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Document No. LPI-LAB-004-04
Page 1 of 26
Amna Crude Oil
The analysis of crude oil sample was carried out using well recognized standard
procedures given in ASTM, IP and UOP methods. The distillation of crude oil was
carried out using a batch fractionation unit made according to ASTM D-2892 method
& ASTM D-1160 method.
The crude oil was distilled under atmospheric and vacuum pressure and the
atmospheric residue was further distilled to obtain distillate fractions. Distillate
fractions corresponding to true boiling point up to 550+0C were collected.
List of Tables
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Amna Crude Oil
TABLE (1)
CRUDE OIL GENERAL TESTS
DESCRIPTION METHOD
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Amna Crude Oil
Continued Table-1
IBP @ 760mmHg 54
5% 108
10% 133
20% 187
30% 246
40% 297
50% 344 ASTM D-86
60% 365 Modified
70% 368
80% -
FBP 371
Recovery % vol. 72
Residue % vol. 27
Loss % vol. 1.0
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Amna Crude Oil
Table (2)
TBP Distillation of Crude Oil
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Amna Crude Oil
Table (3)
Detailed Hydrocarbon Analysis of 70-175 oC Fraction (ASTM D5134)
PIONA Analysis (Identified Compounds Listed in Chromatographic order)
% %
Isobutane 0.166 0.223 0.333 Toluene 0.556 0.522 0.578
n-C4 0.450 0.576 0.903 n-C8 1.765 1.867 1.802
3-Methyl-1- 0.401 0.475 0.667 2,2DMC7 0.109 0.113 0.099
Butene
n-C5 0.634 0.752 1.025 2M4EC6 3.088 3.277 2.808
2,3DMC4 0.495 0.556 0.670 1,1 ,3TMCC6 0.738 0.709 0.682
3MC5 0.361 0.404 0.488 m-Xylene 1.804 1.553 1.982
n-C6 1.914 2.156 2.590 p-Xylene 3.209 2.772 3.525
2,4DMC5 0.190 0.209 0.219 3,3 ,4TMC6 1.245 1.250 1.132
2,2,3TMC4 1.060 1.142 1.227 4EC7 0.426 0.438 0.387
C6? 0.333 0.375 0.450 ctc-1,2,4TMCC6 0.149 0.141 0.138
2MC6 0.498 0.545 0.576 3,3-DEC5 0.101 0.099 0.091
1,1DMCC5 0.130 0.128 0.154 O- 0.324 0.274 0.356
5
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Amna Crude Oil
xylene+1,1,2TMCC6
Benzene 2.257 1.909 3.370 TMC6 (2)? 1.291 1.323 1.147
2,2,4-TMC5 2.500 2.710 2.553 n-C9 11.21 11.62 10.199
6 5
n-C7 2.785 3.028 3.224 n-BCC5 2.176 2.063 2.010
cis-1,2DMCC5 0.862 0.835 1.024 3,3DMC8 0.981 0.988 0.804
MCC6 0.820 0.792 0.974 n-Pbenzene 1.910 1.648 1.853
cis-2-Heptene 0.204 0.214 0.242 1M3Ebenzene 0.900 0.775 0.873
1,1,3-TMCC5 1.486 1.486 1.545 C9? 0.119 0.124 0.108
ECC5 10.47 10.15 12.437 5MC9 2.062 2.106 1.690
0 8
2,3,3-TMC5 7.088 7.301 7.237 1M2Ebenzene 1.384 1.170 1.343
1,1,2-TMCC5 0.724 0.701 0.753 2MC9 0.299 0.306 0.245
3,4DMC6(L) 0.418 0.434 0.426 3EC8 1.034 1.039 0.847
3MC7 0.417 0.439 0.426 3MC9 1.354 1.373 1.110
cis-1.3DMCC6 0.386 0.377 0.401 C9? 0.574 0.595 0.522
1,1DMCC6 0.608 0.583 0.632 10.43 10.63
n-C10 8.555
7 5
C7? 0.142 0.155 0.165 1,2,3TMEbenzene 0.700 0.586 0.680
Continued Table-3
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Amna Crude Oil
Compounds Wt% Vol.% Mol. Compounds Wt% Vol.% Mol.
% %
2,2,4TMC6 0.638 0.667 0.581 1M3IsoPbenzene 0.169 0.146 0.147
1M2n-
1,2,5DEbenzene 0.723 0.612 0.629 Pbenzene+Unidentified
0.463 0.394 0.402
1M3IsoPbenzene 0.169 0.146 0.147 C11 Paraffin 2? 0.349 0.353 0.260
C11 Paraffin 3? 1.761 1.780 1.314 1,3DM4Ebenzene 0.815 0.696 0.708
1,4DM2Ebenzen
0.370 0.314 0.321 C11? 0.401 0.403 0.300
e
C10? 1.767 1.801 1.448 Tert-1B2Mbenzene 0.092 0.080 0.073
1-Undecene 0.223 0.223 0.169 n-C11 4.480 4.502 3.343
100.0 100.0
Total 100.00
0 0
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Amna Crude Oil
Table (4)
Detailed Hydrocarbon Analysis of 70-175 oC Fraction (ASTM D5134)
PIONA Analysis (Hydrocarbon totals by group types)
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Amna Crude Oil
Table (5)
Detailed Hydrocarbon Analysis of 70-175 oC Fraction (ASTM D5134)
PIONA Analysis (Totals by Carbon Number)
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Amna Crude Oil
10
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Amna Crude Oil
Table (6)
GC-Carbon Distribution of Crude Oil
11
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Amna Crude Oil
12
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Amna Crude Oil
TABLE (7)
Yield and Inspection of Light Naphtha Cut
13
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Amna Crude Oil
TABLE (8)
Yield and Inspection of Heavy Naphtha
14
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Amna Crude Oil
TABLE (9)
Yield and Inspection of Kerosene Cut
15
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Amna Crude Oil
Continued Table-9
TABLE (10)
Yield and Inspection of Atmospheric Gas Oil Cut
16
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Amna Crude Oil
Continued Table-10
17
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Amna Crude Oil
TABLE (11)
Yield and Inspection of Vacuum Gas Oil Cut
18
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Amna Crude Oil
Vol. % on Crude 25.85
Wt. % on Crude 26.78
Density15 ºC, g/ml 0.8733 ASTM D-4052
Specific gravity@ 60/60 ºF 0.8742 Calculation
API gravity 30.4 Calculation
Characterisation factor 12.4 UOP 375
Volume Average Boiling Point, (VABP), ºC 435 Calculation
Sulphur content, wt. % 0.127 ASTM D-4294
Aniline point, ºC 100.0 ASTM D-611
K. Viscosity at 37.8 ºC, cSt - ASTM D-445
K. Viscosity at 50 ºC, cSt 20.2890 ASTM D-445
K. Viscosity at 100 ºC, cSt 5.3105 ASTM D-445
Pour point, ºC +39 (ASTM D-97)
Molecular weight 403 Calculation
Distillation, ºC IBP 361
5% 377
10% 380
20% 392
30% 406
40% 419
50% 437
60% 454 ASTM D-1160
70% 463
80% 481
90% 488
95% 511
FBP 535
Residue % vol. 1.0
Loss% vol. Nil
Vanadium, ppm <0.005 ASTM D 5708
Nickel, ppm <0.010 ASTM D 5708
Calcium, ppm 0.492 Dry ashing
Potassium, ppm 0.105 Dry ashing
Sodium, ppm 1.256 Dry ashing
TABLE (12)
Atmospheric Residue 350+ 0C
19
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Amna Crude Oil
TABLE (13)
Vacuum Residue 550+ 0C
20
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Amna Crude Oil
Vol. % on Crude 21.25
Wt. % on Crude 24.44
Density@ 15 ºC, g/ml 0.9659 ASTM D-4052
Specific gravity@60/60 ºF 0.9665 Calculation
API gravity 14.9 Calculation
Asphaltenes content wt. % 0.30 IP 143
n-Heptane Insolubles, wt. % 0.11 ASTM D893
Sulphur content , wt. % 0.238 ASTM D-4294
Pour point, ºC +45 ASTM D-97
K. Viscosity at 50 ºC, cSt - ASTM D-445
K. Viscosity at 100 ºC, cSt 398.902 ASTM D-445
Ash content ,wt.% 0.016 ASTM D-482
Conradson carbon residue, wt. % 14.4 ASTM D-189
Calorific value, MJ/Kg gross 43.7 Calculation
Calorific value, Kcal/Kg gross 10438 Calculation
Vanadium, ppm 1.496 ASTM D 5708
Nickel, ppm 13.908 ASTM D 5708
Calcium, ppm 3.359 Dry ashing
Potassium, ppm 0.751 Dry ashing
Sodium, ppm 5.046 Dry ashing
Appendix
21
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Amna Crude Oil
22
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