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ANSWERS TO QUESTIONS
1. In the experiment, what is considered the “population” and the “sample”? What is the
principal goal of sampling, in general?
The experiment focused on old 25-centavo coins. The real population of the specimen is all the
25-centavo coins that has been produced regardless of whether they had been observed in the
experiment, and the real population is also where the sample is pooled from. The sample of an
experiment is a subset of the population which should be able to effectively characterize the
population when experimented upon [1][2]. The sample of the experiment would be the 10 25-centavo
coins that were weighed. Although there are many types of sampling, all of which are used in specific
experiments, in general, sampling is done to be able to represent the population such that the
experiment can characterize the specimen in question by assuming that the sample behaves like the
population. Sampling is also done to minimize costs and to collect samples that are easily available.
3. Discuss in a concise and organized manner the applicability and limitations of the
different statistical parameters in assessing accuracy and precision?
The standard deviation measures precision. Looking at the equation for standard deviation, it
can be observed that each value X is subtracted from the mean value of the data to see how far apart
each X is from the mean, and the standard deviation gives exactly the degree of distance each X is from
the mean [1][3]. The standard deviation can be applied to both a population and a sample, but the
population needs to have a large amount of specimen, which almost always impossible to collect [3].
The limitations of standard deviation is that in sampling, there might be outliers in the sample, but
they would not be outliers in the population, so it doesn’t give an accurate description of the full range
of the real population. In terms of accuracy, how far a value is from the true value represents how
accurate that value is. The limitations of factoring this error, is that the true value is almost always
unknown, and that it can’t be pooled from just a sample. The true value has to be a value that
represents the entire population, that is to say, a confidence interval would be needed to estimate the
true value of a property [2].
4. Elaborate on the confidence interval and its purpose. Enumerate factors affecting the
range of the confidence interval.
The true value of a property is almost always indeterminate in applications of quantitative
analysis. The true value must be pooled from a vast amount of the specimen, which can be timely and
difficult, bordering on impossible to achieve. The confidence interval, however, gives an idea on where
the true value is between two limits [4]. The confidence interval is based upon the t-test, where the
factors involved are the confidence level and the sample size. A higher confidence level gives a larger
interval while a larger sample size gives a narrower interval. Having a sample with a low standard
deviation also helps reduce the size of the confidence interval.
REFERENCES
[1] Witte, R. S., & Witte, J. S. (2017). Statistics (11th ed.). San Francisco, California, United States of
America: Wiley.
[2] Urdan, T. (2010). Statistics in Plain English (3rd ed.). New York, New York, United States of
America: Routledge.
[3] Curriculum Research & Development Group. (n.d.). Practices of Science: Precision vs. Accuracy.
Retrieved January 30, 2019, from Exploring our Fluid Earth: Teaching Science as Inquiry
(TSI): https://manoa.hawaii.edu/exploringourfluidearth/physical/world-ocean/map-
distortion/practices-science-precision-vs-accuracy
[4] Skoog, D. A., West, D. M., Holler, F., & Crouch, S. R. (2014). Fundamentals of Analytical Chemistry
(9th ed.). Belmont, California, United States of America: Brooks/Cole.
[5] Harris, D. C. (2011). Solutions Manual for Quantitative Chemical Analysis (8th ed.). New York,
New York, United States of America: W. H. Freeman and Company.