August 28, 2017. Until a final decision
is made on the proposal to revoke ancillary provisions of the construction and
shipyards beryllium standards, the status of these two standards will remain in
limbo.
__________________________________________________________________
Introduction
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What do I need to do to comply with OSHA?
Compliance with OSHA’s Respirable Crystalline Silica regulations includes
development of a
written exposure
control program,
personal air
monitoring within
the worker’s
breathing zone,
medical evaluations,
and training.
The written
exposure control
program must
contain at least the
following
information:
▪ A description of
the tasks in the
workplace that
involve
exposure to
respirable
crystalline
silica;
▪ A statement
that the
employer fully and properly implements the engineering controls, work
practices, and respiratory protection specified for the task on Table 1A or;
▪ A description of the engineering controls, work practices, and respiratory
protection that will be used to limit employee exposure to respirable
crystalline silica for each task;
▪ A description of the housekeeping measures used to limit employee
exposure to respirable crystalline silica; and
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▪ A description of the procedures used to restrict access to work areas, when
necessary, to minimize the number of employees exposed to respirable
crystalline silica and their level of exposure, including exposures generated by
other employers or sole proprietors.
The employer is required to review and evaluate the exposure control plan at
least annually and update it as necessary. The written exposure control plan must
be readily available for examination and copying upon request, to each employee,
their designated representatives, and OSHA. A designated competent person is
required to make frequent and regular inspections of job sites, and to implement
the written exposure control plan.
Air monitoring
Medical Surveillance
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All medical evaluations are to be perform by a Physician or a Licensed Health Care
Provider (PLHCP), with results provided to the employee and employer within 30
days of the medical examination.
Training
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Efficiency of a material can also be affected by its friability, or breakdown rate.
The percentage reduction in size is a key factor in determining how recyclable a
material is. The particle size of the media can be analyzed following impingement
at a specified pressure and distance in a specially-designed, contained chamber
and compared to the original size. The change in size (calculated as percentage of
change) is called the Breakdown Rate. Similarly, the dust generation can be
determined in the same manner, either by collecting the dust which would
otherwise be removed by a dust collection system in a cloth bag, or by complete
containment of the spent abrasive in the collection chamber. The breakdown rate
and subsequent dust generation of materials not only affect material costs, but
indirect costs as well. Visibility, equipment wear, and filter replacement are just a
few of the indirect effects of dust generated by a friable media. Up-front
comparison testing can save not only material and labor costs, but these
inadvertent expenses as well.
The benefits of testing of abrasive media reach far beyond specification
compliance. Whether your intention is to protect worker safety or generate
marketing data, the complexity and intricacies of the physical properties and
effectiveness of an abrasive blasting media can not be overstated.
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About KTA’s Paint and Coatings Laboratory
KTA’s coatings laboratory provides paint,
corrosion and material testing services including
paint failure investigations, compositional
analysis, accelerated weathering, cyclic corrosion
testing, abrasive performance, and other physical
testing. Conducted by scientists and chemists, these comprehensive services
provide clients with independent, accurate analyses of coating problems, and
advance the industry’s understanding of the performance characteristics of
protective coatings and abrasive media. Accredited by the American Association
for Laboratory Accreditation (A2LA) in accordance with ISO/IEC 17025 (Testing
Cert. #2455.01), KTA’s Coating Laboratory is the premier provider of forensic
evaluations, a veritable ‘CSI’ of coating system failure investigations.
▪ Abrasives Testing
▪ Coating Performance (Accelerated Weathering and Corrosion Testing) Services
▪ Compositional Analysis of Coatings
▪ Forensic Coating Failure Investigations
▪ Miscellaneous Coatings Testing
▪ Physical Testing of Applied Coatings
▪ Test Panel Preparation and Coating Services
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Contact Information and Credentials
Robert Leggat is the KTA Laboratory Services Manager and
has over 15 years of experience in the protective coatings
industry. He holds a PhD in Materials Science and
Engineering from the University of Virginia and successfully
completed the KTA Level I Basic Coatings Inspection
training course. Mr. Leggat joined KTA in August 2016 as
the Laboratory Services Manager overseeing the operations of the Analytical and
Physical Testing Laboratories. In this position, he oversees all laboratory services
which include paint, corrosion and material testing services, coating failure
investigations, coatings research, and compositional analysis. Under his oversight,
senior chemists, chemists, and research and development specialists provide
clients with independent, accurate analyses of coating problems and advance the
industry’s understanding of the performance characteristics of protective coatings
and abrasive media. Prior to joining KTA, Mr. Leggat held various senior research
and technical management positions with the United States Steel Corporation in
Pittsburgh, PA. Call 412-788-1300 x176 or email me at rleggat@kta.com
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