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Formulation Additives:
Brand portfolio
Non-aqueous
Water based (solvent based)
Rheovis® (organic)
Rheology modifiers Efka®
Attagel® (clays)
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Content
Dispex® Ultra PX 4575 – VOC-free, dispersing agent for waterbased systems with
benchmark performance for inorganic pigments
Summary
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Dispex® Ultra PX 4575
Waterbased dispersing agent
Dispersing agent for waterbased applications
Benchmark performance for inorganic pigments
Excellent overall performance for organic pigments
Broad compatibility towards different resin systems
Designed with CFRP technology for high efficiency and excellent stability
Suited for paints that are VOC-free1 and/or carry Ecolabels2
Designed for colorants but well suited for direct grinds into primers, gloss and semi
gloss paints and for systems where polyacrylic acid dispersing agents are not
preferred
1 VOC content < 0,1% acc. EU 2004/42 ( b.p. > 250°C) (750 ppm)
2 Compliant with the requirements of the European Ecolabel for “indoor paints and varnishes”
2009/544/EC and for “outdoor paints and varnishes” 2009/543/EC
5
Content
Dispex® Ultra PX 4575 – VOC-free, dispersing agent for waterbased systems with
benchmark performance for inorganic pigments
Summary
6
Dispersing agents
Today‘s requirements
Performance requirements Environmental aspects
Broad compatibility in different Free of volatile organic compounds
paint and coating systems
APEO-free
Low mill base viscosities enabling
Low odor
high formulation freedom
Flowable and stable pigment
dispersions even in severe conditions
Easy to handle
No negative impact on paint performance
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Dispersing agents
A new solution: Dispex® Ultra PX 4575
Would you like to…
have a benchmark solution for dispersing inorganic pigments
including transparent iron oxides?
produce low viscosity pigment concentrates that are universally
compatible in full range of waterbased paints?
have a highly effective dispersing agent for inorganic pigments
for direct grind?
formulate with a product that outperforms benchmarks?
8
Content
Dispex® Ultra PX 4575 – VOC-free, dispersing agent for waterbased systems with
benchmark performance for inorganic pigments
Summary
9
Dispersing agents
CFRP and Structure–Performance relationship
random block comb
Copolymer Copolymer Copolymer
(not CFRP)
A-Block B-Block
stabilizer block pigment affinic block
Compatible with paint system, Anchoring onto pigment
e.g. resins and solvents
1 VOC content < 0,1% acc. EU 2004/42 ( b.p. > 250°C) (750 ppm)
2 Compliant with the requirements of the European Ecolabel for “indoor paints and varnishes” 2009/544/EC and for “outdoor paints and varnishes” 2009/543/EC
12
Content
Dispex® Ultra PX 4575 – VOC-free, dispersing agent for waterbased systems with
benchmark performance for inorganic pigments
Summary
13
Dispersing agents
CFRP and Structure–Performance relationship
Pigments used for evaluations
Transparent iron oxides Sicotrans® Red L2817, Sicotrans® Yellow L1916
Opaque inorganic pigments Kronos® 2190, Bayferrox® 3920, Bayferrox® 130 M, Sicopal® Yellow L1100
Organic and carbon black Special Black® 100, Heliogen® Green L8730, Heliogen® Blue L7085
Viscosity / Stability Measurement of viscosity at various shear rates before and after storage at 50°C.
Addition of pigment concentrate to a white (or black) base paint. Application on black
Color strength / Rub-out / Chroma and white card and check rub-out: Measurement by colorimeter. Chroma is the
saturation of a color, the higher the chroma the “cleaner” a color.
Check influence of dispersing agents on gloss of the tinted paints using a gloss
Gloss
meter .
7000
6000
5000
4000
3000
2000
1000 No paste,
0 too viscous
10,0% 15,0% 20,0% 10,0% 15,0% 20,0% 10,0% 15,0% 20,0% 10,0% 15,0% 20,0% 10,0% 15,0% 20,0% 10,0% 15,0% 20,0%
Dis U PX 4575 B1 B2 B3 B4 Dis U PX 4585
2500
Viscosity [mPa.s]
2000
1500
1000
500
No paste, No paste,
too viscous too viscous
0
15% 20% 25% 15% 20% 25% 15% 20% 25% 15% 20% 25% 15% 20% 25% 15% 20% 25%
Dis Ultra PX 4575 B1 B2 B3 B4 Dis Ultra PX 4585
Gloss at 60 degrees
Gloss at 60 degrees
26 80 90
100
70 85
dE* scattering
dE* scattering
25 80 80
60
24 50 75
60
23 40 70
30 40 65
22
20 60
21 20
10 55
20 0 0 50
10%
15%
20%
10%
15%
20%
10%
15%
20%
10%
15%
20%
10%
15%
20%
10%
15%
20%
20% 20% 20% 20% 20% 20%
Dispex B1 B2 B3 B4 Dispex Dispex B1 B2 B3 B4 Dispex
Ultra PX Ultra PX Ultra PX Ultra PX
4575 4585 4575 4585
dE*s gloss 60° dE*s gloss 60°
Dispex® Ultra PX 4575 shows highest gloss overall values with most transparency
in yellow oxide and comparable transparency in red oxide
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Transparency: Iron Oxide Yellow and Red
Performance in an acrylic clear system
dE* scattering: The lower the value, the higher the transparency
Sicotrans® Yellow L1916 Sicotrans® Red L2817
25,00 80 60,0 80
Gloss at 60 degrees
70
Gloss at 60 degrees
70 50,0
20,00
60 60
40,0 50
Opacity
Opacity
15,00 50
40 30,0 40
10,00 30 20,0 30
20 20
5,00 10,0 10
10
0,00 0 0,0 0
20% 20% 20% 20% 20% 20% 15% 20% 15% 20% 15% 20% 15% 20% 15% 20% 15% 20%
Dis U PX B1 B2 B3 B4 Dis U PX
4575 4585 Dis U PX B1 B2 B3 B4 Dis U PX
4575 4585
Dispex® Ultra PX 4575 shows highest gloss values overall with most transparency in yellow
oxide and comparable transparency in red oxide
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Viscosity: Sicopal® Yellow L1100 (60%)
Dispersant dosage: 1% / 2% active on pigment
5000
4500
4000
Viscosity [mPa.s]
3500
3000
2500
2000
1500
1000
500
No paste,
too viscous
0
1,0% 2,0% 1,0% 2,0% 1,0% 2,0% 1,0% 2,0% 1,0% 2,0% 1,0% 2,0%
Dispex Ultra PX 4575 B1 B2 B3 B4 Dispex Ultra PX 4585
Dispex® Ultra PX 4575 gives stable and flowable pastes where most other products
do not work at all
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Concentrate with Sicopal® Yellow L1100
Compatibility in architectural coatings
120 3,5
100 3
Relative color strength [%]
Rub-out [delta E]
2,5
80
2
60
1,5
40
1
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
Dispex B1 B2 B3 B4 Efka Dispex B1 B2 B3 B4 Efka Dispex B1 B2 B3 B4 Efka
Ultra PX 4585 Ultra PX 4585 Ultra PX 4585
4575 4575 4575
Dispersion paint Façade paint emulsion paint
Dispex® Ultra PX 4575 offers excellent balance between color strength and compatibility
22
Concentrate with Sicopal® Yellow L1100
Compatibility in industrial coatings
Colorstrength and Rub-out for tested industrial systems
350 1,4
Relative Colorstrength
300 1,2
250 1
Rub-out dE
200 0,8
150 0,6
100 0,4
No paste,
50 No sample too viscous 0,2
0 0
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
1,0%
2,0%
Dis U PX 4575 B2 B3 B4 Dis U PX 4585
J8300
CS (meas) Rub dE
Dispex® Ultra PX 4575 offers excellent balance between color strength and compatibility
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Viscosity: Special Black® 100 (35%)
Dispersant dosage: 29% / 46% active on pigment
5000
4500
4000
Viscosity [mPa.s]
3500
3000
2500
2000
1500
1000
500
0
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
Dispex Ultra PX 4575 B1 B2 B3 B4 Dispex Ultra PX 4585
Dispex® Ultra PX 4575 and Dispex® Ultra PX 4585 show overall good performance
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Concentrate with Special Black® 100
Compatibility in architectural coatings
120 4,5
4
100
Relative color strength [%]
3,5
Rub-out [delta E]
80 3
2,5
60
2
40 1,5
1
20
0,5
0 0
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
Dispex B1 B2 B3 B4 Dispex Dispex B1 B2 B3 B4 Dispex Dispex B1 B2 B3 B4 Dispex
Ultra PX Ultra PX Ultra PX Ultra PX Ultra PX Ultra PX
4575 4585 4575 4585 4575 4585
acrylic dispersion paint styrene acrylic façade paint VAE emulsion paint
Dispex® Ultra PX 4575 offers excellent balance between color strength and compatibility
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Concentrate with Special Black® 100
Compatibility in industrial coatings
140 3,5
120 3
Relative color strength [%]
100 2,5
Rub-out [delta E]
80 2
60 1,5
40 1
20 0,5
0 0
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
29%
46%
Dispex B1 B2 B3 B4 Dispex Dispex B1 B2 B3 B4 Dispex
Ultra PX Ultra PX Ultra PX Ultra PX
4575 4585 4575 4585
WB stoving enamel self crosslinking acrylic
Dispex® Ultra PX 4585 and Dispex® Ultra PX 4575 show low rub-out and high color strength
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Viscosity: Heliogen® Blue L7085 (45%)
Dispersant dosage: 20% / 30% / 40% active on pigment
3000
2500
Viscosity [mPa.s]
2000
1500
1000
500
0
20% 30% 40% 20% 30% 40% 20% 30% 40%
B1 Dis Ultra PX4575 Dispex Ultra PX 4585
Dispex® Ultra PX 4585 shows lowest viscosity and good storage stability
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Heliogen® Blue L 7085
Color strength in white alkyd urethane system
140,0
Relative color strength [%]
120,0
100,0
80,0
60,0
40,0
20,0
0,0
20% 30% 40% 20% 30% 40% 20% 30% 40%
B1 Dis Ultra PX4575 Dispex Ultra PX 4585
35,00 70,0
30,00 60,0
Gloss at [20°]
Chroma [C*]
25,00 50,0
20,00 40,0
15,00 30,0
10,00 20,0
5,00 10,0
0,00 0,0
20% 30% 40% 20% 30% 40% 20% 30% 40%
B1 Dis Ultra PX4575 Dispex Ultra PX 4585
2500
Viscosity [mPa.s]
2000
1500
1000
500
0
20% 30% 40% 20% 30% 40% 20% 30% 40%
B1 Dis Ultra PX4575 Dispex Ultra PX 4585
Dispex® Ultra PX 4585 show lowest viscosity and good storage stability
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Heliogen® Green L 8730
Color strength in white alkyd urethane system
140,0
Relative color strength [ %]
120,0
100,0
80,0
60,0
18,00
60,0
16,00
50,0
Chroma [C*]
14,00
Gloss [20°]
12,00
40,0
10,00
30,0
8,00
6,00 20,0
4,00
10,0
2,00
0,00 0,0
20% 30% 40% 20% 30% 40% 20% 30% 40%
B1 Dis Ultra PX4575 Dispex Ultra PX 4585