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MODEL PAPER - 2018
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CHEMISTRY (Theory)
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1- i
K[Co(CO)ol Cool ffio<q
rrqr t:-
(er) +r (o) +o (q) -r
(s) -s
The Oxidation number of Co in K[Co(CO)o] is :-
+1
(a) +3
(b) -1 (c) (d) -3
a
{+ t 6t{ qffi q sn d q+pr fuq F{d SFd ersdrrrlrT{s c+ar t -
)cfrdrq @')v;Ha (11)n$-< (E)cr{i}ifrq
Which of the following reacts with chloroform and base to form phenylisocyanide:-
(a) Aniline (b) Phenol (c) Benzene (d) Nitrobenzene
3- uq-fto r+< +geo fi :-
(er) qprsfum orror ET (<) orqriffr oi (ql)s*t-{ oI k) A;frq ol
Natural rubber is a polymer of :-
(a) Acrylic acid (b) Isoprene (c) Ethene (d,t Benzene
4- dris\diT{s or '.r<rrr"r t
r,oi) -.tottT 6) d-fl&i(rr) qodrr (e) rerd
The example of monosaccharide is -
(a) Glucose (b) Lactose (c) Maltose (d) Starch
5- q6edtrn+q ol.TEfr r,ft{ dd-dt il sdi {ffid E{i i ?
Why does trichloromethane stored in dark coloured bottles ?
6- drdq or srwqF-6 nq ftfuc ?
Write chemical name of Teflon ?
7- i
d)difr{ .n\ etd,r dq} qftqftfn oin Z
How brom<lbenzene is converted into toluene ?
6- frfte qraorr rn qfunfr-d otBa ?
Define specific conductivity ?
9- Oj ffif { .se;.1a; ii vqq{ ds1T ftr{is t
orqqq3 r}or B t arqq <qw qfi&Tq z
Explain r,vhy in dilute soluti<lns, there is ele.ration in boiling point and derpi.essln, 1r,r

f'eezing point.
enr+'(ORi
14.625 qTrt E)fuiq odrt{s a) zso q-,q ul.q i ftirc ftqr .rql I slcr i+f,{q
rt'ictam s-re dfuq
.D-1 t

14.625 gm. sodiurn chloride was dissolved in 250 gm. of water. Find out the molality of
the solution.
 10- rrlRqq rdtrT{s B_t,ra q fr'flqc yffi ds 6) rrq-flr{d t 2
Explain Schottky defect in Sodium Chloride crystal.
l1- ffifu( d r&Tft-o ft-qr€ fttur - 2
Write down the electronic configuration of following :-
(a) Cr (b) Cr3*
uero (OR)
sq rrrrcqts{ q}Fro nen Gq roq ii errs {qE otfuc ?
Clarifu the difference between coordination compounds and double salts ?
12. onq q+ko q+q-sr{d fu d-@l'f, d dc. sMq y r<Rfo ori d r 2
Explain with reasons th-at d-block elements show catalytic properties.
13- urgr o1 q)Erq frqr srflr{i ? " 2
Explain the cleaning action of soap ?
14- d-s ftd-qd E\-i srd Gi{ +s ffiqd
c E}i qrd orcqrfo qqr d ? rdo or To-v6 s<rdRur 2
frGl r

i What are biodegradable and non-biodegradable detergents ? Give one example of each.
is- (o) .ra q tuAq d ffit
d ilq fttuc t 1
Write the name of two water soluble vitamins.
(9 q'q dm g qq hH-d 6) fu-o *f d qpl rq fuqT qrar t ? 1
What happens when phenol is heated with zinc powder ? , .
16- ffifu(;i tupecqrq ftfuq ,- ,2
Write the I U P A C names of the following :-
(I) cu.cocH,cn,cu, (II) HCHO (III) cH,=cHCHo 0v) HOOC-COOH
17- (o) r<rgfti.ot l)rrleo cileoaur frqr ftfur q v
rq or ilq frfuc ? ' 1
Write addition polymerisation of styrene and write the name of the product ?
(u) q'aH-n$c t fr.e.d. q4| 61 erftfr-qr fttu{ ? 1
Write down the reaction to prepare D.D.T. from chlorobenzene ?
18- A's ft-flR d srnnq w qfdo TE 3rfdrilfi t fuh( hlftr t 2
On the basis ofband theory differentiate between conductor and semi-conductor.
19- (o) oisril d q,fi-flinT or fiffrw fuflnT AftI ? 2
Give a brief account of classification of drugs ?
@ffierf-a o.r €qilflflo rp ftfur ? 1
Write structural formula of Paracetamol ?
2A- sTerfuo, Efi-q-fi W {'ffq-fi Cfrct afr qrqn +1 ftfu or qfq hlfw I S{ eftfuqsn d {I1]rqF'fi 3
trft+T"T !fi fufur ?
Describe the method for identification of primary, secondary and tertiary amines. Also
write chemical equations of the reactions involved ?
oerar (oR)
t
weft-o, Eft-qo \a E-fis'o c@kia eqr Eid ? aqr r\or t trq wqrfto, C-fiT6 3ir Tfiqo
i@Hf, 570 K w rd 6rq-i w rqrfla H qi
dt
What are primary secondary and tertiary alcohols? Wl.rat happens when primary,
secondary and tertiary alcohols are passed over heated copper at 570 K.
21- fffifuE fr 3pqq {qE o1ftg :- 3
(o) erqr+ oafl s4ftq (g) qfdo d,ert qrgqc'I (q) qrdq 6sn qf{
Differentiate the following :-
(D Ores and Minerals (II) jlux & slae (III) Smelting and roasting "

2
 qrqr re8 6r ilqrfr-d fr-d {rr{E 3n-{ d}i d frqd"T d +{r{ ilFqT \dA d frft-q H q di 3
qfr eftfu-qeri of fufult
Draw a labelled diagram of Blast furnance, and write down the reactions taking place in
different zones in the blast furnance during the extraction of iron.
22- t t
fuo-{{ qqr +dT ? pfti cf\d g@tdld fu-n non HE 6{i d ? sl{{rqfto cfif,$,il 3Htrd
el-flsd r

What is fermentation ? How is Ethyl Alcohol obtained from molasses ? Explain with
chemical equation ?
23- (o) ffi
or ft'go enucc lTqEft E-fi=q fiqq ftfu\ I 1

Write down the liaraday's second low of electrolysis.

(s) fiq sld 6r zga K w -r€ sfr+rnT oer e.m.f. gro olfug :- 2
Write the lrJemst equatio4 and e.m.f. of the following cell at 298 K -
Ms(s)lMs2 to.oorn,tj lc12 1o.oootvjcu1s) ?
24- ftq'q-r r{flSq ftsfr fttuc,- 1+1+1-3
(o) {q"f ricqr (u) EIS-{1ai ftqq (q) HI-f,wT
Write short notes on the following :-
(a) Gold Number (b) Hardy-Schulze rule (c) Peptization
ercrer (oR)
(o) 3rERt)suT crar erq?iqq t{ ercs cdr{i I 2
Write the difference between Adsorption and Absorption .

(u){fi offl{s t efl flcrq ir 1

What is meant by Protective colloid.
25- (o)qrfi 6r qlurilq 20"Cw 17 mm tt so gm vrft ii a gm {RqT (+dr rqqn=60gmol'';qfd 1:
fuflf{ A qrqqrq h1 qqiT olfur t

The vapour pressure of water at zo"C is 17mm. Calculate the vapour pressure of a
solution containing 3gm of urea (molar mass:60g mot'') in 50gm of water.
(s) -qois or vo qdlq fr'a+c 10% (w/w) t'r qR ftaqq or u=rd l.2g ml'' d a) ft-oqq o1 1
qleror sro atfuq r

A solution of glucose is l0% (w/w). Find out the molarity of the solution if the density
of the solution is 1.2g ml''.
26- (o) +afilqs orr€4{ sq] i ? d--e)_frTs e{req{ d qRurq Eqr d z 2
What is Lanthanoid Contraction ? What are the consequences of Lanthanoid
contraction?.
(u) cfrcd\flT d oti a slqf.r ftfu\ | 1
Write any two uses of Actinoids.
27- (m) sffifr-o frffT d oilEr{ c{ onqd qr<ofr f {sil-ff, qrw}rs , ,pSftm d sern Ei fr-i{fl .2
oifuc ?
On the basis of electronic configuration, discuss the position of Nitrogen, Phosphorus
and Arsenic in the periodic table ?.
(u) .roift{, f,dift{, dfta oer .:nqlSc t ot{ orfu6 qrfufi {qqn sT t ? 1
Among F, Cl, Br and I, which one is of metalic nature ?

3
28- (o) qerq 6lE ol ro srftfrqr rc% S
qunr otfuq
*i
t oo ft-+e or qrqq tfr d'r W erftfu-qr ;r1 erdeng +1' 3
r

A first order reaction takes 60 minute for 7 5o/o completion. Calculale its half life period.
t
(s) lrBn"T u'qf ,Qtq\ "F-rd ? rqe dfuc r

What is Activation energy ? Clerify.

oru-ar (oR)
(o) oftmu d iq qr vd{fi 6r rrr qqm qsor t ? 1
What is the effect of catalyst on rate of reaction ?
(q) vrlTq'ftf, 3rftbqr d {iqec fti6r< qfr ft-i-+qT olft{, 2
Discuss the collission theory of chemical reaction.
(r) eft'fu.w d tT o) y,ilftd 6G qra or{f,t or qrltHc vds I

Mention the factors influencing the rate of reaction.

29- (o)ar+< u;E{ grrr NHrd ucvrEq qn Hf4, oufq otftI ,

Describe the manufacture of NH3 by Haber's process with diagram.

(u)qTstro erq q dfuq ot eftfueT ftfurr
Write chemical reaction of nitric acid with toluene.
(.r) XeFa o1 €qqrT ftfuc r 1
Write the structure of XeQ.

1o)3rrqh rE r+6.r*flsr-6 ot arE eqt#f,S.] ? ti qfifi'qt fttuq ffit oilqi{ 2

orrflftfl{fi
o1 rre ord orfr tt
Why does Ozone acts as a powerfui Oxidising agent ? Write down two equations in
which Ozone acts as an Oxidising agent.
(u)So2fus q6R vo org ngo t? 1
How is SO2 an air pollutant ?
(q) rr*qRo srw d o)$ d sqdq ftfurr 1
Write any two uses of sulphuric acid.
F) Ei ftq-ff Nt d qq {dr{n d TdrS{ n's lt {rE qrfr B ? 1
Write the name of two poisonous gases, which can be prepared frorn chlorine gas ?
30- FtqfufuE crq 3rftfu-ffiri rlful qrft6 $qsrsd :- 1+1+1+1+1-5
(o) tG-+Sw etrqq.r @ a;cfti-<r etu++< (q)sda +iq+q
(u) dFrwt orftfr?Tr (e) lrerqrl-ots 3rfnhql
Explain the following name reactions with chemicai equations :-
(a) Rosenmund Reduction (b) Clemrnensen Reduction ( c)Aldoi Condensation
(d) Cannizzaro Reaciion (e) Gattermann-Koch Reaction
qerqr (oR)

What is esterification ? Explain the mechanism of esterification of Carboxylic acid in

detail ?

4
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-
>\

t
(s) Ertrffq trqr ? str6r sq-drr {a[{tr
What is formalin ? Give its uses.
fT) orqTBd qT6 o1 fra-fl d urflr{E ?
Explain the structure of Carbonyl group ?

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