Chem PDF

Created By: Armghan Saeed Page 1
1 Fundamental Concept
Q.1 Which of the following organic solvents is are commonly used in solvent extrac on
A. n-hexane B. Ethoxyethane (an ether)
C. CCI4 ✓ D. All of the above
Q.2 The branch of science dealing with structure, composi on and changes in ma er and laws and principles which govern
these changes is called as:
✓ A. Chemistry B. Geology
C. Physics D. Mechanics
Q.3 Mass spectrometer is used to determine
A. Mass number of isotopes B. Rela ve abundance of isotopes
✓ C. Both a and b D. None of these
Q.4 The volume occupied by 1.4g of N2at STP is:
A. 2.24 dm3 ✓ B. 1.12 dm3
3
C. 112 cm D. 22.4 dm3
Q.5 10.0 g CaCO3 is heated to produce CaO and CO2.The amount of CO2 produced is
✓ A. 4.4 g B. 22 g
C. 2.28 D. 44 g
Q.6 The weight of one molecule of a compound C60H122 is
A. 1.3 x 10-20g B. 5.01 x 10-21g
C. 3.72 x 1023g ✓ D. 1.4 x 10-21g
Q.7 Which of the following compounds contains the highest percentage by mass of nitrogen?
A. ammonia, NH3 B. ammonium carbamate, NH2CO2NH4
C. ammonium carbonate, (NH4)2CO3 ✓ D. hydrazine, N2H4
Q.8 Fluted filter paper is used instead of ordinary filter paper because it has
A. Greater pore size B. Small size
✓ C. Greater surface area D. Less number of pores
Q.9 The best standard of atomic mass is
✓ A. Carbon-12 B. Hydrogen-1.008
C. Oxygen-16 D. Chlorine-35.5
Q.10 Number of moles of solute dissolved in 1 kg of solvent is known as
A. molarity B. formality
✓ C. molality D. mole frac on
Q.11 On collision, airbags in cars inflate rapidly due to the produc on of nitrogen. The nitrogen is formed according to the
following equa ons.
2NaN3 →2Na→ + 3N2
10Na + 2KNO3 → K2O + 5NA2O + N2
How many moles of nitrogen gas are produced from i mol of sodium azide, NAN3?
A. 1.5 ✓ B. 1.6
C. 3.2 D. 4.0
Q.12 An organic compound contains 49.3% carbon,6.84% hydrogen and its vapour density is 73.Molecular formula of
compound is
A. C 3H 5O 2 ✓ B. C6H10O4
C. C3H10O2 D. C4H10O2
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Q.13 The most common example of solvent extrac on is
A. Chloroform ✓ B. Ether
C. Acetone D. Naphthalene
Q.14 A contain 1.2g of diamond. Wow many carbon atoms are in diamond?
A. 6.20 x 1023 B. 3.01 x 1022
✓ C. 6.20 x 1022 D. 3.10 x 1023
Q.15 Number of atoms in 558.5 g of Fe (At.Mass of Fe = 55.85 g mole-1)is
✓ A. Twice that in 60 g carbon B. 6.022 x 1022
C. Half that in 8 g of He D. 558.5 x 6.022 x 1023
Q.16 Who determined atomic masses of elements?
A. J. Berzelius B. Dempster
✓ C. Avogadro D. Aston
Q.17 The forma on of ca on is always ______ process
A. Exothermic ✓ B. Endothermic
C. Hetrothermic D. Homothermic
Q.18 When 12 cm3of ethanol is dissolved per 100 cm3of its solu on in water. The concentra on of this solu on would be
A. 12% w/w B. 12% w/v
C. 12% v/w ✓ D. 12% v/v
Q.19 Which of the following has least mass?
A. 2 gm atom of nitrogen ✓ B. 3 x 1023atoms of C
C. 1 mole of S D. 7.0 g of Ag.
Q.20 What is the molarity of a solu on which contains 5.85 g NaCl (Mr23 + 35.5) in 100 cm3solu on
✓ A. 1 B. 2
C. 3 D. 4
Q.21 The amount of products obtained form the balanced chemical equa on is regarded as
✓ A. theore cal yield B. actual yields
C. % yield D. experimental yield
Q.22 What weight of SO2can be made by burning sulphur is 5 moles of oxygen
A. 640 g B. 160 g
✓ C. 320 g D. 80 g
Q.23 Many elements have frac onal atomic masses. The reason is that:
A. the mass of atom is itself frac onal B. atomic masses are average masses of
isotopes
C. atomic masses are average masses of ✓ D. atomic masses are average masses of
isotopes isotopes which are propor onal to their
rela ve abundance
Q.24 Iodine is insoluble in water but we can make its solu on by adding
A. NaOH B. KOH
C. H2SO4 ✓ D. KI
Q.25 A limi ng reactant is the one which:
A. is taken in lesser quan ty in grams as B. is taken in lesser quan ty kin volume as
compared to other reactants compared to others
C. carries the maximum amount of product ✓ D. gives the minimum amount of the product
which is required under considera on
Q.26 What is the number of proton in one molecule of SO3?
A. 64 ✓ B. 40
C. 32 D. 24
Q.27 What volume of hydrogen gas at 273 K and 1 atm.Pressure will be consumed in obtaining 21.6 g of elemental boron
(Atomic mass = 10.8) from the reduc on of boron trichloride by hydrogen?
A. 89.6L ✓ B. 67.2 L
C. 44.8 L D. 22.4 L
Q.28 The number of moles of CO2which contain 8.0 g of oxygen
A. 0.25 B. 0.50
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C. 1.0 ✓ D. 1.50
Q.29 The number of water molecules in one dm3 pf water is
A. 6.02 x 1023 B. 18/22.414 x 1023
C. 6.023/22.44 ✓ D. 55.6 x 6.02 x 1023
Q.30 For the sake of convenience the atomic mass may be given in ______ units of measurement
A. Grams / mole ✓ B. Kilogram / mole
C. Pounds / mole D. All of these
Q.31 The crystals are drying through a
A. Vacuum pump B. Direct providing that
✓ C. Vacuum desicator D. None
Q.32 The pore size of the filter paper depends upon
A. Nature of the medium B. temperature of the medium
✓ C. Size of the par cles D. Mass of the par cles
Q.33 The total number of covalent bonds in 4.5 grams of water is
A. 6.02 x 1023 B. 6.02 x 1022
C. 3.01 x 1022 ✓ D. 3.01 x 1023
Q.34 3.6% W/V solu on of HCl has the molairity
A. 1.0 B. 1.15
✓ C. 0.98 D. 1.98
Q.35 The dried pa ern obtain in the filter paper in the form of separated component of mixture is called
A. Histogram B. Oscillograph
✓ C. Chromatograph D. Mass spectrum
Q.36 The atomic mass of sodium is
A. 27 amu B. 30 amu
✓ C. 23 amu D. 25 amu
Q.37 The mass of 3.0115 x 1023molecules of O2gas at STP
A. 32 g B. 24 g
✓ C. 16 g D. 8g
Q.38 To differen ate between C-12,C-13 and C-14 the instrument that you would use is
A. Infra-red spectrometer B. Atomic absorp on spectrometer
✓ C. Mass spectrometer D. Ultraviolet spectrometer
Q.39 Which of the following statement is correct for a chemical reac on to occur molecules of substances must
A. collide with each other ✓ B. collide with energy more than ac va on
energy
C. collide with energy less than ac va on energy D. collide with high frequency
Q.40 The isotopes 8O16, Mg24 , Si28 , Ca40, Fe56 from nearly _____ of earth crust
A. 20% B. 30%
C. 40% ✓ D. 50%
Q.41 How many cm3of 1 M H2SO4required to neutralize 10 cm3of 1 M NaOH?
A. 2 cm3 B. 2.5 cm3
✓ C. 5 cm3 D. 10 cm3
Q.42 Objects of the size of an atom can be observed in
✓ A. an electron microscope B. an x-ray spectrum
C. atomic absorp on spectrum D. a visible spectrum
Q.43 The mass of one atom of an element compared with the mass of an atom of carbon taken as 12 is called:
A. Rela ve molecular mass B. Atomic mass
C. Molecular mass ✓ D. Rela ve atomic mass
Q.44 The freezing mixture used in ice cream machine consists of ice and
✓ A. NaCl B. KCl
C. MgCl2 D. NaNO3
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Q.45 Which one of the following statement is not correct
A. a molecule is the smallest par cle of an B. He is a molecule of helium
element which can exist independently
C. S8is a molecule of sulphur
✓ D. O3is a molecule of oxygen
Q.46 Weight of a single molecule of water is
✓ A. 3.0 x 10-23g B. 6.02 x 10-23g
C. 6.02 x 1023g D. 2.4 x 10-24g
Q.47 How will you separate a mixture of two gases?
A. Frac onal dis lla on technique ✓ B. Graham's law of diffusion technique
C. Osmosis D. Chromatography.
Q.48 The number of atoms in 4.25 g of NH3 is approximately
A. 1 x 1023 B. 1.5 x 1023
C. 2 x 10 23 ✓ D. 6 x 1023
Q.49 1g molecule of SO2& H2O (g) each are different in
A. Volume B. Mole
C. Number of par cle ✓ D. Molar mass
Q.50 Efficiency of a reac on can be determined by
A. Yield B. Actual yield
C. Theore cal yield ✓ D. Percentage yield
Q.51 Use of the periodic table is relevant to this ques on.
What mass of solid residue can be obtained from the thermal decomposi on of 4.10g of anhydrous calcium nitrate?
A. 0.70g B. 1.00g
✓ C. 1.40g D. 2.25g
Q.52 Gooch crucible used to filter the solu on of
A. H2SO4 B. HCI
C. KMnO4 ✓ D. Both B & C
Q.53 Use of the data booklet is relevant to this ques on.
Oxides of nitrogen are pollutant gases which are emi ed from car exhausts. in urban traffic, when a car travels one
kilometre, it releases 0.23g of an oxide of nitrogen NxOy' which occupies 120cm3.
what are the values of x and y?
(Assume 1 mol of gas molecules occupies 24.0dm3)
A. x=1,y=1 ✓ B. x=1,y=2
C. x=2,y=1 D. x=2,y=4
Q.54 Which among the following is the heaviest
A. One mole of oxygen ✓ B. 44 g of carbon dioxide
C. 10 moles of hydrogen D. 100 amu of uranium
Q.55 Hemoglobin is such a macromolecule found in blood and it is ______ mes heavier then a hydrogen atom
A. 65000 B. 66000
C. 67000 ✓ D. 68000
Q.56 Which of following separa ng technique is used to separate insoluble par cles froma liquid mixture
A. Sublimma on B. Chromatography
✓ C. Filtra on D. Solvent extrac on
Q.57 Number of moles of the solute dissolved per dm3of the solu on in known as
✓ A. molarity B. formality
C. %age D. none of these
Q.58 A radioac ve isotope of thallium, 20181Ti, is used to assess damage in heart muscles a er a heart a ack.Which
statement about 20181Ti is correct?
A. this isotope has a nucleon number of 120. ✓ B. the number of electrons in one atom of this
isotope is 81.
C. the number of neutrons in one atom of this D. 201
81X is an isotope of
201
81Tl.
isotope is 201.
Q.59
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X litres of carbon monoxide is present at S.T.P it is completely oxidized to CO2.The volume of CO2 formed is 11.207 L at
S.T.P What is the value of X in litres?
A. 22.414 L B. 11.207 L
✓ C. 5.6035 L D. 44.828 L
Q.60 0.5 moles of CH4 and 0.5 moles of SO2gases have equal
A. volume B. mass in grams
C. total number of atoms ✓ D. number of molecules
Q.61 27g of Al will react completely with how much mass of O2to product Al2O3?
A. 8g of oxygen B. 16g of oxygen
C. 32g of oxygen ✓ D. 24g of oxygen
Q.62 Which one of the following substances is used as decolourizing agent during crystalliza on
A. Silica gel ✓ B. Animal charcol
C. Conc H2SO4 D. Asbestos
Q.63 The rela ve abundance of the ions with a definite m/e value is measured by
A. high pressure of vapours ✓ B. strength of electric current measured
C. quan ty of fast moving electrons D. electron gas
Q.64 13.5 g of water is present in a glass. The number of molecule of water in the glass is molecule
A. 3.0115 x 1023 ✓ B. 4.517 x 1023
23
C. 6.023 x 10 D. 9.0345 x 1023
Q.65 Which of the following samples contain the largest number of atoms
A. 1g of Ni B. 1g of Ca
C. 1g of N2 ✓ D. 1g of B
Q.66 Which of the following is not generally same for one mole of different gasses at STP
A. Volume ✓ B. Molecular mass
C. Number of molecules D. All of these
Q.67 Gooch crucible is used in a suc on filtering apparatus, because:
A. a solid compound s purified B. it keeps the stem of funnel full of liquid
✓ C. it is used fore filtra on of precipitates which D. it is used to separate organic compounds from
need to be ignited water
Q.68 Unnilpen um is an ar ficial element, One of the isotope is 262105Upn.
Which of the following statement is correct?
A. 262
105Unp has a nucleon number 105 ✓ B. the atom260105X is an isotope of262105Unp
C. there are 262 neutrons in262105Unp D. the proton number of262105Unp is 262
Q.69 Silicon carbide (SiC) is an important ______ material
A. Building ✓ B. Ceramic
C. Plas c D. Wooden
Q.70 The percentage of which element in the organic compound is determined by the difference method
A. carbon B. hydrogen
C. nitrogen ✓ D. oxygen
Q.71 During the folding of filter paper the apex form angle of about
A. 80° ✓ B. 60°
C. 180° D. 90°
Q.72 One mole of C2H5OHcontains the number of H-atoms
A. 6.02 x 1023 ✓ B. 3.61 x 1024
C. 1.81 x 1024 D. 6.02 x 1024
Q.73 Which one of the following techniques can be used to separate NaCl and sand?
A. sublima on ✓ B. forma on of solu on and filtra on
C. chromatography D. forma on of solu on and evapora on
Q.74 The largest no. of molecules is in
✓ A. 34 g of water B. 28 g of CO2
C. 46 g of CH2OH
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Q.75 Molecular ions are formed in an instrument called:
A. Mass thermometer B. Thermocycler
✓ C. Mass spectrophotometer D. Galvanometer
Q.76 To prepare 10% weight/weight solu on of glucose in water, dissolve
A. 10 g of glucose in 100 cm3of water B. 10 g of glucose in 100 g of water
✓ C. 10 g of glucose in 90 g of water D. 10 g of glucose in 90 cm3of water
Q.77 Isotopes differ in
A. Proper es depend upon the electron ✓ B. Proper es depend upon the atomic mass
C. Effect of electro magne c field D. Arrangement of electron
Q.78 Isotopes differ in
✓ A. Proper es which depend upon mass. B. Arrangement of electrons in orbi als
C. Chemical proper es D. The extent to which they may be affected in
electronic field.
Q.79 A 10% w/v glucose solu on has 1 mol of glucose (Mr90) dissolved in it. What is the volume of solu on
A. 1 dm3 B. 1.8 dm3
C. 200 cm 3 ✓ D. 900 cm3
Q.80 One cm3 H2 gas at S.T.P. contains number of atoms:
A. 1.67 x 1024 B. 6 x 1023
✓ C. 0.53 x 1022 D. 1 x1020
Q.81 When energy is released during a reac on it is
✓ A. exothermic reac on B. endothermic reac on
C. a free radical reac on D. a bond breaking reac on
Q.82 Efficiency of a chemical reac on can be checked by calcula ng:
A. Amount of reactant le unused ✓ B. Amount of product formed
C. Amount of reactant in excess D. Amount of limi ng reactant
Q.83 By adding electron in a neutral species we get
A. Free radical B. Ca on
✓ C. Anion D. Molecular par cle
Q.84 A bo le of copper (ll)oxide has been contaminated with some solid, NaCl, How can NaCl be removed room the copper
(ll)oxide?
✓ A. add water to the mixture and filter B. place the mixture in a separa ng funnel
C. add dilute acid to the mixture and filter D. heat the mixture and allow it to cool.
Q.85 A gaseous mixture contains 50% helium and 50% methane be volume.What is the percent by weight of methane in the
mixture?
A. 19.97% B. 20.05%
C. 50% ✓ D. 80.03%
Q.86 The number of atoms present in a molecule determines its:
A. Molecularity ✓ B. Automa city
C. Basicity D. Acidity
Q.87 A metal "M" reacts with "S" to form "MS". If 3.6 g of M reacts with 0.09 mole of sulphure
A. Cr B. Mg
✓ C. Ca D. Mn
Q.88 The solu on remaining a er the forma on of crystals is called
A. Filtrate ✓ B. Mother liquor
C. Residue D. Drying agent
Q.89 The number of moles of CO which contain 8.0 g of oxygen
A. 0.25 ✓ B. 0.5
C. 0.75 D. 1.0
Q.90 In an acidic medium dichromate ion oxidizes ferrous ion to ferric ion.If the gram molecular mass of potassium
dichromate is 294 g,its gram equivalent mass is .....grams.
A. 294 B. 127
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✓ C. 49 D. 24.5
Q.91 The rela ve abundance of Pb isotopes is 1.5% Pb204, 23.6% Pb206, 22.6% Pb207, 52.3% Pb208. The rela ve atomic mass
of Pb is
A. 207.94 B. 208.24
C. 206.94 ✓ D. 207.24
Q.92 Which one of the following is not a molecular ion
A. N2+1 B. CH4+1
C. C7H8+1 ✓ D. NH4+1
Q.93 A pieceiof paper is burnt in air, the gas produced is passed through dis lled water. The pH of water will be
A. 3 B. 2.1
✓ C. 6.8 D. 7
Q.94 The rela ve atomic mass of chlorine is 35.5. What the mass of 2 mol of chlorine gas
✓ A. 142 g B. 35.5 g
C. 71 g D. 18.75 g
Q.95 Chemical equa ons do not tell about:
A. Reactants B. Rate of reac on
C. Products ✓ D. Condi ons and rate of reac on
Q.96 The phenomenon of isotropy was first discovered by
✓ A. Soddy B. Rutherford
C. Bohr D. Dalton
Q.97 A vessel contains 10g of N2, 10g of H2 and 10g O2. Which one has the largest number of atoms?
A. N2 B. O2
✓ C. H2 D. all have equal number of atoms
Q.98 Any molecular species having posi ve charge is called:
✓ A. Molecular ion B. Atomic ion
C. Micro ion D. Macro ion
Q.99 To achieve a good separa on the two liquids are gently shaken to increase
✓ A. Their area of contact B. Their separa on
C. Their miscibility D. Their solubility
Q.100 Which one of the following has mono atomic molecule?
A. water B. milk
C. ozone ✓ D. helium
Q.101 The mass of Al2S3formed when 20 grams Al reacts completely with S is
A. 60 g B. 50 g
C. 50,55 g ✓ D. 55.55 g
Q.102 Molecular formula is determined form empirical formula because
A. Molecular formula x empirical formula = n ✓ B. Molecular formula = n x empirical formula
C. Molecular formula x n = empirical formula D. Molecular mass x empirical formula = n
Q.103 The number of molecules in one dm3of N2at STP
✓ A. 23
6.023 x 10 /22.414 B. 22.414 x 1023/6.023
C. 6.023 x 10-23/22.14 D. 22.414 x 10-23/6.023
Q.104 A sample of chlorine containing isotopes of mass number 35 and 37 was analysed in a mass- spectrometer, How many
peaks corresponding to Cl+2 were recorded?
A. 2 ✓ B. 3
C. 4 D. 5
Q.105 When nitrogen is 5.6 grams in NO2, then number of moles of NO2is
A. 0.5 ✓ B. 0.4
C. 0.04 D. 0.05
Q.106 For smooth filtra on one of the following precau ons should be observed:
A. the filter paper should be small ✓ B. the stem of the funnel should be small
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C. the stem of the funnel should remain D. the p of funnel should jot touch the beaker
con nuously full of liquids
Q.107 A compound contains one atom of oxygen and % of O 34.78, then molecular mass of compound is
✓ A. 46 B. 78
C. 110 D. 180
Q.108 Aluminum reacts with sulphur to form aluminum sulphide. How many gram of aluminum required to produced 75 g
aluminum sulphide
A. 13.5 g ✓ B. 27 g
C. 40.5 g D. 54 g
Q.109 500 ml of NH3contains 6.00 x 1023molecules at S.T.P. How many molecules are present in 100 ml of CO2at S.T.P?
23
A. 6 x 10 B. 1.5 x 1023
✓ C. 1.2 x 10 23
D. None of these
Q.110 Sublima on is a separa on technique used to remove a:
A. low boiling component from a high boiling B. fast moving component from a slow moving
component component
✓ C. non vola le component from a vola le D. miscible liquid from a solid
component
Q.111 1.12 dm3of N2gas at S.T.P has mass of N2gas
A. 2.8 g B. 2.4 g
✓ C. 1.4 g D. 14 g
Q.112 The mass of molecular ion can be calculated from its:
A. c/m ra o ✓ B. M/e ra o
C. e/m ra o D. M.c ra o
Q.113 2 g of oxygen contains number of atoms equal to that in
A. 0.5 g of hydrogen ✓ B. 4 g of sulphur
C. 7 g of nitrogen D. 2.3 g of sodium
Q.114 Dempster s mass spectrometer is designed for the inden fica on of elements which were available in ____ state
A. Gaseous B. Liquid
✓ C. Solid D. Plasma
Q.115 Which law directly explains the law of conserva on of mass?
✓ A. Dalton's law B. Moley's law
C. Newton's law D. Hund's law
Q.116 Which one of the following compounds does not have the empirical formula CH2O?
A. ethanoic acid, CH3CO2H ✓ B. ethanol, CH3CH2OH
C. glucose, C6H12O6 D. methanal, HCHO
Q.117 0.078 g of a hydrocarbon occupy 22.414 mL of volume at S.T.P The empirical formula of the hydrocarbon is CH.The
molecular formula of hydrocarbon is
A. C 2H 2 ✓ B. C 6H 6
C. C 8H 8 D. C 4H 4
Q.118 A compound contains 50% sulphur and 50% oxygen by mass the empirical formula of compound is
✓ A. SO2 B. S 2O 4
C. SO3 D. S 2O 6
Q.119 How many moles of Helium gas occupy 22.4 L at 0°C at 1 atm.Pressure?
A. 0.11 B. 0.90
✓ C. 1.0 D. 1.11
Q.120 A balloon contains 0.02 gram of H2gas. it contains H2molecules
A. 6.02 x 1023 B. 3.01 x 1022
✓ C. 6.02 x 10 21
D. 3.01 x 1021
Q.121 Most of the atoms show diameter in the order of
A. 2 x 10-10cm B. 10-10pm
C. 0.1 m ✓ D. 0.2 nm
Q.122 All of the following statements is are correct except for Gooch cricible
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A. Made up of porcelain B. Porous base is covered by filter paper
C. Rate can be increased by sanc on pump ✓ D. Reac ve material will not contaminate filter
Q.123 A sample of ammonium phosphate (NH4)3PO4contains 3.18 mole of hydrogen atoms. The number of moles of oxygen
atoms in this sample are
A. 0.265 B. 0.795
✓ C. 1.06 D. 3.18
Q.124 The process of filtra on is used to separate
A. Solute from solu on ✓ B. Insoluble par cles from liquids
C. The two immiscible liquids D. The two miscible liquids
Q.125 The number of subatomic par cles in atoms so far discovered is more than:
A. 110 ✓ B. 100
C. 125 D. 90
Q.126 The term ebullioscopy is used for
A. Depression of freezing point ✓ B. Eleva on in boiling point
C. Lower of vapour pressure D. None of the above
Q.127 In paper Chromatography the rate at which solute moves depend on
A. Distribu on law ✓ B. Distribu on co-efficient
C. Law of par al pressure D. Law of definite propor on
Q.128 Non-metals tend to gain electrons, becoming:
A. Metals B. Posi vely charged ions
✓ C. Nega vely charged ions D. (a) and (c)
Q.129 A pure hydrocarbon is used in bo le gas for cooking and hea ng.
When 10CM3of the hydrocarbon is is burned in 70cm3 of oxygen (an excess), the final gaseous mixture contains 30cm3
of carbon dioxide and 20cm3 of unreacted oxygen. all gaseous volumes were measured under iden cal condi ons.
What is the formula of the hydrocarbon?
A. C 2H 4 B. C 3H 6
✓ C. C 3H 8 D. C4H10
Q.130 He, Ar and Ne are:
✓ A. Mono-atomic molecules B. Hetero-atomic molecules
C. Poly-atomic molecules D. Diatomic molecules
Q.131 Solu on may have units
A. Molarity B. Molality
C. Mole frac on ✓ D. All of them
Q.132 Molecular formula:
A. N x molecular formula B. n x compound formula
C. N x atomic formula ✓ D. n x empirical formula
Q.133 A 10% w/v solu on of glucose has a volume of 100 cm3.How many gram of glucose are present in it
A. 9 ✓ B. 10
C. 18 D. 90
Q.134 The O16, Mg24, Si40, Fe56, form nearly _______ of the earth's curst
A. 25% B. 37.5%
✓ C. 50% D. 62.5%
Q.135 50 cm3of 0.05 molar urea(N2H4CO)solu on has % W/V concentra on
A. 6% B. 3%
✓ C. 0.3% D. 0.6%
Q.136 The modern atomic weight scale is based on
✓ A. C12 B. O16
C. H1 D. C13
Q.137 The number of oxygen atoms in 4.4 g of CO2 is approximately
✓ A. 1.2 x 1023 B. 6 x 1022
23
C. 6 x 10 D. 12 x 1023
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Q.138 A pharmacist prepared 50 ml sample of a cough mixture.It was found that it has a mass of 46g. What is the density
(g/ml) of this mixture? Stated to correct number of significant figures?
✓ A. 0.92 B. 1.087
C. 1.04 D. 0.09
Q.139 6.0 x 1029 molecules of urea are present in 100 mL of its solu on.The concentra on of urea solu on is
A. 0.001 M B. 0.1 M
C. 0.02 M ✓ D. 0.01 M
Q.140 Covalent compounds mostly exist in the form of:
A. Protons B. Atoms
C. Neutrons ✓ D. Molecules
Q.141 Choose the exact name of formula that is based on the actual molecule?
A. simple formula ✓ B. molecular formula
C. empirical formula D. structural formula
Q.142 1.977 g of gold was recovered from a smuggler. How many atoms of gold were recovered? (Au = 197)
A. 6.02 x 1025 ✓ B. 6.02 x 1024
C. 6.02 x 1023 D. 6.02 x 1025
Q.143 Loca ng agent which is used to iden fy colourless acids is
✓ A. Ninhydrin B. H 2S
C. K2CrO4/water D. Rubeanic acid
Q.144 All of the following have the same number of par cles except
A. 40 g calcium B. 32 g oxygen
C. 12 g carbon ✓ D. 14 g nitrogen gas
Q.145 A chemical equa on do not tell about the ______ of reac on
A. Condi on B. Rate
C. Order ✓ D. All of these
Q.146 The number of atoms contained in 11.2 L of SO2 at S.T.P are
✓ A. 3/2 x 6.02 x 1023 B. 2 x 6.02 x 1023
C. 6.02 x 1023 D. 4 x 6.02 x 1023
Q.147 What mass of NaOH is required to prepare 2.5 dm3of 1.5 M NaOH solu on
A. 130 g B. 140 g
✓ C. 150 g D. 160 g
Q.148 N2O4 is a poisonous gas. it can be disposed of safely by reac on with sodium hydroxide.
N2O4(g) + 2NaOH(aq) → NANO3(aq) +NaNO2(aq) + H2O(1)
-3
what is the minimum volume of 0.5 mol dm NaOH (aq) needed to dispose of 0.02 mol of N2O4?
A. 8cm3 B. 12.5cm3
C. 40cm3 ✓ D. 80cm3
Q.149 A ring contains 3 grams diamond. The number of C-atoms which a ring contains is
✓ A. 3.01 x 1023 B. 1.5 x 1023
C. 6.02 x 1024 D. 3.01 x 1024
Q.150 ''A'' compound always consists of the same elements combined in the same fixed ra o,'' The statement is;
A. a fact ✓ B. a law
C. a hypothesis D. microgram
Q.151 The wave length of visible light is 500 nm. In S.I unit this value is
A. 5 x 10-8m B. 5 x 10-9m
C. 500 x 10-7m ✓ D. 500 x 10-9m
Q.152 Solvent extrac on is an equilibrium process and it is controlled by:
A. law of mass ac on B. the amount of solvent used
✓ C. distribu on law D. the amount of solute
Q.153 In case of CCl4, HCL and NH3formulas both empirical and molecular formulas are:
A. Not same ✓ B. Same
_______________________________________________________________________________________
C. Different D. All of above
Q.154 The molarity of 10% w/w aqueous solu on NaOH is
A. 2.56 B. 2.67
✓ C. 2.78 D. 2.89
Q.155 The largest number of molecules are present in
✓ A. 3.6 g of H2O B. 4.8 g of C2H5OH
C. 2.8 g of CO D. 5.4 g of N2O5
Q.156 Volume occupied by 11 g of carbon dioxide at 0°C and 1 atm pressure is
A. 22.414 dm3 B. 2.2414 dm3
✓ C. 5.6035 dm3 D. 1.12 dm3
Q.157 Molecules and atoms can either gain or lose electrons, forming charged par cles called:
A. Positrons B. Photons
✓ C. Ions D. Electrons
Q.158 one mole of SO2 contains:
A. 6.02 x 1023 atoms of oxygen B. 18.1 x 1023 molecules of SO2
✓ C. 6.02 x 1023atoms of sulphur D. 4.2g of atoms of SO2
Q.159 Which one of the following steps is not involved in determina on of empirical formula?
A. Determina on % of each element B. Determina on of gram atoms of each element
✓ C. Determina on of isotopes of each element D. Determina on of atomic ra o of elements
Q.160 The atomic weight of Cu is 63.546. There are only two naturally occurring isotopes of copper, 63Cu and 65Cu. The
natural abundance of the 63Cu isotpe must be
A. 10% B. 30%
C. 50% ✓ D. 70%
Q.161 A compara ve rates at which the solutes move in the paper chromatography depends on:
A. the size of paper used ✓ B. their Rf values
C. their par on coefficients D. the polarity of solvent used
Q.162 Which will weigh more:
✓ A. 2 mol CO2 B. 2 mol O2
C. 2 mol N2 D. 1 mol O3
Q.163 The atomic mass of an element is expressed in
A. gram B. ounce
C. kilogram ✓ D. a.m.u
Q.164 An aqueous solu on of glucose (Mr180) has been labelled as 1 molal. what is the mole frac on of glucose in this
solu on
A. 1/1000 B. 180/1000
C. 1/55.5 ✓ D. 1/56.5
Q.165 The masses of the atoms are extremely:
A. Large B. Comparable
✓ C. Standard D. Substance
Q.166 Which of the following term is used for isotopes
A. Isotropy ✓ B. Isotopy
C. Anisotropy D. Allotropy
Q.167 This has isotopes:
A. 3 B. 9
C. 6 ✓ D. 11
Q.168 Which pairs of the following components can be separated by sublima on
A. Sand+NaCI B. Sand+Glass
✓ C. Sand+naphthalene D. NaCI+KCI
Q.169 The formula which represents actual of atoms of each element in molecule is called:
✓ A. Molecular formula B. Compound formula
_______________________________________________________________________________________
C. Atomic formula D. Empirical formula
Q.170 Use of the data booklet is relevant to this ques on, Titanium (lV) oxide, TiO2, os brilliantly white and much of the
oxide produced is used in the manufacture of paint. What is the maximum amount of TiO2 obtainable from 19.0
tonnes of the ore limenite, FeTiO3?
✓ A. 10.0 tonnes B. 12.7 tonenes
C. 14.0 tonnes D. 17.7 tonnes
Q.171 The highest point at which solvent reaches during chromatography is called
A. Base line B. Eluent
C. Chromatogram ✓ D. Solvent front
Q.172 All of the following statements are incorrect for 20 mol of hydrogen peroxide except:
✓ A. 80 mol of atoms B. 30 mol of oxygen atoms
C. 30 mol of hydrogen atoms D. 20 mol of hydrogen atoms
Q.173 The volume occupied by one mole of an ideal gas at standard temperature and pressure is called
A. Molecular volume ✓ B. Molar volume
C. Molal volume D. Normal volume
Q.174 One mole of carbon 12 has mass:
✓ A. 0.012 kg B. 1 kg
C. 0.0224 kg D. 12 kg
Q.175 The number of moles of CO2which contain 8.0g of oxygen:
✓ A. 0.25 B. 0.50
C. 1.0 D. 1.50
Q.176 During the process of crystalliza on, the hot saturated solu on:
A. is cooled very slowly to get large sized ✓ B. is cooled at a moderate rate to get medium
crystals sized crystals
C. is evaporated to get crystals of product D. id mixed with an immiscible liquid to get the
pure crystals of the product
Q.177 The dried paper containing pa ern on paper is called
A. Chromophore B. Chrome
✓ C. Chromatogram D. Chromatograph
Q.178 A limi ng reactant is one which according to the stoichiometric equa on
A. has excess mass B. has least mass
C. has excess number of moles ✓ D. has least number of moles
Q.179 1 mole of CH4 contains
A. 6.02 x 1023atoms of H ✓ B. 4 g-atom of hydrogen
23
C. 1.81 x 10 molecules of CH4 D. 3.0 g of carbon
Q.180 The prefix 1018 is
A. Giga ✓ B. Exa
C. Kilo D. Nano
Q.181 Repeated extrac on using small amount of solvent in solvent extrac on are then using single extrac on
✓ A. More efficient B. More selec ve
C. Less efficent D. Less produc ve
Q.182 The word mole was first introduced by
A. Berzelius B. Democritus
✓ C. Ostwald D. Avogadro
Q.183 A sample of chlorine containing isotopes of mass numbers 35 and 37 was analysed in a mass-spectrometer.
How many peaks corresponding to cl+2 were recorded?
A. 2 ✓ B. 3
C. 4 D. 5
Q.184 Which of the following methods is the most suitable to obtain a pure and dry sample of sodium chloride from a
mixture of solid sodium chloride and sand?
A. heat the mixture gently and collect the B. shake the mixture O, filter and evaporate
2
substance which melts with H the filtrate
_______________________________________________________________________________________
C. shake the mixture with O and dis ll the
2
✓ D. shake the O, filter and dry the
H liquid mixture with H2substance on the filter paper.
Q.185 Which of the following is a type of chromatography?
A. T. L. C. B. G. L. C.
C. Paper ✓ D. All of them
Q.186 John Dalton's atomic theory, published ion 1808, contained four predic ons about atoms, Which of his predic ons is
s ll considered to be correct?
✓ A. Atom are very small in size B. no atom can be split into simpler parts
C. all the atoms of a par cular element have the D. all the atoms of one element are different in
same mass mass from all the atom of other elements
Q.187 which is the correct statement about limi ng reactant?
✓ A. it gives least number of moles of product B. it is le behind a er the comple on of
reac on
C. it is most a cheaper substance as compared to D. it gives greatest numbher of moles of
other reactants products
Q.188 Which if the following is not a separa on technique?
A. sublima on B. filtra on
✓ C. boiling D. solvent
Q.189 Smallest par cle of an element which may or may not have independent existence is known as:
A. A molecule B. An ion
✓ C. An atom D. An electron
Q.190 The technique in which the solvent travels upwards by capillary ac on is
✓ A. Ascending B. Descending
C. Radial D. Circular
Q.191 Isotopes differ in:
✓ A. Proper es which depend upon mass B. arrangement of electrons in orbitals
C. chemical proper es D. The extent to which they may be affected in
electron magne c field
Q.192 1 mole of MgCl2contains
A. 2.5 moles atoms B. 1 mole molecules
C. 23
6 x 10 nega ve charges ✓ D. 6 x 1023posi ve charges
Q.193 Which of the following is not related to a.m.u?
A. kilogram B. gram
✓ C. gm/lit D. microgram
Q.194 The technique of chromatograph is used in
A. Sepera on B. Isola on
C. Purifica on ✓ D. All
Q.195 The maximum amount of BaSO4 precipitated on mixing BaCI2 (0.5 M) with H2SO4 (1 M) will correspond to
✓ A. 0.5 M B. 1.0 M
C. 1.5 M D. 2.0 M
Q.196 The branch of chemistry which deals with quan ta ve rela onship between reactants and products in a balanced
chemical equa on is called:
A. Analy cal chemistry B. Inogranic chemistry
C. Biochemistry ✓ D. Stoichiometry
Q.197 4 g of copper was dissolved in conc,Nitric acid.The copper nitrate t obtained on strong hea ng gave 5 g of its oxide.The
equivalent weight of copper is
A. 23 ✓ B. 32
C. 12 D. 20
Q.198 Which one of the following is ambiguous?
A. A mole of electrons B. A mole of sodium atoms
C. A mole of potassium ioms ✓ D. A mole of hydrogen
Q.199 When 0.1 g of magnesium is treated with an excess of hydrochloric acid, what volume of gas at room temperature and
pressure will be produced?
A. 10 cm3 B. 25 cm3
_______________________________________________________________________________________
C. 48 cm3 ✓ D. 100 cm3
Q.200 How many moles of oxygen, O2are needed for the complete combus on of two moles of butane, C4H10?
A. 2 B. 8
C. 10 ✓ D. 13
Q.201 Use of the date booklet is relevant to this ques on. It is now thought that where an element exists as several isotopes,
the stable ones usually contain a magic number of neutrons. One of these magic numbers is 126.
Which isotope is unstable?
A. 209 B. 208Pb
Bi
✓ C. 210
Po D. 208
Ti
Q.202 A method of separa ng components from its solu on by adding any other immiscible solvent with the first solvent
according to distribu on law is called
A. Paper chromatography B. Crystalliza on
C. Sublima on ✓ D. Solvent extrac on
Q.203 Ma er is defined as anything which occupies space and:
A. Molecules ✓ B. Atomicity
C. Basicity D. Acidity
Q.204 Haemoglobin contains 0.33% of iron by mass. The molecular mass of haemoglobin is approximately 67200. The
number of iron atom (atomic mass 56) in one molecule of haemoglobin is
A. 6 B. 1
✓ C. 4 D. 2
Q.205 The value of R (General Gas Constant) is
A. 8.3134 JK-1mole-1 B. 1.987 Cal K-1mole-1
✓ C. Both a and b D. 1.987 JK-1mole-1
Q.206 A compound X contains 50% sulphur and 50% oxygen by mass. What is the empirical (simplest) formula of compound
X?
A. SO ✓ B. SO2
C. SO3 D. SO4
Q.207 What is the number of water molecule in 9g of water
A. 3.01 x 1020 B. 3.01 x 1023
C. 6.02 x 1022 ✓ D. 6.02 x 1023
Q.208 A pure hydrocarbon is used in bo led gas for cooking and hea ng.
When 10cm3 of the hydrocarbon is burned in 70cm3 of oxygen (an excess), the final gaseous mixture contains 30 cm3 of
carbon dioxide and 20cm3 of unreacted oxygen. All gaseous volumes were measured under iden cal condi ons.
What is the formula of the hydrocarbon?
A. C 2H 6 B. C 3H 6
✓ C. C 3H 8 D. C4H10
Q.209 The empirical formula of a liquid compound is known to be C2H4O. What other informa on is needed to work out its
molecular formula?
A. the percentage composi on of the compound ✓ B. the rela ve molecular mass of the compound
C. the density of the compound D. the volume occupied by one mole of the
compound
Q.210 The mass of one mole of chlorine gas is:
A. 35.5 g B. 23 g
✓ C. 71 g D. 32 g
Q.211 The foul small that skunks Spray, is due to a number of thiols, one of which is methanethiol, CH3SH, which burns as
follows.
CH3SH + 3O2 → CO2 + SO2 + 2H2O
A sample of 10cm3 of methanethiol was exploded with 60cm3 of oxygen, what would be the final volume of the
resultant mixture of gases when cooled to room temperature?
A. 20cm3 B. 30cm3
C. 50cm3 ✓ D. 70cm3
Q.212
_______________________________________________________________________________________
A solu on consis ng of 92 grams ethyl alcohol (C2H5OH) 96 grams methyl alcohol (CH3OH)90 grams water the mole
frac on and mole percent of methyl alcohol is
✓ A. 0.3, 30% B. 0.2, 30%
C. 0.5, 30% D. 0.2, 20%
Q.213 6g of hydrogen gas is:
A. 4 mol B. 1 mol
✓ C. 3 mol D. 2 mol
Q.214 Choose the pair of following components which can be separated by sublima on process:
A. sand and broken piece of glass ✓ B. sand and Naphthalene
C. NaCl and KCl D. sand and NaCl
Q.215 What is the mass of H2O obtained when 30 g of C2H6completely reacts, with 500 g of O2
A. 36 g B. 6g
✓ C. 54 g D. 18 g
Q.216 Safe and reliable method of drying crystal is through
✓ A. Vacuum desiccator B. Drying in oven
C. Filter paper D. Evapora on of solu on
Q.217 The quan ta ve rela onship between the substances according to balanced equa on describes
A. reversible reac ons ✓ B. s ochiometry
C. limi ng reac ng D. percentage composi on
Q.218 Basic principle of crystalliza ons is that solute Should be dissolved in a solvent at
A. Low temerature B. Moderate temperature
✓ C. High temperature D. Cri cal temperature
In leaded petrol there is an addi ve composed of lead, carbon and hydrogen only.This compound contains 29.7%
carbon and 6.19% hydrogen by mass.What is the value of x in the empirical formula PbC8Hx?
A. 5 B. 6
C. 16 ✓ D. 20
Q.220 The rela ve abundance of the ions with definite m/e value is measured by
✓ A. Strength of electric current measured B. Radius of the circle
C. High pressurized vapours D. None
Q.221 Fluted filter paper is used for:
A. increasing the rate of filtra on ✓ B. filtering the hot saturated solu on
C. to avoid premature crystalliza on of the D. to dissolve large aount of substance at its
solute boiling point
Q.222 In the determina on of atomic ra o of the elements the mole ra os are divided by
✓ A. least value of gram atoms of elements B. Atomic masses of elements
C. given mass of the compound D. molecular mass of the compound
Q.223 Determina on of atomic masses and inven on of system of wri ng symbols was made by:
✓ A. J. Berzilius B. Democritus
C. Dalton D. None of above
Q.224 Chromatography involves the distribu on of solute between
A. Two sta onary phase ✓ B. A sta onary phase and a mobile phase
C. Two mobile phases D. Two sta onary and two mobile phase
Q.225 Bakelite forms when phenol reacts with:
A. Hydrogen ✓ B. Formaldehyde
C. Nitric Acid D. Sulphuric acid
Q.226 In crystalliza on the solvent is selected on the basis of
A. Its hardness B. Its porous nature
C. Its reac vity ✓ D. Hit and trail method
Q.227 To iden fy a limi ng reactant, the steps are performed
A. 2 ✓ B. 3
_______________________________________________________________________________________
C. 4 D. 5
Q.228 A molecular ion is formed by
✓ A. passing high energy electron beam through B. dissolving a salt in dilute acid
gaseous molecule
C. passing electric current through molten salt
D. passing electricity through aqueous solu ons
Q.229 27g of al react completely with how much mass of O2 to produce Al2 O3?
A. 8g of oxygen B. 16g of oxygen
C. 32g of oxygen ✓ D. 24g of oxygen
Q.230 The mass equivalent of 1 a.m.u in grams is
A. 12 g ✓ B. 1.66 x 10-24g
-3
C. 1.66 x 10 g D. 1.66 x 10-2g
Q.231 The number of isotopes of gold is
A. 3 ✓ B. 1
C. 2 D. 4
Q.232 What will be the molarity of solu on if 103 g (NH4)2SO4is dissolved per 600 cm3of water?
A. 2.32 M B. 3.32 M
C. 4.32 M ✓ D. 1.30 M
Q.233 0.5 mole of ethanoic acid, 0.5 mole of ethanol 0.25 mole of ethyl ethanoate and 0.25 mole of water are mixed
together what is mole frac on of ethanoic acid
✓ A. 1/3 B. 1/4
C. 1/5 D. 1/6
Q.234 Which of the following is not mono isotopic element
A. F B. I
✓ C. Ci D. Au
Q.235 The number of moles of CO2 which contain 8g of oxygen:
✓ A. 0.25 B. 0.50
C. 1.0 D. 1.50
Q.236 0.1 molar glucose (C6H12O6) solu on has the % W/V
✓ A. 1.8% B. 18%
C. 0.18% D. 2.8%
Q.237 What is the Molarity (M) of a solu on which contain 20 g NaOH (Mr40) per 500 cm3aqueous solu on
A. 0.5 ✓ B. 1.0
C. 1.5 D. 2.0
Q.238 A pure chemical compound always contains the same elements combined in the same fixed ra o by weight is a
statement of
A. law of mul ple propor on B. law of mass ac on
✓ C. law of definite propor on D. law of conserva on mass
Q.239 The atomic mass is measured in atomic mass unit (a.m.u) which is equal to
✓ A. 1.661 x 10-27kg B. 1.661 x 10-24kg
C. 1.661 x 10-27g D. 1.661 x 10-24mg
Q.240 Assuming full decomposi on,the volume of CO2 released at STP on hea ng 9.85 g of BaCO3 (At.Mass Ba = 137) will be
A. 0.84 L B. 0.24 L
C. 4.06 L ✓ D. 1.12 L
Q.241 Which statement is true
A. mole frac on is same as molarity B. molarity is same as molality for aqueous
solu on
✓ C. the sum of mole frac on of all the D. 40 g NaOH in 960 g water is one molal
components is always equal to unity for any solu on
solu on
Q.242 Solvent extrac on is mostly applies to separate
✓ A. Organic compounds B. Inorganic compounds
C. Both A & B D. None of them
_______________________________________________________________________________________
Q.243 Paper chromatography is a type
A. Absorp on chromatography ✓ B. Par on chromatography
C. Adsorp on chromatography D. None
Q.244 11.2 dm3 of a gas at STP weight 14g. The gas could be
✓ A. N2 B. NO2
C. CO2 D. N 2O
Q.245 The solvent is selected for crystalliza on of a substance on the basis of
A. Its polar nature B. It should react chemically
C. Its non-polar nature ✓ D. On hit and trail basis
Q.246 A molecule ion is formed by :
A. dissolving a salt in dilute acid. B. passing electric current through molten salt
✓ C. passing electricity through aqueous solu ons D. passing high energy electron beam through
gaseous molecule
Q.247 The volume of water to be added to 100 cm3 of 0.5N, H2SO4 to get decinormal concentra on is
✓ A. 400 cm3 B. 500 cm3
C. 450 cm3 D. 100 cm3
Q.248 The empirical formula of a compound is CH2O and its molecular mass is 120.The molecular formula of the compound is
A. C 2H 4O 2 B. C 3H 6O 3
✓ C. C 4 H 8O 4 D. CH2O
Q.249 Which of the following is molecular ion
A. NH4 B. HSO-14
C. MnO4-1 ✓ D. None of these
Q.250 Isotopes of an element have all of the following similar except
A. number of electrons B. number of protons
C. atomic number ✓ D. mass number
Q.251 A flask contains the liquids trichloremethane (chloroform) and H2O. They are separated using a separa ng funnel.
Which conclusion can be made from this observa on alone
✓ A. trichloromethane and water do not mix B. trichloromethane and water having different
rele ve masses
C. trichioromethane and water having different D. trichloromethane has a higher density than
boiling points water
Q.252 The insoluble impuri es in the saturated solu on are removed by
A. Normal filter paper B. Fluted filter paper
✓ C. Both A & B D. None
Q.253 Isotopes differ in the:
A. number of atoms ✓ B. number of neutrons
C. number of protons D. number of electronce
Q.254 Combus on analysis is the example of analysis
A. Volumetric B. Qualita ve
✓ C. Quan ta ve D. All of these
Q.255 When reagent like HCi and KMnO4 are required to filter through Gooch crucible then perfora on should be covered by
A. Filter paper B. Paper pulp
✓ C. Asbestos mat D. Fluted filter paper
Q.256 Sublima on is a process for the separa on of:
A. ionic and covalent compound B. solute and solvent from a solu on
✓ C. vola le and non-vola le solids D. solu on of vola le and non-vola le
Q.257 What is the number of atoms in 28 g of Nitrogen gas?
A. 2 x 1023 ✓ B. 1.2 x 1024
C. 6 x 1023 D. 3 x 1023
Q.258 An atom is:
A. building block of an element. B. Always smaller than molecule .
✓ C. smallest par cle of an element. D. smallest indivisible par cle is an element
_______________________________________________________________________________________
Q.259 Prepara on of aspirine is carried out by the reac on of salicylic acid with:
A. ace c acid and ethyl alcohol B. ace c acid and water
✓ C. ace c acid and ace c anhydride D. ace c acid and sulphuric acid
Q.260 Gooch crucible is used for the filtra on of precipitates having
A. High solubility B. High concentra on
✓ C. High igni on temperature D. Low temperature
Q.261 The total number of protons in 10 g of calcium carbonate is (N0 = 6.023 x 1023)
A. 1.5057 x 1024 B. 2.0478 x 1024
✓ C. 3.0115 x 10 24
D. 4.0956 x 1024
Q.262 Which one is the property of an ideal solvent
A. Should be expensive B. It should react chemically with the solute
C. Impuri es should crystallize along with the ✓ D. Should be safe to use
solute
Q.263 The amount of product obtained or calculated from balanced chemical equa on is called:
A. Actual yield ✓ B. Theore cal yield
C. Experimental yield D. Balanced yield
Q.264 A compound having empirical formula C3H3Oand its molecular mass is 110.02 its molecular formula is
A. C 3H 3O ✓ B. C 6 H 6O 2
C. C 9H 9O 3 D. C 3H 6O 2
Q.265 A beaker contains 9 grams of water. The number of H-atoms is
✓ A. 6.02 x 1023 B. 3.01 x 1023
C. 6.02 x 1024 D. 3.01 x 1024
Q.266 0.56 g of a gas occupies 280 cm3 at N.T.P then its molecular mass is
A. 4.8 ✓ B. 44.8
C. 2 D. 22.4
Q.267 Actual yield is less than theore cal yield because of
A. Inexperienced worker B. Some compe ng side reac on
C. Lake of proper techniques ✓ D. All of the above
Q.268 In a neutral atom, the number of protons are equal to the number of
A. neutrons ✓ B. electrons
C. photons D. nucleons
Q.269 Which of the following compound does not have empirical formula CH2O
A. HCHO B. CH3COOH
C. C6H12O6 ✓ D. CH3CH2OH
Q.270 In paper chromatography the suspended paper is dipped in the solvent to
✓ A. About 5 mm B. Touch the surface only
C. Touch the bo om D. About 5 cm
Q.271 2g of aluminium is treated,separately with excess of dilute H2SO4,and excess of NaOH,the ra o of volumes of
hydrogen evolved is
✓ A. 1:1 B. 2:3
C. 1:2 D. 2:1
Q.272 The mass of one mole of electrons is:
A. 1.008 mg ✓ B. 0.55 mg
C. 0.184 mg D. 1.673 mg
Q.273 By using the fluted filter paper rate of filtra on is
✓ A. Increased B. Decreased
C. Filtra on is constant D. Having no effect
Q.274 The isotopes of an element
A. possess same mass number ✓ B. possess same number of protons
C. do not possess same chemical proper es D. may or may not possess same chemical
proper es
_______________________________________________________________________________________
Q.275 NH3, HCI, H2O, HI are:
A. Diatomic molecules B. Poly-atomic molecules
C. Mono-atomic Molecules ✓ D. Hetero-atomic molecules
Q.276 The molarity of the solu on containing x grams (NH4)2SO4in 500 cm3of the solu on is 0.6. What is x?
✓ A. 39.6 B. 45.1
C. 40.5 D. 42.7
Q.277 To prepare the medium sized crystal the hot filtrate is cooled
A. Slowly B. Fast
✓ C. Moderately D. None
Q.278 What would be the number of carbon atoms in exactly 12 grams of carbon-12?
✓ A. 6.02 x 1023 B. 12 x 6.02 x 1023
C. 6.02 x 1023/12 D. 12 x 1023
Q.279 The process in which the solvent molecules are surrounded and interact with solute ions of molecules is called
✓ A. Solva on B. Hydra on
C. Hydrogena on D. None
Q.280 A sample of phosphorous trichloride (PCO3) contains 1.4 moles of the substance How many atoms are there in the
sample?
A. 4 B. 5.6
C. 8.431 x 1023 ✓ D. 3.372 x 1024
Q.281 'X' grams of calcium carbonate was completely burnt in air.The weight of the solid residue formed is 28 g. What is the
value of 'X' in grams?
A. 44 B. 200
C. 150 ✓ D. 50
Q.282 Volume of 0.1 M K2Cr2O7 required to oxidise 35 mL of 0.5 M FeSO4 solu on is
✓ A. 29.2 mL B. 17.5 mL
C. 175 mL D. 145 mL
Q.283 Which of following has empirical formula CH2O
A. Ace c acid B. Glucose
C. Fructose ✓ D. All
Q.284 Chromatography in which the sta onary phase is liquid is called
A. Absorp on chromatography B. Adsorp on chromatography
✓ C. Par on chromatography D. None
Q.285 When an electron is added to a uniposi ve ion we get:
A. Ca on B. Molecule
✓ C. Neutral atom D. Anion
Q.286 Which of the following process is used to separate insoluble par cles from liquids?
A. Separa on ✓ B. Filtra on
C. Crystalliza on D. Condensa on
Q.287 What is the maximum mass of aluminium which can be obtained from 240 g of aluminium oxide, Al2O3?
A. 26 g ✓ B. 127 g
C. 51 g D. 108 g
Q.288 Solvent extra on method is a par cularly useful technique for separa on when the product to be separated is:
A. vola le or thermally stable ✓ B. vola le or thermally unstable
C. non-vola le or thermally unstable D. non-vola le of thermally stable
Q.289 A molecule of haemoglobin is made up of nearly
✓ A. 10,000 atoms B. 50,000 atoms
C. 2500 atoms D. 1500 atoms
Q.290 The amount of product obtained in a chemical reac on is called:
✓ A. Yield of reac on B. Product of a reac on
C. Conclusion of a reac on D. None of above
_______________________________________________________________________________________
Q.291 The volume occupied by 1.4g of N2 at STP is:
A. 2.24 dm3 B. 22.4 dm3
✓ C. 1.12 dm3 D. 112 dm3
Q.292 Sintered glass crucible is used to:
A. purify a solid ✓ B. convenient filtra on than that b Gooch
crucible
C. avoid premature crystalliza on of solids D. separate two liquids
Q.293 Which of the following is the most convenient way of filtra on by
A. Ordinary filter paper B. Gooch crucible
C. Fluted filter paper ✓ D. Sintered glass crucible
Q.294 Which of the following is not sublime substance
A. Iodine B. Benzoic acid
✓ C. Ammonium chloride D. Potash alum
Q.295 Empirical formula and formula unit of an unit of an ionic compound:
A. are always different B. are always similar
✓ C. may be similar or different D. ionic compounds do not
Q.296 In a sample of glucose there are 3.6 x 1024 atoms of carbon are present Mass of glucose sample is
✓ A. 180g B. 360g
C. 3600g D. 342g
Q.297 The volume occupied by 1.4 g of N2at S.T.P. is
A. 2.24 dm3 B. 22.4 dm3
✓ C. 1.12 dm3 D. 112 cm3
Q.298 First atomic theory was put forward by an English school teacher:
A. Maxwell B. Newton
C. Sanger ✓ D. john Dalton
Q.299 The volume occupied by 1.4g of N2 at S.T.P. is:
A. 2.24 dm3 B. 22.4 dm3
✓ C. 1.12 dm 3
D. 112 cm3
Q.300 Chromatography in which sta onary phase is solid is called
A. Par on chromatography B. Paper chromatography
✓ C. Adsorp on chromatography D. HPLC
Q.301 Due to stability and abundance of carbon compounds carbon is taken as:
A. Element B. Superior
✓ C. Standard D. Substance
Q.302 1:5 mol of O2 combine with Mg to form oxide MgO.The mass of Mg (at.Mass 24) that has combined is
✓ A. 72 g B. 36 g
C. 48 g D. 24 g
Q.303 A compound has molar mass = 228.3g/mol. When it was analyzed by a scien st, it was found that it contains
30.68%nitrogen. How many nitrogen atoms are there in each molecule of dye?
A. 3 B. 4
✓ C. 5 D. 6
Q.304 The analysis in which we iden fied the element in a compound is called as ______ analysis
A. Volumetric ✓ B. Qualita ve
C. Quan ta ve D. All of these
Q.305 The solvent is selected for crystalliza on of a substance on the basis of:
✓ A. on hit and trial basis B. its polar nautre
C. it non-polar nature D. it should react chemically
Q.306 C6H12O6and C12H22O11are:
A. Mono-atomic molecules B. Diatomic molecules
✓ C. Poly-atomic molecules D. hetero-atomic molecules
Q.307 Which type of chromatography has fixed phase
_______________________________________________________________________________________
A. Absorp on ✓ B. Par on
C. Gas D. None of them
Q.308 Which element cannot analyzed directly by combus on analysis?
A. Dilute H2SO4 ✓ B. 50% KOH
C. Dilute HCl D. Mg(CIO4)2
Q.309 One mole of SO2contains:
A. 6.02 x 1023atoms of oxygen B. 18.1 x 1023molecules of SO2
✓ C. 6.02 x 1023atoms of sulphur D. 4 gram atoms of SO2
Q.310 A radioac ve isotope of thallium, 20181 TI, is used to assess damage in heart muscies a er a heart a ack
Which statement about 20181 TI is correct?
A. This isotope has a nucleon number of 120 ✓ B. The number of electrons in one atom of this isotope is 81.
C. The number of neutrons is one atom of this D. 201

82Xis an isotope of20181 IT.
isotope is 201
Q.311 The mass of one moll of electron is:
A. 1.008 mg B. 0.184 mg
✓ C. 0.54 mg D. 1.673 mg
Q.312 0.5 mole of CH4and 0.5 mole of SO2gases have equal
A. Volume B. Mass is grams
C. Total number of atoms ✓ D. Number of molecules
Q.313 0.1 mole of H3PO4 is completely ionized in water The number of total ions produced during its ioniza on are
A. 6.02 x 1023 B. 0.1 x 6.02 x 1023
✓ C. 2.408 x 1023 D. 0.1 x 2.408 x 1023
Q.314 Isotopes of an element differ in
A. Arrangement of electrons in orbitals B. Electronic configura on
C. Chemical proper es ✓ D. Proper es which depends upon mass
Q.315 The numerical value of N/n (where N is the number of molecules in a given sample of gas and n is the number of
moles of the gas) is
A. 8.314 B. 6.02 x 1023
✓ C. 1.62 x 10-24 D. 1.66 x 10-19
Q.316 Use of the periodic table is relevant to this ques on most modern cars are fi ed with airbags. These work by
decomposing sodium azide to liberate nitrogen gas, which inflates the bag.
2NaN3→3N2 + 2Na
A typical driver's airbag contains 50g of sodium azide.
Calculate the volume of nitrogen this will produce at room temperature.
A. 9.2 dm3 B. 13.9 dm3
✓ C. 27.7 dm3 D. 72.0 bm3
Q.317 Chromatography can be classified on the basis of
A. Phase B. Shape
C. Mechanism ✓ D. All of the above
Q.318 The mass which is calculated from the rela ve abundance of isotopes of an element is called
A. Frac onal atomic mass B. Average atomic mass
C. Rela ve atomic mass ✓ D. Both a and b
Q.319 100 g of CaCO3 is treated with 1 litre of 1 N HCI,What would be the weight of CO2 liberated a er the comple on of the
reac on?
A. 5.5 g B. 11 g
✓ C. 22 g D. 33 g
Q.320 The mathema cal rela onship for m/e in terms of radius of curvature of ions strength of electrical field (E) and
magne c field strength (H) is
A. m/e = H/H2r2 B. m/e = 2H/E2r2
✓ C. m/e = H2r/E D. m/e = 2r/E2H2
Q.321 What is the molarity of a solu on containing 15.0 g urea in 500 cm3of solu on
✓ A. 0.5 M B. 1M
_______________________________________________________________________________________
C. 1.5 M D. 2M
Q.322 Which one of the following contains one mole of the stated par cles
A. Chlorine molecules in 35.5 g of chlorine gas B. Oxygen atoms in 22.4 3of oxygen gas at
dm S.T.P
✓ C. Electrons in 1 g of hydrogen gas D. H+ions in 73 g of HCI
Q.323 The limi ng reactant is the reactant which
A. Consumed earlier B. Gave lease no. of mole of product
C. Control the reac on ✓ D. All of these
Q.324 The charge on one mole of proton
A. 2.4 x 104columbs B. 4.825 x 104columbs
C. 7.237 x 104columbs ✓ D. 9.65 x 104columbs
Q.325 What is the molarity of the solu on that contains 20 grams of NaOH in 500 ml of solu on?
A. 0.25 B. 0.5
✓ C. 1 D. 20
Q.326 Which
32 is isotope of an element in the third period of the periodic table contains the same number of j=neutrons as
16S?
A. 23 B. 24
11Na 12Mg
C. 28
14Si ✓ D. 31
15P
Q.327 The number of molecule in one gram molecules is called as

A. Molecule number B. Formula unit
✓ C. Avogadro's number D. All of these
Q.328 The number of moles in CO2 in 11g of gas is:
A. 0.5 mol B. 0.2 mol
✓ C. 0.25 mol D. 0.3 mol
Q.329 If KD for a component is very large then which statement about this component is correct
A. This component mostly remains in sta onary ✓ B. This component is mostly remains in mobile
phase phase
C. Component equally distributes itself between D. All are possible
sta onary and mobile phase
Q.330 A 5.00g sample of an anhydrous Group-ll metal nitrate loses 3.29 g in mass on strong hea ng. Which metal is present?
A. mshnrdium ✓ B. calcium
C. stron um D. barium
E.
Q.331 Isotopes are sister atoms of same element with similar chemical proper es but different:
A. Atomic structure B. Atomic volume
✓ C. Atomic mass D. Atomic number
Q.332 In SI units, the prefix nano means:
A. 10-6 B. 10-12
C. 10-15 ✓ D. 10-9
Q.333 The most efficient solvent extrac on method is by using
✓ A. Repeated extrac on and small por on of B. Repeated extrac on and small por on of
solvent solvent
C. Single extrac on and large por on of solvent D.
Q.334 When carbon dioxide passes through lime water, Ca(OH)2aqueous solu on, white precipitate is formed, it is
A. CaO ✓ B. CaCO3
C. H2CO3 D. Ca2CO3
Q.335 The number of atoms present in 0.5 g atom of nitrogen is not same as the number of atoms in
A. 12 g of carbon B. 32 g of sulphur
✓ C. 8 g of the oxygen D. 24 g of magnesium
Q.336 Macromolecules are
A. organic molecules ✓ B. high molecular mass molecules
C. natural compounds D. rarely occurring molecules
Q.337 Which of the following statement is not involved in determina on of empirical formula
_______________________________________________________________________________________
A. Determina on of % age of each element ✓ B. Determina on of isotopes of each element
C. Determina on of gram atom of each element D. Determina on of atomic ra o of element
Q.338 On strong hea ng a hydrocarbon produces ethene, propane and but-1-ene in the mole ra o 5 : 1 : 1, What is the
molecular formula of the hydrocarbon?
A. C17H34 ✓ B. C17H36
C. C19H38 D. CH19H40
Q.339 The percentage of H is the highest in
✓ A. CH4 B. NH3
C. H2SO4 D. C6H12O6
Q.340 The compara ve rates at which the solutes move in paper chromatography depend on
A. The size of papaer B. Temperature of the experiment
✓ C. Rfvalues of solutes D. Size of the chromatographic tank used
Q.341 The direct change from solid to gaseous state is referred as
A. Dissocia on ✓ B. Sublima on
C. Decomposi on D. Deliquescence
Q.342 A solu on can be
A. Dilute and concentrated B. Saturated and dilute
C. Saturated and unsaturated ✓ D. Supersaturated and saturated
Q.343 When a solid which has high vapour pressure at a temperature below its boiling point,is heated it starts
✓ A. Sublima on B. Mel ng
C. Decomposing D. Condensing
Q.344 The element which is not mono isotopic
A. Arsenic B. Fluorine
C. Gold ✓ D. Silver
Q.345 On collision, airbags in cars inflate rapidly due to the produc on of nitrogen.
The nitrogen is formed according to the following equa ons,
2Nan3→2Na + 3N2
10Na + 2KNO3 →K2O + 5Na2O +N2
How many moles of nitrogen gas are produced of four 1 mol of sodium azide, NaN3 ?
A. 1.5 ✓ B. 1.6
C. 3.2 D. 4.0
Q.346 Which of the following process is exothermic
A. Forma on of uniposi ve ion B. Forma on of unit nega ve ion
C. Forma on of di-posi ve ✓ D. Forma on of di-nega ve
Q.347 The components of which mixture can be separated by chromatography
A. NaCI & CaCI2 B. Sand and naphthalene
C. I2and water ✓ D. Blue red inks
Q.348 The amount of solute present in the given amount of solvent is called
A. Molarity B. Molality
✓ C. Concentra on D. Solubility
Q.349 The molarity of solu on containing 1.5 grams urea (N2H4CO) dissolved in 100 cm3of the solu on is
A. 1 molar B. 0.1 molar
C. 0.2 molar ✓ D. 0.25 molar
Q.350 Chromatography phenomenon is based on
A. Separa on B. Precipita on
C. Filtra on ✓ D. Distribu on
Q.351 Slow cooling the hot saturated solu on yields:
✓ A. large size crystals B. premature crystalliza on of the solute
C. medium size crystal D. immiscible liquids
Q.352 The mass of one mole of proton is
✓ A. 1.008 g B. 0.184 g
_______________________________________________________________________________________
C. 1.673 g D. 1.008 mg
Q.353 Which one of the following statements is incorrect
A. actual yield is always less than the theore cal ✓ B. the formula of a compound is not definite
yield
C. law of conserva on of mass is applied in
stoic ometry
D. Boyles law is applied in stoichiometry
Q.354 There are two isotopes of an element with atomic mass z.Heavier one has atomic mass z + 2 and lighter one has z - 1
then abundance of lighter one is
A. 66.6% B. 96.7%
C. 6.67% ✓ D. 33.3%
Q.355 Rela ve atom mass of O is:
A. 1.00794 a.m.u ✓ B. 15.9994 a.m.u
C. 35.453 a.m.u D. 17.674 a.m.u
Q.356 Mass spectrometer measures the;
A. the number of element present is a molecule ✓ B. m/e values of posi ve ion
C. average mass of an element D. exact mass of an element
Q.357 The paper with dried spots is dip into solvent mixture with the depth of
A. 1-2 cm B. 5-6 cm
C. 1-2 mm ✓ D. 5-6 mm
Q.358 The largest number of molecules are parent in:
✓ A. 3.6g of H2O B. 4.8g of C2H5OH
C. 2.8g of CO D. 5.4g OF N2O5
Q.359 What type of moiecular ions is more abundant
A. Nega vely charged B. Zwi er ions
✓ C. Posi vely charged D. Complex
Q.360 The mass of sulphur which combines with 24 grams oxygen to form SO2
A. 32 grams ✓ B. 24 grams
C. 8 grams D. 12 grams
Q.361 17.1 grams sucrose (C12H22O11) dissolved in 250 cm3of solu on. This has molarity
A. 0.1 M ✓ B. 0.2 M
C. 0.01 M D. 0.1 M
Q.362 The pressure of vapours when sent to the ioniza on chamber in mass spectrometer is
A. 10-5to 10-6torr ✓ B. 10-6to 10-7torr
C. 10-7to 10-8torr D. 10-3to 10-4torr
Q.363 The number of moles of hydrogen atoms in 3.2 g of methane CH4(rela ve atomic mass of H=1, C=12):
✓ A. 0.8 B. 0.2
C. 0.6 D. 0.4
Q.364 If four moles of sulphur dioxide are oxidised to sulphur trioxide, how many mole of oxygen molecules are required?
A. 0.5 B. 1.0
C. 1.5 ✓ D. 2.0
Q.365 Vapour density of a gas is 22.What is its molecular mass?
A. 33 B. 22
✓ C. 44 D. 11
Q.366 Filtra on by a glass funnel and filter paper is very
✓ A. Time consuming B. Fast
C. Difficult D. Accurate
Q.367 The largest number of molecules is present in:
A. 3.6g of H2O B. 4.4g of C2H5OH
✓ C. 2.8g of CO D. 5.4g of N2O5
Q.368 Sintered glass crucible is used for
A. Separa on of two miscible liquids B. Purifica on of slid
_______________________________________________________________________________________
✓ C. Convenient filtra on than that by Gooch D. To avoid premature crystalliza on of solute
crucible
Q.369 Which of the following are iso-electronic species
A. F-,C1-,Br- B. O,O-,O+
✓ C. F-,Ne,Na+ D. Be+2,Mg+2,Ca+2
Q.370 8.0 oxygen reacts with 8.0 g hydrogen to produce water which of the following is limi ng reactant
✓ A. O2 B. H2
C. H2 or O2 D. Both a & b
Q.371 Unnilpen um is an ar ficial element, one of its isotopes is 262105 Unp.
Which of the following statements is correct?
A. 262
105Unp has a nucleon number of 105. ✓ B. The atom262105X is an isotope of262105Unp
C. There are 262 neutrons in262Unp D. The proton number of262105Unp is262
Q.372 One mole of SO2contains
A. 6.02 x 1023atoms of oxygen B. 18.1 x 1023molecules of SO2
✓ C. 6.02 x 1023atoms of sulphur D. 4 gram atoms of SO2
Q.373 Ascorbic acid is also called
A. Vitamin A B. Vitamin B-5
✓ C. Vitamin-C D. Vitamin E
Q.374 Which of the following is not a condi on for S.T.P?
A. 0°C B. 273 k
C. 1 atm ✓ D. 298 k
Q.375 The rela ve atomic mass of chlorine is 35.5. What is the mass of 2 mol of chlorine gas?
✓ A. 142 g B. 71 g
C. 35.5 g D. 18.75 g
Q.376 Solvent extrac on is par cularly useful technique for separa on when the product to be separated is
A. Non-vola le or thermally unstable B. Non-vola le or thermally stable
C. Vola le or thermally stable ✓ D. Vola le or thermally unstable
Q.377 In combus on analysis CO2 produced during the combus on of an organic compound is absorbed in
A. Mg(CIO4)2 B. AI2O3
✓ C. 50%KOH D. H2SO4
Q.378 Atoms can be evident by the use of electron microscope, field ioniza on microscope and:
✓ A. X-reys B. Video camera
C. Telescope D. Compound microscope
Q.379 Chromatography is important in
A. Qualita ve analysis B. Quan ta ve
C. Determina on of purity of substance ✓ D. All of above
Q.380 What is the volume in cm3of 3.01 x 1023molecules of O2gas at S.T. P.
A. 1000 cm3 B. 11000 cm3
✓ C. 1120 cm3 D. 11200 cm3
Q.381 During the process of crystalliza on the hot saturated solu on:
✓ A. is evaporated to get the crystals of the B. id cooled very slowly to get large sized
products crystals
C. is cooled at a moderate rate to get medium D. is mixed with an immiscible liquid to get the
sized crystals pure crystals of the products
Q.382 The soul of chemistry is its dealing with:
A. to reduce the economy of the process B. to carry out complete combus on
✓ C. to reduce the me for comple on of the D. all of above
reac on
Q.383 What is correct rela onship between empirical and molecular formulas?
A. empirical formula ×√n =Molecular formula B. empirical formula/n = molecular formula
C. empirical formula ×n²= molecular formula ✓ D. molecular formula/n = Empirical formula
Q.384 In which species are the numbers of electrons and neutrons and equal?
A. 9 B. 199F
4Be
_______________________________________________________________________________________
C. 23
11Na+ ✓ D. 18
8O
2-
Q.385 How many moles of hydrogen atoms does 3.2 g of methane, CH4, contain?
A. 0.02 B. 0.2
C. 0.4 ✓ D. 0.8
Q.386 Which of the following can always exist independently
A. Atom ✓ B. Molecule
C. Ion D. Radical
Q.387 Which of the following contains 3.01 x 1022 silver ions?
A. 2.7 x 1020 B. 1.003 x 1022
C. 2.7 x 1022 ✓ D. 1.003 x 1023
Q.388 Molecular ions are generated with high energy ____
A. X-rays B. Alpha rays
C. Beam of electron ✓ D. All of these
Q.389 A mixture of two liquids, hydrazine and dinitrogen tetra oxides are used as a fuel in
A. Automobiles B. Space cra s
✓ C. Rockets D. Train
Q.390 The mass of 2 moles of sodium hydroxide will be
A. 20g B. 2g
✓ C. 80g D. 40g
Q.391 Hydrochloric acid available in the laboratory is 36% w/w. The density of HCl solu on is 1.19 g cm-3. The molarity of HCl
solu on is
A. 10.23 moles dm-3 B. 11.55 moles dm-3
✓ C. 11.73 moles dm-3 D. 12.67 moles dm-3
Q.392 The empirical formula of the compound having 50% sulphur and 50% oxygen by mass is
A. SO B. S 2O 3
C. SO3 ✓ D. SO2
Q.393 0.55 mg of electrons collec on is equal to
✓ A. 1 mole of electrons B. 100 moles of electrons
C. 1000 moles of electrons D. 10 moles of electrons
Q.394 Solvent extrac on method is used for compounds which are
A. Vola le B. Thermally unstable
✓ C. Both A & B D. None
Q.395 A compound having the highest % age of oxygen by weight is:
A. C2H5OH B. HCOOH
✓ C. CH3- OH D. H 2O
Q.396 CI2, N2and O2are:
✓ A. Diatomic molecules B. hetero-atomic molecules
C. Poly-atomic molecules D. Mono-atomic Moleclues
Q.397 The mass of 16.8105 dm3volume of nitrogen gas at STP
A. 14 g mole ✓ B. 21 g
C. 28 g D. 35 mole
Q.398 In filtra on process which apparatus is used to avoid the premature crystalliza on of solute
A. Desiccators ✓ B. Hot water funnel
C. Fluted filter paper D. Gooch crucible
Q.399 In alkaline medium CIO2 oxideses H2O2 to O2 and itself gets reduced to CI-.How many moles of H2O2 are oxidized by 1
mole of CIO2?
A. 1.0 B. 1.5
✓ C. 2.5 D. 3.5
Q.400 One mole of SO2 contains
A. 6.02 x 1023atoms of oxygen B. 1.003 x 1023 molecules of SO2
_______________________________________________________________________________________
✓ C. 6.02 x 1023 atoms of sulphur D. 3.01 x 1023 atoms of SO2
Q.401 In combus on analysis, % of oxygen is calculated by subtrac ng others percentages from:
A. 50 ✓ B. 100
C. 25 D. 200
Q.402 The nega vely charged par cles are called
A. ca on B. radical
✓ C. anion D. positron
Q.403 Anions are larger than their:
A. Parent molecules ✓ B. Parent atoms
C. Present electrons D. None of these
Q.404 If 5.85 g of Nacl are dissolved in 90g of water,the mole frac on of Nacl is?
A. 0.1 B. 0.01
✓ C. 0.2 D. 0.0196
Q.405 What method is used to remove insoluble solids from muddy water?
A. dis lla on B. evapora on
✓ C. filtra on D. chlorina on
Q.406 The formula mass of ionic substance expressed in gram is called as
A. Gram atom B. Gram molecule
✓ C. Gram formula D. Gram ions
Q.407 Use of the data booklet is relevant to this ques on.
When a sports medal with a total surface area of 150cm2 was evenly coated with silver, using electrolysis, its mass
increased by 0.216g.
How many atoms of silver were deposited per cm2 on the surface of the medal?
✓ A. 8.0 x 1018 B. 1.8 x 1019
21
C. 1.2 x 10 D. 4.1 x 1022
Q.408 Copper (ll) oxide is mixed with organic compound during combus on. The purpose is:
A. to reduce the economy of the process ✓ B. to carry out complete combuus on
C. to reduce the me for comple on of the D. all of above
reacrion
Q.409 Metals tend to lose electrons, becoming:
✓ A. Posi vely charged ions B. Non-metals
C. Nega vely charged ions D. All of above
Q.410 Freezing point of a substance is a temperature of which a liquid substance is converted to solid. it is:
A. exactly the same as its mel ng point B. always lower than its mel ng point
C. usually a li le lower than its mel ng point ✓ D. none of these
Q.411 Which one is not usually used for the crystalliza on
A. Acetone B. Ace c acid
✓ C. Sulphuric acid D. Chloroform
Q.412 If the solvent is inflammable for hea ng purpose we use
A. Ice bath ✓ B. Water bath
C. Wire gauze D. Thermostat
Q.413 The amount of a product which is really obtained in a chemical reac on is called:
✓ A. Experimental yield B. Theore cal yield
C. Balanced yield D. Actual yield
Q.414 How many atoms are present in one mole of water?
✓ A. 3(6.02 x 1023) B. 54
23
C. 6.02 x 10 D. 3
Q.415 The equivalent weight of a certain trivalent element is 20.Molecular weight of its oxide is
✓ A. 168 B. 68
C. 152 D. 56
Q.416 3.01 x 1022Ag+ions is present in
_______________________________________________________________________________________
A. 85 grams AgNO3 B. 0.85 g AgNO3
✓ C. 8.5 g AgNO3 D. 18.5 g AgNO3
Q.417 N2O4 is a poisonous gas. it can be disposed of safely by reac on with sodium hydroxide.
N2O4(g) + 2NaOH(aq) →NaNo3(aq) + NaNO2(aq) + H2O(I)
What is the minimum volume of 0.5 mol dm3 MaOH (aq) needed to dispose of 0.02 mol of N2O4?
A. 8cm3 B. 12.5cm3
C. 40cm 3 ✓ D. 80cm3
Q.418 Two elements X (atomic mass = 50) and Y ( atomic mass = 16) combine to give a compound having 32% Y. The formula
of the compounds is
✓ A. X2Y3 B. XY
C. XY2 D. X 3Y 4
Q.419 One mole of ehanol and one mole of ethane have an equal
A. mass B. number of atoms
C. number of electrons ✓ D. number of molecules
Q.420 The smaller number of molecules is in
A. 28 g of CO B. 36 g of H2O
C. 46 g of C2H5OH ✓ D. 54 g of N2O5
Q.421 In mass-spectrometer the method used for separa on of isotopes is
A. Ultracentrifuge B. Loser separa on
✓ C. Electromagne c separa on D. All of these
Q.422 When one mole of each of the following is completely burned in oxygen, which gives the largest mass of carbon
dioxide?
A. carbon monoxide B. diamond
✓ C. ethane D. methane
Q.423 Which of the following masses of 12C contain 1 mole of electrons
A. 12 g B. 6g
✓ C. 2g D. 1g
Q.424 X-ray work has shown that the diameters of atom are of the order of
A. 8 x 10-10m ✓ B. 2 x 10-10m
C. 8 x 10-8m D. 2 x 10-8m
Q.425 An insoluble solid can be separated from a liquid by:
✓ A. filtra on B. sublima on
C. crystalliza on D. chromatography
Q.426 The rela ve atomic mass of chlorine is 35.5, What is the mass of 2 moles of chlorine gas?
✓ A. 142g B. 35.5g
C. 71g D. 18.75g
Q.427 How many moles of H3PO4contain NAof PO4-3ions
✓ A. One mole B. 0.5 moles
C. Three moles D. None of these
Q.428 the top of funnel stem should touch the side of the beaker because:
✓ A. this gives medium size crystals B. filtrate runs down without crystals
C. this gives bigger size crystals D. the filtrate is quick
Q.429 The mass of one mole of iodine:
✓ A. 245g B. 127g
C. 74g D. 53g
Q.430 Number of moles of CO2 which contains 8.0 g of oxygen
✓ A. 0.25 mole B. 1.0 mole
C. 0.50 mole D. 1.50 mole
Q.431 Ascorbic acid contains 40.92% carbon,4.58% hydrogen, and 54.5% oxygen.The empirical formula is
✓ A. C 3 H 4O 3 B. C 2H 4O 3
C. C 3H 5O 4 D. none of these
_______________________________________________________________________________________
Q.432 A complete analysis of a compound generally involves

A. 3 steps ✓ B. 4
C. 5 D. 6
Q.433 The percentage of oxygen in NaOH is
✓ A. 40 B. 60
C. 8 D. 10
Q.434 The number of moles of NH4Cldissolved in 500 cm3of its 15% solu on is
A. 1 mole ✓ B. 1.4 moles
C. 2.0 moles D. 2.4 moles
Q.435 Mg metal reacts with HCl to give hydrogen gas. What is minimum weight of HCl required produced 12 g of H2
A. 428 g ✓ B. 438 g
C. 448 g D. 458 g
Q.436 The reason of less experimental yield than theore cal yield are reversible reac on, side reac on and:
A. Temprature ✓ B. Crystalliza on
C. Pressure D. Maximiza on
Q.437 Which of the following produced in the ionioza on of mass spectrometer?
A. F 2+ , O 2+ , H 2 + B. F 2, O 2 , H 2
✓ C. +
F ,H ,O+ +
D. F-, O-2, H-
Q.438 Which one of the following statement is incorrect
A. Actual yield is always less than the theore cal ✓ B. The formula of compound is not definite
yield C. :Law of conserva on of mass is applied in
stoichiometry
D. Law of definite propor ons is applied in
stoichiometry
Q.439 In combus on analysis, the combus on tube is fi ed in
A. Electric heater B. Gas heater
✓ C. Furnance D. Electronic heater
Q.440 One mole of CH3OH and one mole of C2H5 OH have
✓ A. Equal number of molecules B. Equal number of atoms
C. Equal number of electrons D. Equal number of protons
Q.441 Among the following pairs,the one which illustrates the law of mul ple propor ons is
A. NH3, HCI B. H2S,SO2
✓ C. CuO,Cu2O D. CS2,FeSO4
Q.442 The volume in liters of CO2 liberated at STP when 10 grams of 90% pure limestone is heated completely is
A. 22.4 B. 2.24
C. 20.16 ✓ D. 2.016
Q.443 What is the number of par cles in 16 grams of oxygen gas?
A. 6 x 1023 B. 12 x 1023
✓ C. 3 x 10 23
D. 3 x 1022
Q.444 27g of AI will react completely with how much mass of O2 to produce AI2O3
A. 8 g of oxygen B. 32 g of oxygen
C. 16 g oxygen ✓ D. 24 g of oxygen
Q.445 One mole of ethane(C2H6) and one mole of ethanol(C2H5OH) have an equal:
✓ A. Number of molecules B. Number of atoms
C. Number of electrons D. Masses
Q.446 What is the concentra on of nitrate ions,if equal volumes of 0.1 M AgNO3 and 0.1 M NaCI are mixed together?
A. 0.1 M B. 0.2 M
✓ C. 0.05 M D. 0.25 M
Q.447 The process of filtra on is used to:
A. separate solute from solu on B. separate the tow immiscible liquids
C. separate the two miscible liquids ✓ D. separate insoluble par cles from liquids
_______________________________________________________________________________________
Q.448 Which one is not the drying agent
A. Cacl2 ✓ B. Caocl
C. Silica gel D. Phosphorus penta-oxide
Q.449 A beaker contains 9 grams of water. The number of H atoms is
✓ A. 6.02 x 1023 B. 3.01 x 1023
C. 6.02 x 1024 D. 3.01 x 1023
Q.450 Which one of the following is the molecular formula of hydrocarbon which contains 80% by mass of carbon and 20%
by mass of hydrogen
A. CH4 ✓ B. C 2H 6
C. C 3H 6 D. C 3H 6
Q.451 Which of the following statements is not true?
A. isotopes with even atomic masses are B. isotopes of odd atomic masses are
compara vely abundant compara vely abundant.
✓ C. isotopes with even atomic masses and even D. isotopes with even atomic masses and odd
atomic numbers are compara vely atomic numbers are compara vely abundant.
abundant.
Q.452 Use of the periodic table is relevant to this ques on. A garden fer lizer is said to have phosphorus content of 30.0%
'P2O5 soluble in water'. What is the percentage by mass of phosphorus in the fer lizer?
A. 6.55% ✓ B. 13.1%
C. 26.2% D. 30.0%
Q.453 Al3+is a symbol for aluminum
A. atom B. ion
✓ C. ca on D. anion
Q.454 The ______ of atoms present in a molecule determines its atomicity
A. Nature B. Size
✓ C. Number D. All of these
Q.455 Use of the periodic table is relevant to this ques on. Analy cal chemists can detect very small amounts of amino
acids, down to 3 x 10-21 mol.How many molecules of an amino acid (Mr =200) would this be?
A. 9 B. 200
✓ C. 1800 D. 360000
Q.456 What are number of mole of oxygen atoms in 11 g of CO2gas?
A. 1.0 B. 0.75
C. 0.25 ✓ D. 0.50
Q.457 The total number of electrons in the one telluride ion Te-2is (atomic number of Te = 52)
✓ A. 54 B. 50
C. 52 D. 53
Q.458 A compound contains 75% carbon and 25% hydrogen, by mass.
What is the molecular formula of the compound?
A. C 3H 8 ✓ B. CH4
C. C 2H 4 D. C 2H 6
Q.459 Without suc on the filtra on through filter paper is
A. Rapid B. Slow
✓ C. Time consuming D. Occur at the moment
Q.460 Which of the following statement is correct for a chemical reac on?
✓ A. collide with energy more than energy of B. collide with energy less than energy of
ac va on ac va on
C. collide with high frequency D. collide with each other
Q.461 The efficiency of reac on is expressed in the form of ______
A. Percentage abundance B. Rela ve abundance
✓ C. Percentage yield D. Ac va on energy
Q.462 If the rela ve molecular mass of a compound is 90 its empirical formula would be?
✓ A. C 2 H 5O B. C2H5OH
C. C 3H 5O D. C5H11O
_______________________________________________________________________________________
Q.463 Use the date booklet is relevant to this ques on, Hard water contains calcium ions and hydrogencarbonate ions arising
from dissolved calcium hydrogencarbonate,Ca(HCO3)2. How many electrons are present in the hydrogencarbonate
anion?
A. 30 B. 31
✓ C. 32 D. 33
Q.464 10 moles of CH4at R.T.P would produce what volume of CO2?
A. 2.4 x 105dm3 ✓ B. 2.4 x 102dm3
C. 2.4 x 104cm3 D. 2.4 x 106cm3
Q.465 The coloured impuri es are removed from the crystallized substances by
A. Cooling B. Aera on
✓ C. Boiling D. Hea ng
Q.466 How many atoms does a 35.5 gram sample of chlorine gas has?
A. 3 x 1023 B. 6 x 1024
C. 3 x 1022 ✓ D. 6 x 1023
Q.467 Difference in density is the basis of
A. Ultrafiltra on B. Molecular sieving
✓ C. Gravity separa on D. Molecular a rac on
Q.468 The number of moles of 0.1 kg of calcium
A. 0.0025 mole B. 0.025 mole
C. 0.25 mole ✓ D. 2.5 mole
Q.469 The empirical formula of a hydrocarbon is C2H5O. Which of the following cannot be that hydrocarbon?
A. C2H4OH B. C4H8(OH)2
✓ C. C 4 H 8O D. C4H10O2
Q.470 Which of the following compound has highest % age of oxygen
✓ A. H 2 C 2O 4 B. HCHO
C. CH3CH2COOh D. All has same
Q.471 The rela ve abundance of the ion with a definite m/e value is measured by:
A. quan ty of a fast moving electrons ✓ B. strength of electric current measured
C. high pressure of vapours D. electron gas
Q.472 CO+is an example of:
A. stable molecule B. Anionic molecule ion
✓ C. Ca onic D. Free redical
Q.473 Gold has isotopes:
A. 4 B. 3
C. 2 ✓ D. 1
Q.474 Isotopes of an element are recorded separetely in:
✓ A. Mass spectrometer B. Mass spectrophotometer
C. Calorimeter D. Mass meter
Q.475 For decolorizing 1 mole of KMnO4,the moles of H2O2 required is
A. 1/2 B. 3/2
✓ C. 5/2 D. 7/2
Q.476 There are as many as seven steps used in:
A. chromatographic techniques ✓ B. crystalliza on technique
C. solvent extrac on techniqe D. filtra on technique
Q.477 What is the net charge on ferrous ion?
✓ A. +2 B. +3
C. +4 D. +5
Q.478 1 amu is equal to
A. 1.661 x 10-20 kg B. 1.661 x 10-22 kg
✓ C. 1.611 x 10-27 kg D. 1.611 x 10-24 kg
_______________________________________________________________________________________
Q.479 Normally, it is known that in the gaseous state the distance between molecule is ______ mes greater than their
diameter
A. 250 B. 275
✓ C. 300 D. 350
Q.480 Which of the following is not macromolecule
A. Cellulose B. Hemoglobin
C. Glycogen ✓ D. Sucrose
Q.481 when energy is released during a reac on, it is:
A. endothermic reac on ✓ B. exothermic reac on
C. a bond breaking reac on D. a free radical reac on
Q.482 Which of the following is directly related to Qualita ve analysis?
✓ A. Iden fica on B. Separa on
C. Measurement D. Calcula on
Q.483 A diamond chain is 6 g in weight. what is the number of atoms in it:
✓ A. 3.01 x 1023 B. 1.003 x 1023
C. 12.04 x 1023 D. 6.02 x 1023
Q.484 A chemical formula based on an actual molecule is called
A. empirical formula B. structure formula
✓ C. molecular formula D. simples formula
Q.485 Swedish chemist J. Berzelius determined:
A. Atomic density B. Atomic number
✓ C. Atomic mass D. Atomic volume
Q.486 Form which mixture can the fast substance be obtained by adding water, s rring and filtering?
A. oxygen and nitrogen B. magnesium and iron
✓ C. sodium chloride and copper D. sulphate
Q.487 An alkaloid contains 17.28% of nitrogen and its molecular mass is 162.The number of nitrogen atoms present in one
molecule of alkaloid is:
A. Five B. Four
C. Three ✓ D. Two
Q.488 The total redioac ve (stable and unstable) isotopes are
A. 300 B. 280
✓ C. 340 D. 580
Q.489 The reac on:-
4NH3 + 3O2→ 2N2 + 6H2 + 6H2O
A. one mole of NH3will produce 6 mole of N2 ✓ B. one mole of
3
will produce 1/2 of mole of
2
NH N
C. for complete rec on of 2 40g of are D. for the complete reac on and 20g are
3, 2 3 2
moles of NH O required 2 moles of NH of O required
Q.490 Filtra on through Gooch and sintered glass crucibles is aided by a gentle suc on:
A. quick filtra on can be done B. for prepara on of chemical compound
✓ C. it should deposit well formed crystals of the D. if dissolves a large amount of the substance
pure compound
Q.491 What quan ty of limestone (CaCO2) on hea ng will give 56 kg of CaO?
A. 1000 Kg B. 56 Kg
C. 44 Kg ✓ D. 100 Kg
Q.492 Which of the following statement is correct
A. For smooth filtra on stem of the funnel B. Selec on of filter paper depends on the size
should remain con nuously filled by liqiud of precipitate
C. In order to avoid splashing stem of the funnel ✓ D. All of the above
should touch side of the wall of a beaker
Q.493 Which is not branch of chemistry?
A. physical chemistry B. nuclear chemistry
✓ C. electrical chemistry D. bio chemistry
_______________________________________________________________________________________
Q.494 The use of the periodic table is relevant to this ques on.
what is the number of molecules in 500 cm3 of oxygen under room condi ons?
✓ A. 1.25 x 1022 B. 1.34 x 1022
C. 3.0 x 1022 D. 3.0 x 1026
Q.495 The rela ve abundance of isotopes of an element can be determined by
A. Isotopy ✓ B. Mass spectrometry
C. Isotropy D. Anisotropy
Q.496 A hydrocarbon contains 0.0334 mol of carbon,0.0668 mol of hydrogen and 0.0167 mol of oxygen. What is the
emperical formula of the hydrocarbon?
A. C 3H 4O 2 B. C 4H 8O 2
✓ C. C 2 H 4O D. CH2O
Q.497 Rela ve atomic mass of an element is the mass of an element rela ve to
✓ A. 1/12 mass of carbon-12 B. 1/12 mass of carbon
C. 1 mass of hydrogen atom D. 1/16 mass of oxygen
Q.498 The mass of 0.5 gram atom of uranium (U-238)
✓ A. 119 g B. 178.5 g
C. 238 g D. All of these
Q.499 A er filtra on slow cooling yields
A. Bigger & pure crystals ✓ B. Bigger & impure crystals
C. Smaller & pure D. Smaller & impure
Q.500 The hydrogen phosphate of certain metal has formula MHPO4. The formula of metal chloride would be
A. MCI ✓ B. MCL2
C. M2CI2 D. MCI3
Q.501 Which of the following type of chromatography is commonly used in the laboratory
✓ A. Ascending B. Descending
C. Radial D. All of the above
Q.502 If the strength of magne c field two me stronger then electric field and radius is 2m, then m/e ra o is
A. 4E B. 2E
C. 6E ✓ D. 8E
Q.503 Equal masses of oxygen, hydrogen and methane are kept under iden cal condi ons. The ra o of volumes of the gases
will be
A. 2 : 16 : 2 B. 2 : 16 : 1
✓ C. 1 : 16 :2 D. 1:1:1
Q.504 If NA is Avogadro's number then number of valence electrons in 4.2 g of nitride ions N3- is
✓ A. 2.4 NA B. 4.2 NA
C. 1.6 NA D. 3.2 NA
Q.505 A compound having empirical formula C3H3O and its molecular mass is 110.02. Its molecular formula
A. C 3H 3O ✓ B. C 6 H 6O 2
C. C 9H 9O 3 D. C 3H 6O 2
Q.506 The agent which is not used in vacuum dessicator as drying agent is
A. CaCI2 B. P 2O 5
C. Silica gel ✓ D. dil H2SO4
Q.507 The mass of one mole of electron is:
A. 1.008 mg ✓ B. 0.55 mg
C. 0.104 mg D. 1.673 mg
Q.508 Each molecule of haemoglobin is 68000 mes heavier than one atom of
A. C ✓ B. H
C. N D. O
Q.509 The mass of SO2Cl2 chloride which contains 14.2 g chlorine is
✓ A. 27 g B. 135 g
_______________________________________________________________________________________
C. 13.5 g D. 260 mg
Q.510 What is the mass of 2,4,6-trinitroaniline, C6H2(NO2)3NH2(Mr228), that can be obtained from 10 g of aniline,
C6H5NH2(Mr93)?
✓ A. 24.5 g B. 25.5 g
C. 25 g D. 24 g
Q.511 Upon complete combus on of ethanol in excess in air, which of the following is not formed/present in the final
product obtained?
A. CO2 ✓ B. CO
C. H 2O D. O2
Q.512 Steam is passed over heated magnesium to give compound X and hydrogen.
What is not a property of compound X?
A. it has a high mel ng point B. it is a basic oxide
C. it is a white solid ✓ D. it is very soluble in water
Q.513 The total number of atoms in 64 g of sulphur dioxide is
✓ A. 1.806 x 1024 B. 12.04 x 1023
C. 6.02 x 1023 D. 2.408 x 1024
Q.514 The set of numerical coefficients that balances the chemical equa on K2CrO4 + HCI → K2Cr2O7 + KCI + H2O
A. 1, 1, 2, 2, 1 B. 2, 2, 1, 1, 1
✓ C. 2, 1, 1, 2, 1 D. 2, 2, 1, 2, 1
Q.515 The following statement contained in a student's laboratory report is a conclusion:
A. a gas is liberated B. oxide of the gas is strongly acidic
✓ C. the gs is chlorine D. colour of the gas is greenish yellow
Q.516 A solu on of 10 mL of M/10 FeSO4 was trated with KMnO4 solu on in acidic medium,the amount of KMnO4 used will
be
A. 5 mL of 0.1 M B. 10 mL of 0.1 M
C. 10 mL of 0.5 M ✓ D. 10 mL of 0.02 M
Q.517 If 30 mL of H2 and 20 mL of O2 reacts to form water,what is le at the end of the reac on?
A. 10 mL of H2 B. 5 mL of H2
C. 10 mL of O2 ✓ D. 5 mL of O2
Q.518 The atom of an element is
✓ A. the smallest par cle B. the fundamental par cle
C. the independent par cle D. the charged par cle
Q.519 The molecular ions can be generated by passing
A. High energy electron beam B. αpar cles
C. High energy neutron beam ✓ D. Both a and b
Q.520 The diameter of atoms is of the order:
A. 2 x 10-5m ✓ B. 2 x 10-10m
C. 2 x 10-2m D. 2 x 10-3m
Q.521 10g of Mg and 5 g of C contain the same
✓ A. Number of atoms B. Atomic mass
C. Molecules D. All of these
Q.522 The calcula ons based on stoichiometry are known as:
A. Simple calcula ons ✓ B. Stoichiometric calcula ons
C. Complex calcula ons D. None of above
Q.523 A limi ng reactant is one:
✓ A. Which produces minimum number of mole B. Which produces maximum number of moles
of product of product
C. Does not affect the amount of product D. Which is present in least amount
Q.524 A filtra on process could be very me consuming if it were not added by a gentle suc on,, which is developed:
A. if he paper covers the funnel up to its B. if the paper has got small sized pours in it.
circumference C. if the stem of the funnel is large so that it dips
into the filtrate
_______________________________________________________________________________________
✓ D. if the paper fits ghtly
_______________________________________________________________________________________
2 States of Matter
Q.1 The rela onship between volume of a given amount of gas and prevailing condi ons of temperature and pressure are:
A. Charle's law B. Graham's law
C. Boyle's law ✓ D. Gas laws
Q.2 Metals are good conductor of electricity, but their conduc vity decreases by increase in temperature because
A. electrons a racted strongly by the nuclei B. atoms form ionic bond and no free electrons
which resists their free mo on
C. electrons go to the iocalized orbital not free
✓ D. posi ve metal ions begin to oscillate and
their mo on hinders the free movement of
electrons
Q.3 The highest temperature in which a substance can exist as a liquid is called its
A. Absolute temperature ✓ B. Cri cal temperature
C. Maximum temperature D. Body temperature
Q.4 A term to express the par al pressure of water vapours in a gas is known as
A. vapour pressure ✓ B. aqueous tension
C. par al pressure D. moisture
Q.5 The molecules of CO2is dry ice form the
A. ionic crystals B. covalent crystals
✓ C. molecular crystals D. any type of crystal
Q.6 Grey n crystals belong to
A. tetragonal ✓ B. cubic
C. orthorhombic D. rhomtrohedral
Q.7 The bonding which occurs among polar covalent molecules containing H and one of the small electronega ve element
such as O, F or N is called
A. bridge bonding B. metallic bonding
✓ C. hydrogen bonding D. Ionic bonding
Q.8 NH3gas is liquefied more easily than N2Hence
✓ A. Van der Waals constants a and b 3> that of 2
B. Van der Waals constants a and b of < that of
3 2
of NH N NH N
C. a(NH3) > a (N2) but b (NH3) < b(N2) D. a (NH3) < a (N2) but b (NH3) > b (N2)
Q.9 To which of the following mixtures Dalton's law of par al pressures is not applicable?
A. CO and CO2 B. CO2and N2
C. CH4and C2H6 ✓ D. HCI and NH3
Q.10 What types of bonds are broken when water turns into steam on hea ng?
A. covalent B. permanent dipole interac ons
✓ C. hydrogen bonds D. induced dipole interac ons
Q.11 The reason that diamond and graphite have different physical proper es is
A. density B. color
✓ C. bonding D. hardness
Q.12 The ideal gas law holds best under the condi ons of
A. high pressure and high temperature ✓ B. low pressure and high temperature
C. low pressure and low temperature D. high pressure and low temperature
Q.13 Equal masses of methane and oxygen are mixed in an empty container at 25°C The frac on of total pressure exerted
by oxygen is
_______________________________________________________________________________________
✓ A. 1/3 B. 1/9
C. 8/9 D. 16/17
Q.14 Which of the following equa ons represents the 2nd ioniza on energy of Na?
A. Na(g) ---> Na2+(g) + 2e- B. Na(s) ---> Na2+(g) + 2e-
C. Na+(s) ---> Na2+(g) + e- ✓ D. Na+(g) ---> Na2+(g) + e-
Q.15 Temperature at which molecular mo on ceases is called
✓ A. Absolute zero B. Absolute temperature
C. Cri cal temperature D. Difficult to predict
Q.16 R = 0.08205:
✓ A. atm dm3mol-1k-1 B. J mole-1k-1
-1 -1
C. Nm mol k D. cal. mol-1k-1
Q.17 If V1= 5 li ers, P1= 2 atm, T1= 273°C, T2= 0°C and V2= ? When P2= 1 atm.
✓ A. 5 lit B. 10 lit
C. 2.5 lit D. 12.5 lit
Q.18 Which of the following least resembles an ideal gas?
✓ A. ammonia B. helium
C. hydrogen D. trichloromethane
Q.19 Ionic crystals are bri le because
A. they have cubic geometry B. they are bad conductors of electricity
C. coordina on number of ca ons and anions is ✓ D. ca ons and anions are arranged in alternate
same posi ons in layers
Q.20 The number of molecules in one dm3 of water is close to:
A. 6.02/22.4 x1023 B. 12.04/22.4 x1023
C. 18/22.4x 1023 ✓ D. 55.6x6.02x1023
Q.21 How should the condi ons be changed to prevent the volume of a given gas from expanding when its mass increased?
A. temperature and pressure both ara increased B. temperature and pressure both are lowered
✓ C. temperature is lowered and pressure is D. temperature is increased and pressure is
increased descreased
Q.22 Liquefac on of gas can only be carried out if the:
A. without caring for the value cri cal volume at B. the temperature is more than cri cal and
cri cal stage pressure is 1000 atm
✓ C. the temperature is below the cri cal and D. temperature is above the cri cal temperature
pressure is very high and pressure can have any value
Q.23 Which of the following statements is false?
✓ A. Avogadro number = 6.02 x 1021 B. The rela onship between average velocity (v)
and root mean square velocity (u) is v =
0.9213 u
C. The mean kine c energy of an ideal gas is D. The root mean square velocity of the gas 1/2
independent of the pressure of the gas can be calculated by the formula (3RT/M)
Q.24 The kine c energy of 4 moles of nitrogen gas at 127°C is? cals.(R = 2 cal mol-1 K-1)
A. 4400 B. 3200
✓ C. 4800 D. 1524
Q.25 If R, T, M, V and P are gas constant, temperature, molar mass, volume and pressure then density is given by:
A. M/V B. RT/M
✓ C. PM/RT D. V/M
Q.26 In which of the following molecules strongest hydrogen bond is shown
A. water B. ammonia
✓ C. hydrogen fluoride D. hydrogen sulphide
Q.27 The unit of pressure ______ is commonly used by meteorologists
A. mm of Hg B. Kilopascal
✓ C. Millibar D. Pound per square inch
Q.28 A gas has non-ideal behaviour at:
A. high temperature and high pressure B. low temperature and low pressure
✓ C. high temperature and low pressure D. low temperature and low pressure
_______________________________________________________________________________________
Q.29 Which of the following is not molecular crystal
A. Sugar B. Iodine
C. Ice ✓ D. Graphite
Q.30 Joule is a unit of energy which is defied as
A. Kgm-2s-2 B. Kgm2s-1
C. Kgms-2 ✓ D. Kgm2s-2
Q.31 Vapour pressure of a liquid is more if
A. the intermolecular forces between the ✓ B. the intermolecular forces between the
molecules of the liquid are strong molecules of the liquid are weak
C. more liquid is present in a container D. liquid has more surface area to evaporate
Q.32 Evapora on of liquid takes place at every temperature. What when temperature becomes constant?
A. the rate of condensa on is greater than teh B. it depends upon the nature of the liquid
rate of condensa on C. rate of evapora on is greater than the rate of
condensa on
✓ D. the rate of condensa on and evapora on
become equal
Q.33 In a crystal the atoms are locate at the posi on of:
A. infinite poten al energy B. minimum poten al energy
✓ C. Zero poten al energy D. maximum poten al
Q.34 Diffusion of different species is due to difference of
A. poten al energy B. temperature
C. density ✓ D. all the above
Q.35 One dm3of O2at STP has mass
A. 32 g B. 16 g
C. 4.438 g ✓ D. 1.4383 g
Q.36 The graph between P onγ-axis and 1/V at x-axis for a given mass of a gas at temperature T is a
✓ A. straight line B. curved upward
C. curved downward D. circular
Q.37 Which of the following is not a property of crystalline solid
A. geometric shape B. cleavage plane
C. anisotropy ✓ D. isomerism
Q.38 Potassium crystallizes with a
A. Orthogonal la ce ✓ B. Cubic la ce
C. Triclinic D. Ortho rhombic la ce
Q.39 Evapora on causes
A. High temperature B. High pressure
✓ C. Cooling D. Vapour
Q.40
_______________________________________________________________________________________
A. T 1 = T 2= T 3 B. T 1 < T 2< T 3
✓ C. T 1> T 2> T 3 D. T 1 > T 2= T 3
Q.41 During sudden expansion of a gas energy is needed to overcome the intermolecular:
A. Vibra ons ✓ B. A rac ons
C. Repulsions D. All of above
Q.42 Which of the following may be called as London dispersion forces?
✓ A. instantaneous dipole-induced dipole forces B. dipole-dipole forces
C. ion-dipole forces D. dipole-dipole forces
Q.43 The gases suddenly if these are allowed to expand:
A. react ✓ B. cool down
C. heat up D. moved randomly
Q.44 Which of the following substance has maximum cri cal temperature
✓ A. H 2O B. N2
C. SO2 D. Ne
Q.45 At what temperature, would N2molecules have the same average speed as He-molecules at 300 k?
A. 1100 K ✓ B. 2100 K
C. 420 K D. None
Q.46 Cooling happens under the Joule Thomson Effect due to sudden:
A. Contrac on. B. Absorp on.
✓ C. Expansion. D. All of above.
Q.47 The boiling point of radon (211 K) is higher than boiling point of Helium (4.4 K) because
A. the atomic number of Rn is larger than that of B. the atomic mass of Rn is larger than that of He
the He
✓ C. the dispersion forces between Rn atoms are
more prominent that between He atoms
D. Rn atoms are joined by dipole-dipole force
whereas He atoms are joined by hydrogen
bonding
Q.48 The exis ng property of an element in to more than are crystalline state is termed as:
A. isomorphism B. polymorphism
C. isotropy ✓ D. allotropy
Q.49 As gases can adopt the shape of the container so they have
✓ A. no fixed shapes B. fixed shapes
C. different shapes D. definite shapes
Q.50 Glycerin boil at 290°C under normal atmospheric pressure. If the pressure is reduced to 50 mm of Hg, it
will boil
A. above the given temperature ✓ B. below the given temperature
C. at the same temperature D. at 25°C
Q.51 The boding which covalent molecules containing hydrogen and one of the small electronega ve element such as O,
For Mis called:
A. ionic bonding B. bridge bonding
✓ C. H-bonding D. metalic bonding
Q.52 The a racted forces which are created due to repulsion of electronic cloud of the molecules are:
A. ion-dipole forces B. dipole-dipole forces
C. dipoles-induced dipole forces ✓ D. instantaneous dipole-induced dipole
Q.53 The crystal system are of
✓ A. 7 types B. 10 types
C. 5 types D. 8 types
Q.54 Charles s law is only sa sfied if temperature is taken on
✓ A. Kelvin scale (b) B. Celsius scale (°C)
C. Fahrenheit scale (°F) D. All of these
Q.55 4.4 g of CO2 contains how many litres of CO2 at STP?
A. 2.4 litre ✓ B. 2.24 litre
_______________________________________________________________________________________
C. 44 litre D. 22.4 litre
Q.56 Which order of vapour pressure in the following liquids is correct
A. water > ethanol > acetone > ether ✓ B. ether > acetone > ethanol > water
C. ether > ethanol > acetone > water D. water > ether > acetone > ethanol
Q.57 For an ideal gas,number of moles per litre in terms of its pressure P,gas constant R and temperature T is
A. PT/R B. PRT
✓ C. P/RT D. RT/P
Q.58 Amorphous solids
A. have sharp mel ng points B. undergo clean cleavage when cut with knife
C. have perfect arrangement of atoms ✓ D. can possesses small regions of orderly
arrangements of atoms
Q.59 Crystal can be classified in to ......basic crystal habits
✓ A. 7 B. 4
C. 14 D. 3
Q.60 Keeping in view the charge density select the compound amoung the following having highest la c energy:
A. LiBr B. KCI
✓ C. MgO D. NaF
Q.61 If rate of diffusion of A is 5 mes that of B,what will be the density ra o of A and B?
✓ A. 1/25 B. 1/5
C. 25 D. 5
Q.62 Air contains 78% N2, 21% O2 and 1% other gases at sea level the par al pressure of O2 is
A. 760 torr ✓ B. 159 torr
C. 592 torr D. 7.6 torr
Q.63 A teacher told his student that air is a mixture. This is due to the reason that suddenly a student raised his hand and
said:
A. it has different proper es from its B. oxygen can be removed from it
cons tuents
C. it is colourless
✓ D. its composi on is different at different
al tudes.
Q.64 The rela onship which describes the varia on of vapour pressure with temperature is called
A. Hess's law B. Arrhenius equa on
C. Kirchhoff's law ✓ D. Clausius-Clapeyron equa on
Q.65 Two moles of an ideal gas at 1 atm are compressed to 2 atm at 273 K.The enthalpy change for the process is
A. 2 litre atm B. 1 litre atm
✓ C. Zero D. 3 litre atm
Q.66 Which of the following are more temperature senesi ve
✓ A. Liquid crystals B. Solid crystals
C. Ionic stals D. None of above
Q.67 If the pressure of gas reduced to one half and temperature is increased twice then density of gas will be
A. 4 mes B. 2 mes
C. 1/2 mes ✓ D. 1/4 mes
Q.68 If there are weak intermolecular forces in a liquid, it will be
A. more vola le ✓ B. less vola le
C. more dense D. less heavy
Q.69 Ma er having no definite shape and volume is called:
✓ A. gas B. liquid
C. solid D. plasma
Q.70 A graph is plo ed, P on x-axis and V on y-axis for a given mass at constant temperature, we shall get:
A. a curve with different peaks ✓ B. a curve called isotherm
C. straight line parallel to x-axis D. a straight line
Q.71 Glass is a
_______________________________________________________________________________________
A. Micro-crystalline solid ✓ B. Super-cooled liquid
C. Gel D. Polymeric mixture
Q.72 The boiling point of radon (211k)id higher than boiling point of helium (4.4k). This is due to the reason that:
✓ A. the atomic mass Rn is larger than that of He B. the atomic mass Rn is larger than that of He
C. the dispersion forces between Rn atoms are D. rn atomic number of Rn is larger than that of
more prominent than between he atoms He
Q.73 Van der Waal's forces exist in
A. Polar compounds B. Non-polar
C. Covalent ✓ D. All types of atoms and molecules
Q.74 Which is correct?
A. 1 mm Hg = 1 torr = 1 atm B. 1 mm Hg = 760 torr = 1 atm
✓ C. 760 mm Hg = 760 torr = 1 atm D. 760 mm Hg = 1 torr = 1 atm
Q.75 consider the physical proper es of the gases. Which of the following statements about par cles of gases is incorrect?
The par cles are:
A. causing pressure B. having wide spaces
✓ C. orderly arranged D. randomly moving
Q.76 choose the best example of diffusion of gases:
A. vapour condensing on moist surface ✓ B. spreading of small from a scent bo le
C. hot air rising above a candle D. bubbling in soda bo le
Q.77 Which of the following is a reason why real gases do not behave as ideal gases do?
✓ A. real gases have intermolecular forces B. real gases do not have intermolecular forces
between the molecules between the molecules
C. real gases exist as molecules D. molecules of real gases a ract each other
more strongly than molecules of ideal gases
Q.78 Which of the following is an example of diffusion?
✓ A. Spreading of smell of flowers in garden B. Steam condensing on a cold window
C. Bubbles rising in a beaker of boiling water D. All of above
Q.79 Air can be dis lled frac onally because the cons ltuents of the air:
A. have different densi es ✓ B. can be liquefied
C. are gases at room temperature D. have different boiling points
Q.80 The devia on of a gas from ideal behaviour is maximum at
✓ A. -10°C and 5.0 atm B. 100°C and 2.0 atm
C. -10°C and 2.0 atm D. 0°C and 2.0 atm
Q.81 Which of the following has no hydrogen-bonding
✓ A. Diethyl ether B. Water
C. Ethyl alcohol D. Phenol
Q.82 Density of a gas is usually expressed in
A. Kg m3 B. Kg dm3
✓ C. g dm-3 D. g cm-3
Q.83 At constant temperature, volume of given mass of a gas is inversely propor onal to pressure on it. This is statement of
A. Charles law ✓ B. Boyle's law
C. Hooks law D. Grahams law
Q.84 By increasing temperature,the transi on from a gas to an ionized gas gives free electrons called:
A. UV radia on B. gas phase
✓ C. plasma D. vapour density
Q.85 Deep sea divers breath air under increased pressure, therefore they use a mixture of
✓ A. 96% N2and 4% O2 B. 96% O2and 4% N2
C. 94% N2and 6% O2 D. 94% 02and 6% N2
Q.86 Bragg's law is given by equa on
A. n λ = 2 θ sin θ ✓ B. nλ = 2 d sin θ
C. 2nλ = d sin θ D. n λ= 1/2 d sin θ
Q.87
_______________________________________________________________________________________
When graph is plot between P and 1/V at constant temperature. A straight line obtains which move toward ______
when temperature increase
✓ A. Pressure axis B. Volume axis
C. 1/V axis D. 1/P axis
Q.88 which one of the following exhibits intermolecular hydrogen bonding?
✓ A. HF B. HC
C. HBr D. HI
Q.89 The des ny of a gas is directly propor onal to pressure, inversely propor onal to temperature and directly
propor onal to:
A. Viscosity ✓ B. Molar mass
C. Momentum D. All of above
Q.90 The cri cal temperature of NH3 is greater than CO2 due to its:
✓ A. Greater polarity B. Stable polarity
C. Lesser polarity D. None of above
Q.91 Mathema cally, Boyle's law is indicated as:
A. VT = K B. PT = K
✓ C. PV = K D. None of these
Q.92 Which of the following is not a macromolecule?
A. diamond B. graphite
✓ C. iodine D. silica
Q.93 Ionic solids with defects,contain
✓ A. Equal number of ca on and anion vacancies B. Inters al anions and anion vacanies
C. Ca on vacancies only D. Ca on vacancies and inters al ca ons
Q.94 When stress is applied to the metals, the metals are malleable and duc le because
✓ A. their layers slip pass each other B. atoms lose electrons
C. mobility of electrons increased D. none of the above
Q.95 Which thermometer will have its reading 273 degrees greater than that of thermometer C?
A. A ✓ B.B
C. B has 273 degrees greater than A D.C has greater reading than all other
thermometers
Q.96 Which one of the following statements about sodium chloride is incorrect?
A. it has a high mel ng point ✓ B. it conducts electricity at room temperature
C. it is soluble in water D. it is bri le
Q.97 The volume of an ideal gas is decreased to half, What will happen to the force exerted on the walls of the container by
the gas par cles?
A. the force is halved B. the force increases by a factor of 4
C. the force remains constant ✓ D. the force increased by a factory of 2
Q.98 The temperature of the gas is raised from 27°C to 927°C the root mean square velocity is
A. √927/27 mes the earlier value B. Same as before
C. Halved ✓ D. Doubled
Q.99 A real gas obeying Vander Waal's equa on will resemble ideal gas if
A. Both a and b are large ✓ B. Both a and b are small
C. a is small and b is large D. a is large and b is small
Q.100 Hydrogen diffuses six mes faster than gas A.The molar mass gas of gas A is
✓ A. 72 B. 6
C. 24 D. 36
Q.101 The graph between pressure and volume at constant temperature for gas is:
A. Isobaric B. Isothermal
✓ C. Isotherm D. None of above
Q.102 The par al pressure of 02in the lungus is
✓ A. 116 torr B. 159 torr
_______________________________________________________________________________________
C. 560 torr D. 760 torr
Q.103 What is the weight of 10 dm3of CO2at 27°C and 2 atm?
A. 89.3 g ✓ B. 56.1 g
C. 125 g D. 127 g
Q.104 Which solids are called true solids
✓ A. Crystalline B. Vitreous
C. Amorphous D. Metallic
Q.105 A temperature at which two cyrstalline forms of a substances coexist in equilibrium is called
A. standard temperature B. cri cal temperature
✓ C. transi on temperature D. absolute temperature
Q.106 Which of the following is the simplest form of ma er?
✓ A. Gaseous state B. Liquid state
C. Solid state D. All of above
Q.107 Which one of the following statements about mel ng point of metals is true?
A. sodium has a lower mel ng point than B. sodium has a higher mel ng point than
potassium magnesium
✓ C. potassium has a higher mel ng point D. lithium has a lower mel ng point than sodium
rubidium
Q.108 The state of ma er which exist only within a rela vely narrow range of temperature and pressure
A. Solid B. Gas
✓ C. Liquid D. Plasma
Q.109 The number of moles of H2 in 0.224 L of hydrogen gas at STP (273 K, 1 atm) assuming ideal gas behaviour is
A. 1 B. 0.1
✓ C. 0.01 D. 0.001
Q.110 One degree on Celsius scale is ______ me greater then Fahrenheit scale
✓ A. 9/5 B. 5/9
C. 6/5 D. 5/6
Q.111 The total pressure exerted by a mixture of gases is the sum of the par al pressure of all the gases present is a
statement of
A. Charle's Law B. Boyle's Law
✓ C. Dalton's Law D. Graham's Law
Q.112 Which of the following formula is correct for density of any gas
A. d = RT/PM ✓ B. d = PM/RT
C. d = MT/PR D. d = RM/PT
Q.113 An ideal gas obeying kine c gas equa on can be liquefied if
A. Its temperature is more than cri cal B. Its pressure is more than cri cal pressure
temperature
C. Its pressure is more than cri cal pressure but
temperature is less than cri cal temperature
✓ D. It cannot be liquefied at any value of P and T
Q.114 NH3 shows a maximum boiling point among the hydrides of V-A group elements due to :
A. very small size of nitrogen B. lone pair of electrons present on nitrogen
✓ C. enhanced electronega ve character of D. pyramidal structure of NH3
nitrogen
Q.115 The intramolecular forces in gases are:
A. Weak. B. Normal.
✓ C. Very weak. D. Strong.
Q.116 London forces are
A. stronger than dipole-dipole interac ons ✓ B. weaker than dipole-dipole interac ons
C. equal to dipole-dipole interac ons D. some mes stronger and some mes weaker
than dipole-dipole interac ons
Q.117 Which of the following is pseudosolid?
A. CaF2 ✓ B. Glass
C. NaCl D. All
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Q.118 At constant pressure, if the original volume is 546 cm3at which temperature the volume of gas 552 cm3
A. 1°C B. 2°C
✓ C. 3°C D. 4°C
Q.119 An instrument which is used to measure the pressure of a gas is called:
✓ A. barometer B. photometer
C. stalagmometer D. viscometer
Q.120 Hydrogen bonding is involved in
A. Solubility B. Detergents
C. Biological molecules ✓ D. All the above
Q.121 The cri cal temperature of CO2______°C at 73 atm cri cal pressure
A. 21.142 B. 28.892
✓ C. 31.142 D. 35.452
Q.122 Real gases deviate from the ideal behaviour at very
A. high pressure B. low temperature
C. low pressure ✓ D. both a and b
Q.123 Equal volume of all gases at same temperature and pressure contain number of molecules:
A. mul ples ✓ B. equal
C. different D. in frac ons
Q.124 The spreading of ink on blo ng paper is due to
✓ A. capillary ac on B. hydrogen bonding
C. intermolecular forces of the ink D. intermolecular forces of the ink and paper
Q.125 The maximum possible number of hydrogen bonds in which a H2O molecule can par cipate is:
A. 1 ✓ B. 2
C. 3 D. 4
Q.126 Which is the correct order of boiling points
A. structure of ice B. solu on of ethanol in water
✓ C. solu on o fNaCl in benzene D. linking of helix protein molecule
Q.127 A student put two eggs A and B in HCL solu on, A er five minutes he took them out for weighing but egg dropped in
water accidentally. The student was able to take it out a er 30 minutes, He weighed it, Its weight was 40.33g. Weight
of egg B was also 40.33g. Teacher told him that if both eggs have been dropped in water, the weight of egg B would
have been:
A. equal to that of egg A B. less than that of egg A
✓ C. greater than that of egg A D. unaffected instead
Q.128 Sudden expansion of gas molecule cause cooling because
A. Expansion release some amount of energy B. During expansion new force of a rac on are
developed and energy is released
✓ C. During expansion force of a rac on between D. Kine c energy of gas molecules increases
closest molecules break and energy is used
Q.129 Which if the following will have the same number of molecules at S.T.P?
✓ A. 280cm3of CO2and 280cm3of N2O B. 11.2dm3of O2and 32g of O2
3
C. 44g of CO2and 11.2dm of CO D. 28g of N2and 5.6dm3of oxygen
Q.130 covalent network of crystals has:
A. lower mel ng point than molecular crystals B. higher mel ng point than molecular crystals
✓ C. higher mel ng point than molecular crystals D. H-bonding
Q.131 Which element exists as discrete small molecules in the solids state
A. Aluminum B. Silicon
✓ C. Iodine D. Sodium
Q.132 Sugar crystals belong to the system
A. cubic ✓ B. monoclinic
C. triclinic D. orthorhombic
Q.133 Cl2is a gas while iodine is a solid due to
✓ A. stronger London forces with high B. greater electro nega vity of Cl than iodine
_______________________________________________________________________________________
polarizability C. stronger dipole dipole forces
D. iodine is colored while chlorine is colourless
Q.134 An example of ion-dipole force is solu on of
✓ A. NaCl in water B. Glucose in water
C. Bromine in benzene D. Ethanol in water
Q.135 In the forma on of NaCl crystals from its aqueous solu on, its cubic shape is changed to needle like when 10% urea is
present as impurity, this phenomenon is called as
✓ A. habit of crystal B. polymorphism
C. anisotropy D. cleavage
Q.136 Viscosity of a liquid is measured by
A. barometer B. thermometer
✓ C. viscometer D. manometer
Q.137 According to Boyle's law at constant temperature, the product of pressure and volume of a given mass of gas is:
✓ A. a constant B. frac on
C. whole number D. a mul ple
Q.138 What are the S.I. units of excluded volume "b" in Vander Waal's equa on
A. dm3mol-1 ✓ B. m3mol-1
C. mol dm-3 D. mol m-3
Q.139 Which of the following does not represent a type of crystal system
A. Triclinic B. Monoclinic
C. Rhombohedral ✓ D. Isotropical
Q.140 Which of the following gases diffuse quickly:
A. N2 ✓ B. NH3
C. CO2 D. Cl2
Q.141 Which of the following statements about amorphous solids is incorrect?
A. They melt over a range of temperature ✓ B. They are anisotropic
C. There is no orderly arrangement of par cles D. They are rigid and icompressible
Q.142 When two ice cubes are pressed together they unite to form one cube. which of the following forces is responsible for
holding them together?
✓ A. H-bonding B. Covalent bonding
C. van der waal's forces D. dipole-dipole interac on
Q.143 At constant temperature, volume of given mass of gas in inversely propor onal to pressure on it. This statement is
according to:
A. Hook's law B. Graham's law
✓ C. Bolye's law D. Charle's law
Q.144 The par al pressure of CH4and O2are 500 torr and 100 torr repec vely in a 10 dm3vessel at 0°C. The ratio of
number of molecules of CH4: O2is
A. 1: 2 ✓ B. 5:1
C. 5:2 D. 2:1
Q.145 Solids in which atoms, ions or molecules are not regularly arranged are
A. crystalline solid ✓ B. amorphous solids
C. liquid crystals D. low mel ng points
Q.146 If the four tubes of a car are filled to the same pressure with N2, O2, H2 and helium separately,then which one will be
filled first.
A. N2 B. O2
✓ C. H2 D. He
Q.147 Wt. of 112 ml of oxygen at NTP on liquifac on would be
A. 0.32 g B. 0.64 g
✓ C. 0.16 g D. 0.96 g
Q.148 What does no happen when an ideal gas is heated?
A. an increase in the average energy of the gas B. an expansion in the range of kine c energies
_______________________________________________________________________________________
par cles possessed by par cles
✓ C. an increase in the number of molecules with D. a drop in the number of molecules with lower
lower energies energies
Q.149 Which of the following laws study the pressure-volume rela onship of a gas at constant temperature,we get
A. a straight line B. a curve with different peaks
C. straight line parallel to x-axis ✓ D. a curve called isotherm
Q.150 Dipole-dipole forces and London forces are collec vely called
A. hydrogen bonding ✓ B. Vander Waals forces
C. Covalent bonding D. Ionic bonding
Q.151 The unit of R depends on
A. Mole B. Pressure volume
C. Temperature ✓ D. None of these
Q.152 Which of the following gas cannot be liquefied by Linde s method
A. H2O vapours B. N2
✓ C. H2 D. CO2
Q.153 In which of the following a re dipole-dipole interac on present?
A. molecules of CCL4 B. molecules of solid iodine
✓ C. molecules of NH3 D. atoms of the helium gas
Q.154 Triple point of water is
✓ A. 273 K B. 373 K
C. 203 K D. 193 K
Q.155 At 100 atm, CH4 develops:
A. Ideal a tude ✓ B. Non-ideal a tude
C. Serious a tude D. Laughing a tude
Q.156 Smell of cooking gas during leakage from gas cylinder is detected because of the property of:
A. Effusion B. Evapotra on
✓ C. Diffusion D. Conduc on
Q.157 In which one of the following does the central atom not possess an 'octet' in its outer shell?
✓ A. BH3 B. CH4
C. NH3 D. H 2O
Q.158 For a gas the isotherm is the graph between
A. V and T B. T and P
C. n and T ✓ D. P and V
Q.159 Which does not affect vapour pressure
A. Nature of liquid B. intermolecular forces
C. Temp ✓ D. None of these
Q.160 Which of these are isomrophous to one another NaCl, NH4Br, K2CrO4, K2SO4
A. NaCl and NH4Br both cubic B. NH4Br and K2SO4 both tetragonal
✓ C. K2CrO4 andK2SO4orthorhombic D. NaCl and K2SO4both rhobohedral
Q.161 Which of the following tends to approach ideal gas like behavior at R.T.P
A. ammonia ✓ B. neon
C. carbon dioxide D. chlorine
Q.162 NaCI is completely ionized in water due to the presence of:
A. dipole-dipole forces ✓ B. ion- dipole forces
C. H-bonding D. London dispersimforces
Q.163 Super conductors are derived from compounds of
✓ A. P-block elements B. Lanthanides
C. Ac nides D. Transi on elements
Q.164 The surface formed by the breakage of a crystal is called _____ plane
A. Crystal B. Unit
✓ C. Cleavage D. None
_______________________________________________________________________________________
Q.165 Which one the following gases is ideal at -200°C?
A. N2 B. He
C. both ✓ D. none
Q.166 Which of the following is an example of body centred cube?
A. Magnesium B. Zinc
C. Copper ✓ D. Sodium
Q.167 If V1= 5 litres, P1= 2 atm, T1= T2= 273°C and V2= in liter
A. 5 B. 80
C. 125 ✓ D. 10
Q.168 Allotropic forms of carbon are:
A. five B. three
C. four ✓ D. two
Q.169 One statement of isomorphism is incorrect
A. they have different chemical proper es ✓ B. they have same physical proper es
C. they have same atomic ra o D. they have definite geometric shape
Q.170 Which of the following solid is amorphous
A. NaCl B. diamond
✓ C. glass D. MgO
Q.171 The movement of gas molecules from a region of high pressure to vacuum is called:
A. Evapora on ✓ B. Effusion
C. Conduc on D. Diffusion
Q.172 At higher temperature isotherm moves away from y-axis because of increase in
A. Pressure B. Number of moles
✓ C. Volume D. Mass
Q.173 In NaCl cyrstal Na+ion is surrounded by how many ions of Cl-
A. 4 ✓ B. 6
C. 8 D. 10
Q.174 Absolute zero is equal to:
A. -273.15K ✓ B. -273.15oC
C. -237.15K D. -273oC
Q.175 The typical range of the H-bonding is:
A. 1-2 kj/mol of bonds ✓ B. 5-25 kj/mol of bonds
C. 5-25 kj/mol of bonds D. 500 kj/mol of bonds
Q.176 The solid par cles posses only ______ kine c energy
A. Transla onal B. Rota onal
✓ C. Vibera onal D. Circular
Q.177 The nature of l2crystals are
A. Metallic B. Covalent
C. Ionic ✓ D. Molecular
Q.178 Covalent bonds are least likely to be formed:
A. between atoms of the same element B. between atoms of different elements on the
right of the periodic table
C. by head of the group elements with high ✓ D. between an element in Group I and an
ioniza on energies element in Group Vll
Q.179 The rate of diffusion of two gases are inverselly propor onal to the square roots of their densi es or molecular
weights, is a statement of
A. Charle's Law B. Boyle's Law
✓ C. Graham's Law D. Dalton's Law
Q.180 A semiconductor of Ge can be made p-type by adding
✓ A. Trivalent impurity B. Tetravalent
C. Pentavalent impurity D. Divalent impurity
_______________________________________________________________________________________
Q.181 Molar volume of CO2 is maximum at
A. NTP B. 0°C and 2.0 atm
✓ C. 127°C and 1 atm D. 273°C and 2.0 atm
Q.182 The vapour density of a gas is 11.2.The volume occupied by 11.2 g of this gas at N.T.P is
A. 22.4 litres ✓ B. 11.2 litres
C. 1 litre D. 2.24 litres
Q.183 The amount of energy released when gaseous ions of opposite charges combine to give one mole of a crystalline ionic
compound is called
A. bond energy B. heat of forma on
✓ C. la ce energy D. ioniza on energy
Q.184 The material possessing superconduc ng proper es is
A. Yb Ba2Cu2O8 B. Hg Be2Ca2Cu2O8
✓ C. Y Ba2Cu3O7 D. Y B2Cu3O7
Q.185 Gases exert pressure on walls of container because the gas molecules:
A. Obey gas laws. B. Have definite volume.
✓ C. Collide with the walls of container. D. Collide with each other.
Q.186 A crystal system in which the unit cell has different all cell lengths but all angles equal to 90° it is called as
✓ A. orthorhombic B. triclinic
C. monoclinic D. cubic
Q.187 Water has high boiling point which is due to
A. weak dissocia on ✓ B. hydrogen bonding
C. high specific heat D. high dielectric constant
Q.188 A gas is heated in such a way that its volume and absolute temperature both are doubled. the pressure of gas:
A. Becomes 4 me B. Becomes half
C. Becomes 2 me ✓ D. Remains same
Q.189 Cri cal temperature of argon's gas is low. the reason is that
A. it contains four lone pairs B. it is mono atomic gas
C. it has as smell signed ✓ D. its polarizability is low
Q.190 Choose the example having hexagonal system:
✓ A. graphite B. sugar
C. sulphur D. diamond
Q.191 Pressure remaining constant at which temperature the volume of a gas will become twince of what it is at 0∘C.
A. 546∘C B. 200∘C
✓ C. 546K D. 273K
Q.192 The instrument that is used to measure the pressure of a gas is called
A. viscometer B. photometer
✓ C. barometer D. stalagmometer
Q.193 H2O is liquid at room temperature whereas H2S is a gas because
O used as drinking water, S has ro en egg B. H2O is neutral. H2S is a weak acid
A. H2 2
but H smell
✓ C. stronger hydrogen bonding in O than in
2 2S
H H
D. H2O occurs abundantly than H2S
Q.194 In a crystal a ≠ b ≠ c,a = y 90° and β ≠ 90° it is
✓ A. Monoclinic B. Rhombic
C. Trigonal D. Tetragonal
Q.195 Which of the following is not a correct postulate of the kine c theory of gases
A. the gas molecules are in random mo on ✓ B. the collision between the molecules are
perfectly elas c
C. the average kine c energies of different gases D. the pressure exerted on the walls of the
are equal at a par cular temperature container is due to intermolecular forces
Q.196 Air at sea level is dense.This is a prac cal applica on of
✓ A. Boyle's law B. Charle's law
_______________________________________________________________________________________
C. Avogadro's law D. Dalton's law

Q.197 Plasma was introduced by
✓ A. Crookes B. Soddy
C. Faraday D. Van der Waal
Q.198 Gases are good conductor of electricity at
A. Low temperature ✓ B. Low pressure
C. High pressure D. Low temperature and high pressure
Q.199 The phenomenon in which sudden expansion of a gas causes cooling is called
A. evapora on B. cooling
✓ C. Joule Thomson effect D. sublima on
Q.200 Which one of the following statements about diamond is not true?
A. the coordina on number of carbon atoms is 4 ✓ B. diamond is an isotpe of graphite
C. diamond has a high mel ng point D. diamond has a rigid tetrahedral, structure
Q.201 An ideal gas cannot be liquefied because:
A. It solidify before becoming a liquid B.Its cri cal temperature is always above 0oC
C. It is molecule are rela vely smaller in size. ✓ D.Forces opera ve between its molecules are
negligible
Q.202 The highest temperature at which a substance can exist as a liquid is called its:
✓ A. Cri cal temperature B. Zero temperature
C. Absolute temperature D. None of above
Q.203 Areal gas obeying Van der Waal's equa on will resemble ideal gas ilf the:
A. both a and b are large ✓ B. both a and b are small
C. a is small and b is large D. a is large and b is small
Q.204 Which of the following has isomorphous structure
✓ A. NaF B. S
C. Sn D. N
Q.205 According to Boyles law, at constant temperature the product of pressure and volume of a given mass of gas is
A. whole number ✓ B. a constant
C. frac on D. a mul ple
Q.206 Which volume of gas has minimum value
A. Apparent volume ✓ B. Actual volume
C. Excluded volume D. All have equal value
Q.207 Under which condi ons real gases deviate from ideal behaviour
A. Low temperature and low pressure ✓ B. Low temperature and high pressure
C. High temperature and high pressure D. High temperature and low pressure
Q.208 The volume of a gas that is occupied by its one mole at S.T.P. is known as:
A. atomic volume B. molar volume
✓ C. normal volume D. total volume
Q.209 The number of atoms in 0.004 g of magnesium is close to
A. 24 B. 2 x 1020
✓ C. 10 20
D. 6.02 x 1023
Q.210 If the number of gas molecules are doubled in the certain volume the pressure is:
A. Increased to four mes B. Remains unchanged
✓ C. Doubeld D. Decrease to half
Q.211 The devia on of a real gas from ideal behaviour is maximum at
✓ A. -10.0°C and 50 atm B. -10°C and 2 atm
C. 100°C and 2.0 atm D. 0°C and 2 atm
Q.212 The density of a gas is 1.964 g dm-3 at 273K and 76 cm Hg The gas is
A. CH4 ✓ B. CO2
C. C 2H 4 D. Xe
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Q.213 Which forms metallic cyrstals
✓ A. Cu B. NaCl
C. Diamond D. None
Q.214 At same temperature which substance has high kine c energy:
A. Liquid water ✓ B. N2gas in a container
C. Solid piece of iron D. Solu on of alcohol and water
Q.215 The molecules of air don't se le down. This is due to:
A. non-polar nature of gases B. different molar mass
✓ C. elas c collisions of gas molecules D. pressure of dust par cles in air
Q.216 Meniscus is the shape of the surface of a liquid in a cylindrical container:
✓ A. meniscus may be convex B. meniscus is concave
C. meniscus may be convex or concave D. meniscus is plane
depending upon the nature of metal
Q.217 Which one of the following molecules show maximum hydrogen bonding?
✓ A. H 2O B. H2Se
C. H 2S D. HF
Q.218 If 250 cm3of hydrogen gas is cooled from 127°C to -73°C at constant pressure then new volume of gas is ______ dm3
A. 0.25 B. 0.375
✓ C. 0.125 D. 0.0625
Q.219 Mercury does not wet the glass because of
A. repulsion ✓ B. weak cohesive force
C. high viscosity D. capillary ac on
Q.220 The total K.E. of one mole of an ideal gas is given by:
A. 1/2 RT B. 3/2 RT
C. 1/2 KT ✓ D. 3/2 KT
Q.221 Boiling point of water is higher (100°C) than that of ethanol (78.5°C) although both have hydrogen bonding.
This is because
A. water molecules are closely packed B. water is more acidic than ethanol
C. ethanol is an organic liquid ✓ D. number of hydrogen bonds are more in H2O
Q.222 Equal masses of CH4and O2are mixed in a 10 dm3container at 25°C. The partial pressures of CH4and O2are in
the ratio of
A. 1:2 ✓ B. 2:1
C. 1:1 D. 2:3
Q.223 Cri cal temperature for a gas depends upon
A. Shape of molecule B. Size of molecules
C. Inter molecular forces ✓ D. All of these
Q.224 According to the kine c theory of gases,in an ideal gas,between two successive collisions a gas molecule travels
A. Ina circular path B. In a wavy path
✓ C. In a straight line path D. With an accelerated velocity
Q.225 Which of the following successive ioniza on energies belong to a Group ll element?
A. 320,600,1110,1700,5650, ✓ B. 577,1820,2740,1160,14800,
C. 428,3070,4600,5860,7990 D. 736,1451,7740,10500,13600
Q.226 At ordinary temperature, the most nearly ideal gases are
A. N2 B. He
C. H2 ✓ D. all these
Q.227 Value of gas constant R is
✓ A. 8.314 J K-1mol-1 B. 0.082 J K-1mol-1
-1 -1
C. 273.15 J K mol D. 101325 J K-1mol-1
Q.228 In which of the following processes the liquids are made to boil at low temperature
✓ A. Vacuum dis lla on B. Destruc ve dis lla on
C. Dis lla on D. Vacuum destruc ve dis lla on
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Q.229 According to kine c theory of gases there are
A. Intermolecular a rac ons B. Molecules which have considerable volume
✓ C. No intermolecular forces of a rac on D. The velocity of molecules decreases for each
collision.
Q.230 The compound that has zero dipole moment is
A. HCl B. H 2S
C. NH3 ✓ D. CH4
Q.231 In intense electrical field and at a very high temperature ma er generally exist in
A. Solid state ✓ B. Plasma state
C. Liquid state D. Gaseous state
Q.232 Choose the gas law which gives rela onship between volume and pressure:
✓ A. Bolye,s law B. Graham,s law
C. Dalton,s law D. Charles,s law
Q.233 The non polar gases of low polarizability have a very:
✓ A. Low cri cal temperature B. Stable cri cal temperature
C. High cri cal temperature
Q.234 If absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume of the gas will:
✓ A. reduced to 1/4 B. be double
C. increases four mes D. remains unchanged
Q.235 Which of the following gases have maximum root mean square velocity at 25°C:
A. SO2 ✓ B. NH3
C. CO2 D. H 2S
Q.236 To measure the true pressure of a gas collected over water, the pressure due to water vapoure is:
A. added to the total pressure B. mul plied to the total pressure
C. divided by the total pressure ✓ D. subtracted form the total pressure
Q.237 Choose the correct equa on among the following given by clauslus to understand to behaviour of molecules:
A. PV =nRT B. Cr.m.s= √3RT/M
C. d = PM/RT ✓ D. PV = 1/3mnc-2
Q.238 The a rac ve forces between molecules of a gas and their sizes can be ignored at
A. high pressure B. low temperature
C. low temperature and high pressure ✓ D. low pressure and high temperature
Q.239 Which of the following metal oxides is an ferromane c in nature?
✓ A. MnO2 B. TiO2
C. NO2 D. CrO2
Q.240 London dispersion forces are also called
A. Ion-dipole forces B. Dipole-induced dipole forces
C. Dipole-dipole forces ✓ D. Instantaneous dipole induced dipole forces
Q.241 The strength of dipole-dipole forces depends upon
A. Electro nega vity difference B. Distance between atoms
C. Electroposi vity difference ✓ D. Both A & B
Q.242 In van der Waal's equa on of state of the gas law,the constant 'b' is measure of
A. Intermolecular repulsions B. Intermolecular collisions per unit volume
✓ C. Volume occupied by the molecules D. Intermolecular a rac on
Q.243 A mixture of H2, H2 and CH4has total number of 0.51 mole and total pressure of 1 atmosphere. If the mass of H2is 0.8
gram, then its par al pressure is
A. 0.4 atm B. 0.6 atm
✓ C. 0.776 atm D. 0.667 atm
Q.244 Which one is not postulated in the kinetci molecular theory among the following?
A. molecules are in chao c mo on ✓ B. molecules of all the gases have same size and
same mass
C. the volume of the molecules is negligible D. all molecular collisions are elas c
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Q.245 Crystal la ce with alternate +ve and -ve ions has radius ra o of 0.524.Its coordina on number is
A. 4 B. 3
✓ C. 6 D. 12
Q.246 choose the temperature among the following at which real gas obeys ideal gas laws when pressure range is
appreciable:
A. cri cal temperature ✓ B. boyle's temperature
C. inversion temperature D. transi on temperature
Q.247 Which of the following contains maximum of number of molecules?
A. 100 cc of CO2at STP B. 150 cc of N2at STP
C. 50 cc of SO2at STP ✓ D. 200 cc of NH3at STP
Q.248 Which gas molecules escape through a hole of molecular dimension this phenomenon is called
A. diffusion B. mixing
✓ C. effusion D. flowing of gas
Q.249 All of the following have cleavage planes except:
A. molecular crystals ✓ B. metallic crystals
C. covanent crystals D. ionic crystals
Q.250 Liquids are less common than solids and gases because
✓ A. They exist in narrow range of temperature B. They have definite volume
and pressure
C. Liquid molecules can slide past each other
D. Molecules contain three type of mo on
Q.251 How many kinds of space la ces are possible in a crystal?
A. 23 B. 7
C. 230 ✓ D. 14
Q.252 Units of van der Waals constant a is
✓ A. atm dm6/mol2& Nm4/mol2 B. atm dm4/mol2 & Nm4/mol2
C. atm dm4/mol2 & Nm6/mol2 D. None of these
Q.253 The compressibility factor of an ideal gas is
A. 0 ✓ B. 1
C. 2 D. 4
Q.254 Real gases deviate at low temperature from ideal behaviour due to
A. there is transi onal mo on of molecule B. the collissions between the molecules are
decreased
C. volume of gas is decreased ✓ D. the inter molecular a rac ve forces become
significant
Q.255 Deep sea divers take oxygen with:
A. A heavy gas B. A lighter gas
✓ C. An inert gas D. All of above
Q.256 Someone is saying that glass must be a super cooled liquid. The reason that he might have in his mind is that glass has
:
A. definite shape B. definite-volume
C. crystalline structure ✓ D. no crystalline structure
Q.257 What is the weight of 10 litres of CO2at 27°C and 2 atm?
A. 89.3 g ✓ B. 36.1 g
C. 125 g D. 127 g
Q.258 What water freezes at 0∘ , Its density decreases dues to:
A. cubic structure of ice ✓ B. empty spaces present in the structure
C. change of bond lengths D. change of bond angles
Q.259 Rise in vapour pressure of water from 30 to 60°C is only 32 torr to 149.4 torr (117.4 torr) but from 60 to 90°C is
149.4 to 527.8 torr (378.4 torr).it is due to
A. change in O molecules at higher B. decrease in volume takes place at higher
2
geometry of H temperature temperature
✓ C. vapour pressure of liquids increases rapidly D. boiling starts
closer to their boiling points
_______________________________________________________________________________________
Q.260 Which of the following statement is not true?
A. The pressure of a gas is due to collision of the B. The molecular velocity of any gas is
gas molecules with the walls of the container. propor onal to the square root of the
absolute temperature.
✓ C. The rate of diffusion of a gas is directly D. Kine c energy of an ideal gas is directly
propor onal to the density of the gas at propor onal to the absolute temperature.
constant pressure.
Q.261 Which element is expected to show the greatest tendency to form some covalent compounds?
✓ A. aluminium B. calcium
C. magnesium D. sodium
Q.262 Which of the following is the unit for pressure of a gas in system interna onal
✓ A. Nm-2 B. mm of Hg
C. atmosphere D. torrr
Q.263 Volume of O2gas at 0°C is 273 cm3, then volume of O2gas at -10°C is
✓ A. 263 cm3 B. 163 cm3
C. 173 cm3 D. 73 cm3
Q.264 Which forms metallic crystals
✓ A. Cu B. NaCI
C. SO2 D. NH4CI
Q.265 Which of the following is a non-crystalline solids pair
A. Diamond, wood B. Glass, table salt
✓ C. Wood, glass D. Sucrose, glass
Q.266 The rate of diffusion of a gas of molar mass 72 as compared to H2will be:
A. Same ✓ B. 6 mes
C. 1.4 mes D. 1/6 mes
Q.267 The ra o of diffusion of equal volume of He and SO2is (molecular mass He = 4, SO2 = 64):
A. 1:4 B. 16:1
C. 1:16 ✓ D. 4:1
Q.268 One Pascal is equal to
✓ A. 1 Nm-2 B. 1 Nm
-1
C. 1 Nm D. 1 Nm2
Q.269 The kine c theory of gases predicts that total kine c energy of a gaseous assembly depends on
A. Pressure of the gas ✓ B. Temperature of the gas
C. Volume of the gas D. Pressure,temperature,and volume of the gas.
Q.270 Which pare of gases do not obey Dalton's law of par al pressures?
A. H2and He ✓ B. NH3and HCl
C. H2and O2 D. N2and O2
Q.271 The densi es of two gases are in the ra o of 1 : 16.The ra on of their rates of diffusion is
A. 16 : 1 ✓ B. 4:1
C. 1:4 D. 1 : 16
Q.272 There is more devia on in the behaviour of a gas from the ideal gas equa on PV = nRT
A. At high temperature and low pressure ✓ B. At low temperature and high pressure
C. At high temperature and high pressure D. At low temperature and low pressure
Q.273 If v is the volume of one molecule of a gas under given condi ons, then Van der Waals constant b is (NAis Avogadro
number)
A. B.
✓
C. D.
Q.274 The value of cri cal temperature of a gas depends upon its:
A. Size B. Intermolecular forces in it
C. Shape ✓ D. All of above
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Q.275 Which is trigonal crystal
A. CaSO4. 2H2O B. MgSO4
✓ C. NaNO3 D. All
Q.276 The volume of a gas that is occupied by its one mole at STP is called
A. total volume B. normal volume
✓ C. molar volume D. atomic volume
Q.277 The maximum possible number of hydrogen bonds in which a H2O molecule can par cipate is
A. 1 ✓ B. 2
C. 3 D. 4
Q.278 In which system hydrogen bonding is not present
A. solu on of ethanol in water B. linking of helix in protein molecule
C. structure of ice ✓ D. solu on of NaCl in benzene
Q.279 The beaker contains slurry of ice and water, the three thermometers Fahrenheit, Kelvin and cen grade placed init. the
thermometers are represented as A, B and C respec vely, On which thermometer the lowest reading will be?
A. B B. A
✓ C. C D. both A and B
Q.280 Which of the following least resemble an ideal gas?
✓ A. ammonia B. helium
C. hydrogen D. trichloromethane
Q.281 Which is the incorrect value of gas constant R?
A. 2.987 cal k-1mol-1 B. 3.313 Nmk-1mol-1
✓ C. 62400dm3 atm k-1mol-1 D. 1.10821atm dm3k-1mol-1
Q.282 The system in which two out of three axes are of equal length and angles are all 90°
A. cubic system B. hexagonal system
C. trigonal system ✓ D. tetragonal system
Q.283 According to kine c molecular theory, kine c energy of molecules increases when they are:
✓ A. melted from solid to liquid state B. frozen into a solid
C. condensed into liquid D. mixed with other molecular at low
temperature
Q.284 Ar has low cri cal temperature and pressure due to its
A. small size B. monatomic molecule
✓ C. low polarizability D. liquefac on temperature close to room
temperature
Q.285 The temperature below which a gas does not exist is called its
A. Inversion temperature ✓ B. Cri cal temperature
C. Neutral temperature D. Curie point
Q.286 In graphite crystal, carbon is
A. sp hybridized ✓ B. sp2hybridized
C. sp3hybridized D. None
Q.287 The forces present between the ions and water molecules are called:
A. dipole-dipole forces B. dipole-induced dipole forces
C. London dispersion forces ✓ D. ion-dipole forces
Q.288 The gas which obey's the gas laws at all condi ons of temperature and pressure is called:
A. Perfect gas B. Super gas
✓ C. Ideal gas D. Real gas
Q.289 chemist was able to measure the value of la ce energy of KCI to be 690 kj/mol.
From this experiment , he concluded that:
✓ A. la ce energy of KBr is 665 kj/mol and that of B. la ce energy of KBr is 765 kj/mol and that of
Ki is 630 kj/mol Kl 730 kj/mol
C. la ce energy of KBr is 730 kj/mol and that of D. la ce energy of KBr is 630 kj/mol and that of
Ki 765 kj/mol kL 665 KJ/mol
Q.290 Which one of the following equa ons represents the 1st ioniza on energy of Na?
A. Na(s) ---->Na+ (g) + e- ✓ B. Na(g) --->Na+(g) + e-
_______________________________________________________________________________________
C. Na(s) --->Na+(s) + e- D. Na (s) + e----> Na+(g)
Q.291 Which one of the following pair of atoms is most likely to form an inoic bond?
✓ A. Na and F B. C and F
C. N and F D. O and F
Q.292 At different temperature, the vapour pressure of water is
✓ A. different B. same
C. low D. high
Q.293 What is dis lled first?
A. Liquid CO2 B. Liquid N2
C. Liquid O2 ✓ D. Liquid H2
Q.294 Which of the following is exact rela onship between °F and C°
A. °F= 5/9[°C-32] B. °C = 5/9 [°F]+32
✓ C. °F = 9/5°C+32 D. All
Q.295 The ques on vapour cause by hea ng a liquid is due to:
A. increase of intermolecular interac ons ✓ B. increase of K.E of molecules
C. decrease of surface tension D. increase in poten al energy of molecules
Q.296 An example of ion-dipole force is the solu on of:
A. bromine inbenzene B. ethanol is water
✓ C. NaCl in water D. glucose in water
Q.297 What is the pressure of 2 mole of NH3 at 27°C when its volume is 5 lit.in Van der Waals equa on?(a = 0,17,b = 0.03711)
A. 10.33 atm ✓ B. 9.333 atm
C. 9.74 atm D. 9.2 atm
Q.298 The temperature at which volume of ideal gas is hypothe cally zero is called
A. Absolute zero B. 0°C
C. OK ✓ D. Both a and c
Q.299 When water freezes at 0°C, its density decreases due to
A. cubic structure of ice ✓ B. empty spaces present in the structure of ice
C. change of bond lengths D. change of bond angles
Q.300 Which one of the following is not a form of chemical bonding?
A. covalent bonding ✓ B. hydrogen bonding
C. ionic bonding D. metallic bonding
Q.301 Which of the following is not a postulate of the kine c theory of gases?
✓ A. when gas par cles collide, their total kine c B. gases consist of molecules in a constant state
energy increases of random mo on
C. when gas par cles collide their total kine c D. The gas par cles travel in straight lines unit
energy does not change at all they collide with one another or with the
walls of the container
Q.302 All of following acids have hydrogen bond in liquid state except:
A. nitric acid B. sulphuric acid
✓ C. hydrochloric acid D. hydrofluoric acid
Q.303 General gas equa on is combina on of
A. Boyle s law B. Avogadro s law
C. Charles s law ✓ D. All of these
Q.304 Gases of air, always remain in random mo on and do not se le due to:
A. Difference of molecules masses of air gases. B. Difference in par al pressure of gas
molecules.
C. Unequal number of different gas molecules. ✓ D. Elas c collision of gas molecules.
Q.305 The volume of 2.8 g of carbon monoxide at 27°C and 0.821 atm pressure is (R = 0.0821 lit.atm.Mol-1 K-1)
A. 30 L ✓ B. 3L
C. 0.3 L D. 1.5 L
Q.306 Which liquid is more vola le?
A. water B. mercury
_______________________________________________________________________________________
✓ C. benzene D. honey
Q.307 If a = b = c and x = y = z 90° then crystal structure is
✓ A. Cubic B. Tetragonal
C. Orthorhombic D. Triclinic
Q.308 Which of the following govern the diffusion of gases
A. Dalton's law B. Avogadro's law
✓ C. Graham's law D. Newton's law
Q.309 Oxygen molecule is 16 mes heavier than:
A. Helium ✓ B. Hydrogen
C. Neon D. Aluminium
Q.310 The rate diffusion of H2is 4 mes than the of an unknown gas at same temperature and pressure, the molecular mass
of unknown gas is
✓ A. 32 B. 16
C. 4 D. 64
Q.311 The major binding force of diamond,silicon and quartz is
A. Electosta c force B. Elec cal a rac on
✓ C. Ceobalent bond force D. Non convalent bond force
Q.312 Equal volume of all gases at same temperature and pressure contain number of molecules
A. different B. mul ples
✓ C. equal D. in frac ons
Q.313 Boyle's law does not fall even:
A. Temperature is extremely high. B. Pressure is extremely high.
✓ C. Mixture of gases is taken. D. All of above.
Q.314 NH3shows a maximum boiling point among the hydrides of Vth group elements due to
A. very small size of nitrogen ✓ B. hydrogen bonding between its molecules
C. enhanced electronega ve character of D. pyramidal structure of NH3
nitrogen
Q.315 There are three different substances argon hydroiodic acid and hydroiodic acid.
the correct sequence in which the boiling point increases is:
A. HI > Ar > HCI ✓ B. Ar < HCI < HI
C. HI > HCI > Ar D. HCI < HI < Ar
Q.316 The devia on of a gas from ideal behavior is maximum at:
✓ A. -10∘C and 5.0 atm B. -10∘C and 2.0 atm
C. 100∘C and 2.0 atm D. 0∘C and 2.0 atm
Q.317 If absolute temperature of a gas is doubled and pressure is reduced to one half, then the volume of the gas will
A. remains unchanged B. increases unchanged
C. reduces to 1/4 ✓ D. increases 4 mes
Q.318 Absolute temperature of a gas is propor onal to:
A. Rota onal Kine c energy ✓ B. Transla onal Kine c energy
C. Vibra onal Kine c energy D. Poten al energy
Q.319 Compressibility factor for an ideal gas is
A. 1.5 ✓ B. 1.0
C. 2.0 D. 0.5
Q.320 The par cles in solids are
A. widely separated and moving randomly B. widely separated not moving
C. moving randomly but not separated ✓ D. close together and vibra ng slightly
Q.321 When the temperature is raised, the viscosity of the liquid decreases.This is because of
A. Decreased volume of the solu on ✓ B. Increase in temperature increases the
average kine c energy of molecules which
overcome the a rac ve force between them
C. Decreased covalent and hydrogen bond forces D. Increased a rac on between the moelcules
Q.322 Which of the following liquid has higher boiling point?
_______________________________________________________________________________________
A. HCl B. HBr
✓ C. H 2O D. Br2
Q.323 Which of the following is not the applica on of plasma
A. Fluorescent light bulb B. Removal of hazardous chemical
C. Neon signs ✓ D. Corrosion effec ve
Q.324 CO2gas is dissolved in water due
A. dipole-dipole interac ons B. higher molecular mass of CO2
C. ion dipole a rac ve forces ✓ D. hydrogen bonding
Q.325 According to charles law there will be a change in the volume of a given mass of a gas by 1/273 of its original volume
at 0°C if the temperature of the gas is changed by
A. 10° ✓ B. 1°C
C. 100°C D. 2°C
Q.326 which chlorine compound has bonding that can be described as ionic with some convalent character?
A. NaCI ✓ B. MgCI2
C. AICI3 D. SiCI4
Q.327 The amount of heat required to convert one mole of solid into liquid is called
✓ A. molar heat of fusion B. heat of fusion
C. heat of vaporiza on D. heat of liquefac on
Q.328 For gases obeying Boyle's law, if pressure is quadrupled, the volume becomes
A. Double B. One half
✓ C. One fourth D. Remains constant
Q.329 In Boyle's law which of the following pair is variable:
A. Temperature and quan ty of a gas. ✓ B. Pressure and volume.
C. Volume and quan ty of a gas. D. Pressure and quan ty of a gas.
Q.330 Amorphous solids:
A. have sharp mel ng point B. undergo clean cleavage when cut with knife
C. have prefect arrangement of atoms ✓ D. can possesses small regions of orderly
arrangement
Q.331 Acetone and chloroform are soluble in each other due to:
✓ A. intermolecular hydrogen bonding B. dipole-dipole interac on
C. instantaneous dipoles D. all of the above
Q.332 Which one of the following is not true of metallic bonding?
A. it gives rise to excellent electrical conduc vity B. electrons are following to move throughout
the structure
✓ C. the strength of metallic bonds increases D. the strength of metallic bonding affects the
down a group boiling point of metals
Q.333 In which of the following molecules, strongest H-bond is shown?
✓ A. hydrogen fluoride B. water
C. hydrogen sulphide D. ammonia
Q.334 At higher temperature isotherm moves away from both the axes because of increase in
A. Pressure ✓ B. Volume
C. Number of moles D. All
Q.335 Covalent solids are composed of
A. Ions B. Different molecules
✓ C. Neutral atoms D. Diethyl ether
Q.336 In gasses and liquid, temperature is the measure of:
✓ A. Average transna onal kine c energies of B. Average vibra onal kine c energies of
molecules. molecules.
C. Average rota onal kine c energies of D. None of above.
molecules.
Q.337 What will be the ra o of volume of equal masses of O2, H2and CH4kept in same container under same condi ons
A. 2 : 16 : 2 ✓ B. 1 : 16 : 2
C. 2 : 16 : 1 D. 1:2:1
_______________________________________________________________________________________
Q.338 The value of general gas constant R is derived from:
A. Newton's Cooling law B. Maxwell's law
✓ C. Avogadro's law D. Charle's law
Q.339 Which of the following element will have strongest van der Waal force of a rac on between its molecules?
A. nitrogen B. hydrogen
C. oxygen ✓ D. chlorine
Q.340 Total pressure of mixture of two gases is:
A. The ra o of their par al pressure B. The product of their par al pressure
C. The difference par al pressure ✓ D. The sum of their par al pressure
Q.341 Which of the following liquids have low vapour pressure at 25°C
✓ A. Water B. Ethyl alcohol
C. Acetone D. Diethyl ether
Q.342 Gases deviate from ideal behaviour at high pressure.Which of the following is correct for non-ideality?
A. at high pressure the gas molecules move in B. at high pressure the collisions between the
one direc on only gas molecules are increased manifold
C. a high pressure the volume of the gas become ✓ D. at high pressure, the intermolecular
insignificant a rac on becomes significant
Q.343 3
How many balloons of 0.25 dm capacity at I atmospheric pressure can be filled from a hydrogen gas cylinder of 5
dm3capacity at 10 atmospheric pressure
A. 50 B. 90
C. 180 ✓ D. 200
Q.344 Which is the following would have most like an ideal gas at room temperature?
A. carbon dioxide ✓ B. helium
C. hydrogen D. nitrogen
Q.345 If pressure is increased from a 2 atm to 4 atm on a gas then its volume will decrease from:
A. 3L to 1L ✓ B. 4L to 2L
C. 6L to 4L D. 8L to 2L
Q.346 NH3 shows maximum boiling among the hydrides of group V elements. The is due to:
A. pyramidal structure of NH3 ✓ B. H-bonding between its molecules
C. enhanced electronega ve character D. very small size of nitrogen
Q.347 Which of the following statement about graphite is not true?
✓ A. The coordina on number of carbon atoms is B. the carbon atoms are arranged layers.
4. C. the layers in graphite are a racted to each
other weak forces.
D. the corbon atoms use only three of their four
outer electrons for covalent bonding.
Q.348 Ethene C2H4and N2gases diffuse at the same rate at room temperature. it is due to the reason
A. these are non polar gases ✓ B. their molecular masses are same
C. both are covalent molecules D. both have mul ple bonds
Q.349 Which of the following statement is correct if the intermolecular forces in liquids A,B and C are in the order A < B < C?
A. B evaporates more readily than A B. B evaporates less readily than C
C. A and B evaporates at the same rate ✓ D. A evaporates more readily than C
Q.350 The total number of la ce arrangements in different crystal system is
✓ A. 7.0 B. 3.0
C. 8.0 D. 14
Q.351
✓
A. B.
C. D.
Q.352 This is known fact that the molar volumes of different gases at S.T.P. are
_______________________________________________________________________________________
✓ A. much larger than the molar volumes of B. li le bit less than the molar volumes of solids
liquids and solids C. about the same as the molar volumes of
liquids
D. li le bit greeter than the molar volumes of
liquids
Q.353 Under what condi ons do real gases show close to ideal gas behavior?
A. low pressure, low temperature B. high pressure, low temperature
✓ C. low pressure, high temperature D. high pressure, high temperature
Q.354 Boiling point of water remains 100°C although heat is continuous supplied. it is because
A. decomposi on of water takes place B. hydrogen bonding is increased
C. external atmospheric pressure is not changing ✓ D. kine c energy of H2O molecules is increasing
Q.355 By increasing pressure two mes and decreasing temp. two mes the volume of gas
A. Volume increases 4 mes ✓ B. Volume decreases 4 mes
C. Volume increases 2 mes D. Volume decreases 2 mes
Q.356 The gases law describe the ______ Behaviour of gases
A. Variable B. Constant
✓ C. Uniform D. Best
Q.357 The law of distribu on of energy is given by
A. Clausius B. Maxwell
C. Bernoulli ✓ D. Boltzmann
Q.358 If the distance between Na+ and CI- ions in sodium chloride crystal is X pm,the length of the edge of the unit cell is
A. 4X om B. X/4 pm
C. X/2 pm ✓ D. 2X pm
Q.359 In metallic crystals the atomic orbitals combine to produce a large number of closely bands of energy according to
A. electron pool theory ✓ B. molecular orbital theory
C. valence bond theory D. electrosta c force of a rac on
Q.360 what is it difficult to cook food at high as compared to at sea level? Choose the correct reason.
A. H-bonding in H2O changes with height B.
temperature at the top of mountain is low
C. density of water decreases at the mountain ✓ D.
boiling point of water decreases at the
mountain
Q.361 The forces of a rac on between ions and water molecules are known as
A. dipole-dipole forces B. London forces
C. dipole- induced dipole forces ✓ D. ion-dipole forces
Q.362 coordina on number of Na+ in NaC is:
A. 1 B. 2
C. 4 ✓ D. 6
Q.363 At constant temperature when pressure of a gas is plo ed against volume, the cure is:
A. Slan ng straight line. ✓ B. Parabolic.
C. Straight line, parallel to pressure axis. D. Of neither type.
Q.364 In the equa on PV = nRT which one cannot be numerically equal to R
A. 8.31 x 107erg7K-1mol-1 B. 8.31 x 107dynes Cm K-1mol-1
C. 8.31 JK-1mol-1 ✓ D. 8.31 L atm K-1mol-1
Q.365 The original volume of a gas at 0° is 273 cm3at constant pressure, its volume at 273°C becomes
A. zero cm3 ✓ B. 546 cm3
3
C. 446 cm D. 346 cm3
Q.366 All the following statements are incorrect except:
A. all of the gases cannot be liquefied B. increase of pressure will not decrease the
inter molecular distance in a gas
✓ C. gas molecules do not a ract each other at D. actual volume of a gas is not negligible at very
very low temperature pressure
Q.367 When a compressed gas is allowed to pass through a nozzle of a jet into a region of low pressure, it produces
✓ A. cooling B. vaporiza on
C. fusion D. expansion
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Q.368 Which one of the following will behave least like an ideal gas at high temperature and low pressure?
✓ A. hydrogen fluoride B. helium
C. oxygen D. carbon dioxide
Q.369 Stronger the intermolecular forces
✓ A. Lower the Vapour pressure B. Greater the Vapour pressure
C. May be smaller or greater D. None
Q.370 A graph between P and PV constant temperature and number of moles is parallel to:
A. Y-axis B. X-axis
C. Z-axis ✓ D. Pressure axis
Q.371 In a cubic la ce a unit cell is shard equally by how many unit cells?
A. 4 B. 2
✓ C. 6 D. 8
Q.372 Which ion is most polarising?
✓ A. AI3+ B. Ba2+
C. Mg2+ D. Na+
Q.373 In order to men on boiling point of water at 110∘C the external pressure should be:-
✓ A. between 760 torar an 1200 torr B. between 200 torr and 760 torr
C. 765 torr D. any value of preessure
Q.374 Lonic solids are characterized by:
A. low mel ng points B. good conduc vety in solid state
C. high vapour pressures ✓ D. solubility in polar solvents

Q.375 Diamond and silicon carbide are insoluble in all solvents because
A. they have high mel ng and boiling points B. absence of three electrons
✓ C. they are huge giant three dimensional D. their unit cells have tetrahedral geometry
molecules (macromolecules)
Q.376 The ra o of most probable velocity to that of average velocity is
A. π/2 B. 2/π
✓ C. √π/2
Q.377 The rela ve rate of diffusion of a gas (molecular weight = 128) as compared to oxygen is
A. 2 mes B. 1/4
C. 1/8 ✓ D. 1/2
Q.378 London dispersion forces are the only force present among the:
A. molecules of water in liquid state B. atoms of helium in gaseous state at high
temperature
✓ C. molecules of solid iodine D. molecules of hydrogen chloride gas
Q.379 The structure normally associated with ionic bonding is:
✓ A. a giant la ce B. a simple molecule
C. a giant molecule D. a regular arrangement of ions surrounded by
a sea , or cloud, of electrons
Q.380 The boiling point of Kr is higher (-152.23°C) than that of helium (-268.6°C) due to
A. Kr forms greater number of covalent bonds ✓ B. greater polarizability of Kr than He
C. Kr has lowest freezing point D. Kr is in liquid state at ordinary temperature
Q.381 Amorphous substance show
(i) Short and long range order
(ii) Short range order
(iii) Long range order
(iv) Have no sharp mel ng point
A. (i) and (ii) are correct ✓ B. (ii) and (iv) are correct
C. (ii) (iii) and (iv) are correct D. (i) and (iv) are correct
Q.382 La ce energy is also termed as
A. ioniza on ✓ B. crystal energy
C. dissocia on D. bond energy
_______________________________________________________________________________________
Q.383 For the purpose of interacts which one of the following arrangements represents the correct of increasing stability?
A. covalent < hydrogen bonding < London forces B. London forces < hydrogen bonding < dipole-
< dipole-dipole dipole < covalent
✓ C. London forces < dipole-dipole < hydrogen D. Dipole-dipole < London forces < hydrogen
bonding < covalent bonding < covalent
Q.384 Which value is designated as absolute zero or zero of the Kelvin scale?
✓ A. -273.15°C B. -173.15°C
C. 273°C D. none of these
Q.385 The kine c energy of three moles of gas is:
A. 3/2 RT B. 3 RT
✓ C. 1/2 RT D. 2 RT
Q.386 In which of the following compounds hydrogen bonding is not present
A. water B. ethanol
✓ C. ether D. ammonia
Q.387 If allowed to expand, the gases suddenly
A. heat up B. move randomly
C. react ✓ D. cool down
Q.388 It is very much difficult to cook food at Mount Everest, because
A. temperature of atmosphere is very low ✓ B. the boiling point of water is 69°C
C. water becomes heavier D. the boiling point of water is increased
Q.389 London forces are more affec ve at
A. low temperature B. high temperature
C. low pressure ✓ D. low temperature and high pressure
Q.390 H2and O2are enclosed in porous vessel. The effusion of these gases will take place like
✓ A. H2effuses 4 mes the rate of effusion of O2 B. O2effuses into air 4 mes the effusion of H2
C. both effuse at same rate D. H2effuses at 8 mes the rate of effusion of O2
Q.391 Vapour pressure of a liquid
✓ A. increasing with increase of temperature B. increases with decrease of temperature
C. increases with size of container D. increases with volume of liquid
Q.392 The process of effusion is best understood by law
✓ A. Grahams B. Boyle s
C. Charles s D. Avogadro s
Q.393 A pressure of 1Nm-2 is equal to:
A. one bar ✓ B. one pascal
C. stalagmometer D. one aomosphere
Q.394 Which state about gases is not correct?
A. They spread throughout the vessel. B. Pressure is due to collision.
C. There are larger spaces between the ✓ D. Molecules are arranged regularly.
molecules.
Q.395 Which of the following may be called London dispersion forces
A. dipole-dipole forces B. ion-dipole forces
C. dipole-induced dipole forces ✓ D. instantaneous dipole-induced dipole forces
Q.396 The highest temperature above which a gas cannot be liquified no ma er how much pressure is applied, is called as
✓ A. cri cal temperature B. absolute zero
C. liquefac on temperature D. boiling point
Q.397 Which of the following molecules should be more vola le
A. HF ✓ B. HCl
C. HBr D. HI
Q.398 The pressure of 5dm3gas increase from 250 torr to 500 torr then new volume of gas
A. 500 cm3 B. 375 cm3
✓ C. 2500 cm 3
D. None of these
Q.399 Which statement explains why the boiling point of methane is higher than that of neon?
_______________________________________________________________________________________
[Ar:H.1:c,12:Ne,20]
A. A molecule of methane has a greater mass ✓ B. Molecules of methane form hydrogen bonds
than a molecule of neon but those of neon do not
C. Molecule of methane have strongel D. The molecule of methane is polar, but that of
intermolecular forces than those of neon neon is not
Q.400 Graham s law refers to
A. Boiling point of gases B.
Gas compression problems
✓ C. Gaseous diffusion D.
Volume changes of gases due to change in
temperature
Q.401 Pressure remaining constant, at which temperature the volume of a gas will become twice of what it is at 0°C
A. 546°C B. 200°C
✓ C. 546 K D. 273 K
Q.402 Which of the following gases shows more ideal behaviour at 0°C
A. H2 B. CH4
✓ C. He
D. NH3
Q.403 Considering the physical proper es of the gases, which of the following statements about par cles of gas is not true.
The par cles
✓ A. orderly arranged B. randomly moving
C. having wide spaces D. causing pressure
Q.404 Elas c collision involves:
A. gain of energy B. loss of energy
C. no rela onship between elas c ✓ D. no gain or loss of energy
Q.405 The cause of devia on form ideal behaviour is because
A. the actual volume of gas molecules is not B. there is force of a rac on between molecules
negligible of a gas
✓ C. both a and b D. none of these
Q.406 Some substance are good conductors of electricity in both the solid and liquid states. These substance are generally:
A. molecular solids B. ionic substances
✓ C. metallic substances D. covalent network solids
Q.407 Which gas diffuses more rapidly?
A. O2 B. SO3
C. NH3 ✓ D. H2
Q.408 As gases can adopt the shape of the container. Therefore gases have:
A. different shapes B. fixed shapes
✓ C. no fixed shapes D. definite shapes
Q.409 Which pair of elements have bonds of the same type between their molecules in the solid state?
✓ A. phosphorous and nitrogen B. sulphur and magnesium
C. carbon and sodium D. hydrogen and sodium
Q.410 CuSO45H2O crystals belong to
✓ A. triclinic B. cubic
C. tetragonal D. orthorhombic
Q.411 AgNO3 is a polymorphic having two different crystalline forms which are
A. cubic, tetragonal B. monoclinic, hexagonal
C. cubic, orthorhombic ✓ D. orthorhombic, rhombohedral
Q.412 The number of NaCI molecules in unit cell of its crystal is
A. 2 ✓ B. 4
C. 6 D. 8
Q.413 The a rac ve forces which are created due to repulsion of electronic cloud of the molecules are
A. dipole-dipole forces B. ion dipole forces
✓ C. instantaneous dipole-induced dipole forces D. dipole-induced dipole forces
Q.414 The diffusion of gasses at absolute zero will be:
_______________________________________________________________________________________
A. Slightly decrease B. unchanged
C. Slightly increased ✓ D. Zero
Q.415 The molecule of CO2 in dry ice form are the:
A. ionic crystals B. covalent crystals
✓ C. molecular crystals D. any type of crystals
Q.416 Aluminium is in Group lll, its oxide will have the formula.
A. AlO B. AlO2
✓ C. Al2O3 D. Al3O2
Q.417 What can be deduce about two gases which have the same molecular mass:
A. They have same numbers of atoms in a ✓ B. They have same rate of diffusion
molecule
C. They have same boiling points
D. They have equal solubility in water at room
temprature
Q.418 Par al pressure of gases in a mixture depend upon:
✓ A. Number of moles B. Number of protons
C. Number of electrons D. Number of neutrons
Q.419 The process in which solid is directly coverted into gaseous state is called
A. evapora on B. boiling
✓ C. sublima on D. transforma on
Q.420 Which pair of molecules have debye force
A. Ne and Ne ✓ B. Argon and water
C. Na+ion and water D. Water and water
Q.421 The rate of diffusion of hydrogen gas is three mes than that of an unknown gas at same temperature and pressure
than the molar mass of unknown gas is
A. 32 ✓ B. 18
C. 16 D. 27
Q.422 Hydrogen has a = 0.245 atm. dm3. mole-2and
b = 0.0266 dm3. mole-1SO2gas has a = 6.170 atm. dm3mole-2and b =
0.0564 dm3mole where a and b are Van der Waal's constant
A. H2
gas deviates more from ideal behaviour
2
✓ B. SO2
gas deviates more form ideal behaviour
2
tha SO than H
C. both deviate from ideal behaviour equality D. both are ideal gases
Q.423 The highest temperature at which gas can be liquefied and above which liquefac on is impossible is called
A. Boiling temperature B. Upper consulate temperature
C. Transi on temperature ✓ D. Cri cal temperature
Q.424 Which one is not related with evapora on
A. Con nuous B. Cooling
✓ C. Exothermic D. Spontaneous
Q.425 The forces of a rac on between the solid atoms of helium are
A. hydrogen boding B. coordinate covalent bond
C. covalent bond ✓ D. London dispersion force
Q.426 The crystal system which has all cell angles equal, but not 90°and less than 120° , the system is
A. orthorhombic B. monoclinic
C. hexagonal ✓ D. rhombohedral
Q.427 Which one the following is not postulated in the kine c molecular theory of gases
✓ A. molecules of all the gases have same size and B. molecules are in chao c mo on
same mass
C. all molecular collisions are elas c
D. the volume of the molecules is negligible
Q.428 Which of the following gas will have lowest rate of diffusion
A. CH4 B. N2
C. NH3 ✓ D. CO2
Q.429 Rte of evapora on of petrol is greater than that of water at room temperature. This is due to the reason that:
A. petrol is an organic compound B. water molecules have small size
_______________________________________________________________________________________
✓ C. petrol molecules do not have D. petrol molecules have greater size

Q.430 The amount of heat absorbed when one mole of a liquid is changed into vapours at its boiling point is called
A. Heat of sublima on ✓ B. Heat of vaporiza on
C. Heat of fusion D. Enthalpy change
Q.431 Kine c energy of one mole of an ideal gas at 300 K in kJ is
A. 34.8 B. 3.48
✓ C. 3.74 D. 348
Q.432 The sun is a ball of plasma heated by nuclear fusion is
A. 1.0 million km B. 2.0 million km
✓ C. 1.5 million km D. 2.5 million km
Q.433 The a rac ve forces which exist between ionic compounds and water molecules are
A. dipole-dipole forces ✓ B. ion diopole forces
C. istantaneous dipole-induced dipole forces D. dipole-induced dipole forces
Q.434 Which of the following equa on is for idea gas:
A. PV = dRT B. PR = nTP
C. PM = nRT ✓ D. PV = nRT
Q.435 In Boyle's law which of the following pair remains constant:
A. Temperature and quality of a gas. B. Pressure and quality of a gas.
C. Temperature and pressure. ✓ D. Temperature and quan ty of a gas.
Q.436 Lind's ,method for liquefac on of gases is based on the principle of:
A. Graham's law of diffusion ✓ B. Joule Thomson effect
C. Avogadro's hypothesis D. Dalton's law of par al pressure
Q.437 Which pair of the gases doesn't obey Dalton's Law of par al pressures
A. H2and O2 B. N2and O2
C. H2S and H2 ✓ D. NH3and HCl
Q.438 Liquids are less common than:
A. Solids. B. Plasmas.
C. Gases. ✓ D. All of above.
Q.439 Pressure of 1Nm-2 is equal to
A. One bar B. 1 psi
✓ C. One pascal D. One atmosphere
Q.440 A solid has a sharp mel ng point slightly above room temperature and is a poor thermal and electrical conductor, its
crystal classifica on by bond type is
A. Ionic B. Metallic
✓ C. Molecular D. Covalent
Q.441 Steam causes more seers burns than boiling water. It is due to
A. Latent heat of fusion ✓ B. Latent heat of vaporiza on
C. Latent heat of sublima on D. All of above
Q.442 Observed pressure of gas on the walls of container is less than actual pressure due to
A. Hephazard mo on ✓ B. Inter molecular a rac ve forces
C. Elas c collision D. Repulsive forces
Q.443 One mole of a gas refers to
A. The number of molecules in one litre of gas B. The number of molecules in one gram of gas
C. The number of molecules contained 12C ✓ D. The number of molecules in 22.4 liters of a
in 12 grams of isotope gas at S.T.P.
Q.444 Which is trigonal cyrstal
A. BaSO4. 4H2O B. FeSO4
✓ C. NaNO3 D. None
Q.445 In Case of elements the polymorphism is called
A. Isotopic form ✓ B. Allotropy
C. Isomorphism D. Crystalline forms
_______________________________________________________________________________________
Q.446 Freshly cut metals have a shining surface because

✓ A. electrons excited, then excited electrons B. metals have bri le nature
release energy as light
C. metals conduc vity increases
D. metals are malleable and duc le
Q.447 In crystal structure of sodium chloride,the arrangement of CI- ions is
✓ A. Fcc B. Both fcc and bcc
C. Bcc D. None of these
Q.448 Which of the following molecules have a permanent dipole
A. CH4 ✓ B. CHCl3
C. CCl4 D. CO2
Q.449 The ra o of volume to temperature on Kelvin scale is constant according to:
✓ A. Charle's law B. Newton's law
C. Coulomb's law D. Boyle's law
Q.450 Keeping the temperature constant, if the gas is expended:
A. Kine c energy of molecules will increase. B. Number of gas molecules increases.
C. Temperature will increase. ✓ D. Pressure will decrease.
Q.451 Crystal la ce of the substances can be categorized into
A. five types ✓ B. seven types
C. six types D. none of these
Q.452 Diamond is a bad conductor because
A. it has light structure B. it has a high density
✓ C. there are no free electron present in the D. it transparent to light
crystal of diamond to conduct electricity
Q.453 Which of the following solids has a simple molecular la ce?
A. magnesium oxide B. sodium
C. silicon(IV) oxide ✓ D. sulphur
Q.454 If 1 mole of an ideal gas is heated from 273.15 K to 283.15 K at 1 atmospheric pressure, then increase in its energy is
A. 0.082 atm.dm3 ✓ B. 0.821 atm.dm3
C. 8.21 atm.dm3 D. 40.6 kJ
Q.455 At equilibrium rate of evapora on and rate of condensa on
A. Become very high B. Become very low
✓ C. Become equal D. Can never be equal
Q.456 The mass of 8.5 dm3of oxygen gas at 0.0821 atm and -1°C is
A. 100 g B. 10 g
✓ C. 1g D. 0.1 g
Q.457 What is the mass of 1020molecules of CO2at STP?
✓ A. 7.3 x 10-3g B. 7.9 x 10-3g
C. 3.2 x 10-3g D. 4.9 x 10-3g
Q.458 NaNO3and CaCO3crystals are Rhombohedral isomrophism is due to
A. both soluble in water B. their ca ons belong to S block element
✓ C. same shape
3
-1 and
3
-2 ions which is D. same number of O atoms
of NO CO triangular planar
Q.459 NH3can form only one hydrogen bond per molecule though it has three par ally posi vely charged hydrogens
✓ A. nitrogen3has only one ions pair of electrons B. ammonia is a base
in NH which can make one H-bond
C. ammonia is a weak acid
D. it ionizes to give one H+
Q.460 Instantaneous dipole-induced dipole forces are also known as:
A. dipole-dipole interac ons B. hydrogen bonds
C. covlent bonds ✓ D. Van der Waals forces
Q.461 All gases liquefly before reaching at
A. 273°K B. 373°K
_______________________________________________________________________________________
C. 0K ✓ D. 73°C
Q.462 The pressure exerted by the vapours in equilibrium with its pure liquid at given temperature is called the
A. equilibrium pressure B. atmospheric pressure
✓ C. vapour pressure D. external pressure
Q.463 Diamond is a bad conductor of electricity because:
A. it has a ght structure B. it has a high density
✓ C. there are no free electrons D. none of the above
Q.464 All of the following substances are crystalline except:
A. carbon B. ice
✓ C. plas c D. sucrose
Q.465 Equal volumes of ideal gases contain equal number of molecules at:
A. Same temperature B. Same pressure
C. Same environmental condi ons ✓ D. Both (A) and (B)
Q.466 Which of the following has isomorphous structure with MgO
✓ A. NaF B. S
C. Sn D. N
Q.467 Van der Waals equa on explains the behaviour of
✓ A. Real gases B. Mixture of gases
C. Ideal gas D. Diatomic gases
Q.468 Ionic solids are characterized by
A. low mel ng points B. good conduc vity in solid state
C. high vapour pressure ✓ D. solubility in polar solvents
Q.469 Which pair of elements will have the same type of bonds between their atoms in the solid state?
A. carbon and calcium B. lithium and boron
C. aluminium and phosphorus ✓ D. nitrogen and carbon
Q.470 Dalton's law finds its applica on during the process of:
A. Diges on ✓ B. Respira on
C. Reproduc on D. All of above
Q.471 Keeping in view different factors which affect the mel ng point of a substance.the compound having mel ng point
among the following is:
A. LiCl ✓ B. NaCl
C. CsCl D. RbCl
Q.472 The volume of 2.8 g of CO at 27°C and 0.0821 atm is
✓ A. 30 dm3 B. 3 dm3
C. 0.3 dm3 D. 1.5 dm3
Q.473 What is the numerical value of 'R; (the gas constant) in S.I units?
A. 83143 J/mole/K B. Avogadro's law
C. 83.143 J/mole/K ✓ D. 8.3143 J/mole/K
Q.474 The gas which obeys the gas laws at all condi ons of temperature and pressure is
✓ A. ideal gas B. perfect gas
C. real gas D. noble gas
Q.475 The maximum hydrogen bonding is in:
A. diethyl ether B. ethanol
✓ C. water D. benzene
Q.476 The density of methane at 2.0 atmosphere pressure at 27°C is
A. 0.13 gL-1 B. 0.26 gL-1
✓ C. 1.30 gL-1 D. 26.0 gL-1
Q.477 Which equa on among the following is applicable to an ideal gas equa on?
A. P = nRT B. P = MRT
✓ C. P = dPRT/M D. V = dRT/M
_______________________________________________________________________________________
Q.478 According to Avogadros law 1 mole of gas at S.T.P has a volume of
✓ A. 22.4 dm3 B. 24 dm3
C. 24000 cm3 D. 2m3
Q.479 The crystal of K2SO4and K2CrO4are orthorhombic. These are isomrophs due to
A. same physical proper es B. their ca ons iden cal
C. number of O atms is equal ✓ D. same shape of SO4-2and CrO4-2tetrahedral
Q.480 The rate of diffusion of a gas is:
A. Inversely propor onal to its density. ✓ B. Inversely propor onal to square root of its
molecules mass.
C. Directly propor onal to molecular mass. D. Directly propor onal to its density.
Q.481 The amount of heat required to vaporize one mole of liquid at its boiling point without change in temperature is called
✓ A. molar heat of vaporiza on B. molar heat of sublima on
C. molar heat of fusion D. none of these
Q.482 If absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume of the gas will be:
A. Remain uncharged B. Double
C. Reduced ✓ D. Increased four mes
Q.483 A real gas obeying van der Waals equa on will resemble ideal gas if
A. Both a and b are large B. a is large and b is small
✓ C. Both a and b are small D. a is small and b is large
Q.484 Which is the example of diffusion of gases
A. bubbling in soda bo le B. vapour condensing on a moist surface
C. hot air rising above a candle ✓ D. spreading of smell from a scent bo le
Q.485 Which of the following liquid has high vapour pressure?
A. H 2O ✓ B. ether
C. CH3OH D. C2H5OH
Q.486 which one of the following statements bout nega ve ions is incorrect?
A. they are also know as anions B. they are formed when atoms gain electrons
C. they are large than the atom from which they ✓ D. they are smaller than the atom from which
were formed they were formed
Q.487 If the volume of 2 moles of an ideal gas at 540 K is 44.8 litre then its pressure will be
A. 1 atmosphere ✓ B. 2 atmosphere
C. 3 atmosphere D. 4 atmosphere
Q.488 What is the reason of ionic solids for not conduc ng electricity?
A. free electrons are less B. ions don't have translatory men on.
✓ C. ions don't have translatory men on D. the coordina on number of the ion is very
high.
Q.489 The gases H2, O2, H2S and SO2diffuse in the order
A. SO2>H2S>H2>O2 B. H2S>SO2>O2>H2
C. O2>SO2>H2>H2S ✓ D. H2>O2>H2S>SO2
Q.490 The factor responsible for lower mercury level in a capillary tube is
✓ A. High density B. Surface tension
C. Liquid state D. Metallic Colour
Q.491 The density of ice is 1.00gcm-3.
What the volume of steam produced when 1.00-3 of ice is heated to 323∘C (596K) at a pressure of one atmosphere (101kPa)?
[1 mol a gas occupies 24.0dm3 at 25a∘C(295K)and one atmosphere.]
A. 0.267 dm3 B. 1.33 dm3
✓ C. 2.67 dm3 D. 48.0 dm3
Q.492 A gas is heated in a closed vessel. Which of the following statement is not true for the gas?
A. the intermolecular forces between par cles B. the kine c energy of par cles increases
weaken
✓ C. the total internal energy of the gas remains
constant
D. the total internal energy of the gas increases
Q.493
_______________________________________________________________________________________
H2effuses through a porous pot at a rate of 500 cm3per minute at 0°C.The rate of diffusion of O2through the
same vessel at 0°C per minute is
A. 500 cm3 B. 250 cm3
C. 1 dm3 ✓ D. 125 cm3
Q.494 A real gas most closely approaches the behaviour of an ideal gas at
A. 15 atm. and 200 K B. 1 atm. and 273 K
✓ C. 0.5 atm.and 500 K D. 15 tm, and 500 K
Q.495 The smallest unit of a crystal that shows all the characteris c proper es of its pa ern is called
A. cell B. electrolyte
✓ C. unit cell D. crystal
Q.496 The minimum temperature recorded by Kelvin scale is:
✓ A. 273K B. 373K
C. Absolute scale is unable D. 0K to record this temperature
Q.497 An ideal gas cannot be liquefied because
A. Its cri cal temperature is always above 0°C B. Its molecules are rela vely small in size
C. It solidifies before becoming a liquid ✓ D. Forces opera ve between its molecules are
negligible.
Q.498 The par al pressure oof gas can be calculated if we know total pressure of mixture and:
A. Number of protons B. Number of electrons
C. Number of neutrons ✓ D. Mole frac on of gases
Q.499 On the basis of intermolecular forces diamond is a
A. ionic solid ✓ B. covalent solid
C. metallic solid D. molecular solid
Q.500 Dipole-dipole forces are present between:
A. non-polar molecules ✓ B. polar molecules
C. both polar and non-polar D. none pf above
Q.501 A line parallel to x-axis is obtained when graph is drawn between
A. Volume on abscissa & pressure on ordinate B. Volume on abscissa & PV on ordinate at all
condi ons
✓ C. Pressure on abscissa & PV on ordinate at D. None of these
constant temperature
Q.502 Among solids,the highet mel ng point is exhibited by
A. Covalent solids ✓ B. Ionic solids
C. Pseudo solids D. Molecular solids
Q.503 Boiling point of H2O is higher than that of HF although F is more electronega ve than O. It is due to
A. stronger dipole dipole forces in H2O B.
H2O is neutral HF is acidic
C. H2O is angular, but HF is linear ✓ D.
number of hydrogen bonds more than in
2O
in H HF
Q.504 The product of pressure and volume remains constant when temperature and quan ty of gas is:
A. Zero B. Variable
✓ C. Kept constant D. None of above
Q.505 Gases show uniform behavior towards their:
A. Internal condi ons. ✓ B. External condi ons.
C. Internal and external condi ons. D. None of above.
Q.506 The one atmospheric pressure of air in term of pound per square inches is
A. 101.325 B. 1.01325
C. 760 ✓ D. 14.7
Q.507 Absolute zero, the lowest temperature on kelvin scale lies at
✓ A. -273°C B. 273°
C. -100°C D. 100°C
Q.508 In solid, the temperature is the measure of:
A. Rota onal kine c energies. B. Transla onal kine c energies.
✓ C. Vibra onal kine c energies. D. None of above.
_______________________________________________________________________________________
Q.509 Density of H2gas at 0°C is 0.09 under 1 atmospheric pressure. The density of O2gas under the same
conditions of temperature and pressure is
A. 0.36 B. 1.00
✓ C. 1.44 D. 1.18
Q.510 When two ice cubes are pressed together they unite to form one cube. Which of the following forces is responsibles
for holding them together
A. Van der Waal's B. covalent bonding
✓ C. hydrogen bonding D. dipole-dipole interac on
Q.511 Liquids have definite volume due to
A. Negligible spaces B. Intermolecular force
C. Mo on ✓ D. Both a and b
Q.512 In a closed vessel a gas is heated from 300 K to 600K The kine c energy becomes remains
✓ A. Double B. Same
C. Half D. Four mes
Q.513 In which of the following compounds H-binding is not present?
A. ethanol ✓ B. ether
C. water D. ammonia
Q.514 One molecule of gas is approximately Distance______ mes its own diameter from its neighbour at room
temperature.
A. 30 B. 3000
C. 3 ✓ D. 300
Q.515 How many CI- ions are there around Na+ ion in NaCI crystal?
A. 3 B. 4
✓ C. 6 D. 8
Q.516 The volume of gas depends upon the ______ molecules
A. Size of B. Molecular weight
✓ C. Space between D. Both a and b
Q.517 The ra o of close packed atoms to tetrahedral holes in cubic close packing is
A. 1:1 ✓ B. 1:2
C. 1:3 D. 2:1
Q.518 When vapour pressure is equal to atmospheric pressure than it is called
A. Evapora on B. M.P
✓ C. B.P D. Freezing point
Q.519 A substances has Mr74.5, a mel ng point of 772°C and a boiling point of 1407°C. It conducts electricity only
when in the liquid state.What is the bonding present in this substances?
A. covalent ✓ B. ionic
C. metallic D. hydrogen bonding
Q.520 At room temperature, the vapour pressure of water and ether will be
A. equal ✓ B. different
C. zero D. almost same
Q.521 Which one of the following is not true rela onship
A. B.
✓
C. D.
Q.522 Water may boil at 170C when external pressure is
A. 760 torr B. 170 torr
✓ C. 2115 torr D. 700 torr
Q.523 Coordina on number of Zn and ZnS (Zinc blends) is
✓ A. 4 B. 6
C. 2 D. None of these
_______________________________________________________________________________________
Q.524 A graph between P and 1/V at constant temperature and number of moles of a gas meets the:
A. Y-axis B. X-axis
✓ C. Origin D. None of above
Q.525 The rate of diffusion of a gas is propor onal to
A. P /√d ✓ B. √p/d
C. P/d D. √ P/d
Q.526 The correct value of the gas constant R is close to
✓ A. 0.082 litre-atm K-1mol-1 B. 0.082 litre-atm-1K mol
C. 0.082 litre-atm K D. 0.082 litre-atm-1K mol-1
Q.527 Which of the following pairs of not form a da ve covalent bond to each other?
A. NH3and H+ B. H2O and H+
C. NH3and BF3 ✓ D. CH4and AICI3
Q.528 Acetone and Chloroform are soluble in each other due to
✓ A. intermolecular hydrogen bonding B. ion-dipole interac on
C. instantaneous dipoles D. dipole-induced dipole interac on
Q.529 Inside very fluorescent lamp there is present a:
A. Gas ✓ B. Plasma
C. Liquid D. Solid
Q.530 Rela onship between volume of a gas and prevailing condi ons of temperature and pressure are called
✓ A. Gas laws B. Equilibrium laws
C. Rate laws D. None of these
Q.531 The average kine c energy of an ideal gas per molecule is SI units at 25°C will be
A. 6.17 x 10-21KJ ✓ B. 6.17 x 10-21J
-20
C. 6.17 x 10 J D. 7.16 x 10-20J
Q.532 The correct order of increasing a rac ve strength for weak intermolecular forces is....
A. dipole-dipole interac on hydrogen bonding, ✓ B. van der waals forces dipole- dipole
van der Waals forces interac on, hydrogen bonding
C. hydrogen bonding, dipole-interac on, van der D. hydrogen bonding, van der Waals forces,
Waals forces dipole-dipole interac on
Q.533 The value of van der Waal s constant a for gases CO2, N2, and SO2, are 3.59 ,1.39, 1.36, and 6.17 atm dm6 mol-2
respec vely the gas which can be most easily liquefied is
A. CO2 B. O2
C. N2 ✓ D. SO2
Q.534 When a compressed gas is allowed to expand into a region of low pressure, it produce:
A. Vapours ✓ B. Cooling effect
C. Hea ng effect D. None of above
Q.535 The scale of temperature that shows the freezing point of water at 0° is called
A. Fahrenheit B. Kelvin
C. absolute ✓ D. Celsius
Q.536 Which of the following gases have lowest density at room temperature
A. CO B. N2
C. Ne ✓ D. NH3
Q.537 Vapour pressure is not affected by
✓ A. Surface area B. Intermolecular forces
C. Temperature D. Nature of liquid
Q.538 All the following have crystals except:
A. potassium bromide B. diamond
✓ C. cadmium sulphide D. sodium chloride
Q.539 Honey contains glucose and fructose along with some other ingredients. It has greater viscosity due to:
✓ A. irregular shape of the molecules B. greater molecular size and strong
intermolecular forces
C. H-bonding D. irregular shape of the molecules
_______________________________________________________________________________________
Q.540 Kerosene is liquid at room temperature.This is due to:
A. organic nature B. H-bonding
✓ C. molecular size D. dipole-dipole forces
Q.541 If a graph is plo ed between temperature on x-axis and volume on Y-axis for 1 mole of gas,then we get straight line
which cuts the temperature axis at
A. -300°C B. 300 K
C. -273.15 K ✓ D. 273.15°C
Q.542 Which one of the following statements about posi ve ions is incorrect?
A. they are also known as ca ons B. they are formed when electrons are removed
from atoms
✓ C. they are larger than the atom from which D. they are smaller than the atom from which
hay were formed they were formed
Q.543 The respira on process taking place in animals depends upon a difference in:
A. vapour pressure B. osmo c pressure
✓ C. par al pressure D. atmospheric pressure
Q.544 The value of R is SI units is
A. 0.0821 dm3. atm. J-1mole-1 B. 62.4 dm3torr K-1mole-1
C. 8.31 dm3atm. K-1mole-1 ✓ D. 8.31 JK-1mole-1
Q.545 The value of R in term of dm3torr k-1mol-1
A. 62400 ✓ B. 62.4
C. 8.313 D. 0.0821
Q.546 According to Boyle's law, which parameters give a straight line parallel to x-axis, when we plot a graph between:
A. V and T B. P and V
C. P and 1/V ✓ D. P and PV
Q.547 Which one of the following gases has lowest density at room temperature:
✓ A. NH3 B. Ne
C. N2 D. CO
Q.548 The system in which all the three axes are unequal and are at righ angle to each other is called
A. cubic B. hexagonal
✓ C. orthorhombic D. tetragonal
Q.549 The distribu on of energies among the molecules of gases was studied by:
A. Maxwell B. Coulomb
C. Newton ✓ D. Boltzmann
Q.550 The gecko a small lizard can up a smooth glass window the gecko has millions of microscopic hairs on its toes and each
hair has thousand of pads at its p the result is that the molecules in the pad are extremely close to the glass surface
on which the gecko is climbing.
What is the a rac on between the gecko is climbing.
✓ A. co-ordinate bonds B. covalent bonds
C. ionic bonds D. van der Waals forces
Q.551 Intermolecular forces exist between molecules of group 7 elements which of the following sequence represents the
strength of the intermolecular forces?
A. Cl2> Br2> I2 B. Br2> Cl2> I2
✓ C. Cl2> Br2> I2 D. I2> Br2> Cl2
Q.552 The weight of 11.2 liters of CO2 at S.T.P would be
A. 88 g B. 44 g
C. 32 g ✓ D. 22 g
Q.553 Stalagmometer is used to measure
A. the resistance to flow of a liquid B. capillary ac on of a liquid
C. Meniscus of the liquid ✓ D. surface tension of the liquid
Q.554 S.I units for measurements of pressure
✓ A. Pascal B. mm of Hg
C. atm D. Torr
_______________________________________________________________________________________
Q.555 The molar volume of CO2 is maximum at:
A. S.T.P. (0∘C and 1 atm) ✓ B. 127∘C and 1 atm
C. 0∘C and 2 atm D. 273∘C 2atm
Q.556 Surface tension is measured by
A. viscometer B. barometer
✓ C. stalagmometer D. manometer
Q.557 SiO2 is an example of:
A. metallic crystals B. lonic crystals
C. a crystal whose structure depending upon the ✓ D. covalent crystals
temperature
Q.558 The mono atomic gas molecules are ______ gas molecules
A. Halogen B. Zero
✓ C. Noble D. Both b and c
Q.559 The rela ve rates of diffusion of a gas (Mol.wt.=98) as compared to hydrogen will be
✓ A. 1/7 B. 1/5
C. 1/4 D. 1
Q.560 Image a man is si ng in a room. The room is closed from all sides, no entry no exit of any gas. If the room expands
suddenly then:
A. he will be frightened ✓ B. he will feel cool
C. his blood pressure will decrease D. he will feel warmth
Q.561 Pressure remain constant at which temperature the volume of gas becomes twice of what it is at 0°C
A. 546 °C ✓ B. 546K
C. 200°C D. 273K
Q.562 Which of the following is a pseudo solid?
A. CaF2 ✓ B. glass
C. NaCl D. all these
Q.563 London forces are more affec ve at:
A. high temperature B. low temperature
✓ C. low pressure D. high pressure
Q.564 Intermolecular forces are _________ than binding forces
✓ A. stronger B. Equal
C. Weaker D. None
Q.565 There are _________ types of solids
A. 1 ✓ B. 2
C. 3 D. 4
Q.566 Two substances that have the same crystal structure are said to be
✓ A. isomorphous B. anisotropic
C. isotropic D. polymorphous
Q.567 Equal masses of methane and oxygen are mixed in an empty container at 25∘C.
✓ A. 1/3 B. 8/9
C. 1/9 D. 16/17
Q.568 Correct order of intermolecular forces
A. Gas < liquid < solid B. Liquid < gas < solid
✓ C. Gas < liquid < solid D. Gas = liquid = solid
Q.569 The curve which is obtain from Boyle's law is called as
A. Isochoric ✓ B. Isotherm
C. Adiaba c D. All of these
Q.570 Charle's law only obeys when temperature takes in ______ scale
A. Celsius B. Fahrenheit
✓ C. Kelvin D. Rickey
Q.571 The rate of diffusion of a gas is inversely propor onal to:
_______________________________________________________________________________________
✓ A. Density of a gas B. Velocity of the gas
C. Viscosity of the gas D. All of above
Q.572 suppose that an ocean of mercury replaced all the air of the air of the earth . How deep would this ocean have to be to
exert the same pressure as the air:
A. 77cm ✓ B. 76cm
C. 79cm D. 78cm
Q.573 Water has high boiling point which is due to:
A. high electric constant B. weak dissocia on
C. high specific heat ✓ D. H-bonding between its molecules
Q.574 Diamond and graphite are
A. isomorphous B. polymorphous
✓ C. allotropes D. none of these
Q.575 At STP,a container has 1 mole of Ar,2 moles of CO2,3 moles of O2 and 4 moles of N2.Without changing the total
pressure if one mole of O2 is removed,the par al pressure of O2
✓ A. Is changed by about 26% B. Is halved
C. Is unchanged D. Change by 33%
Q.576 The existence of a substance in more than one solid modifica on is known as
A. Isomorphism ✓ B. Polymorphism
C. Amorphism D. None of these
Q.577 Equal volumes of all gases at STP contain equal no of molecules is called
A. Dalton's law of par al pressure B. Graham'a law of diffusion
✓ C. Avogadro's law D. None
Q.578 Liquid crystals are used for the early diagnosis of breast cancer by
A. injec ng liquid crystals B. taking liquid crystals as diet
✓ C. pain ng liquid crystals on the surface of D. inhaling the smell of liquid crystals
breast
Q.579 When liquid water changes to ice, the volume expands. The expansion in volume is
A. 5% B. 7%
✓ C. 9% D. 12%
Q.580 Equal volumes of gases at the same temperature and pressure contain equal number of par cles.This statement is
direct consequence of
A. Perfect gas law B. Par al law of volumes
C. Charle's law ✓ D. Ideal gas equa on
Q.581 For gas obeying Boyle's law if pressure is double, the volume becomes:
A. Remains constant. B. Double.
✓ C. One half. D. None of above.
Q.582 Absolute temperature is the temperature at which
✓ A. All molecular mo on ceases B. volume becomes zero
C. Mass becomes zero D. None of these
Q.583 NaCl is completely ionized in water due to presence of
A. hydrogen bonding B. dipole dipole forces
✓ C. ion dipole forces D. London dispersion forces
Q.584 The pure crystalline substance on being heated gradually first forms a turbid liquid at constant temperature and s ll at
higher temperature turbidity completely disapp-ears.The behaviour is a characteris c of substance forming
A. Allotropic crystal ✓ B. Liquid crystals
C. Isomeric crystals D. Isomorphous crystals
Q.585 If absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume of the gas will
A. remain unchanged ✓ B. increase four mes
C. reduce to 1/4 D. be doubled
Q.586 How should the condi ons be changed to prevent the volume of a given gas from expanding when its mass in
increased
_______________________________________________________________________________________
✓ A. temperature is lowered and pressure is B. temperature is increased and pressured is
increased lowered
C. temperature and pressure both are lowered D. temperature and pressure both are increased
Q.587 One atmosphere is equal ___________ Pascal
A. 760 ✓ B. 101325
C. 14.7 D. 1.01325
Q.588 The basic dis nc on between solids, liquids and gases lies in difference between.
✓ A. Strength of the bonds B. Size of molecules
C. space which the molecules occupy D. All of above
Q.589 All gases can be compressed by:
A. Keeping constant pressure B. Decreasing pressure
✓ C. Increasing pressure D. None of above
Q.590 Gases are effused through a whole due to ______ mo on
A. Vibra on B. Rotaional
✓ C. Transla onal D. Chao c
Q.591 Which one of following statement about three about three states of ma er is incorrect?
A. in solids the par cles vibrate about fixed B. energy is released when a gas turns back to a
posi ons liquid
C. par cles in gases move in a random manner ✓ D. the closer par cles are together, smaller the
force of a rac on between them
Q.592 Most of the universe consists of thema er in :
A. Gaseous state B. Liquid state
✓ C. Plazma state D. Solid state
_______________________________________________________________________________________
3 Atomic Structure
Q.1 A reac on in which heat is given out is:

A. a thermochemicla reac on ✓ B. an exothermic reac on
C. an endothermic reac on D. am energe c reac on
Q.2 The orbitals having same energy are known as
A. d-orbitals ✓ B. degenerate orbitals
C. Hybrid orbitals D. Valence orbitals
Q.3 The e/m ra o of an electron was determined by
✓ A. Millikan B. Rutherford
C. Thomson D. none of these
Q.4 Which one of the following par cles has a mass 1/1836 me, that of hydrogen?
A. Neutron B. Proton
✓ C. Electron D. Postron
Q.5 Nuclear radia on is emi ed by those elements whose
A. Nuclai are stable B. Molecules are stable
✓ C. Nuclai are unstable D. Molecules are unstable
Q.6 Charge on the electron was measure by
✓ A. R.A. Milikan B. J. J. Thomson
C. Rutherford D. Faraday
Q.7 First ioniza on energy decreases down group II although the proton number increases, why it that?
A. greater number of shells are present in the ✓ B. the effect of shielding increases along with
atom an increase in the number of shells
C. number of electrons in inner shells, increases D. the hold of the nucleus decreases on the
leading to a stronger repulsion,which valence electrons due to increasing atomic
facilitates the removal of a valence electron radius
Q.8 Angle of deflec on of cathode rays was studied by
A. Hi orff B. Stoney
C. J. J. Thomson ✓ D. J. Perrin
Q.9 Fora which equa on is the enthalpy changes correctly described as an enthalpy change forma on?
A. 2NO(g)--->N2(g) + O2(g) B. 2CO(g)--->O2(g)+ 2CO2(g)
C. H2O(l)--->NaCl(s)+NaCI(aq) ✓ D. K(s)+ Mn(s) + 2O2(g)---> KMnO4(s)
Q.10 The law of thermodynamics that provides the basis for the determina on of absolute entropy of substance is
A. Zeroth law B. First law
C. Second law ✓ D. Third law
Q.11 If at 298 K the bond energies of C-H,C-C,C=C and H-H bonds are respec vely 414, 347,and 435 kJ mol-1 the value of
enthalpy change for the reac on H2C = CH2 (g) + H2(g) → H3C - CH3(g) at 298 K will be
A. +250 kJ B. -250 kJ
C. +125 kJ ✓ D. -125 kJ
Q.12 Boh's model of atom is contradicted by
A. Planck's quantum theory B. Quarterniza on of energy of electrons
✓ C. Heisenberg's uncertainity principle D. Quarterniza on of angular memeber
Q.13 An electron with n = 3, I = 2 will be in the sub-shell
A. 3p ✓ B. 3d
C. 3f D. 3s
_______________________________________________________________________________________
Q.14 If value of Azimuthal quantum number is '1' the atomic orbital is:
A. f B. s
✓ C. p D. d
Q.15 A macroscopic property of a system that describes the ini al and final state of the system is called:
✓ A. state func on B. energy of the system
C. physical property D. chemical property
Q.16 Choose the ionic specie which has more electrons than neutrons
A. Na+ B. Mg2+
✓ C. O2- D. Na-
Q.17 The enthalpy of a system is defined by the rela on
✓ A. H = E + PV B. H = E - PV
C. E = H + PV D. PV + E - H
Q.18 Enthalpy of neutraliza on of all the strong acids and strong bases has the same value because:
A. neutraliza on leads to the forma on of salt B. strong acids and bases are ionic substances
and water
C. acids always give +ions and bases always -
ions
rise to H furnish OH
✓ D. The net chemical change involves the
combina on of H+ and OH- ions to form
water
Q.19 If au au rule is not followed, 19th electron in Sc (Z = 21 ) will have
A. n = 3, l = 0 B. n = 3, l = 1
✓ C. n = 3, l = 2 D. n = 4, l = 0
Q.20 The mass of neutron is in the range of
A. 1.6750 x 10-26kg B. 1.6750 x 10-23kg
C. 1.6750 x 10-22kg ✓ D. 1.6750 x 10-27kg
Q.21 Mass of simple electron is:
A. 9.1 x 1031kg B. 9.1 x 10-30kg
C. 1.66 x 10-31kg ✓ D. 9.1 x 10-31kg
Q.22 The radius of first orbit of H-atom is
✓ A. 4.75 A° B. 3.87 A°
C. 8.4 A° D. 0.529 A°
Q.23 Electrons arranged in orbitals according to the increasing order of their n + 1 values the this rules is named as
A. Hund's rule B. Heisenberg's principle
C. Paulit exclusion principle ✓ D. Auf bau principle
Q.24 In standard states, enthalpies of all element are:
A. always +ve B. unity
C. always -ve ✓ D. zero
Q.25 Which of the following has maximum e/m value for posi ve rays
✓ A. Hydrogen B. Nitrogen
C. Oxygen D. Helium
Q.26 Quantum number values for 2p orbitals are
✓ A. n = 2, I = 1 B. n = 1, I = 2
C. n = 1, I = 0 D. n = 2, I = 0
Q.27 When an electric current is passed through discharge tube at low pressure, cathode rays are emi ed from cathode
these rays consist of:
A. Alpha rays ✓ B. Nega ve par cles
C. Electromagne c rays D. Posi ve par cles
Q.28 When rate of forward reac on is equal to the backward reac on then
the equilibrium is established called:
A. sta c equilibrium B. chemical equilibrium
✓ C. dynamic equilibrium D. none of above
Q.29 If heat is evolved is the reac on, the process is said to be:
_______________________________________________________________________________________
✓ A. an exothermic B. an endothermic
C. adiaba c process D. isothermal
Q.30 The limi ng line of Baimer series in hydrogen spectrum lies in
✓ A. visible region B. ultraviolet region
C. infrared region D. x-ray region
Q.31 An electron moving in orbit having principle quantum number 4 & azimuthal quantum 2, then subshell will be
A. 4p ✓ B. 4d
C. 4f D. 5s
Q.32 Element having the smallest atomic radius among the following is
A. Sr B. Li
C. Rb ✓ D. Ne
Q.33 The branch of chemistry which deals with thermal energy change in chemical reac on is called:
✓ A. thermochemistry B. thermidynamics
C. mechanics D. chemical kine cs
Q.34 Latent heat of vaporiza on of a liquid at 500 K and 1 atm pressure is 10.0 kcal/mol.What will be the change in internal
energy (Δ E( of 3 mol of liquid at same temperature?
A. 13.0 kcal B. -13.0 kcal
✓ C. 27.0 kcal D. -27.0 kcal
Q.35 If volume of a system is kept constant and heat is supplied to they system then:
✓ A. internal energy of the system increases and B. internal energy of the system increases and
no work is done on the surrounding work is done on surrounding
C. no work is done on the surrounding D. no change in internal energy occurs
Q.36 What is first ioniza on energy?
A. the energy required to extract one electron B. the energy required to extract on mole
from each atom electrons
C. the energy required to extract one mole ✓ D. the energy required to extract one mole
electrons from one mole of atoms electrons from one mole of atoms in gaseous
state to get 1 mole of gaseous ions
Q.37 When 6d orbital is complete, the entering electron goes into
A. 7f B. 7s
✓ C. 7p D. 7d
Q.38 The gaseous oxides of nitrogen have posi ve enthaply changes of forma on. Which factor is likely to make the most
significant contribu on to these enthalpy change
✓ A. the high bond energy of the nitrogen 2
B. the high electron affinity of oxygen atoms
molecule, N C. the similarity of the electronega vi es of
oxygen and nitrogen
D. the high electron affinity of oxygen atoms
Q.39 In chromium (Cr - 24) the number of electrons with azimuthal quantum numbers, l = 1 and 2 are respec vely
A. 12 and 4 ✓ B. 12 and 5
C. 4 D. 5
Q.40 H2 + 1/2 O2 → H2O:ΔH = -68 kcal
K + H2O + aq → KOH (aq) + 1/2 H2; ΔH = -48 kcal
KOH + qa → KOH (aq); ΔH = -14 kcal
from the above data,the standard heat of forma on of KOH in kcal mol-1 is
A. -68 +48 -14 ✓ B. -68 -48 +14
C. 68 -48 +14 D. 68 +48 +14
Q.41 A spontaneous change means:
A. a lowering of free energy B. a lowering of energy
✓ C. an increase in internal energy D. no energy change
Q.42 Which rule allows only two electrons to be placed in an orbital
A. Au au principle ✓ B. Pauli's exclusion principle
C. Hund's rule D. 2n2
Q.43 The wave number of the light emi ed by a certain source is 2 x 106m-1. The wavelength of this light will be
_______________________________________________________________________________________
✓ A. 500 nm B. 500 m
C. 200 nm D. 5 x 107m
Q.44 The orbital which can accommodate a maximum of 10 electrons is
A. f B. p
C. s ✓ D. d
Q.45 In endothermic reac ons the heat content of the :
✓ A. products is more than that of reactants B. reactants is more than that of products
C. both (a) and (b) D. reactants and products are equal
Q.46 Which of the following gas has smaller e/m value
✓ A. Oxygen B. Nitrogen
C. Methane D. Carbon monoxide
Q.47 The mass of electron is
A. 1.602 x 10-10kg B. 1.6022 x 10-19kg
✓ C. 9.1090 x 10-31kg D. None
Q.48 The heat absorbed at constant volume is equal to the system's change in
A. enthalpy B. Entropy
C. Entropy x temperature ✓ D. Internal energy
Q.49 Total values of magne c quantum number (m) can be calculated with the expression
A. 2n2 ✓ B. 2l + 1
C. 2(2l+ 1) D. 3n2
Q.50 Total number of d-electrons in an atom of atomic number 24 is
A. 2 B. 4
✓ C. 5 D. 6
Q.51 The ΔH values for reac on C + 1/2 O2 → CO and CO + 1/2 O2 → CO2 are 100 and 200 kJ respec vely.The heat of
reac on for C + O2 → CO2 will be
A. 50 kJ B. 100 kJ
C. 150 kJ ✓ D. 300 kJ
Q.52 Four d-orbitals contain four lobes while fi h contains only two lobes the orbital is
A. dxy B. dxz
✓ C. dz 2
D. dx2- y2
Q.53 Elements A,B and C lie side by side along a period in the periodic table. Element B has the highest ioniza on energy.
What could be the iden es of A, B and C?
A. oxygen, fluorine, neon B. phosphorous, sulphur, chlorine
✓ C. silicon, phosphorous, sulphur D. magnesium,aluminium, silicon
Q.54 All of the following are state func ons except
A. P B. V
✓ C. q D. H
Q.55 An atom has 35 nucleons and has atomic number equal to 17. the number of electrons with n = 2, m = 0 in it is
✓ A. 2 B. 4
C. 1/2 D. 1/4
Q.56 A gas contained in a cylinder fi ed with piston cons tute
A. An open system B. A heterogeneous system
✓ C. A closed system D. An isolated system
Q.57 Value of R (rydberg's constant)
A. 1.09678 x 107m ✓ B. 1.09678 x 107cm-1
C. 1.09678 x 107cm D. 1.09678 x 107cm-1
Q.58 Energy of bounden electron in H-atom is always
A. Posi ve ✓ B. Nega ve
C. Zero D. Frac onal
Q.59 Which one of the following orbitals has high energy?
_______________________________________________________________________________________
✓ A. 4d B. 3s
C. 4s D. 2s
Q.60 Which of the following units represents largest amount of energy?
✓ A. Calorie B. Joule
C. Erg D. Electron vol.
Q.61 Chemical reac on involves energy change. The study of heat changes during chemical reac on is called:
A. chemical equilibrium ✓ B. thermochemistry
C. chemical poten al D. chemical kine cs
Q.62 Ioniza on energies of the elements of group VA are greater than those of Group VI A. The reason is that
A. Group VI A elements have greater shielding ✓ B. Group V A elements half-filled atomic
effect orbitals
C. Group V A element have less electronega vity D. Group V A elements have greater shielding
effect
Q.63 Charge on electron was discovered by:
✓ A. Millikan B. Crook
C. Neil Bohr D. Rutherford
Q.64 An adiaba c expansion of an ideal gas always has
A. Decrease in temperature ✓ B. q=0
C. W=0 D. ΔH=0
Q.65 Bohr model of atom does not explain
A. Stark effect B. Zeeman effect
C. Origin of line in H2spectrum ✓ D. All these
Q.66 A material or a collec on of materials which is under study is called:
✓ A. system B. state func on
C. surrounding D. substance
Q.67 Which of the following orbitals will be filled first?
A. 5d ✓ B. 4s
C. 4f D. 3d
Q.68 Choose the reac ons which mostly give stable products:-
A. isothermal reac ons ✓ B. exothermic reac ons
C. endothermic reac ons D. none of above
Q.69 Each electron in an atom must have its own unique set of quantum numbers. This is a statement of
A. Periodic law B. Au au principle
✓ C. Pauli exclusion principle D. Hund's rule
Q.70 Photons of yellow colour are ________ energe c than violet colour
A. More ✓ B. Less
C. Equal D. None
Q.71 The heat of neutraliza on is maximum when
A. Sodium hydroxide is neutralized by ace c acid B. Ammonium hydroxide is neutralized by ace c
acid
C. Ammonium hydroxide is neutralized by ✓ D. Sodium hydroxide is neutralized by
hydrochloric acid hydrochloric acid
Q.72 total number of d-electrons in an atom of atomic number 26 is:
A. 7 B. 4
✓ C. 6 D. 5
Q.73 When cathode rays strike the anode metal. X-rays are emi ed and not the posi ve rays because
A. cathode rays are material par cles ✓ B. cathode rays knock out electrons from anode
which emit X-rays when outer electrons take
their place
C. cathode rays are absorbed by the nucleus D. cathode rays become heated
Q.74 The mass of a neutron is mes greater than the mass of electron
A. 540 ✓ B. 1840
C. 1480 D. 2000
_______________________________________________________________________________________
Q.75 According to Heisenbergs uncertainty principle, we cannot measure
A. posi on B. momentum
C. energy ✓ D. posi on and momentum simultaneously
Q.76 Maximum number of electrons in a subshell is given by
A. 2l + 1 B. 2l - 1
✓ C. 2(2l + 1) D. 2(2l - 1)
Q.77 The isotopes of an elements have the same chemical proper es in what aspect do isotopes of the same element differ
from each other?
A. they have different atomic numbers B. they have different number of protons and
neutrons
C. they have different number of nucleus ✓ D. they have different number of neutrons
Q.78 For a spontaneous process
A. ΔG>0 ✓ B. ΔG<0
C. ΔG=0 D. None of these
Q.79 Quantum number values for 2p orbitals are
A. n = 1, l = 2 B. n = 1, l = 0
C. n = 2, l = 0 ✓ D. n = 2, l = 1
Q.80 The rules which describe the distribu on of electron in atomic energy levels are Auf-ban principle. Pauli's exclusion
principle Hunds rule. The Pauli exclusion principles refers to the
A. orienta on of orbital in space ✓ B. fact that two electrons in the same orbital
should have opposite spins
C. energy of the orbital D. spin of the electron
Q.81 Energy can neither be created nor destroyed but can be changed from one from to another is stated by
A. Henrys law B. Joule s principle
✓ C. First law of thermodynamics D. Raoult s law
Q.82 An orbital can accommodate maximum of :
A. 18 electrons B. 12 electrons
C. 8 electrons ✓ D. 2 electrons
Q.83 Balmer's series is in __________ region
✓ A. Visible B. U.V
C. I.R D. None
Q.84 Color of the glow produced in the discharge tube
✓ A. Depends on the gas used in the discharge B. Depends on the pressure in the discharge
tube tube
C. Does not depend on the nature of the gas D. Depends ont eh metal used as cathode
used in the discharge tube
Q.85 Hund's rule states that when electrons enter to the same sub-levels they are:
A. Singly occupied with different spins. B. Doubly occupied with different spins.
✓ C. Singly occupied with same spins. D. Doubly occupied with same spins.
Q.86 According to Heisenberg uncertainty principle, maximum number of electrons an orbital can accommodate is
✓ A. 2 B. 1
C. 0 D. 3
Q.87 A spontaneous change is one in which the system suffers
✓ A. An increase in internal energy B. Lowering in free energy
C. Lowering in entropy D. No energy change
Q.88 Evapora on of water is
A. An exothermic change ✓ B. An endothermic change
C. A process where no heat changes occur. D. A process accompanied by chemical reac on.
Q.89 The nature of posi ve rays depend on:
A. Nature of discharge tube. ✓ B. Nature of resident gas.
C. Nature of electrode. D. All of above.
Q.90 In the presence of magne c field, d-sub-shell is
✓ A. 5 - fold degenerate B. 3 - fold degenerate
_______________________________________________________________________________________
C. 7 - fold degenerate D. Non - degenerate
Q.91 If coefficients of a chemical equa on are double , the enthalpy change will:
A. be half ✓ B. be double
C. not change D. none of all above
Q.92 Bohr's model of atom explains spectrum of:
A. H like species only B. H atom only
✓ C. H and H like species D. None of aove
Q.93 The quantum number that specifies the way the orbital is oriented in space is
A. Electron spin quantum number B. Angular momentum quantum number
✓ C. Magne c quantum number D. Principle quantum number
Q.94 An element with electronic configura on 1s2,2s2,2p6,3s2is
✓ A. metal B. non-metal
C. inert gas D. a liquid
Q.95 The number of orbitals in d sub shell is
A. 1 B. 3
C. 4 ✓ D. 5
Q.96 Point out the orbitals which are degenerate in a mul electron atom
A. 1s, 2s orbitals B. 2d orbitals
C. 3s, 3p, 3d orbitals ✓ D. 3d orbitals
Q.97 Which element will lose electrons most easily?
A. B B. F
C. Cl ✓ D. K
Q.98 Paschen, Pfund and Bracke series are found in
A. uv region B. visible region
✓ C. ir region D. none of these
Q.99 The wave number of the light emi ed by a certain source is 2 x 106m. The wavelength of this light is
✓ A. 500 nm B. 500 m
C. 200 nm D. 5 x 107m
Q.100 In the ground state of an atom, the electron is present
A. In the nucleus B. In the second shell
✓ C. Nearest to the nucleus D. Farthest from the nucleus
Q.101 The charge of an electron is determined by
A. J.J Thomson B. Crooks
C. Perrin ✓ D. R.A Millikan
Q.102 Which of the following statement is not correct for an electron that has the quantum numbers n = 4 and m = 2?
A. The electron may have the quantum number s B. The electron may have the quantum number l
= +1/2 =2
C. The electron may have the quantum number l ✓ D. The electron may have the quantum number
=3 l =0, 1, 2, 3
Q.103 The reason of kine c energy of the molecules of a gaseous substance among the following is:
A. rota on mo on B. vibra onal mo on
C. transla onal mo on ✓ D. the sum of all mo ons which are possible
Q.104 The total values of magne c quantum number of subshell are five, the subshell is
A. s-subshell B. p-subshell
✓ C. d-subshell D. f-subshell
Q.105 Which of the following has the highest energy
A. X-rays ✓ B. Gamma rays
C. Radio waves D. Ultra-violet radia ons
Q.106 Choose the S.i unit for molar heat capacity among the following:
✓ A. joule deg-1mol-1 B. joule deg-1kg-1
C. joule cm-3deg-1 D. joule deg-1atomh
_______________________________________________________________________________________
Q.107 Magne c quantum number is related to
A. shape B. size
✓ C. orienta on D. spin
Q.108 Lyman series lie in:
A. Visible region B. Radio-wave region
C. Infrared region ✓ D. Ultraviolet region
Q.109 Which of the following values of heat of forma on indicates that the product is most stabel
A. -97 kj ✓ B. -231.6 kj
C. +21.4 kj D. +70 kj
Q.110 An endothermic reac on is one in which
A. Heat is converted into electricity ✓ B. Heat is absorbed
C. Heat is evolved D. Heat is converted into mechanical work.
Q.111 The principle quantum number describes
✓ A. the distance form the nucleus B. the shape of the orbital
C. the orienta on of the orbital D. the spin of the electron
Q.112 For a system in equilibrium,Δ G = 0, under condi ons of constant
✓ A. Temperature and pressure B. Temperature and volume
C. Pressure and volume D. Energy and volume
Q.113 Which orbital of the following has a principal quantum of 3 and an angular momentum quantum number of 27
A. 3f ✓ B. 3d
C. 4f D. 3s
Q.114 Which of the following is not a property of cathode rays. These rays
✓ A. Comprise neutron par cles B. Can produce X-rays when they strike a heavy
metal anode
C. Can cause reduc on reac on D. Produce fluorescence in rare earth and
mineral
Q.115 Sublima on vaporiza on mel ng and photosynthesis all are examples of
A. Chemical processes B. Physical processes
C. Biochemical processes ✓ D. Endothermic processes
Q.116 Which quantum number describe the energy of electron
A. s B. m
C. l ✓ D. n
Q.117 Shape of an orbital is determined by
A. spin quantum number ✓ B. azimuthal quantum number
C. magne c quantum number D. principle quantum number
Q.118 What would be the heat released when an aqueous solu on containing 0.5 mol of HNO3 is mixed with 0.3 mol of OH-
(enthalpy of neutraliza on is -57.1 kJ)
A. 28.5 kJ ✓ B. 17.1 kJ
C. 45.7 kJ D. 1.7 kJ
Q.119 Posi ve par cles in discharged tube is produced by ioniza on of gas molecules which is caused by
A. Gas molecules collide with anode B. Gas molecules are at high temperature
✓ C. Cathode rays remove the electrons from gas D. Gas molecules produce X-rays
molecules
Q.120 The law of lavoisier and Laplace illustrates
✓ A. The principle of conserva on of energy. B. Equivalence of mechanical and thermal
energy
C. The principle of conserva on of ma er D. Equivalent of mechanical and chemical energy
Q.121 The nature of posi ve rays depends upon
A. The nature of electrode B. The nature of discharge tube
✓ C. The nature of residual gas D. All of the above
Q.122 Orbital having same energy are called:
✓ A. Degenerate orbitals B. d-orbitals
C. Hybrid orbitals D. Valence orbitals
_______________________________________________________________________________________
Q.123 The branch of science which deals with energy transforma on is known
as:
A. thermodynamics B. kine cs
✓ C. thermochemistry D. photochemistry
Q.124 When 50 cm3 of 0.2 n H2SO is mixed with 50 cm3 of 1 N KOH,the heat liberated is
A. 11.46 kJ B. 57.3 kJ
C. 573 kJ ✓ D. 573 J
Q.125 Colour of fluorescence produced in discharge tube depends upon
A. Gas present in discharge tube ✓ B. Composi on of glass
C. Nature of electrodes D. Nature of par cles
Q.126 Neutral was discovered by
✓ A. Chadwick B. Faraday
C. Newton D. Millikan
Q.127 Which of the following quantum number has nega ve quantum number value
A. Principle ✓ B. Magne c
C. Azimuthal D. Both b & c
Q.128 Total energy depends upon the state of system
A. free energy of reac on B. entropy of reac on
C. enthalpy ✓ D. all above
Q.129 Glow is produced due to
A. Electronic current ✓ B. Gas molecule
C. Anode D. Cathode
Q.130 The quantum number which describe the orienta on of the orbitals is
A. spin quantum number B. principle quantum number
C. azimathal quantum number ✓ D. magne c quantum number
Q.131 The most important factor in determining chemical behaviour of atom
A. Nuclear structure ✓ B. Electronic configura on
C. Atomic mass D. Solubility
Q.132 Which of the following statements is contrary to the first law of thermodynamics?
A. one equivalent amount of heat energy can B. one form of energy can be transferred into an
neither be created nor destroyed equivalent amount of other kinds of energy
C. in an adiaba c process the work done is ✓ D. con nuous produc on mechanical work
independent of its path without supplying an equivalence is amount
of heat possible
Q.133 The radia ons with wavelength shorter than violet light are called
✓ A. ultraviolet B. infrared
C. microwave D. radio frequency
Q.134 The range of visible spectrum is
A. 300 - 600 nm B. 600 - 900 nm
✓ C. 400 - 750 nm D. 100 - 300 nm
Q.135 The nature of the posi ve rays depend on
✓ A. the nature of the electrode B. the nature of the discharge tube
C. the nature of the residual gas D. all of the above
Q.136 Water exists in a solid liquid & gaseous state the least rendom state is in the form
✓ A. ice B. steam
C. liquid water D. equilibrium stage at ice mel ng
Q.137 Charge to mass ra o of electron was discovered by:
A. Millikan B. Rutherford
✓ C. J. J. Thomson D. Chadwick
Q.138 In a ca on the number of protons is more than the number of
✓ A. electron B. photons
C. positrons D. neutrons
_______________________________________________________________________________________
Q.139 In thermodynamics which one of the following is not an intensive property?
A. Pressure B. Density
✓ C. Volume D. Temperature
Q.140 A system absorbs 500 kj heats and performs 250 kj work on the surrounding the increase in internal energy of the
system is
A. 750 kj B. 500 kj
✓ C. 250 kj D. 1000 kj
Q.141 The rules which describes the distribu on of electron in atomic energy level are Au a's principle, Hund's rule and
pauli exclusion principle. The Pauli exclusion principle refers to the
✓ A. Energy of the orbital B. Orienta on of the orbital in space
C. Spin of the electron D. The fact that two electron in the same orbital
should have opposite spins
Q.142 Point out the unit which does not belong to wave number?
A. mm-1 B. cm-1
✓ C. cm D. dm-1
Q.143 The bond dissocia on energies of H2,CL2 and NCI are 104, 58 and 103 kcal respec vely.The enthalpy of forma on of
HCI gas will be
A. -44 kcal B. -88 kcal
✓ C. -22 kcal D. -11 kcal
Q.144 The electrons are put in energy sub-levels in the order of increasing energy values. This is a statement of
A. Hundus rule ✓ B. A au principle
C. Pauli exclusion principle D. Phase rule
Q.145 The apparatus used to measure the enthalpy of combus on of a substance, is:
A. glass calorimeter B. copper calorimeter
✓ C. bomb calorimeter D. all above
Q.146 In the ground state of an atom, the electron is present:
A. In the nucleus. B. In the second shell.
✓ C. Nearest to the nucleus. D. Farthest from the nucleus.
Q.147 Spli ng of spectral lines of the hydrogen atom under the influence of magne c field is called
A. stark effect ✓ B. zeeman effect
C. Compton effect D. photoelectric effect
Q.148 The branch of chemistry which deals with the heat changes caused by chemical resec ons is called
A. Thermodynamics B. Thermal chemistry
✓ C. Thermo chemistry D. Analy cal chemistry
Q.149 In ground state which element has one unpaired electrons?
A. helium ✓ B. hydrogen
C. carbon D. oxygen
Q.150 Which substance have ΔE = ΔH and no pressure volume work
A. Liquids only B. Solids only
C. Gases only ✓ D. Liquid and solids
Q.151 Nega ve charge par cle nature of cathode rays was first demonstrated in 1895 by:
A. Millikan ✓ B. J. Perrin
C. Hi rof D. J. J. Thomson
Q.152 E = hv is the
A. Spectral equa on ✓ B. Plank's equa on
C. de Broglie's equa on D. Heisenburg's equa on
Q.153 Spin quantum number may be
A. 0 B. 1
✓ C. 2 D. None
Q.154 When 3p orbital is complete, the entering electron goes into
✓ A. 4s B. 3d
_______________________________________________________________________________________
C. 4p D. 4f
Q.155 3d orbital has the quantum number values
A. n=3l=3 ✓ B. n=3l=2
C. n=3l=1 D. n=3l=0
Q.156 The unit ergs joule and calorie are inter-conver ble which of following is incorrect
A. 107 rgs = 1j B. 4.184j = 1 cal
C. 1 j = 0.2390 cal ✓ D. 1 erg = 4.184 cal
Q.157 When 6s orbital is complete then next electron goes to
A. 6p B. 6d
C. 5d ✓ D. 4f
Q.158 A proton is quite iden cal to
A. Alpha par cle ✓ B. Ionized hydrogen
C. Hydroxonium ion D. Ionized Hydrogen molecule
Q.159 The e/m value for posi ve rays is maximum:
A. Oxygen B. Nitrogen
C. Helium ✓ D. Hydrogen
Q.160 The standard enthalpy changes of forma on of HCI and Hi and -92 kj lmol-1 and +26 kj mol-1 respec vely. which
statement is most important in eexplainig this difference?
A. chlorine is more electronega ve than iodine B. the ac va on reac on is much less
2/Cl2 2/l2
energy for the H than that for the H
✓ C. The bond energy of HI is smaller than the D. the bond
2
is smaller than the bond
2
bond energy of HCI energy of l energy of Cl
Q.161 The heat change or (enthalpy change) when one mole of a solid substance is converted into the liquid state at its is
called heat of fusion
✓ A. Mel ng point B. Boiling point
C. Freezing point D. Evapora on point
Q.162 The arrangement of subshells in the ascending order of their energy on complete filling of 4f subshell the entering
electron goes to
A. 5s B. 5p
✓ C. 5d D. 5f
Q.163 Which is the units of length
✓ A. Angstrom B. Poise
C. H D. None
Q.164 The correct rela on between internal energy change, enthalpy change and work is:
A. ΔH = ΔE - W B. ΔH = W + ΔH
✓ C. ΔH = ΔE + W D. ΔE = ΔH - W = 0
Q.165 All of the following elements are correct for atomic orbitals except
A. s-orbital has spherical shape B. p-sub energy level has 3 orbitals
✓ C. All d orbitals have four lobes D. 4s has less energy than that of 4d
Q.166 The nit heat change in a chemical reac on is same whether it is brought about in tow or ,ore different ways in one or
several steps .it is known as:
A. Henry,s law ✓ B. Hess,s law
C. joule,s principal D. law of conserva on of energy
Q.167 Spli ng of spectral lines when atoms are subjected to strong electric field is called:
A. Photoelectric effect ✓ B. Stark's effect
C. Compton's effect D. Zeeman's reffect
Q.168 In region in space, around the nucleus in an atom, where the probability of finding an electron is maximum is called.
✓ A. An orbital B. An orbit
C. A shell D. A wave
Q.169 The set of orbitals having n + l = 5 are
A. 2p, 3d, 3s B. 3s, 4p, 4d
C. 3p, 3d, 5s ✓ D. 5s, 4p, 3d
_______________________________________________________________________________________
Q.170 Electron behaves like
A. waves B. par cle
✓ C. wave and par cle D. none of these
Q.171 In planer d-orbitals the maximum probability of finding electrons is at
A. 0° ✓ B. 45°
C. 90° D. 180°
Q.172 Which of the following orbitals is not possible?
A. 1s ✓ B. 2d
C. 4s D. 3p
Q.173 Indicate the correct order of sub shell w.r.t decreasing energy
A. S>p>d>f B. p>s>f>d
✓ C. f>d>p>s D. d>f>s>p
Q.174 Thermodynamics is concerned with
A. Total energy of a system B. Rate of a chemical change
✓ C. Energy changes in a system D. Mass changes in nuclear reac ons
Q.175 If I = 2 then the orbital will be _______ orbital
A. s B. p
✓ C. d D. f
Q.176 Chlorine atom has set of n, l, m quantum number for the nupaired electrons
A. 2, 1, 1 ✓ B. 3, 1, 1
C. 2, 1, 0 D. 3, 0, 0
Q.177 Posi ve rays produce in discharge tube from
A. Electricity ✓ B. Gas molecule
C. Anode D. Cathode
Q.178 Enthalpy of an exothermic reac on is always
C. Zero D. May be posi ve or nega ve
Q.179 e/m value of posi ve rays is maximum for gas
✓ A. Hydrogen B. Helium
C. Nitrogen D. Oxygen
Q.180 When atom is in the ground state, the electron is present
✓ A. Nearest to the nucleus B. Nearest to the valence shell
C. In the second shell D. In the nucleus
Q.181 Which of the following par cles has longest wavelength, if they have same speed:
A. Proton B. Neutron
✓ C. Electron D. Positron
Q.182 The S.I unit of heat and energy is;
✓ A. wa B. calorie
C. joules D. none of all
Q.183 A chemist heated a balloon by supplying 600 J of heat, The balloon expands doing 200 J of work against the
atmospheric pressure. The change in internal energy of:
A. = - k719 B. --400J
C. 0J ✓ D. = + K 319
Q.184 In the atomic emission spectrum the lines which appear bright, appear dark in absorp on spectrum because
✓ A. the radia ons emi ed in emission spectrum B. atomic emission spectrum is con nuous
are absorbed in absorp on spectrum
C. atomic absorp on spectrum is con nuous
D. distance between the lines increases
Q.185 Their e/m, ra o resembles with that of electrons
A. Alpha rays ✓ B. Beta rays
C. Gamma rays D. X-rays
_______________________________________________________________________________________
Q.186 Spontaneous reac ons are those which:
A. are endothermic B. are exothermic
C. require ac va on energy ✓ D. con nue to occur once started
Q.187 The radius of first orbit of hydrogen atom
✓ A. 0.329A° B. 0.429A°
C. 0.529A° D. 0.229A°
Q.188 When the electron jumps form second third, fourth orbit to the first orbit, the transi ons are known as
A. Balmer series ✓ B. Lyman series
C. Pfund series D. bracke series
A. Zeeman effect. ✓ B. Stark effect.
C. Photoelectric effect. D. Compton effect.
Q.190 Milikan determined the charge on electron in oil drop experiment. It value is
A. 6.625 x 10-34C B. 1.602 x 1023C
C. 1.602 x 10-23C ✓ D. 1.602 x 10-19C
Q.191 Heat of reac on when one mole of nitrogen combines with one mole of oxygen to yield nitrogen oxide is
A. +285.58 kj / mol B. -41.6 kj / mole
✓ C. +180.51 kj / mole D. -393.7 kj / mole
Q.192 In an exothermic reac on the internal energy of the products is internal energy of reac ons
A. Greater than ✓ B. Lesser than
C. Equal than D. None of these
Q.193 Heat of neutraliza on of an acid with a base is 13.7 kcal when
A. Both acid and base are weak B. Acid is strong and base is weak
C. Acid is weak and base is strong ✓ D. Both acid and base are strong
Q.194 The size of electronic shell is described by
A. azimuthal Q.No B. magne c Q.No
C. spin Q.No ✓ D. principal Q.No
Q.195 At constant pressure heat of reac on is represented by
✓ A. ΔH B. ΔE
C. ΔP D. ΔV
Q.196 The possible number of orbitals in level with n = 3 is
A. 1 ✓ B. 3
C. 4 D. 9
Q.197 System in which there is no exchange of ma er,work or energy from surroundings
A. Closed ✓ B. Isolated
C. Adiaba c D. Isothermal
Q.198 The maximum number of electrons in a sub-shell is given by the expression
✓ A. 4l + 2 B. 4l - 2
C. 2l + 1 D. 2n2
Q.199 The charge over mass ra o of electron is:
A. 1.6 x 10-1C Kg-1 B. 9.1 x 10-31C
✓ C. 10
1.7588 x 10 C Kg D. 6.62 x 10-34C Kg-1
Q.200 For a reac on to occur spontaneously
✓ A. Δ H must be nega ve B. Δ H must be posi ve
C. Δ H must be zero D. Δ H must be unity
Q.201 The number of d-electrons in Fe (z = 26) is not equal to
A. p-electrons in Ne (Z = 10) B. s-electrons in Mg (Z = 12)
C. s-electrons in Ca (Z = 20) ✓ D. p-electrons in Cl (Z = 17)
Q.202 Mass of electron
A. 1.6022 x 10-19Kg B. 1.6022 x 10-19g
_______________________________________________________________________________________
✓ C. 9.10 x 10-31Kg D. 9.10 x 10-31g
Q.203 Calorie is equivalent to:
A. 104184 J B. 41.84 J
✓ C. 4.184 J D. 418.4 J
Q.204 Velocity of photon is
✓ A. Independent of wavelength B. Depend on source
C. Depend on wavelength D. Equal to square of amplitude
Q.205 If uncertainty in posi on of electron is zero, the uncertainty in its momentum would be:
A. Also zero B. 50%
C. Less than zero ✓ D. Infinite
Q.206 bring of coal in air is ini ated by spark and it is an example of spontaneous reac on because:
A. bring of coal is and endothermic process ✓ B. bring of coal in air releases large amount of
energy
C. coal and air react giving a reversible reac on D. none of these
Q.207 When water is added to quick lime,the reac on is
A. Explosive B. Endothermic
✓ C. Exothermic D. Photochemical
Q.208 Charge of electron was measured by
A. J. J. Thomson ✓ B. Millikan
C. Rutherford D. Perrin
Q.209 Bohr model of atom is contradicted by:
A. Planck's quantum theory. B. Pauli's exclusion theory.
✓ C. Heisenberg's uncertainty principle. D. All of above.
Q.210 The ra o of e/m values of a proton and anα- par cal is
✓ A. 2:1 B. 1:1
C. 1:2 D. 1:4
Q.211 kine c energy of molecules is due to:
A. vibra on mo on B. transla onal mo on
C. rota onal mo on ✓ D. all of above
Q.212 Rutherford's model of atom failed because:
A. The atom did not have a nucleus and B. It did not account for the a rac on between
electrons. protons and neutrons.
✓ C. It did not account for the stability of the D. There is actually no space between the
atom. nucleus and the electrons.
Q.213 Which of the following is not a property of cathode rays
A. they can produce x-rays when they strike a B. they can cause reduc on reac on
heavy metal anode
C. they produce fluorescences in rare earth and
minerals
✓ D. they comprise neutral par cles
Q.214 The energy required to break 1 mole of bonds of from neutral atom is:
A. bond energy B. bond strength
C. bonds length ✓ D. nine of all
Q.215 The amount of heat evolved or absorbed in a chemical reac on when represented in a chemical equa on is called:
A. entropy of a reac on B. free energy of reac on
✓ C. heat of reac on D. none of above
Q.216 Proton was discovered by:
A. Chadwick B. J. J. Thomson
C. Millikan ✓ D. Goldstein
Q.217 Which are not electromagne c radia ons
A. X-rays ✓ B. Sound waves
C. Proton D. Radio waves
Q.218 Which of the following is not the property of spontaneous process
_______________________________________________________________________________________
A. Uni-direc onal B. Natural process
C. Real process ✓ D. All spontaneous process are exothermic
Q.219 Which one of followintg is not spontaneous process?
A. neutraliza on of strong acid with strong base B. flow of water from higher to lower level
C. when a piece of Zn is added to blue copper ✓ D. forma on of nitric oxide
2O 2
at room
sulphate solu on the colour disappears: NO form N temperature
Q.220 Orbitals having same enrgy are called
A. Hybrid orbitals B. Valence orbitals
✓ C. Degenerate orbitals D. D-orbitals
Q.221 For an exothermic reac on the sigh of enthalpy will be :
A. zero ✓ B. nega ve
C. posi ve D. none of these
Q.222 A cylinder of gas supplied by PSO is assumed to contain 14 kg of butane.If a normal family requires 20,000 kJ of energy
per day for cooking butane gas in the cylinder last for .....days (Δ Hc of C4H10 = -2658 kJ per mole)
A. 15 days B. 20 days
C. 50 days ✓ D. 32 days
Q.223 An alpha par cle is a
A. neutron B. photon
✓ C. hellium nucleus D. electrons
Q.224 Rutherford's planetary like picture of the atomic modal was defec ve because
A. it did not describe the quan ty of posi ve B. it did not explain the repulsion of protons
charge within the nucleus
C. no empty space between nucleus and the ✓ D. moving electron should radiate energy
electrons con nuously decreasing its orbit
Q.225 The number of electrons in a given sub shell is given by formula
A. 2n2 B. 2l + 1
C. 2(2l - 1) ✓ D. 2(2l + 1)
Q.226 Hess's law deals with
✓ A. Changes in heat or reac on B. Rate of reac on
C. Equilibrium constant D. Influence of pressure on volume of a gas.
Q.227 P-fund, Bracket and paschen series lie in:
✓ A. Infrared region B. Ultra violent region
C. Visible region D. Microwave region
Q.228 The experimental evidences for the existence of atomic nucleus comes from:
A. Line spectrum of hydrogen. B. Magne c bonding of cathode rays.
C. Millikan oil drop experiment. ✓ D. Sca ering of alpha par cles by thin metal
foil.
Q.229 The wave length of electron as wave is 0.5 nm. What is the wave length in meter
A. 5 x 10-9 B. 5 x 10-12
C. 5 x 10-6 ✓ D. 5 x 10-10
Q.230 Value of e/m ra o of electron is (C Kg-1)
A. 6.02 x 1023 B. 1.7588 x 1020
C. 9.1095 x 10-31 ✓ D. 1.7588 x 1011
Q.231 Charge of an electron is:
✓ A. 1.6 x 10-19C B. 9.1 x 10-34C
-11
C. 1.7588 x 10 C D. 6.62 x 10-34C
Q.232 The heat of combus on of C(graphite) is -393.5 kj mol-1 The heat of forma on of CO2 from graphite is kj mole-1
A. 393.5 B. -787.0
✓ C. -393.5 D. 787.0
Q.233 1 mole of H2SO4 is mixed with 2 moles of NaOH.The heat evolved will be
✓ A. 57.3 kJ B. 2 x 57.3 kJ
C. 57.3/2 kJ D. Cannot be predicted
_______________________________________________________________________________________
Q.234 When 6 orbital is complete, entering electron goes into:
A. 7d B. 7f
C. 7s ✓ D. 7p
Q.235 Generally first ioniza on energy increases across a period. The first ioniza on energy of N is higher than that of O. The
reason for that is
A. the a rac ve force from the nucleus per ✓ B. the electron pair in one of the p orbitals of O
electron is higher in N creates a high energy system,decreasing the
energy required to ionize
C. in oxygen the further shield the valence D. N has smaller atomic radius
2 electrons in xelectrons thus the ioniza on
2P energy is lower
Q.236 Amount of heat evolved when one mole of a substance is completely burnt in excess of oxygen under standard
condi ons is called
A. Enthalpy of neutraliza on ✓ B. Enthalpy of combus on
C. Enthalpy of solu on D. Enthalpy of a miza on
Q.237 If volume of a system is kept constant and heat is supplied to the system then
✓ A. Internal energy of the system increases and B. Internal energy of the system increases and
no work is done on the surrounding work is done on the surrounding
C. No change in internal energy occurs D. No work is done on the surrounding
Q.238 The uncertainty principle was stated by
A. De Brogile ✓ B. Heinsenberg
C. Einstein D. Schrodinger
Q.239 For a given process the heat changes at constant pressure(qp) and at constant volume (qv)are related each other as:
A. qp= qv B. qp< qv
✓ C. qp> qv D. qp =qv/2
Q.240 The series of lines produced when electron falls from higher energy levels n2= 2,3,4,5, .......... to n1= 1 is called
A. Balmer series B. Paschen series
C. Pfund series ✓ D. Lyman series
Q.241 One mole of a an ideal gas expands isothermally to ten mes its original volume.The change in entropy is
A. 0.1 R ✓ B. 2.303 R
C. 10.0 R D. 100.0 R
Q.242 Cathode rays drive a small paddle wheel placed in their path. This observa on shows that
A. cathode rays travel in straight lines B. cathode rays are nega vely charged
C. cathode rays produce X-rays ✓ D. cathode rays are material par cles having
momentum
Q.243 Which atomic orbital has lowest energy?
A. 7s B. 6p
C. 5d ✓ D. 4f
Q.244 With the reference of e/m ra o of anode rays, the e/m ra o of cathode rays is:
✓ A. Greater B. Same
C. Smaller D. Not fixed
Q.245 Quantum numbers are derived from
✓ A. Schrodinger wave equa on B. De-Broglie's equa on
C. Bragg's equa on D. Planck's equa on
Q.246 The value of R (Rydberg's constant) is _____________ m-1
✓ A. 1.0974 x 107 B. 1.0842 x 107
C. 1.082 x 10-7 D. Both a and b
Q.247 The maximum number of electrons in a sub-shell with I=3 is
A. 6 B. 10
✓ C. 14 D. 18
Q.248 The total number of electrons in one Te2-ion (Atomic No = 52)
✓ A. 54 B. 50
C. 52 D. 53
_______________________________________________________________________________________
Q.249 Mechanical work is specially important in systems that contain
A. Solid-liquid B. Liquid-liquid
C. Solid-solid ✓ D. Gases
Q.250 Lyman series lies in
✓ A. UV region B. visible region
C. I R region D. microwave region
Q.251 Heat is a form of energy & has the unit of :
A. degree & calorie B. degree & joule
C. degree & ergs ✓ D. calorie & joule
Q.252 Four containers holds the following quan ty at the same temperature which one has the highest heat capacity?
✓ A. 4 kg H2O B. 3 kg H2O
C. 2 kg H2O D. 1 kg H2O
Q.253 The degenerate orbitals p-sub shell are
A. 2 ✓ B. 3
C. 5 D. 7
Q.254 The atomic radii of elements lie in the order of
A. 108cm B. 10-12cm
✓ C. 10-8cm D. 1012cm
Q.255 Which of the followings is not charged par cle
A. proton B. electron
✓ C. neutron D. hydrogen nucleus
Q.256 Sublima on, vaporiza on mel ng and photosynthesis all are examples of:
A. physical process B. chemical process
✓ C. endothermic process D. biochemical process
Q.257 f-orbital has maximum number of electrons
A. 10 B. 6
C. 2 ✓ D. 14
Q.258 ΔH Neutralisa on is always
C. Zero D. Posi ve or nega ve
Q.259 Neutron was discovered by:
✓ A. Chadwich B. Bohr
C. Rutherford D. Plank
Q.260 Why does the exothermic reac on
C(diamond)------->C(graphite)
not occur spontaneously? ΔH=-3kJ mol-1
A. A tetrahedral configura on is always more B. Diamond has only strong covalent bonds
stable than a planar one whereas graphite has both covalent bonds
and van der Waal's forces.
✓ C. The change from diamond to graphite has a D. The density of grphite is less than that of
high ac va on energy. diamond
Q.261 What is the value of n+l (principle and Azimuthal quantum numbers) for 3rd orbital?
A. 6 B. 3
C. 4 ✓ D. 5
Q.262 Neutraliza on of strong acid with a strong base is:
✓ A. spontaneous reac on B. reversible reac on
C. non-spontaneous reac on D. chemical equilibrium
Q.263 The quantum number which describes the shape of an orbital is called
A. principle quantum number ✓ B. azimuthal quantum number
C. magne c quantum number D. spin quantum number
Q.264 In general, for exothermic reac ons to be spontaneous
A. Temperature should be high B. Temperature should be zero
✓ C. Temperature should be low D. Temperature has no effect
_______________________________________________________________________________________
Q.265 Which of the following series lines in the atomic emmision spectrum of hydrogen is in the visible region:
A. Paschen B. Bracket series
✓ C. Balmer series D. Lyman series
Q.266 Arrangement of the fundament par cles within an atom determines its
A. physical proper es B. chemical proper es
✓ C. physical and chemical proper es D. no proper es
Q.267 Charge to mass ra o (e/m) of the electron is determined by
✓ A. R.A Millikan B. J.J Thompson
C. G.J Stoney D. None of these
Q.268 Elements with ______ first ioniza on energies and ______ electron affini es generally form ca ons. Choose the
correct point
✓ A. Low, posi ve or slightly nega ve B. High, very nega ve
C. Low, very nega ve D. High, posi ve or slightly nega ve
Q.269 C (diamond) → C(Graphite),ΔH = -ve.This show that
✓ A. Graphite is more stable than diamond B. Graphite has more energy than diamond
C. Both are equally stable D. Stability cannot to predicted
Q.270 A calorimeter is an instrument used for the measurement of:
A. heat of forma on B. heat of vaporiza on
C. heat of combus on ✓ D. heat of reac on
Q.271 The radius of the second orbit is
A. 2.11 x 10-11m B. 1.006 A°
✓ C. 2.1A° D. 2.11 x 10-12m
Q.272 Which of the following is an endothermic reac on
A. 2H2(g)+ O2(g) → 2H2O(e) ✓ B. N2(g)+O2(g)→ 2NO(g)
C. NaOH(aq)+ HCI(aq) → NaCi(aq)+ H2O(e) D. C2H5OH(aq)+ 3O2(g) → 2CO2(g)+ 3H2O(e)
Q.273 A par cular reac on has a nega ve value for the energy change.Then at ordinary temperature
A. It has a large -ve value for the entropy change B.
It has a large +ve value for enthalpy change
C. It has small +ve value for enthalpy change ✓ D.
It has a +ve value for the entropy change and
a -ve value for the enthalpy change.
Q.274 By conven on the standard heat of forma on of all compound is assumed to be
✓ A. Zero B. Nega ve
C. Posi ve D. Infinity
Q.275 The divisibility of atom was shown by
A. Stoney ✓ B. J.J Thomson
C. Millikan D. Rutherford
Q.276 Maximum number of electrons can accommodate in N shell
A. 2 B. 8
C. 18 ✓ D. 32
Q.277 Which orbital has lowest energy?
A. 3d B. 4s
✓ C. 3p D. 4f
Q.278 The unite which indicates the largest amount of energy is;
A. joule B. electron-volt
✓ C. calorie D. erg
Q.279 Orbital having energy is called:
A. hybrid orbital. B. Valence orbital.
✓ C. Degenerate orbital. D. D-orbital.
Q.280 No cathode rays are produced in the discharge tube when gas is under ordinary pressure even if voltage of 5000 to
10000 is applied. The reason is
A. voltage is low B. discharge tube is not coloured
✓ C. gas does not conduct current under ordinary D. temperature low
_______________________________________________________________________________________
pressure
Q.281 Anode is the surface on which probability of finding electron is:
A. 50% B. Less then 10%
C. More then 95% ✓ D. Zero
Q.282 Light emi ed from a source has its wave length 500 nm, then its wave number will be
✓ A. 2 x 106m-1 B. 2 x 107m-1
8 -1
C. 5 x 10 m D. 5 x 109m-1
Q.283 The value of charge on electron is
✓ A. 1.602 x 10-19coulombs B. 1.602 x 10-18coulombs
C. 1.602 x 10-17coulombs D. 1.602 x 10-16coulombs
Q.284 Thermochemistry is the study of chemical reac on accompanying
A. Mass change B. rate change
✓ C. heat change D. vol change
Q.285 The region around the nucleus where the probability of finding the electron is maximum is known as
A. shell B. orbit
C. energy level ✓ D. orbital
Q.286 Bohr's model of atom is contradicted by
A. Planck quantum theory B. Pauli's exclusion principle
✓ C. Heisenberg's uncertainty principle D. all of the above
Q.287 Total number of orbitals in a shell having principle quantum number n is
A. 2n ✓ B. n2
C. 2n2 D. ( n + 1)
Q.288 In an exothermic reac on ΔH is
A. Posi ve B. Zero
✓ C. Nega ve D. May be posi ve or nega ve
Q.289 The change is enthalpy that takes place when one mole of the compound is formed from its elements is called
A. Heat of forma on of compound B. Heat of synthesis
C. Heat of combus on ✓ D. Standard heat of forma on
Q.290 In Millikan oil-drop experiment, the charges on several different oil drops were as: -5.92, -4.44, -2.96, -8.88. The units
are orbitrary. Choose the likely value of the electronic charge in these orbitrary units
A. -1.11 ✓ B. -1.48
C. -2.22 D. -2.96
Q.291 Orbitals having same energy are called
A. hybrid orbitals B. valence orbitals
✓ C. degenerate orbitals D. d-orbitals
Q.292 The process for the study of heat of combus on is carried out on bomb calorie mater at:
A. constant temperature B. constant pressure
✓ C. constant volume D. none of above
Q.293 Which of the following will have a completely filled d orbital on gaining 2 electrons?
A. Cu B. Fe
✓ C. Ni D. Co
Q.294 In which of the following change entropy decreases
✓ A. Crystalliza on of sucrose in water B. Mel ng of ice
C. Dissolving sucrose in water D. Vaporiza on of camphor
Q.295 The best characteris c is spontaneous reac ons among the following is that
A. it is reversible ✓ B. it is irreversible
C. it is not irreversible D. none of all above
Q.296 Enthalpy represents:
A. reac on rate ✓ B. heat content
C. ac va on energy D. energy state
_______________________________________________________________________________________
Q.297 Enthalpy of forma on of HF and HCI are - 161 kJ and -92 kJ respec vely.Which of the following statements is incorrect?
A. The affinity of fluorine to hydrogen is greater B. HF is more stable than HCI
than the affinity of chlorine to hydrogen
C. HCI is more stable than HF
✓ D. HF and HCI are endothermic compounds
Q.298 In the ground state of an atom the electron is present
A. In the nucleus B. In the second shell
✓ C. Nearest to the nucleus D. Farthest from the nucleus
Q.299 Arrange the elements, potassium, rubedium, calcium and barium in order of increasing atomic size
✓ A. Ca < k < Rb < Ba B. Ca < k Ba < Rb
C. k < Ca < Rb < Ba D. k < Ca < Ba < Rb
Q.300 Which one of the following statements is true about discovery of neutrons?
✓ A. These par cles were formed by the B. These par cles were Formed by the spli ng
bombardment of Alpha par cles on of Alpha par cles.
Beryllium. C. These par cles were discovered by natural
radioac vity.
D. None of above.
Q.301 Pauli exclusion principle states that no two electrons in a given orbital have
✓ A. Same for quantum number B. Same principal quantum number
C. Same Azimuthal quantum number D. (b) and (c) are correct.
Q.302 When cathode rays strike the anode metal, X-rays are emi ed and not he posi ve rays. The reason is that cathode rays
are
A. Heated B. Material par cles
C. Knocked out electrons from anode that emit ✓ D. Absorbed by the nucleus
X-rays when outer electrons take their place.
Q.303 The heat required to raise the temperature of a body by 1 K is called
A. Specific heat ✓ B. Thermal capacity
C. Water equivalent D. None of these
Q.304 Which rays are non-material in nature?
A. β-rays ✓ B. γ-rays
C. α-rays D. cathode rays
Q.305 When the electron jumps form third, fourth, fi h orbits to the second orbit, the transi ons are known as
A. Paschen B. Pfund
✓ C. Balmer D. Bracke
Q.306 Free energy change for a reversible process is:
A. >0 B. <0
✓ C. Equal to zero D. Unpredictable
Q.307 All of the following processes are spontaneous except
A. Reac on of H2with O2to from H2O B. Combus on of natural gas
C. Neitraliza on of HCI by NaOH ✓ D. Synthesis of glucose by plants
Q.308 Two electrons present in an orbital can be differen ated by
A. Principle quantum number ✓ B. Spin quantum number
C. Magne c quantum number D. Azimuthal quantum number
Q.309 An atom absorbs energy which results in the excita on of its electron, Before excita on the electron was is 2s orbital,
which orbital will the electron move to a er excita on?
A. 3p B. 1s
✓ C. 3s D. 4s
Q.310 The velocity of photon is
✓ A. Independent of its wavelength B. Depends on its wavelength
C. Equal to square D. Depends on its source
Q.311 Mel ng if ice at room temperature is:
✓ A. spontaneous endothermic process B. spontaneous exothermic process
C. non-spontaneous endothermic process D. non-spontaneous exothermic process
_______________________________________________________________________________________
Q.312 To predict whether a reac on will occur spontaneously or not it is necessary to study of the system
✓ A. Free energy B. Free heat
C. Work D. Enthalpy
Q.313 If the value of n = 4, the number of possible values of " l "
A. 2 B. 3
✓ C. 4 D. 5
Q.314 In order to decompose 9 g of water 142.5 kJ of heat is required.Hence enthalpy of forma on of water is
A. -142.5 kJ B. +142.5 kJ
✓ C. -285 kJ D. +285 kJ
Q.315 Energy of a photon is related to:
A. Wave number B. Wave length
C. Frequency ✓ D. All of above
Q.316 Balmer series lie in:
A. Radio-wave region ✓ B. Visible region
C. Ultraviolent region D. Infrared region
Q.317 Spherically symmetrical orbital is:
✓ A. s B. f
C. p D. d
Q.318 Greater the wave number of photons:
✓ A. Greater is the energy associated with them B. Smaller is the energy associated with them
C. Its energy will be variable D. Its energy will remain constant
Q.319 The set of quantum numbers which represents the highest energy of an electrons
A. n = 3, l = 1, m = 1, s = +1/2 B. n = 3, l = 2, m = 1 , s = +1/2
C. n = 4, l = 0, m = 0, s = +1/2 ✓ D. n = 4, l = 3, m = +1, s = 0
Q.320 The arrangement of sodium, oxygen, fluorene and stron um on the basis of increasing first ioniza on energy is
A. Na < Sr < O < F B. Na < Sr < F < O
✓ C. Sr < Na < O < F D. Sr < Na < F < O
Q.321 The sunlight shows the type of a:
A. Lines absorp on spectrum B. Line emission spectrum
✓ C. Con nuous spectrum D. Band spectrum
Q.322 Electronic configura on of K
✓ A. [Ar] 4s1 B. [Ar] 3s1
1
C. [Kr] 4s D. [He] 2s1
Q.323 The values of quantum number for the valence electrons of an atom are give by n = 2, l = 1, m= 0, +1, -1, s = +1/2 The
given atom is
A. Lithium B. Berylium
C. Carbon ✓ D. Boron
Q.324 Free neutron decay into proton and emit
A. Energy B. Positron
✓ C. Electron D. Meson
Q.325 Which of the following has largest ioniza on energy
✓ A. F B. O
C. Na D. Mg
Q.326 Neutron was discovered by
A. Mosely B. Milliken
✓ C. Chadwick D. Rutherford
Q.327 Given that
(i) C + O2 → CO2; ΔH = -xkJ
(ii) 2CO + O2 → 2CO2; ΔH = -ykJ
The enthalpy of forma on of carbon monoxide will be
A. Y - 2x B. 2x - y/2
_______________________________________________________________________________________
✓ C. y - 2x /2 D. 2x - y
Q.328 Choose the correct statement about 2nd ioniza on energy
A. It is equal to the 1st ioniza on energy B. Is is always less than 1st ioniza on energy
C. It may be greater or less than 1st ioniza on ✓ D. It is always greater than 1st ioniza on energy
depending upon the nature of the element
Q.329 All of the following are state func on except:
A. V ✓ B. q
C. H D. P
Q.330 n + l value for 4f will
A. 2 B. 5
✓ C. 7 D. 9
Q.331 The maximum number of electrons in d-orbitals is
A. 6 B. 8
C. 12 ✓ D. 10
Q.332 According to SI, system heat contents are measured in units of
A. ergs ✓ B. calorie
C. wa s D. joules
Q.333 The quantum number which describes the shape of the orbital is
A. principle quantum number B. spin quantum number
✓ C. azimathal quantum number D. magne c quantum number
Q.334 Cathode rays emi ed from cathode are
A. canal rays B. protons
✓ C. electrons D. positrons
Q.335 Choose the value of the Redberg's constant among the following among the following
✓ A. 1.09678 x 107m-1 B. 1.9678 x 107m-1
C. 1.697 x 107m-1 D. 1.007 x 107m-1
Q.336 Gases conduct electricity at
A. high pressure B. ordinary pressure
✓ C. low pressure D. normal pressure
Q.337 The change in heat energy of a chemical reac on at constant temperature an pressure is called:
✓ A. enthalpy change B. bond energy
C. heat of sublima on D. internal energy change
Q.338 An orbitals can accommodate maximum two electrons with opposite spins according to
A. Heisenberg's principle B. Auf Bau principle
C. Hund'srule ✓ D. Pauli exclusion principle
Q.339 "Electrons added to atomic orbitals of the same energy will remain unpaired with parallel spins un l the sub-shell is
more than half filled."
This statement belongs to
✓ A. Hund's rule B. Pauli exclusion principle
C. Au au principle D. Periodic law
Q.340 How many orbitals are allowed for principle quantum number (n) of 3?
A. 5 B. 6
C. 8 ✓ D. 9
Q.341 when 6d orbital is complete, the entering electron goes into:
A. 7f B. 7s
✓ C. 7p D. 7d
Q.342 All of the following chemical reac ons are endothermic except
A. H2O(s) → H2O(e) B. 2H2O(g) → 2H2(g)+ O2(g)
✓ C. H2O(g) → H2O(e) D. AI2O3+ 2Fe(s) → 2AI(s)+Fe2O3(s)
Q.343 Spli ng of spectral lines when atoms are subjected to strong electric field is called
✓ A. Zeeman effect B. Stark effect
_______________________________________________________________________________________
C. Photoelectric effect D. Compton effect
Q.344 For a 3P subshell the set of principal and azimuthal quantum numbers is
A. n = 1, I = 2 B. n = 3, I = 0
✓ C. n = 3, I = 1 D. n = 1, I = 3
Q.345 A mixture of ice and water contains 60g of ice and 60g of water. If 60 J of heat energy is removed from this mixture
some of the:
A. water will vaporize B. ice will melt
✓ C. water will freeze D. ice will sublime
Q.346 Alpha rays consist of:
A. Neutrons B. Helium Nucleus
✓ C. Protons D. Hydrogen Nucleus
Q.347 If an endothermic reac on is allowed to take place very rapidly in the air the temperature of the surrounding air:
A. remains constant B. increases
✓ C. decreases D. remains unchanged
Q.348 The rays which are produced by coliding of electron with heavy metals
A. Beta rays B. Alpha rays
C. Gamma rays ✓ D. X - rays
Q.349 According to the Au au principle the electrons and added first to the orbital:
A. In sub-levels of zero energy B. In sub-levels of highest energy
✓ C. In sub-levels oflowest energy D. of no shell
Q.350 The apparatus used to measure heat changes during chemical reac on is called
A. Polar meter B. Spectrometer
✓ C. Calorimeter D. Thermomerter
Q.351 The principle quantum number describes the
A. Shape of the orbital B. Spin of the electron
✓ C. Distance from the nucleus D. Orienta on from the orbital
Q.352 The amount of energy released when an electron is added to an atom in the gaseous state is called
A. ioniza on energy ✓ B. electron affinity
C. electronega vity D. bond energy
Q.353 Roentgen discovered X-rays and Mosley found that the frequency of the X-rays emi ed from anode increases with
A. Increases in the mass number of the metal ✓ B. Increases in the proton number of the metal
used as anode used as anode
C. Decreases in the mass number of the metal D. Decreases in the proton number of the metal
Q.354 Cathode rays drive a small paddle wheel placed in their path. The observa on indicates that
✓ A. Cathode rays are material par cles having B. Cathode rays are nega vely charged
momentum
C. Cathode rays produce X-rays
D. Cathode rays travel in straight line
Q.355 Schrodinger Wave equa on describes electron completely because
✓ A. it describes a set of four quantum number B. it describes the par cle nature of electron
C. it measures wavelength of electron D. it describes electron moving in specific orbit
Q.356 Which of the following value of ΔHf represent that the product is least stable?
A. -94.0 kcal mol-1 B. -231.6 kcal mol-1
C. +21.4 kcal mol -1 ✓ D. +64.8 kcal mol-1
Q.357 Consider the reac on,
C2H2(g) + 5/2 O2(g) -------->2CO2(g) + H2O(g)
The change in enthalpy of this reac on is called
✓ A. combus on of C2H2 B. vapouriza on of C2H2
C. forma on of CO2 D. fusion of C2H2
Q.358 Transi on from various energy levels to lowest energy level gives:
A. P-fund series ✓ B. Lyman series
C. Balmer series D. Paschen series
_______________________________________________________________________________________
Q.359 Select the arrangement of electromagne c radia on which starts with the lowest energy and increases tot eh highest
energy
✓ A. Microwave, Infrared, visible, ultraviolet B. Radio, visible, infrared, visible, ultraviolet
C. x-radia on, visible, infrared, microwave D. Visible, ultraviolet, infrared, gamma rays
Q.360 Which equa on represents the standard enthalpy change of atomisa on of bromine?
A. Br2(l)---> 2Br(g) B. Br2(g)---> 2Br(g)
✓ C. 1/2Br2(l)---> Br(g) D. 1/2Br2(g)---> Br(g)
Q.361 Posi ve rays give flash on screen
A. AgNO3 B. AgCl
✓ C. ZnS D. ZnO
Q.362 Which of the following enthalpy change is always endothermic
✓ A. ΔH°f B. ΔH°soln
C. ΔH°at D. ΔH°n
Q.363 Two electrons present in same orbital can be dis nguished by
A. Principle quantum number ✓ B. Spin quantum number
C. Azimuthal quantum number D. Magne c quantum number
Q.364 Maximum number of electrons that can be accommodated in a shell is given by:
A. Avogadro's number ✓ B. 2n2formula
C. Empirical formula D. Molecular formula
Q.365 Which have be er penetra ng power
A. Alpha rays B. Beta rays
✓ C. Gamma rays D. X-rays
Q.366 Spectrum of white light is con nuous because
A. colours separated by dark spaces ✓ B. there are no boundary lines between the
colours
C. the radia ons are in infared region D. the radia ons fall in ultraviolet region
Q.367 Quantum number value for 2p orbitals are:
✓ A. n = 2, I = 1 B. n = 1, I = 2
C. n = 1, I = 0 D. n = 2, I = 0
Q.368 Degenerated orbital in d sub shell
A. 1 B. 3
✓ C. 5 D. 7
Q.369 In endothermic reac ons the reactants
A. Have more energy than products B. Are at lower temperature than product
C. Have much energy as the products ✓ D. Have less energy than the products
Q.370 What is the order of increasing energy of listed orbitals in the atom of tanium?
A. 3s 3p 3d 4s ✓ B. 3s 3p 4s 3d
C. 1s 2s 2p 3s 3p 3d 4s D. 4s 3s 3p 3d
Q.371 When electron jumps from n2= 2, 3 ,4, 5, ....... orbit to n1= 1 orbit in the hydrogen atoms the radia ons emi ed give
the spectral lines
✓ A. Lyman series B. BIamer series
C. Paschen series D. Bracke series
Q.372 An oxygen atom has mass of
A. 16 g B. 5.316 x 1023g
✓ C. 2.657 x 10-23g D. 5.316 x 10-23g
Q.373 Heat exchanged in a chemical reac on at constant temperature and pressure is called
A. Entropy change ✓ B. Enthalpy change
C. Internal energy change D. Free energy change
Q.374 Which of the following has no effect on the ioniza on energy of an element?
A. the electrons in the completely filled inner B. the size of the posi ve nuclear charge
shells
✓C. shielding from the electrons belonging to
_______________________________________________________________________________________
same shell as that of e to be removed
D. distance of the electron to be removed from
the nucleus
Q.375 Which of the followings ins not a sub-atomic par cle
A. electron B. proton
C. neutron ✓ D. deuteron
Q.376 As the quantum number n increases, the energy difference between adjacent energy level.
✓ A. Decreases B. Increases
C. Remains fluctua ng D. Remains same
Q.377 Why is the second ioniza on energy of the higher than the first ioniza on energy?
A. the size of the ion decreases a er removal of B. the effec ve nuclear charge increases
an electron C. the distance of the valence electron from the
nucleus decreases
✓ D. all of the above
Q.378 An exothermic reac on is one in which the reac ng substances
✓ A. Have more energy than the products B.
Have less energy than the products
C. Have the same energy as the products D.
Are at a higher temperature than the
products.
Q.379 Maximum poten al energy that an electron can have within the atom is:
A. Equal to zero ✓ B. Less than zero
C. Greater than zero D. Infinite
Q.380 Pauli's principle is applicable to
A. Degenerate orbitals ✓ B. Two electrons in the same orbital
C. One electron D. None
Q.381 Which law among the following has same net change whether it takes place directly or indirectly?
A. Graham's law B. Boyle's law
C. Henry's law ✓ D. Hess's law
Q.382 Which of the following was discovered first:
✓ A. Charge to mass ra o of electrons B. Mass of electron
C. Charge of electron D. All of above at same me
Q.383 The amount of energy released when an isolated atom gains e to form an anion is called
A. ioniza on poten al B. electronega vely
✓ C. electron affinity D. free energy
Q.384 ΔH° represents the enthalpy change
A. At O°C and I atm pressure B. At 0K and i atm pressure
C. At 25K and I atm pressure ✓ D. None of these
Q.385 Radia on emi ed by excited atoms is
A. Nuclear radia ons B. Ultraviolet radia ons
✓ C. In the form of quanta D. In the form of con nuous waves
Q.386 Which of the following specie on loosing an electron, have a half-filled set of p-orbitals
A. C- ✓ B. O
C. N D. O+
Q.387 What is the entropy change (in JK-1 mol-1) when one mole of ice is converted into water at 0°C?(The enthalpy change
for the conversion of ice to liquid water is 6.0 kJ mol-1 at 0°C)
✓ A. 21.98 B. 20.13
C. 2.013 D. 2.198
Q.388 A gas with minimum charge to mass ra o, when cathode rays are passed through it
A. Hydrogen B. Oxygen
C. Nitrogen ✓ D. Chlorine
Q.389 Which of the following transi on in H-atom corresponds to absorp on line of highest frequency?
✓ A. n = 1 to n = 2 B. n = 3 to n = 4
C. n = 2 to n = 1 D. n = 2 to n = 3
_______________________________________________________________________________________
Q.390 ✓ A. heat is absorbed B. temperature increases
C. heat is evolved D. no change in heat contents takes place
Q.391 The wave number of light emi ed by a certain source is 2 x 106m-1. The wavelength of this light will be:
✓ A. 500 nm B. 500 m
C. 200 nm D. 5 x 107m
Q.392 Which of these compounds on complete of one mole will release the greatest amount of energy?
A. CH3CH2CH2OH B. CH3CH2CH3
✓ C. CH3CH2CO2H D. CH3COCH3
Q.393 Pressure in gas discharge tube to discover electrons was kept
C. 0.1 torr ✓ D. 0.01 torr
Q.394 The correct set of quantum number for the unpaired electron of Cl - atom is
A. 2, 0, 2, +1/2 B. 2, 1, -1, +1/2
✓ C. 3, 1, -1, +1/2 D. None of these
Q.395 e/m of cathode rays is same but for posi ve rays e/m changes by changing gas in the discharge tube because
A. cathode rays are small sized par cles B. cathode rays have same charge
✓ C. nature of cathode rays same for all gasses. D. temperature of cathode rays higher
but masses of nuclei are different for
different gases
Q.396 The velocity of photon is:
✓ A. Independent of its wavelength. B. Depends on its wavelength.
C. Equal to square of its amplitude. D. Depends on its source.
Q.397 Quan ty of heat evolved or absorbed during reac on measure according to;
✓ A. q =m x X x ΔT B. ΔH = ΔE + PΔV
C. ΔE = q + w D. PΔV+ nRT
Q.398 If Au au rule is not followed in filling of the sub-shells then the block of which will change in the periodic table
✓ A. K (19) B. Sc (21)
C. V (23) D. Ni (28)
Q.399 Which of the following is not correct?
A. Dissolu on CI in excess of water is an B. Neutralisa on is always exothermic
4
of NH endothermic process
✓ C. The absolute value of enthalpy (H) can be
determined experimentally.
D. The heat of reac on at constant volume is
denoted by ΔE.
Q.400 All the naturally occurring processes proceed spontaneously in a direc on which lead to
A. Decrease of entropy B. Increases of enthalpy
C. Increase of free energy ✓ D. Decrease of free energy
Q.401 The heat of the neutraliza on of any strong acid and strong base is always constant and ΔH = -57.3kj This is because
A. Both the acid and base undergo complete ✓ B. During neutraliza on salt and water are
ioniza on formed
C. I mole of water is formed for H+and OH-ions D. The reac on is exothermic
Q.402 Greater than wavelength Associated with the photon:
A. Greater is its energy ✓ B. Smaller is its energy
C. Its energy will be variable D. Its energy will remain constant
Q.403 The nature of posi ve rays depend on:
A. The nature of electrode. B. The nature of discharge tube.
✓ C. The nature of residual gas. D. All of above.
Q.404 Which element has high the highest first ioniza on energy value?
A. Li B. Be
C. B ✓ D. C
Q.405 When enthalpy and entropy change for a chemical reac on are -2.5 x 103 cals and 7.4 cals deg-1 respec vely.Predict
that reac on at 298 K is
✓ A. Spontaneous B. Reversible
_______________________________________________________________________________________
C. Irreversible D. Non-spontaneous
Q.406 The e/m ra o of ______ resembles with electron
A. Alpha rays B. Gamma rays
✓ C. Beta rays D. X - rays
Q.407 A numerical value that described about the number of orienta on in a sub-shell is
A. Principle quantum number B. Azimuthal quantum number
C. Spin quantum number ✓ D. Magni c quantum number
A. Dependent on its source B. Equal to square to its amplitude
✓ C. Dependent on its wavelength D. Independent on its wavelength
Q.409 The le er s,p,d,f are used to represent which quantum number
✓ A. Azimuthal B. Spin
C. Principle D. Magne c
Q.410 The orbitals having n + 1 = 5 are
A. 2p, 3d, 3s B. 3p, 3d, 5s
C. 3s, 4p, 4d ✓ D. 5s, 4p, 3d
Q.411 Electrons in degenerate orbitals are placed in separate orbitals with same spin according to
✓ A. Hund's rule B. Pauli exclusion principle
C. Au au principle D. Mosley's law
Q.412 The enthalpies of combus on of carbon and carbon monoxide are -393.5 and -283 kJ mol-1 respec vely.The enthalpy
of forma on of carbon monoxide per mole is
A. 110.5 kJ ✓ B. -110.5 kJ
C. -676.5 kJ D. 676.5 kJ
_______________________________________________________________________________________
4 Chemical Bonding
Q.1 The normality of solu on containing 4g NaOH in 10ml of solu on is:

A. 1.0 N ✓ B. 10N
C. 9.8 D. 11.0 N
Q.2 In which molecule, all atoms are coplanar
A. CH4 ✓ B. BF3
C. NH3 D. PH3
Q.3 Electronega vity values of the element F, Cl and Br vary
✓ A. F > Cl > Br B. Br > Cl > F
C. Cl > Br > F D. Cl > F > Br
Q.4 Chemical reac vity of element depends upon the number of
A. Protons is an atom of the element B. Neutrons in an atom of the element
C. Electrons in all shells ✓ D. Valence shell electrons
Q.5 Tripple bond is present in
A. O2 B. H2
✓ C. N2 D. Cl2
Q.6 The triatomic molecule with zero dipole moment has shape:
✓ A. Trigonal plannar B. Terahedral
C. Linear D. Angular
Q.7 How many grams of NaOH are needed to make 100ml of 0.2 molar solu on of NaOH:
✓ A. 0.8g B. 0.02g
C. 800g D. 20g
Q.8 Bond will be ionic when electronega vity difference of bonded atom
A. Equal to 1.7 B. Less to 1.7
✓ C. Greater to 1.7 D. No specificity exist
Q.9 Coordinate covalent bond is present in the molecules
A. H 2O B. BF3
C. SiO2 ✓ D. SO2
Q.10 Which of the following statements is not correct about ionic compounds?
✓ A. they are solid under ordinary condi ons B. they conduct electricity in molten state
C. they have high mel ng and boiling points D. they readly dissolve in non-polar solvents
Q.11 The force of a rac on between hydrogen atom of one molecule and an electronega ve atom of the other molecule
containing one pair of electron is called
A. covalent bond B. ionic bond
✓ C. hydrogen bond D. coodinate covalent bond
Q.12 A chemist poured lemon juice on soil. Which idea may he have in his mind
A. Lemon juice is dangerous for health ✓ B. There may be possibility of a chemical
reac on
C. Water should be preferred over lemon juice D. There may not be a possibility of chemical
for drinking reac on
Q.13 Which of the following bonds explain the nature of HCl:
A. Ionic bond B. Non-polar covalent Bond
✓ C. Polar covalent bond D. Covalent bond
_______________________________________________________________________________________
Q.14 If 18 g of glucose is present in 1000 g of solvent the solu on is said to be
A. 1 molar B. 0.5 molal
C. 0.1 molar ✓ D. 0.1 molal
Q.15 Which of the following molecules has unpaired electrons in an -bonding molecular orbitals?
✓ A. O2 B. N2
C. Br2 D. F2
Q.16 Which of the following is a polar molecules
A. carbon dioxide B. carbon tetrachloride
✓ C. methanol D. ethane
Q.17 A chemical bond which is formed by mutual sharing of electrons is called
A. ionic bond ✓ B. covalent bond
C. metallic bond D. none of these
Q.18 The shape of H2O molecule is:
✓ A. angular B. Pyramidal
C. Tetrahedral D. Linear
Q.19 Chemical reac vity of elements depends upon their characteris c:
A. Shape B. Colour
✓ C. Electronic D. Sizes
Q.20 A solu on contains 3 mole of ethyl alcohol and 7 moles of water. The mole frac on of ethyl alcohol and water will be:
✓ A. 0.3 and 0.7 respec vely B. 0.2 and 0.8 respec vely
C. 0.6 and 0.4 respec vely D. 0.7 and 0.3 respec vely
Q.21 Par al pressure of a solu on component is directly propor onal to its mole frac on.This statement is known as
A. Henry's law ✓ B. Raoult's law
C. Distribu on law D. Ostwald's dilu on law
Q.22 Molecular orbital picture of N2indicates
A. one unpaired electron B. two unpaired electrons
✓ C. no unpaired electron D. none of these is correct
Q.23 The Lewis acid are
A. Electron enrich ✓ B. Electron deficient
C. Octet s complete D. No such acids exist
Q.24 Which of the following successive ioniza on energies belong to Group II elements
A. 577, 1820, 2740, 11600, 14800 ✓ B. 736, 1451, 7740, 10500, 13600
C. 428, 3070, 4600, 5860, 7990 D. 320, 600, 1110, 1700, 5650
Q.25 Ethylene molecule has which hybridiza on
A. sp3 B. sp
✓ C. sp 2
D. none of these
Q.26 The bond length between atoms of hydrogen in the hydrogen molecules is:
A. 7.54 nm ✓ B. 0.0754 nm
C. 0.754 nm D. 0.00754 nm
Q.27 Which has high % ionic character
✓ A. HF B. HCl
C. HBr D. H 2O
Q.28 The tendency of an atom to a ract shared electron pair towards itself is called
A. covalent bond ✓ B. electronega vity
C. ioniza on poten al D. electron affinity
Q.29 Which of the following is noble gas:
✓ A. Ne B. CI2
C. H2 D. N2
Q.30 Solu ons with same osmo c pressure are called
A. Hypertonic B. Hypotonic
_______________________________________________________________________________________
✓ C. Isotonic D. Normal
Q.31 In H2O molecule the bond angle is
A. 90° B. 109.5°
C. 107° ✓ D. 104.5°
Q.32 The number of bonds in nitrogen molecule is
A. Oneσandπ ✓ B. Oneσand twoπ
C. Three sigma bonds only D. Twoσand Oneπ
Q.33 Which of the following statements about posi ve ions is incorrect
A. They are also known as ca ons B. They are formed when electrons are removed
from atoms
✓ C. They are larger than the atoms from which D. They are smaller than the atoms from which
they were formed they were formed
Q.34 The trend of electronega vity from le to right in a period
✓ A. Increases B. Decreases
C. Remain constant D. Variable trend
Q.35 In ammonium ion each bond has covalent character
A. 25% B. 50%
✓ C. 75% D. 100%
Q.36 One of the following bonds is polar but compound is non-polar
A. H 2O B. NH3
C. HCl ✓ D. CO2
Q.37 Which of the hydrogen halides has the highest percentage of ionic character?
A. HCl B. HBr
✓ C. HF D. HI
Q.38 Which of the following is not a colliga ve property?
A. Depression in freezing pint B. Eleva on of boiling point
C. Osmo c pressure ✓ D. Modifica on of refrac ve index
Q.39 Nobel gases have the electronic configura on with their valance shell ns2np6except one
✓ A. He B. Ne
C. kr D. Xe
Q.40 Elements have the tendency to a ain 8 electrons in their valence shell. This is know as
✓ A. Octet rule B. Hunds rule
C. Pauli exclusion principle D. Auf ban principle
Q.41 The mixing of the s and three p-orbital results in the forma on of
✓ A. sp3hybrids B. sp2hybrids
C. sp hybrids D. sp2d hybrids
Q.42 Which of the following molecules has a net dipole moment?
A. CO2 B. CS2
✓ C. SO2 D. CCl4
Q.43 S.I. Unit of dipole moment is
✓ A. Cm B. cm-1
C. Debye D. Poise
Q.44 At room temperature, the mole frac on of a solu on in 0.25 and the vapour pressure of the solvent is 0.80 atm.Then
the lowering of vapour pressure is
A. 0.75 B. 0.60
✓ C. 0.20 D. 0.80
Q.45 Which of the following form conjugate solu on
A. CH3OH + H2O B. H 2 O + C 6H 6
✓ C. Nico ne + H2O D. CH3OCH3+ C2H5OH
Q.46 The bond a er for He2molecule is
✓ A. zero B. 1/2
_______________________________________________________________________________________
C. 1 D. 2
Q.47 NH3has trigonal pyramidal geometry with bond angle 107° and similarly NF3also has trigonal pyramidal shape,
but bond angle of NF3is
A. 107° B. 104.5°
C. 90° ✓ D. 102°
Q.48 In order to determine the molecular mass from Raoult s law we select
A. A vola le solute in solu on B. An electrolyte in solu on
✓ C. A non-electrolyte and non-vola le solute D. A non-electrolyte in concentrated solu on
Q.49 Isotonic solu ons have same
✓ A. Molar concentra on B. Molality
C. Normality D. None of these
Q.50 Which of the following hydrogen halides has the highest percentage of ionic character.
A. HI B. HCl
C. HBr ✓ D. HF
Q.51 Which inorganic precipitate acts as semipermeable membrane?
A. Calcium sulphate B. Barium oxalate
C. Nickel phosphate ✓ D. Copper ferrocyanide
Q.52 Which molecule is 100% ionic
A. NaCI B. HCl
C. HF ✓ D. None
Q.53 Which of the following is the correct electron-dot formula for water
✓
A. B.
C. D.
Q.54 The shape of BeCl2 molecule is:
A. Trigonal plannar B. Pyramidal
✓ C. Tetrahedral D. Linear
Q.55 Colliga ve proper es are applicable to
✓ A. Ideal dilute solu ons B. Non-ideal solu on
C. Concentrated solu ons D. All kinds of solu ons
Q.56 VSEPR theory explains well:
A. Stability of bonds ✓ B. Shape of molecule
C. Paramagne c nature of oxygen D. All of above
Q.57 The trend of Atomic radii in a period of periodic table
A. Increases ✓ B. Decreases
C. Remain constant D. First decreases, then increases
Q.58 What type of bonding is present in NH4Cl:
A. Coordinate covalent bond B. Ionic bnd
C. Covalent Bond ✓ D. All of above
Q.59 By increasing temperature the solubility of which salt decreases
A. NaCI B. Pb(NO3)2
✓ C. Ce2(SO4)3 D. K2Cr2O7
Q.60 By combining "N" atomic orbitals then no. of hybrid orbitals are
A. 2n ✓ B. N
C. 3n D. Impossible to predict
Q.61 Which of the following is not a planar molecules?
A. BF3 B. C 2F4
✓ C. C 3H 6 D. HCN
Q.62 The molarity of pure water is
_______________________________________________________________________________________
A. 100 M B. 50 M
✓ C. 55.6 M D. 18 M
Q.63 The energy that required to remove an electron from an atom is called:
A. Heat of vaporiza on ✓ B. Ioniza on poten al
C. Electronega vely D. Electron affinity
Q.64 Azeotropic mixture of HCI and water has
A. 48% HCI B. 22.2% HCI
C. 36% HCI ✓ D. 20.2% HCI
Q.65 CsF is an ionic compound because:
A. High I.P of Cs and high EA of F B. High I.P of Cs and low EA of F
✓ C. low I.P of Cs and high EA of F D. low I.P of Cs and low EA of F
Q.66 Which of the following has smaller size:
✓ A. Fe+3 B. Fe+2
C. Fe+1 D. Fe
Q.67 An azeotropic mixture of two liquids boils at a lower temperature than either of them which is correct for it
A. It is saturated B. It shows nega ve devia on from Raoult s law
C. It does not deviate from Raoult s law ✓ D. It shows posi ve devia on from Raoults law
Q.68 Ethanol-water is ______ mixture
✓ A. Azeotropic B. Ideal
C. Benedict s D. Heterogeneous
Q.69 Freezing point of equeous solu on will be minimum for:
A. glycogen B. urea
✓ C. NH4CI D. fructose
Q.70 Which one of the following is polar covalent bond
✓ A. HF B. CH4
C. H2 D. N2
Q.71 An aquesous solu on of methanol has vapour pressure
A. Less than that of water ✓ B. More than that a water
C. Equal to that of water D. Equal to that of methanol
Q.72 According to VSEPR theory:
A. Shape of molecules is not explained well B.
Lone pairs do not a ract or repel to each
other
C. Molecular orbitals have low energy than ✓ D. Electrons pairs stay at maximum distance
atomic orbitals with minimum repulsion
Q.73 An chemical bond between two atoms having the difference of electronega vity 1.7 then which statement is correct:
A. Zero ionic character ✓ B. Bond is 50% ionic and 50% covalent
C. Bond is 100% ionic D. Bond is 50% covalent
Q.74 Total number of valence electrons in CH4
✓ A. 8 B. 9
C. 10 D. 12
Q.75 The vapour pressure of two liquids 'P' and 'Q' are 80 and 60 torr respec vely.The total vapour pressure of solu on
obtained by mixing 3 mole of P and 2 mol of Q would be
C. 68 torr ✓ D. 72 torr
Q.76 The bond angles in methane CH4. are equal to
✓ A. 109.5° B. 107.5°
C. 104.5° D. 120°
Q.77 Predict the bond angles present in SO2molecule
A. 120° ✓ B. less than 120°
C. 109.5 D. 107
Q.78 Geometry of simple molecule with Sp2hybridiza on
_______________________________________________________________________________________
✓ A. Triangular B. Tetrahedral
C. Square planner D. Pyramidal
Q.79 The geometrical shape of CH4 is:
A. Pyramidal B. Trianglular
✓ C. Tetrahedral D. cubic
Q.80 If 18 g of glucose (C6H12C6) is present in 1000 g of an aqueous solu on of glucose it is said to be
A. 1 molal B. 1.1 molal
C. 0.5 molal ✓ D. 0.1 molal
Q.81 Molecular orbitals are filled with the available electrons according to:
A. Hund's rule B. Pauli's rule
C. Au au principle ✓ D. All of above
Q.82 Three sp2hybrid are co-planar at an angle of
A. 104.5° B. 109.5°
C. 107° ✓ D. 120°
Q.83 A solu on is defined as a
✓ A. Homogeneous mixture of two or more B. Heterogeneous mixture of two or more
substances substances
C. Homogeneous mixture of liquid and solid D. Homogeneous mixture consis ng of water as
components only one of the components
Q.84 Metals lose electrons more easily than non-metals due to
✓ A. low ioniza on poten al B. high ioniza on poten al
C. high electron affinity D. low electron affinity
Q.85 pH3have ______ shape
A. Trigonal ✓ B. Pyramidal
C. Tetrahedral D. Linear
Q.86 Molarity of pure water is:
A. 1 B. 18
✓ C. 55.5 D. 6
Q.87 When element of group I react with the elements of group VIA theory form
✓ A. Ionic bond B. Covalent bond
C. Polar bond D. None
Q.88 Molality of pure water is:
A. 1 B. 18
C. 36 ✓ D. 55.5
Q.89 The radius of the ion while considering it to be spherical in shape is called:
A. Covalent radii B. Atomic radii
✓ C. Ionic radii D. Both (a) and (c)
Q.90 Which of the following is a colliga ve property?
A. Mel ng point ✓ B. Osmo c pressure
C. Freezing point D. Sublima on temperature
Q.91 In group VII, F is the most electronega ve halogen. Which of the following will be the strongest oxidizing agent
✓ A. F2 B. Cl2
C. I2 D. Br2
Q.92 Most reac ve among the following
A. Li B. Mg
C. Ca ✓ D. Na
Q.93 What is the difference between the atomic radius of Na and Na+
A. 9.1 A° B. 0.91 A°
✓ C. 91.1 A° D. 90 A°
Q.94 Which of the following solids does not contain covalent bond:
A. Graphite B. Diamond
_______________________________________________________________________________________
C. Ice ✓ D. Copper
Q.95 The theory which states that covalent bond is formed by the overlapping of two or more than two half filled atomic
orbitals is
✓ A. M.O theory B. V.B theory
C. VSEPR theory D. none of these
Q.96 Elements combine together due to inherent tendency to stabilize themselves by:
A. Losing electron B. Sharing electron
C. Gaining electrons ✓ D. All of above
Q.97 A 20% solu on of NaCI by weight means that:
✓ A. 20g NaCL / 100ml B. 58.5g NaCL / 100ml
C. 5.58g NaCL / 100ml D. 10.0g NaCL / 100ml
Q.98 The osmo c pressure of 1 m solu on at 27°C is
A. 2.46 atm ✓ B. 24.6 atm
C. 1.21 atm D. 12.1 atm
Q.99 The molarity of the solu on containing x grams (NH4)2SO in 500cm3 of the solu on is 0.6.What is x?
A. 45.1 B. 42.7
C. 40.5 ✓ D. 39.6
Q.100 Dipole moment is defined as:
A. Charge x Displacement B. Bond energy x Charge
✓ C. Charge x Distance D. Charge x Debye
Q.101 The %age by weight of NaCI, if 6.0g of NaCI is dissolved in 120g of H2O is:
A. 5% ✓ B. 8.02%
C. 10.50% D. 11.55%
Q.102 Which one of the following pairs of atoms is most likely to form an ionic bond
A. O and F ✓ B. Na and F
C. C and F D. N and F
Q.103 Which of the following has highest bond order
A. O2 ✓ B. O 2+
-1
C. O2 D. O2-2
Q.104 From the difference between expected bond energies for the normal covalent bond and experimentally determined
values Pauling calculated the values of
A. ioniza on poten al of elements B. electron affinity of elements
✓ C. electronega vity of elements D. bond length
Q.105 On the basis of VSEPR theory SO2is a
A. linear molecule ✓ B. a bent molecule
C. a strong molecule D. a gaseous molecule
Q.106 The theory of chemical bonding has been a major problem of:
A. Modern Physics ✓ B. Modern Chemistry
C. Modern Biology D. Mechanics
Q.107 In which of the following theories the hybridiza on is considered
A. VSEPR B. Lewis
C. Molecule orbital ✓ D. Valence bond
Q.108 The number of moles of ammonium chloride dissolved in 500m of its 15% WN solu on is
A. 1.0mol B. 1.4mol
✓ C. 2.0mol D. 2.4mol
Q.109 Which one of the following molecule is not according to octet rule
A. NH3 B. AICI3
C. BCI3 ✓ D. B and C
Q.110 What is the molarity of a solu on containing 15g urea in 500 cm3 of solu on?
✓ A. 0.5 M B. 1.0M
_______________________________________________________________________________________
C. 1.5M D. 2.0M
Q.111 One of following ways of expressing the concentra on of a solu on does not depends on temperature it is:
A. molarity B. normality
✓ C. molality D. formality
Q.112 A er adding a solute freezing point of solvent decreases to -0.186.Calculate Δ Tb if Kr = 1.86 and Kb = 0.521
A. 0.521 ✓ B. 0.0521
C. 1.86 D. 0.0186
Q.113 SnCl2have __________ shape
A. Planner B. Tetrahedral
✓ C. Angular D. None
Q.114 Dust par cles smoke is a solu on of the type:
A. gas is solute and solid is solvent ✓ B. solid is solute and gas is solvent
C. liquid is solute and solid is solvent D. solid is solute and liquid is solvent
Q.115 The electronega vity if elements in a period from le to right
A. decreases ✓ B. increases
C. first decreases then increases D. first increases then decreases
Q.116 A crystal of NaCl is held through:
✓ A. A rac on of oppositely charged ions B. Covalent bond
C. Posi ve ion in a sea of electrons. D. Coordinate covalent bond
Q.117 Which of the following 0.1 M aqueous solu ons will have the lowest freezing point
✓ A. K2SO4 B. Urea
C. NaCI D. Glucose
Q.118 Colliga ve proper es of the solu on depend upon
A. Nature of the solu on B. Amount of solu on
C. Nature of solvent ✓ D. Number of solute par cles
Q.119 Mg becomes isoelectronic with neon when it
✓ A. loses two electrons B. gains two electrons
C. loses 1 electron D. gains 1 electron
Q.120 Which of the following specles has unpaired electrons in an -bonding molecular orbitals?
A. O2+2 ✓ B. N2
-2
C. B2 D. F2
Q.121 The weight of pure NaOH required to prepare 250 cm3 of 0.1 N solu on is
A. 4g ✓ B. 1g
C. 2g D. 5g
Q.122 In azeotropic mixture showing posi ve devia on from Rault's law the volume of the mixture is;
✓ A. slightly more than the total volume of the B. slightly less than the total volume of the
components components
C. equal to the total volume of the components D. none of these
Q.123 Which of the statements given below concerning proper es of solu on describe a colliga ve effect?
A. Boiling point of pure water decreases by the B. Vapour pressure of pure water decreases by
addi on of ethanol the addi on of nitric acid
✓ C. Vapour pressure of pure benzene decreases D. Boiling point of pure benzene increases by the
by the addi on of naphthalene addi on of toluene
Q.124 The VSEPR theory explains the _________ of molecules
A. Number B. Kinds
✓ C. Geometry D. None
Q.125 In sp2hybridza on bond angle is ___________
✓ A. 120° B. 180°
C. 109.5° D. None
Q.126 In which of the following molecules the bond angle is maximum
A. CH4 B. H 2O
C. NH3 ✓ D. CO2
_______________________________________________________________________________________
Q.127 The molecule having two lone pairs and two bonded pairs around the central atom the shape of the molecule is
A. linear B. pyramidal
C. tetrahedral ✓ D. bent
Q.128 Which of the following statements is not correct regarding bonding molecular orbitals?
A. Bonding molecular orbitals posses less energy ✓ B. Bonding molecular orbitals have low electron
than atomic orbitals from which they are density between the two nuclei.
formed. C. Every electron in the bonding molecular
orbitals contributes to the a rac on between
atoms.
D. Bonding molecular orbitals are formed when
the electron waves undergo construc ve
interference.
Q.129 In which molecule central atom is sp hybridized:
✓ A. BeCl2 B. BF3
C. C 2H 4 D. None of above
Q.130 In the combina on of sodium and hydrogen to form Nah:
✓ A. Hydrogen atom gains an electron B. Sodium atom gains an electron
C. Both the atoms share the electron D. None of above
Q.131 Non-existed molecule of the noble gases
A. XeF2 B. XeO3
✓ C. NeO3 D. B and C
Q.132 Which of the following has polar bond
A. O2 B. N2
✓ C. HCl D. Cl2
Q.133 Which one of the following process is the most likely to be responsible for evolu on of heat:
✓ A. hydra on B. sublima on
C. dissocia on D. ioniza on
Q.134 The strength of Van der Waals forces, i.e. induced dipole-induced dipole depends upon
A. number of electrons in the molecule B. number of proton in the molecule
✓ C. on both a and b D. presence of hydrogen atom in the molecule
Q.135 The temperature at which the vapour pressure of a liquid becomes equal to external pressure is
A. Mel ng point B. Sublima on point
C. Inversion point ✓ D. Boiling point
Q.136 Which one of the following is a colliga ve property?
A. Surface tension ✓ B. Osmo c pressure
C. Viscosity D. Refrac ve index
Q.137 The atomic radius of hydrogen is 37 ______. Choose the correct unit among the followings
A. Angstrom B. Manometer
✓ C. Picometer D. Micrometer
Q.138 According to valence shell electron pair repulsion theory the repulsion is greater
✓ A. lone pair-lone pair repulsion B. lone pair-bonded pair repulsion
C. bonded pair-bonded pair repulsion D. nucleus-nucleus repulsion
Q.139 Which one of the following is an acidic salt
A. NaHSO4 ✓ B. Na2SO3
C. CH3COONA D. Na2SO4
Q.140 The force which holds together two or more atoms or irons to form a large variety of compound is called:
✓ A. A chemical bond B. An ionic bond
C. A covalent bond D. A coordinate bond
Q.141 A solu on contains 0.4 mole of a component A and 0.6 mole component B. the mole frac on of component A is:
✓ A. 0.4 B. 0.45
C. 0.6 D. 0.5
Q.142 Boron atom is the central atom in BF3which has
_______________________________________________________________________________________
A. three bonded pairs and one lone pair ✓ B. three bonded pair
C. four bonded pair D. two bonded pairs and on lone pair
Q.143 Generally the bond formed by metals with non-metals is
✓ A. ionic B. covalent
C. polar D. non-polar
Q.144 Mostly ionic compounds are soluble in:
A. n-hexane ✓ B. Water
C. Alcohal D. Benzene
Q.145 The item of an element is
A. The independent par cle B. The fundamental par cle
C. The charged par cle ✓ D. The smallest par cle
Q.146 Which of the following equa on represents the 2nd ioniza on energy of Na
A. B.
✓
C. D.
Q.147 Which is the correct arrangement following bonds in order of increasing bond strength
✓ A. C – l < C – Br < C – Cl < C – F B. C – Br < C – I < C – Cl < C – F
C. C – l < C – Br < C – F < C – Cl D. C – F < C – Cl < C – Br < C – I
Q.148 In which of the following molecules would you expect the nitrogen to nitrogen bond to be the shortest
A. N 2H 4 ✓ B. N2
C. N 2O 4 D. N 2O
Q.149 The ra o of the number of moles of a par cular component of the solu on to the total number of all the
componenets of the solu on is called:
A. molarity ✓ B. mole frac on
C. %age D. formality
Q.150 The increase in size of anion is due to:
A. Increase in electron-electron repulsion B. Increase in valence shell electrons
C. Decrease in valence shell electrons ✓ D. Both (a) and (b)
Q.151 A white solid forms when BF3reacts with gaseous ammonia. The white solid is F3BNH3. What type of bonding is
responsible for the forma on of this solid?
A. electrovalent (ionic) bonding B. covalent bonding
✓ C. coodinate (da ve covalent) bonding D. Vander waals forces
Q.152 18g of glucose is dissolved in 90g of H2O The rela ve lowering of vapour pressure is
A. 0.2 ✓ B. 1/51
C. 6 D. 5.1
Q.153 If geometry of molecule will be pyramidal then no of electrons in outer most shell of central atom
✓ A. 1 Bond pair, 3 lone pair B. 2 Bond pair, 2 lone pair
C. 3 bond pair, 1 lone pair D. 3 lone pair, 1 lone pair
Q.154 Molecular orbital picture of O2indicates
A. No unpaired electron ✓ B. Two unpaired electron
C. One unpaired electron D. None of these
Q.155 Bond length is minimum in
A. HCI B. NH3
C. H 2O ✓ D. HF
Q.156 As the nuclear charge increase, the pull on the electrons is increased and size of an atom:
✓ A. Decrease B. Remains same
C. Increase D. Is negligible
Q.157 Paramagne c behavior of O2is due to:
✓ A. Two molecular orbitals are par ally filled B. Overlapping of only two par ally filled orbits
_______________________________________________________________________________________
C. Greater strength of pie bond than sigma bond D. All molecular orbits are completely filled
Q.158 Which one of the following correctly describes the trend in electro nega vity
✓ A. Increases across a period and decreases B. Decreases across a period and increases down
down a group a group
C. Decreases across a period and decreases D. Increases across a period and increases down
down a group a group
Q.159 The energy of the non-bonding molecular orbital is __________ than bonding molecular orbital
A. Lesser ✓ B. Great
C. Equal D. None
Q.160 The driving force for making a bond is
A. to make solid compounds ✓ B. to a ain noble gas electronic configura on
C. to make different compounds D. to make gaseous substances
Q.161 Ca, Mg, Be, Ba, belong to the same group the order of their ioniza on energy values is
✓ A. Be > Mg > Ca > Ba B. Ba > Ca > Mg > Be
C. Ca > Mg > Be > Ba D. Ba > Mg > Ca > Be
Q.162 Hydrogen bonding in ammonia exist due to
A. the high reac vity of nitrogen ✓ B. by the high electronega vity of nitrogen
C. the high bond energy of the N - H bond D. both a and c
Q.163 The freezing point of 1 mole NacI solu on assuming NacI to be 100% dissociated in water in
A. -1.86°C ✓ B. -3.72°C
C. +1.86°C D. +3.72°C
Q.164 Which is not a colliga ve property?
A. Osmo c pressure ✓ B. Lowering of vapour pressure
C. Depression of freezing point D. Eleva on of boiling point
Q.165 The forma on of compound like PF5, BCl3, SF6indicates that
A. these halides are ionic B. these halides are covalent
C. they are Lewis acids ✓ D. octet rule not obeyed so the rule is not
universal
Q.166 The molarity of 10% NaOH solu on is
A. 2.4 ✓ B. 2.5
C. 2.3 D. 2.2
Q.167 When two hydrogen atoms approach each other:
A. Forces of a rac on operate B. Forces of repulsion operate
✓ C. Forces of a rac on and repulsion operate D. Nothing happens
simultaneously
Q.168 When two hydrogen atoms approach to form a chemical bond
A. the repulsive forces dominate the a rac ve ✓ B. the a rac ve forces, dominate the repulsive
forces forces
C. the energy of atoms increases D. the two atoms start ioniza on
Q.169 The molal boiling point constant is the ra o of the eleva on in boiling point to:
A. molarity ✓ B. molality
C. mole frac on of solvent D. mole frac on of solute
Q.170 Which explain the over lapping of the bonding atomic orbitals
A. VSEPR theory B. VB theory
✓ C. MO theory D. All
Q.171 Which of the following shows nega ve devia on from Raouit s law
✓ A. CHCI3and CH3COCH3 B. C6H6and C2H3OH
C. C6H5CH3and C6H6 D. C6H6and CCI4
Q.172 Molecular orbital picture of N2indicates
A. Two unpaired electron B. One unpaired electron
✓ C. No unpaired electron D. None of these
Q.173 Select an ion with shortest atomic radius
✓ A. Al+3 B. Na+
_______________________________________________________________________________________
C. Mg2+ D. Ga3+
Q.174 The ra o of eleva on in boiling point to___________is called the molal boiling point constant:
A. mole frac on of solute B. mole frac on of solvent
C. molarity ✓ D. molality
Q.175 Which of the following has the greatest covalent character
✓ A. LiCl B. NaCl
C. KCl D. RbCl
Q.176 Osmo c pressure of a solu on increases by
A. Decreasing the temperature B. Increasing the volume
✓ C. Increasing the number of molecules of the D. None of the above
solute
Q.177 The geometry of H2O is similar to that of
A. MgCI2 B. HgCl2
C. SnCI2 ✓ D. N- H 2
Q.178 SnCl2have ______ shape
A. Planner B. Tetrahedral
✓ C. Angular D. None
Q.179 In what area of periodic table, would you expect the most electronega ve element:
A. Lower le B. Middle
C. Upper le ✓ D. Upper right
Q.180 All covalents bonds formed between the two atoms are non-polar when
A. covalent bond between two non-metal B. covalent bond between metal and non-metal
✓ C. covalent bond between two atoms of same D. covalent bond between metal atoms
element
Q.181 In a mixture A and B components show the nega ve devia ons as
A. ΔVmix> 0 B. A-B interac on is weaker than A - A
✓ C. ΔVmix < 0 D. ΔH = +ive
Q.182 The unit of dipole moemnt is:
A. Calorie ✓ B. Debye
-1
C. Nm D. Poise
Q.183 Which for the following has no dipole moment
A. HCl B. H 2S
C. H 2O ✓ D. CO2
Q.184 Which is not a colliga ve property
A. Osmo c pressure B. Depression in freezing point
C. Lowering in vapour pressure ✓ D. Refrac ve index
Q.185 The value of ioniza on energy is maximum for
A. B B. C
✓ C. N D. O
Q.186 An ionic compound M2S3is formed by the metal M, the metal is
A. Ca B. Ba
C. K ✓ D. Al
Q.187 Which molecules exhibits paramagne c behaviour?
A. N2 ✓ B. O2
C. Cl2 D. HF
Q.188 Camphor is o en used in molecular mass determina on because
A. It is solvent for organic substances B. It is readily available
✓ C. It has a very high cryoscopic constant D. It is vola le
Q.189 A solu on contains 1.2046 x 1024 hydrochloric acid molecules in one dm3 of the solu on.The strength of the solu on is
A. 6N ✓ B. 2N
C. 4N D. 8N
_______________________________________________________________________________________
Q.190 A students subtracted 0.00055 from 10.2345678 and reported the result as 10.23401. But his friend told him that
result was wrong. What is the correct result?
✓ A. 10.23 B. 10.234017
C. 10.2340178 D. 10.234
Q.191 Noble gases are
A. Light substances B. Heavy substances
✓ C. Stable substances D. Reac ve substances
Q.192 The electro-nega vity difference of H - Cl is 0.9 so it should be _______ bond
✓ A. Covalent B. Ionic
C. Coordinate covalent D. Metallic
Q.193 Mostly ionic compound are produced in between elements of group
A. IA and IIA ✓ B. IA, IIA and VII A
C. IB and VIIB D. IA and IB
Q.194 The degree of polarity of molecule is known as its
✓ A. Dipole moment B. Moment arm
C. Bond energy D. Ionic character
Q.195 The molarity of toluene solu on in benzene is 0.22 if 5.0g of toluene dissolved then mass of benzene in grams is:
A. 240 ✓ B. 247
C. 260 D. 267
Q.196 The geometry of NH3is
A. linear B. octahedral
C. angular ✓ D. pyramidal
Q.197 Some covalent compounds are soluble in water because of:
A. Hydroysis ✓ B. Hydrogen bonding
C. Hydra on D. All of above
Q.198 The dipole moment of ortho chloro benzene is:
A. 1.70 D B. 2.70 D
✓ C. 2.5 D D. 1.5 D
Q.199 The force which holds the atoms together to form a compound is called
✓ A. a chemical bond B. Van der Waal's force
C. dispersion force D. London force
Q.200 Mole frac on is not effected by
A. Temperature B. Volume
C. Pressure ✓ D. All of these
Q.201 Which of the following bonds is present in NH4Cl
A. Ionic bond B. Covalent bond
C. Co-ordinate covalent bond ✓ D. All the above
Q.202 Which is made by coordinate covalent bond
✓ A. H 3O + B. H 2O
C. CH4 D. HCl
Q.203 Depression on freezing point is direct to:
A. molarity of solvent B. molality of solvent
C. molarity of solu on ✓ D. molality of solu on
Q.204 Which of the following equa on represents the Ist ioniza on energy of Na
✓
A. B.
C. D.
Q.205 The atomic radius of hydrogen is 37
✓ A. pecometer B. manometer
_______________________________________________________________________________________
C. angstrom D. micrometer
Q.206 In ethene each carbon atom is a ached to three atoms. What is the type of hybridiza on and the shape according to
that?
A. sp2, tetrahedral B. sp3, tetrahedral
✓ C. 2
sp , trigonal D. sp3, trigonal planar
Q.207 Which of the following will from an ideal solu on
A. C2H5OH and water B. HNO3 and water
C. CHCI3and CH3COCH3 ✓ D. C6H6and C6H5CH3
Q.208 The minimum electron pair repulsion is when the electron pairs are at
✓ A. 180° B. 120°
C. 90° D. 109.5°
Q.209 Maximum freezing point falls in
✓ A. Camphor B. Naphthalene
C. Benzene D. Water
Q.210 Which of the following molecules have angel of 120°
A. BeCI2 ✓ B. BF3
C. CH4 D. NH3
Q.211 Which of the hydrogen halides has the highest percentage of ionic character?
✓ A. HCI B. HBr
C. HF D. HI
Q.212 Predict shape of Ethanal, HCHO molecule on the basis of VSEPR theory
A. linear B. trigonal planar
✓ C. pyramidal D. tetrahedral
Q.213 Solu on which dis ll without change in composi on or temperature are called
A. Amorphous ✓ B. Azeotropic mixture
C. Ideal D. Super saturated
Q.214 What would be volume in liters of oil if the density of the oil is 0.8g / ml?
A. 0.8 liter ✓ B. 800 liter
C. 0.5 liter D. 512 liters
Q.215 The solubility of solute in water is high if
A. Hydra on energy = la ce energy B. Hydra on energy >> la ce energy
C. Hydra on energy < la ce energy ✓ D. Hydra on energy << la ce energy
Q.216 The electronega vity of elements in a period from le to right
C. First increases then decreases D. First decreases then increases
Q.217 The freezing point of 1% of lead nitrate solu on in water will be
A. 2°C B. 1°C
✓ C. Below 0°C D. 0°C
Q.218 Valence bond theory is unable to explain:
A. Double and triple bond B. Stability of covalent molecules
✓ C. Paramagne sm in O2molecule D. Shape of H2O molecule
Q.219 0.5 molal solu on:
A. is 0.5 mes more concentrated than 0.5 B. has concentra on equal to 1M solu on
molar solu on
✓ C. is less concentrated than 0.5 molar solu on
D. has concentra on as that of 0.5 molar
solu on
Q.220 Molecule in which overlap p and p orbitals
A. H2 B. HF
✓ C. F2 D. All of these
Q.221 The number of significant figures in 0.00200 is
A. One ✓ B. Three
_______________________________________________________________________________________
C. Two D. Five
Q.222 Which of the following molecules have its central atom sp2hybridized
A. CH4 B. C 2H 2
✓ C. C 2H 4 D. CCl4
Q.223 A solu on of glucose is 10 percent. The volume in which 1g mole of it is dissolved will be
A. 1 dm3 ✓ B. 1.8 dm3
3
C. 200 cm D. 900 cm3
Q.224 The bond order O2molecule is
A. 1 ✓ B. 2
C. 3 D. zero
Q.225 A compound is more likely to be covalent if the ______
✓ A. Ca on has a small size and high charge B. Anion has a small size and high charge
C. Ca on has a large size and a small charge D. Anion has a small size and a small charge
Q.226 An ionic compound will dissolve in water only if:
A. Hydra on energy is low and la ce energy is B. Hydra on energy is high and la ce energy is
low. very high.
✓ C. Hydra on energy is high and la ce energy is D. Hydra on energy is low and la ce energy is
low. high.
Q.227 A molecule has linear structure. How many lone pairs it must have?
✓ A. 2 B. 4
C. 3 D. 5
Q.228 Choose the correct statement
A. Each bonding molecular orbital can ✓ B. As bonding molecular orbitals become more
accommodate only one electron stable, an bonding molecular orbital
become equally less stable
C. In molecular orbitals, the number of bonding D. The molecular orbitals in a molecule equals
electrons equals the number of an bonding twice the number of cons tuent atomic
electrons orbitals
Q.229 Aluminium is in group III. ts oxide will have the formula
A. AlO2 B. AlO
✓ C. Al2O3 D. Al3O2
Q.230 According to valance band theory, O2 and N2molecules:
A. O2is diamagne cand N2is paramagne c B. Both are paramagne c
C. Both are diamagne c ✓ D. N2is diamagne cand O2is paramagne c
Q.231 Colliga ve proper es are the proper es of:
✓ A. dilute solu ons which behave as nearly ideal B. concentra ons solu ons which behave as
solu ons nearly non-ideal solu on
C. both (a) and (b) D. neither (a) and (b)
Q.232 Name the par ally miscible liquids from the following
A. Alcohol-ether B. Benzene-water
✓ C. Nico ne-water D. Water-methanol
Q.233 What happens when isotonic solu on of A (mol. wt. 342) and B (mol. wt 60) are put in to communica on
semipermeable membrane?
A. Transference of solvent from solu on A to B. Transference of solvent from solu on B to
that of B take place that of A takes place
✓ C. No transference of solvent from solu on A to D. Change in temperature of solu ons takes
that of B takes place place.
Q.234 Which of the following best describes the shape and polarity of the carbon disulfide, CS2, molecule
A. Bent and polar ✓ B. Linear and non-polar
C. Pyramidal and polar D. Bent and non-polar
Q.235 Geometry of ammonia is
A. Tetrahedral B. Square planner
C. T. Shape ✓ D. Pyramidal
Q.236 A homogeneous mixture of two or more than two chemical substances is called:
A. solute B. solvent
_______________________________________________________________________________________
✓ C. solu on D. solva on
Q.237 Which of the following is most electronega ve element:
A. CI B. N
C. O ✓ D. F
Q.238 H2O and CO2have very different bond angles. The reason behind is
A. Hydrogen binding in H2O B. the high electronega vity of O in H2O
C. existence of Ione pairs of e on O atoms in CO2 ✓ D. water has bent shape
2
has linear
whereas CO shape
Q.239 The electronega vity of cesium is 0.7 and that of fluorine is 4.0. The bond formed between the two is
A. Covalent ✓ B. Electrovalent
C. Coordinate D. Metallic
Q.240 Which of the following has two pie-bonds
A. CH4 B. C 2H 4
✓ C. C 2H 2 D. CCl4
Q.241 Which of the following molecules have mul ple bonds
A. CH4 ✓ B. C 2H 4
C. C 2H 6 D. CCl4
Q.242 The trend of ioniza on energy down the group in a periodic table
C. No change D. Variable trend
Q.243 Vant Hoff's factor of Ca(NO3)2 is
A. 1 B. 2
✓ C. 3 D. 4
Q.244 Geometry of NH3is
A. Tetrahedral B. Square planer
✓ C. Pyramidal D. Linear
Q.245 Which of the following is the correct electron-dot formula of CO2
A. B.
✓
C. D.
Q.246 Sheilding effect of intervening electrons causes
A. decrease in atomic radii in a period from right B. increase in atomic radii in a period from le to
to le right
C. decrease in atomic radii down the group ✓ D. increase in atomic radii down the group
Q.247 The expected geometrical shape of molecules which have sp3hybridiza on is:
✓ A. Tetrahedral B. Pyramidal
C. Trigonal planner D. Linear
Q.248 Atoms obey octet rule by sharing electrons making covalent bonds according to
✓ A. Lewis and Kossal theory B. Valance bond theory
C. VSEPR theory D. Molecular orbital theory
Q.249 What type of intermolecular forces exist between molecules of CHCl3?
✓ A. permanent dipole-permanent B. induced dipole-ind dipole-interac on
C. hydrogen bonding D. covalent bonding
Q.250 Which of the following compounds is Ionic?
✓ A. Na2O B. H 2O
C. CH4 D. HBr
Q.251 The shape of methanol; ammonia and water molecule can be explained by assuming
✓ A. sp3hybridiza on B. sp2hybridiza on
C. sp hybridiza on D. all of these
Q.252 The twelve outer electrons in O2molecule are distributed according to MOT as under. Find the correct one
_______________________________________________________________________________________
✓ A. 8 in bonding molecular orbitals, 4 in an B. 12 in bonding molecular orbitals and zero in
bonding molecular orbitals an bonding molecular orbitals
C. 9 in bonding molecular orbitals and 3 in an D. 10 in bonding molecular orbitals and 2 in
bonding molecular orbitals an bonding molecular orbitals
Q.253 The molal eleva on constant is the ra o of the eleva on in boiling point to
A. Molarity B. Mole frac on of solute
✓ C. Molality D. Mole frac on of solvent
Q.254 Which of the following shape is exhibited by NH3 molecule:
A. square plannar B. angular
✓ C. pyramidal D. tetrahedral
Q.255 The tendency of bonded atom in a molecule to a ract shared pair of electrons is called:
A. La ce energy B. Ioniza on poten al
✓ C. Electronega vity D. Electron affinity
Q.256 CO2is a triatomic linear molecule, its dipole moment is
✓ A. 0D B. 0.5 D
C. 1.0 D D. 1.5 D
Q.257 The dipole moment of water is:
✓ A. 1.84 D B. 1.94 D
C. 1.08 D D. 8.0 D
Q.258 The covalent bonds are
A. Unidirec onal B. Bi-direc onal
C. Non-direc onal ✓ D. Mul -direc onal
Q.259 When two hydrogen atoms approach to form a chemical bond,
A. The energy of atoms increases ✓ B. The a rac ve forces dominate the repulsive
forces
C. The two atoms start ioniza on D. The repulsive forces dominate the a rac ve
forces
Q.260 Periodic trend of hydra on energy depends upon charge density So in periods & group its trend is respec vely given as
A. Decreases increases ✓ B. Increases decreases
C. Constant decreases D. Increases constant
Q.261 92° bond angle is present in
A. CH4 B. H 2O
C. NH3 ✓ D. H 2S
Q.262 Equal volumes of 0.1 M AgNO3 and 0.2 M NaCI are mixed.The concentra on of NO-3 ions in the mixture will be
A. 0.1 M ✓ B. 0.05 M
C. 0.2 M D. 0.15 M
Q.263 A solu on which contains a rela vely small amount of solute dissolved in the solvent is called:
A. saturated solu on B. ideal solu on
C. concentratedn solu on ✓ D. dilute solu on
Q.264 Which substance among the following gives acidic solu on a er dissolu on in H2O:
A. sodium chloride B. ammonium acetate
✓ C. ammonium chloride D. sodium sulphate
Q.265 Ionic compound do not show the phenomenon:
A. Non-direc onal and non-rigid ✓ B. Non-direc onal and rigid
C. Direc onal and non-rigd D. Direc onal and rigid
Q.266 An ionic compound A+B-ismost likely to be formed when:
A. The ioniza on energy of A is high and electron ✓ B. The ioniza on energy of A is low and
affinity of B is low. electron affinity of B is high.
C. Both the The ioniza on energy of A and D. Both the The ioniza on energy of A and
electron affinity of B are high. electron affinity of B are low.
Q.267 In which of the following pairs, do the elements form a compound by sharing electrons:
A. Potassium and bromine B. Neon and oxygen
C. Lithium and iodine ✓ D. Carbon and chlorine
_______________________________________________________________________________________
Q.268 Van-der Waal's repulsion is the repulsion between
A. dipoles ✓ B. electrons pair in valence shell of central atom
C. nucleus-nucleus repulsion in o-bond D. nucleus-nucleus repulsion in pie-bond
Q.269 Covalent bonds are least likely to be formed
A. Between atoms of the same element B. Between atoms of different elements on the
right of the periodic table
C. By head of the group elements with high ✓ D. Between an element in group I and an
ioniza on energies element in group VII
Q.270 In a group the atomic size increases downward due to
✓ A. addi on of electronic shells B. increases in the proton number
C. repulsion of electrons D. all of the above
Q.271 Beckmann s thermometer measures
A. Boiling point of the solu on B. Freezing point of the solu on
C. Any temperature ✓ D. Eleva on in boiling point or depression in
freezing point
Q.272 ____ is used to lower the mel ng point of ice
A. CaCI2 ✓ B. NaCI
C. Glucose D. CCI4
Q.273 Which of the following solu on has the highest boil point:
✓ A. 5.58% solu on of sodium cahloride B. 18.0% solu on of sodium chloride
C. 6.0% solu on of urea D. all have the same boiling point
Q.274 Saturated solu on of NaCI on hea ng becomes
A. Super saturated ✓ B. Unsaturated
C. Remains saturated D. None
Q.275 Which of the following element has highest ioniza on poten al?
A. Rb B. K
✓ C. Li D. Na
Q.276 In which mode of expression the concentra on of the solu on remains independent of temperature
A. Normally B. Molarity
✓ C. Molality D. Formality
Q.277 Object of the size of an atom can be observed in
A. A visible spectrum B. X-ray spectrum
✓ C. In electron microscope D. Atomic absorp on spectrum
Q.278 18g glucose is dissolved in 90g of water the rela ve lowering of
vapour pressure is equal to:
A. 1/5 B. 5.1
✓ C. 1/51 D. 6
Q.279 Which of the following molecules or ions is non polar, i.e., has at least one atom that is not in the same plane as others
A. BH3 ✓ B. NF3
3
C. SO D. CO32-
Q.280 The process in which water molecule surround solute pra cles is called:
A. hydrolysis B. solva on
✓ C. hydra on D. dehydra on
Q.281 Which of the following is are not characteris cs of nega ve devia on except
A. Boiling point of solu on increases B. Volume of solu on slightly decreases than
that of sum of individual components
✓ C. ΔH is posi ve D. Vapour pressure of solu on is low
Q.282 The solubility of a gas in water depends upon
A. Nature of the gas B. Temperature
C. Pressure of the gas ✓ D. All of the above
Q.283 Which of the following dies not have induced dipole interac ons?
✓ A. H 2O B. CO2
C. CH4 D. He
_______________________________________________________________________________________
Q.284 Which of the following compounds have ionic, covalent and coordinate bond in it:
A. H 2O B. KBr
✓ C. NH4Cl D. NH3
Q.285 Mel ng points of halogens increase down the group, what is the reason for this change?
A. down the group, intermolecular forces change B. number of protons increase down the group
from induced dipoles to permanent
C. size of nucleus increases down the group
✓ D. number of electrons as well as the size of
molecule increase down the group
Q.286 The ionic strength of a solu on containing 0.1 mole/kg of KCI and 0.2 mole/kg of CuSO4 is
A. 0.3 B. 0.6
✓ C. 0.9 D. 0.2
Q.287 Azeotropic mixture of tow liquids boils at a lower temperature than either of them when:
A. its is saturated ✓ B. it shows posi ve devia on from Rault's law
C. it shows nega ve devia on from Rault's law D. it is metastable
Q.288 Buffering ac on of a mixture of CH3COOH and CH3COONa is maximum when the concentra on ra o of salt to acid is
equal to
✓ A. 1.0 B. 10.0
C. 100.0 D. 0.1
Q.289 Which one of the following molecule in which maximum different kinds of electronic repulsion are presents
A. SO3 B. SO2
✓ C. H 2O D. PCI5
Q.290 A bond between two atoms may be obtained by sharing of electrons such a bond is called
A. an ionic bond B. a coordinate bond
C. a da ve bond ✓ D. a covalent bond
Q.291 ionic radius, in a periods from le to right
A. increases B. decreases
✓ C. decreases then increases D. increases then decreases
Q.292 The bond length of halogen atoms increases from chlorine to Asta ne. Which of the following bond will be easiest to
break to individual atoms?
A. I-I B. Br - Br
C. Cl - Cl ✓ D. At - At
Q.293 Which statement is true for Na and Na+
A. Size of Na is smaller than Na+ ✓ B. Size of Na is greater than Na+
C. Both have same proper es D. Both have equal size
Q.294 The process of osmosis was first discovered by
✓ A. Nollet B. Pfeffer
C. Traube D. Dutrochet
Q.295 In a group of periodic table, atomic radii:
A. Remains same ✓ B. Increase
C. First decrease then increase D. Decrease
Q.296 The example of colliga ve property is
A. Boiling point B. Osmosis
C. Freezing point ✓ D. Osmo c pressure
Q.297 The bond angle depends upon the
A. Types of bonds B. Number of bonds
C. Non-bonding electron pairs ✓ D. All of the above
Q.298 A substance conducts electricity both in solid and in liquid form, has a mel ng point greater than 1000°C. What
could it be?
A. NaCl B. MgCl2
✓ C. Cu D. AlCl3
Q.299 Which molecule has linear geometry?
_______________________________________________________________________________________
A. SO2 B. H 2O
✓ C. CO2 D. H 2S
Q.300 An aqueous solu on freezes at -0.186°C (Kf = 1.86, Kb = 0.512).What is the eleva on in boiling point?
A. 0.186 B. 0.512
C. 0.80 ✓ D. 0.0512
Q.301 In a group of periodic table, ioniza on energy:
C. Remains same D. First increases then decreases
Q.302 Atomic number of Al is 13. When it forms ionic bond with oxygen the number of electrons lost by 1 Al atom is
A. 1 B. 2
✓ C. 3 D. 4
Q.303 Which of the following substances can form hydrogen bond
A. argon ✓ B. methane
C. ethanol D. benzene
Q.304 The number of electron pairs shared in carbon tetrachloride molecule is
A. 2 B. 3
✓ C. 4 D. 1
Q.305 If ionic product of solu on s greater than solubility products the solu on is:
A. saturate B. unsaturated
✓ C. supersaturated D. None of above
Q.306 In cold countries ethylene glycol is added to water in radia ons of cars during winter.It results in
A. Lowering in b.pt. B. Reducing viscosity
C. Reducing specific heat ✓ D. Lowering in freezing pt.
Q.307 During the forma on of a chemical bond the poten al energy of the system
C. Does not change D. None of these
Q.308 All of the following statements are incorrect except
A. Scien fic work must be precise, accuracy is B. Scien fic work must accurate, precision is not
not essen al essen al
C. Precision and accuracy should go side by side ✓ D. None of above
in a scien fic work
Q.309 The force which holds the atoms together to form a compound is known as
A. Van der Waal's force B. London force
✓ C. Chemical bond D. Dispersion force
Q.310 F-atom obeys octet rule by acquiring confingura on of
A. He B. Ar
✓ C. Ne D. Kr
Q.311 If two ione pairs are present then bond angle of tetrahedral compound reduces to _________ degrees
A. 109.5° B. 107.5°
✓ C. 104.5° D. None
Q.312 Delocalised molecular orbitals are found in
A. H2 B. HS-
C. CH4 ✓ D. CO32-
Q.313 In which bond The density is maximum between nuclel of two bonded atoms:
✓ A. Sigma B. Polar
C. Pi D. Covalent bond with parallel overlapping
Q.314 By increase in atomic radii in a group the effec ve nuclear charge decreases on electron, which results
A. decreases in bond length B. decrease in bond moments
✓ C. increase in bond length D. increase in bond moment
Q.315 A bond between two atoms may be obtained by sharing of electrons is known as
A. Ionic bond ✓ B. Covalent bond
_______________________________________________________________________________________
C. Coardinate covalent bond D. Da ve bond
Q.316 Two solu on of NaCI and KCI are prepared separately by dissolving same moles of them in the fixed amount of solvent
which of the following statements is true for these solu ons?
A. KCI solu on will have higher boiling point that B. Both the solu on have different boiling point
NaCI solu on
✓ C. KCI and NaCI solu on possess same vapour
pressure
D. KCI solu on possesses lower freezing point
than NaCI solu on
Q.317 How many sigma bond's are present in HCN molecule
✓ A. 2 B. 3
C. 4 D. 5
Q.318 The bond length between atoms of hydrogen in the hydrogen molecules is:
A. 7.54 nm ✓ B. 0.0754 nm
C. 0.754 nm D. 0.00754 nm
Q.319 When a non-vola le solute is dissolved in a solvent the rela ve lowering in vapour pressure is equal to
A. Mole frac on of solvent B. Concentra on of solute in g dm-3
✓ C. Mole frac on of solute D. Concentra on of solute in g per 100 mL
Q.320 According to modern theory of chemical bonding, atoms form bonds as it leads to a:
A. Increase energy B. No energy change
✓ C. Decrease energy D. First decrease then increase in energy
Q.321 Which of the following is a substance
A. Brass B. Tape water
✓ C. Graphite D. Sea water
Q.322 Element of group IA and IIA are
A. Electronega ve ✓ B. Electroposi ve
C. Neutral D. IA is electroposi ve and IIA is electronega ve
Q.323 The depression of freezing point is directly propor onal to
A. Mole frac on of the solu on B. Molarity of the solu on
✓ C. Molarity of the solu on D. Molarity of the solvent
Q.324 Which of the following pair has same shape
✓ A. PH3, NH3 B. H2S, CO2
C. BF3, PCI3 D. SO2, CO2
Q.325 Which of the following compound is not formed according to octet rule:
A. KrF2 B. XeF2
C. XeO3 ✓ D. SF6
Q.326 Which of the following solu on pairs can be separated by frac onal dis lla on
A. Water-HNO3 ✓ B. Benzene-toluene
C. Water-HCI D. C2H5OH
Q.327 The three N - H o-bonds are made by
✓ A. sp3- s overlap B. sp2- s overlap
C. P - p overlap D. sp - overlap
Q.328 When the solute is present in trace quan es the following expression is used
A. Gram per million B. Milligram percent
C. Microgram precent ✓ D. Parts per million
Q.329 Which of the following is isoelectronic with krypton
A. Ca++ B. AI+++
✓ C. Br-1 D. I-1
Q.330 He2molecule is not formed because
A. He is a non-metal B. He is in gaseous state
✓ C. Bond order is zero D. Bond order is 1
_______________________________________________________________________________________
Q.331 Which is following is not a colliga ve property?
A. osmo c pressure ✓ B. density
C. depression of freezing point D. eleva on of boiling point
Q.332 The rela ve lowering of vapour pressure is equal to the mole frac on of the solute.This law is called
A. Henry's law ✓ B. Raoult's law
C. Ostwald's D. Arrhenius law
Q.333 Which of the following molecules has zero dipole moment?
A. NH3 B. CHCI3
C. H 2O ✓ D. BF3
Q.334 Which one of the following statements about nega ve ions is incorrect
A. They are also known as anions B. They are formed atoms gain electrons
C. They are larger than the atom from which ✓ D. They are smaller than the atoms from which
they are formed they are formed
Q.335 Which of the following species has trigonal pyramidal shape
✓ A. H 3O + B. CO3-2
-
C. NO 3 D. BF3
Q.336 Islamian genius told his roommatae that for pure water at room temperature:
A. concept of molality and molarity does not ✓ B. molarity is slight greater than molality
apply
C. molrity is slight greater than molality
D. molaarity os equal to molal y
Q.337 Which one will have lower boiling point?
A. 7.45% KCI ✓ B. 5.58 NaCI
C. 6% urea D. 36 glycerin
Q.338 The property of elements to a ain eight electrons in their valence shell is called
A. Pauli exclusion principle B. Au au's priciple
✓ C. Octet rule D. Hund's rule
Q.339 Which of the following statements is incorrect about ionic compounds:
✓ A. They are gases of room temperature. B. The have regular arrangement of ions.
C. They conduct electricity in molten state. D. they have high mel ng point.
Q.340 Ionic compounds have high
A. m.p B. b.p
✓ C. m.p and b.p D. none of these
Q.341 What is the molarity of H2SO4 solu on that has density of 1.84 gm/cc at 35°C and contains 98% by weight?
A. 4.18 M B. 8.14 M
✓ C. 18.4 M D. 18 M
Q.342 B-atom in BF3has
A. sp3hybridiza on ✓ B. sp2hybridiza on
C. sp hybridiza on D. no hybridiza on
Q.343 Separa on of azeotropic mixture into pure components is carried out by:
A. dis lla on B. vacuum dis lla on
C. frac onal dis lla on ✓ D. none of these
Q.344 Pi bond are produced by overlapping of orbitals
✓ A. Unhybrized orbitals B. Hybrid orbital
C. Hybrid and unhybridized orbitals D. Different orbitals
Q.345 Which of the following is non-polar molecule?
✓ A. CH4 B. H 2O
C. NH3 D. H 2S
Q.346 Ionic radius in a period from le to right
A. Decreases B. Increases
C. First increases then decreases ✓ D. First decreases then increases
y g
Q.347
_______________________________________________________________________________________
A. Sodium atom donates major share of its ✓ B. Hydrogen atom donates the major share of
electrons its electrons
C. Both the atom share the electrons equally D. None of above
Q.348 10ml of 1.5 NaPH solu on is naturalized by 20ml of α-----MHCI solu on , the value of a will he:
A. 0.25 ✓ B. 0.5
C. 0.75 D. 1
Q.349 Which of the bonds, shown by the ______ has the greatest polarity
A. H - Cl B. H - NH2
✓ C. H - OH D. H - SH
Q.350 Which of the following has the greatest covalent character
A. NaCl B. MgCl2
✓ C. SiCl4 D. AlCl3
Q.351 The mass of urea required to prepare 1 dm3 of 10% urea solu on
A. 90 g B. 180 g
✓ C. 100 g D. None of these
Q.352 The tendency of atoms to a ain a maximum of eight electrons is the valence shell is known as:
A. Duplet rule B. Trial rule
✓ C. Octet rule D. Tetrad rule
Q.353 Bond is formed because atom
A. Tries to lose its electrons B. Tries to gain electron
C. Tries to complete its valence shell ✓ D. All of these
Q.354 If the ionic product of a solu on consis on of the type
A. ideal B. saturated
C. supersaturated ✓ D. unsaturated
Q.355 Two H-atom combine to form a strong molecule due to
A. increase in poten al energy ✓ B. decrease in poten al energy
C. energy remains unchanged D. distance is increased
Q.356 Elements having high ioniza on energy are
A. Metal ✓ B. Non metal
C. Liquid D. Solid
Q.357 The structure of ammonia molecule (NH3) is
✓ A. pyramidal B. Linear
C. angular D. square planar
Q.358 Paired electron in a molecule give character of
A. Ferromagne sm B. Paramagne sm
✓ C. Diamagne sm D. Ferrimagne sm
Q.359 Molecular orbital theory explains well
A. stability of molecules ✓ B. all of these
C. paramagne c nature of molecules D. polarity of molecules
Q.360 Measure of the degree of polarity is known as:
✓ A. Dipole moment B. Ionic character of ionic bond
C. Ioniza on energy D. Electron affinity
Q.361 Planar geometry of molecules is due to
A. sp3hybridiza on ✓ B. sp2hybridiza on
C. sp hybridza on D. p - p overlap
Q.362 The bond order in N2molecule is
A. 0 B. 1
C. 2 ✓ D. 3
Q.363 Which of the following is the most polar bond
A. CI - CI B. N-F
✓ C. C-F D. O-F
_______________________________________________________________________________________
Q.364 One dm3 of a buffer solu on containing 0.01M NH4 CI and 0.1 M NH4OH having pKb of has pH of
A. 10 ✓ B. 4
C. 9 D. 6
Q.365 Which of the following elements is not stable:
A. Xe B. Ar
C. Kr ✓ D. Li
Q.366 Which of the following molecules has zero dipole moment?
A. NH3 B. CHCl3
C. H 2O ✓ D. CO2
Q.367 If liquids A and B form an ideal solu on
✓ A. The enthalpy of mixing is zero B. The entropy of mixing is zero
C. The free energy of mixing is zero D. The free energy as well as the entropy of
mixing are each zero
Q.368 The driving force for making a bond is to
A. Make solid compounds B. Make gaseous substrances
✓ C. A ain electronic configura on of noble gas D. Make different compounds
Q.369 Which of the following compound has ionic bond in it:
A. NH3 B. H 2O
C. HCI ✓ D. NaF
Q.370 Which of the following will have the highest boiling point at 1 atm pressure?
A. 0.1 M NaCI B. 0.1 M Sucrose
✓ C. 0.1 M BaCI2 D. 0.1 M Glucose
Q.371 The geometry of 4 sp3hybrid orbitals on an atom is
A. square planar ✓ B. tetrahedral
C. trogonal planar D. linear
Q.372 Number of moles of a solute per Kh of solvent is called:
✓ A. molality B. molarity
C. mole frac on D. normality
Q.373 0.5 M of H2SO4 is diluted from 1 litre to 10 litre.normality of resul ng solu on is
A. 1N ✓ B. 0.1 N
C. 10 N D. 11 N
Q.374 A 0.001 molal solu on of [Pt(NH3)4CI4] in water had a freezing point depression of 0.0054°C.If Kf for water is 1.80, the
correct formula on for the above molecule is
A. [Pt(NH3)4CI3]CI ✓ B. [Pt(NH3)4CI2]CI2
C. [Pt(NH3)4CI]CI3 D. [Pt(NH3)4CI4]
Q.375 Which one of the following is not a conjugate solu on:
A. nico ne + water B. ether + water
✓ C. ethanol + water D. phenol + water
Q.376 (A) Tetracyanomethane (B) Carbon dioxide (C) Benzene (D)1, 3 butadiene Ra o ofσtoπbonds is in order
✓ A. A=B<C<D B. A=B<D<C
C. A=B=C=D D. C<D<A<B
Q.377 Total number of bonding electrons in SF6molecule
A. 8 B. 10
✓ C. 12 D. 14
Q.378 The osmo c pressure of solu on increases if
A. Temperature is decreased B. Solu on constant is increased
✓ C. Number of solute molecules are increased D. Volume is increased
Q.379 The carbon atom in C2H2is
✓ A. sp hybridized B. sp2hybridized
C. sp3hybridized D. non hybridized
Q.380 Which of the following molecules have sp3hybridized carbon
_______________________________________________________________________________________
✓ A. CH4 B. C 2H 4
C. C 2H 2 D. CO2
Q.381 0.5M solu on of NaCI contains
A. 10g NaCI / liter of solu on ✓ B. 20g NaCI / liter of solu on
C. 40g NaCI / liter of solu on D. 89g NaCI / liter of solu on
Q.382 What is the no of unpaired electrons present in NH3 molecule:
A. 3 B. 2
C. 1 ✓ D. 0
Q.383 The decrease in radius is large for:
A. Monovalent ions ✓ B. Trivalent ions
C. Divalent ions D. Atoms
Q.384 The most commonly used unit to measure the dipole moment is
✓ A. Debye B. SI
C. both Debye and SI D. N/m
Q.385 Which of the following show zero dipole moment
✓ A. CH4 B. HF
C. NH3 D. H 2O
Q.386 What of the following is not correct?
A. Triple bond has greater bond energy than B. Polar bond is greater then non-polar bond.
double bond.
C. Sigma bond is greater then pi bond.
✓ D. Single bond is shorter then double bond.
Q.387 A solu on of two components is called:
A. standard solu on B. dilute solu on
C. original solu on ✓ D. Binary solu on
Q.388 Which of the following statements is not correct regarding bonding molecular orbitals?
A. bonding molecular orbitals possess less ✓ B. bonding molecular orbitals have low electron
energy than atomic orbitals from which they density between the two nuclei
are formed C. every electron in the bonding molecular
orbitals contributes to the a rac on between
atoms
D. bonding molecular orbitals are formed when
the electron waves undergo construc ve
interference
Q.389 Which hydrogen halide among the following has the highest percentage of ionic character
✓ A. HF B. HCl
C. HBr D. HI
Q.390 The movement of solvent molecules through a semipermeable membrane is called
A. Electrolysis B. Electrophoresis
✓ C. Osmosis D. Cataphoresis
Q.391 Energy of atom in compound
A. Higher than individual ✓ B. Lesser than individual
C. No change D. Impossible to predict
Q.392 The overlapping of two par ally filled atomic orbital is in such a way that the probability of finding the electron pair is
maximum along the axis joining the two nuclei, the bond is
✓ A. sigma bond B. Pi bond
C. ionic bond D. non-polar
Q.393 1.0 g of pure calcium carbonate was found to require 50 ml of dilute HCI for complete reac on.The strength of HCI
solu on is given by
A. 4N B. 2N
✓ C. 0.4 N D. 0.2 N
Q.394 One of the causes of reac ons is that the systems a ains the energy state which is of
A. Higher in energy ✓ B. Lower in energy
C. Balanced in energy D. Equal in energy
_______________________________________________________________________________________
Q.395 Size of an anion is increased as compared to its atom because of the
A. addi on of new shell ✓ B. repulsion of electrons in the valence shell
C. decrease in nuclear charge D. increase in the nuclear of atoms
Q.396 The process in which solvent molecules surround and interact with solute ions or molecules is called:
✓ A. solva on B. hydra on
C. hydrolysis D. dehydra on
Q.397 Mole frac on of pure water is:
✓ A. exactly equal to one B. slightly greater than one
C. slightly less than one D. none of these
Q.398 If α is the degree of dissocia on of Na2SO4 the van't Hoff's factor (i) used for calcula ng the molecular mass is
A. 1+α B. 1-α
✓ C. 1 + 2α D. 1 - 2α
Q.399 An atom loses or gains electrons, because of
A. Stability B. To form bond
C. To complete its shell ✓ D. All of these
Q.400 Maximum bond angle can be reduced by replacing the 'H' in SbH3with
A. O ✓ B. F
C. CI D. N
Q.401 Electro-nega vely difference for ionic bond must be greater than
A. 1.6 ✓ B. 1.7
C. 1.8 D. 1.0
Q.402 Which of the sub-atomic par cles is not charged
A. Proton ✓ B. Neutron
C. Electron D. All these
Q.403 Nitrogen in NH3is sp3hybridized but the bond angle in NH3is 107° and not 109.5° due to
3
A. sp orbital planar B. sp3orbital trigonal
✓ C. repulsion between lone pair and bonded pair D. none of them
Q.404 H2O is a liquid while H2Sis a gas. Choose the coreect reason to jus fy this fact?
✓ A. H2O has strong hydrogen bonding B. molecular weight
2
S is greater than that
2O
of H of H
C. H - O - H bond angle is greater than H - S -H D. all the above
bond angle
Q.405 The bond formed due to the overlapping of p-orbitals
A. Sigma bond B. Pi-bond
✓ C. Both D. None
Q.406 Units of molarity are
A. gm/lit ✓ B. Mol/lit
C. kg/lit D. None of these
Q.407 Mixing of s and p orbital to from sp2hybrid orbitals is in the ra o of
A. s = 40% + P = 60% B. s = 25% + P = 75%
C. s = 30% + P = 70% ✓ D. s = 33% + P = 67%
Q.408 Which molecule is polar among the following
A. Carbon tetrachloride B. Carbon dioxide
C. Ethane ✓ D. Methanol
Q.409 Which of the following species has the same total number of electrons, as do the Ne atom?
A. Mg+ ✓ B. Na+
C. HCl D. OH-
Q.410 Which of the following is a buffer solu on
✓ A. CH3COOH + CH3COONa B. HCI + NH4CI
C. NaCI + NaOH D. CH3COOH + HCI
Q.411 The covalent radius of CI atom is:
_______________________________________________________________________________________
✓ A. 99.4 pm B. 176.7 pm
C. 38 pm D. 76 pm
Q.412 The molal depression constant depends upon
A. Nature of solute ✓ B. Nature of solvent
C. ΔHSolu on D. Vapour pressure of solu on
Q.413 Metals conduct electricity because
A. they have several valence electrons B. their valence electrons are not involved in
making metallic bond
C. they have la ce of +ve ions ✓ D. they have a la ce of +ve surrounded by
mobile electrons
Q.414 At 25°C the highest osmo c pressure id exhibited by 0.1 M solu on of
✓ A. CaCI2 B. KCI
C. Glucose D. Urea
Q.415 Ioniza on energies increases from le to right along the period due to
✓ A. increase in nuclear charge B. repulsion of electron increases
C. repulsion of protons increases D. atomic size increases along the period
Q.416 Silver amalgam is a solu on consis ng of the type:
A. gas is solute and solid is solvent B. liqiud is solute and solvent is solid
✓ C. liquid is solute and liquid is solvent D. solid is solute and solid is the solvent
Q.417 The electronic configura on of H-us
A. Iso B. Is1
✓ C. Is 2
D. Is22s1
Q.418 Which among the following qualifies as a lewis acid
A. NaF ✓ B. BF3
C. NaCI D. NH3
Q.419 Forma on of chemical bond between atoms of elements is based on
A. Electronega ve character of elements ✓ B. Octer rule `
C. Electroposi ve character of elements D. Pauli exclusion principle
Q.420 Keeping in view the bonding molecular orbitals, find the incorrect statement
A. Every electron in the bonding molecular B. Bonding molecular orbitals possess less
orbital contributes to the a rac on between energy than atomic orbitals from which they
atoms are formed
C. Bonding molecular orbitals are formed when ✓ D. Bonding molecular orbitals have low electron
the electrons waves are undergo construc ve density between the two nuclei
interference
Q.421 If 5.85 g of NaCI are dissolved in 90 g of water the mole frac on of solute is
✓ A. 0.02 B. 0.1
C. 0.2 D. 0.01
Q.422 Number of moles of solute dissolved in 1kg of solvent is called:
✓ A. molarity B. formality
C. molarity D. mole frac on
Q.423 The number of unpaired electrons present in NH3molecules
✓ A. Zero B. 1
C. 2 D. 3
Q.424 Generally ioniza on energy of atoms decreases by
A. decreases in atomic size ✓ B. increases in atomic size
C. increases in nuclear charge D. none of above
Q.425 Generally electron affini es for elements in a period from le to right
A. decreases ✓ B. increases
C. remains same D. increases alterna vely
Q.426 Which statement is incorrect for the molecular orbital theory
A. bonding molecular orbital has lower energy B. bonding molecular orbital is firs filled with
electrons
✓ C. bonding molecular orbitals is formed by D. bonding molecular orbital formed by addi on
_______________________________________________________________________________________
subtrac on of electron waves of atomic of electron waves of atomic orbitals
orbi als
Q.427 A aqueous solu on of ethanol in water has vapour pressure:
A. equal to that of water B. equal to that of ethanol
✓ C. more than that of H2O D. less than that of water
Q.428 When an electron is absorbed in an empty or par ally filled orbital of an atom, the energy released is called
A. ioniza on energy B. poten al energy
✓ C. electron affinity D. bond energy
Q.429 Dipole moment of benzene
A. 1.85 ✓ B. 0.0
C. 0.78 D. Data is insufficient
Q.430 A solu on contains A, B and C components The mole frac on A and C are 0.25 and 0.35 respec vely the mole frac on
B will be:
A. 0.30 B. 0.25
✓ C. 0.40 D. 0.35
Q.431 How much of NaOH is required to neutralize 1500 cm3 of 0.1 N HCI?
A. 60 g ✓ B. 6g
C. 4g D. 40 g
Q.432 The ionic bonds are
A. Unidirec onal B. Bi-direc onal
✓ C. Non-direc onal D. Mul -direc onal
Q.433 In which one of the following does the central atom not possess an octet in its outer shell
A. CH4 ✓ B. BH3
C. NH3 D. H 2O
Q.434 How many g of dibasic acid (mol.wt. 200) should be present in 100 ml of the aqueous solu on to give 0.1 Normality?
✓ A. 1g B. 2g
C. 10 g D. 20 g
Q.435 If 5.85 g of NaCI are dissolved in 90 g of water, the mole frac on of NaCI is
A. 0.1 B. 0.01
C. 0.2 ✓ D. 0.0196
Q.436 Azeotropic mixtures are
A. Mixture of two solids B. Those which can be frac onally dis led
C. Those which boil at different temperatures ✓ D. Those which boil at constant temperature
Q.437 AB4-type with one lone pair, three bond pairs
A. GeH4 B. H 2S
C. SnCI2 ✓ D. PCI3
_______________________________________________________________________________________
5 Chemical Energetics
Q.1 For an endothermic reac on the value ofΔE is denoted by

✓ A. Posi ve sign B. Nega ve sign
C. Without any sign D. None
Q.2 A type of enthlpy which is always posi ve, the enthalpy of
A. Forma on B. Neutraliza on
✓ C. Atomiza on D. Electron affinity
Q.3 The sum of all kinds of energy of system is called internal energy. These energies are
A. Bouncing energy B. Elas c poten al energy
C. All kinds of K.E ✓ D. All of these
Q.4 In exothermic reac ons,∆ H is:
A. Nega ve ✓ B. Posi ve
C. More then products D. Given in surroundings
Q.5 Corrosion is basically a
A. Altered reac on in presence of H2O ✓ B. Electrochemical phenimenon
C. Interac on D. Union between two light metals and a heavy
metal
Q.6 When solid is converted to liquid, entropy is:
✓ A. Increase B. Decrease
C. Zero D. Remains constant
Q.7 The heat of forma on of SO2(g) is -70.9 kcal.The energy required for the decomposi on of 1 mole of SO2(g) is
A. 35.50 kcal ✓ B. 70.9 kcal
C. 141.8 kcal D. -35.9 kcal
Q.8 If a strip of Cu metal is placed in a solu on of FeSO4 then:
A. Cu will be precipitated down ✓ B. Fe is precipitated out
C. Cu and Fe Both dissolve D. no reac on poten al
Q.9 Which of the following values of heat of forma on indicates that the product is least stable?
A. -94 K cal B. -231 K cal
C. + 21.4 k cal ✓ D. + 64.8 k cal
Q.10 The specific conduc on of a o.1 N KCI solu on at 23°C is 0.012 ohm-1
cm-1.The resistance of cell containing the solu on
at the same temperature was found to be 55 ohm.The cell constant will be
A. 0.142 cm-1 ✓ B. 0.66 cm-1
-1
C. 0.918 cm D. 1.12 cm-1
Q.11 A special applica on of the Hess's Law to binary ionic compounds of M+X-type in calcula on of their la ce energies is
A. enthalpy of reac on ✓ B. Born-haber cycle
C. first law of thermodynamics D. enthalpy of combus on
Q.12 The number of coulombs required for the deposi on of 107.870 g of silver is
✓ A. 96500 B. 48250
C. 193000 D. 10000
Q.13 When Cu, Ag,Au and Pt are reacted with acids these metals do not liberate hydrogen this is due to the reason that.
✓ A. Very high posi ve value reduc on poten al B. very low ioniza on poten al values
C. very high nega ve values of reduc on D. reduc on poten al are nega ve
poten al
_______________________________________________________________________________________
Q.14 For a given process, the heat change at constant pressure (p) and constant volume (v)
A. ΔE = q + w B. E=q-w
C. ΔH =ΔE + pΔv ✓ D. ΔH =ΔE
Q.15 The amount of heat is supply at constant volume is 40 KJ at 45°C temperature. Then work done by the system is
A. 40 KJ B. 20 KJ
C. 10 KJ ✓ D. 0 KJ
Q.16 The cathodic reac on in the electrolysis of dil, H2SO4 with Pt electrodes is:
✓ A. reduc on B. oxida on
C. both oxida on and reduc on D. neither oxida on and reduc on
Q.17 Transfer of heat from cold interior part of the refrigerator to the hot surroundings is ______ process
✓ A. Non-spontaneous B. Spontaneous
C. Physical D. Chemical
Q.18 There are how many joules in 1 KWh:
✓ A. 3.6 x 103j B. 6.6 x 103j
C. 9.6 x 103j D. 12.6 x 103j
Q.19 The reac on in which heat is evolved from the system to the surrounding is called
A. endothermic ✓ B. exothermic
C. fast reac on D. emi er
Q.20 The galvanic or voltaic cells which cannot be recharged is called:
A. fuel cells B. infinite cells
✓ C. primary cells D. secondary cell
Q.21 ΔH for an endothermic reaction carries
✓ A. posi ve sign B. nega ve sign
C. both sign D. none of these
Q.22 The electrode through which the electrons enter the electroly c solu on is called:
✓ A. cathode B. anode
C. may be cathode or anode D. none of all
Q.23 If 250 Kj / mole heat is produced from neutraliz on when 10g of solu on reac on to produced 5K temperature change
then specific heat of reac on is
A. 25 KJ g-1k-1 ✓ B. 5 KJ g-1k-1
-1 -1
C. 35 KJ g k D. All of these
Q.24 What is the oxida on number of chormium in ionic compound Na2Cr2O7
A. 2 B. 12
✓ C. 3 D. 6
Q.25 When during electrolysis of a solu on of AgNO3, 9650 coulombs of charge pass through the electropla ng bath, the
mass of silver deposited on the cathode will be
A. 1.08 g ✓ B. 10.8 g
C. 21.6 g D. 108 g
Q.26 The forma on of nitrogen oxide is endothermic then enthalpy change of reac on is ______ KJ/mol
✓ A. 180.51 B. 278.85
C. 285.58 D. 290.87
Q.27 The heat energy change during a chemical reac on at constant pressure and at a given temperature is called
A. change in internal energy ✓ B. enthalpy change
C. temperature change D. work done by the system
Q.28 A cell constant is generally found by measuring the conduc vity of aqueous solu on of
A. BaCI2 ✓ B. KCI
C. NaCI D. MgCI2
Q.29 Strongest reducing agent is
✓ A. K B. Mg
C. AI D. I
_______________________________________________________________________________________
Q.30 In a solu on of CuSO4 how much me will be required to precipitate 2g copper by 0.5 ampere current?
✓ A. 12157.48 sec B. 102 sec
C. 510 sec D. 642 sec
Q.31 96500 C of electricity liberates from CuSO4 solu on
A. 63.5 g of Cu ✓ B. 31.75 g of Cu
C. 96500 g of CU D. 100 g of Cu
Q.32 Enthalpy of neutraliza on of all th strong acids and strong bases has the same value because
and water
C. acids always give +ions and bases always -
ions
✓ D. the net chemical change and -
ions to
involves the combina on of + form
OH
H water
Q.33 Which of the following is directly related with entropy
A. Pressure B. Degree of freedom
C. Temperature ✓ D. Both b and c
Q.34 The standard EMF of Daniel cell is 1.10 volt.The maximum electrical work obtained from the Daniel cell is
✓ A. 212.3 kJ B. 175.4 kJ
C. 106.15 kJ D. 53.07 kJ
Q.35 In electrolysis the chemical reac on occurs at the expense of:
A. heat energy ✓ B. electrical energy
C. chemical energy D. none of all
Q.36 For a given process, the heat changes at constant pressure (qp) and at constant volume (qv) are related to each otehr
as
A. qp= qv B. qp< qv
✓ C. qp> qv D. None of these
Q.37 The proper es or condi ons which describes the system is called as
A. Region ✓ B. State
C. Func on D. All of these
Q.38 Which one of the following cannot be measured by Hess's law?
A. heat of combus on B. enthalpy change
C. heat of dissocia on ✓ D. internal energy
Q.39 Which is not state func on
A. temperature B. enthalpy
✓ C. entropy D. internal energy
Q.40
A. 714.8 kJ B. -1.9 kJ
C. Zero ✓ D. 1.9 kJ
Q.41 IfΔV is zero, then pressure-volume work is
✓ A. zero B. +ve
C. -ve D. both b and c
_______________________________________________________________________________________
Q.42 If the standard electrode poten al of CU2+/Cu electrode is 0.34 V, what is the electrode poten al of 0.01 M
concentra on of Cu2+?(T = 298 K)
A. 0.399 V ✓ B. 0.281 V
C. 0.222 V D. 0.176 V
Q.43 If a salt bridge is removed between the two half cells, the voltage
✓ A. Drops to zero B. Does not change
C. Increases gradually D. Increases rapidly
Q.44 An electrochemical cell in which a spontaneous oxida on reduc on reac on generates electric current is called:
A. dry cell ✓ B. galvanic or voltaic cell
C. electroly c cell D. all above
Q.45 A certain current liberate 0.5 g of hydrogen in 2 h.How many grams of copper can be liberated by the same current
flowing for the same line in a copper sulphate solu on?
✓ A. 12.7 gm B. 15.9 gm
C. 31.8 gm D. 63.5 gm
Q.46 What do you call the apparatus generally used for measuring heat changes?
A. Voltmeter ✓ B. Calorimeter
C. Voltameter D. Coulometer
Q.47 Calculate the amount of charge flowing in 2 minute in a wire of resistance 10 Ω when a poten al difference of 20 V is
applied
A. 120 C ✓ B. 240 C
C. 20 C D. 4C
Q.48 The enthalpy change which occurs when the certain number of moles of reactants as indicated by balanced chemical
equa on, reacts to formed product of standard temperature and pressure is called
✓ A. Entahply of reac on B. Entahply of atomiza on
C. Enthalpy of forma on D. Enthalpy of combus on
Q.49 When a lead storage ba ery is charged then
A. PbO2dissolves ✓ B. Sulphuric acid is regenerated
C. The leaf electrode becomes coated with lead D. The amount of acid decreases
sulphate
Q.50 According to SI-system heat contents are measured in units of
A. calorie ✓ B. joules
C. ergs D. wa s
Q.51 Which is not true for a standard hydrogen electrode
A. The hydrogen ion concentra on is 1M B. Temperature is 25°C
C. Pressure of hydrogen is 1 atmosphere ✓ D. It contains a metallic conductor which does
not absorb hydrogen
Q.52 Which of the following agents is the most oxidizing
✓ A. O3 B. H 2O 2
C. KMnO4 D. K2Cr2O7
Q.53 In the reac on K2Cr2O7 + HCI-----------> KCI + CrCI3 + CI2 + H2O the element which is reduced is:
A. K B. CI
✓ C. Cr D. H
Q.54 When a bond breaks
A. heat is evolved ✓ B. heat is absorbs
C. no change in heat contents takes place D. temperature increases
Q.55 A macroscopic property of a system which describes the ini al and final state of the system is called
A. physical property B. chemical property
C. energy of system ✓ D. state func on
Q.56 KCI is used in salt bridge because
A. It forms a good jelly with agar-agar B. It is strong electrolyte
C. It is a good conductor of electricity ✓ D. The Transference +and -ionsare almost
number of K CI equal
_______________________________________________________________________________________
Q.57 ✓ A. daniel cell B. fuel cell
C. galvanic cell D. electroly c cell
Q.58 When a metal is dipped in 1 molar of its solu on at 298k then poten al set up is called:
A. electric charge B. ioniza on poten al
✓ C. standard electrode poten al D. electropla ng
Q.59 A smuggler could not carry gold by chemically deposi ng iron on the gold surface since
A. Gold is denser B. Iron rusts
✓ C. Gold has higher reduc on poten al then iron D. Gold has lower reduc on poten al then iron
Q.60 The oxida on state of an element is zero when:
A. it forms an oxide B. it is in free state
✓ C. it forms hydride D. only for nobel gasses
Q.61 A calorimeter is an apparatus used for the measurement of
✓ A. heat of reac on B. heat of combus on
C. heat of forma on D. heat of vaporiza on
Q.62 A solu on of sodium sulphate was electrolysed using some inert electrodes. The products at the electrodes are
✓ A. O2,H2 B. O2,Na
C. O2,SO2 D. O2,S2O2-8
Q.63 In a chemical reac on oxida on process involves:
A. increase in oxida on number of all the B. decreases in oxida on number of element
elements in reactants C. Oxida on number neither increases of
element
✓ D. increase in oxida on number of element
Q.64 Enthalpy of combus on of food, fuel and other compounds can be measured by
A. Glass calorimeter ✓ B. Bomb calorimeter
C. Manometer D. Barometer
Q.65 The net heat change in chemical reac on is same whether it is brought in two or more different ways in one or several
steps. it is known as
A. Henry's law B. Joule's principle
✓ C. Hess's law D. Law of conserva on of energy
Q.66 When an exothermic reac on is reversed
A. It becomes another exothermic reac on B. It a ains equilibrium
✓ C. it becomes an endothermic process D. There is no change at all
Q.67 A cell in which chemical energy is converted into electrical energy is called:
A. dry cell ✓ B. electroly c cell
C. fuel cell D. galvanic cell
Q.68 Same amount of electric current is passed through solu ons of AgNO3 and HCI.If 1.08 g of silver is obtained in the first
case,the amount of hydrogen liberated as S.T.P in the second case is:
✓ A. 112 cm3 B. 22400 cm3
C. 224 cm3 D. 1.008 g
Q.69 Hess's law is analogous to
A. law of transforma on B. law of heat exchange
✓ C. law of heat summa on D. law of constant composi on
Q.70 If a spoon of copper metals placed in a solu on of ferrous sulphate then
A. Cu will precipitate out B. Cu and Fe will precipitate
C. Iron will precipitate ✓ D. No reac on will take place
Q.71 A solu on of 500 ml of 0.2 M KOH and 500 ml. of 0.2 M HCl is mixed and s rred, the rise in temperature is T1. The
experiment is repeated using 250 ml. of each of the solu on; the temperature rise is T2. Which of the following is true
______ per mole
✓ A. T 1= T 2 B. T1= 2T2
C. T1= 4T2 D. T2= 9T1
Q.72 A device which converts electrical energy into chemical energy is called:
_______________________________________________________________________________________
✓ A. an electroly c cell B. a galvanic cell
C. a voltaic cell D. a chemical cell
Q.73 Which of the following method does not liberate hydrogen
A. Zn + H2SO4(dil) ✓ B. Cu + H2SO4 (dil)
C. Mg + H2SO4 (dil) D. Zn + HCI (dil)
Q.74 Kine c energy of molecules is due to
A. transna onal mo on B. rota onal mo on
C. vibra onal mo on ✓ D. all of these
Q.75 The SI unit of heat + energy is:
✓ A. Joule B. BTU
C. Calorie D. None of the above
Q.76 For exothermic reac on, the enthalpy change is
C. Neither posi ve nor nega ve D. May be posi ve or nega ve
Q.77 The reac on is spontaneous if the cell poten al is
✓ A. Posi ve B. Zero
C. Nega ve D. Infinite
Q.78 When 0.5 mole of organic is burnt is bomb calorimeter then -242 KJ heat produced the enthalpy of combus on of
given organic compound is ______ KJ / mole
A. -242 ✓ B. -484
C. -363 D. -726
Q.79 Reduc on always occurs:
A. at anode ✓ B. at cathode
C. both (a) and (b) D. none of these
Q.80 A catalyst is a substance which
A. Increases the equilibrium concentra on of the B. Changes the equilibrium constant of the
product reac on
✓ C. Shortens the me to reach equilibrium D. Supplies energy to the reac on
Q.81 Work is a product of force and
✓ A. distance B. area
C. me D. volume
Q.82 Which is the most stable form of C at 25°C?
A. Diamond ✓ B. Graphite
C. Coal D. None of the above
Q.83 Alkaline ba ery has voltage of:
✓ A. 1.5V B. 2.5V
C. 3.5V D. 4.5V
Q.84 Which of the substances Na.Hg S Pt and graphic can be used as electrodes in electroly c cells having aqueous
solu on?
A. Na,Pt and graphite B. Na and Hg
✓ C. Pt and graphic only D. Na and S only
Q.85 A dry alkaline cell has porous Zn anode & MnO2 as cathode the electrolyte used is:
A. Ca(OH)2 B. NaOH
C. NH4OH ✓ D. KOH
Q.86 The enthalpy of neutraliza on of common HCI and NaOH is ______ KJ / mole
A. -52.4 B. -55.4
✓ C. -57.4 D. -58.8
Q.87 The enthalpy of atomiza on of chlorine is ______ KJ / mole
A. 270 B. 240
C. 250 ✓ D. 121
Q.88 Enthalpy changes are measured under standard condi ons which of the following is NOT a standard condi on
_______________________________________________________________________________________
A. a pressure of 100 kilo pascal ✓ B. a temperature of 273 K
C. -3
concentra on of 1 mol dm of a solu on D. reactants and products in their standard
states
Q.89 Which is the oxida on state of oxygen in sodium superoxide?
✓ A. -1/2 B. -2
C. -1 D. +1/2
Q.90
A. X+Y ✓ B. X-Y
C. Y-X D. XY
Q.91 The energy which is sum of all the energies of all the atoms, molecules, or ions with in a system is called:
✓ A. Internal energy B. Bond energy
C. Poten al energy D. Chemical energy
Q.92 Dissocia on of an electrolyte in water into nega ve and posi ve ions is called
✓ A. Ioniza on B. Decomposi on
C. Electrolysis D. Hydrolysis
Q.93 The elctrochemical series is the arrangement of the electrodes in:
A. increasing order of oxida on reduc on B. decreasing order of reduc on poten al
poten al
✓ C. increasing order of reduc on poten al
D. there is no fixed arrangement
Q.94 A substance or a mixture undergoing a physical change is called:
✓ A. System B. Surrounding
C. Compound D. None of the above
Q.95 When electricity is passed through molten electrolyte consis ng of alumina and cryolite, 13.5 g of AI are deposited.The
number of faradays of electricity passed must be
A. 2.0 ✓ B. 1.5
C. 1.0 D. 0.5
Q.96 Any substance under going physical or chemical change is said to be
A. Surrounding ✓ B. System
C. Losphere D. Lithosphere
Q.97 Internal energy of a system is equal to
A. kine c energy of par cles B. poten al energy due to binding forces
between par cles
C. Sum of kine c energy plus poten al energy of ✓ D. heat contents
the par cles
Q.98 N2and O2are present in air but they don't react chemically at ordinary condi ons of temperature and pressure because
it is a
A. spontaneous reac on B. reversible reac on
C. exothermic reac on ✓ D. non-spontaneous reac on
Q.99 Entropy is a measure of _____ system:
✓ A. Disorder B. Internal energy
C. Input D. Efficiency
Q.100 Pick out the wrong statement. In electrochemical cell
A. Electrons are released at anode ✓ B. Cathode is regarded as nega ve electrode
C. Chemical energy is converted into electrical D. Salt bridge maintains the electrical neutrality
energy of the solu on.
Q.101 The conduc vity of strong electrolyte
✓ A. Increases on dilu on slightly B. Does not change on dilu on
C. Decreases on dilu on D. Depends on density of electrolyte it self.
Q.102 If a strip OF Cu metal is placed in a solu on of FeSo4 then:
_______________________________________________________________________________________
C. Cu and Fe both dissolve D. no reac on takes place
Q.103 The enthalpy of combus on of ethyl alcohol is ______ KJ / mole
A. -1240 B. -1302
✓ C. -1368 D. -1397
Q.104 There are how many joules in 1 kilocalorle?
✓ A. 4.184 x 103J B. 8.184 x 103J
3
C. 12.184 x 10 J D. 16.184 x 103J
Q.105 The measurement of degree of disorder is
A. Internal energy B. Enthalpy
✓ C. Entropy D. None
Q.106 The condi on for standard enthalpy change is
A. 1 atm 30°C B. 1 atm 50°C
✓ C. 1 atm 25°C D. 760 atm 25°C
Q.107 One kilocalrie is equal to
✓ A. 4.184 x 103J B. 4.184 x 104J
C. 4.184 x 102J D. none of these
Q.108 A joule is equal to:
A. 1kg2/S2 B. 1kg/S2
✓ C. 1kgm2/S2 D. None of the above
Q.109 The substance having highest conduc vity at room temperature among the following is
A. 0.1 N HCI B. 0.1 N NaCI
✓ C. Graphite D. Glass
Q.110 Which of the following is the use of electrolysis?
✓ A. Electrorefining B. Electropla ng
C. Both A and B D. None of the above
Q.111 What will be the weight of deposited silver on passing 965 coulombs of electricity in solu on of AgNO3?
✓ A. 1.08 g B. 2.16 g
C. 0.54 g D. 0.27 g
Q.112 La ce energy of NaCl
A. +5000 KJ B. -344 KJ
✓ C. -776 KJ D. -411 KJ
Q.113 When electricity is passed through molten AI2O3 + Na3AIF6 and 13.5 gms of AI are deposited, the number of faraday
must be
A. 0.5 B. 1.0
✓ C. 1.5 D. 2.0
Q.114 In endothermic reac ons the heat content of the
✓ A. Products is more than that of reactants B. Reactants is more than that of products
C. Both a and b D. None of the above
Q.115 For an endothermic reac on whereΔH represent the enthalpy of the reac on in KJ mole-1the minimum value for the
energy of ac va on will be
A. ΔH B. Zero
✓ C. >Δ H D. <Δ H
Q.116 The change in heat energy at constant temperature is called
A. enthalpy change ✓ B. heat of vaporisa on
C. bond energy D. internal energy change
Q.117 What is not a state func on?
✓ A. Temperature B. Enthalpy
C. Entropy D. Internal energy
Q.118 What is the value of internal of an element of 25°C at atmospheric pressure?
✓ A. 0 cal/mole B. 10 cal/mole
_______________________________________________________________________________________
C. 50 cal/mole D. 273 cal/mole
Q.119 To predict whether a reac on will occur spontaneously or not it is necessary to study the ______ of the system
✓ A. Free energy B. Free heat
C. Free work D. Free enthalpy
Q.120 The law which states the amount of heat evolved or absorbed in a process is the same whether the process takes
place in one or several steps is called
A. first law of thermodynamics ✓ B. Hess's law
C. law of conserva on of energy D. second law of thermodynamics
Q.121 mental usually conduct electricity because
A. metals have high resistance B. metals are decomposed by current
C. in metals the ions are free to more ✓ D. they are mobile electrons in the metallic
structure
Q.122 Glass calorimeter is usually used to determine the
A. Enthalpy of forma on B. Enthalpy of solu on
C. Enthalpy of neutraliza on ✓ D. Both b and c
Q.123 Enthalpy of neutraliza on of all the strong acis and strong bases has the same value because
and water C. acids always give +ions and bases always -
ions
✓ D. the net chemical change +and -
ions to
form
involve the combina on of H OH
water
Q.124 The SI unit for heat and energy is
✓ A. Joule B. K.Calorie
C. Calorie D. K.Wa hours
Q.125 The amount of heat evolved or absorbed in a chemical reac on, when the molar quan es of products and reactants
being the same as represented in chemical equa on, is called
✓ A. heat of reac on B. free energy of reac on
C. entropy of reac on D. none of these
Q.126 The chemical reac ons in which heat energy is released is called
✓ A. exothermic B. endothermic
C. none of these D. both of these
Q.127 By applying Hess's law, we can calculate
✓ A. ΔH B. ΔS
C. ΔF D. K
Q.128 For an exothermic reac on, the sign of enthalpy wiil be
A. nega ve B. posi ve
✓ C. zero D. none of these
Q.129 The reference calomel electrode is made from which of the following?
A. ZnCI2 B. CuSO4
✓ C. Hg2CI2 D. HgCI2
Q.130 For a give process, the heat changes at constant pressure (qp) and at constant volume (qv) are related to each other as
A. qp= qv B. qp< qv
✓ C. qp> qv D. qp= qv/2
Q.131 The branch of chemistry which deals with thermal energy changes in chemical reac ons is called
A. chemical kine c B. thermodynamics
✓ C. thermochemistry D. mechanics
Q.132 The energy required to break one mole of bonds to form neutral atom is called
A. bond length B. bond strength
✓ C. bond energy D. none of these
Q.133 Molar heat capacity of water in equilibrium with ice at constant pressure is
A. Zero ✓ B. Infinity
_______________________________________________________________________________________
C. 40.45 KJ k-1 D. 75.48 J k-1mol-1
Q.134 Quan ty of heat evolved or absorbed during the reac on is measured according to the equa on
✓ A. q = m x sp. heat xΔT B. ΔE = q + w
C. ΔH =ΔE + PΔV D. PΔV = nRT
Q.135 When quan ty of electricity passed is one faraday then the mass deposited at the electrode is equal to
A. One gm.atomic weight ✓ B. One gm.Equivalent weight
C. Electrochemical equivalent D. None of the above
Q.136 Energy can neither be created nor destroyed, although it can be transformed from one form to another. This is a
statement of
A. law of conserva on of ma er B. law of definite propor ons
✓ C. law of conserva on of energy D. none of these
Q.137
A. 1307 k cal ✓ B. 27.4 k cal

C. 6.85 k cal D. 3.425 k cal
Q.138 Which of the following is NOT an exothermic reac on
A. respira on B. dissolu on of NaOH in water
C. freezing ✓ D. vaporisa on
Q.139 The amount of heat evolved or absorbed during a reac on is same either reac on take place in one step or several
step is
A. 2nd law of thermochemistry B. Hess's law
C. 1st law of thermochemistry ✓ D. Both A and B
Q.140 The galvanic or voltaic cells which are rechargeabel called as:
A. primary cell ✓ B. secondary cells
C. infinite cell D. dry cells
Q.141 If heat is evolved in the reac on, the process is said to be
C. isothermal D. adiaba c
Q.142 The sum of all the energies of atoms, molecule, ion, within system is called
A. Enthalpy B. K.E of the system
✓ C. Internal energy D. None
Q.143 Silver oxide ba ery has a voltage of:
A. 1V ✓ B. 1.6V
C. 2V D. 2.5V
Q.144 Since the enthalpy of elements in their natural state is taken as zero, the heat of forma on of Hf is:
✓ A. Always nega ve B. Posi ve
C. Depending on condi on D. Is zero
Q.145 If an endothermic reac on is allowed to take place very rapidly in the air, the temperature of the system
C. Remains constant D. No effect
Q.146 Any property which depends upon the state of system is called:
A. Enthalpy ✓ B. State func on
C. Free energy D. Internal energy
Q.147 Strong the oxidizing agent greater is the:
A. oxida on poten al ✓ B. reduc on poten al
C. redox poten al D. e.m.f of cell
Q.148 In electrolysis oxida on takes place at
A. Both the eletrodes ✓ B. Anode
C. Cathode D. In the solu on
Q.149 Evapora on of water is a:
_______________________________________________________________________________________
✓ A. An endothermic change B. An exothermic change
C. No heat change occurs D. Chemical energy is produced
Q.150 A system undergoes a change to a ain the state of
A. high energy ✓ B. low energy
C. moderate energy D. none of these
Q.151 A complete of gas changes from P1and V1& T1to P1V1& T2by one path and then back to P1V1and T1∆ E for the process
is:
A. Infinite ✓ B. >0
C. <0 D. =0
Q.152 Heat of neutraliza on of weak acid and a strong base is
A. 13.7 kcal ✓ B. less than 13.7 kcal
C. greater than 13.7 kcal D. none of these
Q.153 Electrochemical series is a list of elements arranged into the increasing order of their:
A. cell voltage B. ioniza on poten al
✓ C. standard reduc on poten al D. standard oxida on poten al
Q.154 Which is an example of endothermic change
A. 6CO2(g) + 6H2O(I)→ C6H-12O6(g) + CO2(g) B. H2O(g) → H2O(I) +∆H
✓ C. C3Og→ CO2(g) ∆H D. None of above
Q.155 which is the correct statement about the following reac on?
2Fe +3Ci2----------> 2FeCI3
✓ A. Fe is oxidized B. Fe is reduced
C. Cl2is oxidized D. no one is correct
Q.156 A current of 9,65 ampere flowing for 10 minutes deposits 3.0 g of the metal which is monovalent.The atomic mass of
the metal is
A. 10 ✓ B. 50
C. 30 D. 96.5
Q.157 A state func on represent:
A. Physical state B. Chemical state
✓ C. Thermodynamic state D. None of above
Q.158 The standard e.m.f of a galvanic cell involving cell reac on with n = 2 is found to be 0.295 V at 25°C.The equilibrium
constant of the reac on would be
✓ A. 1.0 x 1010 B. 2.0 x 1011
C. 4.0 x 1012 D. 1.0 x 102
Q.159 The entropy of the universe
A. constant B. is equal to zero
C. decreasing ✓ D. increasing
Q.160 When lead accumulator is charged it is
✓ A. An electroly c cell B. A Daniel cell
C. A Galvanic cell D. None of these
Q.161 The amount of electricity that can deposit 108 g of silver from silver nitrate solu on is
A. 1 ampere B. 1 coulomb
✓ C. 1 Faraday D. 2 ampere
Q.162 The heat contents of all the elements in their standard states are taken to be
A. 1 B. 2
✓ C. 0 D. None
Q.163 Which is he oxida on number of nitrogen in the molecule N2?:
✓ A. 0 B. 3
C. 5 D. 7
Q.164 The amount of heat supply at constant pressure is 18 KJ / mole at 45°C. Then the enthalpy of system is
A. 9 KJ / mole ✓ B. 18 KJ / mole
_______________________________________________________________________________________
C. 27 KJ / mole D. 36 KJ / mole
Q.165 Which of the following metals is most readily corroded in moist air
A. Copper B. Silver
✓ C. Iron D. Nickel
Q.166 A state func on of the system which describes together the internal energy and the work done is called
A. enthalpy B. internal energy
C. work ✓ D. free energy
Q.167 Spontaneous reac on is such in which the system decreases its _________
✓ A. Energy B. Free energy
C. Entropy D. All
Q.168 Out of Cu,Ag,Fe and Zn the metal which can displace all others from their salt solu ons is
A. Ag B. Cu
✓ C. Zn D. Fe
Q.169 Heat absorbed by a system when its volume does not change is equal to
✓ A. internal energy of system B. enthalpy of system
C. increase in internal energy of system D. increase in enthalpy of system
Q.170 Specific conduc vity of a solu on
A. Increases with dilu on ✓ B. Decreases with dilu on
C. Remains unchanged with dilu on D. Depends on mass of electrolyte.
Q.171 In an exothermic reac on
A. enthalpy of reactants is lesser than that of ✓ B. enthalpy of reactants is greater than that of
products products
C. heat is transfered form surronded into the D. enthalpy of reactants and products same
system
Q.172 An example of a simple fuel cell is
A. Lead storage ba ery B. Daniel cell
✓ C. H2 - O2 cell D. Silver oxide cell
Q.173 If pressure on the mole gas is 2 Nm-2produced 3m3volume change and enthalpy of system is 9 J/mole the internal
energy of system is
A. 12 J / mole B. 6 J / mole
✓ C. 3 J / mole D. 9 J / mole
Q.174
A. -68.39 + 48 - 14 ✓ B. -68.39 - 48 + 14
C. 68.39 - 48 + 14 D. 68.39 + 48 + 14
Q.175 The heat content of system is called
A. Internal energy ✓ B. Enthalpy
C. Entropy D. None
Q.176 The equivalent conduc vity of 0.1 M week acid is 100 mes less than that at infinite dilu on.The degree of
dissocia on is
A. 100 B. 10
✓ C. 0.01 D. 0.001
Q.177 By means of fuel cells chemical energy may be converted into:
A. sound energy ✓ B. electrical energy
C. heat energy D. magne c energy
Q.178 The surface which separate system and surroundings is called
✓ A. Boundary B. Area
C. Line D. All of these
_______________________________________________________________________________________
Q.179
✓ A. -196 KJ mol-1 B. 146 KJ mol-1

-1
C. -494 KJ mol D. -98 Kj mol-1
Q.180 Which of the following is not a state func on
A. pressure B. temperature
C. enthalpy ✓ D. amount of substance
Q.181 The amount of heat evolved or absorbed at constant volume is to change ______ of system
A. Work done B. Enthalpy
✓ C. Internal energy D. All of these
Q.182 One calorie is equal to
A. 5.184 J B. 3.184 J
✓ C. 4.184 J D. 7.184 J
Q.183 The enthalpy of forma on of MgO is ______ KJ / mole
A. -393.7 ✓ B. -692
C. -285.7 D. -474.7
Q.184 The heat content of all elements in their standard states is taken as:
✓ A. 0 B. Maximum
C. Minimum D. Unity
Q.185 When the forma on of bond is more than breakage of bond then reac on is
A. Endothermic ✓ B. Exothermic
C. Hydrothermic D. Felothermic
Q.186
A. -1802 KJ B. +1802 KJ
C. -800 KJ ✓ D. +228 KJ
Q.187 Any property which depends upon the T, P and V is said to be
A. Property due to K.E B. Property due to P.E
C. both a and b ✓ D. Thermodynamic state
Q.188 The example of state func on is
A. Heat B. Work
C. Mole ✓ D. Enthalpy
Q.189 Standard reduc on electrode poten al of three metals A,B and C respec vely +0.05 V, -3.0 and -1.2 V. The reducing
power of
✓ A. B>C>A B. A>B>C
C. C>B>A D. A>C>B
Q.190 An electrolyte
A. Forms complex ions in solu on B. Gives ions only when electricity is passed
✓ C. Possesses ion even in solid state D. Gives ions only when dissolved in water
Q.191 When a pressure of 500 Nm is applied the volume will change from 0.5 m3to 0.03 m3then work done by the system is
-2
A. 10 J ✓ B. -10 J
C. -5 J D. +5 J
Q.192 Which of the following gains electrons more easily
_______________________________________________________________________________________
A. Na+ B. AI+3
C. Zn2+ ✓ D. H+
Q.193 In electropla ng the ar cle to be electroplated serves as
✓ A. Cathode B. Anode
C. Electrolyte D. Conductor
Q.194 Glass calorimeter reac on is one which we measure
A. Enthalpy of combus on ✓ B. Enthalpy of reac on
C. Pressure volume work D. None of above
Q.195 Bomb calorimeter is usually used to determined the enthalpy of
A. Reac on B. Forma on
✓ C. Combus on D. Neutraliza on
Q.196 During a chemical reac on heat may be
A. absorbed B. evolved
✓ C. both evolved and absorbed D. none of these
Q.197 Preven on of corrosion of iron by Zn coa ng is called
✓ A. Galvaniza on B. Cathodic protec on
C. Electrolysis D. Photoelectrolysis
Q.198 96500 C electricity is passed through CuSO4.The amount of copper precipitated is
A. 0.25 mole ✓ B. 0.5 mole
C. 1.0 mole D. 2.00 mole
Q.199 A spontaneous change is one in which a system suffers:
A. Increase in internal energy ✓ B. Lowering in free energy
C. Lowering of entropy D. No energy change
Q.200
A. Zero B. 54 kJ mol-1
✓ C. Less then 57 kJ mol-1 D. More than 57 kJ mol-1
Q.201 Molten sodium chloride conducts electricity due to the presence of
A. Free electrons B. Free molecules
✓ C. Free ions D. Free atoms of Na and CI
Q.202 Best way to prevent rus ng of iron is by
✓ A. Making iron cathode B. Pu ng it in saline water
C. Both of these D. None of these
Q.203 If more bonds are broken than the bonds formed, the reac on will be
A. Exothermic B. Endothermic
C. Both ✓ D. None
Q.204 The art of electropla ng was given by
✓ A. Faraday B. Edison
C. Thomas Gradam D. Brugan
Q.205 The enthalpy of neutraliza on of HCl by NaOH nunder certain condi on is -55.9 J and that of HCN by NaOH is -12.1 KJ.
The enthalpy of ioniza on of HCN is
A. -68.0 KJ mole-1 B. -43.8 KJ mole-1
C. 68.0 KJ mole-1 ✓ D. 43.8 KJ mole-1
Q.206 The oxidizing strength of an element depend upon:-
A. its ioniza on energy B. its electron affinity
✓ C. its electrode poten al D. its oxida on poten al
Q.207
_______________________________________________________________________________________
The amount of heat required of heat required to convert one mole of solid directly into its vapour state at STP is called
as
✓ A. Molar heat of vaporiza on B. Standard heat of vaporiza on
C. Heat of reac on D. Heat of neutraliza on
Q.208 If the bridge is not used between to half cells then the voltage:
✓ A. decrease rapidly B. decreases slowly
C. does not change D. drops to zero
Q.209 A process is said to be ___ if the temperature remains constant throughout:
A. Adiabe c ✓ B. Isothermal
C. Endothermic D. Exothermic
Q.210 WhenΔH for a reaction is a negative quantity the reaction is said to be
A. reversible B. at equilibrium
✓ C. exothermic D. endothermic
Q.211 In a Galvanic cell
A. Chemical energy is converted into electricity B. Chemical energy is converted into heat
✓ C. Electrical energy is converted into heat D. Electrical energy is converted into chemical
energy.
Q.212 Which element has the same has oxida on number in all of its known compounds?
A. beryllium B. chlorine
✓ C. nitrogen D. sulphur
Q.213 One joule is equivalent to ______ calorie
✓ A. 1/4.184 B. 1/41.84
C. 4.184 D. 41.84
Q.214 All the naturally processes proceed with the:
A. Increase of energy ✓ B. Decrease of energy
C. None of above D. All of above
Q.215 The process of electrical of one metal on another to protect decorate or to have a greater resistance to corrosion is
called?
A. Conduc on ✓ B. electropla ng
C. electrolysis D. induc on
Q.216 Which of the following is a strong electrolyte?
✓ A. Ca(NO3)2 B. HCN
C. CH3COOH D. NH4OH
Q.217 The unit of enthalpy is
A. N/m2 B. KJ
✓ C. KJ / mole D. All of these
Q.218 Which condi ons among the following are maintained for the measurement of standard electrode poten al of the
electrode?
A. solu on of nay strength at 25°C compared ✓ B. solu on of 1 molar strength at 298K
with S.H.E compared with S,H.E
C. 1 Molar solu on and at 0°C D. solu on of nay strength at any with
temperature and electrode connected S.H.E
Q.219 What will be the density of H2SO4 when lead accumulator is recharged?
A. 1.15 gcm-3 B. 1.181 gcm-3
C. 2.15 gcm-3 ✓ D. 1.25 gcm-3
Q.220 The branch of chemistry, which deals with the thermal energy change during a reac on is called
A. Hydrodynamics B. Thermodynamics
✓ C. Thermo chemistry D. Hydrolic
Q.221 Two half cells of a galvanic cell are connected by:
A. copper electrode B. hydrogen electrode
✓ C. salt bridge D. ammeter
Q.222
_______________________________________________________________________________________
The la ce enthalpy of sodium fluoride is much greater than that of cesium fluoride.which statement electronega ve
than
A. sodium is more electronega ve than cesium B. sodium has higher mel ng point than cesium
C. the atomic radius of cesium is greater than ✓ D. the ionic radius of sodium is smaller than
that of sodium that of cesium
Q.223 In endothermic reac ons, the heat content of the
✓ A. Products is more than that of reactants B. Reactants is more than that of products
C. Both a and b D. None of the above
Q.224 The values ofΔH andΔE are approximately the same for the process in case of liquids and solids because
A. there is no change in temperature ✓ B. no change in volume
C. heat is absorbed D. heat is released
Q.225 Which property depends on the state of system
A. enthalpy B. free energy
C. entropy ✓ D. all these
Q.226 In passage of electricity through aqueous solu on of AgNo3 silver dissolves at anode to form Ag+ the electrodes are:
A. silver metal B. graphite
C. Pt metal ✓ D. copper metal
Q.227 The energy of the system and surrounding is conserved. This is a statement of
A. law of mass ac on B. law of definite propor on
✓ C. law of conserva on of energy D. second law of thermodynamics
Q.228 Which of the following is an exothermic reac on
✓ A. Combus on of methane B. Decomposi on of water
C. Dehydrogena on of ethane to ethane D. Conversion of graphite to diamond
Q.229 The mathema cal form of first law of thermodynamics is
A. ΔE = q - w B. ΔD = q + w
C. W =ΔE + q ✓ D. q =ΔE - w
Q.230 IfΔH is less than zero, the reac on will be
✓ A. Exothermic B. Work
C. Gibb's free energy D. Enthalpy
Q.231
A. 13.7 k. Cal ✓ B. 27.4 K. Cal

C. 6.85 K. Cal D. 3.425 K. Cal
Q.232 The unit of specific conduc vity is
-1 -2
A. Ohm cm B. Ohm cm
C. Ohm-1cm ✓ D. Ohm-1cm-1
Q.233 Which substances haveΔH =ΔE?
A. solids B. liquids
C. gases ✓ D. liquids and solids
Q.234 Oxida on states of carbon atoms in diamond and graphite are
A. +2,+4 B. -4,4
C. +4,+2 ✓ D. Zero
Q.235 Chose the best reducing agent among the following:
✓ A. I
-1
B. F
-1
-1 -1
C. Br D. CI
Q.236 Entropy of universe tends towards:
A. Maximum B. Minimum
C. Zero ✓ D. Remains constant
Q.237 Which statement is correct about the life period of a galvanic cell?
A. increases with decreases in the size of the B. it increases with increase in the concentra on
_______________________________________________________________________________________
anode of anodic solu on
✓ C. it increases with increase with increase in D. it increases with decrrese in the size of
concentra on of cathodic solu on cathode
Q.238 The reference electrode is made by using
A. ZnCI2 B. CuSO4
C. HgCI2 ✓ D. Hg2CI2
Q.239 The amount of heat evolved or absorbed by keeping reactants and products at one atmospheric pressure at room
temperature is called
A. Heat of forma on B. Standard heat of forma on
✓ C. Standard enthalpy change D. None
Q.240 The process in which chemical change occurs on passing electricity is termed
A. Ioniza on ✓ B. Electrolysis
C. Neutraliza on D. Hydrolysis
Q.241 oxida on number of carbon in NaHCO3 is :
A. +2 ✓ B. +4
C. +6 D. -6
Q.242 According to Hess's law:
A. Kp=Kc(RT)a B. ∆ H = positive
✓ C. ∆ H is same whither process takes D. None of above
places in one step or more then one
step
Q.243 The smallest unit of heat energy is
A. Calorie B. Joule
✓ C. Erg D. Kilocalorie
Q.244 Heat absorbed or released during the chemical reac on of physical process at constant pressure is equal to
A. ΔE ✓ B. ΔH
C. q D. w
Q.245 Which compound is most stable on the basis of theΔH0fvalues given in parenthesis
-1
A. C3H8(g) [ - 103.8 KJ mole ] B. C4H12(g) [ -124.7 KJ mole-1]
C. n - hexane [ -167.2 KJ mole ] -1 ✓ D. n- octane [ -208.4 KJ mole-1]
Q.246 A reac on in which heat transfer between the reac on vessel and large quan ty of water can take place, will be
exothermic if:
A. Heat is transferred from water to the contents ✓ B. Heat contents of reac ons are more than the
of reac on vessel heat contents of products
C. Products have more heat than reac ons D. None of above
Q.247 Thermochemistry is the study of rela onship between heat, energy and:
A. Kine c energy ✓ B. Chemical energy
C. Energy ac va on D. Ioniza on energy
Q.248 When the degree of freedom increases the entropy __________
A. Decreases ✓ B. Increases
C. Remains same D. All
Q.249 The net heat change in a chemical reac on is same whether it is brought about in two or more different ways in one or
several steps. it is known as
A. Henry's law B. Joule's principle
✓ C. Hess's law D. law of conserva on of energy
Q.250 If a exothermic reac on is allowed to take place very rapidly in the air, the temperature of the surrounding air
A. Remains constant ✓ B. Increase
C. Decrease D. Remains unchanged
Q.251
A. Enthalpy of atomiza on B. Enthalpy of neutraliza on

_______________________________________________________________________________________
C. Enthalpy of combus on ✓ D. Enthalpy of solu on
Q.252 2.5 faradays of electricity is passed through solu on of CuSO4.The number of gram equivalents of copper deposited on
the cathode would be
A. 1 B. 2
✓ C. 2.5 D. 1.25
Q.253 Under the process of rus ng of iron, 4fe 3O2-------->2Fe2O3, iron is:
A. Hydrolyzed B. precipitated
✓ C. oxidized D. rduced
Q.254 An oxidizing agent in a chemical reac on is the substance which:
A. loses electrons ✓ B. gains electrons
C. acts as a catalyst D. pH is changed
Q.255 The electric conduc on of a salt solu on is water depends on the
A. Shape of molecules B. Size of solvent
C. Size of its molecules ✓ D. Extent of its ioniza on
Q.256 Heat, work and internal energy of the system and surroundings are related into an equa on which is called
✓ A. first law of thermodynamics B. Hess's law
C. Henry's law D. Born-haber cycle
Q.257 The subject ma er of thermo chemistry is based on the
✓ A. First law of thermo chemistry B. 2nd law of thermo chemistry
C. 3rd law of thermo chemistry D. 4th law of thermo chemistry
Q.258 Reac on takes place at anode is
A. Ioniza on B. Reduc on
✓ C. Oxida on D. Hydrolysis
Q.259 Out of Ci,Ag,Fe and Zn the metal which can displace all others from their salt solu on is
A. Ag B. Fe
C. Cu ✓ D. Zn
Q.260 Pure water does not conduct electricity because it
A. Has low boiling point ✓ B. Is almost unionized
C. Is neutral D. Is readily decomposed
Q.261 If heat absorbed in the reac on, the process is said to be
A. exothermic B. isothermal
C. adiaba c ✓ D. endothermic
Q.262 When electric current is used to carry out non-spontaneous redox reac on the process is called:
A. decomposi on ✓ B. electrolysis
C. neutraliza on D. hydrolysis
Q.263 When a piece of zinc is added to the CuSO4solu on blue-color of the solu on disappears due to the spontaneous
______ reac on
✓ A. Redox B. Neutraliza on
C. Combus on D. Atomiza on
Q.264 The heat of forma on of graphite and P(white) is _________ KJ/mole
✓ A. 0.00 B. -273.0
C. +8.7 D. 813.99
Q.265 If the bonds in product molecules are stronger than, in reactants, the reac on will be
C. Isothermal D. None
Q.266 The standard enthalpy change in the forma on of 1 mole of a compound form its elements in their standard physical
states is
✓ A. enthalpy of forma on B. enthalpy of atomiza on
C. enthalpy of neutraliza on D. internal energy change
Q.267 Born-Haber cycle is an applica on of
_______________________________________________________________________________________
A. first law of thermodynamics B. second law of thermodynamics
C. First law of thermodynamics ✓ D. Hess's law
Q.268 Standard reduc on poten al of F is highest in the electrochemical series which is:
A. 1.87 ✓ B. 2.87
C. 3.87 D. 4.87
Q.269 TheΔH for a reaction is -110 Kcal/mole, which shows that the reaction is
C. not stable D. it needs catalyst
Q.270 The enthalpy change does not depend upon:
A. Condi ons under which reac on is carried out ✓ B. Number of intermediate steps involved
C. State of reac on and products D. Ini al and final energies and enthalpies of
reac on and products
Q.271 Which of the following (1M) conducts more electricity?
✓ A. Sulphuric acid B. Boric acid
C. Nitric acid D. Phosphorus acid
Q.272 The heat of neutraliza on of a strong acid and strong alkali is 57.0 kJ mol-1The heat released when 0.5 mole
HNO3solu on is mixed with 0.2 mole of KOH is
A. 57.0 kJ ✓ B. 11.4 kJ
C. 28.5 kJ D. 34.9 kJ
Q.273 The amount of heat evolved or absorbed in a process in the same whether the process takes place in one or several
steps is the statement of
A. first law of thermodynamics ✓ B. Hess's law
C. Coulomb's law D. Phase law
Q.274 More electronega ve elements have
A. Nega ve reduc on poten al ✓ B. Posi ve reduc on poten al
C. Tendency to lose electrons D. Posi ve oxida on poten al
Q.275 Time required to deposit one millimole pf aluminium metal by the passage of 9.65 amperes through molten
electrolyte containing aluminium ion is
✓ A. 30 s B. 10 s
C. 30,000 s D. 10,000 s
Q.276 The limi ng molar conduc vi es ∧° for NaCI, KBr and KCI are 126, 152 and 150 S cm2 respec vely.The ∧° for NaBr is
✓ A. 128 S cm2mol-1 B. 302 S cm2mol-1
C. 278 S cm2mol-1 D. 176 S cm2mol-1
Q.277 One calorie is equal
A. 4.132 J B. 760 J
✓ C. 4.184 J D. 1J
Q.278 For spontaneity of a cell, which is correct?
A. Δ G = 0,Δ E = 0 B. Δ G = -ve, ΔE = 0
C. Δ G = +ve,ΔE =0 ✓ D. Δ G = -ve
Q.279 The specific conductance of 0.1 M NaCI solu on is 1.06 x 10-2 ohm-1 mol-1,Its molar conductance in ohm-1 cm2 mol-1 is
✓ A. 1.06 x 10 2
B. 1.06 x 103
C. 1.06 x 104 D. 53
Q.280 Which of the following statements is correct about Galvanic cell?
A. anode is nega vely charged B. reduc on occurs at anode
C. cathode is posi vely charged ✓ D. reduc on occurs at cathode
Q.281 In a Galvanic cell,the electron flow from
A. Anode to cathode through the solu on B. Cathode to anode through the solu on
✓ C. Anode to cathode through the external D. Cathode to anode through the external circuit
circuit
Q.282 The amount of heat evolved or absorbed in a chemical reac on indicated by balanced chemical equa on at 25° and
one atmospheric pressure is called
A. enthalpy of forma on B. enthalpy of neutraliza on
_______________________________________________________________________________________
C. enthalpy of combus on ✓ D. enthalpy or reac on
Q.283 The enthalpy of solu on of sodium carbonate is ______ KJ /mole
A. +16.2 B. +25.0
C. -16.2 ✓ D. -25.0
Q.284 The heat contents of a system is called:
✓ A. Internal energy B. Enthalpy
C. Combus on energy D. Heat energy
Q.285 In a hydrogen-oxygen fuel cell,combus on of hydrogen occurs to
A. Generate heat B. Remove adsorbed oxygen from electrode
surface
C. Produce high purity water ✓ D. Create poten al difference between two
electrodes
Q.286 The enthalpy of la ce of NaCl is ______ KJ / mole
A. -878 ✓ B. -787
C. -777 D. +787
_______________________________________________________________________________________
6 Electrochemistry
Q.1 The Cathodic reac on in the electrolysis of dil, H2SO4with Pt electrodes is:
✓ A. Reduc on B. Oxida on
C. Both oxida on and reduc on D. Neither oxida on and reduc on
Q.2 The electrochemical series is the arrangement of the electrodes in
A. Increasing order of oxida on reduc on B. Decreasing order of reduc on poten al
poten al
✓ C. Increasing order of reduc on poten al
D. There is no fixed arrangement
Q.3 The mathema cal rela on between the rate of reac on and the concentra on of reactants is called:
A. Arhenius equa on ✓ B. rate law
C. rate equa on D. both B and C
Q.4 Standard electrode poten al is also called
A. standard oxida on poten al B. standard reduc on poten al
✓ C. standard poten al D. cell poten al
Q.5 In electrolysis, the chemical reac on occurs at the expense of
A. Heat energy ✓ B. Electrical energy
C. Chemical energy D. None of all
Q.6 The reac on 2H2O2 → 2H2O + O2 is, r = k [H2O2]
A. Zero order reac on ✓ B. First order reac on
C. Second order reac on D. Third order reac on
Q.7 Which is the oxida on state of oxygen atom is sodium superoxide
✓ A. -1/2 B. -2
C. -1 D. 1/2
Q.8 The average rate and instantaneous rate of a reac on are equal:
A. at the end B. in the beginning
✓ C. when me interval of two rates is zero D. when molar concentra ons of the reactants
are unity
Q.9 A substance which retards the rate of reac on is called:
A. auto catalyst B. ac vators
✓ C. inhibitor D. all the above
Q.10 A standard hydrogen electrode is used as standard electrode of which electrode poten al is arbitrarily taken as
A. +1 B. -1
C. 0.1 ✓ D. zero
Q.11 Caus c soda is obtained by electrolysis of conc. aqueous solu on of NaCL in a cell called
A. Daniell's cell ✓ B. Nelson' cell
C. Down's cell D. Voltaic cell
Q.12 The efficiency of fuel is
A. 70% ✓ B. 75%
C. 80% D. 85%
Q.13 Ioniza on is the process in which ionic compounds when fused or dissolve in the water split up into charged par cles
called:
A. Atoms B. Electrons
C. Protons ✓ D. Ions
_______________________________________________________________________________________
Q.14 Oxida on of oxalic acid by acidified KMnO4 is an example of autocatalyst, it is due to which of the following?
A. SO2-4 B. MnO2-4
✓ C. Mn 2+
D. K+
Q.15 Greater the value of standard reduc on poten al of a given species
✓ A. greater is its tendency to accept electron to B. greater is its tendency to accept electrons to
undergo reduc on undergo oxida on
C. greater is its tendency to lose electrons to D. greater is its tendency to lose electrons to
undergo reduc on undergo oxida on
Q.16 A student started to work on 100g of a compound whose half-life is 5 hours,how much compound is le a er 25
hours:
✓ A. 3.125g B. 6.25g
C. 12.5g D. 25g
Q.17 A chemical reac on is catalysed by X. Hence X
✓ A. Does not affect equilibrium constant of the B. Decreases rate constant of the reac on
reac on
C. Reduces enthalpy of reac on
D. Increases ac va on energy of the reac on
Q.18 The oxida on number of free element is always taken to be
✓ A. 0 B. 1
C. 2 D. -1
Q.19 The statement is correct for reduc on
A. Removal of electron ✓ B. Addi on of hydrogen
C. Addi on of oxygen D. Addi on of carbon
Q.20 According to Arrhenius equa on rate constant of a chemical
✓ A. Ae-Ea/RT B. AeRT/Ea
C. AeEa/RT D. Ae-RT/Ea
Q.21 Which property of liquid is measured by polarimeter:
A. conductance ✓ B. op cal ac vity
C. refrac ve index D. change in volume
Q.22 A single cell voltage in lead storage ba ery is?
A. 2.5 volt B. 1.0 volt
C. 1.3 volt D. 2.3 volt
✓ E. 2.0 volt
Q.23 The electrolysis of sodium chloride solu on is carried out in ______ cell.
A. Castner keliner B. Cu-Hg cell
✓ C. Both A and D D. Nelson
Q.24 Which types of metals are usually used as catalyst?
A. coinage metal B. alkali metals
✓ C. transi on metals D. alkaline earth metals
Q.25 The rate of a reac on can be increased in general by all the factors except by
A. Using a catalyst B. Increasing temperature
✓ C. Increasing the ac va on energy D. Increasing the conc, of reactants
Q.26 The number of atoms or molecules whose concentra on determines the rate of a chemical reac on is called:
✓ A. order of reac on B. rate constant of the reac on
C. molecularity of the reac on D. specific ac vity of the reac on
Q.27 The oxida on number of Cr in Cr2O-27is
A. +12 ✓ B. +6
C. -12 D. -6
Q.28 Instantaneous rate of a chemical reac on is:
A. rate of reac on in the end B. rate of reac on in the beginning
C. rate of reac on between specific interval ✓ D. rate at any one given instant of me interval
Q.29
_______________________________________________________________________________________
✓ A. Fe is oxidized B. Fe is reduced
C. Cl2is oxidized D. No one is correct
Q.30 Electro chemistry is concerned with the conversion of electrical energy into chemical energy in ______ cell
A. Galvanic B. Voltaic
✓ C. Electroly c D. Both A and B
Q.31 Oxida on number of oxygen in OF2is
A. +1 B. -1
✓ C. +2 D. -2
Q.32 Which of the following statement is incorrect about SHE(standard hydrogen electrode)
✓ A. Reduc on +2is ions when it is B. H2gas passed in it at 1 atm pressure
poten al of smaller +occupied with cooper
Cu than H electrode C. Its oxida on poten al and reduc onal
D. It is made of pla num (wire dipped in HCL
solu on
Q.33 In lead accumulator the electrolyte H2SO4solu on is
✓ A. 30% H2SO4 B. 60% H2SO4
C. 80% H2SO4 D. 90% H2SO4
Q.34 Electrochemistry is concerned with the conversion of electrical energy into chemical energy in:
A. Galvanic cell B. Electroly c cell
C. Voltaic cell ✓ D. Both (a) and (c)
Q.35 The two half cells of a galvanic cell are connected by
A. Copper electrode B. Hydrogen electrode
✓ C. Salt bridge D. Ammeter
Q.36 75% of a first order reac on was completed in 32 minutes.When was 50% of the reac on completed?
✓ A. 16 minutes B. 24 minutes
C. 8 minutes D. 32 minutes
Q.37 Which of the following yield both hydrogen and chlorine on electrolysis:
A. Electrolysis of acidified water B. Electrolysis of molten NaCI
✓ C. Electrolysis of aqueous NACI D. Electrolysis is saline water
Q.38 Which statement is incorrect for balancing of redox reac ons by ion-electron method
A. the reac on is spli ed into two half reac ons and+ions are added for acidic or neutral
B. H2O
H reac on to balance O and H
✓ C. to balance H, HCl is added D. to balance O and H in the alkaline -
added
reac on OH
Q.39 1 dm3 of 2 M CH3COOH is mixed with 1 dm3 of 3 M ethanol to from ester.The decrease in the ini al rate if each
solu on is diluted with an equal volume of water would be
A. 2 mes B. 4 mes
✓ C. 0.25 mes D. 0.5 mes
Q.40 In electrolysis, the electrode itself oxidized is act as
A. Cathode ✓ B. Anode
C. Electrode D. May be anode or cathode
Q.41 With the progression of the reac ons, the slope of the curve between concentra on of products and me:
✓ A. no change occurs in slope B. gradually becomes less steep
C. gradually becomes more steep D. none of all
Q.42 The rate at which a substance reacts depends on its
A. Atomic weight B. Equivalent weight
C. Molecular weight ✓ D. Ac ve mass
Q.43 Oxidizing power of an element depends upon its
✓ A. Oxida on poten al B. Ioniza on energy
C. Electron affinity D. Electrode poten al
_______________________________________________________________________________________
Q.44 For which of the following the units of rate and rate constant of the reac on are inden cal
A. First order reac on B. Second order reac on
✓ C. Zero order reac on D. Frac onal order reac on
Q.45 The half period of 14
6C is 5760 years 100 mg of sample will be reduced to 25 mg in:
A. 5760 years ✓ B. 11520 years
C. 57600 years D. 2880 years
Q.46 A catalyst increases rate of reac on by
A. Decreasing enthalpy B. Decreasing internal energy
✓ C. Decreasing ac va on energy D. Increasing ac va on energy
Q.47 Effect of temperature on reac on rate is given by
A. Claisen-Clapeyron equa on ✓ B. Arrhenius equa on
C. Gibbs-Helmholtz equa on D. Kirchoff's equa on
Q.48 The amount of 53I128,(I1/2 = 25min) le a er 50min is:
A. 1/8 B. 1/2
✓ C. 1/3 D. 1/4
Q.49 The value of reduc on poten al of metal is nega ve for metal then metal act as ______ agent
A. Oxidizing ✓ B. Reducing
C. Metallic D. All
Q.50 Which one of the following is correct statement about ba ery and cell:
A. A cell has more than one ba eries B. Ba ery is another name for cell
C. A ba ery is chargeable whereas cell is not ✓ D. A ba ery has more than one cells
Q.51 A dry alkaline cell has porous Zn anode & MnO2as cathode the electrolyte used is
A. Ca(OH)2 B. NaOH
C. NH4OH ✓ D. KOH
Q.52 What is the oxida on number of chromium in ionic compound Na2Cr2O7
A. 2 B. 12
C. 3 ✓ D. 6
Q.53 In a chemical reac on, oxida on process involves
A. Increase in oxida on number of all the B. Decrease in oxida on number of element
elements in reactants C. Oxida on number neither increases nor
decreases
✓ D. Increase in oxida on number of element
Q.54 A cell in which electric current is produced as a result of spontaneous redox reac on is called:
A. Dry cell B. Electroly c cell
✓ C. Galvanic cell D. Half cell reac on
Q.55 The dimensions of rate of reac on are:
A. mol dm-3s-2 ✓ B. mol dm-3s-1
C. mol dm-3 D. mol-1dm-6s-2
Q.56 The galvanic or vol c cells which cannot be recharged is called
A. Fuel cells B. Infinite cells
✓ C. Primary cell D. Secondary cell
Q.57 The rate of an irreversible reac on:
A. increases with increase in concentra on of ✓ B. increases with the increase in concentra on
reactants of products
C. decreases with increase in concentra on of D. decreases with increase in concentra on of
reactants products
Q.58 The dimension of rate constant of a second order reac on involves
A. Neither me nor concentra on B. Only me
✓ C. Time and concentra on D. Time and square of concentra on
Q.59 Addi on of iron and zinc to copper sulphate causes precipitaion of copper which occurs due to the
A. Ionisa on of CuSO4 B. Oxida on of Cu++
C. Hydrolysis CuSO4 ✓ D. Reduc on of Cu++
_______________________________________________________________________________________
Q.60 In an electroly c cell, the electrons flow from:
A. Cathode to anode or opposite B. Cathode to anode
✓ C. Anode to cathode D. Random flow
Q.61 Electrolysis is used for:
A. Manufacture of caus c soda B. Refining of copper
C. Electropla ng ✓ D. All of above
Q.62 Which of the following is not a redox reac on
A. B.
✓
C. D.
Q.63 A scien st prepared a compound in laboratory.He found that it had two forms. One amorphous form A and another
crystalline form C both A and C reacts with sulphuric acid. One possible predic on is that:
A. increases with in increase in concentra on of ✓ B. increases with increases in concentra on of
product reactants
C. decreases with increases in concentra on of D. decreases with increase in concentra on of
products reactants
Q.64 For a chemical reac on A → B, it is found that the rate of reac on doubles when the concentra on of A is increased
four mes.The order in A for this reac on is
A. Two B. One
✓ C. Half D. Zero
Q.65 The reac on take place at electrode when electricity pass through the solu on of electrolyte is called
A. Hydrolysis B. Hydrous
✓ C. Electrolysis D. May be all
Q.66 The rate of a reac on that does not involve gases,does not depend upon
✓ A. Pressure B. Temperature
C. Concentra on D. Catalyst
Q.67 Stronger the oxidizing agent, greater is the:
A. Oxida on poten al ✓ B. Reduc on poten al
C. Redox poten al D. E.M.F of Cell
Q.68 Silver oxide ba ery has a voltage of
A. 1V ✓ B. 1.6 V
C. 2V D. 2.5 V
Q.69 Choose the cell among the following list in which conversion of electrical into chemical energy takes place
✓ A. Daniel cell B. Fuel cell
C. Galvanic cell D. Electroly c cell
Q.70 In the electrolysis of aqueous solu on of sodium nitrate, the ions which are reduced at the cathode are
✓ A. H 3O + B. Na+
C. OH- D. NO3
Q.71 K, Ca and LI metals may be arranged in decreasing order of their reduc on poten al as:
A. Li, K, Ca B. Ca, K, Li
C. Li, Ca, K ✓ D. K, Ca, Li
Q.72 Give t1/2 = 3 hr, then how many gram of a substance will remain a er 18th hr from 300 gram of a substance
✓ A. 4.6 gm B. 5.6 gm
C. 9.2 gm D. 6.4 gm
Q.73 Rancidity produced in bu er can be decreased by adding quinoline to the bu er this statement shows that:
✓ A. quinoline is an inhibitor B. quinoline is a ac vator
C. quinoline is a catalyst D. nothing is impossible
Q.74 In measurement of Electrode poten al the salt bridge is used to provide a highly between the two electroly c solu on
A. Induc ve path ✓ B. Conduc ve path
C. Diodive path D. All
_______________________________________________________________________________________
Q.75 Cell in which electric current drives a non-spontaneous reac on is called
✓ A. Electroly c cell B. Voltaic cell
C. Biological cell D. Electrochemical cell
Q.76 Reac ons with high ac va on energy:
A. fast B. moderate
✓ C. slow D. does not take place
Q.77 When molten sodium chloride undergoes electrolysis, the ion reduces is
A. Both Na+and Cl- B. Cl-
✓ C. Na +
D. None of these
Q.78 According to collision theory the rate of the reac on is equal to:
✓ A. number of effec ve collision B. number of collsion
C. concentra on of productss D. concentra on of reactants
Q.79 In KO2the oxida on state of oxygen is
A. -2 B. -1
C. +1/2 ✓ D. -1/2
Q.80
A. H+1/H2O ✓ B. OH-1/ H2O

C. SO4-2/H2O D. All of these
Q.81 Cell poten al depends upon:
A. Concentra on of ions B. Nature of electrolyte
C. Temperature ✓ D. All of above
Q.82 The effect of a catalyst in a chemical reac on is to change the
✓ A. Ac va on energy B. Heat of reac on
C. Equilibrium concentra on D. Final products
Q.83 most metals are conductors of electricity because of the:
A. Light wight B. Immobility of the electrons
C. Lustrous surfaces ✓ D. Rela vely free movement of their electrons
Q.84 When a metal is dipped in 1 molar of its solu on at 298 k, then poten al set up is called
A. Electric charge B. Ioniza on poten al
✓ C. Standard electrode poten al D. Electropola ng
Q.85 The me taken for 90% of a first order reac on to complete is approximately
A. 1.1 mes that of half life B. 2.2 mes that of half life
✓ C. 3.3 mes that of half life D. 4.4 mes that of half life
Q.86 For a given reac on t1/2 = 1/ka. The order of reac on is
A. 1 B. 0
C. 3 ✓ D. 2
Q.87 Lead accumulator contains
A. 30% NaCl solu on as electrolyte B. 30% HCl solu on as electrolyte
✓ C. 30% H2SO4solu on as electrolyte D. 30% NaOH solu on as electrolyte
Q.88 According to law of Mass Ac on,rate of a chemical reac on is propor onal to
A. Concentra on of reactants ✓ B. Molar concentra on of reactants
C. Concentra on of products D. Molar concentra on of products
Q.89 The func on of salt bridge in the galvanic or voltaic cell is to
A. carry out oxida on at anode B. to carry out reduc on at cathode
C. carry out electrolysis ✓ D. to prevent the net charge accumula on in
either of the half cells
Q.90 Which statement is correct for the fuel cells
✓ A. these cells operate at low temperature B. these cells operate at low temperature
C. no catalyst used for the forma on of water D. MnO2is used as electrolyte
Q.91 Which of the following statements is true about Galvanic cell?
_______________________________________________________________________________________
A. anode is nega vely charged B. reduc on occurs at anode
C. cathode is posi vely charge ✓ D. reduc on occurs at cathode
Q.92 While balancing an equa on by ion electron method, the number of oxygen atoms are balanced by
A. OH- ✓ B. H 2O
C. O2 D. H+
Q.93 If the rate of reac on between A and B is given by rate = K[A][B]2 then the reac on is
A. First order in A B. Third order overall
C. Second order in B ✓ D. All are correct
Q.94 Zn metal can displace ______ from its solu on
A. K B. Mg
C. Ca ✓ D. Cd
Q.95 Electrode poten al is effected by
A. Concentra on B. Temperature
C. Pressure ✓ D. All
Q.96 The ac va on energy for a reac on is 90 kcal mol-1 the approximate increase in rate constant , when it's temp is
increase from 300k to 310k is:
A. 10% B. 50%
C. 63.25% ✓ D. 100%
Q.97 In the electrolysis of fused bauxite (Al2O3. 2H2O) with fused Cryolite (Na3AlF6) using carbon rods as anode, the product
obtained at cathode is
A. Na metal B. F2gas
✓ C. Al metal D. O2gas
Q.98 Metallic conduc on is also called as:
A. Ionic conduc on B. Protonic conduc on
✓ C. Electronic conduc on D. Super conduc on
Q.99 The electrode through which the electrons enter the electroly c solu on is called
✓ A. Cathode B. Anode
C. May be cathode or anode D. None of all
Q.100 In a voltaic cell the electric current in the ______ can be used to light a bulb, drive a motor and so on
A. Solu on B. Molten electroly c
C. Internal circuit ✓ D. External circuit
Q.101 For first order reac on, the half life period is independent of
✓ A. Ini al concentra on B. Cube root of ini al concentra on
C. First power of final concentra on D. Square root of final concentra on
Q.102 Electroly c cell can be used for the purifica on of copper wire
A. impure copper is made the anode B. a thin sheet of pure copper is made the
cathode
C. copper sulphate solu on is used as an ✓ D. all the above
electrolyte
Q.103 Lead accumulator stops discharging current when
A. lead at anode converted to PbO2 B. PbO2at cathode converted to Pb
✓ C. Both electrodes are completely covered
4
D. Both electrodes are completely covered with
2
with PbSO Pb(OH)
Q.104 An electrochemical cell is based upon
A. Acid-base reac on ✓ B. Redox reac on
C. Nuclear reac on D. None of the above
Q.105 Select the change among the following in which transfer of five electrons take place
✓
A. B.
C. D.
Q.106 The cell which is used in space vehicles is ______ cell
_______________________________________________________________________________________
A. NICAD B. Alkaline
✓ C. Fuel D. All
Q.107 The rate of reac on is doubled for 10°C rise in temperature. The increase in the reac on rate as a result of
temperature rise from 10°C to 100°C is
A. 112 ✓ B. 512
C. 1400 D. 614
Q.108 Corrosion reac ons are
✓ A. Spontaneous redox reac on B. Non-spontaneous acid-base reac ons
C. Spontaneous acid-base reac ons D. None of these
Q.109 The rate of reac on
A. increases as the reac on proceeds ✓ B. decreases as the reac on proceeds
C. remains unchanged D. may increase of decrease as the reac on
proceeds
Q.110 The unit of rate constant is same as that the rate of reac on in:
A. 1st order reac on B. 2nd order reac on
✓ C. zero order reac on D. 3rd order reac on
Q.111 Half life of the reac on becomes half when ini al concentra ons of reactants are made double The order of the
reac on will be
A. First order B. Third order
✓ C. Second order D. Zero order
Q.112 Standard hydrogen electrode has an arbitrarily fixed poten al:
A. 1.0 volt B. 0.34 volt
✓ C. 0.0 volt D. 0.84 volt
Q.113 The rate constant of a reac on at temperature 200 K is 10 mes less than the rate constant at 400 K. What is the
ac va on energy (Ea) of the reac on? (R = gas constant)
A. 1842.4 R ✓ B. 921.2 R
C. 460.6 R D. 230.3 R
Q.114 Metals usually conduct electricity because
A. Metals have high resistance B. Metals are decomposed by current
C. In metals the ions are free to more ✓ D. They are mobile electrons in the metallic
structure
Q.115 In electroly c cells, the chemical changes may be:
A. Either spontaneous or non-spontaneous B. Always spontaneous
✓ C. Always non-spontaneous D. More spontaneous and less non-spontaneous
Q.116 The brown ring complex compound is formulated as [Fe(H2O)5(NO)]SO4. The oxida on state of iron is
A. +1 ✓ B. +2
C. +3 D. +0
Q.117 The cell which generates electricity as a result of spontaneous oxida on-reduc on reac on is called
A. electroly c cell B. Nelson's cell
✓ C. Galvanic cell D. Down's cell
Q.118 Which of the following statement regarding catalyst is not true?
A. A catalyst remains unchanged in composi on ✓ B. A catalyst can ini ate a reac on
and quan ty at the end of the reac on
C. A catalyst does not alter the equilibrium in a
reversible reac on
D. Catalysts are some mes very specific in
respect of reac on.
Q.119 If the rate of reac on for:
2A +B ----------> products is K[A]2 [B] and A is present in large excess, then order of reac on is:
✓ A. 1 B. 2
C. 3 D. none of these
Q.120 A cell which produced electrical current by an oxida on reduc on reac on is called:
A. Electroly c cell ✓ B. Voltaic cell
C. Daniel cell D. Dry cell
_______________________________________________________________________________________
Q.121 What are the products of the electrolysis of brine?
A. hydrogen and chlorine only B. chlorine and NaOH only
✓ C. hydrogen, chlorine and NaOH only D. NaOH only
Q.122 Which increase in10°C of temperature the rate of reac on doubles, This increase in rate of reac on is due to:
A. decrease inac va on energy of reac on B. decrease in the number of collisions between
reactant molecules
✓ C. increase inac va on energy of reactants D. increase in number of effec ve collisions
Q.123 Standard reduc on poten al of F is highest in the electrochemical series which is
A. 1.87 ✓ B. 2.87
C. 3.87 D. 4.87
Q.124 During redox reac on an oxidizing agent
✓ A. Gains electrons B. Is oxidized
C. Loses electrons D. Hydrolysed
Q.125 During electrolysis, the reac on that takes place at cathode is:
✓ A. Reduc on B. Both (a) and (c)
C. Oxida on D. No reac on occurs
Q.126 The rate of reac on between A and B increases by a factor of 100, when the concentra on with respect to A is
increased 10 folds, the order of reac on w.r.t. A is
A. 10 B. 1
C. 4 ✓ D. 2
Q.127 Zn does not displace Mg from MgSO4solu on because
A. Zn is more electroposi ve than Mg ✓ B. Zn is below Mg in electrochemical series
C. Zn is above Mg in electrochemical series D. Zn is trivalent Mg is divalent
Q.128 The oxida on number of Mn is KMnO4is
A. +2 B. +4
C. +6 ✓ D. +7
Q.129 For a chemical reac on......can never be a frac on
A. Order B. Half-life
✓ C. Molecularity D. Rate constant
Q.130 Standard hydrogen electrode has an arbitrary fixed poten al of
✓ A. 0.00 volt B. 1.00 volt
C. 0.10 volt D. 1.20 volt
Q.131 Which is correct about zero order reac on?
A. Rate of reac on depends on decay constant ✓ B. Rate of reac on is independent of
concentra on
C. Unit of rate constant is conc-1 D. Unit of rate constant is conc-1
Q.132 When KCI3 is heated, it decomposes into KCI and O2. If some MnO2 is added, the reac on goes much faster because
A. MnO2decomposes to give O2 B. MnO2provides heat by reac ng
C. Be er contact is provided by MnO2 ✓ D. MnO2acts as a catalyst
Q.133 The reac on A ---->. B follows a second order kine cs. when we double the concentra on of A it will increases the
rate of reac on by a factor of:
A. 2 B. 1/2
✓ C. 4 D. 1/4
Q.134
A. Cr°(s)under goes in reduc on B. Cr°(s)under as oxidizing agent

✓ C. Fe(s)is cathode D. Fe3+(aq)ac ng as reduc on agent
Q.135 The compound which acts both as oxidising as well as reducing agent is
✓ A. SO2 B. MnO2
C. Al2O3 D. CrO3
_______________________________________________________________________________________
Q.136 Fuel cells are mostly used in space are aircra as the source of :
A. Fuel and drinking watrw B. Drinking water only
C. Power only ✓ D. Drinking water and power
Q.137 Collision theory is applica on to
A. First order reac ons B. Zero order reac ons
✓ C. Bimolecular reac ons D. Intermolecular reac ons
Q.138 In Passage of electricity through aqueous solu on of AgNO3silver dissolves at anode to form Ag+the electrodes are
✓ A. silver metal B. Pt metal
C. graphite D. copper metal
Q.139 When Cu, Ag, Au and Pt are reacted with acids, these metals do not liberate hydrogen, This is due to the reason that
✓ A. Very high posi ve value of reduc on B. Very low ioniza on poten al values
poten al
C. Very high nega ve values of reduc on
poten al
D. Reduc on poten als are nega ve
Q.140 When we increase the temperature the rate of reac on increases because of
A. More number of collisions B. Decrease in mean free path
✓ C. More number of energe c collisions D. Less number of energe c collisions
Q.141 A reac on will be spontaneous if its calculated emf is:
A. Posi ve or nega ve B. Nega ve
C. Zero ✓ D. Posi ve
Q.142 Choose the best reducing agent among the following
✓ A. I-1 B. F-1
C. Br-1 D. CI-1
Q.143 By means of fuel cells, chemical energy may be converted into
A. Sound energy ✓ B. Electrical energy
C. Heat energy D. Magne c energy
Q.144 TEL minimizes the knocking effect when mixed with petrol it acts as
A. Posi ve catalyst B. Autocatalyst
✓ C. Nega ve catalyst D. Induced catalyst
Q.145 In electro chemical cell, ______ reac on cause to produce electricity
A. non-spontaneous B. Spontaneous
✓ C. Spontaneous redox D. Non-spontaneous redox
Q.146 The electrodes are hollow tubes made of porous compressed carbon impregnated with ______, which acts as a
catalyst
A. Cupper B. Cadmium
C. V 2O 5 ✓ D. Pla num
Q.147 Electrochemical series is useful in
A. predic on of the feasibility of a chemical B. calcula on of voltage
reac on
C. comparison of rela ve tendency of metals to
get oxidized or reduced
✓ D. all the above
Q.148 In the presence of copper electrolysis of dil.H2SO4with Pt electodes
✓ A. reduc on B. oxida on
C. both oxida on and reduc on D. neither oxida on or reduc on
Q.149 Units of rate constant for the first and zero order reac ons in terms of molarity. M units are respec vely
✓ A. Sec-1, M sec-1 B. Sec-1 M
-1 -1
C. M sec , sec D. m, sec-1
Q.150 What are the products of electrolysis of aqueous sodium chloride at two electrodes:
A. Chlorine at anode and oxygen at cathode B. Hydrogen at anode and chlorine at cathode
✓ C. Chlorine at anode and hydrogen at cathode D. Chlorine at anode and sodium at cathode
Q.151 Choose the incorrect statement from the following:
A. ✓ B. the order of reac on is determined by the
the order of reac on is an experimental
_______________________________________________________________________________________
quan ty stoichiometric calcula on of the reac on
C. the order or reac on is the sum of the powers D. the order of reac on may be given zero or
of the concentra on terms in the rate law frac onal
Q.152 If ini al concentra on of reactant and half life period of the reac on is Known, then we can determine.
✓ A. order of reac on B. rate constant (k)
C. order of reac on D. instantaneous rate
Q.153 emf of the cell is:
A. Sum or difference of two electrodes poten als ✓ B. Sum of two electrode poten als
C. difference of two electrode poten als D. Always zero
Q.154 Which statement is incorrect about standard hydrogen electrode (SHE)
A. Its oxida on and reduc on poten al is zero B. it consists of a Pt wire dipped in 1 molar HCl
solu on
✓ C. the electrolyte is 1 molar NaOH solu on D. H2gas is passed in it at 1 atmospheric pressure
Q.155 Coinage metals like Au, Pt, Ag and Cu are the least reac ve metals and don't liberate H2gas when treated when acids
because
✓ A. these have very high posi ve values of B. these have high nega ve values of reduc on
reduc on poten als poten als
C. their ioniza on poten als are lowest D. their reduc on poten als are close of SHE
Q.156 The chemical method used for the determina on of the rate of reac on is:
A. refractometric B. conductometric
✓ C. tra on D. spectroscopic
Q.157 In a compound an atom has nega ve oxida on states because
A. atom is nega vely charged B. atom acts as cathode
✓ C. atom is more electronega ve D. atom has lowest ioniza on energy
Q.158 The galvanic or viltaic cells which are rechargeable called as
A. primary cells ✓ B. secondary cells
C. dry cells D. infinite cells
Q.159 When the concentra on of a reactant in the reac on is increased by 8 me, the rate increases only 2 me the order of
reac on is
A. 1 B. 2
✓ C. 1/2 D. 1/3
Q.160 An electrochemical cell in which a spontaneous oxida on reduc on reac on generates electric current is called
A. Dry cell ✓ B. Galvanic or voltaic cell
C. Electroly c cell D. All above
Q.161 Standard reduc on of Zn = -0.76 V and that of Ni is -0.25 V. On coupling them by a salt bridge which of these will act as
anode
A. salt bridge will act as anode ✓ B. Zn will act as anode
C. Ni will act as anode D. None of these
Q.162 The two half cells of a gavanic, cell are connected by
A. ammeter ✓ B. salt bridge
C. hydrogen electrode D. copper electrode
Q.163 The func on of salt bridge is:
A. To increase movement of ions B. To increase the emf of cell
C. To decrease the temperature ✓ D. To maintain electrical neutrality
Q.164 Sodium can be obtained by:
A. Electrolysis of acidified water B. By hea ng NaCI and water at 100°
✓ C. Electrolysis of molten sodium chlorine D. Electrolysis of aqueous sodium chlorine
Q.165 If the rate of the reac on is equal to the rate constant, the order of reac on is
A. 3 ✓ B. 0
C. 1 D. 2
Q.166 A dry alkaline cell has porous Zn anode and MnO2as cathode the electrolyte used is
A. Ca(OH)2 B. NaOH
✓ C. KOH D. NH4OH
_______________________________________________________________________________________
Q.167 Which statement is incorrect for fuel cells:

A. H2and O2used as fuels B. Aqueous KOH is used as electrolyte in fuel cell
C. Water is produced in the cells ✓ D. They operate at very low temperature
Q.168 Sulphur dioxide bleaches colouring ma er by
A. Oxida on ✓ B. Reduc on
C. Dehydrogena on D. Dehydra on
Q.169 The ions are produced in the ______ due to ioniza on of the electrolyte
A. Solu on state B. Solid state
C. Molten state ✓ D. Both A & C
Q.170 Which statement is incorrect about the catalyst?
A. cataly c reac ons are very specific in nature ✓ B. a catalyst can ini ate the reac on which is
not thermodynamically favourable
C. a catalyst remains unchanged a er D. a catalyst does not alter the equilibrium in a
comple on of reac on reversible reac on
Q.171 Why is a diaphragm cell used in the electrolysis of brine?
A. to prevent hydrogen from reac ng with ✓ B. to prevent chlorine from reac ng with NaOH
chlorine
C. to prevent Na+from reac ng with NaOH
D. to allow Na+to leave the Anode compartment
Q.172 A cell in which electrical current is produced by redox reac on is called
A. dry cell B. unit cell
✓ C. voltaic cell D. ba ery cell
Q.173 Factor which slows down the rate of reac on is:
A. high temperature of the reac on B. more concentra on of rractants
C. small sizeof the par cles of thereactants ✓ D. lowing the temperature
Q.174 The experimental rela onship between a reac on rate and
concentra on of reactants is called:
A. order of reac on ✓ B. law of mass ac on
C. rate law D. molecuylarity
Q.175 The oxida on number of "Mn" in KMnO4
A. +6 ✓ B. +7
C. +8 D. +5
Q.176 Glucose and fructose are converted into C2H5OH in the presence of
A. Invertase B. Maltase
C. Diastase ✓ D. Zymase
Q.177 The value of SHE is cathode and anode is always taken to be
A. one ✓ B. zero
C. Different D. same
Q.178 The chemical reac on is feasible when the value of cell poten al is
C. May be posi ve or nega ve D. Zero
Q.179 Which of the following metal is very close to SHE and react very slowly with steam to liberate hydrogen gas
A. Al B. Mn
✓ C. Ni D. All
Q.180 Strong reducing agents have
A. Greater posi ve value of standard reduc on ✓ B. Greater nega ve value of standard reduc on
poten al poten al
C. Lesser posi ve value of standard reac on D. None of these
poten al
Q.181 To measure the electrode poten al of zinc, a ______ is established
✓ A. Voltaic cell B. Electroly c cell
C. Conduc ve cell D. All
Q.182
_______________________________________________________________________________________
______ the value of standard reduc on poten al of a metal lesser it's tendency to lose electrons to form metal ions
and so weaker its tendency to displace hydrogen from acid
A. Less ✓ B. Greater
C. Moderate D. May be all
Q.183 When aluminum electrode is coupled with copper electrode in a galvanic cell:
A. Reduc on takes place at aluminum electrode B. Oxida on takes place at aluminum electrode
✓ C. Reduc on takes place at copper electrode D. Both (a) and (b)
Q.184 Which condi on among the following are maintained for the measurement of standard electrode poten al of the
electrode
A. Solu on of nay strength at 25°C compared ✓ B. Solu on of 1 molar strength at 298 K
with S.H.E compared wit S.H.E
C. 1 Molar solu on and at 0°C D. Solu on of nay strength at any temperature
and electrode connected with S.H.E
Q.185 The conduc on of electricity through electrolyte solu on due to ______ is called electroly c conduc on
A. Free ions B. Free proton
C. Ions ✓ D. May be all
Q.186 The oxida on states of the most electronega ve element in the products of the reac on BaO2with dilute H2SO4are
A. 0 and -1 ✓ B. -1 and -2
C. -2 and 0 D. -2 and +1
Q.187
A. 0 B. 4 on the right
✓ C. 4 on the le D. 2 on the le
Q.188 The enzyme which can catalyse the conversion of glucose to ethanol is:
✓ A. zymase B. invertase
C. maltase D. diastase
Q.189 An oxida on or reduc on may be take place at SHE depending upon the nature of the
A. Electrolyte solu on B. Conc of HCl
✓ C. Electrode D. All of these
Q.190 The electrolysis of CuSO4aqueous solu on using copper as cathode as well as anode the substance which deposits at
cathode is
A. H2SO4 B. oxygen
✓ C. copper D. hydrogen
Q.191 Fquel cells are the means by which chemical energy maybe converted in to:
A. Sound energy B. Poten al energy
C. Electric energ7 ✓ D. Heat energy
Q.192 I Daniel cell, if salt bridge is removed between two half cells, the voltage:
A. Increases rapidly B. Increases gradually
C. Does not change ✓ D. drops to zero
Q.193 A substance which increase the efficient of a catalyst is termed as:
A. ac vator B. supper catalyst
C. retarder ✓ D. promotor
Q.194 The reac on in galvanic cell is
✓ A. Spontaneous B. Non-spontaneous
C. Acid-base D. None of these
Q.195 During electrolysis of KNO3.H2is evolved
A. Anode ✓ B. Cathode
C. Both a and b D. None
Q.196 Purifica on of an impure copper is made by electroly c cell, in which impure copper is anode and pure copper is
cathode, and the electrolyte used is
_______________________________________________________________________________________
A. H2SO4 ✓ B. CuSO4
C. ZnSO4 D. Na2SO4
Q.197 75% of first reac on is complete in 30 minutes. What is the me required for 93.75% of the reac on (in minutes)?
A. 45 B. 120
C. 90 ✓ D. 60
Q.198 Which is the oxida on number of nitrogen in the molecules N2
✓ A. 0 B. 3
C. 5 D. 7
Q.199 When fused PbRr2is electrolyzed:
A. Lead appears at anode ✓ B. Lead appears at cathode
C. Bromine appears at cathode D. Lead appears at both electrodes
Q.200 Which statement is not correct?
A. the cataly c ac vity of enzymes is stopped if ✓ B. the cataly c ac vity is poisoned by a
op mum pH is changed coenzyme
C. enzymes show cataylic ac vity at a specific D. enzymes cataly c ac vity at a specific
temperature temperature
Q.201 Half life of a reac on is found to be inversely propor onal to the cube of ini al concentra on. The order of reac on is
✓ A. 4 B. 3
C. 5 D. 2
Q.202 The oxida on number of chromium in K2Cr2O7is
A. 14 B. 12
✓ C. 6 D. None of these
Q.203 A compound contains elements X, Y and Z. The oxida on number of X is +3, Y is +5 and Z is -2. The possible formula of
the compound is
A. XYZ2 B. Y2(XZ3)2
✓ C. X3(YZ4)3 D. X(Y4Z)2
Q.204 In a first order reac on the concentra on of the reactant decreases from 0.8 M to 0.4 M in 15 minutes. The me taken
for the concentra on to change from 0.1 M to 0.025 M is
C. 7.5 minutes D. 15 minutes
Q.205 The rate of a chemical reac on
A. Increases as the reac on proceeds ✓ B. Decreases as the reac on proceeds
C. May increase or decrease during the reac on D. Remains constant as the reac on proceeds
Q.206 The reduc on poten al of copper electrode is +0.34 V and that of Zn electrode is -0.76 V. When these two are coupled
the e.m.f of the cell is
A. -0.42 V B. +0.42
C. -1.10 V ✓ D. +1.10 V
Q.207 Which of the following statements is correct about galvanic cell?
A. Anode is nega vely changed B. Reduc on occurs at anode
C. Cathode is posi vely changed ✓ D. Reduc on Occurs at cathode
Q.208 The name catalysis was given by
A. Rutherford B. Graham
C. Moseley ✓ D. Berzelius
Q.209 When Zn is couple with standard hydrogen electrode then Zn metal act as anode, the oxida on poten al of Zn taken
as
✓ A. Posi ve B. Nega ve
C. May be posi ve or nega ve D. Neutral
Q.210 If ini al concentra on of reactants in certain reac on is doubled,the half life period of the reac on doubles the order
of a reac on is
✓ A. Zero B. First
C. Second D. Third
Q.211 Which statement is correct about the life period of a galvanic cell
_______________________________________________________________________________________
A. It increases with increase in the concentra on B. It increases with decrease in the size of the
of anodic solu on anode
✓ C. It increases with increases in concentra on D. It increases with decrease in the size of
of cathodic solu on cathode
Q.212 Stronger the oxidizing agent, greater is the
A. Oxida on poten al ✓ B. Reduc on poten al
C. Redox poten al D. e.m.f of cell
Q.213 When the rate o reac on is en rely independent of the concentra on of reactant molecules then order of reac on is :
A. in frac ons B. nega ve
✓ C. zero D. pseudo first order
Q.214 The galvanic or voltaic cells which are rechargeable called as
A. Primary cell ✓ B. Secondary cells
C. Infinite cell D. Dry cell
Q.215 Large the surface area of the reactant molecules:
✓ A. higher will be the rate of reac on B. lower will be the rate of reac on
C. the rate of reac on remains uneffected D. none of these
Q.216 When Cr is couple with SHE, the voltmeter gave 0.74 V reading and bubbles are not produced in SHE. Then oxida on
poten al of Cr is
✓ A. -0.74 V B. +0.74 V
C. -0.771 V D. + 0.771 V
Q.217 If a strip of Cu metal is placed in a solu on of FeSO4:
A. Cu will be precipitated out B. Fe is precipitated out
C. Cu and Fe both dissolve ✓ D. No reac on take place
Q.218 Which of the following statements is correct about Galvanic cell
A. Anode is nega vely charged B. Reduc on occurs at anode
C. Cathode is posi vely charged ✓ D. Reduc on occurs at cathode
Q.219 Electroly c cell can be used for the purifica on of copper where
A. impure copper is made the anode B. a thin sheet of pure copper is made the
cathode
C. copper sulphate solu on is used as an ✓ D. all the above
electrolyte
Q.220 The bubble of hydrogen gas are produced, when SHE acts as
A. Electrode ✓ B. Cathode
C. Anode D. May be cathode or anode
Q.221 In zero order reac on the rate in independent of:
A. temperature of reac on B. concentra on of reactants
C. concentra on of products ✓ D. none of these
Q.222 Indicate the enzyme which catalyses the following reac on:
C6H12O6 -------> 2 C2H5OH + 2CO2
A. urease B. invertase
C. diastase ✓ D. zymase
Q.223 The salt bridge contains an aqueous solu on of ______ in a gel
✓ A. KCl B. K2Cr2O7
C. K2CO3 D. K2S2O3
Q.224
A. Hydrolyzed B. Precipitated
✓ C. Oxidized D. Reduced
Q.225 The reac on,
2SO2(g) + O2(g) → 2SO3(g) is carried out in a 1 dm3 vessel and 2 dm3 vessel separately. The ra o of the reac on
veloci es will be
A. 1:8 B. 1:4
C. 4:1 ✓ D. 8:1
_______________________________________________________________________________________
Q.226 What is the oxida on number of oxygen in OF2
A. -2 B. +1
✓ C. +2 D. none of these
Q.227 The oxida on number of phosphorus in Ba(H2PO2)2 is
A. +3 B. +2
✓ C. +1 D. -1
Q.228 During electrolysis, oxida on always occurs at the
✓ A. anode B. cathode
C. electrode D. in solu on
Q.229 An oxidizing agent in chemical reac on is the substance which
A. Loses electrons ✓ B. Gains electrons
C. Acts as a catalyst D. pH is changed
Q.230 What is the me required for a first order reac on to be 99% complete, compared to the me taken for the reac on to
be 90% complete?
A. There is no change ✓ B. Time taken is double
C. Time taken is triple D. The me required is half the ini al value
Q.231 When an increase in temperature during a chemical reac on, the molecules become:
A. first ac vated and then deac vated B. no change in ac va on per unit me
✓ C. ac vated per unit me D. deac vated per unit me
Q.232 H2S is passed through an acidified solu on of CuSO4and a black precipitate is formed. This is due to
A. Oxida on of Cu2+ B. Reduc on of Cu2+
✓ C. Neither reduc on nor oxida on D. Reduc on and oxida on
Q.233 The oxida on state of an element is zero when
A. It forms an oxide ✓ B. It is in free state
C. It forms hydride D. Only for noble gases
Q.234
A. 0 B. 1 on right
C. 1 on le ✓ D. 2 on right
Q.235 Oxida on number of carbon in NaHCO3 is
A. +2 ✓ B. +4
C. +6 D. -6
Q.236 A substance which increase the rate of reac on with being consumed during the reac on is called:
✓ A. a catalyst B. an auto catalyst
C. a nega ve catalyst D. all above
Q.237 If the salt bridge is not used between two half cells, then the voltage:
A. Decrease rapidly B. Decrease slowly
C. Does not change ✓ D. Drops to zero
Q.238 In an oxida on process the oxida on number of the element
C. Does not change D. None of these
Q.239 Which of the following can not conduct electricity:
A. NaCI fused B. NaCI(aq)
✓ C. NaCI(solid) D. Both (b) and (c)
Q.240 The first order of reac on may be determined by
A. Differen al method B. Graphical method
C. Half life method ✓ D. All of these
Q.241 75% of a first order reac on was completed in 32 minute when was 50% of the reac on completed
A. 4 min B. 24 min
C. 8 min ✓ D. 16 min
_______________________________________________________________________________________
Q.242 For an endothermic reac on where ΔH represents the enthalpy of the reac on in Kj/mol the minimum value for the
energy of ac va on will be
A. Less than ΔH ✓ B. More than ΔH
C. Zero D. Equal ΔH
Q.243 F2, Cl2, Br2and I2lie below SHE in the Electro chemical series that is why these
✓ A. undergo reduc on B. undergo oxida on
C. liberate H2gas with steam D. none of these
Q.244 An example of autocataly c reac on is
✓ A. The decomposi on of nitroglycerine B.Thermal decomposi on of and
3 2mixture
KCIO MnO
C. Breakdown of C6 14 D. Hydrogena on of vegetable oil using nickel
catalysts
Q.245 Li has the lowest reduc on poten al while the element with highest reduc on poten al is
A. H ✓ B. F
C. O D. N
Q.246 Fe can displace Cu form CuSO4solu on because
A. Fe is ferromagne c B. Fe is below Cu in electrochemical series
✓ C. Fe is above Cu in electrochemical series D. Fe exists in divalent oxida on state
Q.247 The half life of a reac on is halved as the ini al concentra on of the reac on is doubled. The order of the reac on is
A. 0.5 B. 1
✓ C. 2 D. 0
Q.248 In a galvanic cell, the electrode occupying a higher posi on in the electrochemical series, will act as
A. anode B. oxida on will take place on it
C. cathode ✓ D. both a and b
Q.249 When an aqueous solu on of H2SO4is electrolyzed
A. hydrogen appears at the cathode B. oxygen appears at the anode
✓ C. Both a and b D. hydrogen appears at the anode and oxygen at
the cathode
Q.250 The rate of reac on determined at given mes called:
A. average rate ✓ B. specific rate
C. instantaneous rate D. overall rate
Q.251 The cell in which a non-spontaneous redox reac on takes place as a result if electricity is known as:
✓ A. Electroly c cell B. Voltaic cell
C. Daniel cell D. Dry cell
Q.252 In electrochemical series, the down the series, decrease the
A. Strength as an oxidizing agent B. Reduc on poten al
✓ C. Strength as reducing agent D. Numerical value
Q.253 The most common fuel used in fuel cells are:
A. O2and C2H6 B. O2and CH4
C. H2and O2 ✓ D. H2and CH
Q.254 Lead storage ba ery is recharged by:
A. Adding concentrated H2SO4 B. Adding more water
C. passing more current ✓ D. Reversing the direc on of corrent
Q.255 A cell in which chemical energy is converted into electrical energy is called
A. Dry cell B. Electroly c cell
C. Fuel cell ✓ D. Galvanic cell
Q.256 Fuel cell are
A. Light B. Portable
C. Sources of electricity ✓ D. All
Q.257 Use of catalyst in the reac on changes:
A. entropy B. internal energy
C. enthalpy ✓ D. ac va on energy
_______________________________________________________________________________________
Q.258 For a reac on of type A + B → products it is observed that doubling concentra on of A causes the reac on rate to be
four mes a great, but doubling amount of B does not affect the rate. The rate equa on is
A. Rate = k [A] [B] B. Rate = k/4 [A]2
✓ C. Rate = k [A]2[B]0 D. Rate = k [A]2[B]2
Q.259 The rate of reac on between two specific me intervals is called:
A. ini al rate B. final rate
✓ C. average rate D. instantaneous rate
Q.260 The half lives of 2 samples are 0.1 and 0.1 and 0.4 seconds.Their ini al cons.Are 200 and 50 respec vely. What is the
order of the reac on?
A. 0 ✓ B. 2
C. 1 D. 4
Q.261 1 mole of N2H4loses 10 moles of electrons to from a new compound Y. Assuming that en re the nitrogen appear in the
new compound, what is the oxida on state of nitrogen in Y? (no change in oxida on state of hydrogen)
A. -1 B. -3
✓ C. +3 D. +5
Q.262 One gas bleaches the colour of flower by reduc on while the other by oxida on. The gases are
✓ A. SO2, Cl2 B. CO, Cl2
C. H2S, H2O2 D. NH3, SO3
Q.263
A. Iodine gets oxidised to iodide ions B. Oxida on state of sulphur remains unaltered
✓ C. Thiosulphate ion is oxidized D. Oxida on state of sulphur changes from +1 to
+ 2.5
Q.264 A zero order reac on is one
A. In which reactants do not react B. In which one of the reactants do not react
✓ C. Whose rate is uniform and not affected by D. Whose rate increase with me
me
Q.265 Rate constant is case of first order reac on is
A. Inversely propor onal to the concentra on ✓ B. Independent of concentra on units
units
C. Directly propor onal to the concentra on
units
D. Inversely propor onal to the square of the
concentra on units
Q.266 Aluminium is extracted by electrolysis of fused bauxite
A. in the presence of Cu catalyst B. in the presence of Ni catalyst
✓ C. in the presence of fused cryolite D. both a and b
Q.267 The phenomenon of emission of visible light as result of chemical change is known as
✓ A. Chemiluminescence B. Fluorescence
C. Phosphorescence D. Photosensi sa on
Q.268 Temperature coefficient of a reac on is 2. When temperature is increased from 30°C to 100°C rate of the reac on
increases by
A. 500 mes B. 250 mes
✓ C. 128 mes D. 100 mes
Q.269 Alkaline ba ery has a voltage of
✓ A. 1.5 V B. 2.5 V
C. 3.5 V D. 4.5 V
Q.270 Electrolytes in the form of solu on or in the fused state have the ability to conduct:
A. Light ✓ B. Electricity
C. Ions D. Electrons
Q.271 The purpose of the salt bridge is to prevent any net charge accumula on in either beaker by allowing ______ to have
one to another beaker
A. Solu on ✓ B. Nega ve ion
C. May both b and d D. Posi ve ion
_______________________________________________________________________________________
Q.272 The oxidizing strength of an element depends upon
A. Its ioniza on energy B. Its electron affinity
✓ C. Its electrode poten al D. Its oxida on poten al
Q.273 A standard hyrogen electrode (S.H.E) consists of a pla nized pla num electrode dipped in 1 molar solu on of H+ions
and hydrogen gas is passed at a pressure of
A. One Pascal B. One Kilo Pascal
✓ C. One atmosphere D. then atmosphere
Q.274 The oxida on number "S" in SF6
✓ A. +6 B. -6
C. May be -6 or +6 D. All may be
Q.275 Which of the following types of metals make the most efficient catalysts
✓ A. Transi on metals B. Alkaline earth metals
C. Alkali metals D. Radioac ve metals
Q.276 Value of standard reduc on poten al for strong reducing agents is:
✓ A. Large nega ve value B. Zero
C. Large posi ve value D. Negligibly small
Q.277 Half life period of 2nd order reac on is
A. Propor onal to ini al concentra on of B. Independent of ini al concentra on of
reactants reactants
✓ C. Inversely propor onal to ini al D. Inversely propor onal to square of ini al
concentra on or reactants concentra on of reactants.
Q.278 Strong oxidizing agents have
✓ A. Greater posi ve value of standard reduc on B. Lesser posi ve value of standard reduc on
poten al poten al
C. Greater nega ve value of standard reduc on D. None of these
poten al
Q.279 Rate of 1st order depends upon
A. Time B. Concentra on of reactant
C. Temperature ✓ D. All of these
Q.280 In voltaic cell if the solu ons were to mix direct chemical reac on would be take place then voltage
A. Drop B. Change
✓ C. Drop to zero D. Increase
Q.281 The catalyst used in the hydrogena on of oils is
A. V 2O 5 B. Fe
✓ C. Ni D. Pt
Q.282 The unit of rate constant for a zero order reac on is
A. Line sec-1 B. Litre mol-1sec-1
✓ C. Mol litre-1sec-1 D. Mol sec-1
Q.283 A reac on involving two different reactants can never be
✓ A. Unimolecular reac on B. First order reac on
C. Second order reac on D. Bimolecular reac on
Q.284 What will be the density of H2SO4 when lead accumulator is recharged
A. 1.15 gcm-3 B. 1.81 gcm-3
C. 2.15 gcm-3 ✓ D. 1.25 gmc-3
Q.285 In case of electrolysis of molten PbCl2salt, the products are
A. Pb B. Cl2
C. Pb(OH)2 ✓ D. Both A & B
Q.286 In electronic watches or electronic calculators the ny ba eries used are
A. alkaline ba ery B. NICAD ba ery
C. fuel cell ✓ D. Silver oxide ba ery
Q.287 The ac va on energy of a reac on can be determined by
A. Changing the concentra on of reactants B. Evalua ng rate constant at standard
temperature
_______________________________________________________________________________________
✓ C. Evalua ng rate constant at two different D. By doubling conc.Of reactants
temperatures
Q.288 The half-life period for a first order reac on is 693 seconds. The rate constant of this reac on would be
A. 0.1 sec-1 B. 0.01 sec-1
✓ C. 0.001 sec-1 D. 0.0001 sec-1
Q.289 When a metal strip is placed in a solu on of it's own one molar ions, there are ______ tendencies
A. Six B. Five
C. Four ✓ D. Two
Q.290 The oxida on number of H is -1 in the compound
A. H 2O B. H3BO3
C. NaOH ✓ D. NaH
Q.291 A first order reac on is 75% complete a er 32 minutes.When was 50% of the reac on completed?
C. 4 minutes D. 32 minutes
Q.292 Metallic conduc on is due to the
✓ A. Movement of electrons B. Movement of ions
C. both a and b D. None of these
Q.293 A cell in which spontaneous redox reac on generates an electric current is called
A. Electroly c cell B. Electrochemical cell
✓ C. Voltaic or Galvanic cell D. Biological cell
Q.294 Reduc on always occurs
A. At anode ✓ B. At cathode
C. Both a and b D. None of these
Q.295 In passage of electricity through aqueous solu on of AgNO3silver dissolves at anode to form Ag+the electrodes are
A. Silver metal B. Graphite
C. Pt metal ✓ D. Copper metal
Q.296
A. K B. Cl
✓ C. Cr D. H
Q.297 A reac on 50% complete in 2 hours and 75% complete in 4 hours order reac on is
A. 0 ✓ B. 1
C. 2 D. 3
Q.298 The difference of poten al of two electrodes when concentra on if solu on is 1M each at 25°C and 1 atm is called:
A. Call reac on B. Electrode po en al

C. Cell voltage ✓ D. Standard potent
1/2
Q.299 in equa on CHCI3 + CI2 ---------->CCI4 HCI the rate =k[CHCI3] [CI2] , the order of reac on is:
A. -1/2 ✓ B. 3/2
C. 2 D. -3/2
Q.300 When aqueous solu on of NaOH is electrolysed using graphite electrodes, the product obtained at anode is
✓ A. O2gas B. H2gas
C. Na metal D. Na2O
Q.301 Metal will displace another metal from aqueous solu on of its salt if it lies ______ the electrochemical series
A. Below ✓ B. Above
C. Middle D. May all
Q.302 The oxida on poten al of which metal is posi ve
✓ A. Zn B. F2
C. Cu D. None of these
_______________________________________________________________________________________
Q.303 The voltaic or galvanic cells which cannot be recharged are called
✓ A. primary cells B. secondary cells
C. infinite cells D. fuel cells
Q.304 The process of electrical coa ng of one metal on another to protect, decorate or to have a greater resistance to
corrosion is called
A. Conduc on ✓ B. Eletropla ng
C. Electrolysis D. Induc on
Q.305 A reac on A → B follows a second order kine cs. Doubling the concentra on of B by a factor or
A. 2 B. 1/2
✓ C. 4 D. 1/4
Q.306 Ini ally the rate increase in concentra on of products in a reac on is:
✓ A. rapid B. slowest
C. moderate D. half decrease in concentra on of
Q.307 When fused PbBr2is electrolyzed
A. bromine appears at the cathode ✓ B. lead is deposited at the cathode
C. lead appears at the anode D. none of these happens
Q.308 Metals which are above H2in electrochemical series
✓ A. Can liberate H2from acid B. Cannot liberate H2from acid
C. Cannot always liberate H2from acid D. None of these
Q.309 The method used for balancing when equa on is given in the form of ions
A. Oxida on reduc on method ✓ B. Ion electron method
C. May be both D. None of these
Q.310 Which oxide has +2 oxida on number of oxygen
A. Cl2O B. Na2O
C. Na2O2 ✓ D. F 2O
Q.311 When fused PbBr2is electrolyed then
A. Bromine appears at cathode ✓ B. Lead deposited at the cathode
C. Lead appears at the anode D. None of these happens
Q.312 In oxida on number method for balancing of equa on, iden fy the element which undergo a change in their ______
during reac on
A. Valence electron B. proton
✓ C. Oxida on number D. May be all
Q.313 The first order rate constant for the decomposi on of N2S5 is 6.2 x 10-4 sec-1. The t1/2 of decomposi on is
✓ A. 1117.2 B. 111.7
C. 223.4 D. 150.9
Q.314 In recharging of lead storage ba ery:
A. Pb is converted to PbO2 ✓ B. PbSO4is converted to Pb
C. Pb in converted to PbSO4 D. Both (a) and (b)
Q.315 The oxida on state of molybdenum in its oxo-complex species [Mo2O4(C2H4)2(H2O2)]2-
A. +2 ✓ B. +3
C. +4 D. +5
Q.316 The standard reduc on poten al of silver is about 0.8 v, the value gives informa on that:
A. Ag+has tendency to be oxidized B. Ag has tendency to be oxidized to ag+ ion
✓ C. Ag+ions have tendency to be converted to Ag D. Both (B) and (C)
metal atom
Q.317 The hydrolysis of ester in alkaline medium is a
A. 1st order reac on with molecularity 1 ✓ B. 2nd order reac on with molecularity 2
C. 1st order crea on with molecularity 2 D. 2nd order reac on with molecularity 1
Q.318 Electrochemical series is a list of elements arranged into the increasing order of their
A. Cell voltage B. Ioniza on poten al
✓ C. Standard reduc on poten al D. Standard oxida on poten al
_______________________________________________________________________________________
Q.319 The overall posi ve value for the reac on poten al predicts that process is energe cally:
A. Impossible B. Not feasible
✓ C. Feasible D. Both (A) and (B)
A + B → Products is given by the equa on r = k [A] [B]
If B is taken in large excess, the order of the reac on would be
A. 2 ✓ B. 1
C. 0 D. Unpredictable
Q.321 Sum of exponents of concentra on terms in rate equa on is called:
A. ac ve mass of reactants B. specific rate constant
✓ C. order of reac on D. rate of reac on between specif me interval
Q.322 By using graphite electrode the electrolysis of aqueous solu on of NaCl produces at anode
A. H2gas ✓ B. Cl2
C. NaOH D. Na metal
Q.323 Which of the following statement about the catalyst is/are true?
✓ A. A catalyst accelerates the rate of reac on by B. A catalyst does not par cipate in reac on
bringing down the energy of ac va on mechanism
C. A catalyst makes the reac on more feasible by D. A catalyst makes equilibrium constant more
making Δ G more nega ve favourable for forward reac on.
Q.324 The rate of chemical reac on depends on the nature of reactants because:
A. some of the reactants are coloured B. some of the reactants have high I.p.
✓ C. energy of ac va on differs from one reac on D. some of the reactants are solid at S.T.P
to another
Q.325 The cathodic reac on in the electrolysis of dil. H2SO4with Pt electrodes is
✓ A. Reduc on B. Oxida on
C. Both oxida on and reduc on D. Neither oxida on and reduc on
Q.326 If a strip of Cu metal is placed in a solu on of FeSO4then
C. Cu and Fe both disslove D. No reac on takes place
Q.327 The true representa on for the units of rate constant k for the lat order reac on is:
A. mol dm-3s B. mol dm-3s-1
C. mol-1dm-3s ✓ D. sec-1
Q.328 When electric current is used to carry out non-spontaneous redox reac on, the process is called
A. Decomposi on ✓ B. Electrolysis
C. Neutraliza on D. Hydrolysis
Q.329 The ac va on energy of a reac on is zero The rate constant of the reac on
A. Increases with increases of temperature B. Decreases with increases of temperature
C. Decreases with decreases of temperature ✓ D. In nearly independent of temperature
Q.330 The cell in which electric current is used to drive a non-spontaneous reac on is called ______ cell
A. Galvanic B. Voltaic
✓ C. Electroly c D. Hydrological
Q.331 The increase in concentra on of reactants:
A. has inverse effect on number of collisions ✓ B. increase the number of collisions directly
C. has no effect on number of collisions D. decreases the number of collisions
Q.332 During electrolysis, electrons are:
✓ A. Lost by anions and gained by ca ons B. Gained by anions and lost by ca ons
C. Gained only D. Lost only
Q.333 The best electrode is used in salt bridge is KCI, which other electrolyte can also be used for the purpose:
A. NaCI ✓ B. NH4NO3
C. KNO3 D. NaNO3
Q.334 If the salt bridge is not used between two half cells, then the voltage
A. Decrease rapidly B. Decrease slowly
_______________________________________________________________________________________
C. Does not change ✓ D. Drops to zero
Q.335 When a reac on proceeds in a sequence of steps the overall rate is determined by:
✓ A. slowest step B. fastest step
C. molecularity of all the steps D. order of different steps
Q.336 A zero order reac on is one whose rate is independent of
A. Temperature of the reac on ✓ B. The concentra on of the reactants
C. The concentra on of the products D. The material of the vessel in which the
reac on is carried out
Q.337 Metal can be prevented from rus ng by
✓ A. Connec ng iron to more electroposi ve B. Connec ng iron to more electroposi ve metal
metal - a case of cathodic protec on - a case of anodic protec on
C. Connec ng iron to less electroposi ve metal - D. Connec ng iron to less electroposi ve metal -
a case of anocdic protec on a case of cathodic protec on
Q.338
A. CO ✓ B. N2
C. H2 D. All
_______________________________________________________________________________________
7 Chemical Equilibrium
Q.1 Kavalue (the ioniza on constant) of HF acid is 6.7 x 10-5the acid is a

✓ A. weak acid B. moderately strong acid
C. strong acid D. very weak acid
Q.2 The pH of buffer solu on is 4.74. On adding 0.1 mol (0.00001M) HCl solu on the pH of solu on will be
A. 5.2 B. 2.5
✓ C. 4.74 D. 4.7
Q.3 Mixtures of NH4OH and NH4Cl is one of the best examples of:
A. Acidic buffers B. Natural bffers
✓ C. Basic buffers D. Acid base buffers
Q.4 Chemical equilibrium involving reactants and products in more than on phase is called
A. sta c B. dynamic
C. homogeneous ✓ D. heterogeneous
Q.5 Which element is the most electro posi ve in periodic table
A. Barium B. Calcium
C. Potassium ✓ D. Cesium
Q.6 Which among the following species has the highest ioniza on energy?
✓ A. Ne B. F
C. Li D. B
Q.7 The first a empt to classify the elements of periodic table was made by:
A. Newland B. Mendeleev
✓ C. Al-Razi D. Dobereiner
Q.8 Which of the following element has the maximum electron affinity?
A. F B. S
C. I ✓ D. CI
Q.9 The a empt of classifica on of elements by plo ng the atomic weight of elements against their volumes was made
by:
A. Newlands B. Bohr
✓ C. Lother Meyer D. Dobereiner
Q.10 Classifica on of elements in modern periodic table is based on
A. Bohr s model ✓ B. Moseley s law
C. de-Broglie law D. Rutherford model
Q.11 Law of mass ac on was presented by
A. Henderson B. Lawis
C. Arrhennius ✓ D. Guldburg and waag
Q.12 Which of the following electronic configura on represents an inert gas?
A. 2, 8, 2 B. 2, 8, 1
C. 2, 1, 7 ✓ D. 2, 8, 8
Q.13 Which of the following pair of atomic numbers represents s-block element?
A. 7,15 B. 6,12
C. 9,17 ✓ D. 3,20
Q.14 Buffer is a solu on
_______________________________________________________________________________________
✓ A. Whose pH may or may not change during a B. Which strong enough to maintain its pH
chemical reac on
C. Which resists change in its pH
D. Whose pH is constant
Q.15 pKa value of ace c acid is 4.76 then pKb value of acid
A. 4.76 ✓ B. 9.24
C. -9.34 D. -4.76
Q.16 In the periodic table which of following trend is correct across the periods
A. Electronic affinity decrease B. Electroposi ve character increases
C. Electronega ve character decreases ✓ D. Non-metallic nature increase
Q.17 The compound having lowest boiling point is:
A. H 2S B. H2Se
✓ C. SiH4 D. SnH4
Q.18 Mark the incorrect statement:
A. metallic character increases down the group ✓ B. metallic character increases along a period
C. metallic character decreases along period D. metallic character remain the same down the
group
Q.19 Law of mass ac on states that rate of chemical reac on is directly propor onal to the product of ac ve masses of the
reactants.The term ac ve mass means
A. mass in grams converted to products B. number of moles
✓ C. number of moles per dm3of reactants D. total pressure of the reactants
Q.20 In the forma on of Hl the change of pressure result
A. Shi toward forward direc on B. Shi toward backward direc on
✓ C. Equilibrium will not be effected D. First shi forward then backward
Q.21 Which of the following metal requires radia on of highest frequency to cause emission of electrons?
A. Na ✓ B. Mg
C. K D. Ca
Q.22 When even a weak base is dissolved in water, it gives its conjugate acid. Similarly a weak acid in water produces its
conjugate base. The conjugate acid base pair is stated by
A. Le-Chatlier's principle B. Common ion effect
✓ C. Lowery Bronsted concept D. Law of mass ac on
Q.23 Two place le empty by Mendeleev in the periodic table wera for:
A. an mony & bismuth B. aluminium & silicon
✓ C. gallium & geranium D. arsenic & an mony
Q.24 No of moles of H2O in one dm3
A. 6.02 x 1023 B. 6.02 x 10-23
C. 1000 ✓ D. 55.5
Q.25 When the concentra on of substances are taken in molar units, then the equilibrium constant is represented by
A. K0 B. Kp
✓ C. Kc D. Ka
Q.26 According to the modern periodic law, the physical and chemical proper es of elements are periodic func on of their:
A. atomic size ✓ B. atomic volume
C. atomic weight D. electronic configura on
Q.27 The solubility of PbF2is 2.6 x 10-3mole dm-3, then its solubility product is
A. 2.6 x 10-3 B. 6.76 x 10-6
C. 5.2 x 10-6 ✓ D. 7.0 x 10-8
Q.28 Point out the incorrect statement about metalloids:
✓ A. these are good conductors of heat and B. these usually act as electron donors with non-
electricity metals acceptors with metals
C. Some of these are B,Ge,Si ect. D. these are borderline elements that show
metallic and non-metallic character to some
extent.
Q.29
_______________________________________________________________________________________
Hydrogen gas and iodine vapours combine to form HI at 425°C, The same composi on of the mixture of we start with
decomposi on of HI. It suggests
A. Law of mass ac on B. Irreversible reac on
✓ C. A dynamic equilibrium D. A sta c equilibrium
Q.30 The rate of which the reac on proceeds is directly propor onal to the product of the ac ve masses of the reactants is
according to
✓ A. law of mass ac on B. Le Chateliers principle
C. Equilibrium law D. Law of constant propor on
Q.31 Which of the following sets of atomic numbers belong to that of the alkali metals?
A. 1, 12, 30, 4, 62 ✓ B. 37, 19, 3, 55
C. 9, 17, 35, 53 D. 12, 20, 56, 88
Q.32 The number of elements in the 4th period of periodic table is
A. 8 B. 10
✓ C. 18 D. 32
Q.33 Which of the following elements has greatest value of first ioniza on energy
✓ A. N B. O
C. C D. B
Q.34 In an exothermic reversible reac on increase in temperature shi the equilibrium to:
A. Remains unchanged B. Product side
✓ C. Reactant side D. None of above
Q.35 Neutraliza on of a strong acid with a strong base is
✓ A. Chemical equilibrium B. Spontaneous reac on
C. Reversible process D. Non-spontaneous
Q.36 Chemical equilibrium involving reactants and products is more than one phase is known
A. Homogeneous ✓ B. Heterogeneous
C. Sta c D. Dynamic
Q.37 The atomic radius increases as we move down a group because
A. Effec ve nuclear charge increases B. Atomic mass increases
✓ C. Addi ve electrons are accommodated in new D. Atomic number increases
electron level
Q.38 Units of Kw are
A. mole dm-3 B. mole2dm-3
✓ C. mole2dm-6 D. mole2dm-3
Q.39 Which is amphoteric oxide among the following oxides?
A. rubeduim oxide B. sulphur trioxide
✓ C. lead oxide D. phosphorus pentaoxide
Q.40 The chemical proper es of Li resemble with Na because they have equal:
✓ A. number of electrons in the outermost B. atomic mass and atomic volume
orbitals
C. number of protons in nuclei
D. number of neutrons in nuclei
Q.41 Which one of the following elements is a metalloid?
✓ A. a monry B. lead
C. n D. molybdenum
Q.42 Two elements whose electronega vi es are 1.2 and 3.0, the bond formed between them would be
✓ A. Ionic B. Covalent
C. Coordinate D. Metallic
Q.43 Which one of the following has highest pH:
A. Dis lled water B. Water saturated with chlorine gas
C. 1M NH4OH ✓ D. 1M NaOH
Q.44
_______________________________________________________________________________________
A. 1 x 10-2 B. 2 x 10-3
✓ C. 1 x 10
-5
D. 2 x 10
-5
Q.45 pH of buffer which contain 1 mol dm-3of formic acid and 1 mol dm-3of sodium formats pKa of formic acid =
✓ A. 3.78 B. 2.78
C. 4.78 D. zero
Q.46 0.1 M HCl has pH = 1.0, it is about 100 mes stronger than ace c acid. Then pH of ace c acid will be
A. 0.1 B. 2.0
C. 1.3 ✓ D. 3
Q.47 The strongest base among the following is
A. LiOH ✓ B. RbOH
C. KOH D. NaCH
Q.48 The valence shell electronic structure of an element is ns2 np5. The element will belong to the group of
A. Alkali metals B. Inert metals
C. Noble gases ✓ D. Halogens
Q.49 Conjugate acid of a strong base is
✓ A. Weak acid B. Strong acid
C. Not ionize D. Salt
Q.50 The pair of elements which behave as metalloid is:
A. Rb & ,Cs B. Br & I
✓ C. Al & Zn D. Pt & l
Q.51
A. There will be no change in the overall reac on B. The reac on will occur at a faster rate
✓ C. Less of the reactants will react in order to D. More of the reactants will have to react in
compensate for the increase in the amount order to compensate for the increase in the
of one of the products of the reac on amount of one of the products of the reac on
Q.52 If the difference of pKa values of the two acids is 2, then
A. Acid with greater pKa is 10 mes stronger acid ✓ B. Acid with smaller pKa is 100 mes stronger
acid
C. Acid with smaller pKa is 10 mes stronger acid D. Acid with greater pKa is 100 mes stronger
acid
Q.53
✓ A. 0.61 B. 0.57
C. 0.83 D. 0.46
Q.54
A. Total pressure B. Catalyst

C. Concentra on of H2and l2 ✓ D. Temperature
Q.55 Equilibrium constant in terms of pressure is denoted by
A. K0 ✓ B. Kp
C. Kc D. Ka
Q.56 Which of the following elements is most metallic
A. P B. Sb
C. As ✓ D. Bi
Q.57 In the modern long form of the periodic table, elements are arranged in the increasing order of
_______________________________________________________________________________________
A. Atomic gas ✓ B. Atomic number
C. Mass number D. Isotopic number
Q.58 If we increase pressure in decomposi on of PCl5will favour the rac on in
A. Forward direc on ✓ B. Backward direc on
C. At equilibrium D. No effect
Q.59 Which one of the following is a buffer
A. HCl + NaCl solu on B. CH3COOH + CH3COONH4solu on
C. H2SO4+ CaSO4solu on ✓ D. CH3COOH+ CH3COONa
Q.60 The solubility of CaF2is 2.0 x 10-4g dm-3, then Kspof CaF2is
A. 4.0 x 10 -8 ✓ B. 3.2 x 10-11
-8
C. 2.0 x 10 D. 4.0 x 10-12
Q.61 The value of Kc
A. does not change with the increase in ✓ B. changes with change of temperature
temperature C. does not change with the decrease in
temperature
D. none of these
Q.62 The discovery o which of the followin group of elements gave blow to the Newland's law of octaves
A. ac nides ✓ B. inert gases
C. alkaline earths D. rare earths
Q.63 The law of octaves was enunciated by:
✓ A. Newlands B. Dobereiner
C. Lother Meyer D. Mendeleev
Q.64 The solubility product of AgCl is 2.0 x 10-10mol2dm-6. The maximum concentra on of Ag+ions in the solu on is
A. 2.0 x 10-10mol dm-3 ✓ B. 1.41 x 10-5mol dm-3
C. 1.0 x 10-10mol dm-3 D. 4.0 x 10-20mol dm-3
Q.65 Strength of an acid can be determined by
✓ A. Ka B. Kb
C. pOH D. pKw
Q.66 Gradual addi on of electronic shells in the noble gases causes a decrease in their
✓ A. Ioniza on energy B. Atomic radius
C. Boiling point D. Density
Q.67 Which of the following alkali metals does not exist naturally
✓ A. Francium B. Rubidium
C. Lithium D. Cesium
Q.68 In the long form of the periodic table all the non-metals are placed in
A. s-block B. f-block
✓ C. p-block D. d-block
Q.69 The group number of element in periodic table indicates
A. Valency with respect to hydrogen ✓ B. The number of electron in the outermost
shell
C. The atomicity D. Number of shell
Q.70 The long form of periodic table was developed by:
A. Neil's Bohr B. Moseley
C. Mendeleev ✓ D. Lother Meyer
Q.71
In order to classify the elements, Newland gave the idea of:
A. atomic mass B. atomic volume

C. triads ✓ D. octaves
Q.72 A correct order of electron affinity among the following is
A. F > CI > Br B. Br > CI > F
_______________________________________________________________________________________
✓ C. CI > F > Br D. F > Br > CI
Q.73 The oxide of which of the following elements will be acidic in character
A. Mg B. Rb
C. Li ✓ D. CI
Q.74 A solu on having pH = 4 its OH-ion concentra on in mole dm-3is
A. 1.0 x 10 -4 ✓ B. 1.0 x 10-10
-14
C. 1.0 x 10 D. 1 x 100
Q.75 Which one of the following aqueous solu ons has the lower pH
A. 0.1 MnaOH B. 0.1 MKOH
✓ C. 0.1 MHCl D. 0.1 MBa(OH)2
Q.76 The pH value of 0.001M HCI solu on in water is:
A. Exactly 7 ✓ B. <7
C. >7 D. Nearly 7
Q.77 The correct order of electron affinity of B, C, N, O is
A. O>C>N>B B. B>N>C>O
✓ C. O>C>B>N D. O>B>C>N
Q.78 Prepara on of buffer solu on can be done by mixing
A. Weak acid and its salt with weak base ✓ B. Weak base and its alt with strong acid
C. Strong base and its salt with weak acid D. Strong acid and its alt with weak base
Q.79 Base buffer solu on can be prepared by mixing
A. Weak acid and its salt B. Strong acid and its salt with weak base
✓ C. Weak base and its salt with strong acid D. Strong base and its salt with weak acid
Q.80 Mark the longest period of the longest period of the periodic table:
A. 4th B. 6th
C. 3th ✓ D. 7th
Q.81 Uniqueness of Mendeleev s periodic table is that
A. Atomic mass of element B. Classified elements into 12 periods
C. Placed Na,K with Ca and Mg ✓ D. He le empty spaces for undiscovered
elements
Q.82
A. mol dm-1 B. mol-1dm3

C. mol-2dm3 ✓ D. None of these
Q.83 If a system at equilibrium is disturbed the system will try to undo the effect, this is called
✓ A. Le-chatlier's principle B. Law of mass ac on
C. Hess's law D. Law of heat of forma on
Q.84 Hydrogen gas and iodine vapours combine to form HI at 425°C/ The same composi on of mixture is present if we start
with decomposi on of HI. It suggests
A. Law of mass ac on B. A sta c equilibrium
C. Irreversible reac on ✓ D. A dynamic equilibrium
Q.85 Fe3+etc)
In salt analysis 3rd group basic radicals (Al3+, are detected by adding NH4Cl to the salt solu on and then
NH4OH. 3rd group radicals are precipitated as hydroxide. In this process
✓ A. NH4Cl will ionize to a lesser extent in 4Cl
B. NH4Cl will precipitate
presence of NH
C. NH4Cl will react with NH4Cl
D. AL3+will precipitate as AlCl3
Q.86 When 6g ace c acid (0.1 M) is dissolved in 1000 cm3of the solu on only ______ molecules ionize out of every 1000
CH3COOH moleccules
A. 1.33 ✓ B. 13.3
C. 133 D. 13
_______________________________________________________________________________________
Q.87 Which of the following groups of periodic has metlliod?
✓ A. VIA B. IA
C. IIA D. none of these
Q.88 The periodic table consists of:
A. 7 horizontal an 7 ver cal series B. 8 horizontal and 7 ver cal series
✓ C. 7 horizontal and 18 ver cal series D. 8 horizontal and 18 ver cal series
Q.89 Choose the elements which can dorm amphoteric oxides:
A. Te,B B. Rb,TI
✓ C. In,As D. Si,Cd
Q.90 point out the element that belongs to lllrd groups and lllrd period of the periodic:
A. Phosphorus ✓ B. carbon
C. cobalt D. aluminium
Q.91 Which of the following is a buffer solu on
A. Brine ✓ B. Blood
C. Glue D. Solu on of CuSO4
Q.92 The pH of so drink is:
A. Greater than 7 B. Zero
✓ C. Less than 7 D. 7
Q.93 Which of the following elements is/are not liquid at 30°C?
A. Ga B. Hg
✓ C. Ge D. Cs
Q.94 A solu on ghaving pOH = 5 its hydrogen H+ion concentra on
A. 1 x 10-7 B. 1 x 10-5
✓ C. 1 x 10-9 D. 1 x 10-11
Q.95 If the atomic number of an element of an element is 33, it will be placed in the periodic table in:
A. first group ✓ B. fi h group
C. third group D. seventh group
Q.96 The ionic product of H+ions and OH-in water is called ioniza on constant of water Kw.The value of Kw at 25°C is
A. 0.11 x 10-14 ✓ B. 0.30 x 10-14
C. 1.0 x 10-14 D. 3 x 10-14
Q.97 The value of Kp is greater than Kc Kc for a gaseous reac on when
A. A catalyst is added B. Number of molecules of products is greater
than the reactants
✓ C. Number of molecules of products is greater D. Number of molecules of reactants is greater
than that the reactants than those of product
Q.98 In the periodic table elements are arranged in a period strictly in sequence of :
A. equal change inthenucleus B. constant charges in the nucleus:
C. decreasing charges in the nucleus ✓ D. increasing charges in the nucleus
Q.99 Which of the following is more acidic
A. Bananas B. Apples
C. Bread ✓ D. Lemon
Q.100 What happens when a reac on is at equilibrium and more reactant is added:
✓ A. Forward reac on rate is increase B. Forward reac on rate is decrease
C. Backward reac on rate is increase D. equilibrium remains unchanged
Q.101 pH of 1 MHCl
✓ A. 0 B. 1.1
C. 1.5 D. 1.8
Q.102 The elements with atomic numbers 9, 17, 35, 53, 85 and all
A. Noble gases ✓ B. Halogens
C. Heavy metals D. Light metals
Q.103 Element were classified into groups of three called as triads by:
_______________________________________________________________________________________
A. Lother Meyer B. Rutherford
C. New lands ✓ D. Doberiner
Q.104 The chemical characteris cs of elements in each horizontal row in the periodic table are:
A. similar B. different
✓ C. gradually variable D. iden cal
Q.105 The elements in the periodic table with atomic number 30is expected to be present in:
A. IA ✓ B. IIB
C. IIA D. IB
Q.106 Law of mass ac on was given by:
✓ A. Guldberg and Waage B. Berkeley and Hartly
C. Ramsey and Reyleigh D. Berthelot
Q.107 Ka value explain the strength of acid, If Ka < 10-3then the
A. Very strong acid ✓ B. Very weak acid
C. Moderate acid D. Very strong salt
Q.108 Element of the same group in the periodic table are characterized by the same:
A. ioniza on poten al B. electron affinity
✓ C. number valency electrons D. electronega vity
Q.109
A. Increase 2 mes B. Decrease to half

✓ C. Increase 4 mes D. Decrease 4 mes
Q.110 Element of the same ver cal group of the periodic table contain:
A. same number of atoms B. same number of electrons in outermost shell
of their atoms
✓ C. same electronic configru on D. same atomic size
Q.111
A. 0.002 B. 0.2
✓ C. 50.0 D. 50/RT
Q.112 One litre of water contains 10-7moles of H+ions. Then moles of H2O ionized per li er will be
✓ A. 1 x 10-7 B. 0.8 x 10-9
C. 3.6 x 10-7 D. 3.6 x 10-9
Q.113 pH of 0.1 mole HCl solu on is
✓ A. 1 B. zero
C. 13 D. 14
Q.114 If Kc is very small than reactants are in
A. Small amount ✓ B. Large amount
C. Normal amount D. Equal to product
Q.115 Germanium is a:
A. metal B. non-mental
C. transi on ✓ D. metalloid
Q.116 According to the Periodic Law of elements, the varia on in proper es of elements is related to their
A. Atomic masses B. Nuclear masses
✓ C. Atomic numbers D. Nuclear neutron-proton number ra os
Q.117 Chose a set among the following set of atoms which is arrange in decreasing order of electronega vi es
A. S > Si > P B. N>O>F
✓ C. F>O>N D. Si > P > S
Q.118 Chemically the most similar pair of elements is:
A. Na, Al ✓ B. Zr, Hf
_______________________________________________________________________________________
C. Ti, Zr D. Cu,S
Q.119 Of the given alkali metals, the one with smallest size is
A. Rb B. Cs
C. K ✓ D. Na
Q.120 Common ion effect finds extensive applica on in the:
✓ A. Qualita ve analysis B. Quan ta ve analysis
C. Prepara ons of buffers D. Both (b) and (c)
Q.121 The element with atomic number 55 belongs to which block of the periodic table
✓ A. s-table B. p-block
C. d-block D. f-block
Q.122 Which of the solu on among the following has highest pH
A. 0.02 M Ch3COONa B. 0.01 M NaHCO3
✓ C. 0.01 M NaOH D. 0.1 M H2SO4
Q.123 Buffer solu on may be made of
A. a weak acid and a salt of a strong base ✓ B. a weak base and its salt-with a strong acid
C. a strong base and its salt D. a weak acid and a weak base
Q.124 A catalyst merely speeds up the a ainment of equilibrium by lowering the
✓ A. energy of ac va on B. entropy
C. enthalpy D. internal energy
Q.125 Number of elements present in the fi h period of periodic table is
A. 8 B. 10
✓ C. 18 D. 32
Q.126 An element of atomic number 21 belongs to:
A. s-block elements B. p-block elements
✓ C. d-block elements D. f-block elements
Q.127 pH of pure water is:
A. 0 B. 9
C. 14 ✓ D. 7
Q.128 A catalyst is added to a system to change
A. the direc on of the reac on ✓ B. the rate of the reac on
C. the concentra on of the reac on D. the moleculariy of the reac on
Q.129 In llnd period of periodic table, a regular decreace in found in
A. electronega vity ✓ B. atomic radii
C. ioniza on poten al D. atomic mass
Q.130 pH of water is 7, if 0.01 M NaOH is added, than its pH is
✓ A. 12 B. 14
C. zero D. 10
Q.131 Which of the following pH is considered as acidic?
A. 9 B. 11
C. 8 ✓ D. 1
Q.132 When rate of forward reac on is equal to rate of backward reac on the established equilibrium
A. Chemical equilibrium B. Sta c equilibrium
✓ C. Dynamic equilibrium D. All of these
Q.133 The element with highest electron affinity among the halogen is
A. F ✓ B. CI
C. Br D. I
Q.134 The solu on having zero pH will be
A. Basic B. High basic
✓ C. Highly acidic D. Neutral
Q.135 In case of gases another constant is used instead of Kc
_______________________________________________________________________________________
A. Kn ✓ B. Kp
C. Kx D. All
Q.136 The base of long form of periodic table is:
A. electronega vity B. shape of the atom
C. mass of the atom ✓ D. atomic number of the atom
Q.137 Choose the correct statement for the law of mass ac on
A. the rate of forward reac on is equal to the ✓ B. the rate which a substance reacts is directly
rate of backward reac on propor onal to the product of the ac ve
masses of reac ng substances
C. the rate at which a substance reacts is directly D. the rate at which a substance reacts is directly
propor onal to its ini al concentra ons propor onal to its final concentra on
Q.138 An equilibrium constant of 10-4for a reac on means that the reactuib us
A. One that will have 50% product and 50% B. One that is very favorable and will have
reactant at equilibrium mostly product at equilibrium
✓ C. One that is unfavorable and will not have D. The equilibrium constant only relates to the
very much product at equilibrium speed of a reac on and not to the amount of
product formed
Q.139 At equilibrium 0.6 moles of SO2were found. There equilibrium constant of the reac on will be
A. 0.36 B. 0.45
C. 0.54 ✓ D. 0.67
Q.140 The value of Kp is greater then Kc for a gaseous reac on when
A. Number of molecules of reactants and B. Number of molecules of reactants is greater
products are equal then those of products
✓ C. Number of molecules of products is greater D. Catalyst is added
than those of reactants
Q.141
A. High pressure B. Low pressure

C. Pressence of catalyst ✓ D. High concentra on of N2
Q.142 The dissocia on of a weak acid H2S in water can be suppressed by adding
A. KCl ✓ B. HCl
C. NH4Cl D. Any of these
Q.143 which of the following group may contain a metalloid?
A. IA B. IIA
✓ C. VIA D. IIA
Q.144 pKb value of NH4OH is 4.74. if the concentra on of NH4OH is 1 molar containing 0.1 molar NH4Cl, then pH of this
buffer will be
A. 3.74 ✓ B. 10.26
C. 4.74 D. 9.26
Q.145 The process in which ioniza on of an electrolyte is suppressed by the addi on of another strong electrolyte containing
one same ion is called:
A. Electrolysis B. Hydrolysis
✓ C. Common ion effect D. pyrolysis
Q.146 The element with atomic number 57 belongs to:
A. s-block ✓ B. transi on elements
C. lanthanides D. ac nides
Q.147 In the light of Mendeleev's periodic law. the proper es of element are periodic func on of their
A. atomic number ✓ B. atomic masses
C. volume D. density
Q.148 The energy required in addi on to average energy of reactants to convert them into products is called
A. enthalpy func on B. heat of reac on
C. effec ve energy ✓ D. ac va on energy
Q.149 The elements which lies in the same group of periodic table as mercury is:
A. gold B. thallium
✓ C. cadmium D. n
_______________________________________________________________________________________
Q.150 Concentra on of reactants and products at the state of equilibrium is called
A. final concentra on B. ini al concentra on
C. normal concentra on ✓ D. equilibrium concentra on
Q.151 Which of the following has highest first ioniza on poten al?
A. Carbon B. Oxygen
✓ C. Nitrogen D. Boron
Q.152 Which of the following species has the highest ioniza on poten al?
A. Ne B. AI+
C. Mg+ ✓ D. Li+
Q.153 H2SO4is a dibasic acid which dissociates Completely in water. What will be morality of this acid which has a pH 1:
A. 0.5M B. 0.005M
✓ C. 0.05M D. 1M
Q.154 What is the concentra on of [H+]aqin 0.5 mol dm-3solu on of concentrated sulphuric acid?
-3
A. 0.25 mol dm B. 2 mol dm-3
C. 0.5 mol dm -3 ✓ D. 1 mol dm-3
Q.155 In 1000 molecules of 0.001 M ace c acid the number of H+ions is 12.6, then its percentage of ioniza on is
A. 1.33% B. 1.26%
✓ C. 12.6 D. 1%
Q.156 pH of water by addi on of base is
✓ A. More than 7 B. Less than 7
C. Equal to 7 D. No effect
Q.157 Californium is the member of:
A. alkali metals B. alkaline earth metals
✓ C. ac nide series D. lanthanide seires
Q.158 According to modern periodic law varia ons in the proper es of element are related to their
✓ A. Atomic weights B. Atomic numbers
C. Nuclear weights D. Neutron-pro n ra os
Q.159 Equilibrium mixture contain ammonia in Haber process
A. 25% ✓ B. 35%
C. 30% D. 45%
Q.160 The rate at which a substance reacts is directly propor onal to its ac ve mass and the rate of reac on is directly
propor onal to the product of the ac ve masses of reac ng substances is known as
A. Le-chatelier's principle B. Law of conserva on of energy
✓ C. Law of mass ac on D. None of all
Q.161 How does the ioniza on energy of 1st group elements vary?
A. Increases down the group ✓ B. Decreases down the group
C. Remains unchanged D. Varia on is not regular
Q.162 Which of the following ion has the highest value of ionic radius?
A. Li+ B. F-
✓ C. O2- D. B3+
Q.163 The value of Kpis greater than Kcfor a gaseous reac on when
✓ A. number of molecules of products is greater B. number of molecules of reactants is greater
than the reactants than those of products
C. number of molecules of reactants and D. catalyst is added
products equal
Q.164 element whose outer electronic configura on vary from ns2 np to na1 np6 cons tute:
A. s-block elements ✓ B. p-block elements
C. d-block elements D. f-block elements
Q.165 The set of elements to which law of octaves applies is:
✓ A. Be,Mg,Ca B. B, N, C
C. Ar, K, Ca D. Se, Te, As
_______________________________________________________________________________________
Q.166 The 14 elements have been placed in VI period and lll group of the period table which are called
A. inert gas B. alkaline earth metals
C. alkali metals ✓ D. rare earth metals
Q.167 On cooling Kl salt in water favour
A. More dissolu on B. Forward reac on
✓ C. Crystalliza on D. No effect
Q.168 Kspfor BaF2is 1.35 x 10-5, the concentra on of Ba++ions is
✓ A. 2.38 x 10 -2
B. 4.76 x 10-2
-4
C. 4.76 x 10 D. 7.2 x 10-3
Q.169 The pH of 10-3mole dm-3of an aqueous solu on of H2SO4is
A. 3.0 ✓ B. 2.7
C. 2.0 D. 1.5
Q.170 Which of the following oxides is amphoteric in character?
A. CaO B. CO2
C. SiO2 ✓ D. SnO2
Q.171 Human blood has a pH of:
A. 8.35 B. 9.35
✓ C. 7.35 D. 6.35
Q.172 point out the correct statement:
✓ A. covalent character of metal halides increase B. boiling points of group IVS hydrides decrease
from le to right in a period down the group
C. ionic character of group IIA oxides decreases D. the basicity of group IIA oxides decreases on
on descending the group descending the group
Q.173 The a rac on that an atom exerts on a pair of electrons that are being shared with another atom for forming covalent
bond is referred to as its
A. Electron affinity ✓ B. Electronega vity
C. Ionisa on energy D. Valency
Q.174 chose the most basic oxide:
A. SnO2 B. MgO
✓ C. Na2O D. SiO2
Q.175 A solu on of NaOH has pH = 13, then concentra on of NaOH is
A. 10-13M B. 1013M
✓ C. -1
10 M D. 10+1M
Q.176 In a chemical reac on equilibrium is said to have been established when:
✓ A. Rate of opposing reac ons are equal B. Rate constants of opposing reac ons are
equal
C. Opposing reac ons stop D. Concentra on of reactants and product are
equal
Q.177 Elements in the periodic table are classified into four blocks This classifica on is based upon
✓ A. Valence orbital B. Sub-shell
C. Shell D. All
Q.178 Which of the following pairs are chemically dissimilar?
A. Na and K B. Ba and Sr
C. Zr and Hf ✓ D. Ca and Zn
Q.179 Mark the element having greatest value of electronega vity on combina on with hydrogen:
✓ A. chlorine B. sodium
C. silicon D. sulphur
Q.180 Among O, C, F, CI, Br, the correct order of increasing radii is
✓ A. F O C CI Br B. F C O CI Br
C. F CI Br O C D. C O F CI Br
Q.181 If the concentra on of the reactants is increased then the equilibrium will
✓ A. Shi towards the forward direc on B. Shi towards the backward direc on
C. Not be affected D. None
_______________________________________________________________________________________
Q.182 A reac on is reversible because:
A. Products are stable B. Reactants are reac ve
✓ C. Products are reac ve D. Reactants are stable
Q.183 For which system does the equilibrium constant Kc has units of (concentra on)-1
A. B.
✓
C. D.
Q.184 If pH of buffer of 1 mole dm-3of HCOOH + 0.1 mole dm-3HCOONa having pKa = 3.78 is
A. 1.78 ✓ B. 2.78
C. 3.78 D. 4.78
Q.185 Buffers having pH less than 7 are made
✓ A. mixture of weak acid + salt of it with strong B. mixture of weak acid + salt of it with weak
base base
C. mixture of weak base + salt of it with strong D. mixture of weak base + salt of it with weak
acid base
Q.186 At 90°C, pure water the [H3O+] = 10-6mol L-1. The value of kwat 90°C is
A. 10-6 B. 10-8
✓ C. 10-12 D. 10-14
Q.187 Which has largest first ioniza on energy?
✓ A. Li B. Na
C. K D. Rb
Q.188 Which pair of the following pairs of elements belongs to same period of periodic table?
A. CI, Br B. Na, Ca
C. Ca, CI ✓ D. Na, Cl
Q.189 pH of human blood is
A. 7 B. 7.25
✓ C. 7.35 D. 7.47
Q.190 The solubility product of AgCl is 2 x 10-10mol2dm-6. The maximum concentra on of Ag+in the solu on is
A. -10
2 x 10 mol dm -3 ✓ B. 1.41 x 10-5mol dm-3
C. 1 x 10-10mol dm-3 D. 4 x 10-20mol dm-3
Q.191 The unit of concentra on is
A. mol. ml ✓ B. mol dm-3
-1
C. gm equivalent lit D. g lit-1
Q.192 Law of mass ac on states that rate of chemical reac on is directly propor onal to the product of ac ve masses of the
reactants. The term ac ve mass means
A. Number of moles B. Total pressures of the reactants
✓ C. 3
Number of moles per dm of reactants D. Mass in grams converted to products
Q.193 Which of the following has smallest solubility product
A. Al(OH)3 B. Ca(OH)2
C. MG(OH)2 ✓ D. Fe(OH)3
Q.194 Temperature during contact process equilibrium mixture is recycled at
A. 400C° B. 200C°
✓ C. 400-500C° D. 650C°
Q.195 At 1000 C, the equilibrium constant for the reac on of carbon monoxide and oxygen to produce carbon dioxide is very
large (Kc= 1.2 x 1022). When the reac on is at equilibrium the
✓ A. Concentra on of carbon dioxide will be much B. Concentra on of carbon dioxide will be much
larger than one or both reactant smaller than concentra ons of both reactants
C. Concentra on of carbon monoxide will be D. Concentra ons of both reactants must be
much larger than the concentra on of carbon much smaller than the concentra on of
dioxide carbon dioxide
Q.196 The valency of noble gases, in general is
✓ A. Zero B. One
_______________________________________________________________________________________
C. Three D. Two
Q.197 The defects in the Mendeleev's Periodic table is/are:
A. in spite of their different proper es, alkali B. K(at.wt.39.1)has been placed a er argon
metals and coinage metals have been grouped (at.wt.39.9)
together C. similar elements lime Cu and Zn have been
placed different groups
✓ D. all above statement are correct,
Q.198 What is pH and pOH of pure water at 25°C
✓ A. 7 B. 14
-14
C. 1 x 10 D. 1 x 1014
Q.199
C. Zero D. Cannot be predicted
Q.200 The op mum condi ons of temperature and pressure to get maximum NH3form N2and H2gases is
A. 200°C and 10 atmosphere B. 0°C and 1 atmosphere
✓ C. 400°C and 200-300 atmosphere D. 200°C and 100 atmosphere
Q.201 Mendeleeve's periodic law is based upon:
A. valency ✓ B. atomic weight
C. equivalent weight D. atomic number
Q.202 Which of the following is most electronega ve?
✓ A. Carbon B. Silicon
C. Lead D. Tin
Q.203 Le-chatlier's principle is applied on the reversible reac ons in order to
A. determine the rate of reac on B. predict the direc on of reac on
C. determine the extent of reac on ✓ D. find best condi ons for favourable shi ing
the posi on of equilibrium
Q.204 Sixth period of periodic table contains number of elements:
A. 10 B. 18
✓ C. 32 D. 8
Q.205
A. 40 x 10-4 ✓ B. 4 x 10-4
C. 4 x 10-3 D. Difficult to compoute with out more data
Q.206 Chemical equilibrium involving reactants and products in more than one phase
A. Sta c B. Dynamic
C. Homogeneous ✓ D. Heterogeneous
Q.207 0.1 MHCl has pH = 1.0, it is about 100 mes stronger than ace c acid. Then pH of ace c acid will be
A. 0.1 B. 2.0
C. 1.3 ✓ D. 3.0
Q.208 Which of the following elements is most electronega ve?
A. Oxygen B. Chlorine
C. Nitrogen ✓ D. Fluorine
Q.209
A. 2 B. 1
C. 0.5 ✓ D. 0.25
Q.210 The pressure of a gas will ______ when the volume is decreased and will ______ when the absolute temperature is
decreased
_______________________________________________________________________________________
✓ A. Increase .... Decrease B. Increase .... Increase
C. Decrease ..... Decrease D. Decrease .... Increase
Q.211 On the basis of size of atoms, the correct order is:
A. Zn < Hg B. Sn < P
✓ C. Hf > Ti D. C > Ge
Q.212 A chemical reac on A→ B is said to be in equilibrium when:
✓ A. Rate of transforma on of A to B is equal to B B. 50% reactant has been changed to B
to A
C. Conversion of A to B is 50% compete
D. Complete conversion of A to B has taken place
Q.213 The zero group of periodic table was introduced by:
A. Dobereiner B. Newland
C. Ramsay ✓ D. Mendeleev
Q.214 Buffer ac on can be explained by
A. Le. Chatlier principle B. Law of mass ac on
✓ C. Both a and b D. Ostwald law
Q.215 If Kspvalue is large, the salt in water is:
✓ A. More soluble B. Less soluble
C. Moderately soluble D. No Concentra on
Q.216 pH of 1 molar NaOH is
A. 7 B. zero
✓ C. 14 D. 10
Q.217 Electron affinity depends on
A. Atomic size B. Nuclear charge
C. Atomic number ✓ D. Atomic size and nuclear charge both
Q.218 Which of the following is an inert gas?
A. H2 B. O2
C. N2 ✓ D. Argon
Q.219 The correct statement is:
A. Cu+is smaller than Cu atom ✓ B. Cu+is large than Cu++ion
C. Cu+is lager than Cu++ion D. Cu++ions are equal in size
Q.220 Elements whose atoms have two outermost shells incomplete are called:
✓ C. d-block elements D. f-block elements
Q.221 Almost forward reac on is complete when value of Kcis:
A. Neither large nor very small B. Very small
✓ C. Very large D. Negligible
Q.222 The equilibrium constant can be used to predict
A. Direc on of reac on B. Extent of a reac on
C. Effect of changing condi on ✓ D. All of these
Q.223 If Kcis a reac on of very large, it indicates that equilibrium occurs:
A. With the help of a catalyst B. With no forward reac on
C. At a low product concentra on ✓ D. At a high product concentra on
Q.224 The correct arrangement of increasing order of atomic radius among Na, K, Mg, Rb is
A. Mg < K < Na < Rb ✓ B. Mg < Na < K < Rb
C. Mg < Na < Rb < K D. Na < K < Rb < Mg
Q.225 Which is correct statement?
A. the ioniza on energy of calcuim is lower than ✓ B. the ioniza on energy of calcium is lower
the of berium than that of magnesium
C. the ioniza on energy of calcium is higher than D. the ioniza on energy of calcium is lower than
that of beryllium that of stron um
Q.226 f block elements are also called
_______________________________________________________________________________________
A. Outer transi on element ✓ B. Inner transi on elements
C. Alkaline earth elements D. Coinage earth metal
Q.227 Which of the element is the best conductor of electricity
A. Zn B. Fe
✓ C. Cu D. Ca
Q.228 Mark the hydride which has lowest mel ng point a in the followings
A. H2Te B. H2Se
✓ C. H 2S D. H 2O
Q.229 Which one of the following aqueous solu ons has highest pH:
A. 0.1M HNO3 B. 0.1M HCI
C. 0.02MH2SO4 ✓ D. 0.1M NaOH
Q.230 Units of Kware
A. Mol dm-3 B. Mol-2dm+6
✓ C. Mol2dm-6 D. Mol2dm-3
Q.231 The pH of neutral solu on having pKw = 13.26 at 50°C is
A. 6 ✓ B. 6.63
C. 7 D. 7.13
Q.232 When rate of forward reac on is equal to rate of backward reac on, then the equilibrium established is called
A. Sta c equilibrium ✓ B. Dynamic equilibrium
C. Chemical equilibrium D. None of all
Q.233 Which of the following statements is most appropriate about effec ve nuclear charge? It depends upon
A. The shielding constant B. The atomic number
C. The charge on the nucleus ✓ D. Both the nuclear charge and the shielding
constant.
Q.234 A solu on with pH =0, its H+ion concentra on is
A. 1 x 1014 B. 1 x 10-14
✓ C. 1 D. 1 x 101
Q.235 Variable valency is generally exhibited by
A. Normal elements ✓ B. Transi on elements
C. Metallic elements D. None of these
Q.236 When HCl is added to H2S aqueous solu on its ioniza on:
C. Remains constant D. First decrease than increse
Q.237 The elements having same electronic configura on in the outermost energy levels are expected to show:
✓ A. nearly same physical and chemical B. different physical and chemical proper es
prooper es
C. same physical and chemical proper es
D. divers physical and chemical proper es
Q.238 Unit of Kc for ammonia forma on
A. Mol2dm+6 ✓ B. Mol-2dm+6
C. Mol+2dm-6 D. Mol-2dm-6
Q.239 The ioniza on poten al is lowest for the
A. Halogens B. Inert gases
C. Alkaline earth metals ✓ D. Alkali metals
Q.240 In which of the following cases does the reac on go farthest to the comple on
✓ A. Kc= 102 B. Kc= 10-2
C. Kc= 10 D. Kc= 1
Q.241 In a vessel containing SO3, SO2and O2at equilibrium, some helium has is introduced so that the total pressure
increases while temperature and volume remain constant. According to Le Chatelier's principle, the dissocia on of SO3
A. Increases B. Decreases
✓ C. Remain unaltered D. Changes unpredictably
Q.242 Chose the incorrect statement:
_______________________________________________________________________________________
A. metallic character increases down the group ✓ B. mel ng character in crease along a period
C. metallic character decreases along a period D. metallic character remains the same down the
group
Q.243 By increasing the volume in decomposi on of PCl5reac on at equilibirum
A. Decrease pressure ✓ B. Moved forward direc on
C. Move backward direc on D. No effect
Q.244 pH of milk is
A. 4 ✓ B. 6.5
C. 7 D. 7.5
Q.245 The least metallic character among the following id of:
A. Te B. Rb
✓ C. I D. In
Q.246 Which of the following has greatest tendency to lose electron?
A. F ✓ B. Fr
C. S D. Be
Q.247 The most acidic oxide among the following is:
A. CI2O7 B. Na2O
C. AI2O3 ✓ D. P4O10
Q.248 The rate at which a substance reacts, is directly propor onal to its ac ve mass and the rate of a reac on is directly
propor onal to the product of the ac ve masses of reac ng substances, is called
A. law of conserva on of energy ✓ B. Le-Chateliers principle
C. law of mass ac on D. none of these
Q.249 Point out one of these that does not reflect the periodicity of the elements:
A. ioniza on poten al ✓ B. electronega vity
C. bonding behavior D. neutron/proton ra o
Q.250 A solu on has pH = 0, its H+ion concentra on is
-14
A. 1 x 10 B. 1 x 1014
C. 1 x 10 1 ✓ D. 1
Q.251 Eka-aluminium and Eka-silicon are known as
✓ A. Gallium and Germanium B. Aluminium and silicon
C. Iron and sulphur D. Proton and silicon
Q.252 The solubility of KCIO3salt in water is decreased by adding
A. NaClO3 B. NaCl
C. KCIO4 ✓ D. KCl
Q.253 Which of the following is intermediate hydride
✓ A. MgH2 B. NH3
C. HF D. NaH
Q.254 Idea of pH and POH was put forward by
A. Gibbs B. Einstein
✓ C. Sorenson D. Le. Chatlier
Q.255 0.1 M HCl has pH = 1.1, it is about 100 mes stronger acid, pH of ace c acid is
A. 0.1 ✓ B. 2.1
C. 3.1 D. 1.3
Q.256 Select the hydride among the followings that has highest boiling point:
✓ A. SnH4 B. GeH4
C. SiH2 D. CH4
Q.257 Mark the Dobereiner triad:
A. Ne , Ar, k B. B, C, Si
✓ C. CI, Br, I D. Zn, Cr , Na
Q.258 Which of the following solu ons have zero pH?
✓ A. 0.5M H2SO4 B. 0.1M HNO3
_______________________________________________________________________________________
C. 0.5M CH3COOH D. 0.5M HCI
Q.259 A buffer solu on of 0.1 molar HCOOH and 0.1 molar HCOONa has pH = 3.78. To it 0.01 molar HCl is added, then pH of
the buffer solu on becomes
A. 2.78 B. 4.78
C. 3.78 ✓ D. 3.70
Q.260 Strongest reducing agent among the following is
A. F- B. Br-
C. CI2 ✓ D. I-
Q.261 Among the elements given below, the one with highest electroposi vity is
A. Cu ✓ B. Cs
C. Cr D. Ba
Q.262 Which of the following element does not occur in liquid form
A. Hg B. Ga
✓ C. Li D. Br
Q.263 Hydrides of forth period show greater boiling point than those of third period due to
A. Hydrogen bonding B. Low electronega vity
✓ C. Greater size D. Dipole-dipole interac ons
Q.264 An atom with high electronega vity has
A. Large size ✓ B. High ioniza on poten al
C. Low electron affinity D. Low ioniza on poten al
Q.265 Le-Chatelier's principle on the reversible reac ons in order to
A. Determine the rate of reac on ✓ B. Find the best condi on of favourable shi ing
the posi on of equilibrium
C. Predict the reac on of reac on D. Determine the extent of reac on
Q.266 The pH of rain water is
A. 6.5 B. 6.0
✓ C. 6.2 D. 6.4
Q.267 Which of the following oxides of manganese is more acidic in nature
A. MnO B. Mn2O3
C. MnO2 ✓ D. Mn2O7
Q.268 Mg++ has higher energy of hydra on
A. Si4 B. Al3+
C. Na+ ✓ D. Be++
Q.269 Point out the amphoteric oxide:
A. Magnesium oxide ✓ B. an mony oxide
C. barium oxide D. silicon dioxide
Q.270 Which of the following groups of periodic table has en rely metals?
A. IV ✓ B. II
C. VI D. VII
Q.271 The pair of atomic number that represents elements which are both s-block elements is:
✓ A. 3, 2 B. 7, 15
C. 6, 12 D. 9, 17
Q.272 The change of concentra on of reactants or products per unit me is called
✓ A. order B. molecularity
C. rate of reac on D. none of these
Q.273 The element with atomic number 26 will be found in group
A. 2 ✓ B. 8
C. 6 D. 10
Q.274 Rate expression for ammonia synthesis
A. B.
_______________________________________________________________________________________
✓
C. D.
Q.275 If the difference of pKa valued of two acid is two then acid with smaller pKa is stronger than others
A. 2 mes B. 10 mes
C. 1000 mes ✓ D. 100 mes
Q.276 The element with atomic number 14 belongs to:
A. 2ndperiod ✓ B. 3erperiod
C. 4thperiod D. 5thperiod
Q.277 At 25°C the pH of water is 7. What will be the effect on pH of water at 100°C:
✓ A. pH decreases B. pH increases
C. pH will remain same D. pH first increase then decrease
Q.278 which of the pairs belong to the same group of periodic table?
A. elements with atomic number 11 and 33 B. elements with atomic number 17 and 38
✓ C. elements with atomic numbers 17 and 53 D. elements with atomic number 20 and 40
Q.279 The pH of a solu on is zero, it will be:
A. Highly basic B. Neutral
✓ C. Highly acidic D. Moderately acidic
Q.280 Which one of the following aqueous solu ons has the highest pH
✓ A. 0.1 MnaOH B. 0.1 MHCl
C. 0.2 MH2SO4 D. 0.1 MHNO3
Q.281 Make the correct statement:
✓ A. Na+is smaller than Na atom B. Na+is larger than Na atom
C. Cl-is smaller than Cl atom D. Cl-(ion) and Cl (atom) are equal in size
Q.282 Kc < [ products]/[Reactants] favors
A. Low of mass ac on B. Rate expression
C. Forward reac on ✓ D. Backward reac on
Q.283 Which one of the following aqueous solu ons has lowest pH:
A. 0.1M Ba(OH)2 B. 0.1M NaOH
C. 0.1M KOH ✓ D. 0.1M HCI
Q.284 Which statement is incorrect for a buffer solu on
✓ A. A solu on of strong acid and salt of this acid B. A solu on of weak base and salt of this base
with strong base with strong acid
C. A solu on of mixture of weak acid and its salt D. A solu on which resists the change in its pH
with strong base value by adding small quan ty of acid or base
Q.285 The substance which accept proton is a base favours concept
A. Arrhennius B. Lewis
✓ C. Lowery Bronsted D. Lux.flood
Q.286 In a chemical equilibrium, the rate constant of the backward reac on is 7.5 x 10-4and the equilibrium constant is 1.5.
So the rate constant for the forward reac on is
A. 5 x 10-4 B. 2 x 10-3
✓ C. 1.125 x 10-3 D. 9.0 x 10-4
Q.287 What is the rela onship between kp and Kc
✓
A. B.
C. D.
Q.288 Le-Chatelier's principle is concerned with
A. catalysis B. photolysis
C. photosynthesis ✓ D. chemical equilibrium
Q.289 Hydrogen behaves as an oxidizing agent in its reac on with
A. Chlorine B. Nitrogen
_______________________________________________________________________________________
✓ C. Postassium D. Sulphur
Q.290 The ionic radius of Cr is minimum in which of the following componds
A. CrF3 B. Cr2O3
C. CrCI3 ✓ D. K2CrO4
Q.291 Buffer solu ons are mostly prepared by mixing:
A. Three substances B. Four substances
✓ C. Two substances D. Five substances
Q.292 The degree of hydra on energy from Li+ to Cs⊕
✓ A. decreases B. increases
C. remains same D. none of all
Q.293 Variable valency is characteris c of
A. Halogen ✓ B. Transi on elements
C. Alkali metals D. Noble gas
Q.294 Reac ons that proceed on both sides and never go to comple on are called
A. irreversible reac ons B. reversible reac ons
C. opposing reac ons ✓ D. spontaneous reac ons
Q.295
A. 0.004 B. 0.080
✓ C. 0.016 D. 0.160
Q.296 All of the following are the postulates of Arrhenius theory of ioniza on except
A. Ioniza on is reversible process B. Electrical conduc vity of a solu on of an
electrolyte depends on the extent to which
the electrolyte ionize in solu on
✓ C. Strong electrolyte ionize to a greater extent D. Electrolyte ionize in water to produce ca ons
in water and anions
Q.297 Mark the correct statement keeping in view the electron affini es of
two elements:
✓ A. chlorine has greater value than bromine B. iodine has greater value than bromine
C. oxygen has less value than carbon D. sulphur has less value than oxuygen
Q.298 The ioniza on constant of an acid is expressed of NaHCO3, its Ka= 4.7 x 10-1. Then this solu on has character
A. acidic ✓ B. very weakly basic
C. alkaline D. neutral
Q.299 Which among the following elements have lowest value of IE1?
A. Pb ✓ B. Sn
C. Si D. C
Q.300 The pH of 0.001M NaOH aqueous solu on is:
A. 13 ✓ B. 11
C. 9 D. 8
Q.301 The ionic product of solu on is greater than solubility product. The solu on is
A. Saturated B. Unsaturated
✓ C. Supersaturated D. None of all
Q.302 On passing HCl gas through a saturated solu ons of commercial sodium chloride, pure crystals of NaCl are precipitated
due to
A. increase in pH of the solu on B. decrease in pH of the solu on
✓ C. common ion effect D. increase in ioniza on of NaCl
Q.303 The rate of a chemical reac on is directly propor onal to the product of the molar concentra on of the
A. products ✓ B. reactants
C. concentra ons D. catalysts
Q.304 Mark the incorrect statement for periodic classifica on of elements:
A. The first ioniza on energies of elements along B. the proper es of elements are the periodic
a period do not very in a regular manner with func on of their atomic number
_______________________________________________________________________________________
increases in atomic number C. for transi on elements the sub-shells are
filled with electrons without varia on with
increases in atomic number
✓ D. nonmetals are lesser in number than metallic
elements
Q.305 If water is added at equilibrium in hydrolysis of BiCl3, solu on is obtained
✓ A. Cloudy B. Clear
C. Transparent D. Normal
Q.306 The most abundant metal present in the human body is
✓ A. Ca B. Fe
C. K D. Na
Q.307 The term dynamic equilirbrium means that
A. the reac on has reached comple on and no B. the reac on has not reached comple on but
more product forms no more product forms
C. the rates of forward and backward reac ons ✓ D. the rate of forward reac on is equal to the
are equal and equal to zero rate of backward reac on
Q.308 When the value of Kcis very large
A. Reac on forward B. Reac on backward
✓ C. Reac on almost completed D. Reac on at equilibrium
Q.309
✓ A. Low temperature and high pressure B. High temperature and low pressure
C. Low temperature and low pressure D. High temperature and high pressure
Q.310 Among the following elements which one has the highest value of first ioniza on poten al?
A. Oxygen ✓ B. Argon
C. Barium D. Cesium
Q.311 The dynamic equilibrium is the state of a reversible chemical reac on at which the rate temperature and pressure and
rate of forward reac on are
✓ A. equal B. less
C. more D. changes constantly
Q.312 Alkali metals in each period have
A. Smallest size ✓ B. Lowest IE
C. Highest IE D. Highest electronega vity
Q.313 Keeping in view the sizer of the atoms , which order in correct one:
✓ A. B > Ga B. Ba > Mg
C. Lu > Ce D. CI > I
Q.314
✓ A. The value of Kp falls with the rise in B. The value of Kp falls with increasing pressure
temperature
C. Adding catalyst increases the equilibrium
2O 5 3
V yield of SO
D. The value of Kp is equal to Kc
Q.315 The sum of pH and pOH is:
A. 10 ✓ B. 14
C. 18 D. 7
Q.316 Buffer ac on can be explained by:
A. Le-Chateller's principle B. Law of mass ac on
C. common ion effect ✓ D. All of above
Q.317 Select the covalent hydride among the followings :
A. LiH ✓ B. GeH4
C. SrH2 D. CsH4
_______________________________________________________________________________________
Q.318 Which of the following solu on have zero pH
✓ A. 1 M HCl B. MH2SO4
C. 0.1 M HNO3 D. 1 M CH3COOH
Q.319 The best buffer is prepared when molar concentra ons of the salt and acid are equal, then its pH and pKa value are
related
A. pH = pKa B. pH < pKa
✓ C. pH > pKa D. pH x pKa = 14
Q.320 Who studied the effect of temperature on equilibrium
A. Van der Waal ✓ B. Vant Hoff
C. Arrhenius D. Lewis
Q.321 Catalyst use in Haber process
A. V 2O 5 B. V2O5and pt
C. Fe ✓ D. Pieces of Fe in fused mixture of
2O 3
and
2
MgO, Al SiO
Q.322 Na+,Mg2,AI3+ and Si4+ are isoelectronic ion Their sizes follow the order
A. Na+<Mg2+<AI3+<Si4+ B. Na+<Mg2+>AI3+>Si4+
C. Na+<Mg2+<AI3+>Si4+ ✓ D. Na+>Mg2+>AI3+>Si4+
Q.323 The pH of 10-3mol dm-3of an aqueous solu on of H2SO4is
A. 3.0 ✓ B. 2.7
C. 2.0 D. 1.5
Q.324 Which of the following is different from other three oxides
✓ A. MgO B. SnO
C. ZnO D. PbO
Q.325 Hydrogen gas and iodine vapours combine to gorm HI at 425°C, the same composition of mixture is present if
we start with decomposition of HI. It suggests
A. a sta c equilibrium B. law of mass ac on
✓ C. a dynamic equilibrium D. irreversble reac on
Q.326 A large value of Kcmeans that at equilibrium:
✓ A. Less reactants and more products B. Reactants and products in same amount
C. More reactants and less products D. None of above
Q.327 The substance which increase rate of reac on but remains unchanged at the end of reac on is called:
✓ A. Catalyst B. Indicators
C. Promoter D. Ac vator
Q.328 If the temperature in the synthesis of ammonia is decreased. The ammonia forma on
C. No effect D. Li le change
Q.329 Conjugate base of a very weak acid is:
A. Rela vely strong base B. Rela vely weak bass

✓ C. Rela vely very strong base D. Rela velyvery weak base
Q.330 The correct sequence of elements in the decreasing order of first ioniza on energy is
A. Na > Mg > AI > Si B. Mg > Na > AI > Si
C. AI > Mg > Na > Si ✓ D. Si > Mg > AI > Na
Q.331 In the periodic table, the element with atomic number 16 will be placed in the group
A. Fourteen ✓ B. Sixteen
C. Thirteen D. Fi een
Q.332 The rate of a chemical reac on is directly propor onal to product of major concentra on of reac on substance. It is
called:
A. Law of conserva on of energy ✓ B. Law of mass ac on
C. Rate law D. Ac ve mass rule
Q.333 The rate of reac on:
A. Remains same as reac on proceeds B. May decrease or increase as reac on
_______________________________________________________________________________________
proceeds
C. Increase as reac on proceeds ✓ D. Decrease as reac on proceeds
Q.334 The 14 elements have been placed in VI period and ii group of periodic table. These are called:
✓ C. rare earth metals D. inert gases
Q.335 The electron affinity of noble gas elements is
A. Low B. High
✓ C. Nearly zero D. Very high
Q.336 The element having largest radius is:
A. F ✓ B. I
C. CI D. Br
Q.337 Which of the following does not reflect the periodicity of elements?
A. Bonding behaviour B. Electronega vity
C. Ionisa on poten al ✓ D. Neutron/proton ra o.
Q.338 A buffer of a 0.09 molar ace c acid and 0.11 molar sodium acetate has pH = 4.83. if 0.01 mole NaOH in 1 dm3of the
buffer solu on is added, then pH of the buffer becomes
A. 4.74 ✓ B. 4.92
C. 5.0 D. 4.0
Q.339 Solubility product
A. is not for sparingly soluble ionic compounds ✓ B. is for sparingly soluble ionic compounds
C. is useful for soluble ionic compounds D. none of these
Q.340 The pH of 10-3mol dm-3of an aqueous solu on of H2SO4is
A. 3.0 ✓ B. 2.7
C. 2.0 D. 1.5
Q.341 Acid and bases when dissolves in water:
A. May not be completely dissociated B. May be completely dissociated
✓ C. May or may not be completely dissociated D. None of above
Q.342 Which of the following op ons contain only the factors which can have no effect on the value of the equilibrium
constant of a reac on?
A. concentra on, catalyst B. catalyst
✓ C. concentra on, pressure, catalyst D. temperature , catalyst
Q.343 Which of the following represents elements in order of increasing atomic size?
A. 1, Br, CI B. Na, Mg, C
C. C, N, O ✓ D. Li, Na, K
Q.344 A solu on having pH = 4 its OH-ion concentra on in mol dm-3is
A. 1 x 10-4 ✓ B. 1 x 10-10
C. 1 x 10-14 D. 1 x 10-12
Q.345 The mel ng point is lowest for
A. Be B. Mg
C. Ca ✓ D. Sr
Q.346 The number of elements in fourth period of periodic table is:
A. 8 ✓ B. 18
C. 10 D. 32
Q.347 Whenever a weak base is dissolved in water, it give its conjugate acid.Similarly a weak acid in water produces its
conjugate base.This conjugate acid-base pair concept is stated by
A. law of mass ac on B. Le-chatler's principle
C. common ion effect ✓ D. Lower Bronsted concept
Q.348 Mendeleev s periodic table has number of groups and number of periods
A. 6,7 ✓ B. 8,7
C. 8,12 D. 7,8
Q.349 Strength of an acid can be determined by
_______________________________________________________________________________________
✓ A. Pka B. Pkp
C. POH D. Pkw
Q.350 The pH of bananas is:
A. 3.6 B. 5.5
C. 6.2 ✓ D. 4.6
Q.351 An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtra on. What
are the main ions in the filtrate
A. Ag+and NO-3only ✓ B. Ag+and Ba++and NO-3
2+ -
C. Ba and NO 3only D. Ba2+and NO-3and Cl3-
Q.352 Which of the following is least soluble in water
A. AgCl B. AgBr
✓ C. Agl D. CH3COOAg
Q.353 In a given shell the order of screening effect is
A. f>d>p>s ✓ B. s>p>d>f
C. f>p>s>d D. p>d>s>f
Q.354 Number of elements present in 5th period is
A. 8 ✓ B. 18
C. 32 D. 24
Q.355 pH of water at 25°C q
A. 9.5 B. 7.5
✓ C. 7.0 D. 5.5
Q.356 Which is correct statement
A. 1stelectron affinity value is always nega ve B. Term electronega vity is associated with
molecule
C. Electron affinity is associated with atom ✓ D. All of above
Q.357 If we increase the pressure in decomposi on of PCl5it will favour the reac on in
A. Forward direc on ✓ B. Backward direc on
C. Equilibrium direc on D. None
Q.358 In the forma on of ammonia if pressure of the system is increased then the reac on _______ direc on
✓ A. Moves in forward B. Moves in backward
C. Remains in equilibrium D. None
Q.359 Ce-58 is member of:
C. d-block elements ✓ D. f-block elements
Q.360 Buffer capacity is maximum when both components have:
A. High concentra on B. Equal concentra on
C. Low concentra on ✓ D. High and equal concentra on
Q.361 When sodium hydride is electrolyzed, hydrogen is liberate:
✓ A. at anode B. at cathode
C. in electrolyte D. none of all
Q.362 Which of the following isoelectronic ions has the lowest ioniza on energy?
A. K+ B. Ca2+
C. CI- ✓ D. S2-
Q.363 Who introduced the term pH
✓ A. Henderson B. Sorenson
C. Thomson D. Goldstein
Q.364 The diagonal rela onship is due to:
A. similar polarizing power of ions B. similar electronega vi es
C. similar ionic or atomic radii ✓ D. all the above
Q.365 Which of the following can affect the magnitude of equilibrium constant Kpof a reversible gaseous reac on:
✓ A. Temperature B. Catalyst
_______________________________________________________________________________________
C. Pressure D. All of above
Q.366 Which statement is correct?
A. all the metals are good conductors of B. all the metals are good conductors of heat
electricity
C. all the metals form posi ve ions
✓ D. all the metals form acidic oxides
Q.367 Choose the incorrect statement among the following:
A. reducing power of elements increases from B. electronega vi es of elements increase along
le to right in a period a period
C. oxidizing power of elements increase along a ✓ D. basic nature of oxides increases from le to
period right in a period
Q.368 The sum of pH and POHis
A. 2 B. 7
✓ C. 14 D. 11
Q.369 The alkali metal which is liquid at 15°C is
A. K B. Cs
C. Na ✓ D. None
Q.370 Mark the correct statement:
A. the ioniza on energy of calcium is lower than ✓ B. the ioniza on energy of calcium is lower
that of barium then that of magnesium
C. the ioniza on energy of calcium is higher than D. the ioniza on energy of calcium is lower than
that of berylliun that of stron um
Q.371 Which is true about the electronega vity order of the following?
✓ A. P > Si B. C>N
C. Br > CI D. Sr > Ca
Q.372 Ace c acid is 1.33% ionized in 1000 molecules of 0.1 M ace c acid the number of H+ions is
A. 1.33 ✓ B. 13.3
C. 1.33 D. 1
Q.373 Mark the elements that belong to the same period:
A. Cr, In, Pb ✓ B. Li, Na, k
C. H, He,F D. Ca,Cr,Zn
Q.374 Mark the name of scien st who gave the concept of atomic number:
✓ A. Moseley B. Dalton
C. Newland D. Newton
Q.375 pH of the human blood which is essen ally maintained constant due to carbonates, bicarbonates, phosphates etc, is
A. 7.00 B. 7.25
✓ C. 7.35 D. 7.47
Q.376 The process requiring absorp on of energy is
A. F→F- B. H→H
C. CI→CI ✓ D. O→O-2
Q.377 The light metal in the periodic table is:
A. Hg B. Ca
C. Na ✓ D. Li
Q.378 Which of the following does not exhibit the periodicity in proper es of the elements?
A. Ionisa on energy ✓ B. N/P ra o
C. Electronega vity D. Atomic radius
_______________________________________________________________________________________
8 Reaction Kinetics
Q.1 Plaster of Paris is a hydrate of

A. BaSO4 ✓ B. CaSO4
C. MgSO4 D. ZnSO4
Q.2 The important ore of lead of
A. Chalcopyrites B. Haema te
✓ C. Galena D. Bauxite
Q.3 The example of a photochemical reac on is photosynthesis has order of reac on:
A. 1 B. 2
✓ C. 0 D. 3
Q.4 Keeping in view the uses of Al, mark the incorrect statement. Al is used:
A. as an abrassive in the form of abundum ✓ B. as an oxidizer in ar ficial
C. in form of foil for wrapping D. inform of foil wrapping
Q.5 Graphite is a good conductor of electricity the reason is that:
A. carbon atoms of each plane have sp2 B. there are Van der wall's forces of a rac on
between the planes of c atoms
C. carbon atoms have covlent bonds ✓ D. it has delocalized moblie electron
Q.6 AI2F2SiO4 is named as
A. Gibbsite ✓ B. Emerald
C. Bauxite D. Cryolite
Q.7 Noble gases are chemically inac ve because of
A. mono-atomic nature ✓ B. closed valence shell
C. low boiling points D. rare occurrence
Q.8 Which statement is true about the order of reac on:
✓ A. Order of reac on can only be determined by B. Order of reac on can be determined from a
an experiment balance equa on only
C. Order of reac on increases by increasing D. Order of reac on must be in whole number
temperature and not in frac on
Q.9 Lead pipes are not safe to carry drink water, this is because:
✓ A. lead react with 2O to form lead hydroxide B. αlayer of PbCO3desists over the pope
air and H which is soluble
C. lead reacts with O2to from lethargy
D. Pb form lead oxide with water which one
Q.10 In the thermite welding process we use
✓ A. AI powder B. Fe powder
C. Ca powder D. AI + Fe2O3mixture
Q.11 NaOH is prepared by the method
A. Down's cell B. Castner cell
C. Solvay process ✓ D. Castner Kellner cell
Q.12 Choose a set which has both member from the same periods of periodic table:
A. CI, Br B. Na, Ca
C. Ca, CI ✓ D. Na, CI
Q.13 The alkali metals
✓ A. From salt like hydrides B. Form salts which are predominantly
C. Show decreases chemical reac vity with dry D. Show increasing electro nega vity from Li to
_______________________________________________________________________________________
oxygen in going from Li to Cs Cs.
Q.14 Which of the following is anhydride of HNO2 (nitrous acid)
A. NO B. NO2
✓ C. N2O 3 D. N 2O 5
Q.15 Which one of the following reacts with heamoglobin fo from carboxyhaemoglobin:
A. H 2O 2 B. CO2
✓ C. CO D. O3
Q.16 Sulphuric acid has great affinity for water because
A. It hydrolyses the acid B. It decomposes the acid
✓ C. Acid forms hydrates with water D. Acid decomposes water
Q.17 Over half a million tonnes of bromine are manufactured annually and are mainly used for making other compound.
One important use
is for agricultural chemicals. What is another important use bromine?
A. an sep c agents B. bleaches for tex les and the paper industry
✓ C. flame-retardants and fir ex nguisher D. water purifica on
Q.18 Which is correct order of reac vity?
A. F < CI < Br > I B. F< CI < Br < I
C. F < CI > Br > I ✓ D. F > CI > Br > I
Q.19 When the concentra on of product is increase the instantaneous rate of reac on will be
C. May be nega ve D. May be posi ve
Q.20 The reac on which is zero order reac on
A. Decomposi on of N2O5 ✓ B. Forma on of Glucose in plant
C. Forma on of Fel2 D. Both a and c
Q.21 Ethyl alcohol on trea ng with P2O5 forms
A. Ethane ✓ B. Ethene
C. acetylene D. Phosphorous acid
Q.22 Silicon has the characteris c of a:
A. metal B. metalloid
✓ C. non-metal D. none of all
Q.23 Which of the following elements dose not form stale diatomic molecules:
A. oxygen B. nitrogen
✓ C. phosphorus D. iodine
Q.24 The coloured discharge tube for adver sement mainly contains
A. xenon ✓ B. neon
C. helium D. argon
Q.25 Which one is the weakest oxyacid of chlorine?
✓ A. HCIO B. HCIO4
C. HCIO2 D. HCIO3
Q.26 Alkali metals displace hydrogen from water forming bases due to the reason that
A. They are far above the hydrogen in ✓ B. They are far below the hydrogen in
electrochemical series based on oxida on electrochemical series based on oxida on
poten al poten al
C. Their ioniza on poten al is less than that of D. They contain only one electron in their
other elements. outermost shell
Q.27 Mark the element which shows greatness inert pair effect:
A. fluorine B. chlorine
C. bromine ✓ D. iodine
Q.28 The oxide which is not thermally stable is:
A. HgO ✓ B. Na2O
C. Li2O D. Na2O2
Q.29 Which of the following compounds is explosive in nature?
_______________________________________________________________________________________
A. Phosphorus trichloride ✓ B. Nitrogen trichloride
C. Hyponitrous acid D. Nitrosyl chloride
Q.30 Which borax is heated strongly, it gives:
A. Na2B4O7 ✓ B. NaBO+B2O3
C. B2O3 D. NaBO2
Q.31 Phosphine is not obtained by the reac on when
A. White P is heated with NaOH ✓ B. Red P is heated with NaOH
C. Ca2P2reacts with water. D. PH4I is boiled with water
Q.32
A. r = k[NO]2[ Br2] ✓ B. r = k [ No][Br2]

2
C. r = k[NO2Br][NO] D. r = k[NO][Br2]
Q.33 The elements which belong to group IIlA are called:
A. f-block B. d-block
✓ C. p-block D. s-block
Q.34 The substance not likely to contain CaCO3 is
A. Dolomite B. A marble states
✓ C. Calcried gypsum D. Sea shells
Q.35 Crystalline form of sulphur stable at room temperature is
✓ A. Rhombic sulphur B. Monoclinic sulphur
C. Plas c sulphur D. Prisma c sulphur
Q.36 Which property is not possessed by sillicones
A. Electrical insulators B. Low viscosity
C. Water repelling ✓ D. Good conductor of heat and electricity
Q.37 Which of the following is a Lewis acid?
A. PCI3 ✓ B. AICI3
C. NCI3
Q.38 Washing soda has formula
A. Na2CO3, 7H2O ✓ B. Na2CO3, 10H2O
C. Na2CO3. 3 H2O D. Na2CO3,
Q.39 The rate of reac on when the concentra on of reactants taken as unity is called
A. Speed constant B. Rate of reac on
C. Specific rate constant ✓ D. All
Q.40 In aluminothermic process aluminium acts as:
A. solder B. oxidizing agent
C. a flux ✓ D. reducing agent
Q.41 Stable oxy acidof born is:
A. neutric acid B. tetraboric acid
✓ C. orthoboric acid D. all are equally stable
Q.42 Rela vely pure sulphuric acid is manufactured by
A. lead chamber process B. Haber's process
✓ C. contact process D. Castner's process
Q.43 Which halide has highest mel ng point?
A. NaCI B. NaBr
✓ C. NaF D. NaI
Q.44 The number of atoms or molecules whose concentra on determine the rate of the reac on is called
A. molecularity ✓ B. order
_______________________________________________________________________________________
C. rate of reac on D. rate constant
Q.45 Nitrolim is
✓ A. CaCN2+ C B. Ca(CN)2+ C
C. CaC2+ C D. All
Q.46 Mg is an important component of which biomolecule occurring extensively in living world?
A. Haemoglobin ✓ B. Chlorophyll
C. Florigen D. ATP
Q.47 Which element among the following belongs to group IVA of the
periodic table?
A. Barium B. iodine
✓ C. Lead D. Oxygen
Q.48 White phosphorus is
✓ A. A mono atomic gas B. P4,a tetrahedral solid
C. P8, a crown D. A linear diatomic molecule.
Q.49 Which one of the following compounds does not exist?
✓ A. NCI5 B. AsF5
C. SbCI5 D. PF5
Q.50 Washing soda is
A. Na2CO3 B. Na2CO310 H2O
✓ C. KHCO3 D. NaHCO3
Q.51 The good conductor of electricity among the following is:
A. graphite B. soot
C. graphite ✓ D. carborundum
Q.52 The boron carbon nitrogen and oxygen have the following order the increasing ioniza on energy?
✓ A. B,C,O,N B. B,O,B,C
C. B,N,C,O D. O,B,C,N
Q.53 Oxides of silicon are:
A. gases B. liquids
✓ C. solids D. none of all
Q.54 The rate of reac on between two specific me intervals is called
A. instantaneous rate B. Ordinary rate
C. specific rate ✓ D. Average rate
Q.55 The chemical composi on of white lead is
A. Na2CO3 B. Pb3O4
✓ C. Pb(OH)2.2PbCO3 D. PbO
Q.56 Mark the true statement about the noble gases:
A. argon is used in lamps to make the metal ✓ B. argon is used in welding to stop oxida on if
filament a be er conductor the metal
C. they are very reac ve D. they have a great tendency to stop oxida on
of the metal
Q.57 Alum is not used
A. As a mordant in dyeing ✓ B. As an insec cide
C. In purifica on of water D. In tanning of leather
Q.58 Out of elements of group VA, the highest ioniza on energy is possessed by
✓ A. N B. P
C. Sb D. Bi
Q.59 If the temperature of the gaseous molecules increase then it will increase ______ of molecules
A. Concentra on ✓ B. Pressure
C. Ac va on energy D. May be all
Q.60 The difference of water molecules in gypsum and plaster of Paris is
A. 5/2 B. 2
_______________________________________________________________________________________
C. 1/2 ✓ D. 1 1/2
Q.61 The order of reac on provide value able informa on about _____ of reac on
A. Condi on B. Concentra on
✓ C. Mechanism D. All
Q.62 compound of alkaline earth metals are less soluble in water than the corresponding alkali metals because of :
A. their high eolectronega vity ✓ B. their increase covalent character
C. their high ioniza on energy D. high la ce energy
Q.63 All the elements of the oxygen family are
A. Non-metals B. Metalliods
C. Radioac ve ✓ D. Polymorphic
Q.64 HNO2 acts as an/a
A. Acid B. Oxidizing agent
C. Reducing agent ✓ D. All of three
Q.65 Which of the following phosphorus is most reac ve?
A. Red phosphorus ✓ B. White phosphorus
C. Scrlet phosphorus D. Violet phosphorous
Q.66 The unit of the rate constant is the same as that of the rate of reac on in
A. first order reac on B. second order reac on
✓ C. zero order reac on D. third order reac on
Q.67 The halogens exist as halides, which is not common place whose they are found:
A. in sea B. in lakes
✓ C. in the atmosphere D. as salts beds in ponds
Q.68 Which is true for an element R present in group 13 of periodic table?
A. It is a gas at room temperature B. It has oxida on state of +4
✓ C. It forms R2O3 D. It forms RX2
Q.69 Keeping in view the uses of sodium silicate, select the incorrect statement:
A. it is used in furniture polish B. it is as filler for soap
C. it is used as fire proof in tex le ✓ D. it is used in the forma on of withe
Q.70 The proper es of lithium are similar to those of Mg.this is beacause
✓ A. Both have nearly the same size B. The ra o of their charge to size is nearly the
same
C. Both have similar electronic configura ons D. Both are found together in nature.
Q.71 Which of the following factors does not influenced the rate of reac on
A. concentra on of the reactants ✓ B. nature of the reactants
C. molecularity of the reac on D. temperature
Q.72 The formula of nitre is
✓ A. KNO3 B. NaNO2
C. NaCI D. Na2CO3
Q.73 The noble gases consist of:
A. atoms linked by weak bonds B. triatomic molecules
C. diatomic molecules ✓ D. single free atoms
Q.74 Out of all elements f group VA.the highest mel ng and boiling points shown by the elements
✓ A. Te B. N
C. S D. Sb
Q.75 Bleaching powder has the property of bleaching due to the forma on of:
A. CI2 ✓ B. OCI-
-
C. CI D. O2
Q.76 Which one is colored among the following:
A. NO B. N2O
C. SO2 ✓ D. none of these
_______________________________________________________________________________________
Q.77 The structure of white phosphorus is
A. Square planar B. Pyramidal
✓ C. Tetrahedral
Q.78 Which of the following is correct?
A. In the Castner process of sodium extrac on, ✓ B. Sodium reduces CO2to carbon
NaCI is used as an electrolyte C. Magnesium reacts with cold water and
liberates hydrogen
D. Magnalium is one alloy of Mg and zinc.
Q.79 BiCI3 on hydrolysis forms a white precipitate of
A. Bismuthio acid ✓ B. Bismuthio oxychloride
C. Bismuth pentachloride D. Bismuth hydroxide
Q.80 Anodizing of AI is said when:
A. aluminium allay containing 35% AI B. aluminium prepared electroly cally
✓ C. aluminium coated electrically with D. aluminium obtained at anode
aluminium oxide
Q.81 White P when boiled with strong solu on of caus c soda produces
✓ A. Phosphine B. Posh acid
C. Phosphorus acid
Q.82 The least abundant element in the earth's crust among the following elements is:
A. Ba B. Sr
✓ C. Ra D. Ca
Q.83 Poisoning of a catalyst may be temporary or permanent in permanent poisoning.
✓ A. Catalyst reacts with poison. B. Physical state of catalyst changes.
C. Catalyst reacts with product D. Catalyst reacts with reactant.
Q.84 Which property of a liquid is measured by polarimeter:
A. Change in volume ✓ B. Op cal ac vity
C. Refrac ve index D. Conductance
Q.85 Which salt is produced by adding aqueous ammonia to aqueous sulphur dioxide un l just alkaline?
A. NH4SO3 B. NH4SO4
✓ C. (NH4)2SO3 D. (NH4)2SO4
Q.86 Which of the followoing hydrogen halide is the weakest acid in solu on?
A. HF B. HBr
✓ C. HI D. HCI
Q.87 Phosphide ion has the electronic structure similar to that of
A. Nitride ion B. Fluoride ion
C. Sodium ion ✓ D. Chloride ion
Q.88 The half life of N2O5is 24 minutes if the concentra on of N2O5is 0.1 M the concentra on of N2O5us ibtained 0.0125%
a er ______ minutes
A. 24 B. 48
✓ C. 72 D. 96
Q.89 Refrectrometric method is used when
A. Reac ons involving absorp on of I.R or U.V. ✓ B. Reac ons involving change of refrac ve
index
C. Reac ons involving ions D. change of op cal ac vity
Q.90 When SO2 is passed through acidified K2Cr2O7 solu on
A. The solu on turns blue B. The solu on is decolourised
C. SO2is reduced ✓ D. Green Cr2(SO4)3is formed
Q.91 An atom with atomic number 20 is most likely to combine chemically with the atom whose atomic number is
A. 11 B. 14
✓ C. 16 D. 10
Q.92 Which of the following has the lowest boiling point?
A. B B. AI
_______________________________________________________________________________________
✓ C. Ga D. Ti
Q.93 Borax lead test is given by?
A. all high metals B. all heavy metals
C. all divalent metals ✓ D. metals which form coloured metaborates
Q.94 Polyana on forma on is maximum in
A. Nitrogen B. Oxygen
✓ C. sulphur D. Boron
Q.95 Which is the weakest reducing agent?
A. Li ✓ B. Na
C. K D. Rb
Q.96 The chemical method used for determina on of rate of reac on is
A. spectroscopic B. conduc ometric
C. refractometric ✓ D. tra on
Q.97 Which of the following oxida on states are the most characteris c for lead and n respec vely
✓ A. +2,+4 B. +2,+2
C. +4,+4 D. +4,+2
Q.98 Which is substance not likely to contain calcium carbonate is:
A. dolomite ✓ B. calcined gypsum
C. a marble statue D. sea shells
Q.99 An increase in the concentra on of reactants
✓ A. increases the number of collisions directly B. has no effect on number of collisions
C. has inverse effect on number of collisions D. decrease the number of collisions
Q.100 Sodium metal can be stored under
A. Benzene B. Alcohol
✓ C. Kerosene D. Water
Q.101 The aqueous solu on of potash alum is
A. Basic ✓ B. Acidic
C. Neutral D. None of these
Q.102 Concentrated nitric acid gives ____ when it reacts with n
A. Nitric oxide ✓ B. Meta stannic acid
C. Ammonium nitrite D. Nitrous oxide
Q.103 S-block elements are situated in the along form of periodic taste:
A. outside at its bo om B. in the middle
✓ C. on the le hand side D. on the extreme right
Q.104 Which element among the following shows +2 oxida on as most stable oxida on state?
A. Si B. Fe
C. Ge ✓ D. Pb
Q.105 The unit of the rate constant is the same as that if the rate reac on in:
A. First order reac on B. Second order reac on
✓ C. Zero order reac on D. Third order reac on
Q.106 A catalyst ______ a er comple on of reac on
A. Remain unchanged in physical state B. Remains unchanged in mass
C. Remains unchanged in composi on ✓ D. Both b and c
Q.107 The addi on of a catalyst to a reac on changes the
A. Enthalpy B. Entropy
C. Nature of reactants ✓ D. Energy of ac va on
Q.108 Which of the following compounds of cement sets at the slowest rate?
✓ A. Dicalcium silicate B. Tri-calcium silicate
C. Tri-calcium aluminate D. Tetra calcium aluminoferrite
Q.109 Which is the most amphoteric?
_______________________________________________________________________________________
A. Na2O B. MgO
✓ C. AI2O3 D. CaO
Q.110 Which of the following is a monobasic acid
A. HBO2 ✓ B. H3BO3
C. H 2B 4O 7 D. H 6B 4O 9
Q.111 Which is a sublime substance
A. PCI3 B. PCI5
✓ C. P 2O 5 D. P 2O 3
Q.112 The halogens behave as oxidizing agents when they react with:
A. ac nides B. metalloid
✓ C. metals and non-metals D. all above
A. basic carbonates of Hg and Cu are soluble in B. Li2CO3is soluble in water
water
✓ C. carbonates of Na, K, NH4are soluble in water
D. carbonates of Ca, Ba, Sr are soluble in water
Q.114 Basicity of orthophosphoric acid is
A. 2 ✓ B. 3
C. 4 D. 5
Q.115 The method not used to find out the order of reac on
A. Method of hit and trial B. Graphical method
C. Differen al method ✓ D. Spectrometric method
Q.116 Bleaching proper es of bleaching power are due to its
✓ A. oxidizing proper es B. basic proper es
C. reducing proper es D. disinfec ng proper es
Q.117 In the electrolysis of aqueous solu on of NaCI the primary product obtained at anode is
A. Na B. CI2
✓ C. NaOH D. NaCi
Q.118 The halogens which are gases at room temperature are:
A. fluorine ✓ B. chlorine
C. bromine D. iodine
Q.119 Which of the following not used as pigment in paints?
A. Pb3O4 B. white bad
✓ C. lead dioxide D. lead chromate
Q.120 A catalyst is a substance which increase the rate of a chemical reac on, but remains unchanged at the end of reac on,
because
A. it increases the temperature B. it increase the surface area
C. it increase the rate constant ✓ D. it decrease the energy of ac va on
Q.121 The substance used as a smoke screen in warfare is
✓ A. SiCI4 B. PH3
C. PCI5 D. Acetylene
Q.122 Nitrogen molecule is chemistry less ac ve because of its
A. Small atomic energy ✓ B. High dissocia on energy
C. High electronega vity D. Stable electronic configura on
Q.123 Which of the following has the highest mel ng point?
A. NaCI ✓ B. NaF
C. NaBr D. Nal
Q.124 Alkaline earth metals comes under
A. Halogens ✓ B. Representa ve elements
C. Transi on elements D. Inner transi on elements
Q.125 The number of atoms or molecules whose concentra on determine the rate of reac on is called
_______________________________________________________________________________________
✓ A. rate of reac on B. order of reac on
C. molecularly D. rate constant
Q.126 Reac on kine cs is important to discover the ______ under which reac on will proceed most economically
A. Quan es B. Condi ons
C. Parameter ✓ D. May be all
Q.127 Which of the following is a man made element?
A. Ra ✓ B. Fr
C. Rn D. Lr
Q.128 The first ioniza on energy of silicon is lower than that of :
A. Ca B. K
C. AI ✓ D. C
Q.129 Mark the correct statement about the trend with increasing atomic number down the group of nobl gases
A. the density decreases B. the mel ng points decrease
✓ C. the boiling point increase D. the reac vity decreases
Q.130 Which of the following turn lead acetate paper into black
A. SO2 B. SO3
✓ C. H 2S D. NO3
Q.131 If Na+ ion is larger than Mg2+ and S2- ion is larger than Cl- ion which of the following will be least soluble in H2O?
✓ A. MgSO4 B. Na2SO4
C. MgCI2 D. NaCI
Q.132 XeF6 on complete hydrolysis gives
A. Xe ✓ B. XeO3
C. XeO2 D. XeO4
Q.133 Which metal is commonly used to remove air bubbles from molten metals
✓ A. Aluminium B. Copper
C. Sodium D. Calcium
Q.134 It is common observa on that rates of chemical reac ons differ:
✓ A. Greatly B. A li le bit
C. Moderately D. Do not differ
Q.135 The increase of Van der Waal's forces in halogens is in the order of:
A. Cl2> Br2> l2> F2 B. F2> CI2> Br2> I2
C. Br2> CI2> F2> I2 ✓ D. I2> Br2> Cl2> F2
Q.136 When H3BO3 is heated at 140°C which major product is formed
✓ A. H 6B 4O 9 B. H 2B 4O 7
C. HBO2 D. B 2O 3
Q.137 The element cesium bears resemblance with:
A. Ca B. Cr
C. both of above ✓ D. none of the above
Q.138 Which is true about the noble gases?
A. they are good conductors of heat B. they are good conductors of electricity
✓ C. they are unreac ve gases D. down the group the colour of the gas gets
darker
Q.139 The most stable allotropic form of sulphur is
A. Rhombic B. Monoclinic
C. Plas c ✓ D. Milk of sulphur
Q.140 AICI3 exist as dimmer because
A. AI has greater ioniza on poten al B. AI has larger radius
C. High charge in nucleus ✓ D. Incomplete p-subshell
Q.141 The solubility of aluminium hydroxide in sodium hydroxide solu on is due to forma on of :
✓ A. sodium meta aluminate B. sodium aluminium hydride
C. aluminium peroxide D. sodium aluminium hydroxide
_______________________________________________________________________________________
Q.142 In op cal rota on method, the angle through which plane polarized light is rotated by the reac ng mixture is measure
by
A. Galvanometer B. Voltmeter
✓ C. Polarimeter D. All
Q.143 The strongest oxidant among the following oxyacids is:
✓ A. HCIO4 B. HCIO3
C. HCIO2 D. HCIO
Q.144 Which of the halogens is radioac ve
A. F B. CI
C. I ✓ D. AT
Q.145 Which of the following will affect the rate constant [K] for a reac on:
A. Change in concentra on B. Change in pressure
C. Change in pH ✓ D. Change in temperature
Q.146 Which statement is false ?
A. boron resembles in many proper es with B. boron does not form B3+ ions
silicon
✓ C. boron trifluoride is a strong Lewis base.
D. aluminium is good reducing agent
Q.147 In zero order reac on, the rate is independent of:
A. Temperature of reac on ✓ B. Concentra on of reac on
C. Concentra on of products D. None of these
Q.148 The element having least value of ioniza on energy among the following elements is:
A. Mg B. Ba
C. Li ✓ D. Cs
Q.149 The reac on takes place among the molecules when they have
A. Ac va on energy B. Concentrated
C. Properly oriented ✓ D. Both a and c
Q.150 The first ioniza on poten al of AI is smaller than that of Mg. The reason is that:
A. atomic size of AI> Mg ✓ B. at has one electron in P-orbital
C. atomic size of AI<Mg D. not known
Q.151 The element having density less than 1g/cm3 at 20°C is:
A. Be B. Rb
✓ C. k D. Ca
Q.152 Magnesium reacts with hydrogen at high pressure in the presence of catalyst ---- forming magnesium hydride
A. Dolomite ✓ B. MgI2
C. Mg3N2 D. Epsom salt
Q.153 If the rate equa on of a reac on 2A + B→ products is, rate = K[A]2[B], and A is present in large excess, then
order of reaction is:
✓ A. 1 B. 2
Q.154 A catalyst is more effec ve when it is present in a ______ form
A. Solid ✓ B. Finely divided
C. Plate D. May be all
Q.155 Boric acid is prepared form borax by the ac on of
A. Hydrochloric acid B. Carbon dioxide
C. Sodium hydroxide ✓ D. Sodium carbonate
Q.156 Complex protein molecules which catalyses the organic reac ons in the living cells are called
A. living organisms ✓ B. enzymes
C. viruses D. bacteria
Q.157 Which technique is used to determin tje absorp on of radia on
A. Dilatometer method B. Op cal rota on method
✓ C. Spectrometry D. Refractometric method
_______________________________________________________________________________________
Q.158 Slaked lime reacts with chlorine to form

A. Ca (OCI)2 B. Ca (CIO3)2
✓ C. Ca (OCI) CI D. CaCI2
Q.159 _______ of fine pla num powder can convert 2.5 dm3of H2and 1.254 dm3of O2of water
A. 20 mg B. 15 mg
C. 10 mg ✓ D. 1 mg
Q.160 The maximum metallic bond strength is in:
A. Ca ✓ B. Be
C. Sr D. Mg
Q.161 The most important ore of aluminium is:
A. aluminite ✓ B. bauxite
C. cryolite D. feldspar
Q.162 S-block of periodic table contains:
✓ C. both Alkali and alkaline earth metals D. none of above
Q.163 Which one among the following maximum number of compounds?
A. Rn ✓ B. Xe
C. Ar D. Kr
Q.164 Alkaline earth metals show standard electrode poten al values which are very similar to their alkali metals due to:
A. diamaagne c nature B. high la ce energy of M2+in solu on
✓ C. high energies of hydra on of M2+in solu on D. none of these of M2+ions
Q.165 For a given reac on system, the minimum amount of energy which molecules must have to form an ac vated complex
is called:
A. Heat energy of reac on B. Mechanical energy
✓ C. Ac va on energy D. Ioniza on energy
Q.166 Which of the following is monovalent?
✓ A. Alkali metals B. Alkaline earth metals
C. Metalloids D. Metals
Q.167 Purifica on of aluminium by electroly c refining is known as
A. Hall's process B. Serpeck's process
✓ C. Hoop's process
Q.168 The formula of carnalite is:
A. H2Mg3. 7H2O B. CaMg3 (SiO3)4
C. MgSO4. 7H2O ✓ D. KCI . MgCI2. 6H2O
Q.169 Which gives green colour in firework?
A. Sodium B. Potassium
✓ C. Barium D. Calcium
Q.170 The definite gradua on of the physical property of hydrogen halides is:
A. heat of fusion B. m.p.
C. b.p. ✓ D. bond energies
Q.171 The nature of borax solu on is:
✓ A. acidic B. neutral
C. alkaline D. corrosine
Q.172 Which of the following minerals has no calcium
A. Gypsum B. Dolomite
C. Calcite ✓ D. Carnallite
Q.173 LiF is insoluble in water while NaF and soluble,This is due to:
A. high covalent nature B. high ΔH la ce
C. low ΔH la ce ✓ D. small ionic size of Li+
Q.174 Make the element which is found is solid state:
_______________________________________________________________________________________
A. chlorine B. bromine
✓ C. iodine D. fluorine
Q.175 Carbon acts as a strong
A. Oxidizing agent ✓ B. Reducing agent
C. Dehydra ng agnet D. None of these
Q.176 Which is a reducing agent
A. HNO3 B. H2SO4
C. H3PO4 ✓ D. HCi
Q.177 In dilatometric method ______ is directly propor onal to extent of reac on
A. Change in concentra on B. Change in pressure
✓ C. Change in volume D. Change in temperature
Q.178 Which metal is protected by a layer of its own oxide?
✓ A. AI B. Ag
C. Au D. Fe
Q.179 Decrease in concentra on of reactant is denoted by
A. dc/dt ✓ B. -dct/dt
C. +dct/dt D. None
Q.180 The halogen which reacts spontaneously with Au(S) to produce Au3+ is:
A. F2 B. CI2
C. I2 ✓ D. Br2
Q.181 Which of the following is the anhydride of perchloric acid?
A. CI2O B. CI2O6
C. CIO2 ✓ D. CI2 O7
Q.182 Which of the following alkali metal hydroxides in the strongest base?
A. LiOH B. NaOH
C. KOH ✓ D. CsOH
Q.183 The compounds of alkaline earth metals have the following magne c nature
✓ A. Diamagne c B. Paramagne c
C. Ferromagne c D. An ferromagne c
Q.184 Which of the following mineral does not contain AI?
A. Cryolite B. Mica
C. Feldspar ✓ D. Fluorspar
Q.185 The energy of hydra on of Mg2+ is larger than that of:
+
A. K B. AI3+
✓ C. Na+ D. Be2+
Q.186 Which of the following is different from the order three oxides?
✓ A. MgO B. SnO
C. ZnO D. Cr2O3
Q.187 Permonosulphuric acid is known as
A. Marshall's acid ✓ B. Carlo's acid
C. Sulphuric acid D. None of these
Q.188 A catalyst is a substance that
✓ A. increases the speed of reac on by lowering B. increases the speed of reac on by increasing
the ac va on energy the ac va on energy
C. increases the speed of reac on by decreasing D. increases the speed of reac on by increasing
the surface area the surface area
Q.189 Which of the following is most abundant alkali metal in combined state in a nature:
✓ A. s - or - p B. d- only
C. f- only D. Both d- and f-
Q.190 The metal used in the thermite process because of its ac vity is:
A. copper ✓ B. aluminium
_______________________________________________________________________________________
C. zinc D. iron
Q.191 With the progressive of the reac on the slope of the curve between concentra on of product and me
A. gradually becomes more steep ✓ B. gradually becomes less steep
C. no change occurs in slope D. none of these occurs
Q.192 When NaOH is made, the gas released at the cathode is
A. CI2 ✓ B. H2
C. O2 D. H 2O
Which is true for calcium or it compounds compared with the corresponding statement for magnesium?
A. calcium gas a smaller atomic radius B. calcium oxide reacts less vigorously with
water
✓ C. calcium reacts more vigorously with water D. the sum of the first tow ioniza on energies of
calcium is greater
Q.194 The atoms with high values of first ioniza on poten al values always have:
A. metallic proper es B. small ionic size
C. large atomic size ✓ D. strongly bound valence electrons
Q.195 The oxide in which N has the highest oxida on state
A. Nitrous oxide B. Nitric oxide
C. Nitrogen peroxide ✓ D. Nitrous anhydride
Q.196 Which one of the following ions has maximum the of hydra on?
✓ A. Mg2+ B. Ba2+
C. Na+ D. Cs+
Q.197 The acid used in the manufacture of explosives like trinitrotoluene is
A. Nitrous acid ✓ B. Nitric acid
C. Sulphuric acid D. Propanoic acid
Q.198 Among the halogens,the one which is oxidized by nitric acid is
A. fluorine B. bromine
C. chlorine ✓ D. iodine
Q.199 Increase in temperature increases the reac on rates of all
A. exothermic reac on B. endothermic reac on
✓ C. both of them D. none of them
Q.200 The name of mineral having formula NaA (SiO3)4.H2O is:
A. kaolin ✓ B. zeolite
C. calcite D. po ery clay
Q.201 PIC5 exists but NCI5 does no.It is due to the reason that.
A. nitrogen atoms is much smaller B. nitrogen is highly intert
C. NCI5is unstable ✓ D. nitrogen has no vacant d-orbital
Q.202 The gases which are released when carbon is oxidized by hot concentrated sulphuric acid are
✓ A. CO2 and SO2 B. CO and SO2
C. CO2and SO3 D. CO and SO3
Q.203 The actual number of atoms or molecules taking part in rate determining step is
A. Rate of reac on B. Velocity of reac on
✓ C. Order of reac on D. Molecularity
Q.204 Hypo is used in photography for
A. Developing picture B. Picture printed
C. The colour of picture ✓ D. The fixa on of picture
Q.205 In laboratory burners we use
✓ A. Producer gas B. Oil gas
C. Coal gas D. Gobar gas
Q.206 Which salt on hea ng does not give brown coloured gas
A. LiNO3 B. Pb(NO3)2
_______________________________________________________________________________________
✓ C. KNO3 D. AgNO3
Q.207 One sulphur molecule contains
A. 2 atoms of sulphur B. 4 atom of sulphur
✓ C. 8 atoms of sulphur D. 16 atom of sulphur
Q.208 Which of the following mineral of aluminum is most abundant
A. AI2O3 B. AI2O3H2O
✓ C. AI2O32H2O D. Al2O33H2O
Q.209 If the graph is plot between concentra on and me is a straight line then the rate of reac on is
A. Variable ✓ B. Uniform
C. Instantaneous D. May be all
Q.210 Portland cement is manufactured by using
A. Limestone, clay and sand B. Limestone, gypsum and sand
C. Limestone, gypsum and alumina ✓ D. Limestone, clay and gypsum
Q.211 Of the following species, one which is non-existent
A. XeF6 B. XeF4
✓ C. XeF5 D. XeF2
Q.212 Oxides of beryllium are
A. Acidic B. Basic
C. Amphoteric ✓ D. None
Q.213 choose the correct statement :
✓ A. diamond is the hardest and graphite is the B. graphite is the hardest which lamp black is the
so est so est
C. coal is the hardest and coke is the so est D. diamonis the hardest and coke is the so est
Q.214 Which of the following conceivable structures for CCI4 will have a zero dipole moment?
A. Square planar B. Square pyramid (carbon at apex)
C. Irregular tetrahedron ✓ D. None of the above
Q.215 The wire in the flash bulbs is made up of
✓ A. Mg B. Ba
C. Cu D. Ag
Q.216 With the increase in atomic weights,mel ng points of the alkali metals
A. Increase ✓ B. Decrease
C. Remain constant D. Do not show definite trend
Q.217 Ac on of caus c soda on aluminium hydroxide gives a compound having formula
A. AI2(OH)4 B. Na2AI(OH)4
✓ C. NaAIO2
Q.218 Which is formula of oirthoboric acid?
A. HBO2 B. H 2B 2O 7
C. H6B4O9 ✓ D. H3BO3
Q.219 Which of the following is liberated at cathode by the electrolysis of brine solu on (aqueous solu on of NaCI)
A. Na ✓ B. CI2
C. H2 D. NaOH
Q.220 Select the point in which boric acid is not used:
A. in candles B. in medicines
✓ C. in tra on as indicators D. in po ery industry
Q.221 The principle cons tuent of pyrex glass is
A. Zn ✓ B. B
C. Pb D. CI
Q.222 Which allotropic form of phosphorous is more reac ve
✓ A. White B. Black
C. Red D. Violet
_______________________________________________________________________________________
Q.223 Which one of the following is likely to have electronega vity similar to that of AI
A. Ba B. Ca
C. Mg ✓ D. Be
Q.224 Chemical formula of washing soda is:
A. NaHO3 B. Na2CO3, H2O
C. Na2CO3 ✓ D. Na2CO3, 10H2O
Q.225 Alkali metals are generally prepared by:
A. reduc on of corresponding oxide with B. reduc on of halides with hydrogen
powdered 'AI'
C. reduc on of metals oxide with crabon
✓ D. electrolysis of their anhydrous molten
halides
Q.226 A salt which on reac on with conc. H2SO2 gives colourless gas is:
A. nitrite B. iodide
C. nitrate ✓ D. chloride
Q.227 Mark the point which is isoelectronic with carbon atom:
A. O2- ✓ B. N+
C. AI3+ D. Na+
Q.228 The conversion of molecules of A to B follows a second order kine cs. Doubling the concentra on of A will increase
the rate of forma on of B by a factor of
A. 2 ✓ B. 4
C. 1/2 D. 1/4
Q.229 Mark the best reducing agent:
A. F̅ B. CI ̅
C. Br ̅ ✓ D. I̅
Q.230 Cement clinker is a mixture of:
✓ A. cacium silicate and calcium aluminate B. calcium silicate and gypsum
C. CaO, AI2O3and SiO2 D. CaO, MgO, AI2O3and Fe2O3
Q.231 BeF2 is soluble in water, whereas the fluorides of other alkaline earth metals are insoluble due to:
A. covalent nature of BeF2 B. ionic nature of BeF2
✓ C. greater energy of ++ion as compared to D. none of all
hydra on of Be crystal la ce
Q.232 Fluorine differs from other helogens due to its small size and restric on fit valence shell to an octet,Mark the incorrect
behaviouhr of fluorine:
A. it restricts to oxida on state-1 only B. it is more reac ve than other halogens
✓ C. it has highest first ioniza on energy D. it has electornega vity
Q.233 The order of alkali metals is:
A. Na, K. Li, Rb, Fe, Cs ✓ B. Li, Na, K, Rb, Cs, Fr
C. Fr, Li, Rb, K, Na, Cs D. Li, Na, Cs, k, Rb, Fr
Q.234 Mark the correct reason for the last reac vity of noble gases:
A. these are monoatomic B. atoms are very small
C. these are not found abundantly ✓ D. electronic shells are stable and completely
paired up
A. Increase as the rate of proceeds ✓ B. Decrease as the rate of proceeds
C. Remains the same as the reac on proceeds D. May decrease or increase as the reac on
proceeds
Q.236 When dangerous chemicals are transported by road vehicles must carry signs that indicate what measure should be
taken in the event of a spillage of the chemical carried.
Which material must be used if there were a spillage of the chemical carried.
A. ethanol B. jets of water
✓ C. sand D. water spray
Q.237 Which id the correct statement about the solubility of magnesium sulphate?
✓ A. energy of hydra on 4is higher than its B. ionic poten al of Mg2+is very low
of MgSO la ce energy
_______________________________________________________________________________________
C. SO42-contributes toward hydra on D. Mg2+and SO4-2have same radii
Q.238
✓ A. A first order reac on B. A second order reac on

C. Independent of the ini al concentra on of D. A zero order reac on
the salt
Q.239 Which of the following ac on occur at moderate rate:
A. Rus ng of iron B. Chemical weathering of stone work of
buildings by acidic gases in atmosphere
✓ C. Hydrolysis of an ester D. Fermenta on of sugars
Q.240 Which one of the compound is not known
✓ A. NCI5 B. AaCI5
C. PCI5 D. NCI3
Q.241 A pseudo uni-molecular reac on has order of reac on:
A. 3 B. 2
✓ C. 1 D. 0
Q.242 Which of the following is used for taking X-ray spectra of the diges ve system
A. CaSO4 B. MgSO4
✓ C. BaSO4 D. BaCO3
Q.243 Which of the most basic of the following
✓ A. Na2O B. BaO
C. As2O3 D. AI2O3
Q.244 When bleaching power is treated with carbon dioxide
✓ A. chlorine is evolved B. no reac on occours
C. calcium chloride is formed D. it absorbs the gas
Q.245 White enamel of our teeth is
A. Ca2(PO4)2 ✓ B. CaF2
C. CaCL2 D. CaBr2
Q.246 Which of the following allotropes of phosphorus is the most stable
A. White ✓ B. Black
C. Red D. violet
Q.247 The concentra on of product is increasing from 30 mole/dm to 40 mole/dm3in 0.5 sec then rate of reac on will be
3
______ mole dm-3sec-1

A. 10 B. 15
✓ C. 20 D. 25
Q.248 With increase of 10°C temperature the rate of reac on doubles. This increase in rate of reac on is due to:
A. Decrease in ac va on energy of reac on B. Decrease in number of collisions between
reactant molecules
C. Increase in ac va on energy of reactants ✓ D. Increase in number of effec ve collisions
Q.249 A substance X when heated with cons.H2 SO4 liberates a gas which turns starch paper blue.The substance X is
✓ A. Nal B. NaCI
C. NaBr D. NaNO3
Q.250 The metal used for making radia on shield is
A. AI B. Fe
C. Zn ✓ D. Pb
Q.251 Which of the following metals is protected by a layer of its own oxides?
✓ A. AI B. Ag
C. Au D. Fe
Q.252 The element which has a simple cubic la ce in solid state is
A. Se B. Te
✓ C. Po D. None of these
_______________________________________________________________________________________
Q.253 Lithium is strongest reducing agent among alkali metals due to which of the following factor?
A. Ioniza on energy B. Electron affinity
✓ C. Hydra on energy D. La ce energy
Q.254 Which of the following oxides is peroxide?
✓ A. Na2O2 B. MnO2
C. BaO D. SO2
Q.255 If reactants are conductor of electricity then ______ method is used to measure the change in concentra on of
reac on
A. Op cal rota on B. Refractrometric
C. Dilatometric ✓ D. Electrical conduc vity
Q.256 The one which does not show variable valency is
✓ A. Barium B. Titanium
C. Copper D. Lead
Q.257 The first ioniza on energies of alkaline earth metals are higher than those of the alkali metals.This is because
✓ A. There is increase int he nuclear charge of the B. There is decrease in the nuclear charge of the
alkaline earth metals alkaline earth metals
C. There is no change in the nuclear charge D. None of the above
Q.258 Which of the following proper es is not possessed by CO
A. Colourless B. Dissolve par ally in water
✓ C. Combus ble D. Very toxic
Q.259 Which of the following acids act both as reducing and oxidizing agent
✓ A. HNO2 B. H2SO4
C. H3PO4 D. HCIO4
Q.260 Which of the following elements is not present abundantly in earth crust?
A. O2 ✓ B. Na
C. Si D. AI
Q.261 The electroposi ve character increases from B to Al and decreases from Al to Tl.because of ?
✓ A. ineffec ve shielding of unclear charge by d- B. decrease ion electronega vity of the elements
electrons in case of Ga in and ll.
C. decrease in ioniza on energy
D. increase in size of the elements
Q.262 The rate of reac on is denoted by
A. dc/dp B. dc/ac
C. dc/dT ✓ D. dx/dt
Q.263 One gas bleaches the colour of flowers by reduc on and other by oxida on.These gases are
✓ A. SO2 andCI2 B. NH3 and SO2
C. CO and CI2 D. H2S and Br2
Q.264 Sodium reacts with water more vigorously than lithium because
A. It has higher atomic mass B. It is more electronega ve
✓ C. It is more electroposi ve D. It is a metal
Q.265 The rate of reac on is double when the temperature of a substance increases by
A. 10°F B. 5°C
✓ C. 10K D. May be all
Q.266 Which of the following is acidic in na ure
A. Be(OH)2 B. AI(OH)2
C. Mg(OH)2 ✓ D. B(OH)2
Q.267 A first order reac on is 20% completed in 10 minutes. In how much me will it be 75% complete approximately
A. 52 min ✓ B. 62 min
C. 72 min D. 82 min
Q.268 Which element belong to lV-A group of the periodic table?
A. O B. l
✓ C. Pb D. Ba
_______________________________________________________________________________________
Q.269 Limestone is not used in which of the following manufacturing processes?
✓ A. Phosphorus from phosphorite B. Ordinary (soda lime) glass
C. Iron from haema te D. Solvay process of sodium carbonate
Q.270 The number of unpaired electrons in the p-subshell of oxygen atom
A. 1 ✓ B. 2
C. 3 D. 4
Q.271 Iodine is mostly soluble in the solu on of:
A. NaOH B. H 2O
C. KMnO4 ✓ D. KI
Q.272 Leblanc process is employed in the manufacture of
A. Baking soda B. Washing soda
✓ C. Potash D. Plaster of paris
Q.273 If two ini al concentra on and mes for reac ons are given then which method is used to find out order of reac n
A. Method of hit and trial basis B. Method of large excess
C. Differen al method ✓ D. Half-life method
Q.274 Thermite reac on is used in the extrac on of?
A. Fe B. Mn
C. Cr ✓ D. all these
Q.275 Sulphuric acid is an anhydride of
A. sulphurous acid B. suphuric acid

✓ C. hyposulphurc aicd D. hydro sulphuric acid
Q.276 The temperature at which catalyze ac on is maximum is called ______ temperature
A. Appear consulate B. Transi on
C. Cri cal ✓ D. Op mum
Q.277 Rate of a chemical reac on generally increases rapidly, even for small increase in temperature because of rapid in:
✓ A. Frac on of molecules with energies more B. Collision energy
than ac va on
C. Average kine c energy of molecules
D. Ac va on energy
Q.278 Aqueous NaCI solu on is electrolyzed using pla num electrodes.What is the product formed at cathode?
A. Na ✓ B. H2
C. O2 D. CI2
Q.279 Borax is formed by reac ng colemanite with:
A. sodium chloride B. sodium carbonate
✓ C. sodium carbonate D. sodium nitrate
Q.280 The exponent appears in the rate equa on is called
A. Rate of reac on B. Molecularity
✓ C. Order of reac on D. May be all
Q.281 Mortar is a mixture of:
A. magnesium chloride tar and lime B. portland cement lime and water
✓ C. slaked lime sand and H2O D. slaked lime plaster of paris and H2O
Q.282 Caesium oxide will be
✓ A. Very strongly basic B. Acidic
C. Weakly basic D. Amphoteric
Q.283 In an experiment the concentra on of a reactant 'A' is doubled the rate increase four mes. If concentra on is tripled,
then rate increase nine mes. Thus the rate is propor onal to _________ of concentra on of 'A'
A. square root ✓ B. square
C. twice D. cube
Q.284 The energy of ac va on of forward reac on is less than that of backward reac on in:
✓ A. Exothermic reac ons B. Isothermic reac ons
_______________________________________________________________________________________
C. Endothermic reac ons D. All reac ons
Q.285 Which element form group 15 gives most basic compound with hydrogen?
✓ A. Nitrogen B. Bismuth
C. Arsenic D. Phosphorus
Q.286 Sodium conducts electricity because
A. It is a so alkali metal B. It has only one electron in the outermost orbit
✓ C. It has mobile electrons D. It gives hydrogen with water
Q.287 Choose the incorrect statement about alkali metals:
A. these metals are very reac ve B. alkali metal hydroxides are alkaline in nature
✓ C. alkali metals form carbonates which D. these are S-block elements
decompose when heated
Q.288
A. B.
✓
C. D.
Q.289 Which of the following imparts violet coloura on to the non-luiminous flame of Bunsen burner?
A. NaCI B. BaCI2
C. CaCI2 ✓ D. KCI
Q.290 Which of the following is not characteris cs of a pure quartz
A. Hard B. Refractor
C. Bri le ✓ D. Coloured solid
Q.291 Nitrogen dioxide cannot be obtained by hea ng
✓ A. KNO3 B. Ca(NO3)2
C. Pb(NO3)2 D. AgNO3
Q.292 The sum of the exponents of the concentra on of reactant is called
A. molecularly ✓ B. order of reac on
C. both of these D. a and b are same terms
Q.293 In the manufacture of cement which of the following is used?
A. Clay and silica ✓ B. Limestone and silica
C. Lime stone and clay
Q.294 Na is obtained by the electrolysis of molten NaCI by
A. Galvanic cell B. Down cell
✓ C. Nelson cell D. Fuel cell
Q.295 The chloride of an element A gives a neutral solu on in water.In the periodic table the element A belongs to
✓ A. First group B. Third group
C. Fi h group D. First transi on series
Q.296 The rate of reac on is doubled for every 10° rise in temperature. The increase in reac on rate as a result of
temperature rise from 10° to 100° is
A. 112 ✓ B. 512
C. 400 D. 614
Q.297 Which one has strong bond?
A. CI-Br ✓ B. F-F
C. F-CI D. F-Br
Q.298 Metals belonging to the same group in the periodic table are
A. Magnesium and sodium B. Magnesium and copper
✓ C. Magnesium and barium D. Magnesium and potassium
Q.299 Oleum is
A. Castor oil B. Oil of vitriol
_______________________________________________________________________________________
✓ C. Fuming of H2SO4
Q.300 The formula of china caly is:
A. Al2O3 B. AI2O32H2O
✓ C. AI2O3.2SiO2.2H2O D. AI2O3.SiF4
Q.301 Among the alkaline earth metals the element forming predominantly covalent compound is
A. Barium B. Stron um
C. Calcium ✓ D. Beryllium
Q.302 Mg(NO3)2 decompose on hea ng to give:
A. MgO + NO2 B. MgO + NO + O2
C. Mg + N2O +O2 ✓ D. MgO + NO2+ O2
Q.303 On hea ng upto 160 boric acid is converted into
A. HBO3 ✓ B. H 2 B 2O 7
C. H2BO3 D. B 2O 3
Q.304 Pbo is:
A. acidic B. basic
✓ C. amphoteric D. neutral
Q.305 The effect of temperature on the rate of reac on is given by
A. Arrhenius equa on B. Newton's equa on
✓ C. Boltzmann equa on D. Faraday's equa on
Q.306 Choose the correct statement about heat of vapouriza on of noble gases
A. noble gases have no heat of vapouriza on B. it decreases gradually down the group
✓ C. it increases gradually down the group D. none of all
Q.307 By the use of catalysis the energy of ac va on is
✓ A. Decreased B. Increased
C. Not affected D. None
Q.308 Rela ve sulphuric acid is manufactured by:
A. lead chamber acid is manufactured by B. Haber's process
✓ C. contact process D. Castner's process
Q.309 NaNO3 decomposes on hea ng at high temperature to give:
A. NO2 B. Na2O
✓ C. O2 D. N2
Q.310 The reac vity of the alkali metal sodium with water is made use of
A. In drying of alcohols ✓ B. In drying of bezene
C. In drying of ammonia solu on D. As a general drying agent.
Q.311 Which of the following has the least ioniza on poten al?
✓ A. Li B. He
C. N D. Zn
Q.312 What is not use of bleaching powder?
A. for the prepara on of chlorine and oxygen B. as disinfectant in the steriliza on of water
C. for bleaching co on ✓ D. for bleaching raw sugar
Q.313 Beryllium is placed above magnesium in the second group.Beryllium dust, therefore, when added to MgCI2 solu on
will
✓ A. Have no effect B. Precipitate Mg metal
C. Precipitate Mg D. Leads to the dissolu on of beryllium metal
Q.314 boron had very high,.p among the elements of group because of ?
A. small size of B B. very high E.N of B
C. very high I.Eof B ✓ D. strong bonding between individual atoms in
the solid state
Q.315 Which of the following is true peroxide?
✓ A. NO2 B. PbO
C. MnO2 D. BaO2
_______________________________________________________________________________________
Q.316 If the constant for half-life is 64 and the ini al concentra on of reactant of 2M for third order of reac on then half-life
of reac on is ______ sec
A. 4 ✓ B. 0.006
C. 8 D. 10
Q.317 The electronic configura on of metal M is 1s2,2s2,2p6,3s1, The formula of its oxide would be
A. MO ✓ B. M 2O
C. M 2O 3 D. MO2
Q.318 Which of the following salt cant be decomposed on hea ng
✓ A. Li2O3 B. Na2CO3
C. CaCO3 D. MgCO3
Q.319 Which is the name of mineral of aluminum?
✓ A. emerald B. talc
C. golemanite D. analcite
Q.320 Chlorophyll the main pigment responsible for absorp on of light in plants contains
A. Calcium B. Sodium
✓ C. Magnesium D. Potassium
Q.321 The name of mineral having formula Na2CO3 2NaHCO3 ,2H2O is:
A. sylvite B. carnalite
✓ C. trona D. chile saltpetre
Q.322 The experimental rela onship a reac on rate and the concentra on of reactants is called
A. order or reac on ✓ B. rate of law
C. ac vated complex D. molecularity
Q.323 Alkaline earth metals form diposi ve ions instead of uniposi ve ions choose the correct reason:
A. their second ioniza on energies are not ✓ B. compounds having diposi ve ions have more
different from first ioniza on energies. la ce energy
C. diposi ve ions have more charge D. undiopsi ve ions do not have stable electronic
configura on.
Q.324 The amount of energy required to form ac vated complex is called
A. Heat of reac on B. Enthalpy of reac on
✓ C. Ac va on energy D. All
Q.325 Which of the following is used in the bandage
A. CaCO3. MgCO3 B. CaSO4.2H2O
C. CaSO4.1/2 H2O ✓ D. CaSO4
Q.326 Which of the following elements of VIA group has the highest mel ng point & boiling point
A. S ✓ B. Te
C. Se D. Po
Q.327 Which of the following is a tetrabasic acid?
A. Orthophosphoric acid B. Hypophosphorous acid
C. Metaphosphoric acid ✓ D. Pyrophosphoric acid
Q.328 The atomic and ionic radii do not increase much from gallium to
thallium due to the reason of :
A. high nuclear charge from gallium to the ✓ B. intervening d and f electrons
thallium
C. high ioniza on poten al of these lelctrons
D. none of above
Q.329 The common mineral of alkali metal sodium id borax which has formula:
A. Na2B3O6 , 10H2O B. Na2B4O7
C. Na2B4O7 , 5H2O ✓ D. Na2B4O7 , 10H2O
Q.330 Which of the following will combine with Fe (II) ion to form a brown complex compound
A. N 2O ✓ B. NO
C. N 3O 3 D. NO2
Q.331 Which of the following is amorphous allotropes of sulphur
A. α-sulphur B. β-sulphur
_______________________________________________________________________________________
✓ C. γ-sulphur D. None of these

Q.332 The colour of I2 CCI4 is:
A. raddish brown ✓ B. violet
C. bluish green D. colourless
Q.333 PCI5 is kept in well stopped bo led because
A. It is highly vola le ✓ B. It reacts readily with mositure
C. It reacts with oxygen D. It is exploxive
Q.334 The ore CaSO4. 2H2O has the general name:
✓ A. gypsum B. dolomite
C. calcite D. epsom salt
Q.335 Which of the lead pigment is amphoteric in nature
A. Pb2O ✓ B. PbO
C. PbO2 D. 2PbCO32PbCO2
Q.336
A. 1.25 g ✓ B. 0.63 g
C. 1.77 g D. 0.50 g
Q.337 Decomposi on of Ph3O gives:
A. Pb + O2 ✓ B. Pb + PbO
C. PbC2O4 D. Pb3O4
Q.338 Which is the main product formed when chlorine is passed over dry shaked line
✓ A. CaOCI2 B. CaCIO2
C. Ca(OCI2) D. Ca(CIO2)2
Q.339 Borax lead test is responded by:
2+ 2+
A. Zn B. Pb
C. Al
3+
✓ D. none of these
Q.340 The oxide and chloride of an element X are separately mixed with water, The two resul ng solu ons have the same
effect on litmus.
A. sodium B. magnesium
C. aluminium ✓ D. phosphorus
Q.341 The correct formula of Plaster of Paris is
A. CaSO4.2H2O B. CaSO4
✓ C. CaSO4.1/2H2O D. CaSO4.3H2O
Q.342 The half- me for the first order decomposi on of a substance dissolved in CCl4in 2.5 hours at 30°C. The amount of the
substance le 10 hours, if the ini al weight of substance is 160g, is
A. 5g ✓ B. 10 g
C. 15 g D. 20 g
Q.343 _________ are called biocatalysts
A. Organic acids B. Organic bases
✓ C. Enzymes D. All
Q.344 Which of the following proper es of white phosphorous are shared by red phosphorus
A. It phosphorescences in air B. It dissolved in CS2
✓ C. It burns when heated in air D. It reacts with NaOH to give PH3
Q.345 All element of oxygen family are
A. Non metals B. Metalloids
C. Radioac ve ✓ D. Polymorphic
Q.346 The atomic numbers of four elements are given below. Which one is an alkaline earth metal?
A. 10 ✓ B. 20
C. 30 D. 40
_______________________________________________________________________________________
Q.347 the name of mineral having formula CaMg3 (SiO3)4 is:
A. soap stone (tale) B. carnalite
✓ C. asbestos D. epsum salt
Q.348 Fluorine is the best oxidizing agent because it has
A. highest electron affinity ✓ B. highest E∘red
C. highest E∘oxi D. lowest electro nega vity
Q.349 The rate determining step is the:
✓ A. Slowest step B. Fastest step
C. Moderate step D. Both (a) and (b)
Q.350 The property of halogens,that indicated incorrect is
A. F > CI > Br > I....ioniza on energy ✓ B. F > CI > Br > I.....electron affinity
C. F > CI > Br > I......electronega vity D. I >Br > CI > F.......density in liquid state
Q.351 Which one of the following g elements occurs free in nature?
✓ A. N B. P
C. As D. Sb
Q.352 Select the gas which is used in electrical discharge lights>
A. nitrogen B. oxygen
✓ C. neon D. helium
Q.353 Alkali metals are generally extracted by
A. Reduc on methods B. Double decomposi on methods
C. Displacement methods ✓ D. Electroly c methods
Q.354 The metals x and y form oxide but y also forms nitride when burnt in air . the metals x and y are:
A. Li : Na B. Cs,K
✓ C. K,Mg D. Mg,Ca
Q.355
Which one among the following acid is found as equilibrium mixture of monomer and hexamer?
A. HI B. HCI
✓ C. HF D. HBr
Q.356 The element having least value of heat of hydra on is:
A. Ca B. Li
C. Be ✓ D. Rb
Q.357 When we perform the same reac on by taking two different ini al concentra ons of a reactant for a second order
reac on then
A. reac on becomes exothermic B. energy of ac va on is different
C. mechanism of reac on is changed ✓ D. half life period is changed
Q.358 Bleaching powder may be produced by passing chlorine over
A. calcium carbonate B. hydrated calcium
C. anhydrous calcium ✓ D. calcium hydroxide
Q.359 Which of the following is most abundant in the earth's crust?
A. B ✓ B. AI
C. Ga D. Ti
Q.360 Epsom salt is the hydrate of one of the following
✓ A. Magnesium sulphates B. Ferrous ammonium sulphate
C. Magnesium ammonium phosphate D. Calcium sulphates
Q.361 Electroposi ve character increase sown the group due to
A. decrease in I.P B. decrease in electronega vity of the elements
C. increase in atomic size of elements ✓ D. all to the above
Q.362 The order of reac on of carbon tetra chloride from chloroform is
A. 4 B. 2.5
✓ C. 1.5 D. zero
_______________________________________________________________________________________
Q.363 Which of the following is an electron management of a noble gas?
A. 2,8,7 B. 2,8,2
✓ C. 2,8 D. 2,8,18,2
Q.364 Bond energy is highest for
A. Sn-Sn B. Si-Si
✓ C. C-C D. Ge-Ge
Q.365 Choose the non metallic element whose molecules contain maximum number of its atoms
A. SI ✓ B. P
C. O D. As
Q.366 A zero order reac on is one in which:
✓ A. Rate is not affected by changing B. Concentra on of reactant do not change with
concentra on of reactant of reactants passage of me
C. Reactants do not react D. One reactant s in large excess
Q.367 Chlorine acts as a bleaching agent only in the presence of
A. dry air ✓ B. moisture
C. sunlight D. pure oxygen
Q.368 Which one of the following is not an alkali metal?
A. francium B. cesium
C. rubidium ✓ D. radium
Q.369 Which one of the following has highest electroposi ve character?
A. Cu ✓ B. Cs
C. Ba D. Cr
Q.370 The chemical reac vity of substance is controlled by
A. Mass of atoms B. Atomic number
✓ C. Arrangement of electron in outer shell D. May be all
Q.371 An aqueous solu on of sodium carbonate is alkaline because sodium carbonate is a salt of
A. Weak acid and weak base B. Strong acid and weak base
✓ C. Weak acid and strong base D. Strong acid and strong base.
Q.372 For exothermic reversible reac on the ac va on energy for forward reac on is
✓ A. Less B. Greater
C. Equal D. May less or greater
Q.373 The experimental rela onship between a reac on rate and the concentra on of reactants is known as
A. order B. molecularity
C. rate constant ✓ D. rate law
Q.374 A catalyst accelerates the reac on by:
A. Increasing ac va on energy B. Lowering enthalpy change
✓ C. Lowering ac va on energy D. Lowering kine c energy
Q.375 The specific rate constant of a first order reac on depends on the
A. Concentra on of the reactant B. Concentra on of the product
C. Time ✓ D. Temperature
Q.376 The percentage of lead in lead pencil is
✓ A. Zero B. 20
C. 80 D. 70
Q.377 Natron has chemical formula:
A. H2Mg3. 7H2O B. KCI, MgCI2, 6H2O
✓ C. Na2CO3 . H2O D. KCI
Q.378 Which statement is incorrect about phosphorous
A. Phosphorus means light bearing B. It is essen al cons tuent of bones
C. It occurs in seeds yolk of egg ✓ D. Exists in the pentatomic form
Q.379 Which is the chemical formula of mica?
A. NaAISiO43H2O B. NaKSiO410H2O
_______________________________________________________________________________________
C. K2HAL(SiO4)3 ✓ D. KH2SAl3(SiO4)3
Q.380 Consider gas in measure in bars then the units of rate of reac on is
A. Mole dm-3sec B. Mole dm-3sec-1
C. Bars sec ✓ D. Bars sec-1
Q.381 The oxidizing power of halogens depends upon various factors. Which
is not the correct reasons?
A. energy dissocia on B. electron affinity
C. hydra on energy of ion ✓ D. higher atomic number
Q.382 The highest value of heat of hydra on among the following elements is of:
A. Ca B. Li
✓ C. Be D. Cs
Q.383 Which of the following types of forces lind together the carbon atoms in atoms in diamond?
A. ionic ✓ B. covalent
C. dipolar D. van der waal's
Q.384 The rate law of an equa on is wri en as -dx/dt = K[A][B]?
A. Reac on is independent in the concentra on B. Product is decreasing with passage of me
of A and B:
✓ C. Reactant is decreasing with passage of me
D. Reactant is increasing with passage of me
Q.385 Nitrogen is frequently used as an inert atmosphere because it is an unreac ve gas. Which is the best explana on of
this uneac vity?
A. its molecules contains a triple bond ✓ B. the bond energy of the molecule is high -1)
(994 kJ mole
C. The three p orbitals of nitrogen are half-filled D. the bond in its molecules is very shot
(0.110nm)
Q.386 The metal used in the termite process because of its ac vity is:
✓ A. AI B. Fe
C. Zn D. Cu
Q.387 Gypsum is added to clinker during cement manufacture to
A. Decrease the a rate of se ng of cement B. Facilitate the forma on of colloidal gel
C. BInd the par cles of calcium silicate ✓ D. All of the above
Q.388 In the rate equa on when the concentra on of reactant are unity, then rate is equal to
A. instantaneous rate B. average rate
C. ac ve mass of products ✓ D. specific rate constant
Q.389 Caus cisa on process is used for the prepara on of
✓ A. Caus c soda B. Caus c potash
C. Baryata solu on D. Slaked lime
Q.390 Which of the following compounds has the lowest anion to ca on size ra o?
A. LiF B. NaF
C. Csl ✓ D. CsF
Q.391 Elements of which one of the following groups will form anions most readily?
A. oxygen group ✓ B. halogens
C. nitrogen group D. alkali metals
Q.392 Phosphorous can form PCI5 but nitrogen cannot form NCI5 This is because
A. N2is diatomic B. It has no allotropic form
C. If can form mul ple bond ✓ D. Does not have 3rd-orbital
Q.393 Alkali and alkaline earth metals show increasing trend down the group in:
A. atomic volume B. electroposi vity
C. atomic radii ✓ D. all above
Q.394 Ozone is an allotropic form of
A. sulphur B. phosphours
✓ C. oxygen D. carbon
_______________________________________________________________________________________
Q.395 Which of the following is not gas?
A. Xe B. Rn
C. Kr ✓ D. K
Q.396 Pyrex glass is a mixture of
✓ A. Sodium borosilicate and aluminium B. Sodium silicate and calcium silicate
borosilicate
C. Sodium silicate and lead silicate
D. Sodium silicate and aluminium borosilicate
Q.397 All reac ons occur in:
A. A single step B. A series of steps
C. Two steps ✓ D. Both (a) and (b)
Q.398 The element having maximum density is :
A. C B. Ge
✓ C. Pb D. Si
Q.399 In the electroly c extrac on of aluminium fused cryolite is added
✓ A. To make a conduc ng solu on of bauxite B. To act as reducing agent
C. To increase AI produc on D. To protect the anodes
Q.400 Half life period of a first order reac on is independent of:
A. Presence of catalyst B. Condi ons of temperature
✓ C. Ini al concentra on of the compound D. All of above

Q.401 The element having maximum electroneg vity among the following is:
A. Si ✓ B. C
C. Ge D. Pb
Q.402 Which of the following statement is not correct?
A. argon is used in electric bulbs ✓ B.
Krypton is obtained during radioac ve
disintegra on
C. half life of radon in only 3.8 days D. helium is used in producing very low
temperatures
Q.403 Which oxide of nitrogen is obtained on hea ng ammonium nitrate at 250°C?
A. Nitric oxide ✓ B. Nitrous oxide
C. Nitrogen oxide D. Dinitrogen tetraoxide
Q.404 P2O5 is heated with water to give
A. Hypophosphorous acid B. Phosphorous acid
C. Hypophosphoric acid ✓ D. Orthophosphoric acid
Q.405 Which of the following has excep onally high boiling point:
A. KOH B. NaCl
✓ C. MgO D. NaOH
Q.406 The common basic unit of mica quartz and asbestos is:
A. SiO2-4 B. SiO2
✓ C. SiO4-4 D. SiO32-
Q.407 When NaCI is dissolved in water the sodium ion is
A. Oxidised B. Hydrolysed
C. Reduced ✓ D. Hydrated
Q.408 In curing cement plasters, water is sprinkled from me.This helps in
A. Conver ng sand into silici acid ✓ B. Developing interlocking needle like crystals
of hydrated silicates
C. keeping it cool D. Hydra ng sand and gravel mixed with cement.
Q.409 Which is almost insoluble compound:
✓ A. BaSO4 B. MgSO4
C. BeSO4 D. CaSO4
Q.410 When rate of reac on is restarted by adding a substance, it is said to be:
A. Posi ve catalyst B. Auto catalyst
C. Catalyst ✓ D. Nega ve catalyst
_______________________________________________________________________________________
Q.411 Which gas is obtained when urea reacts with nitrous acid
✓ A. N2 B. NO
C. N 2O D. NO2
Q.412 Mark the electroly c cell which is used for the produc on of metallic sodium:
A. Solvay's call B. Haber's cell
✓ C. Down's cell D. none of al
Q.413 In what order does the reducing power of the hydrogen halides increase?
✓ A. HCI,HBr, HI B. HCI,HI, HBr
C. HBr, HI, HCI D. HI, HBr, HCI
Q.414 Which of the following will liberate hydrogen by its reac on with hydrochloric acid?
A. Copper B. Phosphorus
C. Mercury ✓ D. Magnesium
Q.415 Magnesium keeps on burning in
A. N2 B. CO2
C. N 2O ✓ D. N2as well as CO2
Q.416 Which of the following will affect the rate:
A. First step of reac on B. Last step of reac on
✓ C. Rate determining step D. Fastest step
Q.417 Which one is formula of borax?
A. Ca2B6O11.5H2O B. Na2B4O7.4H2O
✓ C. NaOH.B2O3 D. Na2B4O7.10H2O
Q.418 Oxygen molecule has two unpaired electrons. It is therefore
A. ferromagne c ✓ B. paramagne c
C. diamagen c D. magne c
Q.419 Which of the following statements is not true about potash alum?
A. Its empirical formula is KAI(SO4).12H2O ✓ B. Its aqueous sol.Is basic in nature
C. It is used in dyeing industry D. On hea ng it melts in its water of
crystalliza on
Q.420 A white precipitate if silver chloride immediately formed on addi on of:
✓ A. Silver nitrate solu on to sodium chloride B. Silver chloride solu on to sodium nitrate
solu on solu on
C. Silver nitrate solu on to potassium chloride D. Silver nitrate solu on to hydrogen chloride
solu on solu on
Q.421 Sodium metal cannot be stored under
A. Benzene B. Kerosene oil
✓ C. Alcohol D. Toluene
Q.422 Which is the complete list of all the product form the reac on of concentrated sulphuric acid with potassium bromide?
A. potassium hydrogensulphate and hydrogen B. potassium hydrogensulphate hydrogen
bromide bromide and bromine
C. potassium hydrogensulphate hydrogen ✓ D. potassium hydrogensulphate hydrogen
bromide bromine and water bromide bromine water and sulphur dioxide
Q.423 Which of the following theories has been used to explain the subject of chemical kine cs
A. collision theory of bimolecular reac on B. absolute reac on rates or the ac vated
complex theory
✓ C. both of them D. none of the above
Q.424 The element which occurs free in nature is
A. Sb ✓ B. N
C. P D. As
Q.425 Which of the following on hea ng at 125°C gives plaster of Paris?
A. Borax ✓ B. Gypsum
C. Alum D. Calomel
Q.426 Catalyst changes:
A. Enthalpy reactants B. Enthalpy of products
C. Enthalpy of reac on ✓ D. enthalpy of none.
_______________________________________________________________________________________
Q.427 In large excess method one of the reactants is taken:
A. In large amounts as composed to rest of ✓ B. In small amounts as composed to rest of
reactants reactants
C. All reactants are taken in large amounts D. A standard volume
Q.428 Keeping in view the comparison of alkali metals with alkaline earth metals the alkali metals have:
✓ A. lower ioniza on energy B. smaller ionic radii
C. greater hardness D. high mel ng point
Q.429 Calomanite is the ore of:
A. B B. Be
✓ C. AI D. Ba
Q.430 One mole of each of the following compounds is strongly heated and any gas produced is collected at room
temperature and pressure,
From which compound is 24 dm3 of gas likely to be collected?
[One mole of any gas occupies 24 dm3 at room temperature and pressure]
A. MgCI2 ✓ B. MgCO3
C. Mg(NO3)2 D. Mg(OH)2
Q.431 The decolouriza on of KMnO4by Mn+2 ions. This is an example of:
A. Poisoning catalysis B. Inhibitor
✓ C. Chemo-catalysis D. Auto-catalysis
Q.432 In a mul ple step reac on the rate determining step is always
A. the first step B. the last step
✓ C. the slow step D. the fast step
Q.433 The number of reac ng molecule whose concentra on change a er reac on is called
A. Rate of reac on B. Ac vated molecule
✓ C. Order of reac on D. May be all
Q.434 Half life period of a reac on is inversely propor on to the ini al concentra on of the reactant, then order of reac on
is
A. third order ✓ B. second order
C. first order D. zero order
Q.435 On hea ng quick lime with coke in an electric furnace,we get
A. Ca and CO2 B. CaCO3
C. CaO ✓ D. CaC2
Q.436 Which reagent when mixed and heated with ammonium sulphate , liberates ammonia?
A. aqueous bromine B. dilute hydrochloric acid
✓ C. limewater D. acidified potassium dichromate(VI)
Q.437 Which of the following oxides of nitrogen exists as a pale yellow liquid
A. NO2 ✓ B. N2O 4
C. N 2O D. N 2O 3
Q.438 A metal is brunt in air and the ash on moistening smells of ammonia.The metal is
A. Na B. Fe
✓ C. Mg D. AI
Q.439 In the reac on of oxalic acid with KMnO4and H2SO4is slow at the begining but a er some mes the reac on becomes
faster due to
✓ A. forma on of 4
which acts as 'Auto B. forma on of CO2which acts as 'Auto catalyst
MnSO catalyst
C. forma on of K2SO4which acts as 'Auto catalyst
D. evolu on of O2gas which acts as 'Auto catalyst
Q.440 Dilatometer method is useful for the reac on that involve:
✓ A. Small volume changes in solu ons B. Change in refrac ve indicates
C. Where reactants absorb U.V, visible or D. Ionic species
infrared radia on
Q.441 Bleaching ac on of bleaching powder is due to the libera on of
A. O2 B. OCI-
_______________________________________________________________________________________
✓ C. CI2 D. CI-
Q.442 Aluminium reacts with caus c soda to form
A. Aluminium hydroxide B. Aluminium oxide
✓ C. Sodium meta-aluminate D. Sodium tetra aluminate
Q.443 When aluminium is heated in atmosphere of nitrogen forms a nitride of formula
✓ A. AIN B. AIN3
C. AI3N D. AI2N3
Q.444 Generally by increasing temperature, rate of chemical reac on increases. it is due to:
✓ A. Greater number of molecules having B. Great number of collisios
ac va on energy
C. Great velocity of molecules
D. Lesser number of molecules having ac va on
energy
Q.445 Inter pair effect plays an important role in case of
A. F B. AI
C. Si ✓ D. TI
Q.446 The ;emission from a power sta on contain about 14 tonnes of SO2 per hour form the oxida on of FeS2 contained in
the coal.
What is the most prac cal way of preven ng the SO2 from being released into the atmosphere?
A. cool the gases and will liquefy and can B. dissolve the ionic FeS2in hexane
2
the SO removed
✓ C. pass the emissions through a bed of calcium
oxide
D. pass the gases through concentrated
2
sulphuric acid to dissolve the SO
Q.447 The electronic configura on of TI(Z=81)
A. [Xe]4d105s26p1 B. [Xe]4f145d106s2p1
✓ C. [kr]4d105s2p1 D. [kr]4f145d106s2p1
Q.448 Cassiterite is an ore of
A. Mn B. Ni
C. Sb ✓ D. Sn
Q.449 Orthophosphoric acid is
A. Monobasic B. Dibasic
✓ C. Tribasic D. Tetrabasic
Q.450 Mark the property among the following which is more applicable to alkaline earth metals as compared with alkali
metals:
A. lower ioniza on poten als B. large ionic radii
C. lower electronega vi es ✓ D. less basic hydroxide
Q.451 Which of the following statements is incorrect?
A. Sodium is the not most abundant metal in B. Sodium is the most abundant metallic
earth's crust element in sea water.
C. Mel ng and boiling points of alkali metals ✓ D. Ionic character of alkali metal halides
decrease down the group decreases down the group
Q.452 Point out the common property in diamond and graphite:
A. density ✓ B. rela ve atomic weight
C. electrical conduc vity D. crystal structure
Q.453 Sulphuric acid reacts with PCI5 to give
A. Thionyl chloride B. Sulphur monocloride
✓ C. Sulphuryl chloride D. Sulphur tetrachloride
Q.454 Aluminium is:
A. amphoteric ✓ B. a reducing agent
C. highly electronega ve elements D. an oxidizing agent
Q.455 Decreasing order of electron affinity of halogens is:
A. Br > CI > F > I B. I > CI > F > Br
✓ C. CI > F > Br > I D. I > F > CI > Br
_______________________________________________________________________________________
Q.456 Calcium cyanamide on treatment with steam under pressure gives NH3 and
✓ A. Calcium carbonate B. Calcium hydroxide
C. Calcium oxide D. Calcium bicarbonate
Q.457 Choose the set of elements having good capacity of losing electrons:
✓ A. Li, Na, K B. O, S, Se
C. N, P, AS D. F2, CI2, Br2
Q.458 The reac on kine cs concerned with the ______ chemical reac on
A. Velocity of B. Factor effec ng
C. Direc on of reac on ✓ D. Both a and b
Q.459 Which is called pseudo halide?
A. ICI B. IF5
✓ C. CN ̅ D. ?I3 ̅
Q.460 If the rate of decay of radioac ve isotope decreases from 200 cpm a er 24 hours, what is its half life:
✓ A. 8 hours B. 6 hours
C. 4 hours D. 3 hours
Q.461 Which statement about Arrhenius equa on is incorrect
A. factor 'A' called Arrhenius constant, depends B. rate of reac on increase by increasing
upon collision frequency of reactants temperature
C. rate constant k is increased ✓ D. ac va on energy Ea is decreased by rise in
temperature
Q.462 If ini al concentra on of the reactants and half life period of the reac on is known, then we can determine
A. average rate of reac on ✓ B. order of reac on
C. rate constant k D. instantaneous rate
Q.463 An example of halide ore is:
A. bauxite ✓ B. cryolite
C. galena D. ginnabar
Q.464 Aluminium (III) chloride forms a dimer because
✓ A. Higher co-ordina on cab be achieved by AI B. AI has high ioniza on energy
C. AI belongs to third group D. It can not form a trimer
Q.465 The reac on rate is expressed in the units of
✓ A. mol dm-3S- B. mol dm-3
C. mol dm-3N- D. dm-3S-
Q.466 Which is the gas among the following that react with H2 in darkness?
✓ A. F2 B. CI2
C. Br2 D. I2
Q.467 The sum of exponents of the conc. terms in the rate equa on is called
A. Rate of reac on ✓ B. Order of reac on
C. Specific rate constant D. Average rate
Q.468 In certain respects lithium differs from other alkali metals the main reason for this is
✓ A. Small size of lithium atom and Li+ion B. Extremely high electroposi vity of Li.
C. Greater hardness of Li. D. Hydra on of Li+ion
Q.469 The solu on of carbonates decrease down the magnesium group due to a decrease in
A. Entropy of solu on forma on B. La ce energies of solids
✓ C. Hydra on energies of ca ons D. Inter ionic a rac on
Q.470 The oxides of born and silicon are:
A. amphoteric B. basic
✓ C. acidic solu on D. natural
Q.471 Oxida on reduc on reac on involve the transforma on of electrons and are ______ than ionic reac on
A. Faster B. Equal
✓ C. Slower D. May faster
Q.472 Anhydride of sulphuric acid is
_______________________________________________________________________________________
A. SO2 ✓ B. SO3
C. H 2S2O 3 D. H2SO3
Q.473 Which one of the following allotropic forms of carbon is isomorphous with crystalline silicon?
A. Graphite B. Coal
C. Coke ✓ D. Diamond
Q.474 Which of the following is a correct set for SiO2?
A. Linear acidic B. Linear basic
✓ C. Tetrahedral acidic D. Angular disc
Q.475 Microcosmic salt is
✓ A. Na(NH4)HPO4, 4H2O B. Na(NH4). H2O
C. HPO4, 4H2O D. K(NH4)HPO3. 2H2O
Q.476 Mica and bauxite are ores of:
✓ A. Al B. Ba
C. Zn D. Ca
Q.477 Sulphur dioxide is an important food preserva ve.
A. it is a gas B. it reacts with oxygen to form sulphur trioxide
C. it reacts with water to form an acidic solu on ✓ D. it is a reducing agent
Q.478 When copper is allowed to react with HNO3, the reac on is slow in the begining, finaly becomes very fast. It is due to
the forma on of an auto catalyst which is
A. Cu(NO3)2 B. CuO
C. O2 ✓ D. HNO2
Q.479 The element among the following having electron affinity is:
A. C B. Pb
✓ C. Sn D. Ge
Q.480 Rate of a chemical reac on depends upon:
A. The number of total collision per second B. Number of molecules taking part in a
chemical reac on
✓ C. Number of frui ul collision per second D. Number of a fruitless collision per second
Q.481 Which oxide does not act as a reducing agent
A. NO B. NO2
✓ C. N2O 3 D. N 2O
Q.482 Choose the element which dies not belong to group ;;A of the periodic table:
✓ A. Sb B. Be
C. Tl D. In
Q.483 chile saltpeter has the chemical formula:
✓ A. NaNO3 B. KNO3
C. Na2B4O7 D. Na2CO3 . H2O
Q.484 The first ioniza on energy of AI is smaller than that Mg, the reason is that?
A. atomic size of aluminium is smaller than B. atomic size of aluminium is larger than
magnesium magnesium
✓ C. aluminium has one electron in p-orbital D. none of these
Q.485 Electroposi ve character increase down the group due to:
A. decrease in ioniza on poten al B. increase in atomic size of the elements
C. decrease in electronega vety of the elements ✓ D. all the above
Q.486 Which of the following substance is used for drying gases?
A. Calcium carbonate B. Sodium carbonate
C. Sodium bicarbonate ✓ D. Calcium oxide
Q.487 Boron does not form ionic compounds with sulphate nitrate and others anions because
✓ A. It does not form stable ca on B. It cannot react with transi on metals
C. It is a non-metal D. All of the above
Q.488 Ozone is not
_______________________________________________________________________________________
A. An allotrope B. A powerful oxidizing agent
✓ C. Paramagne c D. A bent molecule
Q.489 Which compound will show the highest la ce energy?
A. RbF B. CsF
✓ C. NaF D. KF
Q.490 For two ionic solids CaO and KI, iden fy the wrong statement among the following?
A. La ce energy of CaO is much higher than that ✓ B. KI is soluble in benzene
of KI.
C. CaO has high m.p
D. KI has high m.p
Q.491 Select the weakest acid among the following:
A. HCI B. HBr
✓ C. HF D. HI
Q.492 Which metal is commonly used to remove air bubbles from molten metals.
✓ A. Aluminum B. Copper
C. Sodium D. Calcium
Q.493 Which one is the biggest ion?
✓ A. Mg2+ B. Ba2+
C. Al2+ D. Na+
Q.494 point out the wrong statement:
A. baCle like AICI 3 is covalent B. carbides of both be and Al react with eater
evolving methane
✓ C. Be like AI does not dissolve in alkalies D. oxides of both Be and AI are amphoteric
Q.495 Mark the incorrect statement about 'Li':
A. 'Li' has great tendency to from hydrates B. 'Li' is not effected by air
✓ C. when burn in oxygen, 'Li' forms super oxide
2
D. 'Li' combine with nitrogen directly to form
Lio Lithium nitride
Q.496 Which one of the following is the strongest oxidizing agent?
✓ A. HCIO B. HCIO2
C. HCIO3 D. HCIO4
Q.497 In method of large excess one reactant should be ______ at one me and other reactants change at the same me
A. Increase B. Decrease
✓ C. Constant D. All
Q.498 When Al is heated with aqueous solu on of NaOH the produce formed is:
A. NaAIo2and H2O B. AI(OH)3
C. AI2O3H2O ✓ D. NaAIO2and H2
Q.499 Which noble gas is used in labours?
A. argon B. helium
C. neon ✓ D. krypton
Q.500 Which of the following is the most soluble in water
A. CaSO4 ✓ B. MgSO4
C. SrSO4 D. BaSO4
Q.501 Which statement about catalyst is incorrect:
A. It is regenerated at the end of chemical B. It lowers the ac va on energy.
reac on.
C. It increases the reac on rate.
✓ D. It decreases the enthalpy of a reac on.
Q.502 Phosphorus uses the following orbitals for bonging
A. 3s B. 3p
C. 3d ✓ D. all of theses
Q.503 Among the following oxides, the one which is most basic is
A. Zinc oxide ✓ B. Magnesium oxide
C. Aluminium oxide D. Nitrogen pent oxide
_______________________________________________________________________________________
Q.504 The chemical formula of bauxite is:
✓ A. AI2O3.2H2O B. AI2O3
C. AI2O3.SiF4 D. None of these
Q.505 B, AI, Ga. in and ll belong to IVA group of the period table show a increasing with increasing rela ve atomic mass:
A. the stability of +2 oxida on state B. ionic character of the compound
✓ C. the first ioniza on energy D. the basic character of the oxides
Q.506 When there are changes in refrac ve indices of the substance taking part in the chemical reac on then the method is
called as ______ method
A. Op cal rota on B. Reflec on
✓ C. Refractrometric D. All
Q.507 The electronega vity of the following elements in crease in the order
A. O,Si,N,C ✓ B. Si,P,C,N
C. C,N,Si,P D. S,Si,C,P
Q.508 Most electronega ve element in group V A is
✓ A. N B. P
C. AS D. Sb
Q.509 Alkali earth metals have tow electrons outermost:
A. p-orbital B. d-orbital
C. f-orbital ✓ D. s-orbital
Q.510 Make the correct statement about the noble gases:
✓ A. they are all colourless gases B. they readily burn in oxygen
C. they are good conductors of electricity D. they are good conductors of heat
Q.511 Potassium is kept in
A. Water B. Ammonia
C. Alcohol ✓ D. Kerosene.
Q.512 Which of the following elements is the most reac ve
A. Li B. Na
C. K ✓ D. Rb
Q.513 Which of the following is a neutral oxide
✓ A. N2O B. N 2O 3
C. NO2 D. N 2O 5
Q.514 The chemical formula of litharge is:
A. Pb2O3 B. PbO2
C. Pb3O4 ✓ D. PbO
Q.515 Down's cell is used to prepare:
A. sodium carbonate B. sodium bicarbonate
✓ C. sodium metal D. sodium hydroxide
Q.516 For which one of the following minerals the composi on given is incorrect
A. Soda ash-Na2CO3 B. Carnallite-KCI.MgCI2.6H2O
✓ C. Borax-Na2B4O7.7H2O D. Glauber s salt-Na2SO4. 10H2O
Q.517 Lead suboxide is obtained on hea ng from:
A. Pb(NO3)2 B. PbCrO4
✓ C. PbC2O4 D. Pb3O4
Q.518 If a reactant or product of a reac on absorbs radia on, then physical method for determining the rate of reac on is
✓ A. spectrometry B. refractometry
C. conduc vity measurement D. op cal method
Q.519 Drying agent which is used to remove both water and CO2 from certain gases
✓ A. Soda lime B. CaCO3
C. CaCI2 D. Ca(NO3)2
Q.520 The most vola le among the following is:
_______________________________________________________________________________________
A. HF ✓ B. HCI
C. HBr D. HI
Q.521 The metal extracted by electrolysis of its fused salt is
A. Iron ✓ B. Sodium
C. Copper D. Lead
Q.522 Which is the main use of aluminum
A. Excellent conductor of heat and electricity B. Excellent reflector of radiant energy
C. Used to make petrol & milk storage tank ✓ D. All of the above
Q.523 A substance which increases the rate of a reac on without being consumed during the reac on is called
A. an autocatalyst ✓ B. a catalyst
C. a nega ve catalyst D. all of these
Q.524 Which noble gas is used in infilament bulls to stop the filament burning out too quickly:
A. helium B. neon
✓ C. argon D. krypton
Q.525 Which reason best account for the use of helium in modern airships?
A. lighter than air and cheap to produce B. expensive but easy to store in cylinder
C. expense but a very unreac ve gas ✓ D. less dense than air and not flammable
Q.526 A radioac ve element which can decay to give two noble gases,is
A. U238 B. Ac239
C. Th 232 ✓ D. Ra226
Q.527 The halogen which has only one oxida on state is:
✓ A. F B. CI
C. Br D. I
Q.528 White lead is
A. Basic lead acetate B. Acidic lead carbonate
✓ C. Basic lead carbonate D. Basic lead hydroxide
Q.529 Solu on of sodium metal in liquid ammonia in strongly reducing due to the presence in the solu on of the following
A. Sodium hydride B. Sodium amide
C. Sodium atoms ✓ D. Solvated electrons
Q.530 The change in concentra on of reactant or product per unit me is called:
A. Rate of constant ✓ B. Rate of reac on
C. Rate equa on D. Rate law
Q.531 Which shows maximum catena on property?
✓ A. S B. Se
C. Te D. O
Q.532 Mark the halogen having greast bond energy.
✓ A. CI2 B. BI2
C. F2 D. I2
Q.533 The rate of reac on determined at a given me is called
A. average rate ✓ B. instantaneous rate
C. specific rate D. overall rate
Q.534 In which of the following elements +1 oxida on state is more stable than +3
A. B B. AI
C. Ga ✓ D. Ti
Q.535 The name of CaSO4, 1/2 H2O is
A. Gypsum B. Epsom salt
✓ C. Plaster of Paris D. Dolomite
Q.536 Ripening of fruits can be carried out in presence of
A. Na2SO4 B. Na2SO4
C. CaCI2 ✓ D. CaO
_______________________________________________________________________________________
Q.537 The most reac ve mental among the following is:
A. Rb ✓ B. Li
C. Na D. K
Q.538 Which of the following is most dense?
A. Fe B. Cu
C. B ✓ D. Pb
Q.539 In the expression rate = k[A]a[B]bk is
A. the order of reac on B. the speed of reac on
✓ C. the specific rate constant D. the overall order of reac on
Q.540 The metal that dissolves in liquid ammonia giving a dark blue coloured solu on is
✓ A. Sodium B. Lead
C. Zinc D. Silver
Q.541 In alkaline earth metals, as radium is at the bo om, it should:
A. possess minimum density B. have highest reduc on poten al
C. be least electroposi ve ✓ D. be most easily ionizable
Q.542 Dolomite has the composi on
A. KCL.MgCL2.6H2O B. Na3AIF6
✓ C. CaCO3.MgCO3 D. CaCI2.MgCI2.6H2O
Q.543 Ac va on energy is the difference of energy between the energy of the reactant by
A. the product ✓ B. the ac vated complex
C. ΔH of exothermic reaction D. ΔH of endothermic reaction
Q.544 The noble gas has was discovered by:
A. Rutherford B. Dorn
✓ C. Frankland and lockyer D. Chadwick
Q.545 A catalyst:
A. Increases the rate of forward reac on. ✓ B.
Increases the rate of both forward and
reverse reac ons.
C. changes equilibrium posi on D. Increases the rate of forward reac on and
decreases the rate of reverse reac on.
Q.546 When sulphur is boiled with Na2SO3 solu on the compound formed is
A. Sodium sulphides B. Sodium sulphates
C. Sodium persulphate ✓ D. Sodium thiosulphate
Q.547 The oxides of beryllium are:
A. acidic B. basic
✓ C. amphoteric D. none of these
Q.548 V2O5 catalyst is used in
✓ A. Contact process B. Ostwald s process
C. Lead chamber process D. Birkland Eyde process
Q.549 Sodium silicate is a useful compound of silicon which state is false?
A. it is used as furniture polish ✓ B. it is used for making which cement
C. it is used in tex le as fire proof D. it is used as a filter for soap
Q.550 AI is more reac ve than Fe but AI is less easily corroded than Fe because
A. It is a noble metal ✓ B. Oxygen forms a protec ve reac on easily
with water
C. Iron undergoes reac on easily with water D. Fe form mono and divalent ions.
Q.551 Choose the number of group of periodic, table to which alkali metals belong to:
A. IB ✓ B. IA
C. VII D. IIA
Q.552 Which one is the mineral of sodium?
A. carnalite B. sylvite
✓ C. trona D. rock salt (Halite)
Q.553 Which one of the following sulphates is not soluble in water?
_______________________________________________________________________________________
A. sodium sulphate B. potassium sulphate
C. zinc sulphate ✓ D. barium sulphate
Q.554 Which of the following salts is not soluble in water
A. LiF ✓ B. KBr
C. CaCI2 D. BaCI2
Q.555 Which is the formula of chrome yellow?
A. K2Cr4O4 B. K2Cr2O7
C. PbMoO4 ✓ D. PbCrO4
Q.556 Elements of group IA give colour in Bunsen flame due to:
A. single electron in outer most orbit B. low mel ng point
C. so ness ✓ D. low ioniza on
Q.557 With increase in temperature of 10 K of the reac ng gases the rate of reac on is doubled because
A. increase in number of collisions ✓ B. number of molecules having energy more
than Ea is double
C. increased in order of reac on D. increase in surface area
Q.558 in mortar func on of sand is:
A. to decrease the plas city of mass B. to prevent excessive shrinkage
✓ C. to detect the hardness D. to make the mass compact
Q.559 Value of rate constant k is specific for a reac on, and varies from reac on to reac on.value of k of a reac on cahnges
with
A. me ✓ B. temperature
C. concentra on of reactants D. order of reac on
Q.560 Which statement is true about the noble gases?
✓ A. they have li le tendency to share or gain B. they are very reac ve
electron to from a chemical bond C. argon is used in lamp to make the metal
filament a be er conductor.
D. argon is used in welding it keep the
surrounding metal cool.
Q.561 Aluminium is most abundant in earth crust, yet is obtained from bauxite because
✓ A. Bauxite is available in large quan ty B. Bauxite contains maximum of AI
C. Bauxite is less impure.
Q.562 Mark the compound which does bot exist.
A. PF5 B. AsF5
C. SbCI5 ✓ D. NCI5
Q.563 Which of the following alkaline earth metals is the strongest reducing agent?
A. Ca B. Sr
✓ C. Ba D. Mg
Q.564 Bleaching powder is a compound having a formula
A. CaCO3 B. CaCLO
✓ C. CaOCI2 D. CaOCI3
Q.565 Which one among the following is more stable?
Q.566 Which does not belong to alkaline earth metal
A. Be B. Ra
✓ C. Ba D. Rn
Q.567 Which of the following has highest dipole moment?
✓ A. NH3 B. PH3
C. AsH3 D. SbH3
Q.568 Which of the following is in the solid state
✓ A. N2O 5 B. N 2O
C. N 2O 4 D. NO2
Q.569 Which of the following metal is present in chlorophyll?
A. Chromium B. Cobalt
_______________________________________________________________________________________
✓ C. Magnesium D. Iron
Q.570 Rus ng of iron is the example of _______ reac on
A. Fast B. Moderate
✓ C. Slow D. May be all
Q.571 Electrolysis of fused anhydrous KCI,MgCI2.6H2O gives
A. Potassium only B. Magnesium only
✓ C. Magnesium and chlorine D. Potassium and magnesium
Q.572 The reason of bleaching ac on of chlorine is:
✓ A. oxida on B. reduc on
C. hydrogena on D. chlorina on
Q.573 In homogenous catalysis, the catalyst and reactants are in the same phase and reac ng system is
A. Heterogeneous throughout ✓ B. Homogeneous throughout
C. Heterogeneous at intermediate state D. Homogenous at intermediate and then
become heterogeneous
Q.574 The formula of calcium cyanamide is
A. Ca(CN)2 B. CaC2N
✓ C. CaNCN D. CaCHNH2
Q.575 Rate of a chemical reac on is defined as
✓ A. the change in concentra on of a reactant or B. amount of substance formed in the first
a product divided by the me taken for the second
change C. amount of substances consumed in the first
second
D. amount of substance consumed in mole per 3
dm
Q.576 Which of the following is true for magnesium?
A. It is more electroposi ve than sodium B. It is manufactured by electrolysis of aqueous
magnesium chloride.
✓ C. It is strong reducing agent D. It resembles, in chemical proper es, with its
diagonally placed element Boron in III group
of the Periodic Table.
Q.577 Dilatometric method is used for rate determina on when
A. Reac ons involving ions B. Reac ons involving change of op cal ac vity
✓ C. Reac ons involving small volume change D. None of above
Q.578 The experimental rela onship between a reac on rate and the concentra on of the reactants is called
A. order law ✓ B. rate law
C. molecularly D. order law
Q.579 Which one of the following elements belongs to belongs to halogen family?
A. radium B. polonium
C. francium ✓ D. asta ne
Q.580 The hardness of diamond is due to the property that:
A. it is a gains molecule B. it has greater value refrac ve index
✓ C. all the electrons of valence shell of each D. it is allotropic and crystalline form of carbon
carbon take part in bonding
Q.581 The bicarbonate which does not exist as solid is:
A. Ca(HCO3)2 ✓ B. LiHCO3
C. KHCO3 D. NaHCO3
Q.582 Which oxide is weakly basic and at the same me a powerful oxidizing agent
A. SiO2 ✓ B. PbO2
C. CO2 D. SnO2
Q.583 Which of the following is formed by the ac on of water on sodium peroxide?
A. H2 B. N2
✓ C. O2 D. CO2
Q.584 All element that has a high ioniza on energy and tends to be chemically inac ve wold mist likely to be:
A. an alkali metal B. a transi on element
✓ C. a noble gas D. a halogen
_______________________________________________________________________________________
Q.585 Choose the compound which decomposes on hea ng similar to LiNO3

A. Sr (NO3)2 ✓ B. Mg (No3)2
C. Be(No3)2 D. all above
Q.586 When the curve (which is obtain when graph plot between concentra ons and me) become horizontal to me axis
the rate of reac on become
A. Increase B. Constant
✓ C. Zero D. May it increase or decrease
Q.587 Aluminium oxide is:
A. acidic oxide B. basic oxide
✓ C. amphoteric oxide D. none of these
Q.588 Which one of the following proper es of alkali metals increases in magnitude as the atomic number rises?
✓ A. Ionic radius B. Mel ng point
C. Electro nega vity D. First ioniza on energy
Q.589 Which of the following fluorides does not exist?
✓ A. NF5 B. PF5
C. AsF5 D. SbF5
Q.590 Which of the following is pale yellow to reddish yellow in color
A. Pb2O B. PbO2
✓ C. PbO D. 2PbCO3Pb(OH)2
Q.591 _____ is necessary for development of leaves and it tends to accumulate in leaves and bark
A. NO2 ✓ B. Calcium
C. Gypsum D. Nitrogen
Q.592 Elements of group VIA show a covalency of +2,+4, and +1 except
A. S B. secondary cells
C. PO ✓ D. O
Q.593 Alkaline earth metals have higher densi es, mel ng and boiling points than alkali metals because of :
A. high nuclear charge ✓ B. high ioniza on poten al
C. high nuclear change and ioniza on D. none of all
Q.594 Choose the incorrect statement about boric acid:
A. it has a planar structure ✓ B. it acts as tribasic acid
C. it behaves as monobasic acid D. it is soluble in H2O
Q.595 Amongst the metal Be,Mg,Ca and Sr of group 2 of the periodic table, the least ionic chloride would be formed by
A. Mg ✓ B. Be
C. Ca D. Sr
Q.596 Which statement about oxygen and sulphur is not true
A. both exhibit allotropoic forms B. both combine with metals to form O2-and S2-
C. both are usually divalent ✓ D. both are paramagne c
Q.597 Keeping in view proper es of alkalies of alkali metals mark the property which increases as atomic number increases:
✓ A. ionic radius B. mel ng point
C. first loniza on Energy D. electronega vity
Q.598 In which of the following the hydra on energy is higher than la ce energy
✓ A. MgSO4 B. SrSO4
C. RaSO4 D. BaSO4
Q.599 Aluminimum oxide (AI2O3)
A. acidic oxide B. basic oxide
✓ C. amphoteric oxide D. nine of these
Q.600 Spectrometry method is applicable if a reactant or a product absorbs ______ radia on
A. Ultraviolet B. Visible
C. Infrared ✓ D. All
Q.601 CI2O7 react with H2O to form:
_______________________________________________________________________________________
✓ A. chlorine and oxygen B. hypochlorous
C. chloric acid D. perchloric acid
Q.602 Main process for the manufacture of Na3CO3 is
A. Castner process ✓ B. Solvay process
C. Down process D. Nelson process
Q.603 Choose the chief ore of aluminium
A. kaolin B. cryolit
✓ C. beuxite D. feldspar
Q.604 Heavy water is obtained by
✓ A. Prolonged electrolysis of water B. Dissolving heavy salt in water
C. Simple dis lla on of water D. Removing impuri es of calcium and
magnesium form water.
Q.605 Choose the incorrect statement about fluorine:
✓ A. fluorine can not be prepared from B. the electron does affinity of chlorine is great
electrolysis of metal fluorides than fluorine
C. fluorine does not form oxyacids D. the bond energy of fluorine is less than
chlorine
Q.606 Red P can be obtained form white P by
✓ A. Hea ng if with a catalyst in an inert B. Dis lling it in an inert atmosphere
atmosphere
C. Dissolving it in CS2and crystallizing
D. Mel ng it ad pouring the liquid into water.
Q.607 The type of hybridisa on of boron in diborane is
A. Sp-hybridisa on B. Sp2-hybridisa on
✓ C. Sp3hybridisa on D. Sp3d2-hybridisa on
Q.608 Which of the following proper es is not true for an alkali metal?
✓ A. Low atomic volume B. Low ioniza on energy
C. Low density D. Low electro nega vity
Q.609 Which of the following has no n in its composi on?
A. Solder B. Bronze
✓ C. Brass D. Tin stone
Q.610 The reac on of Al with O2 to form Al2O3 is:
A. an endothermic reac on ✓ B. an exothermic reac on
C. reversible reac on D. none of the above
Q.611 Non-metal combine with oxygen to form usually
A. Basic oxide B. Neutral oxide
✓ C. Acidic oxide D. Amphoteric oxide
Q.612 Solid carbon dioxide is used as
A. Poison B. Refrigerant
✓ C. Fire ex nguisher D. Ar ficial respirant
Q.613 Which gas among the following burns with blue flame?
✓ A. CO B. CO2
C. NO D. N2
Q.614 Which of the following elements is not present abundantly in earth's
crust|?
A. silicon B. aluminium
✓ C. sodium D. oxygen
Q.615 The ac va on energy of a reac on is usually:
A. Zero for exothermic reac ons ✓ B. Different from forward to backward reac on
C. Unaffected by the presence of a catalyst D. Low for reac on that takes place slowly
Q.616 Presence of which of the following salt increases the rate of se ng of Plaster of Paris.
✓ A. NaCI B. KCI
C. BaSO4 D. CuSO4
_______________________________________________________________________________________
Q.617 Aluminothermy used for on the spot welding of large iron structure is based upon the fact that
✓ A. As compared to iron, aluminium has greater B. As compared to aluminium iron has greater
affinity for oxygen affinity for oxygen
C. Refrac on between aluminium and oxygen is D. Reac on between iron and oxygen is
endothermic endothermic.
Q.618 Which of the following group VA elements is gas at room temperature.
A. P ✓ B. B
C. As D. Sb
Q.619 Which one of the following substances is used in the laboratory for a fast drying of neutral gases?
A. Phosphorus pentoxides B. Ac ve charcol
✓ C. Anhydrous calcium chloride D. Na3PO4
Q.620 When AI is added to KHO solu on?
A. O2is evolved ✓ B. H2is liberated
C. H2O is produced D. no reac on take place
Q.621 The element which evolves two gases with conc H2SO4 is
A. Si ✓ B. C
C. S D. P
Q.622 When one mole of bleaching powder is completely decomposed, then the mass of chlorine gas that is liberated will be
A. 35.45 g ✓ B. 70.90 g
C. 17.72 g D. 88.60 g
Q.623 BeSO4 is soluble in water but BaSO4 is sparingly soluble due to the reason that:
is crystalline white is amorphous B. BaSO4is ionic withe BaSO4is colvalent
A. BaSO4 4
BaSO
✓ C. BaSO4 has smaller la ce energy and high
heat of hydra on as compared to BaSO4
D. none of all
Q.624 When catalyst is added in a reac on then ______ of a catalyzed reac on is different from that of an un-catalyzed
reac on
A. Concentra on B. Pressure
✓ C. Mechanism D. All of these
Q.625 choose the oxide which acidic in nature:
✓ A. SiO2 B. Al2O3
C. PbO2 D. SnO2
Q.626 Which is electron deficient?
A. PCI3 B. NH3
✓ C. BCI3 D. none of all
Q.627 Nitrogen shows anomalous behaviour due to
A. Small atomic radius B. High ioniza on energy
C. Absence of d orbital in the valence shell ✓ D. All of the above
Q.628 If the rate of reac on is independent of the concentra on of the reactant, the reac on is of
✓ A. zero order B. first order
C. second order D. third order
Q.629 For a chemical reac on to take place the par cles must have sufficient energy for the effec ve collisions, the energy is
called
A. average energy ✓ B. ac va on energy
C. poten al energy D. collision energy
Q.630 The solubility of hydroxides of alkaline earth metals increases from Mg (OH) to Ba (OH)2 ,this is due to:
A. increase in thermal stability ✓ B. increase in la ce energy
C. increases in ioniza on energy D. decrease in la ce energy
Q.631 The element having highest electronega vity among the following is:
A. Sr ✓ B. Mg
C. K D. Cs
Q.632 With increase of 10°C temperature the rate of reaction doubles. This increase in rate of reaction is due to
_______________________________________________________________________________________
A. decrease in ac va on energy of reac on B. decrease in the number of collisions between
reactants molecules
C. increase in ac va on energy of reactants ✓ D. increase in number of molecules with energy
more than Ea
Q.633 The acid which has a peroxy linkage is
A. Sulphurous acid B. Pyrosulphuric acid
C. Dithionic acid ✓ D. Caro's acid
Q.634 For effec ve collisions the molecules slow down before collision and their kine c energy decreases which results in
increase in their
A. ac va on energy B. average energy
✓ C. poten al energy D. collisions frequency
Q.635 Sulphuric acid does not act as
A. Dehydra ng agent B. Pickling
✓ C. Reducing agent D. Acid producing acid
Q.636 The formula of gypsum is:
A. CaSO4 B. CaSO4 . H2O
✓ C. CaSO4. 2H2O D. CaSO4. 5H2O
Q.637 The oxyacids of phosphorus in which phosphorus has the lowest oxida on state
✓ A. Hypophosphorous acid B. Orthophosphoric acid
C. Pyrophosphoric acid D. Metaphosphoric acid
Q.638 Electron affinity of sulphur is
✓ A. More than O and Se B. More than O but less than Se
C. Less than O but more than Se D. Equal to O and Se
Q.639 The metal with highest electrical resistance at room temperature is
A. Pb ✓ B. Te
C. Po D. Fe
Q.640 Sodium hexametaphosphate is known as
✓ A. Calgon B. Permu t
C. Nata te D. Nitrolim
Q.641 Hydrolysis pf ethyl-acetate (ester) has order of reac on:
A. 3 B. 2
✓ C. 1 D. 0
Q.642 In Solvay ammonia process, sodium bicarbonate is precipitated due to
A. Presence of NH3 B. Reac on with CO2
✓ C. Reac on with brine solu on D. Reac on with NaOH
Q.643 Iden fy the incorrect statement with respect to ozone.
A. Ozone is formed in the upper atmosphere by B. Ozone is more reac ve than dioxygen
a photochemical reac on involving dioxygen
C. Ozone is diamagne c whereas dioxygen is
paramagne c
✓ D. Ozone protects the earth's inhabitants by
absorbing gamma-radia ons.
Q.644 The element that does not form a monoxide is
A. Lead B. TIn
C. Germanium ✓ D. Silicon
Q.645 In the decomposi on of KClO3, ______ is used to increase the reac n
A. CuCl2 ✓ B. MnO2
C. Mn2O2 D. Cu-metal
Q.646 Which one of these is most reac ve?
A. Na ✓ B. K
C. Pb D. Mg
Q.647 One can obtain silica garden if:
A. SiF4in hydrolysed B. silicon salts are grown in a garden
✓ C. sodium silicate solu on is treated with a D. crystals of coloured ca ons are added to a
_______________________________________________________________________________________
base strong solu on of sodium silicate
Q.648 What causes nitrogen to be chemically inert?
A. Mul ple bond forma on in the molecule B. Absence of bond polarity
C. Short intermolecular distance ✓ D. High bond energy
Q.649 Carbon and silicon have?
A. same physical but different chemical B. same physical proper es
proper es
C. different physical proper es
✓ D. different physical and chemical proper es
Q.650 The chemical formula of calcite is:
A. MgCO3 B. CaMg3(SiO3)4
✓ C. CaCO3 D. H2Mg3(SOiD3)4
Q.651 Which of the following is used as disinfectant?
✓ A. boric acid B. phosphoric acid
C. phosphorous acid D. sulphuric acid
Q.652 In chemical method _____ is used find out the concentra on of reac on
A. Salt analysis B. Combus on analysis
✓ C. Titra on D. May be all
Q.653 Boric acid can not be use:
A. as an sep c medicine B. for washing of eyes
✓ C. in soda bo les D. for enamels and glazes
Q.654 Which gives violet colour with borax?
✓ A. Mn B. Ni
C. Co D. Fe
Q.655 Plaster of Paris is used
A. As a plaster for walls ✓ B. In den stry and surgery
C. In metallurgical process D. As a drying agent
Q.656 Galena is an ore of
A. Gallium ✓ B. Lead
C. Tin D. Germanium
Q.657 A major cons tuent of Portland cement (except lime) is
✓ A. Silica B. Alumina
C. Iron oxide D. Magnesia
Q.658 In the hydrolysis of CH3COOC2H5the acid produced is
A. Inhibitor B. Catalyst
C. Auto catalyst ✓ D. none of above
Q.659 The catalyst will affect the ______ of the reac on
A. Concentra on B. Thermodynamic proper es
✓ C. Ac va on energy D. All of these
Q.660 On hea ng sodium metal in a current of dry ammonia, the compound formed is
✓ A. Sodium amide B. Sodium azide
C. Sodium nitride D. Sodium hydride
Q.661 Due to their similar ionic radii the reac ons of lithium and magnesium and the corresponding compounds are very
similar,
Which statement concerning the reac ons of lithium and its compounds is corrects?
✓ A. Lithium carbonate decomposes on hea ng at B. Lithium nitrate decomposes on hea ng
a rela vely low temperature. forming lithium forming lithium nitrile and oxygen
oxide and carbon dioxide C. Lithium burns only slowly in oxygen
D. Lithium reacts violently with cold water
rela vely hydrogen
Q.662 Diagonal rela onship is not shown by
A. Li and Mg ✓ B. B and Si
C. C and P D. Be and Ga
_______________________________________________________________________________________
Q.663 Op cal rota on method is used when
A. Reac on involve ions B. Change of refrac ve indices
✓ C. Reac ons involving change of op cal acivity D. None of the above
Q.664 In view of their low ioniza on energies the alkali metals are
A. Weak oxidizing agents ✓ B. Strong reducing agents
C. Strong oxidizing agents D. Weak reducing agents
Q.665 When the rate of reac on is en rely independent of the conc. of reactant molecules then order of reac on is
✓ A. zero B. first
C. second D. third
Q.666 Which oxide is purely basic nature
A. B 2O 3 B. AI2O3
C. Ga2O3 ✓ D. Tl2O3
Q.667 Bleaching powder loses its power on keeping for a long me because
A. It change into calcium hypochlorate B. It changes into CaCI2and Ca(OH)2
C. It absorbs moisture ✓ D. It changes into calcium chloride and calcium
chlorate
Q.668 Which element is deposited at the cathode during the electrolysis of brine in Nelson's cell?
✓ A. H2 B. Na
C. CI2 D. O2
Q.669 Chlorine cannot be prepared by the ac on of HCI on
A. MnO2 ✓ B. NaCI
C. KMnO4 D. K2Cr2O7
Q.670 Phosphorus pentaoxide is powerful
A. oxidizing agent B. reducing agent
✓ C. dehydra on agent D. catalyst
Q.671 The cataly c ac vity of Pt is much higher when
A. it is mixed with asbestos B. it is mixed with Pd
C. it is mixed with arsenic ✓ D. in is made colloidal pla num
Q.672 Compared with the alkaline earth metals, the alkali metals exhibit
A. Smaller ionic radii B. Highest boiling points
C. Greater hardness ✓ D. Lower ioniza on energies
Q.673 Silicon is an important cons tuent of:
A. vegetables B. animals
✓ C. rocks D. alloys
Q.674 Aqua regia dissolve noble metal s due to the forma on of
✓ A. Nitrosyl chloride B. Nascent nitrogen
C. Nitric oxide D. Nitrous acid
Q.675 Which one of the following is the most Vola le acid?
A. HF B. HBr
✓ C. HCI D. HI
Q.676 All the elements of IV A group do not show which property
A. Form hydricle B. Form tetrachloride
C. Form dioxide ✓ D. Form basic oxides
Q.677 mark the statement having correct name and formula:
A. gypsum (CaSO4, 5H2O) B. sylvite (NaNO3)
✓ C. carnalite (KCI . MgCI26H2O) D. asbestos (CaMg2 (NO))
Q.678 Chose the amphoteric oxide?
A. N 2O ✓ B. Al2O3
C. SO2 D. NO2
Q.679 The number of atoms or molecules whose concentra on determines the rate of a chemical reac on is called the
A. Molecularity of the reac on ✓ B. Order of the reac on
_______________________________________________________________________________________
C. Specific ac vity of the reac on D. Rate constant of the reac on
Q.680 Xenon difluoride is
✓ A. linear B. trigonal
C. angular D. pyramidal
Q.681 The electron affinity group llA elements the order:
A. Ca > Be > Ba B. Be > Mg > Sr
C. Sr > Mg > Be ✓ D. Ba > Sr > Mg
Q.682 Which of the following would dissolve in hot NaOH solu on?
A. iron ✓ B. zinc
C. magnesium D. calcium
Q.683 Which of the following group of elements form border line compounds
A. IA B. ILA
✓ C. III A D. IV A
Q.684 The reac on of CI2 with cold and hot NaOH to give NaCI and NaCIO is an example of
A. neutraliza on reac on B. oxida on reac on
C. reduc on reac on ✓ D. dispropor on reac on
Q.685 The elements having highest mel ng point is:
A. Be ✓ B. Li
C. Sr D. Be
Q.686 When treated with nitric acid which of the following will liberate hydrogen
A. Zinc ✓ B. Magnesium
C. Copper D. Mercury
Q.687 Which is the chemical formula of zircon?
A. H2Mg3(SiO3)4 B. AI2F2SiO4
C. Na3AIF6 ✓ D. ZrSiO4
Q.688 Which property is not shown by borate
A. White crystalline solid B. Sparingly soluble in cold water
C. Shows monoclinic geometry ✓ D. Its aqueous solu on is acidic
Q.689 The strongest reducing agent out of Na, K, Rb and Cs is
A. Na ✓ B. Rb
C. K
Q.690 The metals of group II react readily with oxygen to from compounds of general formula MO when each of these
oxides is added to water
which forms the most alkaline solu on?
A. MgO B. CaO
C. SrO ✓ D. BaO
Q.691 .The most acidic of the following compounds reac ve?
A. Red phosphorus ✓ B. White phosphorus
C. Scrlet phosphorus D. Violet phosphorus
Q.692 Dinitrogen pentaoxide has oxida on no of nitrogen:
A. 2 B. 3
C. 4 ✓ D. 5
Q.693 The poten al energy diagram for ac va on energy can also be used to study the ______ during the reac on
A. Heat evolved B. Light absorbs
C. Heat absorbs ✓ D. Both a and c
Q.694 Some mes a yellow turbidity appears while passing H2S gas even in the absence of II group radicals.This is because
A. Sulphur is present in the mixture as impurity B. IV group radicals are precipitated as sulphides
✓ C. Of the oxida on of H2S gas by some acid D. III group radicals are precipitated as
radicals hydroxides
Q.695 Which statement about oxygen and sulphur is not true?
A. both exhibit allotropic form B. both are usually divalent
_______________________________________________________________________________________
C. both combine with metals to form O2- and S2- ✓ D. both are paramagne c
Q.696 Available chlorine is liberated from bleaching powder when it is
A. heated ✓ B. reacted with excess of acid solu on
C. reacted with alkali solu on D. reacted with water
Q.697 Factor which slows down the rate of reac on is
A. small size of the par cles of the reactant B. high temperature of reac on
C. more concentra on of reactant ✓ D. lowering the temperature
Q.698 Silicon is an important cons tuent of
A. Chlorophyll B. Hemoglobin
✓ C. Rocks D. Amalgams
Q.699 Which of the following is a component of ruby?
A. CaCO3 B. MgCO3
✓ C. AI2O3 D. AI(OH)3
Q.700 The number of electrons that are paired in oxygen molecule are
A. 16 B. 12
✓ C. 14 D. 7
Q.701 Mark the incorrect statement about the conductance semi conductance used in photoelectric cells and solar ba eries.
semi conductors show:
A. different resistance under different ✓ B. increase in resistance with increase in
circumstance temperature
C. decrease in resistance with increase in D. decrease in resistance with intensity of light
temperature
Q.702
✓
A. B.
C. D.
Q.703 Choose the element having highest boiling point among the following:
A. Si ✓ B. Ge
C. Sn D. Pb
Q.704 The rate of reac on between two specific me intervals is called:
A. Instantaneous rate of reac on ✓ B. Average rate of reac on
C. Rate of a reac on D. Minimum rate of a reac on
Q.705 In the manufacture of NH3by Haber's process catalyst used is iron its catalyst efficiency is poisoned by
A. presence of Al2O3 B. presence of Cr2O3
C. MnO2 ✓ D. CO present with H2gas
Q.706 Which element forms an ion with charge +3?
A. Be ✓ B. AI
C. C D. Si
Q.707 Phosphorus pentoxide finds use as
A. An oxidizing agent B. A reducing agent
C. A bleaching agent ✓ D. A dehydra ng agent
Q.708 Which is not correct reason about the oxidizing power of halogens depending on various factors?
A. electron affinity B. energy dissocia on
✓ C. hydra on energy D. high atomic number
Q.709 The gas which cannot be dried by conc H2SO4
A. SO4 B. CO2
✓ C. H 2S D. H2
Q.710 At room temperature fluorine is:
✓ A. pale yellow gas B. greenish yellow gas
_______________________________________________________________________________________
C. red brown liquid D. shiny grayish
Q.711 Neon glows in discharge tube as:
✓ A. raddish B. bluish
C. greenish D. yellowish
Q.712 The solubility of carbonates decrease down the Mg group due to decrease in:
A. inter-ionic a rac on B. entropy of solu on forma on
✓ C. hydra on energies of ca ons D. la ce energy of solids
Q.713 select the metal which dissolves in HaOH with evolu on of H2?
A. Ba ✓ B. Be
C. Mg D. Ca
Q.714 Which one of the elements reacts directly with nitrogen to form nitride?
✓ A. Li B. Ba
C. K D. Rb
Q.715 If CO2 is passed in excess into lime water the milkiness first formed disappears due to
A. Reversal of original reac on ✓ B. Forma on soluble calcium bicarbonate
C. Forma on of vola le calcium deriva ve D. Forma on of soluble magnesium hydroxide
Q.716 The insoluble oxide in water among the following is:
A. BaO B. SrO
✓ C. BeO D. CaO
Q.717 Which is the symbol of element whose atoms have the outermost configura on 2s22p3 is
A. C B. Li
✓ C. N D. P
Q.718 The bonds present in N2O5 are
A. Only ionic ✓ B. Covalent and coordinate covalent
C. Only covalent D. Covalent and ionic
Q.719 A pseudo solid is
A. Diamond ✓ B. Glass
C. Rock salt D. CaCO3
Q.720 The acid used in lead storage cells is
A. Phosphoric acid B. Nitric acid
✓ C. Sulphuric acid D. Hydrochloric acid
Q.721 Which one of the following pentafluoride cannot be formed?
A. PF5 B. AsF5
C. SbF5 ✓ D. BiF5
Q.722 One mole of each of the following compounds is strongly heated and any gas produced is collected at room
temperature and pressure,
Fron which compound is 24dm3 of gas likely to be collected?
[One mole of any gas is 24dm3 of gas likely to be collected?
A. MgCI2 ✓ B. MgCO3
C. Mg(NO3)2 D. Mg(OH)2
Q.723 Reac vity of borazole is of greater than that of benzene because
A. Borazole is nonpolar compound ✓ B. Borazole is polar compound
C. Borazole is electron deficient compound D. Of localized electrons in it.
Q.724 Because of its small size and due to restric on of its valence shell to
an octet
A. it has highest first I.E B. it has highest E.N
✓ C. it is more reac ve than other halogens D. it restricts to oxida on state -1 only
Q.725 Half life period of N2O5is 24 minutes and it remains same where we increase or decrease its ini al concentra on, then
reac on is
A. third order B. second order
✓ C. first order D. zero order
_______________________________________________________________________________________
Q.726 The brown gas formed when metal reduces HNO3
A. N 2O 5 B. N 2O 3
✓ C. NO2 D. NO
Q.727 When ammonia is heated with cupric oxide, a molecule of ammonia will
A. Gain 3 electrons ✓ B. Lose 3 electrons
C. Gain 2 electrons D. Lose 2 electrons
Q.728 Rate law of an equa on is obtained:
A. From a balanced equa on B. Can be calculated theore cally as well as
determined experimentally
C. It is only calculated theore cally ✓ D. Experimentally
Q.729 Mark the mineral of Al which contains no oxygen:
A. corundum B. cryolite
C. diaspore ✓ D. bauxite
Q.730 Boric acid can not be used:
A. as an sep c medicine B. for washing of eyse
✓ C. in soda bo les D. for enamels and glazes
Q.731 A solu on of sodium metal in liquid ammonia is strongly reducing due to the presence of
A. Sodium atoms B. Sodium hydride
C. Sodium amide ✓ D. Solvated electrons
Q.732 Which of the halogens flails to give a precipitate with AgNO3?
A. Br ̅ B. CI ̅
✓ C. F̅ D. I̅
Q.733 Borax lead test is not given by:
A. a nickel salt ✓ B. an alumiuium salt
C. a copper salt D. a cobalt salt
Q.734 The purifica on method of bauxite containing iron oxide as impurity is known as
A. Hoop's process B. Serpeck's process
✓ C. Baeyer's process D. Electroly c process
Q.735 CaCO3reacts with H2SO4more effec ve when it will take in ______ form
✓ A. Powder B. Big pieces
C. Bulk D. May be all
Q.736 The rate of reac on for a reac on is 30 moledm-3sec-1if the product of concentra on of reactant is unity the specific
rate constant is
A. 2.5 ✓ B. 30
C. 15 D. 25
Q.737 Point out the property which is not characteris c of alkali metal:
A. low electronega vity B. low mel ng point
C. their ions are isoelectronic with noble gases ✓ D. high ioniza on energy
Q.738 Which of the following metal doesnt produce hydrogen gas dil sulphuruc acid
A. Fe B. Zn
C. Mg ✓ D. Cu
Q.739 Se ng of Plaster of Paris involves
A. Oxida on with atmospheric oxygen B. Combina on with atmospheric CO2
C. Dehydra on ✓ D. Hydra on to yield another hydrate.
Q.740 Nitrogen dioxide can be obtained by the thermal decomposi on of
A. Silver nitrate B. Sodium nitrate
C. Potassium nitrate ✓ D. Lead nitrate
Q.741 Which of the following nitrate gives a nitrite on hea ng
A. NaNO3 ✓ B. Mg(NO3)2
C. Ca(NO3)2 D. LiNO3
Q.742 Bleaching powder is not used to
_______________________________________________________________________________________
✓ A. bleach raw sugar B. disinfect in the sterliza on of water
C. bleach co on D. prepare CI2and O2
Q.743 which is the electronic configura on of sn?
A. [Ar]4s23d104p2 B. [Xe]6s24F145d106p2
✓ C. [Kr],5s2.4d105p2 D. [Ar]4s23d104p1
Q.744 Mixing aqueous silver nitrate and aqueous sodium chloride produced a precipitate addi on if which reagent to the
mixture gives a colourless solu on?
A. aqueous ammonia B. aqueous potassium iodide
✓ C. dilute hydrochliric acid D. dilute nithric acid
Q.745 Which of the following element is metallic in nature
A. P B. As
C. Sb ✓ D. Bi
Q.746 Lime water is an aqueous solu on of
A. MgSO4 B. CaCO3
✓ C. Ca(OH)2 D. CaSO4
Q.747 The most acidic of the following compounds is
✓ A. P 2O 3 B. Sb2O3
C. B 2O 3 D. As2O3
Q.748 When concentrated nitric acid is heated it decomposes to give
A. Oxygen and nitrogen B. Nitric oxide
C. OXygen ✓ D. Nitrogen dioxide and oxygen
Q.749 Hydrogena on of vegetable oils is accelerated by Ni catalyst. The cataly c ac vity of Ni is increased by a promoter of
ac vator which is
A. Na and K B. Na and Hg
C. Hg and Zn ✓ D. Cu and Te
Q.750 The colour of iodine solu on is discharged by shaking with
✓ A. aqueous sulphur dioxide B. sodium sulphate
C. sodium sulphide D. sodium chloride
Q.751 Which of the following is not a correct statement about iodine?
A. A crystal of iodine contains covalent bond B. iodine vapour is purple
and van der Waals forces.
C. The first ioniza on energy of iodine is less
than that of bromine.
✓ D. The hydride of iodine is if greater thermal
stability than that of bromine
Q.752 Mark the element which is not oxidized by MNO2:
A. I2 ✓ B. F̅
C. CI ̅ D. I3
Q.753 The least value of ioniza on energy among the following elements is:
A. Ca ✓ B. Rb
C. Na D. Sr
Q.754 Bond angel is minimum for
A. H 2O B. H 2S
C. H2Se ✓ D. H2Te
Q.755 Mark one of the following ions which does not exist:
✓ A. B3+ B. Al3+
C. Ga3+ D. ln3+
Q.756 A radioac ve material disintegrates by first order reac on and takes 24 hours to go from 1 g to 0.125 g. The half life of
the material is
A. 72 hours B. 36 hours
C. 12 hours ✓ D. 9 hours
✓ A. Decreases as the reac on proceeds B. Increases as the reac on proceeds
_______________________________________________________________________________________
C. May decrease or increase as the reac on D. Remains same as the reac on proceeds
proceeds
Q.758 The excite state electronic configura on of phosphours has unpaired electrons
A. 3 B. 4
✓ C. 5 D. 9
Q.759 SO3 is absorbed in water directly to form H2SO4 because
A. The reac on does not go to comple on B. The reac on is quite slow
✓ C. The reac on is exothermic D. SO3is insoluble in water
Q.760 In which compound of xenon, Xe has maximum oxida on state?
A. XeOF4 B. XeF6
✓ C. XeO4 D. XeFOF2
Q.761 Each of the following is true of white and red phosphorus except that they
✓ A. Are both soluble in CS2 B. Can be oxidized by hea ng in air
C. Consist of the same kind of atoms D. Can be converted into one another.
Q.762 point out one of the following which shows moderate electrical conduc vity:
A. silica ✓ B. graphite
C. carbraundum D. diamond
Q.763 Which of the following has the maximum tendency to form complexes
A. K B. Rb
C. Na ✓ D. Li
Q.764 Which of the following does not give NO with dil HNO3
A. Cu B. Hg
✓ C. Zn D. Ag
Q.765 Chlorine con not displace:
A. bromine from NaBr ✓ B. fluorine from NaF
C. iodine from Nal D. none of all
Q.766 Ac va on energy is
✓ A. the minimum amount of energy required for B. it is the difference of energy between the
an effec ve collision leading to the forma on reactant and the product
of product C. it is the energy required to change a solid
reactant into gaseous form
D. it is always greater for the reac on in case of
exothermic reac on
Q.767 Plaster of paris hardens by
A. Giving off O2 B. U lizing water
C. Changing of CaCO3 ✓ D. Giving out water
Q.768 Marke the nitrate which decomposes differently on hea ng:
A. RbNO3 ✓ B. LiNO3
C. NaNO3 D. KNO3
Q.769 The alkali metal that reacts with nitrogen directly to form nitride is
✓ A. Li B. Na
C. K D. Rb
Q.770 Oxida on of ammonia at NO in the presence of ______ helps us to manufacture HNO3
A. Cu Gauze B. Mn Gauze
✓ C. Pt Gauze D. May be all
Q.771 Choose the most stable among the following?
A. SI2+ ✓ B. Pb2+
2+
C. Ge D. Sn2+
Q.772 Group I-A elements react with water fastly than the reac on of group II-A elements because
A. IAelements are more so than IIA B. IAelements are non-metals
✓ elements have 1 electron in their D. IAelements make ionic bond
C. IAoutermost s-orbital and are strongly
electroposi ve
_______________________________________________________________________________________
Q.773 All the minerals have sulphide radical except
A. Galena B. Zinc blende
C. Cinnabar ✓ D. Heavy spar
Q.774 An element that has high ioniza on energy and tends to be chemically inac ve would most likely to be:
A. an alkali metal B. a trasi on element
Q.775 Which one of the following proper es is not correct for ozone?
A. It oxidizes lead sulphides B. It oxidizes potassium iodidle
C. It oxidizes mercury ✓ D. It cannot act as a bleaching agent
Q.776 The variety of glass used in making lenses and prisms is
A. Soda glass B. Borosilicate glass
✓ C. Flint glass D. Crook's glass
Q.777 If the surface area of aluminum increase then burning of aluminum will be
C. May decrease D. May be increase
Q.778 The unit of rate of reac on is
A. mole dm-3 B. mole kg-1
✓ C. moles dm-3sec-1 D. grams dm-3
Q.779 All the following decompose easily on hea ng to give oxygen except
A. Lead nitrate B. Potassium chlorate
C. Mercuric oxide ✓ D. Manganese dioxide
Q.780 Several blocks of magnesium are fixed to the bo om of a ship to
A. Prevent puncturing by under sea rock B. Keep away the sharks
C. Make the ship lighter ✓ D. To prevent the ac on of water and salt.
Q.781 Which does not react with aluminum under normal condi on
A. H2SO4 ✓ B. HNO3
C. NaOH D. HCI
Q.782 The minimum amount of energy required to form an ac vated complex is called
A. reac on energy ✓ B. ac va on energy
C. deac va on energy D. comple on energy
Q.783 If half life period of a reac on is independent of the concentra on of the reactants, then the reac on is
A. zero order ✓ B. first order
C. second order D. order is in frac on
Q.784 The halide which is not hydrolysed is
A. SiCI4 B. SiF4
✓ C. CCI4 D. PbCI4
Q.785 Be and Al have diagonal rela onship. There tore both have:
A. amphoteric nature of oxides B. same radius/ charge ra o
C. BeCI2
and
3
and vola le and fume in moist ✓ D. all above
AICI air
Q.786 Which of the following is acidic?
✓ A. SO3 B. N 2O
C. BeO D. HgO
Q.787 Alkali metal hydroxides are stable to heat except:
A. NaOH B. KOH
✓ C. LiOH D. RbOH
Q.788 Name the non-metallic element in lllA group of the period table:
A. Al ✓ B. Ga
C. B D. ln
Q.789 In exothermic reac ons decrease in poten al energy of the products will result in
A. decrease in kine c energy of the par cles ✓ B. increase in kine c energy of the par cles
_______________________________________________________________________________________
C. no change in kine c energy D. decrease in ac va on energy
Q.790 Metallic lustre exhibited by Na can be explained by:
A. excita on of free protons B. diffusion of sodium ions
✓ C. oscilla on of loose electrons D. existence of body centred cubic
Q.791 Calcium is obtained by
A. Roas ng of lime stone B. Electrolysis of solu on of calcium chloride in
water
C. Reduc on of calcium chloride with carbon ✓ D. Electrolysis of molten anhydrous or fused
calcium chloride
Q.792 Freon-12 is used as a
✓ A. Refrigerant B. Insec cide
C. Fungicide D. Herbicide
Q.793 The reac on of an akali metal oxide with water is
A. Complexa on reac on B. Precipita on reac on
C. Redox reac on ✓ D. Acid-base reac on
Q.794 Sodium sulphates is solute in water but barium sulphates is insoluble because
A. The hydra on is more than its B. The la ce energy is more than its
2SO4 4
energy of Na la ce energy of BaSO hydra on energy
C. The la ce energy has no role to play in ✓ D. Both a and b
solubility
Q.795 a combus ble gas is liberated when caus c soda solu on is heated with
A. S B. NH4CI
C. I2 ✓ D. Zn
Q.796 Iden fy the correct statement
A. Element sodium can be prepared and isolated B. Elemental Na is a strong oxidizing agent
by electrolyzing an aqueous solu on of NaCI.
C. Elemental Na is insoluble in NH3
✓ D. Elemental Na is easily oxidized.
Q.797 In the hydrolysis of CH3COOC2H5the acid produced is
A. Inhibitor B. Catalyst
C. Auto catalyst ✓ D. None of above
Q.798 Mark the incorrect statement about bleaching powder:
A. it is an oxidizing agent ✓ B. it is very soluble in H2O
C. it reacts with dilute to releases Cl2 D. it is powder of light yellow colour
Q.799 Red phosphorus is made by hea ng yellow phosphorus is the presence of an inert gas at temperature
A. 60°C ✓ B. 240°C
C. 200°C D. 100°C
Q.800 Order of reac on is
A. the power to which the concentra on of the B. the power to which the concentra on of the
reactant is raised product is raised
✓ C. the power to which the concentra on of the D. the power to which the concentra on of the
reactant is raised in the experiments reactants is raised in the fast step
determined rate equa on
Q.801 sodium metal can not be stored under:
A. toluene B. kerosene oil
C. benzene ✓ D. alcohol
Q.802 The halogen that is most readily readily is
✓ A. fluorine B. bromine
C. chlorine Tincture of iodine is D. iodine
Q.803 Alkail metals have one electron in their:
A. f-orbital B. p-orbital
✓ C. s-orbital D. d-orbital
Q.804 The most stable +2 oxida on state is exhibited by
A. Fe B. Sn
✓ C. Pb D. SI
_______________________________________________________________________________________
Q.805 Which is not an alkali metals?
A. Cs ✓ B. Rh
C. Fr D. Rb
Q.806 What happen when chlorine is bubbled through aqueous potassium
iodide?
A. chlorine oxidized to chloride ions B. hydrochloric acid is formed
✓ C. iodide ions are oxidized to iodine D. potassium iodide is reduced to iodine
Q.807 Chlorine is used for
✓ A. purifica on of water B. as a beaching agent
C. extrac on of gold D. all to the above
Q.808 Choose the gas among the following which turns line water milky:
A. CO B. Br2
C. PbMoO4 ✓ D. PbCrO4
Q.809 Which of the following element can only react with NaOH
✓ A. Be B. Mg
C. Ca D. Ba
A. increases as the reac on proceeds ✓ B. decrease as the reac on proceeds
C. remains the same as the reac on proceeds D. may decrease increase as the reac on
proceeds
Q.811 Boron compounds behave as Lewis acid because of their
A. Acidic nature ✓ B. Electron deficiency
C. Covalent nature D. Ioniza on property
Q.812 The process associated with sodium carbonate manufacture is known as
A. Chamber B. Haber
✓ C. Solvay D. Castner
Q.813 The unit of rate constant k is the same as that of the rate of reac on in
A. first order reac on B. second order reac on
C. third order reac on ✓ D. zero order reac on
Q.814 The compounds of beryllium are covalent because of:
✓ A. small highly charged ion B. high electronega vity value
C. small ionic radius D. high hydra on energy of Be2+ions
Q.815 Mark the element which forms a solid oxide at room temperature is:
A. P B. H2
✓ C. Mg D. S
Q.816 Nitrous oxide is prepared in the laboratory by
A. Combina on of nitrogen and oxygen B. Reduc on of nitric acid
C. Reduc on of NO ✓ D. Thermal decomposi on of NH4NO3
Q.817 Which statement is most likely to be true for asta ne. Which is below iodine in group VII of the periodic table?
A. Asta ne and aqueous potassium chloride B. Potassium asta de and hot dilute sulfuric acid
react to form aqueous potassium asta de and react to form white fumes of only hydrogen
chlorine. asta de
C. silver asta de reacts with dilute aqueous ✓ D. sodium asta de and hot concentrated
ammonia in excess to form a solu on of a sulfuric acid react to form asta ne.
soluble complex
Q.818 One which is not dissolved by dilute hydrochloric acid is
A. ZnS B. MnS
C. BaCO3 ✓ D. BaSO4
Q.819 Se ng of plaster of paris is:
A. combina on with atmospheric CO2 ✓ B. dehydra on to yield another hydrate
C. dehydra on D. oxida on with atmospheric oxygen
Q.820 When a colourless gas is passed through bromine water only decolourisa on takes place the gas is
✓ A. SO2 B. HBR
_______________________________________________________________________________________
C. HCI D. H 2S
Q.821 AICI3 fumes in moist air because
A. It is very vola le B. It is covelent
✓ C. HCI is formed in moist air D. It is highly hygroscopic
Q.822 Sulphur trioxide is an anhydride of
A. suphurous acid B. sulphurous acid
✓ C. hyposulphuric acid D. hydro sulphuric
Q.823 BF3 acts as acid according to the concept of
✓ A. Lewis B. Bronsted
C. Arrhenius D. None
Q.824 Calcium bicarbonate and calcium hydroxide can not be strong in the same vessel because bicarbonate behaves as:
A. strong alkali ✓ B. acid with Ca(OH)2
C. base with Ca(OH)2 D. none of all
Q.825
A. 100 kg min
-1
✓ B. 80 kg min
-1
-1 -1
C. 64 kg min D. 32 kg min
Q.826 Carbon atoms is diamond are bonded with each other in a configura on
A. Linear ✓ B. Tetrahedral
C. Planar D. Octahedral
Q.827 Red lead is
A. PbO ✓ B. Pb3O4
C. PbO2 D. Pb2O3
Q.828 For reac on of methane and chlorine if light is not available then
A. Reac on will take place rapidly ✓ B. Reac on will take place slowly
C. No reac on take place D. May all cases occur
Q.829 The elements should process the following proper es:
A. lower mel ng point B. smallest size
C. highest ioniza on energy ✓ D. lowest electgronega vity
Q.830 Which of the following elements is most metallic?
A. P B. As
C. Sb ✓ D. Bi
_______________________________________________________________________________________
9 Periods
Q.1 A sudden large difference between the values of second and third ioniza on energies of elements would be associated
with which of the following electronic configura on
A. 1 s2, 2s2, 2p6 B. 1s2, 2s2, 2p6, 3s2, 3p2
✓ C. 1s2, 2s2, 2p6, 3s2 D. 1s2, 2s2,2p6, 3s2,3p6, 4s2, 3d4
Q.2 Passive iron can be rendered ac ve by
A. Scratching B. Immersing it is alkaline
C. Hea ng in the atmosphere of H2O or CO ✓ D. All of above
Q.3 What is the shape of Fe(CO)5 molecule?
A. Tetrahedral B. Octahedral
✓ C. Trigonal bipyramidal D. Square pyramidal
Q.4 Which chlorine compound has bonding that can be described as ionic with some covalent character?
A. NaCl ✓ B. MgCl2
C. AlCl3 D. SiCl4
Q.5 Corrosion of iron can be prevented by coa ng the surface with
A. Zn B. Sn
C. Ni ✓ D. Any of the above
Q.6 Ioniza on energy depends upon
A. Nuclear charge B. Atomic size
C. Shielding effect ✓ D. All of the above
Q.7 Potassium ferrocyanide (potassium haxacyano ferrate ll) is a/an ______ complex.
A. ca onic ✓ B. anionic
C. neutral D. none of above
Q.8 Ethylene diamine is:
A. mono dentate legand ✓ B. bidentate
C. polydentate ligand D. it is Lewis acid
Q.9 Which type of steel is used in making parts of machinery
A. Mild Steel B. High carbon steel
✓ C. Medium carbon steel D. All of above
Q.10 Newland's arranged elements in group of:
✓ A. Duplets B. Triads
C. Pentaves D. Octaves
Q.11 Modern period table has families:
A. Lanthanide family B. Halogens family
C. alkali metals family ✓ D. all of these
Q.12 Sodium thisoulphate is used in photography because of its
A. Oxidizing behaviour B. Reducing behaviour
✓ C. Complexing behaviour D. Photochemical behaviour
Q.13 Mos transi on elements show
A. diamagn c behavior B. ferromagne c behavior
✓ C. paramagne c behavior D. none of these
Q.14 Aqueous solu on of which substance is green in colour
_______________________________________________________________________________________
A. K2CrO4 B. K2Cr2O7
C. KMnO4 ✓ D. K2MnO4
Q.15 Indicate the correct statement
A. all lanthanidees are present in the same B. all halogens are present in the same period
✓ C. all the alkali metals are present in the same D. all the noble gases are present in the same
group period
Q.16 The color of the transi on metal compounds is due to
A. p-d transi on B. d-d transi on
C. s transi on ✓ D. none of these
Q.17 Which is typical transi on element?
A. Sc B. Cd
C. Zn ✓ D. Cr
Q.18 Halides with the dimensional la ce are
C. Polymeric D. a,b, and c
Q.19 Bill metal iis an alloy of Sn and
✓ A. copper B. iron
C. zinc D. magne c
Q.20 Which one of the following metal ions is colourless?
A. V2+ B. Cr3+
✓ C. Zn2+ D. Ti3+
Q.21 The horizontal rows in the Periodic Table are called periods. The number of period are
A. 5 B. 6
✓ C. 7 D. 8
Q.22 Ac noids are of atomic number
A. 58 - 71 ✓ B. 90 - 103
C. 7 - 71 D. 89 - 102
Q.23 According to Mendleev, the physical and the chemical proper es are the periodic func on of their
A. Atomic number ✓ B. Atomic mass
C. Atomic wt D. None
Q.24 There were seven groups in periodic table proposed by:
A. Al-Razi B. Dobriener
C. Newland ✓ D. Mendeleev
Q.25 Group VI B of transi on elements contains:
A. Cr B. Mo
C. W ✓ D. All of these
Q.26 Electron affinity value from higher to heavier element:
C. Remains same D. Not effect
Q.27 Transi on elements are less reac ve because of
A. Huge heat of vaporiza on B. Low heat of hydra on of ions
✓ C. High I.E D. All of these
Q.28 Across the lanthanide series, the basicity of the lanthanide hydroxides
C. First increases and then decreases D. First decreases and then increases
Q.29 The energy absorbed when an electron is added to a gaseous atom to from a gaseous ion is called
✓ A. electron affinity B. ioniza on energy
C. both of these D. none of these
Q.30 Oxida on state of Sn in SnCI4is:
A. +1 B. +2
C. +3 ✓ D. +4
_______________________________________________________________________________________
Q.31 The most durable metal pla ng on iron to protect against corrosion is
A. Tin pla ng ✓ B. Zine pla ng
C. Copper pla ng D. Nickel pla ng
Q.32 Which of the following elements forms polymeric halides
A. Ca B. P
✓ C. Al D. Zn
Q.33 Potassium forms K1+ions and not K2+easily because
A. l.E1> l.E2 ✓ B. I.E1<<< I.E2
C. l.E1= l.E2 D. Unpredictable
Q.34 Trend of ioniza on energy in a group from top to bo om is:
✓ A. Increase B. Decreases
C. remains same D. (a) and (b) both
Q.35 How many unpaired electrons are there to Ni(II)
A. 0 ✓ B. 02
C. 04 D. 08
Q.36 Mendeleev periodic table was arranged in the order of atomic masses:
A. Decreasing ✓ B. Increasing
C. Decreasing D. Descending
Q.37 Which oxide is different from others
A. PbO B. ZnO
✓ C. CaO D. Al2O3
Q.38 Which of the following has smalles size
A. Al B. Al+
C. Al ++ ✓ D. Al+++
Q.39 A mixture of the oxides of two elements of the third period is dissolved in water. The solu on is approximately
neutral.
What could be the cons tuents of the mixture?
A. Al2O3and MgO B. Na2O and MgO
✓ C. Na2O and P4O10 D. SO3and P4O10
Q.40 Oxida on state of boron, aluminium and gallium is:
A. +1 B. +2
✓ C. +3 D. +5
Q.41 Cinnabar is an ore of ______
✓ A. Hg B. Cu
C. Fe D. Zn
Q.42 Which is the longest period of the Periodic Table?
A. 5th B. 7th
✓ C. 6th D. 2nd
Q.43 Complexes with bidentate ligands are called:
A. Ligands B. Complexes
✓ C. Chelates D. None of these
Q.44 Which of the following transi on metal ions will have definite value of magne c moment?
A. Sc3+ ✓ B. Ti3+
+
C. Cu D. Zn2+
Q.45 Which of the following is a carbonate are?
A. Pyrolusite ✓ B. Malchite
C. Diaspore D. Cassiterite
Q.46 the binary compounds of nitrogen are called.
A. hydrides B. halides
C. oxides ✓ D. nitrides
_______________________________________________________________________________________
Q.47 color of silver iodide is:
✓ A. deep yellow B. white
C. blue D. pink
Q.48 Co-ordina on umber of silver is:
A. 1 ✓ B. 2
C. 4 D. 3
Q.49 NaH is
✓ A. Ionic hydride B. Complex hyride
C. Covalent hydride D. Inters al hydride
Q.50 The binary compound i which one element is fluorine is called:
A. Hydride B. Chloride
C. Bromide ✓ D. Fluoride
Q.51 Chemical formula of chronic anhydride is
A. CrO3 ✓ B. Cr2O3
2-
C. CrO 4 D. Cr2O2-7
Q.52 Ioniza on energy of sodium is (KJ/mol):
A. 503 ✓ B. 513
C. 523 D. 524
Q.53 Halides with ionic bond is called:
A. Ionic B. Covalent
✓ C. only a and b D. None
Q.54 Mendeleeve periodic table has groups:
A. 6 ✓ B. 7
C. 8 D. 9
Q.55 Each ver cal coloumn of the Periodic Table includes elements with chemical characteris cs that are, in general
A. inden cal ✓ B. similar
C. different D. similar as well as different
Q.56 How many moles of acidified FeSO4 solu on can be completely oxidized by one mole of KMnO4?
A. 10 ✓ B. 5
C. 6 D. 2
Q.57 The pair which is the most similar chemically is
A. Na, Al B. Cu, S
C. Ti, Zi ✓ D. Zr, Hf
Q.58 Which orbital is in the process of comple on in case of transi on elements?
A. p-orbital B. f-orbital
✓ C. d-orbital D. s-orbital
Q.59 Lanthanides are present in period of periodic table:
A. 1 B. 2,3
C. 4,5 ✓ D. 6
Q.60 Dobriener Gave his law in the year:
A. 1829 B. 1864
✓ C. 1871 D. 1913
Q.61 Strength of binding energy of transi on of elements depend upon:
✓ A. Unpaired electrons B. Core elements
C. Lone pair of electrons D. Valence electron
Q.62 Oxida on state of an element in free state is:
A. Its number of electrons lost B. Its number of electrons gained
✓ C. Zero D. Its number of electrons shared
Q.63 Unexpected electronic configura on is shown by the elements of
A. I B group B. VI group
_______________________________________________________________________________________
C. IV B group ✓ D. Both A and B
Q.64 Hydrogen is diatomic gas, a property in accordance of group of periodic table:
A. I-A B. II-A
C. IV-A ✓ D. VI-A
Q.65 KMnO4 is used........
A. As oxidizing agent B. As disinfectant + germicide
C. In the manufacturing of organic compounds ✓ D. All of these
Q.66 Hypo is trade name of sodium this sulphate it is used in photography for:
A. developing the nega ve ✓ B. reduc on of nega ve
C. to make it nega ve D. to make it nega vely
Q.67 Which group combina on from same group of periodic table have tendency to form anions
A. P, S, Cl ✓ B. As, Sb, Bi
C. Fe, Co, Ni D. Li, Be, B
Q.68 Which of the following has no variable valency
A. Co B. Fe
C. Mn ✓ D. Zn
Q.69 Amount of carbon in wrought iron is
✓ A. 0.12 -0.25% B. 0.25-2.5%
C. 0.7-1.5% D. 2.5-4.5%
Q.70 In sixth period 14 of its transi on elements are called
✓ A. Lanthanides B. Ac nides
C. Radioac ve elements D. None
Q.71 Which element belongs to 5d series?
A. V B. Nb
C. Pd ✓ D. Hf
Q.72 The first ioniza on energy is the smallest for the atom of configura on
A. ns2np3 ✓ B. ns2np4
2 5
C. ns np D. ns2np6
Q.73 Chemical formula of Hema te is
A. FeO ✓ B. Fe2O3
C. Fe3O4 D. Na3AIF6
Q.74 The colour of transi on metal complexes is due to:
✓ A. d-d transi on of electron B. Ioniza on
C. Paramagne c nature of transi on elements D. Loss of S-electron
Q.75 The property which shows descending trend across the periods (le to right)
A. Ioniza on energy B. Hydra on energy
C. Electronega vity ✓ D. Atomic radius
Q.76 Which of the following metal exhibits more than one oxida on?
A. Na B. Mg
✓ C. Fe D. AI
Q.77 The elements with atomic number 8, 16, 34, 52 and 84 are
A. Halogens B. Noble gases
✓ C. Chalcogens D. Coinage metals
Q.78 In the manufacture of iron from haema te,limestone is added to act as.
✓ A. Flux B. A reducing agent
C. Slag D. An oxidizing agent
Q.79 Alkali and alkaline earth metals are basic oxides except:
A. Li ✓ B. Be
C. Fr D. Ba
Q.80 Forma on of intersi al compound makes the transi on metal
_______________________________________________________________________________________
A. More duc le ✓ B. More hard
C. More so D. More metalic
Q.81 Li,Be,B,C,N,O,F, Ne are elements of
✓ A. second period B. first period
C. fourth period D. third period
Q.82 Mel ng point is highest for the elements of group
A. IA B. IIA
C. IIIA ✓ D. IV A
Q.83 Atomic radius is affected by:
A. Proton numbers B. Shielding effect
C. Nuclear change ✓ D. All above
Q.84 An atom gains electrons to become:
A. Ion B. Radical
C. Posi ve ion ✓ D. Complex ion
Q.85 The binary compound in which one element is chlorine is called:
A. Hydride ✓ B. Chloride
C. Bromide D. Fluoride
Q.86 The number of unpaired electrons in ferrous ion (Z = 26) is
A. 3 B. 2
✓ C. 4 D. 5
Q.87 When an element "M" reacts with chlorine, an acidic chloride is formed. What is the element "M"
✓ A. Hydrogen B. Sodium
C. Potassium D. Calcium
Q.88 Which of the following elements have the largest radius?
A. F B. Cl
C. Br ✓ D. I
Q.89 Non informa on of menisus by Hg in presence of O3 is due to the forma on of
A. Mercuric oxide ✓ B. Mercurous oxide
C. Mercuric chloride D. Mercurous chloride
Q.90 Tendency of hydrides to be covalent in a period from le to right:
A. Decreases B. remains same
✓ C. Increases D. all
Q.91 Which is the best method to prepare steel?
A. Pudding ✓ B. Bessemer process
C. Open hearth process D. None of the above
Q.92 The statement that the proper es of every eight elements are similar to the first is the law of
A. Dobereiner ✓ B. Newland
C. Mendeleev D. L.Meyer
Q.93 The oxides of electronega ve elements are
A. basic B. neutral
✓ C. acidic D. amphoteric
Q.94 Cuprous ore among the following is
A. Chalcopyrites B. Azurite
✓ C. Cuprite D. Malachite
Q.95 Complex ion which has no d-elements in the central atom is
A. [Co(NH3)6]3+ B. [Fe(CN)6]3-
C. [Cr(H2O)6]3+ ✓ D. [MnO4]-
Q.96 The amount of energy released an addi on of an electron into valence shell of gaseous isolated atom is called
A. Ioniza on energy ✓ B. Electron Affinity
C. Electron nega vity D. Electron posi vity
_______________________________________________________________________________________
Q.97 The amount of energy required to remove an electron form an atom of an element in the gaseous state is called
A. electron affinity B. electronega vity
✓ C. ioniza on energy D. none of these
Q.98 In Bessemer converter Air bubbles are removed from molten steel by adding small amount of
A. Carbon B. Sulphur
✓ C. Aluminum D. Mn
Q.99 Which is the most vola le compound
A. HI ✓ B. HCl
C. HBr D. HF
Q.100 Which of the element shows abnormal electronic configura on?
A. Zn B. Cu
✓ C. Co D. Fe
Q.101 Transi on metal ion give color due to:
✓ A. d-d transi on B. s-p transi on
C. p-p transi on D. charge transfer
Q.102 Group VIB of transi on elements contains:
A. Zn,Cd,Hg B. Fe,Ru,Os
✓ C. Cr,Mo,W D. Mn,Te,Re
Q.103 Acidified potassium permanganate is decolorized by:
A. White vitriol B. Laughing gas
C. Bleaching powder ✓ D. Mohr's salt
Q.104 Mosley gave his periodic law in the year:
A. 1829 B. 1864
C. 1871 ✓ D. 1913
Q.105 Newland said, Every eight element repeats proper es of element:
A. 1st B. 2nd
C. 3rd ✓ D. 4th
Q.106 S-block statements closely ramble in their physical and chemical proper es. which statement is incorrect?
A. they show variable valency B. their ions and compounds are colored
C. they are good conductors of heat and ✓ D. their compounds are diamagne c
electricity
Q.107 Square planner co-ordina on complex has co-ordina on No
✓ A. 04 B. 06
C. 05 D. Both A and B
Q.108 Newland'swas a scien st:
A. Russian B. German
✓ C. English D. French
Q.109 The half distance between centres of two nuclei of two atoms in an elements is called.
✓ A. Atomic radii B. Covalent radii
C. Ionic radii D. Ca on radii
Q.110 Mel ng in presence of coke and silica is called:
A. caking B. cooking
✓ C. smel ng D. roas ng
Q.111 out of 110 known elements transi on elements are:
A. 30 ✓ B. 60
C. 50 D. 80
Q.112 Although hydrogen resembles with the elements of group IA, IVA and VII but it is usually placed in
✓ A. group IA B. group IV A
C. group VII D. group VIII
Q.113 Which of the following technique is used to stop iron from corrosion:
A. Annealing ✓ B. Prilling
_______________________________________________________________________________________
C. Galvanizing D. Cracking
Q.114 Which of the following is an atomic number of a non-metal
A. 12 ✓ B. 35
C. 26 D. 40
Q.115 AgCI is soluble in
A. Aqua regia B. H2SO4
C. HCI D. NH3
✓ E. Mn3O4
Q.116 According to Mendeleev, the proper es of the elements are periodic func on of their
A. atomic numbers B. atomic volumes
✓ C. atomic masses D. atomic densi es
Q.117 The number of groups in the Periodic Table is
A. 6 B. 7
✓ C. 8 D. 9
Q.118 Who gave the concept of atomic number?
A. Newton ✓ B. Mosley
C. Dalton D. Newland
Q.119 Which one of the following is not ionic hydride
A. CsH B. LiH
✓ C. HCl D. NaH
Q.120 Hydra on energy depends upon:
A. Charge of ion B. Size of ion
✓ C. Charge to size ra o D. Heat change
Q.121 Turnbull's blue is a compound called?
A. Ferricyanide ✓ B. Ferrous ferricyanide
C. Ferrous cyanide D. Ferri-Ferro cyanide
Q.122 A radius smaller than parent atom is called:
A. Atomic radii B. Covalent radii
C. Aionic radii ✓ D. Ca on radii
Q.123 An element 'A' has atomic number 9 and atomic mass 19. Its ion will be represented as
A. A+3 ✓ B. A-1
-2
C. A D. A+1
Q.124 In a period, mel ng points of elements
A. increases B. decreases
C. remains constant ✓ D. first increases then decreases
Q.125 Elements having proper es in between metals and non-metals are called:
A. Halogens B. Alkali metals
C. alkaline earth metals ✓ D. Metalloids
Q.126 The binary compounds of oxygen are called:
A. hydrides B. haildes
✓ C. oxides D. nitrides
Q.127 Transi on metal sow maximum oxida on no of:
A. 7 ✓ B. 8
C. 4 D. 10
Q.128 An atom loses electrons to become:
A. Ion B. Radical
✓ C. Posi ve ion D. Nega ve ion
Q.129 Highest ioniza on poten al in a period is shown by
A. Alkali metals B. Transi on elements
✓ C. Halogen D. Alkaline earth metals
_______________________________________________________________________________________
Q.130 Bessemer converter is used in the manufacture of
A. Pig iron ✓ B. Steel
C. Wrought iron D. Cast iron
Q.131 Rare earth elements are
C. d-block elements ✓ D. f-block elements
Q.132 f-block elements are are also called:
A. non-transi on elements B. outer-transi on elements
C. number of elements ✓ D. inner transi on
Q.133 Which of the following statements about electron affinity of two elements is correct
A. carbon has greatest than oxygen B. sulphur has less than oxygen
C. iodine has greatest than chlorine ✓ D. bromine has less than chlorine
Q.134 The impuri es associated with ores are called:
✓ A. gangue B. flux
C. slag D. silicates
Q.135 Newland gave his law in the year:
A. 1829 ✓ B. 1864
C. 1871 D. 1913
Q.136 Highest oxida on state is shown by the element of configura on
A. 3d3,4S2 B. 3d5,4S1
✓ C. 3
3d ,4S 2
D. 3d6,4S2
Q.137 Blocks of elements give informa ons about the:
✓ A. Chemistry of elements B. Behaviour towards physical proper es
C. Atomic mass D. Mass number
A. Electron affinity is a measure of energy ✓ B. Ioniza on energy is a measure of energy
required to remove the electron asked by removing an electron
Electron affinity is a measure of energy D. Electron affinity is measure of energy released
C.
required to excite an electron by removing an electron
Q.139 In Hemoglobin iron has oxida on state
✓ A. +2 B. +3
C. Zero D. +4
Q.140 Horizontal rows a are called in periodic table:
A. Groups ✓ B. Period
C. Blocks D. Lanthanides
Q.141 Salts of _______ are colorless
A. copper ✓ B. zinc
C. Mn D. Cr
Q.142 The radius of Fluorine atom is .
A. 157 B. 136
C. 95 ✓ D. 72
Q.143 Hydrides used as catalysts generally are:
C. Intermediate ✓ D. Complex
Q.144 In a group, the ioniza on energy
A. increases ✓ B. decreases
C. remains constant D. first increases then decreases
Q.145 Misch mental is
A. An alloy of Aluminium B. A mixture of chromium and lead chromate
✓ C. An alloy of lanthanoid metals D. An alloy of copper
Q.146 In transi on metal complex metal ca on acts as:
_______________________________________________________________________________________
✓ A. Lewis acid B. Bronsted acid
C. Bronsted base D. none of above
Q.147 Which of the following element is responsible for oxida on of water to O2 in biological process?
A. Fe ✓ B. Mn
C. Cu D. Mo
Q.148 No of ligands a ached to central metal atom or ion is called
A. Valency B. Oxida on state
C. Co-ordina on No ✓ D. None
Q.149 The binary compounds of halogens are called:
✓ A. Hydrides B. Halides
C. Oxides D. Nitrides
Q.150 Transi on element firm complexes due to the par cipaion par ally filled:
A. f-orbital ✓ B. d-orbital
C. s-orbital D. p-orbital
Q.151 size of an atom is measured:
A. Directly ✓ B. Indirectly
C. May be D. May be directly or indirectly
Q.152 Carbon has high m.p in
✓ A. Diamond B. Graphite
C. Charcoal D. Coke
Q.153 Which of the following form intersi al compounds
A. Fe B. Co
C. Ni ✓ D. All of these
Q.154 High purity copper metal is obtained by
A. Carbon reduc on B. Hydrogen reduc on
✓ C. Electroly c reduc on D. Thermite reduc on
Q.155 Transi on metals mostly are
A. Diamagne c ✓ B. Paramagne c
C. Neither diamagne c nor paramagne c D. Both diamagne c and paramagne c
Q.156 Which of the following is not an element?
A. Graphite B. Diamond
✓ C. 22-Carat gold D. Rhombic sulphur
Q.157 Green vitriol is formed by
A. FeS2+ co ✓ B. FeS2+ H2O + O2
C. FeS2 + H2+ CO2 D. FeS2 + CO + CO2
Q.158 The protec on of steel by chrome pla ng is due to
A. Cathodic protec on B. Anodic protec on
✓ C. Covering of steel surface D. Forma on of alloy with iron
Q.159 The most stable oxida on state of Mn is:
A. 4 B. 5
C. 7 ✓ D. 2
Q.160 The valence shell of hydrogen is half filed like those of
✓ A. IV - A B. VIA
C. V-A D. VIIA
Q.161 Which of the following has highest oxida on poten al
A. Be ✓ B. Li
C. Na D. Ca
Q.162 Brass, bronze and German silver have one metal in common.This is
A. Zn ✓ B. Cu
C. Fe D. AI
_______________________________________________________________________________________
Q.163 Which diagram shows the varia on of metallic radius of group ll elements, Mg, Ca, Ba with increasing atomic number
✓
A. B.
C. D.
Q.164 Lanthanides and ac nides resemble in
A. Electronic configura on B. Ioniza on state
✓ C. Oxida on state D. Forma on of complexes
Q.165 Which one is non-metal?
A. Na B. Pb
✓ C. S D. Po
Q.166
A. P and S B. R and S
✓ C. Q and T D. R and T
Q.167 I-A & II-A groups halides are examples of halides:
C. Polymeric D. a,b, and c
Q.168 Which one is diamagne c in character
+2 +2
A. Zn B. Cd
C. Hg
2+
✓ D. All of these
A. Mel ng points of halogens decreases down ✓ B. Mel ng points of halogens increases down
the group the group
C. Mel ng points of halogens remain the same D. Mel ng points of halogens first increases and
throughout the group than decreases down the group
Q.170 The binary compounds of hydrogen are called:
✓ A. Hydrides B. Halides
Q.171 Which of the following set of elements is not transi on elements
A. Ti, Zn, Hf B. Cu, Ag, Au
✓ C. Ga, In, Tl D. Ni, Pt, Pd
Q.172 E.N. value of fluorine is:
A. 2.1 B. 2.5
C. 3.5 ✓ D. 4.0
Q.173 Which of the following is formed when KMnO4 undergoes reduc on in strongly basic medium
_______________________________________________________________________________________
A. MnO2 B. Mn2O7
✓ C. MnO 2-
4 D. Mn+2
Q.174 What is wrong about transi on metals?
✓ A. Diamagne c B. Paramagne c
C. Form complex D. Shows variable oxida on state.
Q.175 The electroposi ve elements from
A. Acidic oxides ✓ B. Basic oxides
C. Neutral oxides D. None
Q.176 The total number to d-block elements is:
✓ A. 110 B. 14
C. 40 D. 30
Q.177 Chromium compound widely used in the tanning of leather is
A. Cr2O3 B. CrO2CI2
C. CrCI3 ✓ D. K2SO4. (SO4)3.24H2O
Q.178 The periodic table the element with atomic number 30 is expected to be found in
A. IB B. IA
C. IIA ✓ D. IIB
Q.179 What is the nature of SO2?
A. basic ✓ B. strongly acidic
C. weakly acidic D. amphoteric
Q.180 Which of the following pairs of ions is colourless?
A. Ti3+ ,Cu2+ B. Co2+,Fe3+
✓ C. Sc3+ ,Zn2+ D. Ni2+ ,V3+
Q.181 The valency, ioniza on energy and electronga vity of elements are related to its
✓ A. atomic number B. proper es
C. atomic weight D. family group
Q.182 Keeping in view the size of atoms, which order is the correct one
A. Mg > Sr ✓ B. Ba > Mg
C. Lu > Ce D. Cl > l
Q.183 Transi on elements belong to block of elements:
A. "s" B. "p"
✓ C. "d" D. 'f"
Q.184 Binary compound of hydrogen are called:
A. Halides ✓ B. hydrides
Q.185 stainless steel contains:
A. 8% nickle ✓ B. 28% Ni
C. 18% Ni D. Ni is not present in steel
Q.186 Transi on elements have valence electrons in
A. s-orbital B. p-orbital
✓ C. d-orbital D. f-orbital
Q.187 The property, which is not characteris c of transi on metals, is
A. Variable oxida on states B. Forma on of coloured compounds
C. Tendency to form complexes ✓ D. Natural radioac vity
Q.188 Which of the group of element shows maximum binding energy?
A. III B B. IIB
C. IV ✓ D. VB
Q.189 Which of the following oxide is most basic
✓ A. Bi2O3 B. Al2O3
C. SeO2 D. Sb2O3
_______________________________________________________________________________________
Q.190 The strength of binding energy of Transi on elements depends upon:
✓ A. Number of unpaired electrons B. Number of neutrons
C. Number of electron pairs D. Number of protons
Q.191 An atom with high electro nega vity generally has
A. Tendency to form posi ve ions ✓ B. High ioniza on poten al
C. Large atomic size D. Low electron affinity
Q.192 Number of elements in the first period of the Periodic Table are
✓ A. two B. four
C. one D. eight
Q.193 Which statement is correct:
✓ A. Hydrogen resembles proper es with I- A, IV- B. Hydrogen resembles in proper es with II-A,
A and VII-A elements IV-A and V-A elements
C. Hydrogen resembles in proper es with II-A, D. Hydrogen resembles in proper es with II-A,
IV-A and VI-A elements III-A and VII-A elements
Q.194 The least stable ion amongst the following is
✓ A. Li- B. B-
C. Be- D. C-
Q.195 In the iso-electronic species, the ionic radii of N3-, O2-and F-are respec vely given by
A. 1.36, 1.40, 1.71 B. 1.36, 1.17, 1.40
✓ C. 1.71, 1.40, 1.36 D. 1.71, 1.36, 1.40
Q.196 According to the periodic law, the chemical proper es of the elements are periodic func ons of their
A. density ✓ B. atomic number
C. atomic mass D. mass number
Q.197 In a group form top to bo om, the hardness of alkali metals
A. Remains unchanged B. Increases
C. Decreases ✓ D. None
Q.198 Rus ng is speeded up in the presence of:
A. acid B. base
C. salts ✓ D. a and c
Q.199 IB elements are called
A. Halogens ✓ B. Coinage metals
C. Transuranic elements D. Rare earth elements
Q.200 Mark the correct statement
✓ A. Na+is smaller than Na atom B. Na+is larger than Na atom
-
C. Cl is smaller than Cl atom D. Cl-(ion)and Cl (atom) are equal in size
Q.201 (NH4)2Cr2O7 is used in some fireworks the green colored powder blowing in the air is
A. CrO3 ✓ B. Cr2O3
C. CrO(O2) D. Cr
Q.202 Elements in the same family have
A. Same atomic number B. Molecular wt same
✓ C. Same chemical proper es D. Same electronic configura on
Q.203 Element with higher oxida on state form oxides:
✓ A. Acidic B. Basic
C. Amphoteric D. Peroxides
Q.204 Which of the following is bidentate ligand?
A. Hydroxide ion B. Oxalate ion
✓ C. Ammonia D. EDTA
Q.205 The only property of elements which increase in periods as will as group usually is
A. Ioniza on energy ✓ B. Density
C. Electron affinity D. Shielding effect
Q.206 The ion which forms highly soluble hydroxide in water is
_______________________________________________________________________________________
✓ A. K+ B. Zn2+
C. Al3+ D. Ca2+
Q.207 Amongst the following wins which has highest para magne sm is
A. [Cr(H2O)6]3+ B. [Fe(H2O)6]2+
✓ C. [Cu(H2O)6]2+ D. [Zn(H2O)6]2+
Q.208 The radius of fluoride ion is
A. 157 ✓ B. 136
C. 95 D. 72
Q.209 Coordina on number of pt in Pt in [RtC(NO2)(NH3)4)]2- is
A. 2- B. 4
C. 1 ✓ D. 6
Q.210 The number of unpaired electrons in Fe3+ (Z = 26) are
✓ A. 5 B. 6
C. 3 D. 4
Q.211 Periodic table has elements of nature.
A. Metals B. Non-metals
C. Metalloids ✓ D. a,b,c all
Q.212 German silver does not contains
A. Cu B. Zn
C. Ni ✓ D. Mn
Q.213 Maximum mel ng point
A. Magnesium B. Nitrogen
C. Fluorine ✓ D. Carbon
Q.214 Doberiner arranged the similar elements into
A. Pairs ✓ B. Triads
C. Triplets D. Rows
Q.215 Which of the following is non-typical transi on element
A. Sc B. Zn
C. Cd ✓ D. All of these
Q.216 What type of reac on is involved in most corrosion processes
A. Oxida on B. Reduc on
✓ C. Oxida on-reduc on D. Neutraliza on
Q.217 Paramagne c behaviour of substance is measured by
A. Analy cal balance ✓ B. Guoy s balance
C. Electrical balance D. Single beam balance
Q.218 All facts of chemistry must be in simple logical pa erns because chemistry is a subject:
A. Simple ✓ B. Complex
C. Uni-understandable D. Easy
Q.219 In the metallurgy of iron when limestone is added to the blast furnace the calcium ion ends up in:
✓ A. Slag B. Metalic Calcim
C. Gangue D. Calcium Carbonate
Q.220 The number of unpaired electrons in Mn2+ is
✓ A. 5 B. 4
C. 3 D. 2
Q.221 Short periods contain elements:
A. 2 ✓ B. 8
C. 18 D. 32
Q.222 The %age of C indifferent types of iron products is in the order of:
A. cast iron> wrought iron > steel B. wrought iron > steel > cast iron
✓ C. cast iron > steel > wrought iron D. cast iron = steel > wrought iron
_______________________________________________________________________________________
Q.223 Which of the following is not correct about transi on metals?
A. Their mel ng and boiling points are high B. Their compounds are generally coloured
C. They can form ionic or covalent compounds ✓ D. They do not exhibit variable valency
Q.224 Law of octaves was given by:
✓ C. Newland D. Mendeleev
Q.225 Which of the following elements does not show variable oxida on states?
A. Copper B. Iron
✓ C. Zinc D. Titanium
Q.226 Which of the element are called non-typical transi on elements
A. Ti B. Fe
C. Cr ✓ D. Cd
Q.227 All ligands are
A. Lewis acids B. Neutral
✓ C. Lewis bases D. None of these
Q.228 Which of the following metals is some mes found in na ve in nature?
A. AI ✓ B. Cu
C. Fe D. Mg
Q.229 The electrons present in the penul mate orbit of coinage metal atoms are
A. 8 ✓ B. 18
C. 2 D. 32
Q.230 The radius of a nega ve ion is called:
A. Atomic radii B. Covalent radii
✓ C. Aionic radii D. Ca on radii
Q.231 The size of species l, l+and l-decreases in the order
A. l +> l - > l ✓ B. l- > l > l +
C. l - > l +> l D. l > l +> l -
Q.232 Which of the following proper es increases upto the middle of the period and then decreases
A. Ioniza on energy B. Atomic radii
✓ C. Mel ng and boiling point D. Atomic volume
Q.233 The highest transi on metal is:
A. tanium B. zinc
✓ C. scandium D. Iilhium
Q.234 Dobriener's was a scien st:
A. Russian ✓ B. German
C. English D. French
Q.235 While moving down the group in the periodic table, which of the following will increase
A. Number of valence electrons B. Electronega vity
✓ C. Atomic volume D. Non-metallic character
Q.236 The elements of sub-group A are called
A. transi on elements ✓ B. main elements
C. typical elements D. rare earth elements
Q.237 Which of the following is obtained when Fe reacts with dil. HNO3?
A. N 2O B. NO
C. NO2 ✓ D. None of these
Q.238 Which of the following is a anon-typeical transi on elements?
A. Cr B. Mn
✓ C. Zn D. Fe
Q.239 Atomic radius changes from top to bo om in a group:
_______________________________________________________________________________________
C. Remains same D. Some mes increases & decreases
Q.240 The coinage metals are
A. Ni, Pd, Pt ✓ B. Cu, Ag, Au
C. Zn, Al, Pb D. Fe, Si, Sn
Q.241 The first ioniza on energy of elements varies
A. increases in period and group ✓ B. increase in a period and decrease down the
group
C. decreases in period and group D. decreases in a period and increases down the
group
Q.242 Which statement is correct:
A. All the metals are good conductor of B. All the metals are good conductor of heat
electricity
C. All the metals form posi ve ions
✓ D. All the metals form acidic oxides
Q.243 Atomic radius increases in a group because of increase in:
A. Atomic number B. Nuclear charge
C. shielding effect number ✓ D. shielding effect and proton.
Q.244 The period tables contains elements in ver cal column. These ver cal column are called
✓ A. groups B. periods
C. blocks D. sub groups
Q.245 Which has the largest radius?
A. CO3+ B. Mn3+
C. Fe 3+ ✓ D. Cr3+
Q.246 The following pair represents elements of the same group
A. A = 17 and A = 38 B. A = 20 and A = 40
✓ C. A = 17 and A = 53 D. A = 11 and A = 33
Q.247 Sodium belongs to block of periodic table:
✓ A. s-block B. p-block
C. d-block D. f-block
Q.248 Which is exhibited by transi on metal compounds
A. Para magne sm B. Diamagne sm
C. Ferromagne sm ✓ D. All
Q.249 The radius of a posi ve ion is called:
A. atomic radii B. Covalent radii
C. Ionic radii ✓ D. Ca on radii
Q.250 Which of the form of iron is the hardest?
✓ A. Pig iron B. Wrought iron
C. High carbon steel D. Mild steel
Q.251 Transi on elements are:
A. insula on B. good conductors
C. bad conductors ✓ D. none of these
Q.252 The total number of inner transi on elements in the periodic table is
A. 10 B. 14
✓ C. 28 D. 30
A. All Ianthanides are present in the same group B. All halogens are present in the same period
✓ C. All the alkali metals are present in the same D. All the nobles gases are present in the same
group period
Q.254 Newland's gave law:
A. Triad's law ✓ B. Octaves law
C. Periodic law D. Modern periodic
Q.255 The oxida on state of chromium in the final product formed by the reac on between KI nad acidified K2 Cr2 O7 solu on is
A. +4 B. +2
_______________________________________________________________________________________
C. +6 ✓ D. +3
Q.256 From 39Y to 48Cdare called
A. Transi on elements B. Outer transi on elements
C. Inner transi on elements ✓ D. 2nd transi on series
Q.257 Lanthanides and Ac nides belong to block of elements:
A. "s" B. "p"
C. "d" ✓ D. "f"
Q.258 Substance which is added to remove the impuni es is called as
A. Ore B. Slog
✓ C. Flux D. Gangue
Q.259 Which element should have the greatest value for electronega vity when combined with hydrogen
A. Na B. Si
C. S ✓ D. Cl
Q.260 Law of triads was given by:
A. Al-Razi ✓ B. Dobriener
C. Newland D. Mendeleev
Q.261 Amongst the following inden fy the specie with an atom in +6 oxida on state
A. [MnO-4] B. [Cr(CN)6]3-
✓ C. CrO2CI2 D. NiF2-6
Q.262 The elements of f-block are also known as
✓ A. inner-transi on B. outer transi on
C. normal elements D. alkaline earth metals
Q.263 The radius of Na-atom is (in pm).
✓ A. 157 B. 136
C. 95 D. 72
Q.264 The element with atomic number 13 belongs to ______ group and ______ period
A. IA, third B. IIIA, second
✓ C. IIA, third D. IVA, second
Q.265 For the representa ve elements from le to right across a period in the Periodic Table, the electron effinity of the
atom generally
✓ A. increases B. remains constant
C. decreases D. not clear
Q.266 Sub-group -A in periodic table consists of elements.
A. Halogens B. Alkali metals
C. Non-typical ✓ D. Typical or normal
Q.267 Which is the transi on element among the following
A. B B. Al
✓ C. Cu D. Cs
Q.268 Rus ng of iron is catalysed by
A. Fe B. O2
C. Zn ✓ D. H+
Q.269 What will be the external pressure at which water may boil at 120∘C?
✓ A. 1489 mmr of Hg B. 790 mm of Hg
C. 700 mm of Hg D. 100 mm of gH
Q.270 Ionic hydrides are generally
A. liquid at room temperature B. Good electrical conductors
✓ C. Good reducing agents D. Easily reduced
Q.271 The outer most electronic configura on of the most electronega ve element is
A. ns2np3 B. ns2np4
✓ C. 2
ns np 5
D. ns2np6
_______________________________________________________________________________________
Q.272 Which of the following pairs has both members from the same group
✓ A. Mg, Ba B. Mg, Na
C. Mg, Cu D. Mg, Cl
Q.273 Period 4 & 5 has elements:
A. 2 B. 8
✓ C. 18 D. 32
Q.274 Addi on of iron fillings to CuSO4 solu on caused precipita on of Cu owing to the
✓ A. Reduc on of Cu2+ B. Oxida on of Cu2+
C. Reduc on of Fe D. Reduc on of Fe3+
Q.275 Mendeleev was a scien st:
✓ A. Russian B. German
Q.276 In which of the following process energy is released
A. B.
✓
C. D.
Q.277 A pair of elements in the same family in the periodic classifica on is
A. Cl and C B. Ca and Al
C. N and Ne ✓ D. Na and K
Q.278 Period number of 6 contains elements in it:
A. 2 B. 8
C. 18 ✓ D. 32
Q.279 The classify the statements, Newland gave the idea of
✓ A. octaves B. triads
C. atomic volume D. atomic mass
Q.280 The fourth period contains elements
A. 8 B. 16
✓ C. 18 D. 32
Q.281 Which one is an organometallic compound?
A. Lithium acetate B. Lithium dimethylamide
C. Lithium methoxide ✓ D. Methyl lithium
Q.282 Which of the following is a member of d-block
✓ A. Zn B. Al
C. B D. Br
Q.283 The most acidic among the following is
✓ A. P 2O 3 B. Sb2O3
C. B 2O 3 D. As2O3
Q.284 A transi on metal complex can be recognized by various terms which
is not the proper term
A. central metal ion B. co-ordina on number
C. ligand ✓ D. geometry of complex
Q.285 In the modern Periodic Table the elements are placed in the ascending order of their
A. atomic masses B. mel ng points
C. boiling points ✓ D. atomic numbers
Q.286 Mark the incorrect statement:
A. Metallic character increases down the group B. Metallic character increases along a period
✓ C. Metallic character decreases along a period D. Metallic character remains the same down
the group
Q.287 The compound which gives oxygen on moderate hea ng is
A. Zinc oxide ✓ B. Mercuric oxide
_______________________________________________________________________________________
C. Aluminium oxide D. Ferric oxide
Q.288 Keeping in view the size of a atom, which order is the correct one:
A. Mg > Sr ✓ B. Ba > Mg
C. Lu > Ce D. CI > I
Q.289 Mercury is the only metal which is liquid at 0°C this is due to its
✓ A. Very high ioniza on energy and weak B. Low ioniza on poten al
metallic bond
C. High atomic weight
D. High vapour pressure
Q.290 From le to right, atomic radii of transi on elements
C. Remains same D. None of the above
Q.291 Ver cal columns in periodic table are called.
✓ A. Groups B. Periods
C. Blocks D. Lanthanides
Q.292 Periodic law was given by:
Q.293 Which one of the following species is iso-electronic with Ca+2
A. Sr2+ ✓ B. Ar
C. Na D. Mg+2
Q.294 The structure of complex hydrides is
✓ A. Tetrahedral B. Trigonal
C. Octahedral D. Square planar
Q.295 Ioniza on poten al increases in moving from le to right in a period
A. because nuclear charge increases B. because atomic size decreases
✓ C. both a and b D. because atomic size increases
Q.296 The purest form of iron is:
A. hamae te B. magne te
C. cast iron ✓ D. wrought iron
Q.297 Ioniza on energy of sodium is (kj/mol)
A. 513 B. 738
✓ C. 1451 D. 1480
Q.298 The correct order of 2nd I, P. of C, N, O and F is
✓ A. O>F>N>C B. O>N>F>C
C. C>N>O>F D. F>O>N>C
Q.299 Which of the following elements does not belong to first transi on series?
A. Fe B. Cu
C. V ✓ D. Ag
Q.300 In the long form of periodic table, the elements having lowest ioniza on poten al are present in
✓ A. I Group B. IV Group
C. VII Group D. Zero Group
Q.301 In Bessemer process steel is prepared by using
✓ A. Cast Iron B. Wrought iron
C. Steel D. All of these
Q.302 Periodic table provides a basic framework to study the periodic behavior of:
A. Physical proper es of elements B. Chemical proper es of elements
C. Physical proper es of compounds ✓ D. Periodic table provides basic informa on
about proper es
Q.303 Modern periodic table is based upon periodic func on:
A. Atomic mass B. Mass number
C. Nuclide number ✓ D. Atomic number
_______________________________________________________________________________________
Q.304 The element which shows maximum electrical conduc vity among the following is
A. Na B. Mg
✓ C. Al D. Si
Q.305 The correct order of radii is
A. Na < Li < K < Cs B. Cr < Mn < Fe < Ni
C. N < Be < B < Li ✓ D. S < P < Si < Al
Q.306 Which property of the first six elements of period 3 (sodium to sulphur) con nuously increases numerically
A. Atomic radius B. First ioniza on energy
✓ C. Maximum oxida on number in oxide D. Mel ng point
Q.307 Which of the gas cannot be drived over conc. H2SO4
A. SO2 B. N2
✓ C. NH3 D. H2
Q.308 Which of the following is less basic
A. MnO B. MnO2
C. Mn2O2 ✓ D. Mn2O7
Q.309 Scien sts made contribu ons in the field of designing periodic table:
A. Newland B. Dobriener
C. Mendeleev & Mosley ✓ D. All of these
Q.310 In the extrac on of iron in the blast furnace, the reducing agent for the ore is:
A. Carbon B. Carbon dioxide
✓ C. Carbon monoxide D. Silica
Q.311 An element in +3 oxida on state has the electronic configura on (Ar) 3d3, its atomic number is
✓ A. 24 B. 23
C. 22 D. 21
Q.312 Which of the following is a typical transi on metal?
A. Sc B. Y
C. Ra ✓ D. Co
Q.313 Which element is likely to have an electronega vity similar to that of aluminium?
A. barium ✓ B. beryllium
C. magnesium D. stron um
Q.314 Period 1 has elements:
✓ A. 2 B. 8
C. 18 D. 32
Q.315 All 3d series elements variable oxida on states the one show by all 3d elements:
✓ A. 2 B. 3
C. 4 D. 5
Q.316 The most nonmetallic out of the following is
A. Be ✓ B. B
C. Mg D. Al
Q.317 What is the nature of Al2O3?
A. acidic B. basic
✓ C. amphoteric D. neutral
Q.318 The group number and valency has no rela on in
✓ A. 0 group B. I group
C. III group D. VII group
Q.319 Electron affinity value is expressed in figures:
C. some mes Posi ve D. some mes nega ve
Q.320 The color of transi on metal complexes is due to:
✓ A. d-d transi on of electrons elements B. loss of electrons
_______________________________________________________________________________________
C. ioniza on D. loss of electrons
Q.321 Which of the following has the maximum number of unpaired d-electrons?
A. Zn ✓ B. Fe2+
C. Ni3+ D. Cu+
Q.322 The total number of rare earth elements is
A. 8 B. 32
✓ C. 14 D. 10
Q.323 The most dis nc ve character among the elements is their division into
✓ A. metals and non-metals B. solids, liquids and gases
C. atoms and molecules D. ac ve and inac ve elements
Q.324 Which metal is in liquid state at room temperature?
A. Na B. Mg
✓ C. Hg D. Au
Q.325 Which of the following has maximum first ioniza on poten al
A. Al B. Si
✓ C. P D. Mg
Q.326 Which of the following is isoelectronic with carbon atom
A. Na+ B. Al+3
C. O 2- ✓ D. N+
Q.327 The elements of group IA are called
A. chalocogens B. halogens
✓ C. alkali metals D. alkaline earth metals
Q.328 Which one the following has the highest atomic volume
A. Rn B. Ra
✓ C. Fr D. Hf
Q.329 Which of the following element shows minimum mel ng and boiling point
A. Cr B. Sc
C. Ti ✓ D. Zn
Q.330 Period 6 has elements:
A. 2 B. 8
C. 18 ✓ D. 32
Q.331 Many proper es of an element and its compound can be predicted from the posi on of the element in the periodic
table. What property could not be predicted in this way
A. The acidic or basic nature of its oxides B. The formula of its oxide
C. The charge on its ions ✓ D. The number of isotopes it has
Q.332 Oxida on state of metal in metal carbonyI is
✓ A. Zero B. +2
C. +3 D. Variable
Q.333 The chloride of element Q is hydrolysed by water to form an acidic solu on and its oxide reacts with acid to form a
salt.
What could be the element Q?
A. magnesium ✓ B. aluminium
C. silicon D. phosphorus
Q.334 Which of the following oxides is unlikely to dissolve in aqueous sodium hydroxide?
A. Al2O3 ✓ B. MgO
C. SO2 D. SIO2
Q.335 Steam is passed over heated magnesium to give compound X and hydrogen.
What is not a property of compound X?
A. it has a high mel ng point B. it is a basic oxide
C. it is a white solid ✓ D. it is very soluble is water
_______________________________________________________________________________________
Q.336 Chemically philosophers wool is
✓ A. ZnO B. BaO
C. HgCI2 D. Hg2CI2
Q.337 Bell metal is an alloy of
A. Cu, Zn, and Sn B. Cu, Zn and Ni
C. Cu and Zn ✓ D. Cu and Sn
Q.338 Grada on in proper es in the periods of periodic Tables are due to change in
A. atomic weight B. the number of electrons
✓ C. number of protons D. electronic configura on
Q.339 The hydra on energy is the heat evolved when one mole of gaseous ion is dissolved in water. The hydra on energy of
an ion
✓ A. increases with increase of charge to mass B. decreases with increase of charge to mass
ra o ra o
C. depends on sign of charge +ve or -ve D. depends upon the solvent
Q.340 The equivalent weight of KMnO4 (formula weight = M) when it is used as an oxidant in neutral medium is
A. M B. M/2
✓ C. M/3 D. M/5
Q.341 On descending a group, electroposi ve character of elements
C. Remains same D. Suddenly becomes zero
Q.342 Hydrides are:
C. Intermediate ✓ D. All of above
Q.343 The element is the III group and III period in the periodic table is
A. Carbon B. Phosphorus
C. Cobalt ✓ D. Aluminium
Q.344 The element not known ll Mendleev tabulated his periodic table:
A. Systema c study ✓ B. Grouping of alkali metals with coinage
C. Predica on of unknown D. Introduc on of elements groups & periods
Q.345 Which has maximum number of unpaired electrons
A. Mg+2 B. Ti3+
C. V+3 ✓ D. Fe2+
Q.346 In reac on 2KMnO4+3H2SO4+5H2C2O4→ K2SO4+2MnSO4+10A+8B, what are A and B
✓ A. CO2+ H2O B. SO2+ H2O
C. CO + H2O D. H 2S + H 2O
Q.347 Which of the following is not true for metalloids?
A. they are borderline elements that exhibit both B. they usually act as electron donors with non-
metallic and non-metallic proper es to some metals and as electron acceptors with metals
extent C. some of these elements are boron,silicon and
germanium
✓ D. they are good conductors of heat and
electricity
Q.348 The periodic func on of proper es of elements is their atomic number:
A. Al-Razi ✓ B. Mosley
C. Newland D. Mendeleev
Q.349 Rus ng of iron is catalyzed by
A. O2 B. Zn
C. AI ✓ D. H+
Q.350 Electronic configura on of the hydrogen is in agreement to the group of periodic table:
✓ A. I-A B. II-A
C. IV-A D. V-A
Q.351 Each period in the periodic table starts with a sub shell of a new shell and ends with
A. Small sub shell B. Different sub shell of the same shell
_______________________________________________________________________________________
C. The next higher shell ✓ D. p-sub shell of the same shell
Q.352 First of all, idea of groups and rows was introduced by:
Q.353 Which group elements are the least metallic in nature:
A. IV-A B. V-A
C. VI-A ✓ D. VII-A
Q.354 Second ioniza on energy is than first ioniza on energy.
A. Less B. Least
C. same ✓ D. Greater
Q.355 Most common oxida on states shown by cerium are
A. +2, +4 ✓ B. +3, +4
C. +3, +5 D. +2, +3
Q.356 An element of the third period (Na to S) is heated in chlorine. The product is purified and then added to water. The
resul ng solu on is found to be neutral. What is the element?
✓ A. Sodium B. aluminium
C. silicon D. phosphorus
Q.357 Which element belongs to 4d series?
A. Ti B. Na
C. Mn ✓ D. Te
Q.358 12: Na2O is
A. Acidic ✓ B. Basic
C. Neutral D. Amphoteric
Q.359 Cathodic protec on of iron involves the used of:
✓ A. Mg B. An
C. As
D. copper
Q.360 Which of the following pairs has elements containing the same number of electrons in the outer most orbit
A. N, O B. Na, Cl
✓ C. As, Bi D. Pb, Sb
Q.361 Bronze is an alloy of:
✓ A. 90% Cu + 10% Sn B. 90% Cu + 10% Fe
C. 90% Sn + 10% Cu D. none of these
Q.362 In an octahedral crystal field spli ng the number of orbitals pushed down in energy is
✓ A. 3 B. 2
C. 5 D. Zero
Q.363 The periodic func on of proper es of elements is their atomic mass:
Q.364 Proper es of metals are:
A. Malleable and duc le B. From basic oxides
C. Tarnish in air ✓ D. All are true
Q.365 Besides Zn and Cu, German silver contains the metal
A. Sn B. Ag
✓ C. Ni D. Mg
Q.366 The fourteen elements following ac nium are known as
A. Ianthanones B. Ianthanides
C. rare earths ✓ D. ac nides
Q.367 Element A of group V A combines with an element B of group VI A. the resul ng compound may have formula
✓ A. A 2B 2 B. A 3B 2
C. A 5B 6 D. A 6B 5
_______________________________________________________________________________________
Q.368 The percentage of carbon in medium carbon steel is:
A. 0.7-1.5 B. 0.1-0.2
✓ C. 0.2-0.7 D. 1.6-2.00
Q.369 AgCI precipitate dissolves in NH4OH due to the forma on of
A. [Ag(NH4)2]CI B. [Ag(NH4)4]CI
C. [Ag(NH3)2]OH ✓ D. [Ag(NG3)2]CI
Q.370 Which is the only non-metal is liquid state?
A. Chlorine B. Iodine
✓ C. Bromin D. Silicon
Q.371 Mendeleev gave his periodic law in the year:
A. 1829 B. 1864
✓ C. 1871 D. 1913
Q.372 All the elements belonging to the 2nd period are
✓ A. Normal elements B. Transi on elements
C. Stable elements D. Halogens
Q.373 Dobriener's arranged elements in group of:
A. Duplets B. Triads
C. Pentaves ✓ D. Hexaves
Q.374 Sub-group B in periodic table consists of elements:
A. Halogens B. alkali metals
✓ C. Transi on elements D. typical or normal
Q.375 Which of the following compounds gives red precipitate with AgNO3?
A. KI ✓ B. K2CrO4
C. Co and Mn D. Mn and Ni
Q.376 The number of elements in the first, second and third period is
A. 2, 8 , 18 B. 8, 2 , 18
C. 2, 18 , 8 ✓ D. 2, 8 , 8
Q.377 Iron is protected by coa ng it with a thin layer of:
A. Cu B. Pb
✓ C. Zn D. Mg
Q.378 NaBH4and LiAIH4are
A. ionic hydrides B. Covalent hydrides
C. Interposal hydrides ✓ D. Complex hydrides
Q.379 Most of the known elements are
✓ A. Metals B. Non metals
C. Inner transi on metals D. Transi on metals
Q.380 The iron obtained from blast furnace is
✓ A. Pig iron B. Wrought ion
C. So iron D. Steel
Q.381 Mendeleev gave his periodic law in the year:
A. 1829 B. 1864
✓ C. 1871 D. 1913
Q.382 Chemical composi on of natural chromite is
✓ A. FeO. Cr2O3 B. K2CrO4
C. Fe2O3 D. Fe2O3 H2O
Q.383 Hydrogen is placed at the top of group:
✓ A. I-A B. II-A
C. IV-A D. VI-A
Q.384 In the extrac on of iron, slag is produced which is
A. CO B. FeSiO3
_______________________________________________________________________________________
C. MgSiO3 ✓ D. CaSiO3
Q.385 Formula of fuming sulphuric acid is
A. H2SO4 B. H2SO3
✓ C. H2SO4+ SO3 D. None
Q.386 Blow holes of steel can be removed by adding
A. C B. Ni
C. Sand ✓ D. Spiegeleisen
Q.387 Which of the following elements should be the least metallic in character
A. Rb B. In
C. Te ✓ D. I
Q.388 The IA elements are called
A. alkaline earth metal ✓ B. alkali metals
C. the halogens D. the inert gases
Q.389 Which has highest 1st I.E?
A. Br B. Cl
✓ C. F D. I
Q.390 Group I-A & II -A belongs to block of elements:
✓ A. "s" B. "p"
C. "d" D. "f"
_______________________________________________________________________________________
10 Groups
Q.1 Semi conductors have been used in photoelectric cells and in solar ba eries.which statement about their conductance
is not true
✓ A. their resistance increased with increasing B. their resistance decreases with intensity of
temperature light
C. their resistance decreases with increasing D. semi conducts have different resistance under
temperature different circumstances
Q.2 Which is true calcium or its compounds compared with the corresponding statements for magnesium?
✓ A. calcium has a smaller atomic radius B. calcium oxide reacts less vigorously with
water
C. calcium reacts more vigorously with water D. the sum of the first two ionisa on energies of
calcium is greater
Q.3 Which of the element is not an alkaline earth metal
A. beryllium B. stron um
C. barium ✓ D. caseium
Q.4 Chlorate ion is the
A. Oxidizing agent B. Reducing agent
✓ C. Bleaching agent D. All of them
Q.5 Hydrolysis of borax yields solu on.
C. Amphoteirc D. Neutral
Q.6 Which of the following has linear geometry?
A. alkane B. alkene
✓ C. alkyne D. benzene
Q.7 Colour of aluminum nitride precipitate is
✓ A. White B. Blue
C. Intense green D. Yellow
Q.8 TEL is used in petrol ot increase octane number. 1 ml TEL per liter of petrol is sufficient the scavenge used in this case
is:
A. TML B. ethane
✓ C. ethlenedibromide D. iodoform
Q.9 100 grams of water dissolves borax in it at 100ºC
A. 1 gm B. 2 gm
C. 3 gm ✓ D. 99.3 gm
Q.10 Hf is stored in
A. Glass vessel B. Bo les made up to gu a parcha
C. Lead vessel ✓ D. Nickle vessel
Q.11 As metallic radii increases in Group II, density
C. Remains same D. Depends upon elements its reacts with
Q.12 Which salt is used for the treatment of hyperacidity in stomach?
A. NaCl B. KCl
✓ C. Mg(OH)2 D. Na2CO3
Q.13 Which is litharge or massicot?
✓ A. PbO B. Pb2O
_______________________________________________________________________________________
C. Pb3O4 D. PbO2
Q.14 HNO2 is only known on the form of its salts because
A. It is a dibasic B. It is a strong oxidizing agent
C. It is a reducing agnet ✓ D. It is decomposed as soon as it is formed
Q.15 Fossil fuels are sources of organic compounds. Which one is not fossil fuel:
A. petroleum B. coal
C. natural gas ✓ D. wood
Q.16 Which is not the characteris c property of the 4 halogens (F, Cl, Br, I)
A. all are very reac ve non-metals B. all exist as diatomic molecules
C. all have seven electrons in their outer most ✓ D. all are gases at room temperature
shell (valence shell)
Q.17 Ozonolysis of ethene produces:
✓ A. aldehyde B. ketone
C. mixture of a and b D. ether
Q.18 Vola lity of halogens indicate the
A. Difficulty with which they react ✓ B. Ease with which they evaporate
C. Density of halogens D. All of above
Q.19 With increase in atomic number the basic character of a s block elements
✓ A. increases B. decreases
C. first increased and then decreases D. no change
Q.20 Hydrated variety of quartz is called
A. Silica ✓ B. Opal
C. Smoky quartz D. rose quartz
Q.21 The halogen which is solid at room temperature is
A. F B. Cl
C. Br ✓ D. I
Q.22 Isomerism which is only found in alkenes?
A. metamerism B. func onal group isomerism
C. posi on isomerism ✓ D. cls-trans isomerism
Q.23 One of form of calcium carbonate which is used to make expensive decora on les is
A. Limestone B. Calcium chloride
✓ C. Marble D. None of these
Q.24 Deca hydrated crystals of borax are obtained above:
A. Room temperature B. 0ºC
C. 28ºC ✓ D. 62ºC
Q.25 Which of the following has highest boiling point
A. S B. Se
✓ C. Te D. Po
Q.26 The most abundant element in the earth's crust is
✓ A. silicon B. aluminium
C. iron D. oxygen
Q.27 Sulphur will have highest Electronega vety in
A. S2CI2 B. SCI2
✓ C. SCI4 D. Same
Q.28 The unexpected lower heat of hydrogena on of benzene is due to:
✓ A. dilocaliza on of electrons B. lower stability
C. a and b D. its high electrophilicity
Q.29 The vital force theory was proposed by:
A. Wohler B. Berthelot
✓ C. Berzelius D. Kolbe
_______________________________________________________________________________________
Q.30 Solubility of orthoboric acid in water at 107oC
A. 17% B. 27%
✓ C. 37% D. 47%
Q.31 Known oxida on state of Xenon in its compound range from
✓ A. +2 to +8 B. +2 to +6
C. +4 to +6 D. +4 to +8
Q.32 Chlorine can be manufactured from
A. Electrolysis of fused NaCl B. Electrolysis of brine
C. Electrolysis of bleaching powder ✓ D. All of these
Q.33 Metallic ethynides are formed y the reac on of _________ with ammonical silver nitrate or ammonical cuprous
chloride.
A. ethene ✓ B. acetylene
C. benzene D. ethanoic acid
Q.34 A double bond consists of:
A. two sigma bonds ✓ B. one sigma and one pi bond
C. one sigma and two pi bonds D. two pi bonds
Q.35 Metals are more reac ve with oxygen
A. Across periodic table B. Across period 2
✓ C. Down group II D. Up group II
Q.36 Boric acid can not be used:
A. As an sep c in medicine B. For washing eyes
✓ C. In soda bo les D. For enamels and glazes
Q.37 Geometrical isomers differ in:
A. Posi on of func onal group B. Posi on of atoms
✓ C. Special arrangement of atoms D. Length of carbon chain
Q.38 Mel ng point of magnesium oxide is higher than
A. 2010°C ✓ B. 2800°C
C. 2000°C D. 2011°C
Q.39 Size on atom can be described with help of
A. Atomic radius ✓ B. Metallic radius
C. Covelnt radius D. Van der Wall's radius
Q.40 When hea ng stron um, compounds gives off flames of colors
✓ A. Red B. Green
C. Blue D. White
Q.41 Which one of the following is a hetrocyclic compound?
A. cyclohexanol B. phenol
✓ C. pyridine D. anthrancene
Q.42 Which halogen occurs naturally in a posi ve oxida on state?
A. fluorine B. chlorine
C. bromine ✓ D. iodine
Q.43 about 25% of earth crust mass is made up of element.
A. Carbon ✓ B. Silicon
C. Germanium D. Tin
Q.44 CaC2on hydrolysis form
A. CH4 B. C 2H 4
✓ C. C 2H 2 D. C 6H 6
Q.45 Corrundam is ore of:
A. Li B. Be
C. B ✓ D. Al
Q.46 Chemical formula of heavy spar ___________
_______________________________________________________________________________________
A. CaSO4 ✓ B. BaSO4
C. MgSO4 D. Ca(NO3)2
Q.47 The halogens exist as halides. Which is not the common place where they are found
A. in sea B. in lakes
✓ C. in the atmosphere as HX D. as salt beds in ponds
Q.48 Metal used in Borax bead test is:
A. Al B. Na
C. Co ✓ D. Pt
Q.49 Ammonium is injected at the depth of about
A. 1 inch B. 2 inches
C. 4 inches ✓ D. 6 inches
Q.50 Reac ons of 2-Butene with HBr gives only one product because:
✓ A. the molecule is symmetrical around C-C B. the molecule is asymmetrical around c-c bond
bond
C. it is more stable
D. it is less stable
Q.51 Which of the following are electroposi ve in nature?
C. halogens ✓ D. alkali and alkaline of Epson salt is
Q.52 Barium metal is highly reac ve if it is stored in
A. Gas ✓ B. Oil
C. Water D. Petrol
Q.53 The method of conver ng high boiling hydrocarbons onto low boiling hydrocarbons is called:
A. polymerizaiton ✓ B. cracking
C. condensa on D. isomeriza on
Q.54 N atom of HNO2 and rINO3 are hybridized
✓ A. Sp2& Sp2 B. Sp , Sp2
C. Sp3 , Sp3 D. Sp2 , Sp3
Q.55 A difference in Boron and rest of elements of group III-A.
A. Three valence electrons B. ns2p1configura on
✓ C. Molecular addi on compound D. Electron deficient
Q.56 Tincal is a mineral of:
A. AI ✓ B. B
C. Si D. C
Q.57 The chemist who synthesized urea from ammonium cyanate was:
A. Bezelius B. Kolbe
✓ C. Wholer D. Lavisier
Q.58 Electrons are least ghtly bound in
A. Iodine B. Fluorine
C. Bromine ✓ D. Asta ne
Q.59 Electrons are least ghtly bound in
A. Iodine B. Fluorine
C. Bromine ✓ D. Astan ne
Q.60 Ioniza on energies of noble gases are very high because of their
A. Vander Waal's forces B. Large size
C. No electron affinity ✓ D. Closed shell
Q.61 Bromoethane can be converted to ethene by
A. reac on with aq KOH ✓ B. reac on with alcoholic KOH
C. oxida on D. reduc on
Q.62 Chief ore of aluminium is:
A. Na3AIF6 ✓ B. Al2O32H2O
_______________________________________________________________________________________
C. Al2O3 D. Al2O3.H2O
Q.63 Gypsum is a common mineral of
A. magnesium B. stron um
✓ C. calcium D. barium
Q.64 If water reacts with calcium oxide it will produce
✓ A. Calcium hydroxides B. Calcium oxides
C. Calcium chloride D. All of them
Q.65 Which one of the following is the heterocyclic compound:
A. Anisole Pyrene B. Phenol
✓ C. Thiophene D. Aniline
Q.66 Mostly widely used nitrogenous fer lizer in Pakistan is
A. NH3 ✓ B. Urea
C. NH4NO3 D. (NH4)2 SO4
Q.67 Which is formed when phosphorous is heated with conc HNO3
A. NO ✓ B. NO2
C. N 2O 3 D. N 2O 5
Q.68 Which is the strongest acid?
A. HCIO B. HCIO2
C. HCIO3 ✓ D. HCIO4
Q.69 Lime, CaO, is used to reduce the acidity of soil, and ammonium sulphate is a nitrogenous fer liser.
What cannot they be used in a mixed form?
A. the dry mixture is explosive B. CaSO4, formed on mixing, causes hard water
✓ C. when damped, ammonia is given off D. sulphuric acid will form
Q.70 In the oxy acid of chlorine, HCIO3, the oxida on state of chlorine is
A. +1 B. +3
✓ C. +5 D. +7
Q.71 Which technique is used to separate various frac ons from petroleum?
A. Dry dis lla on B. Vacuum dis lla on
✓ C. Frac onal dis lla on D. Destruc ve dis lla on
Q.72 Which of the following is not an organic compound:
✓ A. ammonium cyanate B. glucose
C. urea D. methane
Q.73 Which statement is most likely to be true for asta ne, which is below iodine in Group VII of the Periodic Table?
A. asta ne and aqueous potassium chloride B. potassium asta de and hot dilute silphuric
react to form aqueous potassium asta de and acid react to form white fumes of only
chlorine hydrogen asta de
C. silver asta de reacts with dilute aqueous ✓ D. sodium asta de and hot concentrated
ammonia in excess to form a solu on of a sulphuric acid react to form asta ne
soluble complex
Q.74 Which one has zero octance number:
A. iso-octance B. n-Hexane
✓ C. n-Heptane D. decane
Q.75 Which can added to common salt is known as iodized salt
A. Sodium iodide B. Lithium iodide
C. Potassium iodide ✓ D. Both A and C
Q.76 Which is an essen al cons tuent of chlorophyll
A. Be B. Fe
✓ C. Mg D. Ca
Q.77 Which type of cracking is used to produce gasoline of higher octane number?
A. Thermal cracking ✓ B. Cataly c cracking
C. Steam cracking D. All
Q.78 Which of the following does not react with HNO3?
_______________________________________________________________________________________
✓ A. Au , Pt B. Mg, Mn
C. Cu , Hg D. All of above
Q.79 Features included in group VII elements are
A. Non metals B. Diatomic molecules
C. Single covelnt bond ✓ D. All of them
Q.80 Acetylene has characteris c ethereal smell resembling the that of:
A. ginger B. vinegar
✓ C. garlic D. onion
Q.81 Element necessary for proper plant growth in small amounts:
✓ A. B B. Al
C. Ga D. In
Q.82 Mixing aqueous silver nitrate and aqueous sodium chloride produces a precipitate.Addi on of which reagent to the
mixture gives a colourless solu on?
✓ A. aqueous ammonia B. aqueous potassium iodide
C. dilute hydrochloric acid D. dilute nitric acid
Q.83 Which of the following is used in photographic film
✓ A. AgBr B. MgBr2
C. Na2S2O3 D. gela n
Q.84 ___________ is added to petrol because it saves the petrol from pre-igni on:
✓ A. Tetraethyl lead B. Methyl iodide
C. Phenol D. Naphthalene
Q.85 Which of the following elements is not present abundantly in earth's crust?
A. Silicon B. Aluminium
✓ C. Sodium D. Oxygen
Q.86 When H2S is passed over acidified KMnO4, product formed is
A. K2SO3 B. KHSO3
✓ C. S D. MnO2
Q.87 Which metal is used in the thermit process because of its ac vity?
A. Iron B. Copper
C. Aluminium ✓ D. Zinc
Q.88 In ter ary butyl alcohol, the ter ary carbon id bonded to:
A. tow hydrogen atoms B. three hydrogen atoms
C. one hydrogen atom ✓ D. no hydrogen atom
Q.89 Which one of the following is aliyclic hydrocarbon?
✓ A. cyclohexane B. benzene
C. isobutylene D. noepentene
Q.90 Which of the following is not a mixture of hydrocarbons:
A. Candle wax ✓ B. Vegetable oil
C. Kerosine oil D. Paraffin oil
Q.91 Halogen having greatest electron affinity is
A. I ✓ B. Cl
C. F D. Br
Q.92 Al is the most element in earth crust:
A. O B. Si
✓ C. Al D. Pb
Q.93 Which of the compound does not show cis-trans isomerism:
A. 2 Butane B. 2 Pentene
C. 1 Bromo 2 Chloropropene ✓ D. Propene
Q.94 The oxide of beryllium is
A. acidic B. amphoteric
_______________________________________________________________________________________
C. superoxide ✓ D. basic
Q.95 Which of the following alkanes has neither secondary nor ter ary hydrogen's
A. Iso-butane B. n-Pentane
C. Iso-Pentane ✓ D. Neo-Pentane
Q.96 The oxida on number of each element of group II-A is
A. 0 B. +1
✓ C. +2 D. -1
Q.97 Which one of the following is found in solid state?
A. bromine ✓ B. iodine
C. fluorine D. chlorine
Q.98 How does ammonia behave when its aqueous solu on is used to dissolve silver chloride, AgCl?
A. as a base ✓ B. as a ligand with the Ag+ion
C. as a ligand with the Cl-ion D. as a reducing agent
Q.99 The formula of lime stone is
A. CaCl2 B. MgCO3
C. Na2CO3 ✓ D. CaCO3
Q.100 Dipole moment of CO molecule is:
A. 0.0 B. 1.112 D
✓ C. 0.112 D D. 2.112 D
Q.101 Down group, hydrogen halides could be
A. More stable ✓ B. Less thermally stable
C. More reac ve D. Less reac ve
Q.102 ______ is the halogen which causes burns on the skin which heals slowly
A. F2 B. Cl2
✓ C. Br2 D. l2
Q.103 Octahedral crystals of pentahydrated borax are obtained above.
A. Room temperature B. 0ºC
C. 28ºC ✓ D. 62ºC
Q.104 Which of the following reacts with H2in dark
A. Cl2 B. Br2
C. l2 ✓ D. F2
Q.105 Which halogen will react spontaneously with Au(s) to produce Au3+?
A. Br2 ✓ B. F2
C. I2 D. Cl2
Q.106 Which of the following represents the correct electronic configura on of the outermost energy level of an element of
zero (VIIIA) group in the ground state
A. s 2p 2 B. s 2p 4
C. 2 5
sp ✓ D. s 2p 6
Q.107 What is formula of asbestos?
✓ A. CaMg3(SiO3)4 B. CaSiO3
C. Na2SiO3 D. Mg3H2(SiO3)4
Q.108 Which element is non metallic in nature?
A. Al B. Ge
C. Ga ✓ D. B
Q.109 (NH4)2SO4 contains 21% Nitrogen and 25%
A. Hydrogen ✓ B. Sulphur
C. Oxygen D. None
Q.110 MgO is used to line kilns and furnaces because of
A. Its ability to react as a reducing agent B. Its ability to neutralized exceed acid
✓ C. Its high mel ng point D. Its greater metallic radius
_______________________________________________________________________________________
Q.111 Plaster of pares is obtained by hea ng
✓ A. gypsum B. Epsom
C. lime stone D. dolomite
Q.112 In which of the following carbon is double bonded with itself?
A. Alkane B. Ether
✓ C. Alkene D. Alkyne
Q.113 Formula of colemanite is:
A. Na2B4O7.10H2O ✓ B. Ca2B6O11.5H2O
C. Al2O3.2H2O D. Al2O3
Q.114 In alkaline earth metals, from top to bo om the heat of hydra on is
A. Increases ✓ B. Decreased
C. not affected D. None
Q.115 Oxide of nitrogen which is white solid
A. NO B. NO2
C. N 2O 3 ✓ D. N2O 5
Q.116 Which metal does corrode badly in salt solu on?
A. Li B. Cu
C. Co ✓ D. Al
Q.117 Ether shows the phenomenon of:
A. posi on isomerism B. chain isomerism
✓ C. metamerism D. cis-trassisomerism
Q.118 Dolomite is a mineral of carbon and magnesium. its formula is
✓ A. MgCO3. CaCO3 B. MgCO3
C. CaMg3(SiO3)4 D. Mg(HCO3)2
Q.119 In a group IIA from top to bo om as the atomic number increases, there is regular decrease in
A. Ionic size B. atomic size
✓ C. ioniza on poten al D. none of these
Q.120 Which of the following useful compound of chlorine is now considered as hazard for the ozone layer
✓ A. CCl2F2(CFC) used as refrigerant B. CF3CHCl Br (halothane) used as anaesthe c
C. CaOCl2bleaching powder as source of chlorine D. polyvinyl chloride (PVC) used as plas c
Q.121 The frac on obtained from frac on dis lla on of petroleum are placed in increasing order of their boiling
points.Which order is corrects?
✓ A. natural gs petroleum ether gasoline B. petroleum ether kerosene gasoline natural
kerosene gas
C. gasoline kerosene natural gas petroleum D. kerosene gasoline petroleum ether natural
ether gas
Q.122 Which one of the following is an incorrect statement regarding the reac on between H2and Cl2in direct sunlight
A. Sunlight causes homolysis of H2molecules ✓ B. Sunlight causes homolysis of Cl2molecules
C. The enthalpy change for the reac on is D. It is a chain reac on
nega ve
Q.123 The anhydride of HCIO4is
A. CIO3 B. CIO2
C. Cl2O5 ✓ D. Cl2O7
Q.124 S-block elements consist of
✓ C. alkali and alkaline earth metals D. none of these
Q.125 Which of the following is most acidic
A. ZnO B. Na2O2
✓ C. P4O10 D. MgO
Q.126 Which is used for arc welding and cu ng
A. Kryton ✓ B. Argon
C. Helium D. Both A and C
_______________________________________________________________________________________
Q.127 Which of the following is lightest metal?
✓ A. Li B. K
C. Na D. Ca
Q.128 Which one of the following is organic compound?
A. calcium cyanamide B. carbon disulphide
C. calcium carbide ✓ D. none of the above
Q.129 One strong hea ng a hydrocarbon produces ethene propane and
but-1-ene in the mole ra o 5 : 1: 1
What is the molecular formula of the hydrocarbon?
✓ A. C17 H34 B. C17H36
C. C19H38 D. C19H40
Q.130 When H2SO4 is heated with excess of ethene of at 140°C,The major product is:
A. alcohol ✓ B. ether
C. ketone D. ethene
Q.131 Send is infect:
✓ A. Silica B. Opal
C. Smoky quartz D. Rose quartz
Q.132 Bleaching powder may be produced by passing chlorine over
A. calcium carbonate B. hydrated calcium sulphate
C. anhydrous calcium sulphate ✓ D. calcium hydroxide
Q.133 A molecular orbitals is formed by the linear combina on of two atomic orbitals, A molecular orbital must
accommodate__________electrons:
✓ A. 2 B. b
C. 1 D. 4
Q.134 Reducing flame of Ni by borax bead test is
A. Reddish brown ✓ B. Grey
C. Opaque D. Both b and c
Q.135 Which of the following substance is not present in acid rain
A. Sulphuric acid B. Nitric acid
C. Sulphurous acid ✓ D. Ace c acid
Q.136 Which is used in naviga onal equipments?
A. B B. Be
C. Mg ✓ D. Al
Q.137 Which of the following is the most powerful oxidising agent
A. Cl2 B. Br2
✓ C. F2 D. I2
Q.138 The geometric isomerism is caused by:
✓ A. the restricted rota on of pi bond B. the presence of similar group on a carbon
atom
C. the presence of similar group on a carbon D. the presence of a triple bond in a compound
atoms
Q.139 Formula of corundum is:
A. Na2B4O7.10H2O B. Ca2B6O11.5H2O
C. Al2O3.2H2O ✓ D. Al2O3
Q.140 Which is used in radio therapy for cancer and for earth quake predic on
✓ A. Radon B. Xenon
C. Krypton D. Both A and C
Q.141 Alkenes usually undergo ________ reac ons:
✓ A. addi on B. subs tu on
C. elimina on D. dehydra on
Q.142 Gysum is applied to the soil to provide calcium and
A. oxygen B. nitrogen
_______________________________________________________________________________________
C. phosphorous ✓ D. sulphur
Q.143 Boon Aluminium, Gallium, Indium, and thallium belong to group.
A. I-A B. II-A
✓ C. III-A D. IV-A
Q.144 Which of the following sulphates has the highest solubility in water?
A. BaSO4 B. CaSO4
✓ C. MgSO4 D. BeSO4
Q.145 Electronic configura on of fluorine is
✓ A. [He] 2s2, 2p5 B. [Ne] 3s2, 3p5
C. [Ar] 3d10, 4s2, 4p5 D. [Kr] 4d10, 5s2, 5p2
Q.146 Hybridiza on of sulphur in SO2 is
A. Sp3 ✓ B. Sp2
C. Sp D. dSp2
Q.147 Which is a mercapto func onal group?
✓ A. -SH B. -OH
C. -COOH D. -CHO
Q.148 Which of the following is not isomeric with diethyl ether:
A. n-propyl methyl ether B. 2- methyl-2-propanol
C. 1-butanol ✓ D. Butanone
Q.149 Which element is a semi-metal?
A. Al ✓ B. Ge
C. Ca D. B
Q.150 Weedkillers and herbicides are manufactured by
A. Flourides B. Bromides
C. Iodides ✓ D. None of them
Q.151 Which of the following is most suitable drying agent for NH3
A. Conc.H2SO4 B. P4O10
C. Anhydrous CaCI2 ✓ D. Quick line
Q.152 Alkaline earth metals are usually
✓ A. reducing agent B. oxidizing agent
C. amphoteric D. acidic
Q.153 The major por on of natural oil is:
A. ethane B. propane
C. butane ✓ D. methane
Q.154 Which will have the maximum value of heat of hydra on
A. Na+ B. Cs+
C. Ba+2 ✓ D. Mg+2
Q.155 halogen with highest electroniga vity is
✓ A. F B. Br
C. Cl D. l
Q.156 Which of the following oxides of nitrogen is a colored gas
A. NO B. N 2O
C. N 2O 4 ✓ D. NO2
Q.157 A compound used as eye wash:
A. Borax ✓ B. Boric acid
C. Metaboric acid D. pyroboric acid
Q.158 Which of the following of Epson salt is
A. MgSO4 B. MgCl2
✓ C. MgSO4. 7H2O D. MgCl2. 7H2O
Q.159 What is chrome yellow?
_______________________________________________________________________________________
A. PbO B. Pb2O
✓ C. PbCrO4 D. Pb3O4
Q.160 The destruc ve dis lla on of coal gives three products which is not the product of destruc ve dis lla on f coal?
A. coal gas B. carbon dioxide
✓ C. coal tar D. coke
Q.161 Glassy bead formed in borax bead test is:
✓ A. NaBO2 B. B 2O 3
C. Na2B4O7 D. Na2B9O7.2NaBO2
Q.162 Which is the complete list of all the products from the reac on of concentrated sulphuric acid with potassium
bromide?
A. potassium hydrogensulphate and hydrogen B. potassium hydrogensulphate, hydrogen
bromide bromide and bromine
C. potassium hydrogensulphate, hydrogen ✓ D. potassium hydrogensulphate, hydrogen
bromide, bromine and water bromide, bromine, water and sulphur
dioxide
Q.163 The oxidising power of halogens depends on various factors. Which is not the correct reason
A. energy of dissocia on B. electron affinity
C. hydra on energy of ion ✓ D. high atomic number
Q.164 The elements in which electrons enter in the s-orbitals are called
✓ A. s-block elements B. p-block elements
C. f-block elements D. d-block elements
Q.165 Some of the elements of a period show similar behavior with the elements of next group in next period this is called
A. Ver cal rela onship B. Obligue rela onship
✓ C. Diagonal rela onship D. None
Q.166 Zn reacts with dil.H2SO4 and conc.H2SO4 to give to give H2 gas and SO2 gas respec vely in these reac ons
A. Zn reduces H+to H2 B. Zn oxidizes H+ to H2
C. Zn reduces SO 2-
4 to SO2 ✓ D. Both a and c
Q.167 Which of the following is the strongest base
✓ A. NH3 B. PH3
C. As 3 D. BiH3
Q.168 The shape of ethylene molecule is:
A. Tetrahedral ✓ B. Planar
C. Pyramidal D. Linear
Q.169 Noble gas present in atomosphere, obtain as by product during frac onal liquefac on of air and slightly soluble in
water
A. Radon B. Neon
✓ C. Xenon D. Ar
Q.170 The metallic characters increase form, in group III-A:
✓ A. B to Th B. Ti to B
C. Ga to B D. In to Al
Q.171 SO2 produced by volcanoes is about
A. 75% ✓ B. 67%
C. 67% D. 70%
Q.172 An alkene forms isomers if the number of carbon atoms is at least:
✓ A. 4 B. 3
C. 2 D. 1
Q.173 Group II metals burn with characteris cs color because
A. These metals are highly colored B. Metals are reduced when they react
✓ C. Metals are oxidize when they react D. metals are highly densed
Q.174 Lime, calcium oxide, is used in agriculture for
A. adding ca metal in soil B. making soil acidic
✓ C. neutralizing acidic soil D. adding oxygen to soil
_______________________________________________________________________________________
Q.175 Replacement of hydrogen atom by - SO3H group in benzene is called:
A. nitra on B. alkyla on
✓ C. sulphona on D. acyla on
Q.176 Which of the following salt is soluble in water?
A. CaCO3 B. CaSO4
✓ C. MgSO4 D. BaSO4
Q.177 10 grams of water dissolves borax in it at 10ºC
A. 1 gm B. 2 gm
C. 3 gm ✓ D. 99.3 gm
Q.178 Borax in water is:
A. Soluble B. Insoluble
C. Immiscible ✓ D. Sparingly soluble
Q.179 Sample of HBr decomposes at 430°C
A. 20% ✓ B. 10%
C. 22% D. 11%
Q.180 Aldehyde and ketones are:
A. Homologous B. Allotropes
✓ C. Isomers D. Polymers
Q.181 Tincture of iodine is
✓ A. l2,Kl and rec fied spirit B. l2and rec fied spirit
C. Kl and rec fied spirit D. l2and water
Q.182 The chemical formula of gypsum is
A. CaSO4. 5H2O B. CaSO4. 4H2O
✓ C. CaSO4. 2H2O D. none of these
Q.183 Difference of Boron form rest of elements of group III-A is due to to:
A. Boron shows +3 and -3 oxida on B. Boron in non-metallic
C. Boron forms molecular addi on compouds ✓ D. All above
Q.184 Aluminium oxide is:
A. Acidic oxide B. Basic oxide
✓ C. Amphoteric oxide D. None of these
Q.185 Hybridiza on in oxygen is:
A. sp ✓ B. sp2
C. sp3 D. dsp3
Q.186 Formula of bauxite is:
✓ C. Al2O3.2H2O D. Al2O3
Q.187 The func onal group isomer of dimethylether is:
✓ A. ethyl alcohol B. propyl alcohol
C. diethyl ether D. butyl alcohol
Q.188 The maximum number of electrons in the outermost shall of s-block elements is
A. one ✓ B. two
C. three D. four
Q.189 Solubility of orthoboric acid in water at 40oC is
✓ A. 2.6% B. 3.6%
C. 4.6% D. 5.6%
Q.190 On passing ethene into concentrated sulphuric acid the intermediate compound formed on hydrolysis with boiling
water gives:
A. methyl alcohol ✓ B. ethyl alcohol
C. ethyl hydrogen sulphate D. methyl hydrogen sulphate
Q.191 Iden fy the incorrect statement
_______________________________________________________________________________________
behaves both as oxidizing and reducing B. H2O2acts as oxidizing and reducing agent
A. SO2
agnet
C. H2S is stronger reducing agent than H2O
✓ D. Bond angle in water is lesser than H2S
Q.192 Halogen which occurs naturally in posi ve oxida on state is
A. Fluorine B. Chlorine
C. Bromine ✓ D. Iodine
Q.193 Al element that has a high ioniza on energy and tends to be chemically inac ve would most likely to be
A. an alkali metal B. a transi on element
Q.194 The structure of benzene is:
✓ A. hexagonal B. pyramidal
C. square planer D. tetrahedral
Q.195 Bond length is maximum in
✓ A. Hl B. HBr
C. HCl D. HF
Q.196 Pair of element belonging to group III-A?
A. Al & Ca B. B & Be
C. Ga & Ge ✓ D. In & Te
Q.197 The use of tetra ethyl lead in petrol as an efficient an knock agent is being discouraged. Which reason is correct?
A. it is costly B. it damages the engine
✓ C. the cobbus on product, lead causes air D. Pb is difficult to obtain is in bulk quali es
polu on
Q.198 Which of following has the smallest size
A. Na+ B. Mg2+
✓ C. Al3+ D. Cl
Q.199 At room temperature chlorine is
A. pale yellow gas B. greenish yellow gas
C. red-brown liquid ✓ D. shiny greylish black solid
Q.200 In ter ary butyl alcohol, ter ary carbon is bonded to
A. 2 H-atom B. 3-H atom
C. 1-H atom ✓ D. Non Hydrogen atom
Q.201 Element of group IV-A
A. C ✓ B. ln
C. Th D. Al
Q.202 Friedrich Wohler rejected vital force theory by ar ficial synthesizing urea as a result of hea ng of:
A. Ammonium nitrate B. Ammonium sulphate
C. Ammonium chloride ✓ D. Ammonium cyanate
Q.203 The use of tetra ethyl lead in petrol as an efficient an knock agent is being discouraged.Which reason is correct?
A. it is costly B. it damages the engine
C. Pb is difficult to obtain in bulk quali es ✓ D. the combus on product lead causes air
pollu on
Q.204 Ac on of conc. HNO3 on metallic n produces
A. Stannous nitrite B. Stannous nitrite
C. Stannic nitrite ✓ D. Meta stannic acid
Q.205 The branch of chemistry which deals with the study of compounds containing carbon as an essen al element is called:
A. physical B. inorganic
C. nuclear ✓ D. organic
Q.206 Which one of the following will not react with tollens reagent?
A. ethyne B. 1-butyne
C. 3-methyl-1-Butene ✓ D. 2-pentyne
Q.207 There are three fluorides of Xenon, which can be prepared by hea ng Xe and F2in 1 : 5 ra on in nickel container
_______________________________________________________________________________________
✓ A. XeF4 B. XeF2
C. XeF6 D. All of them
Q.208 The 3rd most abundant element in the earth crust a er oxygen and silicon
A. Si ✓ B. Al
C. O D. H
Q.209 Atomic number of barium is
A. 38 B. 10
C. 12 ✓ D. 56
Q.210 Cracking id a process by which higher hydrocarbons are broken down into low boiling hydrocarbon.Which one is not
generally a producer for cracking.
A. thermal cracking B. cataly cal cracking
C. steam cracking ✓ D. normal cracking
Q.211 At room temperature iodine is
C. red-brown liquid ✓ D. shiny greyish black solid
Q.212 Lightning bolts in atmosphere causes the forma on of
✓ A. NO B. NH3
C. NH4OH D. NH2OH
Q.213 Iden fy the hydrocarbon formed when ethyl bromide reacts with alcoholic KOH at 1000°C:
A. methane B. ethane
✓ C. ethane D. ethyne
Q.214 Chlorine is used for
A. purifica on of water B. as a bleaching agent
C. extrac on of gold from its ores ✓ D. all of the above
Q.215 Who rejected the vital force theory?
✓ A. Wholer B. Fisher
C. Newton D. Lewis
Q.216 The < HCh angle in ethene is:
A. 120 B. 125
✓ C. 117 D. 109.5
Q.217 Percentage of nitrogen in KNO3 is
✓ A. 13% B. 48%
C. 16% D. 43%
Q.218 Nitrogen (I) oxide is produced by
✓ A. Thermal decomposi on NH4NO3 B. Hea ng NH4NO2
C. Dispropor ona on ac on of N2O4 D. Reac on of NH4OH & HNO2
Q.219 Pb has insert pair of electrons:
A. One ✓ B. Two
C. Three D. Four
Q.220 Which of the following is not a nobel gas
A. Xe B. Rn
C. Kr ✓ D. K
Q.221 During pyrolysis which bond will break rapidly:
✓ A. C−C B. C−H
C. C=C D. C=C
Q.222 The element with highest first ioniza on energy is
A. B B. C
✓ C. N D. O
Q.223 Which of the following acids possesses oxidizing reducing and complex forming proper es
A. HNO3 ✓ B. HNO2
_______________________________________________________________________________________
C. H2SO4 D. HCi
Q.224 In benzene carbon-carbon bonds are
A. single cova B. double covalent
✓ C. of the order 1.5 D. 3 single and 3 double
Q.225 It TEL is added to iso octance,octance number will be:
A. 100 B. < 100
✓ C. > 100 D. none
Q.226 Borax bead test is used for the detec on of
✓ A. metallic ca ons B. oxidising agent
C. reducing agent D. anions
Q.227 Which element has highest oxida on poten al
✓ A. Li B. Be
C. Ba D. Ra
Q.228 Indicate the incorrect factor. The increase in the oxida on state of the halogen from +1 to +7 accompanied by
A. increased in the thermal stability of the oxy B. the decrease in oxidising power of the oxy
acid acid
C. the increase in acidic strength of the oxy acid ✓ D. the increase in oxidising power of the oxy
acid
Q.229 Soecific gravity of H2SO4 at 15C° is
✓ A. 1.834 B. 1.348
C. 1.438 D. 18.34
Q.230 Formula of cryolite is:
C. Al2O3.2H2O ✓ D. Na3AIF6
Q.231 Silicon exists as quartz in the form of its
✓ A. Oxides B. Hydrides
C. Halides D. Hydroxide
Q.232 Which one of the following is the least stable hydrocarbon?
✓ A. cyclopropane B. propane
C. chyclobutane D. cyclohexane
Q.233 Which one of the following compounds has longest C-H H bond?
✓ A. ethane B. ethene
C. ethyne D. benzene
Q.234 Chlorine acts as a bleaching agent in the presence of
A. Dry air ✓ B. Moisture
C. Sunlight D. Pure oxygen
Q.235 In balloons He gas is filled but not H2. why
A. He is lighter than H2 ✓ B. H2is inflammable
C. H2is lighter than He D. H2is not available
Q.236 Which element forms an ion with charge 3+?
A. Beryllium ✓ B. Aluminium
C. Carbon D. Silicon
Q.237 The ore CaSO42H2O has the general name
✓ A. gypsum B. dolomite
C. calcite D. epsom salt
Q.238 Kerosene oil is also called:
A. jet oil B. paraffin oil
✓ C. both a and b D. crude oil
Q.239 Electronic configura on of chlorine is
A. [He] 2s2. 2p2 ✓ B. [Ne] 3s2, 3p5
C. [Ar] 3d10, 4s2, 4p5 D. [Kr] 4d10 ,5s2, 5p2
_______________________________________________________________________________________
Q.240 At room temperature bromine is
C. red-brown liquid ✓ D. shiny greyish black solid
Q.241 Which of the following does not contribute towards the forma on of photochemical smog
A. NO ✓ B. SO2
C. O3 D. Hydrocarbons
Q.242 The main reason for a large number of organic compounds is unique property of:
A. Isomerism ✓ B. Catena on
C. Homologous series D. Complexity of organic compound
Q.243 In methane all the bonds are:
✓ A. sigma B. Pi
C. single covalent D. a and c
Q.244 Borax occurs as natural deposits as:
✓ A. Tincal B. Feldspar
C. Alumite D. Borite
Q.245 Chlorine heptoxide (Cl2O7) reacts with water to form
A. hypochlorous acid B. chloric acid
✓ C. perchloric acid D. chlorine and oxygen
Q.246 Which has soapy touch?
A. Na2B4O7 ✓ B. H3BO3
C. Ca2B6O11 D. HBO2
Q.247 When an electron enters into outermost shell of fluorine, it
✓ A. Experiences least shielding from posi ve B. Experiences most shielding from posi ve
nuclear charge nuclear charge
C. Experiences least shielding from nega ve D. Experiences most shielding from nega ve
nuclear charge nuclear charge
Q.248 Copper oxide is detected by borax bead test with colour:
✓ A. Blue B. Red
C. Yellow D. Black
Q.249 Oxidizing powers of halogen depends on
A. Energy of dissocia on B. Electron affinity
C. Hydra on energies of ions ✓ D. All of above
Q.250 The alkaline earth elements have in their s-orbital
A. one electron ✓ B. two electron
C. no electron D. three electron
Q.251 In an historically famous experiment wohler heated 'inorganic' ammonium cyanate in the absence of air. The only
product of the reac on was organic urea CO(NH2)2No of he produce were formed in the reac on.
What is the formula of the cyanate ion present in ammonium cyanate?
✓ A. CNO ̅ B. CNO2 ̅
C. CO ̅ D. NO ̅
Q.252 The first product obtained during frac onal dis lla on of petroleum is:
✓ A. Petroleum ether B. Kerosene
C. Diesel D. Gasoline
Q.253 Hydrolysis of borax can be prevented in the presence of
A. Alcohol B. KCl
C. NaCl ✓ D. Glycerin
Q.254 Which of the following elements can be toxic to plants growing in highly acidic soil
A. AI ✓ B. N
C. Fe D. Cu
Q.255 Borax is a salt of tetraboric acid of metal:
A. K ✓ B. Na
C. Mg D. Ca
_______________________________________________________________________________________
Q.256 Which is used in making glass lasers
A. Neon B. Argon
C. Helium ✓ D. Both A and C
Q.257 The homocyclic compounds which contain a ring of three or more carbon atoms and resembling alipha c compounds
are called:
✓ A. Alicyclic B. Heterocyclic
C. Acyclic D. Aroma c
Q.258 Its viscosity is less then water due to absence of three dimensional network of H-bonds which occurs in H2O
✓ A. HF B. Ice
C. All HX D. None of these
Q.259 Highest mel ng point among these four elements is of
✓ A. Be B. Ca
C. Sr D. Mg
Q.260 MgCO3decomposes when hea ng
A. CO ✓ B. CO2
C. H2CO3 D. CO3-2
Q.261 In benzene carbon-carbon bond are:
A. single covalent B. double covalent
✓ C. of the order 1.5 D. 3 single and 3 double
Q.262 Which is formed when phosphorous is heated with conc HNO3?
A. NO ✓ B. NO2
C. N 2O 3 D. N 2O 5
Q.263 Which one is not a hydrocarbon?
A. naphthalene B. anthracene
✓ C. chloroform D. phenanthrene
Q.264 Halogen which reacts very slowly with hydrogen is
A. Fluroine B. Chlorine
C. Bromine ✓ D. Iodine
Q.265 Hydrogen bond is the strongest between the molecules of
✓ A. HF B. HCl
C. HBr D. HI
Q.266 Which type of coal has maximum percentage of carbon?
A. Peat B. Lignite
C. Bituminous ✓ D. Anthracite
Q.267 Compounds have same empirical formula but different molecular formula must have:
A. the same vescosity B. the same vpaour density
✓ C. different molecular weights D. same molecular wights
Q.268 Borax is:
A. White B. Crystalline
C. Sparingly soluble ✓ D. All above
Q.269 How many alcohols (including both structural isomers and stereoisomers) can have the molecuylar formula C4H10C
✓ A. 3 B. 4
C. 5 D. 6
Q.270 The element which displaces three halogens from their compounds is
A. Cl B. Br
C. I ✓ D. F
Q.271 Bleaching powder is
A. CaCl2and CaOCl2 B. CaOCl2and Ca(OCI)2
C. CaCl2and Ca(OCI)2 ✓ D. CaOCl2
Q.272 ________ reacts with alkalis to give hydrogen
_______________________________________________________________________________________
✓ A. Be B. Mg
C. Ca D. None
Q.273 Which element among the following belongs to group IV-A of the periodic table?
A. Barium B. Iodine
✓ C. Lead D. Oxygen
Q.274 Forces between diatomic halogens are
✓ A. Van der Wall's forces B. Permanent dipole-dipole forces
C. Electrovialent forces D. Temporary dipole forces
Q.275 A 80% Helium - 20% O2mixture is preferred to air for breathing by deep-sea divers because
✓ A. Helium is less soluble in blood than N2 B. Helium is denser than hydrogen
C. Helium is non-combus ble D. Helium is difficult to liquefy
Q.276 Which electronic configura on corresponds to an element of group III-A of the periodic table?
✓ A. 1s2,2s2,2p6,3s2,3p1 B. 1s,2s2,2p6,3s2,3p6,4s2
C. 1s2,2s2,2p6 D. 1s,2s2,2p6,3s2,3p3
Q.277 Boric acid is
A. Crystalline B. So soapy touch
C. Vola le in steam ✓ D. All above
Q.278 The first organic compound which was prepared from inorganic compounds is:
A. Ace c acid ✓ B. Urea
C. Methane D. Ethyl alcohol
Q.279 Commercial common salt becomes slight damp on storing because
✓ A. common salt is hygroscope B. common salt contains some impurity,which is
hygroscopic
C. salt in efflorescent D. salt is crystalline
Q.280 Replacement of hydrogen atom byf-SO3H group in benzene is called:
A. nitra on B. alkyla on
✓ C. sulphona on D. acyla on
Q.281 Density of aluminium is (g cm-3):
A. B ✓ B. Al
C. Si D. Ge
Q.282 Sulpute aerosols cause severe respiratory problems par cularly among
A. Infants B. Women
C. Young people ✓ D. Old people
Q.283 The heat of vaporiza on of nobel gases
✓ A. increases gradually down the group B. decreases gradually down the group
C. none of these D. have no heat of vaporiza on
Q.284 Which oil refinery has the capacity to refine 1.25 million tonnes of petroleum:
✓ A. A ock oil refinery B. Pak Arab refinery
C. Oil refinery at Karachi D. None of above
Q.285 There is no direct test for the detec on of one of the following is an organic compound.Which is it?
A. C B. S
C. N ✓ D. O
Q.286 Which process is used to improve quality of petrol:
A. Cracking ✓ B. Reforming
C. Annealing D. Pickling
Q.287 Pi electrons of benzene make it:
A. electrophic ✓ B. nucleophilic
C. heterocyclic D. alicyclic
Q.288 air bubbles are removed from molten metals by ssing metal
A. Li B. Cu
C. Co ✓ D. Al
_______________________________________________________________________________________
Q.289 The reac on of chlorine with cold and hot NaOH to give NaCl and NaCIO is an example of
A. neutraliza on reac on B. oxida on reac on
C. reduc on reac on ✓ D. dispropor on reac on
Q.290 Which is the chain isomer of n-pentane?
✓ A. isopentane B. neopentane
C. n-pentene D. isopetene
Q.291 Hybridiza on in carbon is:
✓ A. sp B. sp2
C. sp3 D. d2sp
Q.292 In the earth crust sodium is
A. 2.50% B. 2.30%
✓ C. 2.40% D. 3.50%
Q.293 Which element form an ion with charge 3+
A. beryllium ✓ B. aluminium
C. carbon D. silicon
Q.294 As the number of carbon atoms increases the number of isomers also increase. The 6C compound hexane has many
as:
A. 3 isomers ✓ B. 5 isomers
C. 6 isomers D. 10 isomers
Q.295 Chemical composi on of colemnite is:
✓ A. Ca2B6O11.5H2O B. CaB4O7.4H2O
C. Na2B4O7.4H2O D. CaNaB5O9.8H2O
Q.296 Borax or Tincal formula is:
✓ A. Na2B4O7.20H2O B. Ca2B6O11.5H2O
C. Al2O3.2H2O D. Al2O3
Q.297 Orthoboric acid has crystalline solid
A. Tetrahedral B. Orthogonal
C. Cubic ✓ D. Triclinic
Q.298 Which of following represents correct electronic configura on of VII A group elements in ground slate
A. ns2p2 B. ns2p4
✓ C. ns2np5 D. ns2p6
Q.299 Ethyl alcohol on ___________ gives ethane:
✓ A. dehydrogenaion B. hydra on
C. dehydra on D. oxida on
Q.300 Where lime is not used
A. in refining of metals B. in paper industry
C. in glass industry ✓ D. in the prepara on of NaOH
Q.301 Manure is
A. Inorganic material ✓ B. Organic material
C. Mixture if inorganic & organic D. Chemical compound
Q.302 Which one of the following does not belong to alkaline earth metals?
A. Be B. Ra
C. Ba ✓ D. Rn
Q.303 Aqua regia is formed by mixing one volume of nitric acid and three volumes of
A. H2SO4 ✓ B. HCl
C. NaOH D. Any of the above
Q.304 Elements not present in free state.
✓ A. B B. Th
C. Ga D. In
Q.305 Which is not the characteris c property of organic compounds:
_______________________________________________________________________________________
A. they form long chain compounds B. organic compound are generally covalent
compounds
C. they exist in homologous series ✓ D. organic compounds are water soluble
Q.306 which is not the form of silica?
A. Amethyst quartz B. Rose quartz
C. Smoky ✓ D. None of these
Q.307 Which fer lizer is used in liquid state
A. Urea B. NH4NO3
C. KNO3 ✓ D. None of these
Q.308 Which element has the same oxida on number in all of its known compounds?
✓ A. beryllium B. chlorine
C. nitrogen D. sulphur
Q.309 double bond is ethane makes its:
A. electrophilic ✓ B. nucleophilic
C. acidic D. basic
Q.310 In alkali and alkaline earth metals down the group, there is decreasing trend in
A. m.p B. b.p
C. ioniza on poten all ✓ D. all of these
Q.311 White marble buildings are effected by
A. O2 ✓ B. SO2
C. CI2 D. CFCS
Q.312 Bleaching powder has the formula
✓ A. CaOCl2 B. Ca(CIO)2
C. Ca(OH)2. CaCl2 D. CaCIO2
Q.313 Main product of calcium carbonate is
A. Lime B. Carbonate
C. Calcium ✓ D. Limestone
Q.314 Which is not the common are of fluorine
A. fluorspar B. cyrolite
C. apa te ✓ D. carnalite
Q.315 Ammonium nitrate is not a good fer lizer for
A. Co on B. Wheat
C. Sugar cane ✓ D. Paddy rice
Q.316 Which ionic compound of boron does exist?
✓ A. BCl3 B. B(NO3)3
C. B2(SO4)3 D. B(OH)3
Q.317 Boric acid is used as
A. dus ng powder B. Boric ointment
C. Eye wash ✓ D. all above
Q.318 Hea ng P4O10 with conc. HNO3 gives
A. NO B. N 2O
C. NO2 ✓ D. N2O 5
Q.319 White solid oxides are produces by burning of group II metals in presence of
A. Nitrogen B. Carbon dioxide
✓ C. Oxygen D. Helium
Q.320 Actually benzene has_______ double bond
A. 3 B. 2
C. 4 ✓ D. No
Q.321 Calcium carbide reacts with water to produce
✓ A. acetylene B. methane
C. ethylene D. ethane
_______________________________________________________________________________________
Q.322 Alkenes are also called:

A. Parraffin's ✓ B. olefins
C. napthene D. arenas
Q.323 Which can be prepared by hea ng Xe and F2in 3 : 20 ra o in steel vessel
✓ A. XeF6 B. XeF4
C. XeF2 D. None of these
Q.324 Which metal Group-II A of the Periodic Table, will form the least ionic chloride
✓ A. Be B. Mg
C. Ca D. Sr
Q.325 Borex is used
A. Borate glasses B. In water so ening
C. as flux ✓ D. All above
Q.326 Gold dissolves in aqua Regia forming
✓ A. Auric chloride B. Aurous chloride
C. Aurochloric acid D. Aurous nitrate
Q.327 A gas which can not be collected over water is
A. N2 B. O2
✓ C. SO2 D. PH3
Q.328 Polythene is a polymer of:
A. ethane ✓ B. ethene
C. acetone D. propylene
Q.329 Which coal is having percentage of carbon higher calorific value of lower moisture:
✓ A. anthracite B. bitumenus
C. lignite D. sub-bitumenous
Q.330 Borax is hydrated:
A. Penta ✓ B. Deca
C. Hepta D. Octa
Q.331 What is going to replace the petroleum?
A. Silica B. Silicates
✓ C. Silicons D. Silicon
Q.332 Which of halogen have lowest dissocia on energy
✓ A. F2 B. Cl2
C. Br2 D. None of them
Q.333 Specific Redox reac on of chlorine is known as
✓ A. Dispropor ona on B. Oxida on
C. Reduc on D. None of these
Q.334 The chemical formula of magnesite is
A. MgCl2 B. Mg(HCO3)2
✓ C. MgCO3 D. none of these
Q.335 Which is the chain isomer of n-pentance?
✓ A. isopentane B. neo-pantene
C. n-pentene D. iso-pentene
Q.336 Because of its small size and due to restric on of its valence shell to an octel fluorine differs from other halogens.
Which behaviour of fluorine is incorrect
A. it has highest first ioniza on energy B. it has highest electronega vity
✓ C. it is more reac ve than other halogens D. it restricts to oxida on state -1 only
Q.337 Which property is not present in Al?
A. Reacts with acids B. Reacts with bases
C. Changes litmus paper ✓ D. Changes methyl orange colour
Q.338 The alkaline earth metal carbonates, sulphates, phosphates are water ___________ at room temperature
_______________________________________________________________________________________
A. Soluble ✓ B. Insoluble
C. Par ally soluble D. None
Q.339 Bromine is a liquid with
A. pale yellow colour ✓ B. red-brown colour
C. grenish yellow colour D. graylish black
Q.340 Which is the strongest acid
A. HCIO B. HCIO2
C. HCIO3 ✓ D. HCIO4
Q.341 Which combine directly with inert gases
A. Cl2 B. Br2
C. l2 ✓ D. F2
Q.342 Which element cons tute basic of organic chemistry.
✓ A. C B. Si
C. Ge D. Sn
Q.343 Which is strongest acid
A. HClO B. HClO2
C. HClO3 ✓ D. HClO4
Q.344 Which salt is used for preserving food?
A. CaCl2 ✓ B. CaCO3
C. Na2CO3 D. NaHCO3
Q.345 Na2B4O7 + 2HCl +5H2O ----------->2NaCl + ------?
✓ A. H3BO3 B. HBO2
C. H 2B 4O 7
D. H 6B 4O 9
Q.346 Which one is condensa on polymer?
A. polethene ✓ B. bakelite
C. both a&b D. PVC
Q.347 ________ is called milk magnesia
✓ A. NaOH B. KOH
C. LiOH D. None
Q.348 Ammonia reacts with CO2 to form
A. Urea ✓ B. Ammonium carbonate
C. Ammonium cyanate D. None
Q.349 Total coal resources of Pakistan is es mated by geological survey of Pakistan to be:
A. 148 billion tons ✓ B. 184 billion tons
C. 418 billion tons D. 814 billion tons
Q.350 The total coal resources of Pakistan are es mated to be:
✓ A. 184 billion tonnes B. 184 million tonnes
C. 1.84 billion tonnes D. 1.84 million tonnes
Q.351 Which of the following is an inorganic fer lizer
A. Urea B. Manure
✓ C. Ammonium nitrate D. None
Q.352 Which of the following sulphates is not soluble in water?
A. sodium sulphate B. potassium sulphate
C. zinc sulphate ✓ D. barium sulphate
Q.353 Iden fy the compound formed when ethylene combines with water in
the presence of 10%. Sulphuric acid and HgSO4 as catalyst:
A. carbinol B. methanol
✓ C. ethanol D. glycol
Q.354 Nitrogen dioxide cannot be prepared by hea ng
_______________________________________________________________________________________
✓ A. KNO3 B. Pn(NO3)2
C. CuNO3)2 D. All of these
Q.355 Halogen having highest bond energy is
A. F2 ✓ B. Cl2
C. l2 D. Br2
Q.356 Which of the following oxides of nitrogen is paramagne c
✓ A. NO2 B. N 2O
C. N 2O 4 D. All of these
Q.357 Silicon atom is hybridized:
A. sp B. sp2
✓ C. sp 3
D. dsp2
Q.358 Which element does not belong to III-A group?
A. Al ✓ B. Ge
C. Ga D. Th
Q.359 LiOH ________ soluble than NaOH
A. More soluble ✓ B. Less soluble
C. Equally soluble D. None
Q.360 Which of the following HX is the strongest acid, best reducing agent, is the least stable and is easily oxidized
A. HF B. HCl
C. HBr ✓ D. HI
Q.361 Which of the element is not alkali metal
A. lithium B. rubidium
C. francium ✓ D. magnesium
Q.362 _______ gives peroxide
A. Li ✓ B. Ba
C. Sr D. Be
Q.363 Which of the following catalysts is used during the manufacturing of H2SO4 by lead chamber process
A. V 2O 5 B. Mo
✓ C. Mixture of NO & NO2 D. NO + N2O
Q.364 The first ioniza on energy of He is 2372 KJ mol-1and that of Ar is 1521 KJ mole-1. What is the first ioniza on energy of
Ne likely to be
✓ A. 2081 B. 1425
C. 2590 D. 3060
Q.365 Which of the following salt is used as purga ve?
A. CaSO4 ✓ B. MgSO4
C. BeSO4 D. NaCl
_______________________________________________________________________________________
11 Transition Elements
Q.1 Spectrum of helium is expected to be similar to that of

A. H ✓ B. Li+
C. Na D. He+
Q.2 The mass of neutron is in the range of:
A. 1.6750 x 10-26kg B. 1.6750 x 10-23kg
C. 1.6750 x 10-22kg ✓ D. 1.6750 x 10-27kg
Q.3 The nature of posi ve rays depends upon:
A. the nature of electrode B. the nature of discharge tube
✓ C. the nature of residual gas D. all of the above
Q.4 Ions which are produced from ligands are
A. ca on B. anion
✓ C. complex ion D. all of them
Q.5 Kβ line of x-rays spectrum is associated with the transi on from
A. L→K ✓ B. M→K
C. N→K D. L→M
Q.6 Transi on elements have binding energies:
A. Low ✓ B. High
C. No effect D. All of these
Q.7 A transi on metal complex can be recognized by various terms. Which is not the proper term
A. central metal ion B. coordina on number
C. ligand ✓ D. geometry of complex
Q.8 When neutrons are bombarded on the F atom α=par cles are emi ed what would be the new element formed
A. Carbon B. Oxygen
✓ C. Nitrogen D. Fluorine
Q.9 which orbital of the following has a principal quantum number of 3 and an angular momentum quantum number of
27:
A. 3f ✓ B. 3d
C. 4f D. 3s
Q.10 A non-typical transi on element is:
A. Cu B. Y
C. Cr ✓ D. Zr
Q.11 The energy of a photon is given as,Δ E/atom = 3.03 x 10-19 J atom-1 then,the wavelength (λ) of the photon is
A. 65.6 nm ✓ B. 656 nm
C. 0.656 nm D. 6.56 nm
Q.12 The total number of possible values of magne c quantum number for the value of / = 3 is
A. 3 B. 1
C. 5 ✓ D. 7
Q.13 If the radius of first Bohr orbit be a0,then the radius of third Bohr orbit would be
A. 3 x a0 B. 6 x a0
✓ C. 9 x a0 D. 1/2 x a0
Q.14 The radius of hydrogen atom in the ground state is 0.53 A the radius of 3Li2+ in the similar state is
_______________________________________________________________________________________
A. 1.06 A B. 0.265 A
✓ C. 0.17 A D. 0.53 A
Q.15 D-block elements are arranged in
✓ A. Three series B. Six series
C. Two series D. Seven series
Q.16 Elements showing no net effect of applied magne c field are called:
A. Magne sm ✓ B. Paramagne sm
C. Diamagne sm D. none of them
Q.17 f-block elements are also called
A. Non-transi on elements B. Outer-transi on elements
C. Number of elements ✓ D. Inner transi on
Q.18 Which has least mel ng point among the given?
A. Zn B. Co
C. V ✓ D. W
Q.19 In transi on metal complex, metal ca on acts as
✓ A. Lewis acid B. Bronsted acid
C. Bronsted base D. None of the above
Q.20 Choose the value of the Redberg's constant among the following among the following:
✓ A. 1.09678 x 107m-1 B. 1.9678 x 107m-1
7 -1
C. 1.697 x 10 m D. 1.007 x 107m-1
Q.21 Cathode rays drive a small paddle wheel placed in their path. The observa on indicates that:
✓ A. Cathode rays are material par cles having B. cathode rays are nega vely charged
momentum
C. cathode rays produce X-rays
D. cathode rays travel in straight line
Q.22 For dsp3hybridiza on the expected geometry will be
A. Tetrahedral B. Square planar
✓ C. Pyramidal D. Octahedral
Q.23 Find the magne c moment of a divalent ion in aqueous solu on if its atomic number is 25
A. 3.0 BM B. 4.9 BM
✓ C. 5.9 BM D. 6.9 BM
Q.24 Units of ° is
A. NmC-2 ✓ B. C2N-1m-2
C. C2Nm2 D. C2N-1m2
Q.25 Use of the Data Booklet is relevant to this ques on. In forming ionic compounds, elements generally form an ion with
the electronic structure of a noble gas. which ion does not have noble gas electronic structure?
A. l- B. Rb+
✓ C. Sn2+ D. Sr2+
Q.26 Oxide state of transi on elements can be changed by trea ng it with a suitable
A. Reactant B. Catalyst
✓ C. Reagent D. All of them
Q.27 Valence electronic configura on of Ag+1is:
A. 3d9 B. 4d9
✓ C. Sd9 D. 6d9
Q.28 A molecule or ion with one or more lone pairs of electrons available to donate to a transi on metal ion is called a
✓ A. Ligand B. Ion
C. Dentate D. All of them
Q.29 The colour of the transi on metal compounds is due to
A. p-d transi on ✓ B. d-d transi on
C. s-p transi on D. none of these
Q.30 Consider that in the posi on of an electron, the uncertainty is zero. What will be uncertainty in its momentum?
_______________________________________________________________________________________
✓ A. infinite B. zero
C. 2h/π D. h/2π
Q.31 The colour of transi on metal complexes is due to:
✓ A. d-d transi on of electrons B. Paramagne c nature of transi on elements
C. Ioniza on D. Loss of s-electrons
Q.32 Which of the following is non-typical transi on element?
A. Cr B. Mn
✓ C. Zn D. Fe
Q.33 Both the m.p and density of Fe is higher from those of Ca. Which statement explains this
A. Ca has stronger metallic bond B. Fe has more delocalised electrons
C. Fe has larger Ar but same radius as that of Ca ✓ D. Both b and c
Q.34 Which of the following d-block elements can show the highest oxida on number in its compounds?
A. chromium B. copper
C. nickel ✓ D. manganese
Q.35 The valence orbital configura on of an element with atomic number 23 is
A. 3d5 ✓ B. 3d3,4s2
C. 3d3,4s1,4p1 D. 3d2,4a2,4p1
Q.36 Cathodic protec on of iron involves the use of
A. Mg B. An
✓ C. As D. Copper
Q.37 5-d series is in the period:
A. 4th B. 5th
✓ C. 6th D. 7th
Q.38 Non-typical elements belong to the series:
A. I-A and II-A ✓ B. II-A and II-B
C. II-B and III-B D. III-B and III-A
Q.39 When quantum number is sufficient to describe the electron is hydrogen atom?
A. / ✓ B. n
C. m D. s
Q.40 The number of d-electrons retained in Fe2+ (At,No,of Fe = 26) ions is
A. 3 B. 4
C. 5 ✓ D. 6
Q.41 Steel may be manufacture by two processes.which two are correct
✓ A. open hearth process and besemer process B. open hearth process and Haber process
C. bessemer process and Haber process D. contact process and Haber process
Q.42 The number of neutrons in heavy hydrogen atom is
A. 0 ✓ B. 1
C. 2 D. 3
Q.43 K2[Fe(CN)6] is called
✓ A. Potassium hexacyanoferratre II B. Potassium ferricyanide
C. Potassium hexacyanferrate III D. Persian blue
Q.44 All 3d series elements show an oxida on state of ______ in addi on to higher
A. +1 ✓ B. +2
C. +3 D. Zero
Q.45 Commonly transi on elements have high
A. Densi es B. Mel ng points
C. Vola lity rate ✓ D. Both A and B
Q.46 Oxida on number of Fe in K2[Fe(CN)6] is
A. +2 ✓ B. +3
C. +4 D. +1
_______________________________________________________________________________________
Q.47 Ethylene diamine is
A. Mono dentate legand ✓ B. Bidentate
C. Polydente ligand D. It is Lewis acid
Q.48 Effec ve magne c moment of Sc3+ ion is
A. 1.73 ✓ B. 0
C. 5.92 D. 2.83
Q.49 Titanium is used as a catalyst in
A. Hydrogena on B. Dehydrogena on
✓ C. Polymeriza on of P.E D. Oxida on of ammonia
Q.50 Which element has maximum binding energy:
A. Zn B. Co
C. V ✓ D. W
Q.51 The color of transi on metal complexes is due to
✓ A. d-d transi on of electrons B. Paramagne c nature of transi on elements
C. Ioniza on D. Loss of electrons
Q.52 Following ion is a bidentate ligand
A. Ammonia B. Carbonyl
✓ C. Oxalato D. Cyanide
Q.53 For a sub-shell quantum no for all electrons should be
A. n=4 ✓ B. l= 1
C. 1=0 D. s= + 1/2
Q.54 chlorine atom has set of n, l, m quantum numbers for the unpaired electrons:
A. 2,1,1 ✓ B. 3,1,1
C. 2,1,0 D. 3,0,0
Q.55 Potassium ferrocyanide (potassium hexacyano ferrate II) is a/an complex
A. Ca onic ✓ B. Anionic
C. Neutral D. None of the above
Q.56 Each transi on element have more than one
A. Ion B. Oxida on state
C. Nucleus ✓ D. Both A and B
Q.57 In periodic table, element in a second row of transi on elements beneath tanium is
A. Zinc (Zn) B. Zirconium (Zr)
✓ C. Scandium (Sc) D. Copper (Cu)
Q.58 Which is not true with respect to cathode rays?

A. A stream of electrons B. Charged par cles
✓ C. Move with speed as that of light D. Can be deflected by magne c fields
Q.59 Rutherford's model of atoms failed because:
✓ A. it did not account for the stability of the B. it did not account for the a rac on between
atom proton and neutron
C. there is actually no space between the D. the atom did not have uncleus and electrons
uncleus and electrons
Q.60 Which of the following is a transi on element?
A. Sr B. Sn
✓ C. Cr D. Pb
Q.61 Anhydrous CuSO4is dissolved in water and then excess of NH3is added.Which statement describes the colour change
that occurs
✓ A. white to blue to deep blue B. white to purple to deep blue
C. blue to white purple D. white to blue to red
Q.62 Which of the following orbitals have a dumb bell shape?
A. s ✓ B. p
C. d D. f
_______________________________________________________________________________________
Q.63 By obeying the hands what is correct about the electronic configura on of Mn
A. It has +7 oxida on state B. It has 5-paired electrons
✓ C. It has 5 unpaired electrons D. It is a d-block element
Q.64 Limi ng line of Balmer series lies in the region
A. Visible B. Infrared
✓ C. Ultraviolet D. x-rays
Q.65 Potassium ferrocyanide is a
A. mixed salt B. double salt
✓ C. complex salt D. normal salt
Q.66 The formula of curprite is
A. Cu2S B. CuS
✓ C. Cu2O D. CuCO3
Q.67 A proton is quite iden cal to:
A. α - Par cle ✓ B. ionized hydrogen
C. hydroxonium ion D. ionized Hydrogen molecules
Q.68 Which of the following electronic transi ons between energy levels in hydrogen atom produces the line of shortest
wave length in the hydrogen spectrum
A. Paschen series B. Pfund series
C. Bracke series ✓ D. Balmer series
Q.69 The number of unpaired electrons present in Fe3+ion is
A. 1 B. 2
✓ C. 5 D. 0
Q.70 Rutherford's atomic model suggests the existence of
A. Atom ✓ B. Nucleus
C. α-par cle D. Mesons
Q.71 Which element belongs to 4d series
A. Ti B. Na
C. Mn ✓ D. Te
Q.72 K3[Co(NO2)6] is
A. Potassium cobal ni te ✓ B. Potassium hexanitro cobaltate (III)
C. Moher's salt D. All of the above
Q.73 The percentage of carbon in different types of iron products is in the order of:
✓ A. Cast iron >wrought iron > steel B. Wrought iron > steel > cast iron
C. Cast iron > steel > wrought D. Cast iron = steel ? wrought
Q.74 Millikan determined the charge on electron in oil drop experiment. It value is:
A. 6.625 x 10-34C B. 1.602 x 1023C
C. 1.602 xx 10-23C ✓ D. 1.602 x 10-19C
Q.75 Any specie can be reduced, if oxida on state is
A. oxidized B. gained
✓ C. reduced D. lost
Q.76 In the electronic configura on of Cr one electron from 4s sub-shell is transfered to 3d sub-shell because
A. the 3° orbital is of lower energy than 4s B. the 4s orbital is of equal energy to 3d orbital
✓ C. the half filled d-subshell is more stable than D. 6 unpaired electrons make Cr more
incomplete d-sub shell paramagne c
Q.77 Transi on elements shows ______ oxida on state
✓ A. Variable B. Constant
C. Single D. Infinite
Q.78 The energy of the first electron in helium will be
A. -13.6 eV ✓ B. -54.4 eV
C. -5.44 eV D. Zero
Q.79 In the ground state of an atom, the electron is present:
_______________________________________________________________________________________
A. in the nucleus B. in the second shell
✓ C. nearest to the nucleus D. father from the uncleus
Q.80 Coordina on number of Pt in [PtCl(NO2) (NH3)4]2+is
A. 2- ✓ B. 4
C. 1 D. 6
Q.81 Hypo is trade name of sodium thio sulphate. It is used in photography for
A. Developing the nega ve ✓ B. Reduc on of nega ve
C. To make it nega vely D. To make it nega vely charged
Q.82 Oxida on state +2 is obtained by losing 2 electrons from
A. 2s ✓ B. 4s
C. 2p D. d
Q.83 Which one of the following has highest density?
A. Zn ✓ B. Os
C. Ni D. Cu
Q.84 The oxida on state of Fe in [Fe(CN)6]3-is
A. +2 ✓ B. +3
C. +4 D. -3
Q.85 During the transi on of metal ion in five D orbitals split into two non degenrate orbitals
✓ A. co-ordinate bonding B. Ionic bonding
C. Covalent bonding D. All of them
Q.86 Group VIB of transi on elements contains
A. Zn, Cd, Hg B. Fe, Ru, Os
✓ C. Cr, Mo, W D. Mn, Te, Re
Q.87 [Ti(H2O)6]3+looks ______ in colour
A. Blue and red ✓ B. Violet
C. Yellow light D. Both A and C
Q.88 The geometry of [Co(NH3)6]3+is
A. tetrahedral B. square planar
✓ C. octahedral D. none of these
Q.89 Which of the following is not charged par cles?
A. electron B. proton
✓ C. neutron D. hydrogen
Q.90 Transi on elements are called so because:
A. From inters al compound ✓ B. Have high m.p
C. In between 's' and 'p' block elements D. All of these
Q.91 Bill metal is an alloy of Sn and
✓ A. Copper B. Iron
C. Zinc D. Magne c
Q.92 A property NOT in transi on elements:
A. Complexes forma on B. Diamagne c
✓ C. Alloys forma on D. Inters al compounds
Q.93 Second series of transi on elements starts with
✓ A. Y rium B. Chromium
C. Zinc D. Scandium
Q.94 What is the packet of energy called?
A. Electron B. Photon
✓ C. Positron D. Proton
Q.95 Which of the following is not isoelectronic?
A. Na+ B. Mg2+
C. O2- ✓ D. CI-
_______________________________________________________________________________________
Q.96 When atom is in the ground state, the electron is present
✓ A. nearest to the nucleus B. nearest to the valence shell
C. in the second shell D. in the nucleus
Q.97 The symbol of the element whose atoms have the outer most electronic configura on 2s2 2p3 is
✓ A. N B. Li
C. P D. Na
Q.98 Out of 110 known elements, transi on elements are
A. 40 ✓ B. 60
C. 50 D. 80
Q.99 All elements of 3d series are not transi on element. A transi on element must have incomplete d-orbitals in at least
one of its stable ions. Which of the following element of 3d series is a transi on element
A. Sc B. Zn
✓ C. Cu D. Ca
Q.100 Salts of chromic acids are called:
A. Chromates B. Dichromates
✓ C. Silicates D. Silicones
Q.101 What 6b orbital is complete, the entering electron goes into:
A. 7f B. 7s
✓ C. 7p D. 7d
Q.102 Which is an different phase from other metals?
A. Ni ✓ B. Hg
C. Cd D. Na
Q.103 Element with ____ first ioniza on energies and ____ electron affini es generally generally from ca ons, Choose the
correct point.
✓ A. low , posi ve or slightly nega ve B. high, very nega ve
C. low very nega ve D. high, posi ve or slightly nega ve
Q.104 Heaviest par cle is
A. Meson ✓ B. Neutron
C. Proton D. Electron
Q.105 The arrangement of sodium, oxygen, fluorene and stron um on the basis of increasing first ioniza on energy is:
A. Na < Sr < O < F B. Na < Sr < F < O
✓ C. Sr < Na < O < F D. Sr < Na < F < O
Q.106 The principle quantum number describes the:
A. shape of the orbital B. spin of the electron
✓ C. distance from the nucleus D. orienta on from the orbital
Q.107 de-Brogiles concept is maximum jus fied by
✓ A. Protons B. α-par cles
C. γ-rays D. Neutrons
Q.108 The spectrum of He is expected to be similar to that of
A. H B. Na
C. He+ ✓ D. Li+
Q.109 e/m of cathode rays is same but for posi ve rays e/m charges by charging gas in the discharge tube. The reason is that:
A. cathode rays have same charge B. cathode rays are small size par cles
C. cathode rays have higher temperature ✓ D. the nature of cathode is same for all gases
but nuclie of different gases are of different
masses
Q.110 The probability of finding the electron in dxy orbital is maximum at
A. Parallel of to x-axis B. Parallel to y-axis
C. Both ✓ D. 45° angle from x and y axis
Q.111 The number of neutrons in the element 9 Be is
4
A. 4 ✓ B. 5
_______________________________________________________________________________________
C. 9 D. 13
Q.112 d-block elements are also called:
A. Alkali metal ✓ B. Alkaline earth metals
C. Transi on elements D. Electron deficient elements
Q.113 Which of the following is not a property of cathode rays, These ray:
✓ A. comprise neutron par cles B. can produce X-rays when they strike a heavy
metal anode
C. can cause reduc on reac on D. produce fluorescence in rare earth and
mineral
Q.114 Salt of ______ are colorless
A. Copper ✓ B. Zinc
C. Mn D. Cr
Q.115 [Co(NH3)6]3+will form ________ structure
A. Square planar B. Tetrahedral
✓ C. Octahedral D. Trigonal bipyramidal
Q.116 3-d series elements are present in:
A. First period B. Second period
✓ C. Third period D. 4th period
Q.117 [Zn(NH3)4]3+possess geometry
A. square planar B. hexagonal
✓ C. tetrahedral D. none of these
Q.118 Atomic radius of nickel is
✓ A. 0.115/nm B. 0.105/nm
C. 0.117/nm D. 0.132/nm
Q.119 d and f block elements are called:
A. Outer transi on elements B. Inner transi on elements
✓ C. Transi on Elements D. Chalcogens
Q.120 The number of electrons in the M shell of the element with atomic number 24 is
A. 24 B. 12
✓ C. 13 D. 8
Q.121 Pa ents are prescribed iron dietary supplement tablets to cure enaemia, which is a deficiency of haemoglobin in the
blood, Which of the following statement describes the func on of haemoglobin
A. oxygen is a ligand B. haemoglobin contains Fe2+ion
✓ C. to carry O2from lungs to muscles/ ssues D. Oxygen is a ached to iron reversibly
Q.122 [Ti(H2O)6]3+transmit
A. Blue light B. Red light
C. Yellow light ✓ D. Both A and b
Q.123 Which of the following is a typical transi on metal
A. Sc B. Y
C. Ra ✓ D. Co
Q.124 Which is not a bidentate ligand
A. C2O4-2 B. CO3-2
C. SO4-2 ✓ D. None
Q.125 Which metal is used of for cataly c hydrogena on of oils?
A. Cu B. Pt
✓ C. Ni D. Pd
Q.126 Electrons added to atomic orbitals of the same energy will remain unpaired with parallel spins un l the sub-shell is
more than half filled.,, This statement belongs to:
✓ A. Hund's rule B. pauli exclusion principle
C. Au au principle D. periodic law
Q.127 Which element pair is although transi on elements, yet have half filled s-orbitals?
A. Cu and Co B. Co and Cr
_______________________________________________________________________________________
✓ C. Cu and Cr D. Zn and Cr
Q.128 Group of element belongs to IIB group
✓ A. Zn, Cd, Hg B. Cu, Ag, Au
C. Sc, Y, La D. Ni, Pd, Pt
Q.129 Corrosion may be prevented by
A. Alloying B. Paints
C. Metallic coa ngs ✓ D. All
Q.130 When cathode rays strike the anode meta, X-rays are emi ed and not the posi ve rays. The reason is that cathode rays
are:
A. heated B. material par cles
C. knocked out electrons from anode that emit ✓ D. absorbed by the nucleus outer electrons take
X-ray when their place
Q.131 The credit of discovering neutron goes to
A. Rutherford B. Langmuir
✓ C. Chadwick D. Austen
✓ A. independent of its wavelength B. depends on its wavelength
C. equal to square D. depends on its source
Q.133 Atomic no of an element is always equal to
A. Atomic weight divided by 02 B. No.of neutrons in nucleus
C. Weight of nucleus in a.m.u ✓ D. Electrical charge on nucleus
Q.134 The wave number of the light emi ed by a certain source is 2 x 106m. The wavelength of this light is :
✓ A. 500nm B. 500m
C. 200nm D. 5 x 107m
Q.135 Which element does not belong to 4d series
A. Y B. Zr
C. Mo ✓ D. Zn
Q.136 In which of the following pairs,the numbers of electrons in the outermost shell are different?
A. As,Sb B. Ge,Sn
✓ C. In,Pt D. Se,Te
Q.137 Choose the ionic specie which has more electrons than neutrons:
A. Na+ B. Mg2+
✓ C. O2- D. Na+
Q.138 Orbitals having same energy are called:
A. hybrid orbitals B. valence orbitals
✓ C. degenerate orbitals D. d-orbitals
Q.139 The compounds which donate one electron pair in a compound is called
✓ A. Monodenatate ligand B. Central metal
C. Bidentate ligand D. Polydnetate ligand
Q.140 F-block elements are also called:
A. Non-typical transi on elements B. Outer transi on elements
✓ C. Normal transi on elements
Q.141 In the ground state,an element has 13 electrons in its M shell.The element is
A. Copper ✓ B. Chromium
C. Nickel D. Iron
Q.142 The number of spherical nodes in 3p orbitals are
✓ A. One B. Three
C. Non D. Two
Q.143 Rutherford's experiment led to the discovery of
✓ A. Nucleus B. Electron
C. Proton D. α-par cle
_______________________________________________________________________________________
Q.144 loniza on energies of the elements of group VA are greater than those of Group VI A.The reason is that:
A. group Vi A elements have greater shielding ✓ B. group V A elements half-filled atomic orbitals
effect
C. group V A element have less electronega vity
D. group V A element have greater shielding
effect
Q.145 For principle quantum number, n = 4, the total number of orbitals having 1 = 3 is
A. 3 ✓ B. 7
C. 5 D. 9
Q.146 Which of the following ions is more stable and why
A. CO2+it forms stable complexes B. CO4+it forms stable complexes
C. 2+ -
CO it has no e in 4s orbital ✓ D. CO4+it has half filled d-orbital
Q.147 The electronic configura on of Fe2+and Fe3+show that
✓ A. Fe3+is more stable than Fe2+ B. Fe2+is more stable than Fe3+
C. Both are equally stable D. Both are unstable
Q.148 Which electronic configura on is associated with the maximum no of unpaired electrons in the ground state
A. IS2, 2S2, 2P6, 3S2, 3P1 B. IS2, 2S2, 2P6, 3S2, 3P3
C. IS2, 2S2, 2P6, 3S2, 3P6, 3d1, 4S2 ✓ D. IS2, 2S2, 2P6, 3S2, 3P6, 3d4, 4S2
Q.149 Which period starts from 11Sc30Zn?
A. First period ✓ B. Second period
C. Third period D. 4th period
Q.150 The amount of Ni in stainless steel is
A. 3% B. 4%
C. 5% ✓ D. 8%
Q.151 Colnage metal are:
A. Cu B. Ag
C. Au ✓ D. All of these
Q.152 When potassium metal is exposed to violet light
✓ A. Ejec on of electrons takes place B. Ejec on of some potassium atoms occurs
C. There is no effect D. The absorp on of electrons takes place
Q.153 Group III-B series elements have electrons in d-orbitals:
✓ A. One B. Two
C. There D. Nil
Q.154 Total no of orbitals of an atom with principle quantum no value 4 is
A. 08 B. 12
✓ C. 16 D. 32
Q.155 The percentage of carbon is different types of iron products is in the order of
A. cast iron > wrought iron > steel ✓ B. wrought iron > steel > cast iron
C. cast iron > steel > wrought iron D. cast iron = steel > wrought iron
Q.156 All the following statements about transi on elements are true except
A. All of the transi onal elements are B. In aqueous solu on many of their simple ions
predominantly metallic are coloured
C. All of these elements have unfilled d-orbitals ✓ D. Most of the transi onal elements show only
one oxida on state
Q.157 d-block elements are called
✓ A. Outer transi on metal B. Inner transi on elemtents
C. Lanthanide series D. Ac nide series
Q.158 Group VI-B of transi on elements contains:
A. Zn, Cd, Hg B. Fe, Ru, Os
✓ C. Cr, Mo, W D. Mn, Te, Re
Q.159 Due to ligands' ac on of spli ng color of transi on metal compound, this change occurs at
A. S-orbital ✓ B. D-orbital
C. P-orbital D. F-orbital
_______________________________________________________________________________________
Q.160 The atomic number of an element is 35.What is the total number of electrons present in all the p-orbitals of the
ground state atom of that element?
A. 6 B. 11
✓ C. 17 D. 23
Q.161 Inters al compounds have
A. half formula B. fixed formula
✓ C. Indefinite formula D. None
Q.162 Valency of gold is:
A. +1 ✓ B. +2
C. +3 D. +4
Q.163 Transi on metals from complexes due to the par cipa on par ally filled
A. f-orbital ✓ B. d-orbital
C. s-orbital D. p-orbital
Q.164 Maximum frequency of x-rays would be emi ed from
A. Ai B. Fe
✓ C. Cu D. Ni
Q.165 For sp3d2hybridiza on, the expected geometry will be
A. Tetrahedral B. Square planar
C. Trigonal bipyramidal ✓ D. Octahedral
Q.166 Transi on metals show maximum oxida on no of
A. 7 ✓ B. 8
C. 4 D. 10
Q.167 The de-Broglie wavelength of a par cle with mass 1g and velocity 100 m/s is
✓ A. 6.63 x 10-33m B. 6.63 x 10-34m
-35
C. 6.63 x 10 m D. 6.65 x 10-35m
Q.168 Structure of P4 is
A. Trigonal ✓ B. Tetragonal
C. Hexagonal D. Monoclinic
Q.169 Potassium hexacyanoferrate (II) has the formula
✓ A. K4[Fe(CN)6] B. K3[Fe(CN)6]
C. K2[Fe(CN)5] D. K[Fe(CN)5]
Q.170 Which is the formula of tetra-ammine chloronitro pla num (VI) sulphate?
A. [Pt(NH3)4(NO2)]SO4 B. [PtNO2Cl(NH3)4]SO4
✓ C. [PtCl(NO2)(NH3)4]SO4 D. [Pt(NH3)4(NO2)Cl]SO4
Q.171 Which of the following specie has 1-proton 1-neutron and 2-Electrons
A. Deuterium ✓ B. D
C. He D. H+
Q.172 Electronic configura on of Cu+2is
A. 4S2, 3d9 B. 4s-1, 3d10
✓ C. 4S0, 3d9 D. None of these
Q.173 A 4f orbital has
A. One node B. Two nodes
✓ C. Three node D. Four nodes
Q.174 An oxygen atom has mass of:
A. 16g B. 5.316 x 1023g
✓ C. 2.657 x 10 g -23
D. 5.316 x 10-23g
Q.175 Reverberatory furnace is loned with:
A. Steel ✓ B. Carbon
C. Graphite D. Haema te
Q.176 The total number of d-block transi on element is
_______________________________________________________________________________________
A. 10 B. 14
C. 40 ✓ D. 30
Q.177 Subsidiary quantum number specifies
A. Size of orbital ✓ B. Shape of orbital
C. Orienta ons of orbital D. Nuclear stability
Q.178 Which is used to iden fy Cu2+ions
A. Nitric acid B. Sulfuric acid
✓ C. NaOH D. HCl
Q.179 Transi on elements are
✓ A. Cobalt B. Zinc
C. Scandium D. All of them
Q.180 D-block show variable oxida on state because the difference in energies between
A. ns and nd orbitals in very slight ✓ B. ns and (n - 1) d orbits is very slight
C. ns and (n - 1) orbitals is large D. np and (n - 1) d orbitals is small
Q.181 An electron has principal quantum number 3.The number of its (i) subshells and (ii) orbitals would be respec vely
A. 3 and 5 B. 3 and 7
✓ C. 3 and 9 D. 2 and 5
Q.182 The mass of the neutron is of the order of
A. 10-23kg B. 10-24kg
C. 10 kg-26 ✓ D. 10-27kg
Q.183 Number of da ve bonds to central metal ion is its
A. oxida on number B. compound number

✓ C. co-ordina on number D. da ve number
Q.184 What is the order of increasing energy of the list edorbitals in the atom of a tanium
A. 3s 3p 3d,4s ✓ B. 3s 3p, 4s 3d
C. 3s, 4s 3p, 3d D. 4s, 3s 3p 3d
Q.185 The maximum P.E that an electron can have within the atom is
✓ A. Less than zero B. Greater than zero
C. Equal to zero D. Infinite
Q.186 Which of the following is a typical metal?
A. Sc B. Y
C. Ra ✓ D. Co
Q.187 f-block elements are called:
A. Alkali metal ✓ B. Alkaline earth metals
C. Transi on elements D. Electron deficient elements
Q.188 What are alloys?
✓ A. a homogenous mixture of two or more B. a homogenous mixture of metal and a non-
elements metal
C. a homogenous mixture of two or more metals D. none of the above
Q.189 Arrange the elements, potassium, rubedium, calcium and barium in order of increasing atomic size:
✓ A. Ca < k < Rb < Ba B. Ca < K < Ba < Rb
C. k < Ca < Rb < Ba D. K < Ca < Ba < Rb
Q.190 Which of the following shows group IIIB
A. Zn, Cd, Hg B. Cu, Ag, Au
✓ C. Sc, Y, La D. Ni, Pd, Pt
Q.191 Most transi on elements show
A. Diamagne c behavior B. Ferromagne c behavior
✓ C. Paramagne c behavior D. None of the above
Q.192 Which element does not belong to 3d transi on series
A. Ti B. V
_______________________________________________________________________________________
C. Mn ✓ D. Te
Q.193 Ligands which can form two coordinate bonds from each ion or molecule to transi on metal ion are known as
A. Ligands ions B. Dentate ligands
C. Monodentate ligands ✓ D. Bidentate ligands
Q.194 In the presence of magne c field orbital of d-sub-shell is
A. Degenerate ✓ B. Non-degenerate
C. Hybrid D. Both a+b
Q.195 What type of a coordina on sphere may be:
A. anionic B. ca onic
✓ C. neutral D. all of these
Q.196 The ra o of the ioniza on energy of H and Be3+ is
A. 1:1 B. 1:3
C. 1:9 ✓ D. 1 : 16
Q.197 The highest transi on metal is
A. Titanium B. Zinc
✓ C. Scandium D. Lilhium
Q.198 Different ions will split up by different compounds to given of
A. Same colored complexes ✓ B. Different colored complexes
C. Same density complexes D. Same temperature complexes
Q.199 In Quran, al-hadeed means:
A. copper ✓ B. Iron
C. gold D. silver
Q.200 The configura on 1s2 2s2 2p5 3s1 shows
A. Excited state of O-2 ✓ B. Excited state of neon
C. Excited state of fluorine D. Ground state of fluorine atom
Q.201 Ligand exhange takes place when a stronger ligand replaced a weaker ligand in the complex.
Which pair correctly describes the rela on of a pair of ligands
A. H2Ois a stonger ligand than NH3 B. CN-ion is a weaker ligand than H2O
✓ C. CO is a stronger ligand than O2 D. Cl-is a weaker ligand than SO2
Q.202 What could be the correct representa on of quantum numbers for the last electron in F-atom
✓ A. 2, 1, 1,½ B. 2, 0, 0, ½
C. 2, 0, 0, -½ D. 2, 1, 2, -½
Q.203 Which element belong to 5d series
A. V B. Nb
C. Pd ✓ D. Hf
Q.204 The uncommon oxida on states of Mn are
A. +2, +4, +6 B. +4, +6, +7
✓ C. +1, +3, +5 D. +3, +4, +5
Q.205 A transi on element is that element of 3d series which has incomplete d-orbital in at least one of its stable ion.
Which element of 3d series is not a transi on element
A. Mn B. CO
C. V ✓ D. Zn
Q.206 Maximum number of electrons in a subshell is given by:
A. 2l + 1 B. 2l - 1
✓ C. 2(2l +1) D. 2(2l - 1)
Q.207 Which is used in filling cavi es in teeth
A. Cu(Hg) ✓ B. Ag(Hg)
C. Zn(Hg) D. Ni(Hg)
Q.208 When 3p orbital is complete, the entering electron goes into:
✓ A. 4s B. 3d
_______________________________________________________________________________________
C. 4p D. 4f
Q.209 Select the arrangement of electeromagne c radia on which starts with the lowest energy and increases to the highest
energy:
✓ A. microwave, infrared, visible, ultraviolet B. raido, visible, infrared, visible, ultraviolet
C. x-radia on , visible, infrared, microwave D. visible, ultraviolet, infrared, gamma rays
Q.210 The maximum number of electrons in a subshell for which / = 3 is
✓ A. 14 B. 10
C. 8 D. 4
Q.211 The specie which donates electrons to central metal atom in co-ordina on sphere is called
A. Anion B. Ca on
✓ C. Lignad D. Acid
Q.212 The free spaces between the metal atoms and its crystal la ce are called
A. Valance spaces B. Empty spaces
✓ C. Inters ces D. None
Q.213 The %age of C in different types of iron products is in the order of
A. Cast iron > wrought iron > steel B. Wrought iron > steel > cast iron
✓ C. Cast iron > steel > wrought iron D. Cast iron = steel > wrought iron
Q.214 In which of the following compounds iron has the lowest oxida on state
✓ A. Fe(CO)5 B. Fe2O
C. K4Fe(CN)6 D. FeSO4.(NH4)2SO4. 6H2O
Q.215 Which of the following is not related to transi on metals?
A. they have a high tensile strength B. they are duc le
C. they are malleable ✓ D. they are low mel ng points
Q.216 During the nuclear reac ons
✓ A. New elements are formed B. New compounds are formed
C. Electric clouds is involved in reac ons D. All of these
Q.217 Electrical conduc vity of calcium is much higher than any
✓ A. Transi on element B. Noble gas
C. Alkali D. Acids
Q.218 A transi on element X has a configura on [Ar] 4s13d4in its +3 oxida on state. Its atomic number is
A. 25 ✓ B. 26
C. 22 D. 19
Q.219 Valence electronic configura on of Cu+2 is:
A. 3d9 B. 4d9
✓ C. Sd9 D. 6d9
Q.220 The Mn3+has ________ color
A. Violet B. Green
✓ C. Red/brown D. No color
Q.221 Radia on emi ed by excited atoms is:
A. nuclear radia ons B. ultraviolet radia ons
✓ C. in the form of quanta D. in the form of con nuous waves
Q.222 Zn, Cd and Zn belong to the series:
A. I-B B. II-B
✓ C. III-B D. IV-B
Q.223 Oxida on state of copper is:
✓ A. +1 , +2 B. +2 , +3
C. +1, +3
Q.224 The poten al energy of electron is zero when it is at infinity beacause
A. P.E is not the character of this system B. α point is closer to nucleus
✓ C. Electron is not the part of atom at infinty D. None
_______________________________________________________________________________________
Q.225 Elements having d-orbital in process comple on are called:
✓ C. Transi on elements D. Chalcogens
Q.226 All of the following elements are correct for atomic orbitals except:
A. s-orbital has spherical shape B. p-sub energy level has 3 orbitals
✓ C. all d orbitals have four lobes D. 4s has less energy than that of 4d
Q.227 Elements found in D-block of periodic table are known as
A. Noble gases ✓ B. Transi on elements
C. Alkalis D. Acids
Q.228 6d-series is in the period:
A. 4th B. 5th
C. 6th ✓ D. 7th
Q.229 Point out the orbitals which are degenerate in a mul electron atom:
A. 1s, 2s orbitals B. 2d orbitals
C. 3s, 3p, 3d orbitals ✓ D. 3d orbitals
Q.230 How do the atomic radii of transi on elements vary from chromium to copper. Which statement describes this best
A. atomic radii increase from Cr to Cu B. atomic radii decrease from Cr to Cu
✓ C. atomic radii do not change from Cr to Cu D. the structure form Cr to Cu remains
unchanged
Q.231 Nuclear radia on is emi ed by those elements whose:
A. nuclai are stable B. molecules are stable
✓ C. nuclai are unstable D. molecules are unstable
Q.232 Balmer series of H-spectrum has different lines in the range of
A. 400-750nm B. 800-1200nm
✓ C. 100-400 D. radio frequency region
Q.233 Series start from 39Yto 48Cdis in period:
A. 4th B. 5th
C. 6th ✓ D. 7th
Q.234 In subs tu on reac on, ligands in a complex can be exchanged
A. Totally B. Par ally
C. Consecu vely ✓ D. Both A and B
Q.235 Series star ng from 57La42Hf- 80Hgis in the period:
A. 4th B. 5th
C. 6th ✓ D. 7th
Q.236 Bronze is an alloy of Cu and
✓ A. Zn B. As
C. Sb D. Sn
Q.237 Greater the number of unpaired electrons stronger will be the:
A. Binding energies ✓ B. Mel ng and boiling points
C. Paramagne sm D. All of these
Q.238 The purest form of iron is
A. Hamae te B. Cast iron
✓ C. Wrought iron D. None of these
Q.239 The total number of d-block elements is
✓ A. 110 B. 14
C. 40 D. 30
Q.240 Transi on metals form complexes due to the par cipa on of par ally filled
A. r-orbitals ✓ B. d-orbitals
C. s-probitals D. p-orbitals
Q.241 A disinfectant for water
✓ A. KMNO4 B. K2MnO4
_______________________________________________________________________________________
C. KOH D. MnSO4
Q.242 Pla ng of iron with zinc is called:
✓ A. Corrosion B. Sacrificial corrosion
C. Galvanizing D. Cathode coa ng
Q.243 The total number of orbitals in a shell with principal quantum number 'n' is
A. 2n B. 2n2
✓ C. n 2
D. n+1
Q.244 The central atom along with ligands is called
A. Complex ion ✓ B. Coordina on sphere
C. Ligand D. Complex compound
Q.245 Process of chemical decay due to atmospheric effect is called.
A. corrosion B. anodiza on
C. pudding ✓ D. oxida on
Q.246 A transi on element is defined as an element of 3d series
A. which is metal B. which has one stable ion
C. which has two stable ions ✓ D. which has at least one stable ion with
incomplete d-orbital
Q.247 The total number of transi on elements is
A. 10 ✓ B. 14
C. 40 D. 50
Q.248 d-block elements closely resemble in their physical and chemical proper es. Which statement is incorrect
A. they show variable valency B. their ions and compounds are coloured
C. they are good conductors of heat and ✓ D. their compounds are diamagne c
electricity
Q.249 f-block elements are called:
A. Outer transi on elemets B. Inner transi on elements
✓ C. Transi on elements D. Chalcogens
Q.250 The colour of transi on metal complexes is due to
A. d-d transi ons of electrons B. para magne c nature of transi on elements
C. ioniza on ✓ D. loss of s-electrons
Q.251 Point out the unit which does not belong to wave number:
A. mm-1 B. cm-1
✓ C. cm D. dm-1
Q.252 Which of the following ions contains five unpaired d-electrons
A. Cr3+ ✓ B. Fe3+
C. Mn3- D. N+21
Q.253 No cathode rays are produced in the discharge tube when gas is under ordinary pressure even if voltage of 500 to
10000 is applied:
A. temperature low B. voltage is low
C. discharge tube is not coloured ✓ D. gas does not conduct current under ordinary
presure
Q.254 Out of 110 known elements transi on elements are
A. 40 ✓ B. 60
C. 50 D. 80
Q.255 Geometry of complex compounds depends upon
A. No of ligands B. No of chelates
C. Hybridiza on of central atom ✓ D. All above
Q.256 Which of the following par cles would, on losing an electron, have a half-filled set of P orbitals?
A. C- B. N
✓ C. N- D. O+
Q.257 The geometrical shape of a transi on complexion is related to the state of hybridiza on of the central atom.What is
the hybridiza on of the shape is trigonal bipyramidal
_______________________________________________________________________________________
A. sp3 B. dsp2
✓ C. dsp3 D. d2sp3
Q.258 Coordina on number of Pt in [PtCl(NO2)(NH3)4]2-is:
A. 2- ✓ B. 4
C. 1 D. 6
Q.259 Co-ordina on no of silver is
A. 1 ✓ B. 2
C. 4 D. 3
Q.260 With increasing principle quantum number,the energy difference between adjacent energy levels in H atom
C. Remains constant D. Decreases for low value of Z and increases for
higher value of Z.
Q.261 In Physical and chemical proper es, transi on elements show
A. similari es B. dissimilari es
✓ C. both of these D. some mes similari es, some mes
dissimilari es
Q.262 The total number of orbitals possible for the quantum number n is
A. n ✓ B. n2
C. 2n D. 2n2
Q.263 4-d series is in the period:
✓ A. 4th B. 5th
C. 6th D. 7th
Q.264 The impuri es associated with ores are called
✓ A. Gangue B. Flux
C. Slag D. Silicates
Q.265 There is a decrease down group in radius of
A. Atom B. Ion
C. Nucleus ✓ D. Both A and B
Q.266 The orbitals having same energy are known as:
A. d-orbitals ✓ B. degenerate orbitals
C. hybrid orbitals D. valence orbitas
Q.267 In a galvanic cell of zinc with iron,zinc destroys, it is called.
A. Corrosion ✓ B. Sacrificial corrosion
C. Galvanzing D. Cathode coa ng
Q.268 An atom or molecule having par ally filled orbitals show:
A. Magne sm B. Paramagne sm
✓ C. Diamagne sm D. none of them
Q.269 Bohr model of atom does not explain:
A. stark effect B. zeeman effect
C. origin of line in H2spectrum ✓ D. all these
Q.270 Boh's model of atom is contradicted by:
A. Planck's quantum theory B. Quarterniza on of energy of electrons
✓ C. Heisenberg's uncertainty D. Quarterniza on of angular mambers
Q.271 Potassium chromate has formula
A. KCIO3 B. K2CO3
✓ C. K2CrO4 D. K2Cr2O7
Q.272 Elements of D-block are good conductors of
A. Heat B. Electricity
✓ C. Pressure D. Both A and B
Q.273 Which of the following has maximum e/m value of posi ve rays:
✓ A. hydrogen B. nitrogen
_______________________________________________________________________________________
C. oxygen D. helium
Q.274 At 200°C hydrogen molecules have velocity 105 cm sec-1.The de-Brogli wavelength in this case is approximately
✓ A. 2A B. 1000 A
C. 100 A D. 10 A
Q.275 In which de-excita on of electron of hydrogen atom maximum energy is released
A. n2to n1 B. n3 to n2
✓ C. nα to n1 D. n6 to n2
Q.276 The four quantum numbers of the valency electron of potassium are
A. 4,1,1,1/2 ✓ B. 4,0,0,1/2
C. 4,1,0,1/2 D. 4,4,0,1/2
Q.277 Consider the ground state of Cr atom (Z = 24).The numbers of electrons with the azimuthal quantum numbers / = 1
and / = 2 are respec vely
A. 12 and 4 B. 16 and 5
C. 16 and 4 ✓ D. 12 and 5
Q.278 A property which includes the II-B series, in transi on elements:
A. I-B B. II-B
✓ C. III-B D. IV-B
Q.279 The elements in which d or f-orbitals are incomplete are called
✓ A. transi on elements B. typical elements
C. ac nides D. lanthanides
Q.280 Stainless steel contains
A. 8% nickel ✓ B. 28% Ni
C. 18% Ni D. Ni is not present in steel
Q.281 If the value of principal quantum number is 3,the total possible values for magne c quantum number will be
A. 1 B. 4
✓ C. 9 D. 12
Q.282 A transi on element M has the electronic configura on [Ar] 3d2. What are it likely oxida on states
A. 2 and 3 B. 3 and 4
C. 2, 3 and 4 ✓ D. 2,3,4 and 5
Q.283 Each electron in an atom must have its own unique set quantum numbers this is a statement of:
A. Periodic law B. Au au principle
✓ C. pauli exclusion principle D. Hund's rule
Q.284 The shape of 2s orbital resembles
✓ A. a sphere B. an ellipse
C. an American foot ball D. an ellipse
E. a hockey puck
Q.285 Highest oxida on state of the transi on element is
A. +8 ✓ B. +7
C. +5 D. +1
Q.286 Transi on elements have property(ies):
A. Pure metals B. Complex forma on
✓ C. Alloys forma on D. All of these
Q.287 Elements showing net effect of applied magne c field are called:
A. Magne sm B. Paramagne sm
✓ C. Diamagne sm D. None of them
Q.288 Aluminium resists the process of corrosion because of the foma on of
A. aluminium nitride B. aluminium carbonate
✓ C. aluminium sulphate D. aluminium oxide
Q.289 [Cu(NH3)4]+2will form __________ structure
✓ A. Square planar B. Tetrahedral
_______________________________________________________________________________________
C. Octahedral D. Trigonal bipyramidal
Q.290 The strength of binding energy of transi on elements depends upon:
A. Number of electron pairs ✓ B. Number of unpaired electrons
C. Number of neutrons D. Number of protons
Q.291 A transi on metal complex can be recognized by various terms, which is not the proper term
A. Central metal ion B. Co-ordina on number
C. Ligand ✓ D. Geometry of complex
Q.292 D-block elements show cataly c ac vity because
A. of their large surface area B. Of their large atomic volume
✓ C. Of their ability to exist in mul ple oxida on D. Of their ability to provide finely divided
states surface for reac on
Q.293 Transi on elements form which type of bond
A. ionic bonds only B. covalent bonds only
✓ C. ionic and covalent bonds D. polar bonds
Q.294 Two electrons present in an orbital can be differen ated by:-
A. principal quantum number ✓ B. spin quantum number
C. magne c quantum number D. azimuthal quantum number
Q.295 V-B and VI-B have binding energy:
✓ A. Maximum B. Minimum
C. Zero D. Medium
Q.296 The electronic configura on of an atom/ion can be defined by the following
A. Au au principle B. pauli's exclusion principle
C. Hund's Rule ✓ D. All of the above
Q.297 Which of the following is not sub-atomic par cle?
A. proton B. electron
✓ C. deuteron D. neutron
Q.298 The oxida on number of Ni in [Ni(CO)4]is
A. +1 ✓ B. 0
C. +4 D. -4
Q.299 Azimuthal quantum number of last electron of 11Na is
A. 1 B. 2
C. 3 ✓ D. 0
Q.300 Maximum paramagne sm are present in:
✓ A. Fe+3 B. Mn+2
+3 +2
C. Fe and Cu D. Fe+3and Sc+3
Q.301 IIB elements (Zn, Cd, Hg) and III B elements (Sc, Y and La) are
✓ A. non typical transi on elements B. typical transi on elements
C. normal elements D. inner transi on element
Q.302 The radius of second Bohr's orbit is
A. 0.053 nm B. 0.053/4 nm
✓ C. 0.053 x 4 nm D. 0.053 x 20 nm
Q.303 Group II-B series elements have electrons in d-orbitals:
A. One ✓ B. Two
C. There D. Nill
Q.304 An atom or molecule with all completely filled orbitals show:
A. Magne sm ✓ B. Paramagne sm
C. Diamagne sm D. None of them
Q.305 annually, amount of iron get corroded is of its produc on.
A. 1/2 ✓ B. 1/4
C. 3/4 D. 1/10
_______________________________________________________________________________________
Q.306 A transi on element X has the electronic configuara on [Ar] 4s2 3d3. What is the electronic configura on of the ion
X3+.
A. [Ar] B. [Ar] 4s2
C. [Ar] 3d3 ✓ D. [Ar] 3d2
Q.307 Total No of regions in the spectrum are
A. 05 B. 06
✓ C. 08 D. 09
Q.308 d-block elements are called:
✓ C. Transi on elements D. Chalogens
Q.309 Which of the following is not correct for n = 5 and m = 3
✓ A. 1=4 B. 1=3
C. 1 = 0,1,2 D. S = +1/2
Q.310 Which of the following color of visible spectrum has longest wave length
A. Blue B. Indigo
C. Yellow ✓ D. Orange
Q.311 Radii of transi on elements decreases rapidly
A. At end B. At middle
✓ C. At start D. At start and end
Q.312 Which of the following sets are not the transi on elements
A. Ti, Zr, Hf B. V, Nb, Ta
C. Rn, Rb, Pd ✓ D. Fr, Ra, Ti
Q.313 Wrought Iron is prepared from pig Iron by the process:
A. Bessemer's atom B. Blast furnace
C. Pudding ✓ D. Open hearth process
Q.314 Elements in which f-orbitals are in the process of comple on are called
A. outer transi on elements B. inner transi on elements
✓ C. non-transi on elements D. radioac ve elements
Q.315 Coordina on number of Cu in [Cu(NH3)6]2+is
A. 4 B. 5
✓ C. 6 D. 8
Q.316 Coordina on number of Pt in [Pt Cl(NO2) (NH3)]2-is
A. 2- B. 4
C. 1 ✓ D. 6
Q.317 If atomic numbers of nickel and copper are 28 and 29 respec vely.Which of the following does the electronic
configura on 1s2 2s2 3s2 3p2 3d6 represent?
✓ A. Cu+ B. Cu2+
C. Ni2+ D. Ni
Q.318 The effec ve nuclear charge for an atom is less than the actual nuclear charge. This is due to:
A. paramagna sm ✓ B. shielding
C. electron pair repulsion D. penetra on
Q.319 Which of the following element's outermost orbits last electrons has magne c quantum number m = 0?
✓ A. Na B. O
C. CI D. N
Q.320 Moseley employed 38 elements as target in x-ray the ranging from
A. Ai to Au B. Na to Cu
C. Ai to Cu ✓ D. Ai to Ag
Q.321 The electron in an atom
A. Moves randomly around the nucleus B. Has fixed space around the nucleus
C. Is sta onary in various energy levels ✓ D. Moves around its nucleus in definite energy
levels.
_______________________________________________________________________________________
Q.322 Which element has 4 unpaired electrons in 3d-orbital
A. chromium - 24 B. manganese - 25
✓ C. iron - 26 D. cobalt - 27
Q.323 The correct set of quantum numbers (n,/ and m) respec vely of the unpaired electron of chlorine atom is:
A. 2,1,0 B. 2,1,1
✓ C. 3,1,1 D. 3,2,1
Q.324 Transi on elements are mostly used in construc on materials because they are
A. Hard B. Rigid
✓ C. Both A and B D. Flammable
Q.325 Which are not electromagne c radia ons?
A. x-rays ✓ B. sound waves
C. proton D. radio waves
Q.326 Which of the following is most appropriate for a proton and x-par cles moving with same speed
A. Wave no of proton is greater than α-par cle B. Wave no of proton is 1836 mes greater than
electron
✓ C. Wave length of protons is 4 mes greater D. Wave length of x-par cles is 7344 mes
than α-par cles greater than electrons
Q.327 Binding energies of group II-B is:
✓ A. Maximum B. Minimum
C. Zero D. Medium
Q.328 All 3d series elements variable oxida on states. The one shown by all 3d elements is
✓ A. 2 B. 3
C. 4 D. 5
Q.329 The mass of a neutron is mes greater than the mass of electron:
A. 540 ✓ B. 1840
C. 1480 D. 2000
Q.330 Which of the following has more unpaired d-electrons?
A. Zn+ ✓ B. Fe2+
C. Ni3+ D. Cu+
Q.331 Spli ng of spectral lines when atoms are subject to strong electric field is called:
✓ A. Zeeman effect B. stark effect
C. photoelectric effect D. compton effect
Q.332 No of lobes of f-orbital are
A. 02 B. 04
C. 06 ✓ D. 08
Q.333 Transi on elements show:
✓ A. Magne sm B. Paramagne sm
C. Diamagne sm D. None of them
Q.334 An oxidixing agent
✓ A. K2Cr2O7 B. H2SO4
C. FeSO4 D. MnSO4
Q.335 Transi on elements differ from s and p block elements due to their characteris c proper es. What is not the
characteris c property of transi on elements
A. transi on elements show variable oxida on B. their salts are coloured
states
C. they can be used as catalyst
✓ D. all of them are metals
Q.336 Which one of the following will have some no of electrons as an alpha par cle
A. H ✓ B. H+
C. He D. Li+1
Q.337 The rules which describes the distribu on of electron in atomic energy level are au a's principal Hund's rule and pauli
exclusion principle. The Puli exclusion
✓ A. energy of the orbital B. orienta on of orbital in space
_______________________________________________________________________________________
C. spin of the electron should have opposite D. the fact that two electron in the same orbital
spins
Q.338 Bronze is an alloy which contains
✓ A. 60% Cu B. 70% Cu
C. 80% Cu D. 99% Cu
Q.339 Elements having f-orbital in process of comple on are:
✓ C. Transi on elements D. Chalogens
Q.340 Bronze is an alloy of
✓ A. 90% Cu + 10% Sn B. 90% Cu + 10% Fe
C. 90% Sn + 10% Cu D. None of the above
Q.341 In a comparison with S-block elements, mel ng point of transi on elements are
✓ A. Higher B. Lower
C. Same D. Constant
Q.342 When electrons revolve in sta onary orbits.
✓ A. There is no change in energy level B. They vecome sta onary
C. They are gaining kine c energy D. There is increase in energy
Q.343 A photographic plate is coated with an emulsion of silver nitrate and
A. AgCl B. Agl
✓ C. AgBr D. NaNO3
Q.344 The Ligand which has a ring in its structure when it combines with central metal is called
A. Polydemtate ligand ✓ B. Chelate
C. Monodentate ligand D. Hydrate
Q.345 Which is the formula of tetra-ammine chloro-nitro pla num (IV) sulphate
✓ A. [Pt (NH3)4(NO2)] SO4 B. [Pt NO2Cl(NH3)4] SO4
C. [Pt Cl(NO2) (NH3)4] SO4 D. [Pt (NH3)4(NO2) Cl] SO4
Q.346 Element having the smallest atomic radius among the followings is:
A. Sr B. Li
C. Rb ✓ D. Ne
Q.347 Electrons in 5f energy level are filled up in case of
A. Lanthanides B. Transi on metals
✓ C. Ac nides D. Rare gases
Q.348 S-block elements closely ramble in their physical and chemical proper es. Which statement is incorrect
A. They show variable valency B. Their ions and compounds are colored
C. They are good conductors of heat and ✓ D. Their compounds are diamagne c
electricity
Q.349 Salts of dichromic acids are:
A. Chromates B. Dichromates
C. Silicates ✓ D. Silicones
Q.350 All 3d series elements show variable oxida on states. The one shown by all 3d elements is
✓ A. +2 B. +3
C. +4 D. +5
Q.351 Colnage metal is:
A. Co ✓ B. Ag
C. Pt D. Ni
Q.352 The orbital in Rutherford's model is
A. Spiral ✓ B. Circular
C. Both D. None
Q.353 What is the electronic configuarion of Fe3+ion, Fe has 26 e-s
A. 1s3,2s2,2p6,3s2,3p6,3d6,4s2 B. 1s2,2s2,2p6,3s2,3p6,3d4,4s2
C. 1s2,2s2,2p6,3s2,3p6,3d5,4s2 ✓ D. 1s2,2s2,2p6,3s2,2p6,3d5
_______________________________________________________________________________________
Q.354 How many electrons can be accumulated in sub-shell with n=3,1=1
✓ A. 06 B. 10
C. 32 D. 14
Q.355 Mel ng in presence of coke and silica is called
A. Caking B. Cooking
✓ C. Smel ng D. Roas ng
Q.356 The atomic radii of elements lie in the order of
A. 108cm B. 10-12cm
✓ C. 10 cm-8
D. 1012cm
Q.357 The total number of transi on elements is:
A. 10 B. 14
C. 40 ✓ D. 50
Q.358 The less reac vity of transi on metal is due to
A. high heats of sublima on B. high ioniza on energies
C. low heats of salva on ✓ D. all these
Q.359 The quantum number which determines the shape of the orbitals is
A. Principal ✓ B. Azimuthal
C. Magne c D. Spin
Q.360 Iron was produced in sub-con nent since:
A. prehistoric mes B. 1500 BC
C. 2500 BC ✓ D. 600 BC
Q.361 Transi on elements are
A. Insula on B. Good conductors
C. Bad conductors ✓ D. None of these
Q.362 1 erg of energy corresponds to
A. 6.02 x 1023J/mol ✓ B. 6.02 x 1016J/mol
C. 1 erg/mol D. 10-7J/mol
Q.363 The lightest atom with completely filled 3d-orbital in the ground state is
A. Ni ✓ B. Cu
C. Zn D. Ga
Q.364 Which element has zero binding energy?
A. Zn ✓ B. Co
C. V D. W
Q.365 Iron is known to Egypt since:
✓ A. prehistoric mes B. 1500 BC
C. 2500 BC D. 600 BC
Q.366 Which of the following set of quantum numbers is possible
A. n = 3, 1= 2, m = 1, s = 0 B. n = 3, 1= 0, m = 0, s = 0
✓ C. n = 1, 1= 2, m = 2, s = ½ D. n = 1, 1 = 0, m = 2, s = 1/2
Q.367 Cu2+with d9electronic configura on appears
A. yellow B. pink
✓ C. blue D. green
Q.368 In Millikan oil-drop experiment the charges on several different oil drops were as:-5.92, -4.44, -2.96, -8.88. The units
are orbitrary , choose the likely value of the electronic charge in these orbitrary units
A. -1.11 ✓ B. -1.48
C. -2.22 D. -2.96
Q.369 Colour of the glow produced in the discharge tube:
✓ A. depends on the gas used in the discharge B. depends on the pressure in the discharge
tube tube
C. does not depend on the nature of the gas D. depend on the metal used as cathode
used in the discharge tube
_______________________________________________________________________________________
Q.370 Rutherfords sca ering experiment is related to size of the
A. Atom ✓ B. Nucleus
C. Orbit D. All of these
Q.371 This shape of cobalt hexa ia mine ca on, which has its central cobalt atom surrounded by six ammonia molecules is
A. Tetrahedral ✓ B. Octahedral
C. square planer D. Trigonal
Q.372 When alumina is placed in the path of cathodes rays it glows
✓ A. Red B. Yellow
C. Pale yellow D. Green
Q.373 Rus ng as speeded up in the presence of
A. Acid B. Base
C. Salts ✓ D. A and c
Q.374 Why Cr and Cu has half filled s-orbitals?
A. They belong to s-block elements B. They are alkali metals
C. This gives stability to d-orbitals ✓ D. They are alkaline earth metals
Q.375 Mel ng point, boiling point and binding energies of transi on elements is high because of:
A. Electrons are present in d-orbitals only B. All are metals and form alloys
✓ C. All show variable oxida on state D. Electons in 's' and 'd'- orbitals involve in
binding
Q.376 How many orbitals are allowed for principle quantum number (n) of 3?
A. 5 B. 6
C. 8 ✓ D. 9
Q.377 Valence electronic configura on of Au+3is:
A. 3d9 B. 4d9
C. Sd9 ✓ D. 6d9
Q.378 The coordina on number of iron in [Fe(H2O)6]3+is
A. 2 B. 3
C. 4 ✓ D. 6
Q.379 E. D. T. A is
A. mono-dentate B. bi-dentate
✓ C. polydentate D. having three Ione pairs of electrons
Q.380 Quantum number values for 2p orbitals are:
A. n=1 , l = 2 B. n=1 , l = 0
C. n=2 , l = 0 ✓ D. n=2 , l =1
Q.381 The radius of the second orbit is:
A. 2.11 x 10-11m B. 1.006A∘
✓ C. 2.1A∘ D. 2.11 X 10-12M
Q.382 A typical transi on element is:
A. Sc B. Y
C. Zr ✓ D. Zn
Q.383 Iron is known to the Chinese since:
A. pre-historic mes B. 1500 BC
C. 2500 BC ✓ D. 600 BC
Q.384 An important biological molecule containing iron is haemoglobin. Which statement describes the role of haemoglobin
in the body?
A. haemoglobin generates oxygen in the blood ✓ B. haemoglobin transport oxygen in the blood
C. haemoglobin acts as a catalyst D. haemoglobin oxidises Fe2+to Fe3+
Q.385 CuSO4. 5H2Ois used to prepare
✓ A. Transi on complex B. Fehling's A sol
C. Fehling's B sol D. Fehling's sol
Q.386 Color of silver iodide is
_______________________________________________________________________________________
✓ A. Deep yellow B. White
C. Blue D. Pink
Q.387 For which of the following sets of quantum numbers an electron will have the highest energy?
A. 3,2,1,1/2 ✓ B. 4,2,-1,1/2
C. 4,1,0,-1/2 D. 5,0,0,1/2
Q.388 When an ac ve metal like AL come in contact with less ac ve element like Cu, then it produces ______
A. Voltaic cell B. Galvanic cell
C. Electroly c cell ✓ D. A and B
Q.389 The property which determines the posi on of an element in modern periodic table is
A. Chemical reac vity B. Electronega vety
C. No of valence electrons ✓ D. No of protons in nucleus
Q.390 No of possible spectral lines when electrons in hydrogen atom de-excite from N-shell to lower shells
✓ A. 06 B. 04
C. 03 D. 02
Q.391 Typical transi on elements are transi on elements except the group:
A. I-A and II-A B. II-A and II-B
✓ C. II-B and III-B D. III-B and III-A
Q.392 [Ti(H2O)6]3+absorb
A. Blue light B. Red light
✓ C. Yellow light D. Both A and B
Q.393 Which of the following is a not typical transi on element?
✓ A. Cr B. Mn
C. Zn D. Fe
Q.394 Roentgen discovered X-ray and Mosley found that the frequency of the X-rays emi ed from anode increases with:
✓ A. increases in the mass number of the metal B. increase in the proton number of the metal
used as anode used an anode
C. decrease in the mass number of the metal D. decrease in the proton number of the metal
Q.395 Oxida on of state of iron are :
A. +1 , +2 B. +2 , +3
✓ C. +1, +3 D. +2, +4
Q.396 Chose the correct statement about 2nd ioniza on energy:
A. it is equal to the lst ioniza on energy B. it is always less than lst ioniza on energy
C. it may be greeter or less than the ist ioniza on ✓ D. it is always greater than lst ioniza on energy
depending upon the nature of the element
Q.397 Bell metal is an alloy of Sn and
✓ A. copper B. iron
C. zinc D. magnesium
Q.398 Spin quantum number was given to explain
A. Self rota on of electrons B. Doublet line structure of H-Atom
C. Pauli s exclusion principle ✓ D. All of above
Q.399 The colour of Cr3+ion is
A. violet B. blue
C. pink ✓ D. green
Q.400 Which is the name of the complex [Ni(CO)4]?
✓ A. tetracarbonylnickel (o) B. tetracabonylnickel
C. teracarbonylnickel (II) D. tercarbonylnickel (IV)
Q.401 The most stable oxida on state of Mn is
A. 4 B. 5
C. 7 ✓ D. 2
Q.402 Fe3+and Mn2+ are strong paramagne c because the number of unpaired electrons in each is
A. 4 ✓ B. 5
_______________________________________________________________________________________
C. 6 D. 7
Q.403 Stability of Cu-metal is due to ______ filled of d-orbital
A. Half ✓ B. Completely
C. Par ally D. Quarterly
Q.404 Posi ve par cles in discharge tube is produced by ioniza on of gas molecules which is caused by:
A. gas molecules collide with anode B. gas molecules are at high temperature
✓ C. cathode rays remove the electrons from gas D. gas molecules produce X-rays
mlecules
Q.405 Which alloy contains 50% copper, 25% zinc and 25% nickel?
A. German silver B. gun metal
C. bell metal ✓ D. brass
Q.406 Which of the following has the highest energy?
A. x-ray s ✓ B. gamma rays
C. radio waves D. ultra-violet raida ons
Q.407 Stainless steel contains Cr upto
A. 12% ✓ B. 18%
C. 10% D. 5%
Q.408 Transi on metal ion give color due to
✓ A. d-d transi on B. s-p transi on
C. p-p transi on D. Charge transfer
_______________________________________________________________________________________
12 Nitrogen and Sulphur
Q.1 Choose the correct statement:

A. each bonding molecular orbital can ✓ B. as bonding molecular orbital become more
accommodate only one electron stable, an bonding molecular orbital
become equally less stable.
C. In molecular orbitals , the number of bonding D. the molecular orbitals in a molecular orbitals
electrons equals the number of an bonding in molecular equals twice the number of
electrons cons tuent atomic orbitals.
Q.2 Longest bond length is expected for
A. O2 B. O+12
C. O-12 ✓ D. O2-2
Q.3 Ozone is effec vely removed by
A. TNT ✓ B. CFCs
C. PVC D. CNG
Q.4 The number and type of bonds between carbon atoms in calcium carbide are
A. Two sigma,one pi B. Two sigma,two pi
C. One sigma,one pi ✓ D. One sigma,two pi
Q.5 Which of the following is not used as disinfectants
✓ A. NaCl B. NaOCl
C. Cl2 D. HOCl
Q.6 Which of the following has the greatest covalent character?
✓ A. LiCl B. NaCl
C. KCI D. RbCI
Q.7 In human being the liver cancer is due to
A. Oxygen deficiency ✓ B. Chloroform
C. Carbon dioxide D. Methane
Q.8 Which of the sub-atomic par cles is not charged?
A. proton ✓ B. neutron
C. electron D. all these
Q.9 Forma on of chemical bond between atoms of elements is based on:
A. electronega ve character of elements ✓ B. octet rule
C. electroposi ve character of elements D. pauli exclusion principle
Q.10 Which three elements are needed for the healthy growth of plants
A. N, S, P B. N, Ca, P
✓ C. N, P, K D. N, K, C
Q.11 Which of the following would have a permanent dipole moment?
A. BF3 B. SiF4
✓ C. SF4 D. XeF4
Q.12 Potassium helps plants to carry out
✓ A. Photosynthesis B. Germina on of seeds
C. Healthy flowering D. Both b and c
Q.13 Oleum is dissolved in ________ to get pure sulphuric acid
A. H 2O 2 ✓ B. H 2O
C. NaOH D. H2SO3
_______________________________________________________________________________________
Q.14 When two hydrogen atoms approach to form a chemical bond:
A. the energy of atoms increases ✓ B. the a rac ve forces dominate the repulsive
forces
C. the two atoms start ioniza on D. the repulsive forces dominate the a rac ve
fordes
Q.15 Which of the following is polar and has central atom with SP2 Hybridiza on
✓ A. H2CO3 B. S I F4
C. BF3 D. HCIO2
Q.16 Which are metalloid?
A. Nitrogen and phosphorous ✓ B. Arsenic and an mony
C. Phosphorous and arsenic D. An mony and bismuth
Q.17 Reac on of copper with cone HNO3gives a gas:
A. NO ✓ B. NO2
C. N 2O D. N2
Q.18 Inter molecular forces in solid hydrogen are
A. Covalent forces ✓ B. Van der Waal forces or London dispersion
forces
C. Hydrogen bonds D. All of these.
Q.19 The elements like boron, chlorine, cobalt, copper etc are added in small amounts to the soil. They are called
A. macronutrients ✓ B. trace elements
C. micronutrients D. addi ves
Q.20 Which gas is heavier than air?
A. CO2 B. NH3
C. NO4and SO2 ✓ D. All of these
Q.21 Which gas will produce in the reac on of zine with dil HNO3?
A. NO B. NO2
✓ C. N2O D. N 2O 2
Q.22 The water is considered to be polluted when the concentra on of oxygen in it is
A. 6 - 9 ppm B. 6 ppm
C. 8 ppm ✓ D. Less than 4 ppm
Q.23 Laughing gas is chemically:
A. NO ✓ B. N2O
C. NO2 D. N 2O 4
Q.24 Kl is to iodine during reac on with FeSO4
✓ A. Oxidized B. Reduced
C. Decomposed D. Dispropor onate
Q.25 A student subtracted 0.00055 from 102345678 and reported the result as 10.23401.But his friend told him that result
was wrong. What is the correct result?
✓ A. 10.23 B. 10.234017
C. 10.2340178 D. 10.234
Q.26 Molecule of oxygen is paramagne c because
A. Na > NA B. NA > NB
C. N A = NB ✓ D. It has unpaired electrons
Q.27 Which are the possible products? 6Hl + 2HNO3(conc.)→
A. NO B. H 2O
C. l2 ✓ D. A, b, c
Q.28 A bond between tow atoms my be obtained by sharing of electrons is known as:
A. ionic bond ✓ B. covalent bond
C. coardinate covalent bond D. da ve bond
Q.29 A compound is more likely to be covalent if the__________:
✓ A. ca on has a small size and high charge B. anion has a small size and high charge
C. ca on has a large size and a small charge D. anion has a small size and a small charge
_______________________________________________________________________________________
Q.30 Which one of the following chars when warmed with conc. H2SO4
A. Protein B. Fat
C. Hydrocarbon ✓ D. Carbohydrate
Q.31 Catalyst use in Haber process
A. V 2O 5 B. V2O5and pt
C. Fe ✓ D. Pieces of Fe in fused mixture of
2O 3
and
2
MgO, Al SiO
Q.32 H2SO4cannot be used
✓ A. A a pickling agent B. In lead storage ba eries
C. In white paints D. In the manufacture of dyes
Q.33 Which one is nitrogen fer lizer among the following
A. Calcium sulphate ✓ B. Urea
C. Mangnesium carbonate D. Potassium phosphate
Q.34 Which of the following statements about posi ve about posi ve ions is incorrect?
A. they are also known as ca ons B. they are formed when electrons are removed
from atoms
✓ C. they are larger than the atoms from which D. they are smaller than the atoms from which
they were formed they were formed
Q.35 Micro-nutrients are required in quan ty ranging from
A. 4g-40g ✓ B. 6g-200g
C. 6kg-200kg D. 4kg-40kg
Q.36 Among the following the molecule which is planner is
✓ A. BCI3 B. NH3
C. NF3 D. SO2CI2
Q.37 Ammonium nitrate fer lizer is not used for which crop
A. co on B. wheat
C. sugar cane ✓ D. paddy rice
Q.38 The fer lizer contains 33 - 35% N is
✓ A. Ammonium nitrate B. Potassium nitrate
C. Urea D. Ammonia
Q.39 Maximum hydrogen bonds in water are,
✓ A. 4 B. 3
C. 2 D. 8
Q.40 Which of the following molecules shows pentagonal bipyramidal geometry
A. SF6 ✓ B. IF7
C. PCI5 D. None of these
Q.41 Dissolu on of SO3in H2O produces
✓ A. mist of H2SO4 B. 98% H2SO4
C. Oleum D. None of these
Q.42 A reddish brown gas is:
A. NO B. NO2
✓ C. N2O D. N2
Q.43 Which one of these is weakest?
A. Ionic bond B. Covalent bond
C. Metallic bond ✓ D. Van der Waal's forces
Q.44 Compound which contains six bonding electrons is
A. C 2H 4 B. CO2
C. H 2S ✓ D. NCI3
Q.45 Ionic radius in a period form le to right
A. decreases B. increases
C. first increases then decreases ✓ D. first decreases then increases
Q.46 Which of the following molecules has no net dipole moment?
_______________________________________________________________________________________
A. HCI B. H 2O
✓ C. CCI4 D. CH3CI
Q.47 In OF2, number of bond pairs and ione pairs of electrons are resoec vely
A. 2,6 ✓ B. 2,8
C. 2,10 D. 2,9
Q.48 Which property is not present in non-metals:
A. Predominantly covalent B. Poor conductor
C. Hig E.N. value ✓ D. High electroposi vity
Q.49 Freshly prepared Fe (OH)3is used to remove
A. dust par cles from SO2 B. Water vapours from SO2
C. Fe2O3from SO2 ✓ D. Arsenic oxide from SO2
Q.50 SO2on dissolu on in atmospheric moisture produces ______ which is oxidized to sulphuric acid
A. Sulphur oxide B. Ozone
✓ C. Sulphurous acid D. Both a and c
Q.51 The element having highest value of 2nd I.P is
A. F ✓ B. Na
C. Ne D. o
Q.52 Nitrogen gas is commercially obtained from
A. Liquid NH3 ✓ B. Liquid air
C. HNO3 D. Nitrogen fixing becteria
Q.53 Which is explosive compound ?
A. NaNO3 ✓ B. NH4NO3
C. AgNO3 D. Ca(NO3)2
Q.54 The most commonly and widely used nitrogen fer lizer in Pakistan is
✓ A. urea B. ammonium nitrate
C. ammonium sulphate D. ammonium chloride
Q.55 High quality nitrogenous fer lizers
A. Ammonia B. (NH4)2HPO4
✓ C. Urea D. KNO3
Q.56 Which molecule contains only six bonding electrons?
A. C 2H 3 B. C 2F6
C. H 2O ✓ D. NF3
Q.57 PCl5 at 100 oC
A. Melts B. Boils
✓ C. sublimesd D. evaporates
Q.58 The process not involved in improvement of water quality is
A. Coagula on B. Aera on
C. Chlorina on ✓ D. Self-oxida on reduc on
Q.59 Reac on of copper with nitrous oxide gives a gas:
✓ A. N2 B. NO
C. NO2 D. O2
Q.60 Skin turns yellow in contact with conc. HNO3because
A. Water is removed from the skin B. Skin is burnt
C. Nitro-cellulose is formed ✓ D. Xanthoproteins are formed
Q.61 Sea gets polluted by accidental oil spills and
A. Atmospheric pressure B. Nitrogen gas
✓ C. Cargo oil tankers D. Aero plane
Q.62 Which of he following successive ioniza on energies belong to group II elements?
A. 577,1820,2740,11600,14800 ✓ B. 736,1451,7740,10500,13600
C. 428,3070,4600,5860,7990 D. 320,600,1110,1700,5650
_______________________________________________________________________________________
Q.63 Noble gases are:
A. light substance B. heavy substances
✓ C. stable substances D. reac ve substances
Q.64 Which molecule is polar among the following?
A. carbon tetrachloride B. carbon dioxide
C. ethane ✓ D. methanol
Q.65 The smog having high constents of SO2is
A. Neutral smog ✓ B. Reducing smog
C. Oxidizing smog D. Ar ficial smog
Q.66 The elements like nitrogen, phosphorus, calcium are added in large amounts to the soils and are called
✓ A. nutrients elements B. basic elements
C. trace elements D. addi ves
Q.67 Which of the following has the highest electron affinity
A. F ✓ B. Ci
C. Br D. I
Q.68 Calcium carbonate contains oxygen in it:
✓ A. 48% B. 50%
C. 53% D. 60%
Q.69 Which element of group IV-A does not use d-orbital?
✓ A. N B. P
C. As D. Sb
Q.70 Which hydrogen halide among the following has the highest percentage of ionic character?
✓ A. HF B. HCI
C. HBr D. HI
Q.71 The successive ioniza on energies, in kJ mol-1,of an element X are given below.
870 1800 3000 3600 5800 7000 13200
What is X?
A. 33As B. 40Zr
✓ C. 52Te D. 53I
Q.72 Which element belongs to group V-A?

A. Cs B. Ba
C. Sr ✓ D. Bi
Q.73 Main source of SO2in atmosphere is
✓ A. Volcanic erup on B. Burning of petrol
C. Decay of organic ma er D. None of these
Q.74 Which one of the following is not a micro-nutrient for plants?
A. Zinc B. Manganese
C. Boron ✓ D. Phosphorous
Q.75 Keeping in view the bonding molecular orbitals, find the incorrect statement:
A. every electron in the bonding molecular B. bonding molecular orbitals possess less
orbital contributes to the a rac on between energy than atomic orbitals from which they
atome are formed
C. bonding molecular orbitals are formed when ✓ D. bonding molecular orbitals haves low
the electrons waves are undergo construc ve electron density between the two nuclei
interference
Q.76 What is the approximate value of the O-C-O bond angle in ethanoic acid is
A. 45° B. 90°
C. 109° ✓ D. 120°
Q.77 Which of the bonds shown by the has the greatest polarity?
A. H-CI B. H-NH2
✓ C. H-OH D. H-SH
Q.78 Which can be prepared from HNO3?
_______________________________________________________________________________________
A. T .N. T B. Fer lizers
C. Picric acid ✓ D. All of these
Q.79 An bonding MO is formed by
A. Addi on of atomic orbitals ✓ B. Subtrac on of atomic orbitals
C. Mul plica on of atomic orbitals D. None of these
Q.80 Which of the following has zero dipole moment
A. CI-F ✓ B. PCi3
C. SiF4 D. CFCI3
Q.81 Sulphuric acid is used:
A. As fer lizers B. As dehydra ng
C. As oxidizing agent ✓ D. All of above
Q.82 Which of the following synthe c fer lizer do not make soil acidic
A. urea B. thin urea
C. ammonium phosphate ✓ D. potassium nitrate
Q.83 Acidifica on of the soils due to addi on of synthe c nitrogen fer lizer, is corrected by using
A. gypsum B. sodium nitrate
✓ C. limostone D. Potassium nitrate
Q.84 Which of the following has zero deople-moment?
A. CIF B. PCI3
✓ C. SiF4 D. CFCI3
Q.85 The yellow color present in the photo chemical smog is due to presence of the
A. Carbon dioxide ✓ B. Nitrogen dioxide
C. Chlorine D. All
Q.86 Which one of the following is produced where SO3is dissolved in conc.H2SO4?
A. Oleum B. Conc. H2SO4
C. Pyrosulphuric acid ✓ D. Both a and c
Q.87 Which one of the following is an inorganic fer lizer
A. Manure B. Urea
✓ C. Ammonium nitrate D. All
Q.88 The temperature of the incinera on of industrial and hazardous waste process has range
A. 900 - 1000°C B. 250 - 500°C
✓ C. 950 - 1300°C D. 500 - 900°C
Q.89 Decomposi on of lead nitrate gives:
A. N 2 & O2 B. N 2O & O 2
✓ C. NO2& O2 D. NO & O2
Q.90 which of the following is a substance ?
A. brass B. tape water
✓ C. graphite D. sea water
Q.91 Why is the pressure inside the chamber is kept 2 - 3 atmosphere?
✓ A. At high pressure SO3is very corrosive B. At low pressure SO3is very stable
C. Low pressure increases the percentage into D. None of the above
2 3
conversa on of SO SO
Q.92 The force which holds the atoms together to from a compound id know as:
A. van der waal's force B. London force
✓ C. chemical bond D. dispersion force
Q.93 The bond order of individual C - C bond is benzene is
A. One B. Two
✓ C. Between one and two D. One and two alternately
Q.94 Which of the following in incorrect statement about nitrogen importance
A. It enhances plant growth B. It is involved in the synthesis of protein and
nucleic acids
_______________________________________________________________________________________
✓ C. It accelerates fruits and flowers growth D. It is involved in the chlorophyll synthesis
Q.95 In acetylene molecule the two carbon atoms are linked by
✓ A. One sigma bond and two pi-bonds B. Two sigma bonds and one pi-bond
C. Three sigma bonds D. Three pi-bonds
Q.96 The item of an element is:
A. the independent par cle B. the fundamental par cle
C. the charged par cle ✓ D. the smallest par cle
Q.97 Temperature required to connect N2 & O2 into NO is:
A. 1000°C B. 2000°C
✓ C. 3000°C D. 4000°C
Q.98 The percentage of nitrogen in ammonium nitrate is
✓ A. 32 - 33.5% B. 34 - 36%
C. 40 - 45% D. none of these
Q.99 Allotropic forms of sulphur are
A. Two ✓ B. three
C. Four D. Five
Q.100 The substances added in the paints for improving the mechanical proper es is called
A. pigment ✓ B. filter
C. stabilizer D. binder
Q.101 The decreasing order of bond dissocia on energy of O2, O+12,O-12,ε1 O2-2is
A. O-2>O-22>O2>O+12 ✓ B. O+2>O2>O-2>O2-2
C. O2>O+2>O2-2>O-12 D. O-2>O2-2>O+12>O2
Q.102 In a molecule non-bonding electron pairs affect
A. Bond length ✓ B. Bond angle
C. Bond strength D. Type of bond
Q.103 In the reduc on of HNO3to N2O, the number of moles of electrons involved per mole of HNO3is
A. 8 ✓ B. 4
C. 3 D. 6
Q.104 Silica contains oxygen by weight.
A. 48% B. 50%
✓ C. 53% D. 89%
Q.105 How much quan ty of total water is available as fresh water
A. 3% ✓ B. 1%
C. 10% D. 21%
Q.106 The structure of ICI-2 is
A. Trigonal ✓ B. Trigonal bipyramidal
C. Octahedral D. Square planar
Q.107 The most stable phosphorus allotrope is
A. White B. Red
✓ C. Black D. All
Q.108 According to MO Theory the species O+2 possesses
✓ A. Bond order of 2.5 B. Three unpaired electrons
C. Diamagne c character D. Stability lower then O2
Q.109 When H2SO4dissolve in water temperature raises up to
A. 105°C B. 115°C
✓ C. 120°C D. 130°C
Q.110 Water is essen al for life on
A. Moon B. Space
✓ C. Earth D. Sun
Q.111 What are non-metals?
_______________________________________________________________________________________
A. Sb & Bi B. P & Bi
✓ C. N&P D. As & N
Q.112 Ionic bond is formed between metals and non-metals because
A. I.P. of metals is high and E.A of non-metals is ✓ B. I.P. of metals is low and E.A of non-metals is
low high
C. I.P of metals and E.A of non-metals is low D. I.P of metals and E.A of non-metals is high
Q.113 According to VSEPR theory, the shape of the water molecule is
A. Octahedral ✓ B. Distorted tetrahedral
C. Planar triangle D. Linear
Q.114 When Tin react with conc. HNO3it produce
A. Stannous nitrate B. Stannic acid
C. NO2 ✓ D. Both b and c
Q.115 HO2forms acidic solu on:
A. Red ✓ B. Blue
C. Green D. Brown
Q.116 The number of an bonding electron pairs in O2-2 molecular ion on the basis of MOT is
✓ A. 4 B. 3
C. 2 D. 5
Q.117 How much quan ty of water is the domes c use
✓ A. 0.08% B. 16%
C. 24% D. 90%
Q.118 What are the bond engles in the PH3 molecule likely to be?
A. 90∘ ✓ B. 104∘
C. 109∘ D. 120∘
Q.119 Which of the following molecules has the lowest value of dipole moment
✓ A. CO B. NH3
C. NF3 D. SO2
Q.120 The number of σ and π-bonds present in pent-4-en-1 yn e is
A. 3, 10 B. 9, 4
C. 4, 9 ✓ D. 10, 3
Q.121 Most concentrated solid nitrogen fer lizer is
A. Ammonia B. Nitrates
✓ C. Urea D. Calcium super nitrate
Q.122 In BrF3 molecule,the lone pairs occupy equatorial posi ons to minimize
A. Lone pair-lone pair repulsion only B. Lone-pair bond pair repulsion only
C. Bond pair-bond pair repulsion only ✓ D. Lone pair-lone pair repulsion and lone pair-
bond pair repulsion
Q.123 Fluorine molecule is formed by
✓ A. The axial p-p overlap B. The sidewise p-p overlap
C. The axial s-p overlap D. The overlap of two sp2hybrid orbitals
Q.124 Which of the following nitrogen fer lizer contains more nitrogen
A. NaNO3 B. KNO3
C. NH4NO3 ✓ D. urea
Q.125 Enolic form of acetone contains sigma bonds Pi-bonds and lone pairs respec vely
✓ A. 9, 1, 2 B. 8, 2, 2
C. 10, 1, 1 D. 9, 2, 1
Q.126 Maghesium oxide is used to line industrial furnaces because it has a very high mel ng point?
Which type of bond needs to be broken for magnesium oxide to melt?
A. co-ordinate B. covalent
✓ C. ionic D. metallic
Q.127 The most suitable method of the separa on of a mixture of ortho and para-nitrophenol mixed in the ra o of 1:1 is
_______________________________________________________________________________________
✓ A. Dis lla on B. crystalliza on
C. Vapourisa on D. Colour spectrum
Q.128 Catalyst employed in the manufacture of sulphuric acid in contact process is
✓ A. Vanadium (v) oxide B. Chromium oxide
C. Iron (iii) oxide D. Nickel
Q.129 Nitrogen is obtained by the frac onal dis lla on of
A. Petroleum ✓ B. Liquid air
C. Water gas D. None of these
Q.130 The structure of CH2 = C = CH2 is
A. Linear ✓ B. Planar
C. Non-planar D. Has several resonance structures
Q.131 The ozone depla on in the stratosphere is mainly due to the reac on of ozone with
A. Freous B. CFCs
✓ C. Both A and B D. None
Q.132 The shape of the molecule SF2CI2 is
✓ A. Trigonal bipyramidal B. Cubic
C. Octahedral D. Tetrahedral
Q.133 Which has garlic like odour:
A. N 2O B. NO
C. NO2 ✓ D. P 2O 5
Q.134 Ammonium nitrate fer lizer is not used for the crop
A. Co on B. Wheat
C. Sugar cane ✓ D. Paddy rice
Q.135 KNO3has ______% nitrogen
A. 10 ✓ B. 13
C. 18 D. 46
Q.136 In double bond connec ng two atoms there is a sharing of
A. 2 eletrons ✓ B. 4 electrons
C. 1 electron D. 6 electrons
Q.137 A gas, itself not combus ble but rekindle a glowing splinter?
A. NO B. NO2
✓ C. N2O D. N 2O 3
Q.138 What element is not essen al the growth of plants and is not required in the fer lizers
A. nitrogen ✓ B. potassium
C. phosphorus D. barium
Q.139 Which is called laughing gas?
A. NO B. NO2
✓ C. N2O D. N 2O 3
Q.140 Which of the following does not possess tetrahedral structure
A. SO2CI2 B. SO2-4
✓ C. SF4 D. SIO2-4
Q.141 H-bonding is not present in
A. Glycerine B. Water
✓ C. Hydrogen sulphide D. Hydrogen fluoride
Q.142 Hydrogen chloride molecule contains
✓ A. Covalent bond B. Double bond
C. Co-ordinate bond D. Electrovalent bond
Q.143 Calcium carbonate contains oxygen
✓ A. 48% B. 50%
C. 53% D. 89%
_______________________________________________________________________________________
Q.144 Which solid more than one kind of chemical binding ?
A. brass B. copper
C. diamond ✓ D. ice
Q.145 What is the best explana on for the low reac vity of nitrogen gas?
A. All non-metals are un-reac ve B. There is no hydrogen in the atmosphere
✓ C. The covalent bonds in nitrogen are very D. Due to the presence two ione pains on both
strong nitrogen atom
Q.146 Oxygen is present in atmosphere about
A. 1/2 ✓ B. 1/4
C. 3/4 D. Not exactly so
Q.147 Which of the following synthe c phosphorous fer lizers is marked as super phosphate
✓ A. calcium dihydrogen phosphate B. appe te
C. calcium phosphate D. wavellite
Q.148 Forma on of NO from N2and O2requires temp:
A. 30°C B. 300°C
✓ C. 3000°C D. 30000°C
Q.149 Least angle is associated with the hybridiza on as ______
A. SP3 B. SP2
C. SP ✓ D. dSP2
Q.150 Plant needs phosphorous to grow good
A. Flowers ✓ B. Roots
C. Fruits D. Seeds
Q.151 Which of the following types of compound contains nitrogen?
A. Fats ✓ B. Proteins
C. Carbohydrates D. Starches
Q.152 Formula of apa te is:
A. Ca2(PO4)2 ✓ B. Ca5F(PO4)3
C. KCl D. NaNO3
Q.153 Which is an inert gas?
✓ A. Nitrogen B. Oxygen
C. Hydrogen D. CO
Q.154 Which fer lizer provides the most nitrogen per mole?
✓ A. (NH4)3PO4 B. NaNO3
C. NH4NO3 D. (NH4)2SO4
Q.155 Which gas has pleasant smell and swee sh taste?
A. NO B. NO2
✓ C. N2O D. N 2O 3
Q.156 Ammonium nitrate is used in combina on with
✓ A. Lime B. Lime stone
C. Quick lime D. All of them
Q.157 The force which holds the atoms together to form a compound is known as:
A. van der Waal's force B. London force
✓ C. chemical bond D. dispersion force
Q.158 Allotropic forms of oxygen , Te, Se are
✓ A. Two B. Three
C. Four D. Five
Q.159 Ozone is usually produced in the
A. South polar region B. North pole region
✓ C. Tropical region D. Thermosphere zone
Q.160 The contact process of manufacture of H2SO4involves
✓ A. Heterogeneous cataly c oxida on of to B. Heterogeneous cataly c to using
2 3 2 3 2
_______________________________________________________________________________________
2 3 2 3 2
SO SO oxida on of SO SO oxides of N
C. Direct absorp on of SO3into water D. None of these
Q.161 Reac on of copper with dil HNO3 gives:
✓ A. NO B. NO2
C. N 2O D. N2
Q.162 Types of bonds present in CuSO4.5H2O are
A. Ionic and covalent B. Ionic and co-ordinate
C. Covalent and co-ordinate ✓ D. Ionic covalent and co-ordinate
Q.163 Which of the following species is considered to be more cancer causing
A. Cr(III) ✓ B. Cr(IV)
C. K D. Ba(II)
Q.164 The potassium fer lizers are preferred for hor culture, tobacco and potatoes, which of the following is popular
potassium fer lizer
A. potassium oxide ✓ B. potassium chloride
C. potassium sulphate D. potassium nitrate
Q.165 Which gas produces here? 2P + 4SOCl2→ products:
A. CO2 B. P 2O 5
C. PCl3 ✓ D. SO2
Q.166 In nitrogen fer lizer, nitrogen is the
A. Main cons tuent of protein B. Impart green colour to plants
Q.167 The no and the type of bonds between two carbon atoms in CaC2 are
A. 1σ and 1π ✓ B. 1σ and 2π
C. 1σ and 1.5π D. 3σ and 2π
Q.168 The nitrogen present in some fer lizers helps plants
A. to fight against disease B. to produce fat
C. to undergo photosynthesis ✓ D. to produce protein
Q.169 The raw material for the manufacture of urea fer lizer is
A. hydrogen and ammonia B. steam, methane, ammonia
✓ C. methane and air D. none of these
Q.170 Which is not the property of the carbon monoxide is
A. Water soluble B. Highly toxic
C. Lighter than air ✓ D. Helps in phtosynthesis
Q.171 Natural fer lizers are materials derived from
A. plants only B. animals only
✓ C. both plants and animals D. none of these
Q.172 The suspended par cles in the raw water can be removed by the
✓ A. Coagula on B. Aera on
C. Hydra on D. Dehydra on
Q.173 Which carbon is more electronega ve?
A. sp3-hybridized carbon ✓ B. sp-hybridized carbon
2
C. sp -hybridized carbon D. Always same irrespec ve of its hybrid state
Q.174 Aqua Regia has ra o of conc. HCl and HNO3:
A. 1:2 ✓ B. 1:3
C. 1:4 D. 2:3
Q.175 Which metals dissolve in aqua regla only?
A. Au & Cu ✓ B. Au & pt
C. Au & Ni D. Cu & Pt
Q.176 The substances that are added to the soil to provide nutrient or assen al elements required for plant growth, are
called
_______________________________________________________________________________________
A. addi ves ✓ B. fer lizer
C. manures D. pes cides
Q.177 Nitrogen is present in atmosphere by weight:
A. 75% B. 76%
C. 77% ✓ D. 78%
Q.178 During the chlorina on of water the quali es of water improves due to
✓ A. Killing of pathogens B. DO increases
C. Hardness decreases D. pH is controlled
Q.179 H2SO4is used to displace strong acids such as HClO4, HNO3,HCl from their salts because of its
A. High viscosity B. High dielectric constant
C. High b.p. ✓ D. High solubility in water
Q.180 The pH range of the acid rain is
A. 7 - 6.5 B. 6.5 - 6
C. 6 - 5.6 ✓ D. Less than 5
Q.181 Ozone layer is
✓ A. 25 -28 km high B. 26 - 29 km high
C. 24 - 27 km high D. 20 - 28 km high
Q.182 The nature of interpar cle forces in benzene is
A. Dipole-dipole interac on ✓ B. Dispersion force
C. Ion-dipole interac on
Q.183 The normal amount of overhead ozone is
✓ A. 350 DU B. 450 DU
C. 400 DU D. 300 DU
Q.184 which of the following species is paramagne c?
A. CO2 ✓ B. NO
2-
C. O D. CN-
Q.185 Which fer lizer contains highest %age of nitrogen?
A. Ammonium nitrate ✓ B. Urea
C. Ammonium sulphate D. Ammonium Phosphate
Q.186 Out of all the elements of the group VI-A the highest mel ng and boiling points is shown by the element:
✓ A. Te B. Se
C. S D. Pb
Q.187 In which pair is the radius of the second atom greater than that of the first atom?
A. Na, Mg B. Sr,Ca
C. P,N ✓ D. CI,Br
Q.188 A molecule in which Sp2 hybrid orbitals are used by the central atom in forming covalent bonds is
A. He2 ✓ B. SO2
C. PCI5 D. N2
Q.189 Allotropic forms of phosphurus are:
A. Three B. Four
C. Five ✓ D. Six
Q.190 Which one of the following does not have hydrogen bond
A. Liquid NH3 B. Liquid HF
✓ C. Liquid HCi D. Phenol
Q.191 Which pair of metals don't react with HNO3?
✓ A. Au & Pt B. Fe & CO
C. W &U D. Mg & Ca
Q.192 Which is laughing gas?
A. NO ✓ B. N2O
C. NO2 D. NO3
_______________________________________________________________________________________
Q.193 The diagram shows the energy level of various sub-shells of an atom of transi on element in fourth period of periodic
table is
✓ A. x = 3d, y = 4S B. x = 4S, y = 3d
C. x = 4S, y = 4P D. x = 4P, 3d
Q.194 All elements of group VI-A non-metals except
A. Te B. S
C. Se ✓ D. Po
Q.195 In which one of the following does the central atom not possess an octet in its outer shell?
A. CH4 ✓ B. BH3
C. NH3 D. H 2O
Q.196 Which of the following molecules has pyramidal shape
✓ A. PCI3 B. SO3
2-
C. CO 3 D. NO-3
Q.197 The driving force for making a bond is to:
A. make solid compounds B. make gaseous substances
✓ C. a ain electronic configura on of noble gas D. make different compounds
Q.198 The shape of gaseous SnCI2 is
A. Tetrahedral B. Linear
✓ C. Angular D. T-shaped
Q.199 Which molecule is planar?
A. NF3 ✓ B. C2Cl4
C. C 3H 6 D. C 3H 8
Q.200 Air is polluted with SO2due to
A. Evapora on B. Condensa on
✓ C. Combus on D. Hydrogena on
Q.201 Which of the following species has the maximum number of unpaired electrons?
✓ A. O2 B. O 2+
C. O 2- D. O2-2
Q.202 The shape of CIO-3 according to valence shell electron pair repulsion theory will be
A. Planar triangle ✓ B. Pyramidal
C. Tetrahedral D. Square planar
Q.203 In contact process, pressure in the contact chamber is
A. 200 atom B. 200 - 400 atom
C. 100 atoms ✓ D. 2 - 3 atom
Q.204 In contact process for the manufacture of H2SO4arsenic impuri es are removed by
A. Pb B. Fe (OH)2
✓ C. Fe (OH3) D. Fe2U3
Q.205 Iron pyrite on roas ng produces
A. SO2, Fe ✓ B. SO2, Fe2O3
C. SO3. Fe3O4 D. None of these
Q.206 CO2 iso structural with
✓ A. C 2H 2 B. SnCI2
C. NO2 D. All of these
Q.207 Molecular orbital picture of N2 indicates;
A. two unpaired electron B. one unpaired electron
✓ C. no unpaired electron D. none of these
Q.208 The overall effect of the photochemical smog in the a ernoon is built up of
A. Neutraliza on ✓ B. Oxidizing agent
C. Reducing agent D. Ac va ng agent
Q.209 Nitrogen present in many fer lizer is used by plants
_______________________________________________________________________________________
A. to produce fats ✓ B. to produce proteins
C. to produce carbohydrates D. to catalyse the phtosynthesis
Q.210 Type of linkage between two atoms mainly depends upon
A. Atomic masses B. Ioniza on energies
C. Size ✓ D. Electronega vety
Q.211 The brown gas formed when metal reduces HNO3is:
A. N 2O 5 B. N 2O 3
✓ C. NO2 D. NO
Q.212 Fer lizer consis ng of faeces and urine of domes c livestock is called
A. Plant fer lizer B. Synthe c fer lizer
✓ C. Manure D. None
Q.213 The atomic radius of hydrogen is 37 ___________. Choose the correct unit among the followings:
A. angstrom B. manometer
✓ C. picometer D. micrometer
Q.214 At present the number of fer lizers plants in Pakistan are
A. 10 B. 12
✓ C. 14 D. 20
Q.215 If the temperature in the synthesis of ammonia is decreased. The ammonia forma on
C. No effect D. Li le change
Q.216 Lycra is a polyurethane fibre used in the fashion industry. It is a polymer made from two monomers one of which has
the following formula.
O=C=N-(CH2)n-N=C=O
What is the O-C-N bond angle in this molecule?
A. 90∘ B. 109∘
C. 120∘ ✓ D. 180∘
Q.217 Specific gravity of HNO3 is:
A. 1.35 ✓ B. 1.53
C. 1.39 D. 1.93
Q.218 Among the alkaline earth metals the element forming predominantly covalent compounds is
✓ A. Be B. Mg
C. Sr D. Calcium
Q.219 The substances which are added to the soil to provide one or more nutrient elements essen al for plant growth are
called
A. co on B. wheat
Q.220 The bond order of H+2 is
A. 01 ✓ B. 0.5
C. 1.5 D. None of these
Q.221 Which species has the largest radius?
A. P-3 B. CI-
✓ C. Ar D. K+
Q.222 Which has garlic like odour:
A. N 2O B. NO
C. NO2 ✓ D. P 2O 5
Q.223 Metallic luster shown by sodium metal is explained by
A. DIffusion of Na+ions B. Excita on of free protons
✓ C. Osilla on of lose electrons D. Existence of bcc la ce
Q.224 To keep potato chips crispy in packets ______ gas is filled
A. He B. Oxygen
✓ C. Nitrogen D. Sulphurdioxide
_______________________________________________________________________________________
Q.225 Which of the following fer lizers is useful for paddy rice?
A. ammonium nitrate ✓ B. ammonium sulphate
C. urea D. ammonium chloride
Q.226 The nitrogen present in some fer lizers helps plants to
A. Fight against diseases B. Produce fats
C. Undergo photosynthesis ✓ D. Produce proton
Q.227 Bond angle in water is
A. 120° B. 109.5°
C. 107° ✓ D. 104.5°
Q.228 The %age of nitrogen in urea is
✓ A. 46 B. 36
C. 56 D. 66
Q.229 A compound X reacts with some metals to liberate hydrogen and is used to make fer lizes. It also give white
precipitate with aqueous barium chloride.What is x?
A. Potassium nitrate B. Hydrochloric acid
✓ C. Sulphuric acid D. Ammonium sulphate
Q.230 Which fer lizer contains 46.6% nitrogen?
✓ A. Urea B. Ammonium sulphate
C. Ammonium phosphate D. Ammonium Sulphate
Q.231 In contact process SO3is dissolved
A. H 2O B. Dil H2SO4
✓ C. Conc. H2SO4 D. H 2O 2
Q.232 Which is aqua regia:
A. HCl : NO ✓ B. HCl : HNO3
C. HCI : H2SO4 D. H2SO4: HNO3
Q.233 Phosphorus belongs to a group:
A. III-A B. IV-A
✓ C. V-A D. VI-A
Q.234 Which nitrogen fer lizer is favoured in tropical regions because of its non-hygroscopic nature
A. ammonium sulphate B. ammonium nitrate
C. ammonium chloride ✓ D. ammonium phosphate
Q.235 Specie which has more electrons than protons and more protons than neutrons is
A. D- ✓ B. OH-
+
C. D 3O D. OD-
Q.236 The number of significant figures in 0.00200 is:
A. one ✓ B. three
C. two D. five
Q.237 The widely used nitrogen fer lizer that contains about 46% nitrogen is
A. ammonia B. ammonium nitrate
C. ammonium sulphate ✓ D. urea
Q.238 Reac on of metals with acids produce gas.
A. CO2 B. N 2O
✓ C. NO2 D. N2
Q.239 The twelve outer most electrons in O2 molecule are distributed according to MOT as under, Find to correct one:
✓ A. 8 in bonding molecular orbitals, 4 in an B. 12 in bonding molecular orbitals and zero in
bonding molecular orbitals anto bonding molecular orbitals
C. 9 in bonding molecular orbitals and 3 in D. 10 in bonding moleculaa orbitals and 2 in
an bonding molecular orbitals
Q.240 Chemical reac vity of element depends upon the number of :
A. protons id an atom of the element B. neutrons in an atom of the element
C. electrons in all shells ✓ D. valence shell eledtrons
_______________________________________________________________________________________
Q.241 Which compound does not provide one of the essen al element needed for plant growth?
✓ A. Calcium hydroxide B. Ammonium sulphate
C. Potassium chloride D. Calcium phosphate
Q.242 Electronic configura on gallium is [Ar] 3d10, 4s2, 4p1 what is the correct order of electron loss by Ga from Ga+4 ion
A. 3d, 4P, 4S, 4S B. 3d, 4S, 4S, 4P
C. 4S, 4S, 4P,3d ✓ D. 4P, 4S, 4S, 3d
Q.243 One of all the elements of group V-A, the highest ioniza on energy is possessed by:
✓ A. N B. P
C. Sb D. Bi
Q.244 When two ice cubes are pressed over each other,they unite to form one cube.Which of the following forces is
responsible to hold them together?
A. Hydrogen bond forma on ✓ B. Van der Waal's forces
C. Covalent a rac on D. Dipole intera on
Q.245 Which group of par cles is in order of increasing size?
A. N O F B. N3- O2- F-
C. Na+ Mg2+ Al3+ ✓ D. Na+ Ne F-
Q.246 Bone ash contains calcium phosphate:
A. 70% ✓ B. 80%
C. 90% D. 100%
Q.247 Energy difference b/w 2S and 2P in N2 is
A. 595 KJ/mole ✓ B. 1195 KJ/mole
C. 1595 KJ/mole D. 2078 KJ/mole
Q.248 The electronega vity of elements in a period from le to right:
✓ A. increases B. decreases
C. first increases then decreases D. first decreases then increases
Q.249 Which one of the following statement is correct for urea
✓ A. It is a synthe c fer llizer B. Sulphur containing fer lizer
C. It provides mecronutrients ot the plants D. It is an inorganic water soluble compound
Q.250 Pla nised asbestos is used as a Catalyst in
A. Ostwald B. Lead chamber process
✓ C. Contact process D. Hailer's process
Q.251 How many elements are there in ammonia?
A. Two ✓ B. Three
C. Four D. One
Q.252 Phosphorous helps the growth of
A. root B. leave
C. stem ✓ D. seed
Q.253 Which is nitrous acid?
A. HNO3 B. HNO
✓ C. HNO2 D. H2NO3
Q.254 Molecular orbital picture of O2 indicates:
A. no unpaired electron ✓ B. two unpaired electron
C. one unpaired electron D. none of these
Q.255 Which of the following hydrides has the lowest boiling point?
A. H 2O ✓ B. H 2S
C. H 2S3 D. H2Te
Q.256 Noble gases are most stable of all other elements because
A. They are mono atomic gases B. they do not react with one another
C. they have high ioniza on energies ✓ D. they have completely filled s and p orbitals
Q.257
_______________________________________________________________________________________
Which of the following geometry is associated with the compound in which the central atom assumes sp3 d
hybridiza on?
A. Planar B. Pyramidal
C. Angular ✓ D. Trigonal bipyramidal
Q.258 All of the following statements are incorrect except:
A. scien fic work must be precise, accuracy is to B. scien fic work must accurate, precision is not
essen al essen al
C. precision and accuracy should go side by side ✓ D. none of above
in a scien fic work
Q.259 Forma on of NO from N2and O2requires temp:
A. 30°C B. 300°C
✓ C. 3000°C D. 30000°C
Q.260 Among the nitrogen containing fer lizing, the one with about 82% nitrogen content is
A. ammonium nitrate ✓ B. ammonia
C. ammonium phosphate D. ammonium sulphate
Q.261 Water contains oxygen about
A. 48% B. 50%
C. 53% ✓ D. 89%
Q.262 Among group V-A elements, the most electronega ve element is:
A. Sb ✓ B. N
C. P D. As
Q.263 Group VI-A element are called
A. Halogens B. electron deficient
C. alkaline earth metals ✓ D. Chalcogens
Q.264 Use of the Date Booklet is relevant to this ques on. Which element is likely to have an electronega vity similar to that
of aluminium?
A. barium ✓ B. beryllium
C. magnesium D. stron um
Q.265 In which reac on does the carbon-containing product have a smaller bond angle than the organic reactant?
A. bromoethane refluxed with ethanolic sodium B. complete combus on of methane in air
hydroxide
C. men on and an excess of chlorine under
ultraviolet light
✓ D. polymerisa on of ethene
Q.266 Number of π-bonds in naphthalene is
A. 6 B. 3
C. 4 ✓ D. 5
Q.267 A good fer lizer
A. Never changes soil B. Is soluble in water
C. Not injurious to plant ✓ D. All of them
Q.268 Carbonates and bicarbonates react with acids to release
A. CO ✓ B. CO2
C. NO D. NO2
Q.269 Which one of the following pairs of atoms is most likely to form an ionic bond?
A. O and F ✓ B. Na and F
C. C and F D. N and F
Q.270 Which has the minimum bond angle?
A. H 2O ✓ B. H 2S
C. NH3 D. CH4
Q.271 How many sigma and pi bonds are present in tetra cyano ethylene?
✓ A. Nine σ and nine π B. Five π and nine σ
C. Nine σ and seven π D. Eight σ and eight π
Q.272 Formula of calcium supper phosphate is
_______________________________________________________________________________________
A. CO3(PO4)2 ✓ B. Ca (H2PO4)2
C. Ca3P2 D. CaHPO4
Q.273 Colour of N2O4 is:
A. Reddish Brown ✓ B. Yellow
C. Colourless D. Green
Q.274 Detergent greatly effect the
✓ A. Aqua c life B. Modern life
C. Terrestrial life D. Plants life
Q.275 The formula of calcium superphosphate is
A. CaHPO4 B. CaH2PO4
✓ C. Ca(H2PO4)2 D. none of these
Q.276 Temperature during contact process equilibrium mixture is recycled at
A. 400°C B. 200°C
✓ C. 400-500°C D. 650°C
Q.277 Which of the following compound will have both polar and non-polar bonds
A. CO2 B. CH4
✓ C. H 2O 2 D. NH4CI
Q.278 Lead pollu on is mainly due to
A. Metallic pollu on B. Space pollu on
✓ C. Acid rain D. Cd pollu on
Q.279 The chemical used for cooling in refrigera on
A. NH4Cl ✓ B. Liquid NH3
C. NH4OH D. NH4NO3
Q.280 Which of the following is not a fer lizer?
A. nitrophos B. dolomite
✓ C. super phosphate of lime D. urea
Q.281 The bond angle H - O - H in ice is closest to
A. 120° . 28° B. 60°
C. 90° ✓ D. 109°
Q.282 Which of the following compounds is electrons deficient
A. CO2 ✓ B. B 2H 6
C. C 2H 6 D. NaCI
Q.283 Which one of the following correctly describes the trend in electro nega vity?
✓ A. increases across a period and decreases B. decreases across a period and increases down
down a group: a group
C. decreases across a period and decreases D. increases across a period and increases down
down a group group
Q.284 The natural fer lizers consist of
A. plants B. animals
✓ C. both plants and animals D. microorganisms
Q.285 The percentage of nitrogen in ammonia is
A. 80% ✓ B. 82%
C. 90% D. 50%
Q.286 Which phosphorus is the most poisonous?
✓ A. White B. Red
C. Black D. All
Q.287 SO2is dehydrated by
A. CaO ✓ B. Conc. H2SO4
C. P 2U 5 D. Anhyd CalCl2
Q.288 Formula of oleum is
✓ A. H2S2O7 B. H2SO3
_______________________________________________________________________________________
C. H2SO4 D. b and c
Q.289 Which element comprises about 50% of earth crust?
✓ A. Oxygen B. Silicon
C. Aluminum D. Hydrogen
Q.290 Aqua regia is a solu on
✓ A. HNO3: 3HCl B. HCl : 3HNO3
C. HCl : HNO3 D. HCl : 2HNO3
Q.291 A ione pair of electrons in an atom implies
A. A pair of valence electrons B. A pair of electrons
C. A pair of electrons involved is bonding ✓ D. A pair of valence electrons not involved in
bonding
Q.292 Which of the following has unchanged valency?
A. H ✓ B. Na
C. Fe D. Oxygen
Q.293 SO3Is not absorbed in the water directly to or H2SO4because:
A. The reac on does not go to comple on ✓ B. The reac on is quit slow
C. The reac on is exothermic D. SO3is insoluble in water
Q.294 In CCI4, the four valencies of carbon are directed towards the corners of a
A. Cube B. Hexagon
C. Prism ✓ D. Tetrahedron
Q.295 Covalent compounds are soluble in
A. Polar solvents ✓ B. Non-polar solvents
C. Concentrated acids D. All solvents
Q.296 Ozone is a gas having boiling point
A. Unstable B. High
✓ C. Low D. Moderate
Q.297 Which one of the following is a macronutrient for plants
A. Copper ✓ B. Nitrogen
C. Manganese D. Iron
Q.298 Which of the following is correct order for manufacture of urea
✓ A. Carbamate condensa on, decomposi on, B. Carbonate condensa on, urea synthesis-
urea sythesis decomposi on
C. Decomposi on, urea synthesis, carbonate D. None of these
Q.299 Water (H2O) is liquid while hydrogen sulphide (H2S) is a gas because
A. Water has higher molecular weight B. Hydrogen sulphide is a weak acid
C. Sulphure has high electronega vity than ✓ D. Water molecules associate through hydrogen
oxygen bonding
Q.300 XeF4 has shape of
A. Sphere B. Trigonal bipyramidal
C. Tetrahedral ✓ D. Square planar
Q.301 Number of sigma bonds in P4O10 is
A. 6
B. 7
C. 17 ✓ D. 16
Q.302 Reac on of HNO3with every dilute Zinc and at low temperature gives:
✓ A. Oxides B. Chlorides
C. Nitrides D. Nitrates
Q.303 Which of the following molecules has greatest bond length
A. F2 B. N2
✓ C. CI2 D. O2
Q.304 If the molecule of HCI were totally polar,the expected value of dipole moment is 6.12 D (debye) but the experimental
value of dipole moment was 1.03 D.Calculate the percentage ionic character.
A. 17 B. 83
_______________________________________________________________________________________
✓ C. 50 D. Zero
Q.305 The first seven ioniza on energies of an element between lithium and neon in the periodic table are as follows:
1310 3390 5320 7450 11 000 13 300 71 000 kj mol-1
Which is table are as follows:
A. 2s2 B. 2s22p1
✓ C. 2s22p4 D. 2s22p6
Q.306 Carbon tetrachloride has no dipole moment because
A. Its planner structure ✓ B. Its tetrahedral structure
C. Similar E.As of C and CI D. Similar sizes of C and CI
Q.307 T.N.T is an explosive , it is prepared by the acid:
A. H2SO4 B. HCl
✓ C. HNO3 D. H3PO4
Q.308 Catalyst used in Hailer's process is
A. vanadium (v) oxide B. Nichel
✓ C. Iron D. Pla num
Q.309 Which of the following compounds can form hydrogen bond?
A. CH4 ✓ B. H 2O
C. NaCI D. CHCI3
Q.310 Object of the size of an atom can be observed in:
A. a vesible spectrum B. X-ray spectrum
✓ C. in electron microscope D. atomic absorp on spectrum
Q.311 Oxida on of NO in air produces:
A. N 2O B. N 2O 3
✓ C. N2O 4 D. N 2O 5
Q.312 Which one is a nitrogen fer lizer
✓ A. Urea B. calcium sulphate
C. potassium phosphate D. magnesium carbonate
Q.313 Which one of the following statements about nega ve ions is incorrect?
A. they are also known as anions B. they are formed atoms gainelectrons
C. they area larger than the atom from which ✓ D. they are smaller than the atoms from which
they are formed they are formed
Q.314 Nitrogen is present in atmosphere.
A. 21% B. 36%
✓ C. 78% D. 89%
Q.315 Ring test is given by ions:
A. Nitrides ✓ B. Nitrates
C. Cyanates D. Nitriles
Q.316 Aluminium is in group III. Its oxide will have the formula
A. AlO2 B. AIO
✓ C. AI2O3 D. AI3O2
Q.317 Which has swee sh taste?
✓ A. N2O B. NH3
C. CI2 D. CO2
Q.318 Which of the following equa ons represents the lst ioniza on energy of Na?
A. Na(s) -----> Na+(g) + e- ✓ B. Na(g) ----->Na+(g) +e-
+ -
C. Na(s) ----->Na (s) +e D. Na(s) + e ---------> Na+(g)
Q.319 NO2dissolve in water in absence of air to produce
A. HNO2 B. HNO3
Q.320 A chemist poured lemon juice on soil, which idea may he have in his mind?
A. lemon juice is dangerous for health ✓ B. there may be a possibility of a chamical
_______________________________________________________________________________________
reac on
C. water should be preferred over lemon juice D. there may note be a possibility of chemical
for drinking reac on
Q.321 Which catalyst is used in contact process?
A. Fe2O3 ✓ B. V 2O 5
C. SO3 D. Ag2O
Q.322 Ammonia gas used directly as a fer lizer injected into the soil at a depth of about
A. Teo inches B. Three inches
C. Five inches ✓ D. Six inches
Q.323 The electronic configura on of four elements is given below Which of these elements has the highest first ioniza on
energy
✓ A. 1S2, 2S2, 2P3 B. 1S2, 2S2, 2P4
C. 1S2, 2S2, 2P6, 3S1 D. 1S2, 2S2, 2P6, 3S2, 3P3
Q.324 Which of the following is iso electronic with CN-
A. O- 2 B. O2-2
C. F2 ✓ D. Si
Q.325 Annual produc on of urea in Pakistan is
✓ A. 5.6 million metric tons B. 10.2 million metric tons
C. 1 million metric tons D. 3.7 million metric tons
Q.326 The carbon atoms in calcium carbide are held by
A. Ionic bonds B. 2 sigma bonds
C. 2 covalent, one co-ordinate bond ✓ D. 2 π and one σ bond
Q.327 Why do former treat-soil with ammonium sulphate?
A. To reduce the acidity of the soil B. To increase the sulphur contents of the soil
✓ C. To increase the nitrogen content of the soil D. To kill the insects
Q.328 The boiling point of heavy water is
A. 108°C B. 101.4°C
✓ C. 99°C D. 110°C
Q.329 The property of elements to a ain eight electrons in their valence shell is called:
A. pauli exclusion principle B. Au au's principle
✓ C. octet rule D. Hund's rule
_______________________________________________________________________________________
13 Fundamental Principles
Q.1 Isomers have same proper es:

A. Physical B. Chemical
C. (a) and (b) ✓ D. Nuclear
Q.2 When bromine reacts with propene in an organic solvent at room temperature, what is the mechanism by which the
bromine a acks the propene?
✓ A. electrophilic addi on B. electrophilic subs tu on
C. nucleophilic addi on D. nucleophilic subs tu on
Q.3 Octane no of gasoline is improved by the process of
A. Cracking ✓ B. Reforming
C. Hydrogena on D. Oxida on
Q.4 The four bonds of carbon in methane are directed towards the corners of
A. Cube B. Pentagoan
C. Hexagon ✓ D. Tetrahedron
Q.5 How many structual and cis-trans isomers are there for dischloroprepe, C3H4Cl2
A. 3 B. 5
C. 6 ✓ D. 7
Q.6 n-butane and iso butane are an example of
✓ A. Chain isoterism B. Posi onal isomerism
C. Meta merism D. Func onal group isomerism
Q.7 When will cyclic compounds show aroma city according to Huckel rule? The correct statement is when it has:
A. 4π electrons B. (4π + 2) o elec ons
✓ C. ( 4n + 2) π electrons D. (4n - 2) π electrons
Q.8 Which reac on occur when ethane and chlorine are mixed diffused sunlight?
A. a free-radical subs tu on with hydrogen B. a free-radical subs tu on with hydrogen
given off chloride given off
✓ C. a free-radical subs tu on with no gas give D. a nucleophilic subs tu on with hydrogen
off chloride given off
Q.9 Wood under the bacteria and chemical reac ons get converted into:
A. Coal ✓ B. Peat
C. Anthracite D. Lignite
Q.10 Sp3 hybridiza on occurs when carbon is bound to
✓ A. Four other atoms B. Three other atoms
C. Two other atoms D. One other atoms
Q.11 Which set of hybrid orbital has planner triangular shape
A. SP3 ✓ B. SP2
C. SP D. dSP2
Q.12 In benzene ring all the angles are of:
✓ A. 120° B. 190°
C. 109.5° D. 145°
Q.13 Choose the strongest o-,p-direc ng group among the following:
A. -C6H5 B. -CI
C. -Br ✓ D. -OH
_______________________________________________________________________________________
Q.14 General formula of starch is:
A. (CH2O)n ✓ B. (C6H12O5)n
C. (C3H6O2)n D. (C4H6O2)n
Q.15 In early days, the compounds were named on the basis of
A. History B. Method prepara on
C. Name of person ✓ D. All of these
Q.16 A liquid hydrocarbon is converted into a mixture of gaseous hydrocarbons by
✓ A. Pyrolysis B. Reforming
C. Reduc on D. Hydrogen on
Q.17 The structure of benzene is
✓ A. Hexagonal B. Pyramidal
C. Square planer D. Tetrahedral
Q.18 Benzene is an example of
✓ A. aroma c compound B. cyclic compound
C. alipha c compound D. a cyclic compound
Q.19 Orbital hybridiza on explains the concept of valency:
A. Monovalency B. Divalency
C. Trivalency ✓ D. tetravalency
Q.20 Closed chain compounds can be classified into
A. Homocyclic B. Hetrocyclic
C. Alipha c ✓ D. Both a and b
Q.21 Which of the following contains single bonds
A. Benzene B. Alkyne
C. Alkene ✓ D. Alkane
Q.22 Coal is obtained from dead remains of
✓ A. Plants B. Animals
C. Both a & b D. None
Q.23 Isomers are wri en for a compound, if it has carbon atoms at least.
A. One B. Two
C. Three ✓ D. Four
Q.24 The major components of coal gas are
✓ A. hydrogen and methane B. ethane and carbon monoxide
C. nitrogen and ethane D. ethane and carbon dioxide
Q.25 The C - C bond length in the acetylene is
A. 1.35A° B. 1.54A°
C. 1.39A° ✓ D. 1.20A°
Q.26 No of sigma electrons in C2H4
A. 04 B. 06
C. 08 ✓ D. 10
Q.27 Homoly c fission of covalent bond results in the forma on of
✓ A. Free radicals B. Carbanions
C. Carboca ons D. Both a and b
Q.28 Which of the following molecules is non-benzenoid
A. An ne ✓ B. Pyridine
C. Xylene D. Toluene
Q.29 Which method is no used for the for the prepara on of alkenes:
A. Dehyedro halogena on of alkyl halides B. Dehydra on of alcohol
C. Dehalogena on of vic-dihalides ✓ D. Par al hydrogena on of alkanes
Q.30 Hydrogen bromide reacts with ethene to form bromoehane.
what is the best descrip on of the organic intermediate in this reac on?
_______________________________________________________________________________________
A. it contains carbon, hydrogen and dromine. B. it has a nega ve charge
✓ C. it is an electrophile D. it is a free radical
Q.31 Major component of natural gas is:
A. Ethane B. Ethene
C. Propane ✓ D. Methane
Q.32 Amongest the following the compound that can be most readily sulphonated is:
✓ A. toluene B. benzene
C. nitrobenzene D. chlorobenzene
Q.33 Electronega vity value of hydrogen is
A. 3.1 B. 2.5
✓ C. 2.1 D. 2.3
Q.34 Hydrocarbons contain
A. C and S only ✓ B. C and H only
C. C, H, and O only D. C, H, O and N only
Q.35 Nitro alkane exhibit the
A. Chain isomerism ✓ B. Posi onal isomerism
C. Func onal group D. metamerism
Q.36 Which reagent could be used to convert CH3CO2CH3 into CICH2CO2CH3?
A. concentrated hydrochloric acid at 100°C B. phosphorus pentachloride at room
temperature
C. sulphur dichloride oxide (thionyl
3
) at ✓ D. chlorine in bright sunlight at 100°C
chloride, SOCI 50°C
Q.37 Ethers show the phenomenon of:
A. Posi on isomerism B. Func on group isomerism
✓ C. Metamerism D. Cis-trans isomerism
Q.38 Organic compounds are:
A. Compounds of carbon ✓ B. Compounds of carbon and their deriva ves
C. Compounds of carbon and halogens D. Compounds of carbon and nitrogen
Q.39 Light ini ates the following reac on.
alkane + chlorine → chloroalkane + hydrogen chloride
What happens to chlorine in this photochemical reac on?
A. heteroltuic fission to given an electrophile B. homoly c fission to give an electrophile
C. heteroly c fission to give a free radical ✓ D. homoly c fission to give a free radical
Q.40 The rota on of two carbon atoms joined by double bond would happened only if
✓ A. Pi bond is broken B. Sigma bond is broken
C. Both bonds are broken D. None of above
Q.41 The dis lla on of coal at high temperature and in absence of air is called
A. vaccum dis lla on B. normal dis lla on
C. frac onal dis lla on ✓ D. destruc ve dis lla on
Q.42 The geometry in ethane is:
A. Tetrahedral ✓ B. Trigonal
C. Trigonal pyramid D. V-shaped
Q.43 The structure of ethyne is
A. Angular B. Trigonal
✓ C. Linear D. Trigonal planner
Q.44 The electrophile in aroma c sulphona on is:
A. H2SO4 B. HSO4
✓ C. SO3 D. SO3+
Q.45 In alkynes the bonds between carbon atoms are
A. All sigma bonds B. All pi(π) bonds
✓ C. One is sigma and two are π (pi) bonds D. One is π (pi) and two are sigma bonds
_______________________________________________________________________________________
Q.46 Tetrabromoethane on hea ng with Zn gives:
A. Ethyl bromide B. Ethene
C. Ethane ✓ D. Ethyne
Q.47 Alkynes normally have _______ hybridiza on
✓ A. Sp B. Sp2
C. Sp3 D. dsp2
Q.48 In ethane no of atoms which are present in same plane are
A. 03 B. 04
C. 02 ✓ D. 06
Q.49 Which set of hybrid orbitals has planar triangular shape?
A. sp3 B. sp
✓ C. sp 2
D. dsp2
Q.50 In which molecule carbon atom is sp2 hybridized
A. CH4 ✓ B. C 2H 4
C. C 2H 2 D. None of the above
Q.51 A func onal group consists of:
A. atom B. group of atoms
C. double bond ✓ D. all
Q.52 Which of the following is not an aroma c compound
A. Furan B. Thiophene
C. Pyrrole ✓ D. All are aroma c
Q.53 Posi on of double bond in alkenes can be iden fied by:
A. Bromine water ✓ B. Ozonolysis
C. Ammonical silver nitrate solu on D. None of these
Q.54 Catena on is a process in which carbon shows the proper es of making
A. mul ple bonds B. hybridiza on
✓ C. long chains or rings of carbon atom D. showing isomerism
Q.55 The self linking property of carbon is called as
A. Linking polymeriza on B. Addi on
✓ C. Catena on D. Elimina on
Q.56 The nature of -COOH group is:
✓ A. meta direc ng B. ortho direc ng
C. para direc ng D. ortho and metal direc ng
Q.57 The open chain compounds are also called
✓ A. Alipha c B. Alicylic
C. Aroma c D. Both a and b
Q.58 Cracking normally gives smaller ___________
A. Alkanes B. Alkenes
C. Alkynes ✓ D. Both a and b
Q.59 The use of tetra ethyl lead in petrol as an efficient an knock agent is being discouraged which reason is correct
A. It is costly B.
It damages the engine
C. Pb is difficult to obtain in bulk quan es ✓ D.
The combus on product, lead, causes air
pollu on
Q.60 Which of the following products is obtained when methyl magnesium bromide reacts with alcohol?
A. ethane B. alcohol
C. acetone ✓ D. methane
Q.61 The state of hybridiza on of carbon atom in methane is
✓ A. sp3 B. sp2
C. sp D. dsp2
Q.62 Similarity in proper es of different organic compounds give rise to the under standing of ___________
A. Polymeriza on B. Non-polar nature
_______________________________________________________________________________________
✓ C. Homologous series D. Isomerism
Q.63 Benzene does not undergo:
A. subs tu on reac ons B. addi on reac ons
C. oxida on reac ons ✓ D. elimina on reac on
Q.64 Which one of the following belongs to meta direc ng group?
A. halogens B. alkyl group
C. phenyl group ✓ D. keto group
Q.65 Which of the following molecules is non-planer
✓ A. Ethane B. Ethene
C. Ethyne D. Benzene
Q.66 Acetylene on reac on with ammonical silver nitrate gives
A. silver metal B. silver mirror
✓ C. solver acetylide D. silver acetate
Q.67 Hydrogen bromide reacts with ethene to form bromoethane.
what is the best descrip on of the organic intermediate in this reac on?
A. it contains carbon hydrogen and bromine B. it has a nega ve charge
✓ C. it is an electrophile D. it is a free radical
Q.68 The process in which orbitals of different energies and shapes mix up with each other to give equivalent orbitals is
called,
✓ A. Hybridiza on B. Polymeriza on
C. Isomerisa on D. Carboniza on
Q.69 Which of the following is NOT a organic compound
A. Ace c acid B. Paraffine
✓ C. Hydrazine D. None
Q.70 1-Chlorobutane on reac on with alcoholic potash (KOH) gives:
✓ A. 1-Butene B. 1-Butene
C. 1-Butanol D. 2-butanol
Q.71 Alkynes can be reduced to alkenes by hydrogena on in the presence of:
✓ A. Pd B. Raney Ni
C. Lindlar's Catalyst D. anhyd AICI3
Q.72 The major por on of natural gas is
A. ethane B. propane
C. butane ✓ D. methane
Q.73 On passing ethane into concentrated suphuric acid the intermediate compound formed on hydrolysis with boiling
water gives
A. Methyl alcohol B. Ethyl alcohol
✓ C. Ethyl hydrogen sulphate D. Methyl hydrogen sulphate
Q.74 Compound which has one isopropyl group
✓ A. 2-methl pentane B. 2-methyl butane
C. 2,3-dimethl pentane D. 2, 2,3,3 -tetramethyl butane
Q.75 Self linkage in carbon is called:
A. Polymeriza on ✓ B. Catena on
C. Polymorphism D. AAllotropy
Q.76 The quality of petroleum is determined by
A. decane number ✓ B. octane number
C. hexane number D. none of these
Q.77 Source of organic compounds primarily is:
A. Plants B. Animals
C. Minerals ✓ D. A&B
Q.78 Wholer prepared urea from
_______________________________________________________________________________________
A. Ammonia ✓ B. NH4CNO
C. NH3 D. Uric acid
Q.79 Hea ng of coal in the absence of air at 500 - 1000°C, converted it into:
A. Coke B. Coal gas
C. Coal tar ✓ D. All of these
Q.80 When H2SO4 is heated with excess of ethanol at 140°C,the major product is:
A. alcohol ✓ B. ether
C. ketone D. ethene
Q.81 Wohler synthesized first of all the organic compound:
A. Carbohydrates ✓ B. Urea
C. Aniline D. Totuene
Q.82 Self linkage if carbon to produce long chains is:
A. Isomerism B. Polymorphism
C. Polymeriza on ✓ D. Catena on
Q.83 Type of isomerism in BrCH=CHBr is:
A. Structural isomerism B. Conforma onal isomerism
✓ C. Geometrical isomerism D. Posi on isomerism
Q.84 CH3-O-CH3and CH3CH2OHis example of isomerism:
A. Chain isomerism B. Posi on isomerism
✓ C. Func onal group isomerism D. Metamerism
Q.85 Isomerism observed among diethyl ether and methoxy propane is
A. Chain isomerism ✓ B. Metamerism
C. Tautomerism D. Posi on isomerism
Q.86 Which property of benzene may be directly a ributed to the stability associate with its delocalized structure?
A. it has a low b.p B. it does not conduct electricity
✓ C. it tends to undergo subs tu on rather than D. it enthalpy change of forma on is posi ve
addi on reac on
Q.87 The slow rate of organic reac on is due to ______ of organic compounds
A. Ionic nature ✓ B. Molecular nature
C. Polar nature D. All of these
Q.88 Cracking done at low pressure and with a catalyst is called ________ cracking
A. Thermal ✓ B. Cataly c
C. Steam D. None of them
Q.89 Ethylene combine with water in the presence of H2SO4 + HgSO4 and forms:
A. ethyl chloride ✓ B. ethyl alcohol
C. carboxylic acid D. none of all
Q.90 Which reac on is used as test for the presence of alkenes:
✓ A. reac on of cold dilute alkaline KMnO4 B. combus on
C. polymeriza on D. cataly c hydrogena on
Q.91 The formula of esters is
A. ----- CONH2 ✓ B. ----- COOR
C. ----- COOH D. ----- COX
Q.92 Those compound which have any atom other than C as member of rings are called as
A. Monocyclic ✓ B. Hetrocyclic
C. Alipha c D. Both a and b
Q.93 In a heteroly c bond fission reac on
A. A molecule of H2O is formed B. A molecule of H2O is eliminated
C. A free radical is formed ✓ D. A posi ve and a nega ve ion is formed
Q.94 Vital force theory was rejected by the work of scien st:
✓ A. F. Wohler B. Gibbs
C. Henderson D. Avogadro's
_______________________________________________________________________________________
Q.95 Alkenes give

A. Free radical subs tu on reac ons ✓ B. Electrophilic addi on reac ons:
C. Nucleophilic addi on reac ons D. Elimina on reac ons
Q.96 Sub-bituminous coal is used for
A. Carboniza on of coal B. Domes c fuel
✓ C. Power genera on D. All of these
Q.97 Point out the polycyclic compound among the following:
A. styrene B. xylene
C. cumene ✓ D. haphthalen
Q.98 In which way are ethene and propane similar?
CH2=CH2 CH3CH2CH3
ethene Propane
A. They are both obtained by the dehydra on of ✓ B. they are both neutral to an indicator
alcohols. solu on.
C. They can both be hydrogenated using a D. they can both undergo polymerisa on under
suitable catalyst suitable condi ons
Q.99 When ethen is passed through a dilute solu on of KMnO4 the pink colour changes to:
A. red B. blue
C. green ✓ D. colourless
Q.100 Organic compounds are in nature :
A. Ionic B. Coordinate covalent
✓ C. Covalent D. Polar
Q.101 Organic compounds resemble to those of inorganic compounds having same
A. Ionic proper es B. Carbon forming long chain or rings
✓ C. Chemical forces D. Isomerism
Q.102 Which statement is true about a free radical
A. An atom with a posi ve charge B. An atom with a nega ve charge
C. An atom with a Ione pair of electrons ✓ D. An atom with unpaired electron
Q.103 Paraffins is the common name used for
✓ A. Alkanes B. Alkenes
C. Alkynes D. Arenes
Q.104 The general formula for alkenes is
A. CnH2n+1 B. CnH2n+2
✓ C. CnH2n D. CnH2n-2
Q.105 Vicinal dihalides n treatment with zinc dust gives:
A. alkanes ✓ B. alkenes
C. alkynes D. all of above
Q.106 The compounds which have any atom other than Carbon atom, in rings are called as
A. Monocyclic ✓ B. Heterocyclic
C. Homocyclic D. None of the above
Q.107 Which hydrovarbon can form a monochloro-subs tu on deriva ve which shows both chirality and cis-trans
isomerism?
A. CH3CH =CH2 B. (CH3)2C =CH2
C. CH3CH = C(CH3)2 ✓ D. CH3CH = CHCH2CH3
Q.108 The ac ve part in a molecule is called
A. Homologous series ✓ B. Func onal group
C. Chemical bonding D. Ionic complex
Q.109 Amongst the following the compound that can be most readily sulphonate is:
Q.110 Which of following acid can be used as a catalyst in Friedal-Cra 's reac on:
✓ A. AICI3 B. HNO3
_______________________________________________________________________________________
C. BeCI2 D. NaCI
Q.111 Carbon also form stable compound by single, mul ple bonds with atoms like
A. Oxygen B. Carbon
C. Nitrogen ✓ D. All of these
Q.112 When acetlyene is passed through a copper tube at 300°C,it polymerizes to:
A. polyacetylene B. polyethylene
✓ C. benzene D. none of all
Q.113 Which of the following has linear shape?
✓ A. SP B. SP2
C. SP3 D. None of the above
Q.114 Which of the following has highest boiling points:
✓ A. n-octane B. iso-octane
C. n-butane D. 2,2,3,3,-Tetramethyl butane
Q.115 Which of the following compound show the geometrical isomerism
✓ A. 2-butene B. 2-butyne
C. 2-butanol D. Butanol
Q.116 The characteris c reac ons of alkanes are
A. Addi on reac ons ✓ B. Subs tu on reac ons
C. Condensa on reac ons D. Polymeriza on reac ons
Q.117 Which hybridiza on is not associated with planner geometry
✓ A. SP3 B. SP2
C. SP D. dSP3
Q.118 Amines exhibit
A. Chain isomerism B. Posi onal isomerism
C. Metamerism ✓ D. All of them
Q.119 Isomers of butane are:
✓ A. 2 B. 5
C. 8 D. 10
Q.120 Which of the following has the minimum boiling point
A. n-Butane B. 1-Butane
✓ C. Isobutane D. 1-Butane
Q.121 Free rradicals are characterized by
✓ A. Paramagne sm B. Diamagne sm
C. Loss of Electrons D. Low reac vity
Q.122 The mode of hybridiza on in CH4 is
✓ A. Tetrahedral B. Trigonal
C. trigonal pyramid D. V-shaped
Q.123 An isomer of ethanol is
A. Methanol ✓ B. Dimethyl ether
C. Di ethyl ether D. Ethylene glycol
Q.124 Catalyst used during cracking is
A. SiO2 B. AI2O3
✓ C. Both a and b D. AICI3
Q.125 Which of the following is not alicyclic
A. Cyclohexene B. Cyclobutane
C. Cyclopentyne ✓ D. Toluene
Q.126 The open chain organic compounds are called
A. Linear compounds B. Aroma c
✓ C. Alipha c D. Both A and B
Q.127 Pantane has isomers:
_______________________________________________________________________________________
A. One B. Two
✓ C. Three D. Four
Q.128 Which form of coal contains carbon 92-98%
✓ A. Anthracite B. Bituminous
C. Lignite D. Peat
Q.129 Who rejected the vital force theory
✓ A. Wholer B. Fisher
C. Newton D. Lewis
Q.130 When a carbon atom forms single bonds with order carbon atoms, these hybrid orbitals overlap with the orbitals of
hydrogen to form four bonds which are
A. Three sigma and one Pi B. Two sigma and two Pi
C. One sigma and three Pi ✓ D. Sigma
E.
Q.131 Which method is used to prepare alkane, alkene and alkyne?
A. Hydrolysis of aluminum carbide B. Hydrolysis of CaC2
C. Hydrolysis of Grignard reagent ✓ D. Kolbe's electroly c method
Q.132 The use of tetra ethyl lead in petrol as an efficient an knock agent is being discouraged. Which reason is correct
A. It is costly B. It damages the engine
C. Pb is difficult to obtain in bulk quan es ✓ D. the combus on product, lead , causes air
pollu ons
Q.133 Open chain compounds are also called
A. Alipha c compound B. Acyclic compound
Q.134 Which is used for welding purposes?
A. ethane B. nitrogen
C. methane ✓ D. acetylene
Q.135 Which of the following is and electrophile
✓ A. Bromine B. KBr
C. NH3 D. Benzene
Q.136 Type of isomerism shown by fumeric acid and maleic acid is
A. Func onal group ✓ B. Geometrical
C. Op cal D. Posi onal
Q.137 The number of sigma and pi bond in the 1-buten-3-yne is
A. 6σand 3π B. 5σand 5π
✓ C. 7σand 3π D. 8σand 2π
Q.138 Organic compounds are soluble in all except
A. Benzene B. Petroleum
C. Ether ✓ D. Water
Q.139 Acetylene is used in the manufacture of:
A. rubber B. plas c
C. ethyl alcohol ✓ D. all above
Q.140 Which of these always applies to a nucleophile
A. It a acks a double bond ✓ B. It has a Ione pair of electrons
C. It is single atom D. It is nega vely charged
Q.141 Gasoline is a mixture of hydrocarbons containing carbon atoms
✓ A. 5 to 10 B. 5 to 8
C. 5 to 13 D. 5 to 11
Q.142 The isomers due to the unequal distribu on of carbon atoms on either side of the func onal group belonging to the
same homologous series are called
A. Func onal isomers B. Posi on isomers
C. Chain isomers ✓ D. Metamers
_______________________________________________________________________________________
Q.143 How many carbon atoms are sp3hybridized in 1,5 Hexadiene-3-yne
A. Only one B. Two
C. Three ✓ D. None of these
Q.144 Pyrrole is a
A. Acyclic compound B. Carbocylic compound
C. Homocyclic compound ✓ D. Hetero cyclic compound
Q.145 Which of the following posses linear geometry
A. Alkane B. Alkene
✓ C. Alkyne D. Benzene
Q.146 Light ini als the following reac on.
alkane + chlorine → chloroalkane + hydrogen chloride
What happens to chlorine in this photochemicala reac on?
A. heteroly c fission to give an electrophile ✓ B. homoly c fission to give an electrophile
C. heteroly c fission to give a free radical D. homoly c fission to give a free radical
Q.147 The reac on of alkenes with halogens is explosive in case of:
✓ A. F2 B. CI2
C. Br2 D. I2
Q.148 The self-linking of carbon atoms is called
A. Chela on B. Isomerism
✓ C. Catena on D. None of above
Q.149 Benzene is insoluble in:
✓ A. water B. alcohol
C. pelcol D. ether
Q.150 Cracking products are:
A. Only alkanes B. Only alkenes
✓ C. Alkanes and alkenes D. Alkynes
Q.151 Aroma c compounds burn with sooty flame because
A. they have high % age of hydrogen B. they have a ring structure
✓ C. they have high % age of carbon D. they resist reac on with air
Q.152 How many chain isomers can be obtained from C6H14
A. 04 ✓ B. 05
C. 06 D. 08
Q.153 Which is not the characteris c property of organic compounds
A. They form long chain compounds B. Organic compounds are generally covalent
compounds
C. They exist in homologous series ✓ D. Organic compounds are water soluble
Q.154 Glucose and fructrose are isomers
A. Chain isomers B. Posi ve isomers
✓ C. Func onal group isomers D. Metamers
Q.155 Tetraethyl lead causes disease:
A. Typhoid ✓ B. Respiratory
C. Stomach D. Muscular
Q.156 The elimina on of HX from adjacent carbon atoms is called:
A. halogena on B. hydrohalogena on
✓ C. dehydrohalogena on D. hydra on
Q.157 Saturated alicyclic hydrocarbons has general formula
A. CnH2n+2 ✓ B. CnH2n
C. CnH2n-2 D. CnH2n+1
Q.158 An element essen al for organic compounds:
A. Hydrogen ✓ B. Carbon
C. Nitrogen D. Halogen
_______________________________________________________________________________________
Q.159 The IUPAC name of CH2= Ch - CH(CH3)2is
A. 2-vinylpropane ✓ B. 3-methylbut-1-ene
C. 1-isopropylethlene D. 1, 1-dimethylprop-2-ene
Q.160 The general formula of saturated alicyclic hydrocarbons is:
A. CnHn ✓ B. CnH2n
C. CnH2n+2 D. CnH2n-1
Q.161 Which of the following is NOT a heterocyclic compound
A. Ethyleneoxide B. Pyridine
C. Pyrrol ✓ D. None
Q.162 The essen al component of organic compound is
A. O ✓ B. C
C. P D. N
Q.163 Only sigma bond is present in
A. Propene B. Butanoic acid
✓ C. Butanol D. Ethoxy butene
Q.164 Which compound does not show isomerism?
✓ A. Propane B. Butane
C. Pentane D. Hexane
Q.165 The catalyst, which is used as specialist for cracking, are
A. aluminates ✓ B. aluminosilicates
C. aluminium slats D. all can be used
Q.166 The percentage of methane in natural gas is
A. 50% B. 60%
✓ C. 85% D. 90%
Q.167 Which method is used to prepare alkane?
A. Hydrolysis of Grignard reagent B. Wolf Kishner reduc on
C. Electrolysis of aqueous solu on of sodium salt ✓ D. All of above
of carboxylic acid
Q.168 Which of the following reacts with sodium with the elimina on of hydrogen:
✓ A. C 2H 2 B. C 2H 6
C. CH4 D. C 2H 4
Q.169 Ethyl hydrogen sulphate on hydrolysis with boiling water is converted to:
A. methyl alcohol B. propyl alcohol
✓ C. ethyl alcohol D. ethylene
Q.170 Homologues differ from each pair contains isomers of each other?
A. propanoic acid and propanone B. acetone and acetaldehyde
✓ C. ethyl alcohol and diethyl ether D. methyl alcohol and dimethyl ether
Q.171 Benzene can not under go:
A. subs tu on reac ons B. addi on reac ons
C. oxida on reac ons ✓ D. elimina on reac ons
Q.172 Gasoline is a mixture of hydrocarbon containing carbon atoms
A. 1-5 B. 5-8
C. 8 - 11 ✓ D. 6-8
Q.173 Which of the following is and aroma c compound
A. Propanol B. Cyclohexane
C. Acetone ✓ D. Benzene
Q.174 A bound bond consists of:
A. Two sigma bonds ✓ B. One sigma and one pi bonds
C. One sigma and two pi bonds D. Two pi bonds
Q.175 The func onal group isomer of dimethylether is
✓ A. ethyl alcohol B. propyl alcohol
_______________________________________________________________________________________
C. diethyl ether D. butyl alcohol
Q.176 The next homologue of C10H22 will be
A. C9H20 B. C12H26
✓ C. C11H24 D. C13H28
Q.177 Which is not an organic compound?
A. Glucose B. Plas cs
C. Medicines ✓ D. Water
Q.178 Which of the following compounds contains a triple bond?
A. Alkane B. Alkene
✓ C. Alkyne D. Benzene
Q.179 Which of the following is complex?
A. CaSO4, 0.5 H2O ✓ B. (C6H10O5)n
C. C6H12O6 D. CH4
Q.180 General formula of carboxylic acids is:
A. RCOH B. RCOR
C. RCOOR ✓ D. R-OH
Q.181 A double bond consists of
A. two sigma bonds ✓ B. one sigma and pi bond
C. two sigma and two pi bonds D. two pi bonds
Q.182 Peat is converted into, due ro bacteria and chemical reac ons:
✓ A. Coal B. Coal tar
C. Anthracite D. Lignite
Q.183 Which compound is the most reac ve one?
A. benzene ✓ B. ethane
C. ethane D. ethyne
Q.184 Benzene undergoes cataly c (V2O5) oxida on at 500°C to give:
A. acetylene B. maleic acid
C. benzoic acid ✓ D. maleic
Q.185 Who many different subs tu on products are possible, in principle
when a mixture of bromine and ehtane is allowed to react
A. 3 B. 5
✓ C. 7 D. 9
Q.186 Natural gas is composed primarily of:
✓ A. Methane B. n-Octane
C. n-Butane D. A mixture of octanes
Q.187 Ethylene hydrogen sulphate i s obtained by reac on of H2SO4 with?
A. ethane B. ethanol
✓ C. ethylene D. ethyl chloride
Q.188 Which one of the following reagent dis nguishing ethylene form acetylene?
A. CI2dissolved in CCI4 ✓ B. ammonical Cu2Cl2
C. aqueous alkaline KMnO4 D. conc. H2SO4
Q.189 Which of the following is not formed by the reac on of CI2 on CH4 in sunlight?
A. CH2CI2 B. CH3CI
C. CICI3 ✓ D. CH3CH2CH3
Q.190 Compounds having the same molecular formula, but different func onal groups show
A. metamerism B. posi on isomerism
C. chain isomerism ✓ D. func onal group isomerism
Q.191 iden fy the compound formed when ehtene combines with water in the presence of 10% sulphuric acid and HgSO4 as
catalyst:
A. carbinol B. methanol
_______________________________________________________________________________________
✓ C. ethanol D. glycol
Q.192 Types of cracking are:
A. Thermal B. Cataly c
C. Steam ✓ D. All a, b, c
Q.193 Which is not a fossil fuel
A. Petroleum B. Coal
C. Natural gas ✓ D. None of them
Q.194 Which of the following is NOT oxygen containing func onal group
A. Aldehyde B. Ketone
C. Amide ✓ D. Mer capto
Q.195 Which reac on occurs with saturated hydrocarbons?
A. cataly c hydrogena on B. ready decolourisa on of aqueous bromine
C. polymerisa on ✓ D. thermal cracking
Q.196 Which of the following compound has longest C-H bond?
✓ A. ethane B. ethene
C. ethyne D. benzene
Q.197 Which reac on would not give propene as one product?
A. adding an excess of concentrated sulfuric acid ✓ B. adding warm aqueous sodium hydroxide to
to propan-1-ol 2-bromopropane
C. adding warn ethanolic sodium hydroxide to 1- D. pass propan-2-ol vapour over heated
bromopropane alumimum oxide
Q.198 Structural isomerism is given by:
A. hydrocarbons only ✓ B. hydrocarbons and their deriva ves
C. deriva ves of hydrocarbons D. only carbohydrates
Q.199 In which of the following hybrid orbitals bond angle is minimum
A. SP3 ✓ B. dSP2
C. SP D. SP2
Q.200 The destruc ve dis lla on of coal gives three products. What is not the product of destruc ve dis lla on of coal
A. coal gas ✓ B. carbon dioxide
C. coal tar D. coke
Q.201 Similarity in proper es of different organic compound give rise to the understanding of
A. Polymeriza on B. Non polar
✓ C. Homologous series D. Isomerism
Q.202 Due to the bacterial ac on on wood it is converted into
✓ A. Peat B. Lignite
C. Bituminous coal D. Anthracite
Q.203 Which of the following test helps us to dis nguish between alkane and alkene?
A. Tollen's reagent test ✓ B. Baeyer's test
C. Ammonical cuprous chloride test D. All
Q.204 Which of the following has bond formed by the overlap of SP-SP2 Hybrid orbitals
A. Propyne ✓ B. Propene
C. Ethyne D. 1, 3-butadiene
Q.205 Aroma c compounds burn with sooty flame because:
A. they have high % age of hydrogen B. they have a ring structure
✓ C. they have high % age of carbon D. they resist reac on with air
Q.206 Fossil fuels are:
A. Petroleum B. Coal
C. Natural gas ✓ D. All of these
Q.207 Inorganic compounds are derived from sources:
C. Living ✓ D. Minerals
_______________________________________________________________________________________
Q.208 Which of following is a func onal group
A. Group of atom B. Double bond
C. Triple bond ✓ D. All of these
Q.209 The addi on of HBr to propylene takes place opposite to Markovnikov's rule in presence of:
A. Sunlight B. Pla num catalyst
✓ C. Hydrogen peroxide D. Hg catalyst
Q.210 Replacement of hydrogen atom by -SO3H group in benzene is called
A. Nitra on B. Alkyla on
✓ C. Sulphona on D. Acyla on
Q.211 In ter-butyl alcohol, the ter ary carbon is bonded to
A. two hydrogen atoms B. three hydrogen atoms
C. one hydrogen atom ✓ D. no hydrogen atom
Q.212 Which of the following is not an organic compound
✓ A. Ammonium cyanate B. Glucose
C. Urea D. Methane
Q.213 The general formula of cycloakane is
A. CnH2n+2 ✓ B. CnH2n
C. CnH2n-2 D. CnHn
Q.214 Product of coal is:
A. Peat B. Lignite
C. Bituminous coal ✓ D. All of above
Q.215 Metallic ethynides are formed by the reac on of ________ with
ammonical silver nitrate ammonical cuprous chloride.
Q.216 Peat before conversion to bituminous coal is converted to
✓ A. Lignite B. Anthracite
C. Asphalt D. None
Q.217 Fossil fuels consist of:
A. Coal B. Natural gas
C. Petroleum ✓ D. All of these
Q.218 n-Butane belongs to the
A. Open chain hydrocarbons B. Alicyclic hydrocarbons
C. Alipha c hydro carbons ✓ D. All of these
Q.219 Alkanes containing _________carbon atoms are waxy solids.
A. Upto 4 B. 5 to 17
✓ C. 18 or more D. None of these
Q.220 Polythene is a polymer of
A. Ethane ✓ B. Ethene
C. Acetone D. Propylene
Q.221 Which of the following is not the heterocyclic in nature is
A. Furan B. Thiophene
C. Pyridine ✓ D. Aniline
Q.222 Compound with molecular formula C4H10O can show
A. Metamerism B. Func onal group isomerism
C. Posi on isomerism ✓ D. All of these
Q.223 Metallic ethynides are formed by the reac on of __________ With ammoincal silver nitrate or ammonical cuprous
chloride.
_______________________________________________________________________________________
Q.224 The process in which orbitals of different energies and shapes mix with each other it give equivalent hybrid orbitals is
called:
A. isomeriza on B. polymeriza on
✓ C. hybridiza on D. resonance
Q.225 Which one of the following is a heterocyclic compound
A. Cyclohexanol B. Phenol
✓ C. Pyridine D. Anthracene
Q.226 Organic compounds are derived form sources:
✓ C. Living D. Minerals
Q.227 Indicate the number of isomers of C6H14
A. 4 ✓ B. 5
C. 6 D. 7
Q.228 Alkenes combines readily with electrophilic reagents such as halogens giving:
A. haloalkanes B. gem dihalides
✓ C. vicinal dihalides D. vinyl halide
Q.229 Which of the following compound does not have sp3hybridizaiton state
A. Water B. Ethane
✓ C. BF3 D. Methane
Q.230 Isooctanes burns smoothly having arbitrary value of octane number:
A. 0 B. 25
C. 50 ✓ D. 100
Q.231 Which of the following is the main source of organic compounds
A. Animals B. Plants
C. Coal ✓ D. Petroleum
Q.232 Compounds of carbon and hydrogen in which the tetra valency of carbon is fully sa sfied are called
✓ A. Saturated B. Un-saturated
C. Magne c D. Para-magne c
Q.233 Which is true for mustard gas?
A. It has mustard like odour B. It is not gas but high boiling point liquid
C. It is powerful vesicant ✓ D. All of above
Q.234 Compounds having same molecular formula but different structures are said to be
A. monomers ✓ B. isomers
C. metamers D. tautomers
Q.235 Two unhyberdized p orbital on a carbon atom will overlap separately with the p-orbital of the other carbon atom to
give two bonds wit perpendicular the sigma frame work of
A. Ethane B. Ethene
✓ C. Ethyne D. None
Q.236 Compound C2H4Br2 permits the existence of
A. Metamerism B. Tautomerism
✓ C. Posi on isomerism D. Func onal group isomerism
Q.237 Bonds present between two carbon atoms in Ethylene are
A. Two sigma & One Pi B. One sigma and two Pi
✓ C. One sigma & one Pi D. Two sigma and two Pi
Q.238 Vital force theory was rejected by
A. Berzelius B. Kolbe
✓ C. Wholer D. Lavoiser
Q.239 Peat contains about
A. 60% carbon B. 80% carbon
✓ C. 78% carbon D. 50% carbon
_______________________________________________________________________________________
Q.240 2-propanol shows the
A. Chain isomerism ✓ B. Posi onal isomerism
C. Metamerism D. Geometrical isomerism
Q.241 Which is a mixture of low boiling hydrocarbon
✓ A. Natural gas B. Petroleum
C. Wood D. Graphite
Q.242 Hybridiza on explain the --of orbitals
A. Type of bonding B. Shapes
✓ C. Shape and type of bonding D. None of above
Q.243 Which of following hydrocarbons is liquid at room temperature?
A. butane ✓ B. hexane
C. ethene D. ethane
Q.244 Which of the dihalide on dhalogena on give alkene?
✓ A. Vicinal halide B. Geminal dihalide
C. Both a & b D. None
Q.245 Linear geometry is present in:
A. sp3 B. sp2
✓ C. sp D. d2sp3
Q.246 The conver on of n-hexane into benzene by hea ng in the presence of Pt is called:
A. isomeriza on B. aroma za on
✓ C. dealkyla on D. rearrangement
Q.247 The most unsaturated hydrocarbon is
A. C 2H 4 ✓ B. C 2H 2
C. C 2H 6 D. None of these
Q.248 The frac ons obtained from frac onal dis lla on of petroleum are placed in increasing order of their boiling points.
Which order is correct
✓ A. natural gas, petroleum ether, B. petroleum ether, kerosene, gasoline, natural
gasoline,kerosene gas
C. gasoline, kerosene, natural gas, petroleum D. kerosene, gasoline, petroleum ehter, natural
ether gas
Q.249 The least soluble in water is
✓ A. Phenol B. Methanol
C. Ethanol D. Ace c acid
Q.250 Alkanes commonly give:
A. Subs tu on reac on B. Thermal and cataly c reac on
C. Addi on reac ons ✓ D. Both a & b
Q.251 Select the compound among the following which reacts slower than benzene in electrophilic subs tu on:
A. aniline ✓ B. nitro benzene
C. toluene D. phenol
Q.252 The bond angle between hydrogen atoms and carbon in alkane is
A. 104.5° B. 107.5°
✓ C. 109.5° D. 120.5°
Q.253 Paraffins are also called:
✓ A. alkanes B. alkynes
C. alkenes D. none of these
Q.254 Baeyer's reagent in used in the laboratory for:
✓ A. Detec on of unsatura on B. Reduc on
C. Detec on of glucose D. Oxida on
Q.255 Ini ator in halogena on of alkane is:
✓ A. Free radical B. Anion
C. Addi on D. Sunlight of UV light
_______________________________________________________________________________________
Q.256 Nature of products obtains during cracking depends upon
A. Temperature B. Pressure
C. Nature of hydrocarbons ✓ D. All of these
Q.257 Which compound is the most reac ve one:
A. benzene ✓ B. ethene
C. ehtane D. ethyne
Q.258 The general formula of alcohol is
A. CnH2n+1O ✓ B. CnH2n+1OH
C. CnH2n-1COOH D. CnH2n+1On
Q.259 Which of the following gases is used for illumina ng purpose?
A. Methane ✓ B. Ethane
C. Propane D. Butane
Q.260 Alkanes normally have _______ hybridiza on
A. Sp B. Sp2
✓ C. Sp3 D. d sp3
Q.261 The compound buta-1, 2-diene has
✓ A. Only sp2hybridised carbon atoms B. sp, sp2and sp3hybridised carbon atoms
C. Both sp and sp2hybridised carbon atoms D. Only sp hybridised carbon atoms
Q.262 Straight chain alkanes have lower mel ng and boiling point because:
✓ A. Non polar, weak forces, symmetrical B. Polar, strong forces symmetrical
C. Polar, unsymmetrical D. Strong forces, non-polar
Q.263 Ozonolysis of ethene result in form of
✓ A. Formaldehyde B. Acetaldehyde
C. Acetone D. All of above
Q.264 Which is the chain isomer of n-pentane
✓ A. Isopentane B. Neopentene
C. n-pentene D. Isoopentene
Q.265 Acetylene had a characteris c ethereal smell resembling that of
A. Ginger B. Vinegar
✓ C. Garlic D. Onion
Q.266 Petroleum mainly by contains:
A. aroma c hydrocarbons ✓ B. alipha c hydrocarbons
C. alipha c alcohol D. none of above
Q.267 The process in which one s and two p orbitals mix up with each other is called
A. Sp-hybridiza on ✓ B. Sp2-hybridza on
C. Sp3-hybridza on D. Dsp2-hybridiza on
Q.268 A mixture of hydrocarbons having 13 - 20 carbon atoms
A. Gasoline B. Diesel
✓ C. Kerosene oil D. Lubrica ng oil
E.
Q.269 No of possible alcohol isomers for C4H10O are
A. 02 B. 03
✓ C. 04 D. 05
Q.270 Which is used for welding purposes:
A. ethane B. nitrogen
Q.271 Which type of xylene is the most easily sulphonated:
A. o-Xylene B. p-Xylene
C. m-Xylene ✓ D. all these
Q.272 High-energy irradia on in the stratosphere produces radicals from chlorofluoroalkanes, commonly known as CFCs.
_______________________________________________________________________________________
A. CHFCICFCI B. CHCICF2FCI
✓ C. CHFCF2CI D. CFCICF2CI
Q.273 Ethylene polymerizes at 100 atm pressure at 400°C give:
A. polbenzene B. polyalcohol
C. polypropylene ✓ D. polythylene
Q.274 Which is the general formula of Ketones
A. R2CHO ✓ B. R2CO
C. RCO2H D. RCO2R
Q.275 The atom other than C in a hetrocyclic compound is called as
✓ A. Hetroatom B. Hetroion
C. Hetromolecule D. Hetroelement
Q.276 In t-butyl alcohol, the ter ary carbon is bonded to:
A. Two hydrogen atoms B. Three hydrogen atoms
C. One hydrogen atom ✓ D. No hydrogen atom
Q.277 A present oil refineries in Pakistan are:
A. One B. Two
Q.278 Which is the C_C bond length in benzene among the following:
A. 1.5A° B. 120A°
✓ C. 134A° D. 139A°
Q.279 Which is not present in heterocyclic compound
A. O B. N
C. S ✓ D. CI
Q.280 A compound of carbons and hydrogen use in welding is:
A. C 2H 6 B. CH4
✓ C. C 2H 2 D. C 2H 4
Q.281 The func onal group of ester is
✓ A. RCOOR B. RCOOH
C. ROR D. RCHO
Q.282 Cracking done with heat at high temperature is called as ________ cracking
✓ A. Thermal B. Cataly c
C. Steam D. None of them
Q.283 Secondary carbons in methyl cyclopropane are
A. 01 ✓ B. 02
C. 03 D. Zero
Q.284 The compound C4H10O can show
A. Posi on isomerism B. Metamerism
C. Func onal isomerism ✓ D. All types
Q.285 Forma on of alkanes by ac on of Zn of alkyl halides in aqueous solu on is called:
✓ A. Frankland reac on B. Wurtz reac on
C. Cannizzaro reac on D. Kolbe's reac on
Q.286 Which shows maximum hindrance for rota on at C-C bond
A. Ethane B. Ethene
✓ C. Ethyne D. Propane
Q.287 Alkyl halides when reduced with nascent hydrogen in the presence of ZN + HCI, are converted to:
A. alkynes B. alkenes
✓ C. alkanes D. alcohol
Q.288 Ether show the phenomenone of
A. Posi on isomerism B. Func onal group isomerism
✓ C. Meta merism D. Cis. trans isomerism
_______________________________________________________________________________________
Q.289 Which is the most reac ve?

A. Alkane ✓ B. Alkene
C. Alkyne D. Benzene
Q.290 Geological survey of Pakistan es mates about billion tons of coal in Pakistan:
A. 182 B. 183
✓ C. 184 D. 185
Q.291 Which is not a nucleophile
A. Benzene ✓ B. Chlorine
C. Ethene D. Ethanol
Q.292 Number of ter ary carbon atoms in methyl cyclopropane is
A. zero ✓ B. 1
C. 2 D. 3
Q.293 As the number of carbon atoms increases the number of isomers also increase. The 6C compound hexane has as many
as
A. 3 isomers ✓ B. 5 isomers
C. 6 isomers D. 10 isomers
Q.294 The nature of - CI group is:
A. ortho direc ng ✓ B. meta direc ng
C. para direc ng D. ortho and para direc ng
Q.295 Func onal dis lla on of which separates many compounds?
A. Coke B. Coal gas
✓ C. Coal tar D. All of these
Q.296 Rates of organic reac ons are
A. Fast B. Very fast
✓ C. Slow D. Non-reac ve
Q.297 Coal heated in the absence of air of about 500-1000°C is converted to
A. Coke B. Coal gas
C. Coal tar ✓ D. All above
Q.298 A property in which a compound have same molecular formula but different structural formula:
A. Polymeriza on B. Polymorphism
✓ C. Isomerism D. Metamerism
Q.299 With AICI3 as catalyse, benzene reacts with alkyl and acyl chlorides giving alkylated and acyclated benzene
respec vely ,this reac on is known as:
✓ A. Friedel and cra reac ons B. nitra on reac on
C. halogena on reac on D. aldol condensa on
Q.300 Which gasoline is be er?
A. Of low boiling points B. Of low molecules mass
C. Of high octane ✓ D. All of these
Q.301 When bromine reacts with propane in an organic solvent at room temperature. what is the mechanism by which the
bromine a acks the propane:
✓ A. electrophilic addi on B. electrophilic subs tu on
C. nucleophilic addi on D. nucleophilic subs tu on
Q.302 Butene can have ,,,,,
A. Geometrical isomerism B. 2-posi on isomers
✓ C. Both a and b D. All structural isomers
Q.303 Ether shows the phenomenon of
A. Posi on isomerism B. chain isomerism
✓ C. metamerism D. cir-trans isomerism
Q.304 Iden fy the heterocyclic compound
A. Toluene ✓ B. Pyridine
_______________________________________________________________________________________
C. Butanoic acid D. Propenol
Q.305 The shape of benzene molecule is:
A. linear ✓ B. plane hexagonal
C. pyramidal D. tetrahedral
Q.306 Halogena on of alkanes involve:
✓ A. Free radical subs tu on B. Electrophilic subs tu on reac on
C. Nucleophilic subs tu on reac on D. Elimina on reac on
Q.307 Wohler succeeded in obtaining, urea from
A. cyanogen ✓ B. ammonium cyanate
C. ammonium hydroxide D. none of these
Q.308 Organic compounds generally react at ________ rates
✓ A. Slow B. Fast
C. Moderate D. None of them
Q.309 Which reagent could detect the presence of alcohol in a petrol consis ng mainly of a mixture of alkanes and alkenes?
✓ A. Na B. Br2(in CCI4)
C. KMnO4(aq) D. 2,4-dinitrophenylhydrazine
Q.310 Fossil fuels form under ground due to:
A. Itself from minerals B. Decompose of organisms under the ac on of
becteria
✓ C. Decomposi on of living bodies without the D. High temperature and pressue
presence of microorganisms
Q.311 Which acetylene is passed through a copper tube at 300°C . It polymerizes to:
✓ C. benzene D. none of all
Q.312 The gasoline with high octane No. has __________
A. More knocking ✓ B. Less knocking
C. No knocking D. Only knocking
Q.313 In ter ary butyl bromide ter ary carbon is a ached to hydrogen atoms
A. 01 B. 02
C. 03 ✓ D. Zero
Q.314 Which one of he following can be used as catalyst in Friedel Cra 's reac on?
A. HNO3 B. ZnCI2
✓ C. AICI3 D. HCI
Q.315 The cyclic compound having atoms other than carbon in its ring are called
A. Carbocyclic B. Alicyclic
✓ C. Hetero cyclic D. Homocyclic
Q.316 Which of the following alkenes follow Markovnikov's rule?
A. Ethene ✓ B. Propene
C. Butene D. All of above
Q.317 Organic compounds are very complex. Which of following is simplest organic compond
A. Starch B. Hemoglobin
✓ C. Methane D. None of these
Q.318 The branch of chemistry which deals with the study of compounds containing carbon as an essen al element is called
A. physical B. inorganic
C. nuclear ✓ D. organic
Q.319 Methane is produced when aluminum carbide is treated with
A. Alcohol B. Base
✓ C. Water D. Acid
Q.320 Toluene reacts with CH3CI in the presence of anhydrous AICI3 to form:
A. diphenyl methane ✓ B. o-and p-xylenes
C. m-xylene D. 1,3,5,-triethyl benzene
_______________________________________________________________________________________
Q.321 According to x-ray studies all C-C H bond lengths in benzene are:
A. 1.279A° and 1.09A° respec vely ✓ B. 1.397A° and 1.09A° respec vely
C. 1.01A° and 1.297A° D. none of these
Q.322 LPG (liquefied petrolum gas) main contains
A. CH4 B. C 2H 2
C. C 3H 8 ✓ D. C4H10
Q.323 Iden fy the hydrocarbon formed, when ethyl bromide reacts with alcoholic KOH at 100°
A. Methane B. Ethane
✓ C. Ethene D. Ethyne
Q.324 How many Pi bonds are present in ethane molecule
A. Two B. One
C. Three ✓ D. No pie bond
Q.325 Which of the following pairs shows isomerism
A. CH2Cl2and CHCl3 B. C2H4and C3H6
C. C6H6and C3H8 ✓ D. CH3OCH3and C2H5OH
Q.326 Vital force theory is:
A. Organic compounds can be prepared B. Organic compounds can be prepared form
themselves. inorganic compounds
✓ C. Organic compounds cannot be prepared in D. None of these
laboratory from inorganic compounds
Q.327 Length of carbon-carbon bond is least in.
A. ethane B. ethyne
✓ C. ethene D. Benzene
Q.328 The carbon atom of the HCHO is
A. Sp hybridized ✓ B. Sp2hybridized
C. Sp3hybridized D. Not hybridized
Q.329 The number of pi bonds present in acrylonitrile is
A. 1 B. 2
✓ C. 3 D. 4
Q.330 Iden fy the compound formed, when ethylene combines with water in the presences of 10% sulphuric acid and HgSO4
as catalyst
A. Carbinol B. Methanol
✓ C. Ethanol D. Glycol
Q.331 Most organic compounds are soluble in:
✓ A. Non-polar solvents B. Benzene
C. Petroleum ether D. Polar solvents
Q.332 Aroma c hydrocarbons are the deriva ves of:
A. normal series of parafiens B. alkene
✓ C. benzene D. cyclohexane
Q.333 State of hybridiza on in the carboca on is
A. sp3 ✓ B. sp2
C. sp D. dsp2
Q.334 Chlorofluoroalkanes, commonly known as CFCs, undergo homoly c fission by ultraviolet irradia on in the
stratosphere.
Which radical could result from this irradia on of CHFCICF2CI?
A. CHFCICFCI B. CHCICF2CI
✓ C. CHFCF2CI D. CFCICF2CI
Q.335 Which of the following compounds will form a hydrocarbon on reac on with Grignard's reagent?
✓ A. CH2CH2CH3 B. CH3CHOH3
C. CH3COOCH3 D. CH3CHO
Q.336 Diversity of organic compound in millions is:
A. Four B. Five
_______________________________________________________________________________________
✓ C. Six D. Seven
Q.337 The maximum number of isomer for an alkene with the molecular formula C4H8
A. 2 B. 3
✓ C. 4 D. 5
Q.338 F. Wohler prepared compound from ammonium cyanate:
A. Protein B. Lipids
C. Carbohydrates ✓ D. Urea
Q.339 Hydrogena on of alkenes/alkynes in the presence of Ni as catalyst at 300°C results in the forma on of corresponding
alkanes, this reac on is known as:
✓ A. Saba er - Sendrens reac on B. Kobes reac on
C. Cannizaro's reac on D. Haloform reac on
Q.340 Coal is used to bake bricks in lime kiln:
A. 40% B. 50%
✓ C. 80% D. None of these
Q.341 Branched chain paraffins having ter aty carbon atoms are named as
A. Alkanes ✓ B. Iso alkanes
C. Neo alkanes D. All of these
Q.342 The geometric isomerism is caused by
✓ A. The restricted rota on of pi bond B. Free rota on of a pi bond
C. The presence of similar groups on a carbon D. The presence of a triple bond in a compound
atom
Q.343 I-Chloropropane has two isomers. It is an example of
A. Chain isomerism ✓ B. Posi on isomerism
C. Func onal group isomerism D. Metamerism
Q.344 Which reac on produces a free radical
A. SN reac on ✓ B. Homoly c fission reac on
C. Heteroly c fission reac on D. Addi on reac on
Q.345 Which reagent could detect the presence of alcohol in a petrol consis ng mainly of a mixture of lakanes and alkenes?
✓ A. Na B. Brin (CCI4)
C. KMnO4(aq) D. 2,4-dinitrophenylhydrazine
Q.346 Quality of fuel is judged from its octane number. The best fuels are
A. straight chain hydrocarbons ✓ B. branched chain hydrocarbons
C. cyclic compounds D. compounds containing benzene ring
Q.347 Maximum no of isomers of alkane with molecular formula C4H8 are
A. 03 ✓ B. 04
C. 05 D. 06
Q.348 Major por on of natural gas is
✓ A. CH4 B. C 2H 6
C. C 3H 8 D. C4H10
Q.349 During nitra on of benzene the ac ve nitra ng agent is;
A. NO3 ✓ B. NO+2
C. NO-2 D. HNO3
Q.350 Which of the type of alcohol needs more conc, H2SO4 and high temperature for dehydra on:
✓ A. Primary alcohol B. Secondary alcohol
C. Ter ary alcohol D. None
Q.351 Alkenes normally have _______ hybridiza on
A. Sp ✓ B. sp2
C. Sp3 D. d sp3
Q.352 1-butene an 2-butene are an example of
A. chain isomerism ✓ B. posi onal iosomerism
C. metamerism D. func onal group isomerism
_______________________________________________________________________________________
Q.353 If similar group are a ached to the same side, of C=C of alkene then it is
✓ A. Cis isomer B. Trans isomer
C. Tautomer D. All
Q.354 Iden fy the compound which which has a bond angle of 109.5°
A. Ethyne B. Ethere
✓ C. Methane D. Benzene
Q.355 In the presence of high temperature and pressure peat is converted to:
✓ A. Lignite B. Bituminous coal
C. Anthracite D. Coal
Q.356 Which set of hybrid orbital has planer triangle shape?
A. sp3 B. sp
✓ C. sp2 D. dsp2
Q.357 Normal by product of cracking is
A. Ethane B. Butane
C. Benzene ✓ D. All of them
Q.358 C4H8shows ______ isomerism
A. Chain isomerism B. Geometric isomerism
C. Posi on ✓ D. All of these
Q.359 Which of the following is the most stable:
A. 1-butene B. 1-pentene
C. 2-butene ✓ D. 2-pentene
Q.360 Which of the following is a product of destruc ve dis lla on of coal
A. ammonia ✓ B. coke
C. cyanides D. kerosene
Q.361 A group of atoms or atom which Imparts characteris cs proper es to the class of compounds is called:
A. Isomerism B. Polymorphism
✓ C. Func onal group D. Polymerism
Q.362 A mixture of iso octane and n-heptane containing 20% n-heptane octane number of gasoline is
A. 20 B. 40
C. 60 ✓ D. 80
Q.363 Methane is used:
A. in the prepara on if urea B. in the prepara on of hydrogen
C. in the prepara on of chloroform ✓ D. in all theses prepara ons
Q.364 Which of the following is not an electrophilic subs tu on reac on of benzene?
A. nitra on B. sulphona on
C. Fridal-Cra alkyla on ✓ D. free radical chlorina on of benzene
Q.365 Which of the following is isolated polycyclic compound
A. Anthracene B. Naphthalene
C. Phenathrene ✓ D. None of these
Q.366 Linear shape is associated with which set of hybrid orbitals?
✓ A. sp B. sp2
C. sp3 D. dsp2
Q.367 Undersaturated hydrocarbons containing a double bond are called
A. Paraffin B. Alkanes
✓ C. Olefins D. Acetylene
Q.368 Which is the use of methane?
A. As a fuel B. For prepara on of chloroform
C. For prepara on of methyl alcohol ✓ D. All
Q.369 Total coal resources in Pakistan are ___ billion tons
A. 150 B. 175
_______________________________________________________________________________________
✓ C. 184 D. 210
Q.370 High-energy irradia on in the stratosphere produces radicals from chlorofluoroalkanes, commonly known as CFCs
Which radical could result from this irradia on of CHFCICF2CI?.
A. CHFCICFCI B. CHCHCF2CI
✓ C. CHFCF2CI D. CHCICF2CI
Q.371 Which has sp hybridiza on?
A. CH3--CH3 B. CH2=CH2
✓ C. CH≡ CH D. CH3CL
Q.372 A nucleophile must
A. be an atom B. a group of atoms
✓ C. have a Ione pair D. be nega vely chargedd
_______________________________________________________________________________________
14 Hydrocarbon
Q.1 CH4 react with CI2 in direct sunlight and is obtained

A. CH3CI B. CHCI3
C. CH3CI2 ✓ D. None of these
Q.2 Which of the following possesses the highest mel ng point?
A. Chlorobenzene B. o-Dichlorobenzene
C. m-dichlorobenzene ✓ D. p-Dichlorobenzene
Q.3 Synthe c rubber is made by the polymeriza on of
A. Chloroform B. Acetylene
C. Divinylacetylene ✓ D. Chloroprene
Q.4 Benzene reacts with ozone and gives
A. Glycerin ✓ B. Glyoxal
C. Maleic anhydride D. Benzoic acid
Q.5 For halogena on reac ons which is the fastest reac on
A. Chlorina on B. Bromina on
C. Iodina on ✓ D. Fluorina on
Q.6 Which one of the following is (m-xylene)
A. 1,2 dimethyl benzene ✓ B. 1,3 dimethyl benzene
C. 1,5 dimethyl benzene D. 1,4 dimethyl benzene
Q.7 Nitroalkane are used in
A. Fuel B. Solvents
C. Organic synthesis ✓ D. All of them
Q.8 Alkyl halide on reac ng with Mg. form alkyl-Mg-halide which on futher hydrolysis produces
✓ A. Alkane B. Alcohol
C. Acid D. Phenol
Q.9 In the presence of anhydrous AICI3 Toluene can be prepared by the reac on of
A. C6H6 + CH4 ✓ B. C6H6 + CH4CI
C. C6H6CI + CH4CI D. C6H6CI + CH4
Q.10 Compound 2.2 dimethyl propane is also called
A. Iso actane ✓ B. Neopentane
C. Iso butane D. All above
Q.11 Benzene does not undergo
A. subs tu on reac ons B. addi on reac on
C. oxida on reac on ✓ D. elimina on reac ons
Q.12 Sulphona on of benzene yields:
✓ A. benzene sulphonic add B. nitrobenzene
C. maleic anhydride D. benzophenone
Q.13 Each different compound should have a different name was published by IUPAC system of nomenclature in
A. 1892 B. 1830
C. 1947 ✓ D. 1979
Q.14 Benzene can be prepared from the method:
A. From polymeriza on of acetylene B. From chlorobenzene
_______________________________________________________________________________________
C. From dehydrogena on of alkenes ✓ D. All of these
Q.15 Monosubs tuted benzene can have disubs tu on at posi on:
A. Ortho B. Meta
C. Para ✓ D. a, b, c
Q.16 Cataly c hydrogena on is an analy cal tool in the laboratory as the reac on is generally
A. Qualita ve B. Quan ta ve
✓ C. Both A and B D. None of these
Q.17 The difference of energy showing high stability is (kj/mol)
A. -119.5 B. -231.5
C. -358.5 ✓ D. -208
Q.18 Alkenes normally have _______ geometry
A. Tetrahedral B. Linear
✓ C. Planer D. None
Q.19 Which reac on is used as test for the presence of alkenes
✓ A. reac on of cold dilute alkaline KMnO4 B. combus on
C. polymeriza on D. cataly c hydrogena on
Q.20 Bromo ethane can be converted into ethene by the reagent
✓ A. Alcoholic KOH B. (Aq) KOH
C. dil HCl D. H3PO4
Q.21 Benzene is not prepared from
A. Acetylene B. Phenol
✓ C. Benzoic acid D. Bromo benzene
Q.22 Aroma c compounds burn with sooty flame because
A. they have high percentage of hydrogen B. they have a ring structure
✓ C. they have high percentage of carbon D. they resist reac on with air
Q.23 Which of the following compound is sulphonated with difficulty
A. Benzene B. Toluene
✓ C. Nitrobenzene D. Aniline
Q.24 Ethylene decolorizes cold dilute solu on of KMnO4. This test is known as
A. coloura on test ✓ B. Baeyer's test
C. silver mirror test D. ring test
Q.25 The molecular mass determined by vapour density method for benzene was
A. 70.108 B. 80.108
C. 90.108 ✓ D. 78.108
Q.26 Different subs tuents are named based upon :
✓ A. High priority group B. Low priority group
C. Intermediate priority group D. No priority group is preferred
Q.27 Subs tuted phenyl groups are called
A. Acyl groups B. Phenyl groups
✓ C. Aryl groups D. Alkyle groups
Q.28 The three alterna ng double and single bonds in benzene are in fact:
A. Pure single bonds B. Resona ng bonds
C. Conjugate bonds ✓ D. b and c
Q.29 The molecule of ethane possess which hybridiza on
A. sp3 B. sp2
✓ C. sp D. sp2d
Q.30 Which compound is less reac ve than benzene
A. Anisole ✓ B. Benzoic Acid
C. Toluene D. Aniline
Q.31 When the nitrobenzene is treated with chlorine in the presence of Ferric chloride then
_______________________________________________________________________________________
A. O-nitochlorobenzene ✓ B. m-chloronitrobenzene
C. p-nitochlorobenzene D. O,P-nitrodichlorobenzene
Q.32 Aroma c hydrocarbons are the deriva ves of
A. Normal series of paraffin ✓ B. Alkenes
C. Benzene D. Cyclohexane
Q.33 Benzene was first of all discovered in gas of vegetable oil in:
A. 1800 B. 1805
C. 1810 ✓ D. 1825
Q.34 Halogen on trea ng with solver salts of acids give:
A. alcohols B. esters
C. phenol ✓ D. alkyl halide
Q.35 The most stabel molecule is:
A. Benzene B. Ethene
C. Ethyne ✓ D. Ethane
Q.36 Sn1 reac on is favoured by:
A. Non-polar solvents ✓ B. Bulky groups on the carbon atom a ached to
halogen atom
C. Small groups on the carbon atom a ached to D. None of the above
halogen atom
Q.37 The hydrocarbon used for polymeriza on is
✓ C. Alkynes D. All of above
Q.38 The C-C bond length of benzene is, than of alkane and alkenes.
A. greter B. lesser
✓ C. Intermediate D. None of these
Q.39 The heat of hydrogena on of most of the alkene is about
✓ A. 120 kj/mol B. 100 kj/mol
C. 140 kj/mol D. 105 kj/mol
Q.40 When methane reacts with Cl2in the presence of diffused light the products obtained are
A. chloroform only B. carbon tetrachloride only
C. chlormethane and dichloromethane ✓ D. mixture of a, b , c
Q.41 Monocyclic aroma c hydrocarbons are benzene rings:
✓ A. One B. Two
C. Two condensed rings D. Two isolated rings
Q.42 During the prepara on of alkanes the hydrogena on of alkenes or alkynes the catalyst may be
A. H2SO4 ✓ B. Ni
C. Fe2O3 D. AI2O3
Q.43 Empirical formula mass of benzene is mes lesser than molecular formula mass:
A. Four B. Five
✓ C. Six D. Seven
Q.44 Marsh gas was the name given to
✓ A. Methane B. Ethane
Q.45 The hydribiza on in benzene is:
A. sp3 ✓ B. sp2
C. sp D. dsp2
Q.46 All are ortho & Para direc ng except
A. X B. OH
✓ C. NR3 D. NH2
Q.47 Hydrolysis of benzene sulphonic acid yield
✓ A. Benzene B. Chloro benzene
_______________________________________________________________________________________
C. nitrobenzen D. analine
Q.48 Characteris cs of aroma c are:
A. Low hydrogen carbon ra o than alkanes B. Characteris cs odour
✓ C. a&b D. Characteris cs proper es
Q.49 Hea ng a micture of sodium benzoate and soda lime gives
✓ A. Benzene B. Methane
C. Sodium benzoate D. Calcium benzoate
Q.50 Benzene + Ozone → Y.in this sequence Y is
A. Benzene monoozonide B. Benzene triozonide
✓ C. Benzene triozonide D. Succinic acid
Q.51
✓ A. Pent-1-en-3yne B. 2-pentyne-4ene
C. 1-pentene-3-yne D. Pent-2-yen-4-ene
Q.52 An alkynes having Carbon count of 20 is
A. Gas B. Liquid
✓ C. Solid D. None
Q.53 Simplest aroma c compound is:
✓ A. Benzene B. Toluene
C. Aniline D. Phenol
Q.54 Benzophenone is also called the
✓ A. Diphenyl ketone B. Dimethyl Ketone
C. Methyl phenyl Ketone D. Biphenyl
Q.55 No sigma bonds in benzene are
A. 03 B. 06
✓ C. 12 D. 15
Q.56 IUPAC name of compound CH3(CH2)4-C(CH3)-CH2-CH3
✓ A. 4.Ethyl-4-methyl nonane B. 3.4-dimethyl-3-n-propyl nonane
C. 6-methyl-6-Ethyl-nonane D. None of these
Q.57 Meta direc ng group decreased the,,,,,,,,,of the benzene ring
A. Physical ac vity ✓ B. Chemical reac vity
C. Density D. None
Q.58 Acetone can be prepared by Ozonolysis of
A. 1-butene ✓ B. Iso-butene
C. 2-butane D. 2-butyne
Q.59 During the prepara on of alkynes the ac ve metals that react with tera halo-alkanes are
A. Zn B. Mg
✓ C. Both a and b D. None
Q.60 Which can be used for dehydra on of alcohol
A. P4O10 B. H2SO4
C. H3PO4 ✓ D. All of them
Q.61 A fuel has the same knocking property as a mixture of 70 isooctane (2, 2, 4- trimethyl pentane) and 30% n-heptane by
volume the octane number of the fuel is
A. 100 ✓ B. 70
C. 50 D. 40
Q.62 In alkynes C = C bond length is
A. 1.54 A° B. 1.34 A°
✓ C. 1.20 A° D. 1.397 A°
Q.63 The reac on in which ketone is reduced to the alkane is called
A. Kolb ✓ B. Clemmensen
_______________________________________________________________________________________
C. Cannizzaro D. None
Q.64 In CH4, all the H - C - H bond angles are
A. 120° B. 107°
C. 109° ✓ D. 109.5°
Q.65 Ethylene combines with water in the presence of H2SO4+ HgSO4and forms
A. ethyl chloride ✓ B. ethyl alcohol
C. carboxylic acid D. none of these
Q.66 The possibility of different pairing schemes of valence electrons of atoms is called
A. hyperconjuga on B. taulomerism
✓ C. Resonance D. Molecular oribtal
Q.67 Benzene is stable to :
A. oxida on B. nitra on
✓ C. KMnO4 D. Sulphona on
Q.68 Ozonolysis of propene gives
A. Methanal B. Ethanal
C. Prop anal ✓ D. Both a and b
Q.69 Which of the following group are ortho and para direc ng?
✓ A. OH B. NO2
C. COOH D. CHO
Q.70 The temperature used for the hydrogena on of alkenes using Ni is
A. 200°C B. 400°C
✓ C. 200 - 300°C D. 1000°C
Q.71 Which group when a ached to benzene decreases
A. -OCH3 ✓ B. -CHO
C. -CH3 D. -NH2
Q.72 Oxida on of secondary alcohol gives:
A. organic acid B. ether
C. aldehyde ✓ D. ketone
Q.73 Hybridiza on of each carbon atom in benzene ring is
A. sp hybridized ✓ B. sp2hybridized
C. sp3 D. dsp2
Q.74 The hydrocarbons having double bonds normally end with suffix
A. Ane ✓ B. Ene
C. Yne D. Oic
Q.75 Gas evolved when sodium acetate is heated with sods lime
A. CO2 B. H2
✓ C. CH4 D. Both and b
Q.76 Ethyne is produced when tetrabromo ethane reacts with
✓ A. Zn B. Fe
C. K D. Ca
Q.77 Which alcohol is more reac ve towards dehydra on
A. Ethanol B. 2-Propanol
C. Methanol ✓ D. Isobutyl alcohol
Q.78 Which gas is produced by trea ng CaC2with water?
✓ C. acetylene D. HCl
Q.79 Ethylene polymerized at 100 atm pressure and 400°C to give
A. Polybenzene B. Polyalcohol
C. Polypropylene ✓ D. Polyethylene
Q.80 Composi on of nitra ng mixture is
_______________________________________________________________________________________
A. Conc HCi + Conc. HNO3 ✓ B. Conc. H2SO4+ Conc. HNo3(1:1)
C. Conc. H2SO4 + NO3 D. Conc. H2SO4 + NO23
Q.81 Cataly c oxida on of benzene gives:
A. Benzene sulphonic acid B. Nitrobenzene
✓ C. Maleic anhdride D. benzophenone
Q.82 Which one of following is not monocyclic aroma c hydrocarbon
A. Benzaldehyde B. Benzoic acid
C. Benzene sulfonic acid ✓ D. Biphenyl
Q.83 Benzene was discovered by first of all:
✓ A. Micheal faraday B. Hofmann
C. Ainderson D. Sorenbon
Q.84 Theπ-electron in the styrene is
A. 12 B. 10
✓ C. 8 D. 6
Q.85 When propylene reacts with HBr in the presence of peroxide the product is
A. n-propyl alcohol B. propyleneperoxide
✓ C. n-propyl bromide D. Iso-propyl bromide
Q.86 Which of the following compound reacts slower than benzene in the electrophilic subs tu on
A. Phenol B. Toluene
✓ C. Nitrobenzene D. Aniline
Q.87 Benzene can react with __________ easily to produce subs tuated product
A. Nucleophile B. Electrophiles
C. Weak Electrophiles ✓ D. Strong Electrophiles
Q.88 For which mechanism the first step involved is the same:
A. E1and E2 B. E2and SN2
C. W1and E2 ✓ D. E1and SN1
Q.89 Benzene was discovered by Michael Faraday's in
A. 1824 ✓ B. 1825
C. 1826 D. 1827
Q.90 Resonance energy of benzene is (in KJ mol-1):
A. 120 ✓ B. 150
C. 170 D. 180
Q.91 A single benzene ring can have _________ ortho posi ons maximally
A. one ✓ B. two
C. three D. four
Q.92 Main source of aroma c compound is
A. Petroleum ✓ B. Coal tar
C. Living organisms D. Dead animals
Q.93 Hexagonal structure of benzene was confirmed by the
A. NMR B. Mass spectrometer
✓ C. X-ray D. HPLC
Q.94 Introduc on of a second methyl group in methylbenzene will give how many isomeric dimethylienzenes
A. 2 B. 1
C. 4 ✓ D. 3
Q.95 Aroma means :
✓ A. Fragrant B. indivisible
C. Least affinity D. Rock oil
Q.96 The deriva ve not found in nature are:
A. Alkanes B. Fats
C. Carbohydrates ✓ D. Alkyl halides
_______________________________________________________________________________________
Q.97 Ozonolysis of 2.methyl-2-butane produces
A. Aldehyde B. Ketone
✓ C. Both aldehydes & Ketone D. Mixture of Ketones
Q.98 Alkanes can be also prepared from the alkyl halide using the pd-charcoal as catalyst the method is known as
A. Hydrogena on B. Hydrolysis
✓ C. Hydrogenolysis D. Hydra on
Q.99 Catalyst for Friedal cra reac on is
A. AlCI3 B. NaCI
C. DCI3 ✓ D. Anhydrous AICI3
Q.100 The nature of - Cl group is
A. ortho direc ng B. meta direc ng
C. para direc ng ✓ D. ortho and para direc ng
Q.101 Which of the following is a primary halide:
A. Isopropyl iodide B. Ter ary butyl bromide
C. Secondary butyl iodide ✓ D. Neo hexyl chloride
Q.102 Molecular formula of naphthalene is
A. C8H10 ✓ B. C10H8
C. C10H10 D. C12H10
Q.103 In Alkanes, every carbon atoms undergoes
A. sp hybridiza on ✓ B. sp3hybridiza on
2
C. sp hybridiza on D. dsp2
Q.104 The greatest bond angle is present in
A. Cyclopropane B. Cyclobutane
C. Cyclopentane ✓ D. Cyclohexane
Q.105 How many molecules of chlorine adds in benzene in the presence of sunlight
A. One B. Two
Q.106 When one hydrogen atom of alkanes is replaced / removed, then it is called
A. Alkene ✓ B. Alkyl
C. Aldehyde D. Saturated hydrocarbons
Q.107 Reac on of sodium benzoate with NaOH in presence of CaO is called
C. Polymeriza on ✓ D. Decraboxyla on
Q.108 Which one of the following will produce a primary alcohol by reac ng with CH3MGI.
A. Acetone ✓ B. Acetaldehyde
C. Methyl cyanide D. Ethyl acetate
Q.109 Reduc on of ketone involves the conversion of the carbonyl compound into
A. Methyl group ✓ B. Methylene group
C. Hydrogen D. Both A & B
Q.110 Amongst the following, the compound that can be most readily sulphonated is
Q.111 Vinyl acetylene combines with HCl to form
A. poly acetylene B. benzene
✓ C. chloroprene D. divinylacetylene
Q.112 The order of reac vity of halogens in alipha c subs tu on reac ons is
A. Br2>CI2>F2 B. CI2>Br2>F2
✓ C. CI2 CI2>Br2 D. F2>Br2>CI2
Q.113 Which of the following alkanes cannot be prepared by Kolbs electrolysis
A. Methane B. Propane
_______________________________________________________________________________________
C. Pentane ✓ D. All of these
Q.114 The term aroma c was derives from
✓ A. Greek word B. La n
C. Russian D. English
Q.115 Benzene does not undergo polymeriza on and it is also resistant to
A. Reduc on ✓ B. Oxida on
C. Alkyla on D. Ozonolysis
Q.116 Which one does not decolourized KMnO4
A. Alkenes B. Alkynes
✓ C. Benzene D. All above
Q.117 Synthesis of rubber is made by polymeriza on of
A. chloroform ✓ B. acetylene
C. divinylacetylene D. butene
Q.118 When sodium benzoate is treated with soda lime (NaOH) benzene is formed. What is the other product
✓ A. Na2CO3 B. NaHCO3
C. Ca(OH)2 D. CaCO3
Q.119 Which compound is the most reac ve one?
A. Benzene B. Ethene
C. Ethane ✓ D. Ethyne
Q.120 Alkanes containing carbons C18 ownwards are
A. Gases B. Liquids
✓ C. Waxy solids D. Solids
Q.121 Cataly c oxida on of alkanes is used for the prepara on of
A. Ketones B. Adehydes
✓ C. Fa y acids D. Carbonyylic acids
Q.122 The treatment of benzene with isobutene in the presence of sulphuric acid give
A. isobutyl benzene B. tert-Butyl benzene
C. n-Butyl benzene ✓ D. No reac on
Q.123 The method used only for the produc on of symmetrical alkanes
✓ A. Kolb's method B. Clemmenen
C. Cannizzaro D. Wolf kishner
Q.124 Sp3hybrid orbitals are oriented at an angle of
A. 107.5° B. 108.5°
✓ C. 109.5° D. 103.5°
Q.125 The sp2hybrid orbitals are oriented in space at on angle
A. 180° B. 109.5°
C. 100° ✓ D. 120°
Q.126 C-C bond length in benzene is intermediate between those in
✓ A. Alkane and alkene B. Alkene and alkyne
C. Alkane an alkyne D. None of these
Q.127 Arenes are also called :
A. Atom B. Hydrocarbons
C. Aroma c ✓ D. Benzene
Q.128 With AlCl3as catalyst, benzene reacts with Alkyl and Acyl chlorides giving alkylated and acylated benzene respec vely.
This reac on is known as
✓ A. Friedel and Cra s reac on B. Nitra on reac on
C. Halogena on reac on D. Aldol condensa on
Q.129 The suitable condi on of cataly c oxida on of alkanes is
✓ A. Cu & 400°C B. Pt & room temperature
C. Ni & 250°C D. V2O5& 100°C
_______________________________________________________________________________________
Q.130 An organic compound on treatment with Br2 in CCI4 gives bromoderiva ve of an alkene. The compound will be
A. CH3 - CH = CH2 B. CH3CH = CHCH3
✓ C. HC = CH D. H2C CH2
Q.131 Alkenes combine readily with electrophilic reagents such as halogens giving
A. haloalkanes B. gem-dihalides
✓ C. vicinal dihalides D. vinyl halides
Q.132 Replacement of hydrogen by NO2group is called
A. sulphona on B. hydra on
✓ C. nitra on D. cracking
Q.133 Benzene rings are fused at posi on:
✓ A. Ortho B. Meta
C. Para D. Meta and para
Q.134 Amongst the following, the compound that can be most readily sulphonated is:
✓ A. Toluene B. Benzene
C. Nitrobenzene D. chlorobenzene
Q.135 Among the following, poly cyclic compound is:
A. Styrene B. Cumene
✓ C. Naphthalene D. Xylene
Q.136 Saba er senderens reac on proceeds using a type of catalysis called
A. Electron catalysis ✓ B. Surface catalysis
C. Ac va on catalysis D. Transi on catalysis
Q.137 Which of the following is the best nucleophile?
A. CI B. Br
✓ C. I D. F
Q.138 The conversion of n-hexane into benzene by hea ng in the presence of Cr2O3is called:
A. Isomeriza on ✓ B. Aroma za on
C. Dealkyla on D. Rearrangement
Q.139 When benzene is burnt in free supply of air, it is completely oxidized to
A. CO ✓ B. CO2, H2O
C. H2CO3 D. None
Q.140 Acetylene gives
A. White ppt. with
3
and red ppt. with ✓ B. White ppt. with ammonical AgNo3 and red
ammoniacal AgNO ammonical Cu(NO3)2 ppt. with ammonical Cu2CI2
C. White ppt. with both D. Red ppt. with both
Q.141 Bayer's reagent is mexture of
A. HCl and ZnCl2 B. Aqous bromine
✓ C. Alkaline KMnO4 D. Mix of Br2& KMnO4
Q.142 Which of the following species par cipate in sulphona on of benzene ring?
A. H2SO4 B. HSO-3
✓ C. SO3 D. SO-2
Q.143 Under iden cal condi ons even though to proceeds by the same mechanism reac on 1 is faster than reac on 2.
reac on 1 CH3CHBrCH3 + NACH → CH3 CH(CN)CH3 + NaBr
reac on 2 CH3CHBrCH3 + NAL → CH3 CHICH3 + NaBr
What factor will explain this result?
A. the C____l bond is a stronger bond than the B. The C_____N bond is a stronger bond then
C___B bond the C___I bond
✓ C. the cyanide ion is a stronger nucleophile D. the cyanide ion is a weaker nucleophile than
than the iodide ion the iodide ion
Q.144 Complete combus on of alkane yields
A. CO2+ H2O B. CO2+ heat
C. CO + H2O heat ✓ D. CO2+ H2O + heat
Q.145 Maximum number of carbon atoms are present in
_______________________________________________________________________________________
A. Toluene B. Mesithlene
✓ C. Naphthalene D. Xylene
Q.146 Compound that has lowest Boiling point
A. n.hexane B. 2-methlpentane
C. 3-methyl pentane ✓ D. 2,2-dimethyl butane
Q.147 The unreac vity of alkanes is based upon
A. Inertness of sigma-bond B. Non-polarity of the bonds
✓ C. Both A and B D. None of above
Q.148 Diphenyl methane has benzene rings:
A. One B. Two
C. Two condensed rings ✓ D. Two isolated rings
Q.149 The catalyst used for Friedel Cra reac on is
A. FeX3 B. AlCl3
C. FeCl3 ✓ D. Anhydrous AlCl3
Q.150 Which of the following best explains the role of H2SO4
A. removing the water produced ✓ B. protona ng HNO3
C. ac ng as a solvent D. forming an unstable complex
Q.151 Mustard gas is a
A. Gas ✓ B. High boiling liquid
C. High mel ng liquid D. Steam
Q.152 When phenyl group itself is subs tuted it is called group:
A. Ph B. C 6H 5
✓ C. Ar D. A&B
Q.153 Aroma c compounds burn with sooty flame cause:
A. They have high percentage of hydrogen B. They have a ring structure
✓ C. They have a high percentage of carbon D. They resist reac on with air
Q.154 When alkyl halides are heated with aqueous solu on of ammonia at about 100°C amines are formed this is known as:
A. Willamson's synthesis ✓ B. Hoffmans reac on
C. Wurtz reac on D. Clemnsen reac on
Q.155 Which of the following is not an electrophi c subs tu on reac on of benzene
A. nitra on B. sulphona on
✓ C. Fridel-Cra alkyla on D. free radical chlorina on of benzene
Q.156 Cyclohexane can be converted not benzene in the presence of
A. Pt at 100° C ✓ B. Pt at 250° C
C. Pd at room temperature D. Pt at room temperature
Q.157 Which of the following haloalkanes is most reac ve:
A. 1-Chloropropane B. 2-Chloropropane
✓ C. 1-Brompropane D. 2-Brompropane
Q.158 the heat of hydrogena on of cyclohexene is (in kj/mol)
✓ A. -119.5 B. -231.5
C. -358.5 D. -208
Q.159 Aroma c hydrocarbon are the deriva ves of
A. Normal series of paraffin B. Alkene
✓ C. Benzene D. Cyclohexane
Q.160 The compound not giving white precipitate with Tollen's reagent
A. 1-butyne B. Ethyne
✓ C. 2-pentyne D. 1-pentyne
Q.161 Phenyl group is symbolized as :
A. Ph B. C6H5
C. Ar ✓ D. R
_______________________________________________________________________________________
Q.162 Which one of the following is meta direc ng group
A. Halo group B. Alkyl group
C. Phenyl group ✓ D. Keto group
Q.163 Hydrogena on of alkenes/alkynes in the presence of Ni as catalyst at 300°C , it polymerizes to
✓ C. benzene D. none of these
Q.164 Which is the correct priority series:
✓ A. -COOH, -CN, -CHO, -COCH3, -OH B. -CN, -CHO, -COCH3,-OH, COOH
C. -CHO, -COCH3,-OH,-COOH,-CN D. -COCH3,-OH,-COOH,-CN,-CHO
Q.165 Which can behave as an electrophilic reagent?
✓ A. Br2 B. Na
C. Nh3 D. CN-
Q.166 Wurtz reac on involves the interac on of alkyl halides in dry ether with
✓ A. Sodium B. Copper
C. Zinc D. Pla num
Q.167 Synthe c rubber is made by polymeriza on of
A. chloroform B. acetylene
C. divinylacetylene ✓ D. butene
Q.168 The IUPAC name of the compound having the formula (CH3)3 C - CH = CH2 is
A. 1, 1-Dimethyl -3-butene B. 1,1,1-Trimethyl-3-propene
✓ C. 3,3,-Dimethyl-1-butene D. 3,3,3-Trimethyl-1-propene
Q.169 When benzene is nitrated, conc. HNO3and conc. H2SO4react form an intermediate which a acks the benzene
ring.Which one of the following represents this intermediate?
A. NO+ ✓ B. NO2+
C. NO2- D. NO2
Q.170 If the structure of benzene is an open chain then it must have
A. 2-pi bonds ✓ B. 3-pi bonds
C. 4-pi bonds D. No pi bonds
Q.171 Which is property of benzene?
✓ A. Decolourize KMnO4 B. Straight chain structure
C. Only double bond is present D. Triple and double bond
Q.172 Which compound was recognized the parent member of aroma c compounds
A. Aniline B. Phenol
✓ C. Benzene D. Toluene
Q.173 Zn + HCl are used in
✓ A. Clemenson reduc on B. Wof kishner reduc on
C. Kolb's electrolysis D. Wutruz reac on
Q.174 Ethyl hydrogen sulphate on hydrolysis with boiling water is converted to
A. methyl alcohol B. propyl alcohol
✓ C. ethyl alcohol D. ethylene
Q.175 Benzene is stuble than ethane because it has
A. Cyclic structure B. More sigma bonds
C. More π bonds ✓ D. Delocalized π electrons
Q.176 On hydrogena on of benzene the heat liberates
A. 358 kj/mol ✓ B. 208 kj/mol
C. 272 kj/mol D. 320 kl/mol
Q.177 A six membered ring containing one double bond called
✓ A. Cyclohexene B. Cyclohexane
C. Cyclohexadiene D. None
Q.178 Kekule structure contributed toward actual structure of benzene:
_______________________________________________________________________________________
A. 60% B. 70%
✓ C. 80% D. 90%
Q.179 Which is the most priority group among follows?
✓ A. -----COOH B. ----CN
C. -----CHO D. ----COCH3
Q.180 C - C bond distance in the benzene is
✓ A. 1.392°A B. 1.345°A
C. 1.54°A D. 1.44°A
Q.181 The hydrocarbon which is used as an illumina ng agent
✓ A. Methane B. Methene
C. Methyne D. B%B
Q.182 Which of the following group is meta direc ng?
A. Cl ✓ B. NO2
C. OH D. CH3
Q.183 Polycycic aroma c hydrocarbons have benzene rings:
A. One B. Two
C. Two condensed rings ✓ D. More than one rings
Q.184 Ozonolysis of benzene gives:
A. Nitra on B. Sulphona on
C. Ozonide ✓ D. Glyoxal
Q.185 German chemist Kekule solved the problem of benzene structure in:
A. 1855 ✓ B. 1865
C. 1875 D. 1885
Q.186 The simplest and the parent members of aroma c hydrocarbon is
C. Biphenyis D. Naphthalene
Q.187 Biphenyl has benzene rings:
A. One B. Two
C. Two Condensed rings ✓ D. Two isolated rings
Q.188 The calculated chart of hydrogena on of 1,3,5 hexatriene is (kj/mol):
A. -119.5 B. -231.5
C. -358.5 ✓ D. -208
Q.189 10 cm3of
an alkane is burned in 70 cm3of
oxygen (an excess), the final gaseous mixture contains 30 cm3of CO2and 20
cm3of unreacted oxygen. All gaseous volumes were measured under iden cal condi ons what is the formula of the
hydrocarbon
A. C 2H 6 ✓ B. C 3H 8
C. C4H10 D. C5H12
Q.190 The elimina on of HX from adjacent carbon atoms is called
A. halogena ons B. hydrohalogena on
✓ C. dehydrohalogena on D. hydra on
Q.191 Use of the Date Booklet is relevant to this ques on.
in which reac on is the rela ve molecular mass of the organic product the largest?
A. bromoethane + aqueous sodium hydroxide B. bromoethane + alcoholic sodium hydroxide
✓ C. ethane + bromine D. ethanol + phosphorus pentachloride
Q.192 System of naming benzene and its deriva ves depends upon subs tuents:
A. Posi on B. Number
C. Direc on ✓ D. Posi on and number
Q.193 Alkanes are generally not reac ve towards acids, alkalis, oxidising or reducing agents they however undergo some
reac on, which one is the reac on undergone by alkanes
A. elimina on B. addi on
✓ C. free radical subs tu on D. nucleophilic substa on
_______________________________________________________________________________________
Q.194 Calculated heat of hydrogena on of benzene is

A. 119.5 Kj/mole ✓ B. 358.5 KJ/mole
C. 208 KJ/mole D. 153.5 KJ/mole
Q.195 De halogena on of tetrahalides happens in the presence of ac ve metal like
✓ A. Zn B. Mg
C. Both a and b D. None of them
Q.196 β-β'-dichloroethyl sulphide is commonly known as
✓ A. mustard gas B. laughing gas
C. phosgene gas D. bio-gas
Q.197 The method involved for electrolysis of Na or K salts of carboxylic acids
A. Saba er's sendrens reac ons ✓ B. Kolbe's method
C. Clemmensen D. Wolf kishner reduc on
Q.198 Alkyl halides no treatment with metallic Na give:
✓ C. alkanes D. alcohols
Q.199 In benzene the longest bond length is expected for the bond which is formed by the overlapping of
✓ A. P-P orbital B. SP2-SP2orbital
C. SP2 -S orbital D. Cannot be predicted
Q.200 The heat of hydrogena on of 1,3 cyclohexadiene is (kj/mol)
A. -119.5 ✓ B. -231.5
C. -358.5 D. -208
Q.201 The general formula of alkane is
✓ A. CnH2n+2 B. CnHn
C. CnH2n D. CnH2n-1
Q.202 Which of the following method is most appropriate for the manufacture of methane?
A. By reduc on of CH2CL2 B. Wurtz reac on
✓ C. Liquifica on of natural gas D. None of these
Q.203 The nature of - COOH group is
✓ A. meta direc ng B. ortho direc ng
C. para direc ng D. ortho and meta direc ng
Q.204 Number of isomeric forms of hexane is
A. 3 B. 4
✓ C. 5 D. 6
Q.205 The difference between amount of heat actually released and that of calculated is called
A. Bonding energy B. Ac va on energy
✓ C. Resonance energy D. Transi on energy
Q.206 The saturated hydrocarbons usually end with suffix __________
✓ A. Ane B. Ene
C. Yne D. Oic
Q.207 Which terms was drived from "aroma"?
A. Atom B. Hydrocarbons
✓ C. Aroma c D. Alipha c
Q.208 The order of reac vity of halogen acids towards alkenes
✓ A. HCI > HBr > HI B. HBr > HCI > HI
C. HCI > HBr D. HI > HBr > HCI
Q.209 Benzene is simplest member of:
✓ A. Aroma c Hydrocarbons B. Alipha c Hydrocarbons
C. Organic compounds D. Inorganic compounds
Q.210 Aroma city of benzene ring is due to
A. presence of sigma bond ✓ B. Delocaliza on of pi electrons
_______________________________________________________________________________________
C. Ring structure D. Three double bond
Q.211 Alkyl halides are used for the prepara on of:
A. Alkanes B. Alcohols
C. Alkenes ✓ D. All of these
Q.212 Subs tuents not in priority order is named:
✓ A. Alphabe cally B. From high atomic number
C. From least atomic number D. From high molecular mass
Q.213 The carbon, carbon bond length in benzene is
A. 1.54A° B. 1.34A°
C. 1.20°A ✓ D. 1.39A°
Q.214 The most reac ve compound is
A. Benzene ✓ B. Ethene
C. Ethane D. Ethyne
Q.215 The correct order of reac vity of halogens with alkanes is
A. I1> Br2> Cl2> F2 B. I2> Cl2> F2> Br2
C. F2> Cl2> I2> Br2 ✓ D. F2> Cl2> Br2> I2
Q.216 Write the name of following compound
✓ A. 5 - methyle - 2- hexene B. 2 - methyle hexene
C. 4 - ethyle - 2 - methyle hexene
Q.217 Benzene is prepared from n- hexane in the presence of catalyst
A. Cr2O3 B. AI2O3
C. SiO2 ✓ D. All above
Q.218 Naphthalene has benzene rings:
A. One B. Two
✓ C. Two condensed rings D. Two isolated rings
Q.219 SN2 reac on ca be best carried out with:
✓ A. primary alkyl halides B. secondary alkyl halides
C. ter ary alkyl halides D. all the three
Q.220 Subs tu on of halogens in the benzene ring requires catalyst
A. AICI3 ✓ B. FeCI3
C. SiO2 D. Organo - nickel
Q.221 Oxida on of benzene occurs in the presence of catalyst:
✓ A. V 2O 5 B. Ni
C. Al2O3 D. FeCl3
Q.222 Bond length in benzene between C-C is:
A. 1.54°A B. 1.34°A
C. 1.44°A ✓ D. 1.39°A
Q.223 Hoffmann discovered benzene is coal tar in:
A. 1800 B. 1805
C. 1810 ✓ D. 1825
Q.224 Hydrolysis of benzene sulphuric acid with super heated steam or by boiling with dil.HCi gives
A. Toluene ✓ B. Benzene
C. Xylene D. Chlorobenzene
Q.225 Which is more soluble in water
A. CH3OH ✓ B. C2H5OH
C. Propanol D. Butanol
Q.226 Molecular mass of benzene was determined by,,,,,,,,
A. X-ray diffrac on B. Elemental analysis
C. Combus on analysis ✓ D. Vapour density method
Q.227 Bromina on of ethene involves
_______________________________________________________________________________________
A. Electrophilic addi on B. Proceed through halogenonium ion
C. Trans addi on ✓ D. All of these
Q.228 CnH2n is the general formula of
A. Alkanes ✓ B. Alkenes
C. Alkynes D. None of above
Q.229 During the electrolysis of aqueous sodium accetate gas evolved at a node is
A. CO2 B. C 2H 6
C. H2 ✓ D. Both a and b
Q.230 Benzene is insoluble in
✓ A. water B. alcohol
C. petrol D. ether
Q.231 Which type of reac on is Friedel cra reac on?
A. addi on ✓ B. subs tuion
C. reduc on D. oxida on
Q.232 Hydrogena on is not given by
A. Mustard oil B. Isobutylene
C. Acetylamide ✓ D. Mustard gas
Q.233 Sulphuric acid generates nitronium ion by reac ng with
✓ A. Nitric acid B. Nitrogen acid
C. Nitrous acid D. Potassium nitrate
Q.234 The C-C bond angles in benzene ring are
A. 119° ✓ B. 120°
C. 121° D. None
Q.235 The other name of Benzophenone is
A. Biphenyl B. Dimethyl ketone
✓ C. Diphenyl D. Methyl phenyl ketone
Q.236 The addi on of unsymmetrical reagent to an unsymmetrical alkene is in accordance with the rule
A. Hund's rule ✓ B. Markownifov's rule
C. Pauli's exclusion principle D. Auf bau principle
Q.237 De halogena on of tetra halide happens in the presence of ac ve metal like
A. Mg B. Ni
C. Zn ✓ D. All of them
Q.238 The total coal resources of Pakistan are es mated to be
✓ A. 184 billion B. 184 million tones
C. 1.84 billion tounces (d) 1.84 million tonnes D. 183 billion
Q.239 The boiling point of branched hydrocarbons are ______ than the their normal chain isomer
A. Higher ✓ B. Lower
C. Same D. Moderate
Q.240 Ethylene polymerizes at 100 atm pressure and 400°C to give
A. polybenzene B. polyalcohol
C. polypropylene ✓ D. polyethylene
Q.241 The reac on of alcohol with SOCI2 presence of pyridine as catalyst gives:
A. acids B. acid chloride
✓ C. alky halide D. benzene
Q.242 Alkanes are soluble in all except
A. Benzene B. Ether
✓ C. Water D. Carbon tetra chloride
Q.243 If we remove one hydrogen atom from an alkane we obtain a group called
A. Acetyl group B. Formyle group
✓ C. Alkyle group D. Ketyle group
_______________________________________________________________________________________
Q.244 For sulphona on of benzene with SO3the temperature is 0°C
A. 50 B. 80
✓ C. 25 D. 100
Q.245 Polymeriza on of ethane take place at pressure of 100 atm and a temperature of
A. 200°C ✓ B. 400°C
C. 600°C D. 800°C
Q.246 The alkynides are used for the ______of alkynes
A. Pxpera on B. Purifica on
C. Sepera on ✓ D. All of above
Q.247 Vinyl acetylene combines with HCI to form
A. Poly acetylene B. Chloro benzene
✓ C. Chloroprene D. Neoprene
Q.248 The major reac on occurring in the engines of automobiles is
✓ C. Combus on D. Decomposi on
Q.249 Ethyl alcohol is obtained when ethyl chloride is boiled with:
A. Water B. Alcoholic KOH
✓ C. Aqueous KOH D. H2SO4
Q.250 Benzene can not undergo:
A. Subs tu on reac ons B. Addi on reac ons
✓ C. Elimina on reac ons D. Oxida on reac ons
Q.251 Study of aroma c hydrocarbons starts with study of:
C. Anline D. Phenol
Q.252 Bond angel in benzene is:
A. 109.5° B. 180°
✓ C. 120° D. 107.2°
Q.253 The empirical formula of benzene is determined by
A. IR spectra B. U.V
✓ C. Elemental analysis D. NMR spectra
Q.254 When n-hexane is heated in the presence of Pt at 500° C, it cyclists to give
A. benzene ✓ B. cyclohexene
C. benzene D. dehydrogenta on
Q.255 Kolb's method is not useful for the produc on of
✓ A. Methane B. Ethane
Q.256 Reac on which can be used to prepare methane
A. Kolbs electrilysis ✓ B. Decarboxyla on
C. Wurtz Synthesis D. All of these
Q.257 The geometry of acetylene is
A. angular B. bent
C. trigonal ✓ D. linear
Q.258 Amongst the following the compound that can be most readily sulphonated is
A. toluene B. benzene
C. nitrobenzene ✓ D. chlorobenzene
Q.259 Benzene can be obtained by hea ng either benzoic acid with X or phenol with Y. X and Y are respec vely
A. Zinc dust and soda lime ✓ B. Soda lime and zinc dust
C. Zinc dust and sodium hydroxide D. Soda lime and copper
Q.260 Which species represents the electrophile iroma c nitrotaion?
A. NO-2 ✓ B. +
NO2
_______________________________________________________________________________________
C. NO2 D. NO-3
Q.261 The three alternate single and double bonds in the benzene ring are called
A. Conjugate bonds B. Resona ng bonds
✓ C. Both A and B D. None of the above
Q.262 Which of the following decolorizes Br2-water?
✓ C. ethene D. propane
Q.263 The ra on ofσandπbond in the benzene is
✓ A. 4:1 B. 8:3
C. 6:1 D. 2:1
Q.264 Ethyl bromide reacts with lead-sodium alloy to from:
✓ A. Tetraethyl lead B. Both A and B
C. Tetraethyl lead bromide D. None of the above
Q.265 The order of dehydra on of alcohol
A. Sec > pri > ter B. Pri > sec > ter
✓ C. Ter > sec > pri D. None of then
Q.266 Aroma c of higher molecular mass are degraded and generated basic fundamental unit of molecule of:
C. Anline D. Biphenyl
Q.267 Benzene is soluble in
A. alcohol B. petrol
C. ether ✓ D. all of the above
Q.268 Which of the following is a polycyclic hydrocarbon
✓ A. Biphenyl B. Phenolphthalene
C. Naphthol D. None
Q.269 Physical proper es of alkanes increase with increase of all physical constants except
A. Boiling points B. Mel ng points
C. Density ✓ D. Solubility
Q.270 The addi on of HBr is easiest with
A. CH2 = CHCI B. CICH = CHCI
C. CH3 - CH = CH2 ✓ D. (CH3)2 C = CH2
Q.271 Alkyl halide are considered to be very reac ve compound towards nucleophiles because:
A. they gave an electrophilic carbon B. they have an alectrophilic carbon and good
leaving group
✓ C. they have an electrophilic carbon and had D. they have a nucleophilic carbon and good
leaving group leaving group *
Q.272 Which one of the following statements is wrong:
A. Lower alkyl halides are either colourless gases ✓ B. Alkyl halides are very soluble in water
or vola le liquids C. Alkyl halides burn easily with green edged
flame
D. All of these
Q.273 Which of the following will not give subs tu on reac on
C. Alkyne D. Both b and c
Q.274 Incomplete oxida on of alkanes yields
A. CO2& carbon black B. CO2+ heat
✓ C. CO and carbon black D. CO + Heat
Q.275 Vicinal dihalides with zinc dust gives
C. Alkyne D. All of them
Q.276 Acyla on of benzene to product alipha c aroma c ketones is known as:
A. Friedel Cra 's reac on B. Benzene condensa on
_______________________________________________________________________________________
C. Hydroforyla on ✓ D. Clemmensen reduc on
Q.277 In a primary alky halide the halogen atom is a ached to a carbon which is further a ached to:
A. only one carbon atom B. two carbon atoms
C. three carbon atoms ✓ D. one or no carbon atom
Q.278 Which is too fast to control of alkyla on.?
A. Fluorina on B. chlorina on
C. Bromina on ✓ D. Chlorina on and bromina on
Q.279 Wurtz fi ng reac on is used to prepare
A. Benzene ✓ B. Alkylbenzene
C. Acylbenzene D. Halobenzene
Q.280 Acetylene is used in the manufacture of
A. rubber B. plas c
C. ethyl alcohols ✓ D. all of these
Q.281 The next homologue of C10H22will be
A. C9H20 B. C12H26
✓ C. C11H24 D. C13H28
Q.282 Benzene is obtained by frac onal dis lla on of
A. Heavy oil B. anthracene oil
✓ C. Middle oil D. Light oil
Q.283 Hydrocarbon which is liquid at room temperature is:
✓ A. Pentane B. Butane
C. Propane D. Ethane
Q.284 Which is a free radical
A. CH4 B. CO2
C. CH2COO ✓ D. CH3
Q.285 Which of the following acid can be used as a catalyst in Friedel Cra 's reac ons:
✓ A. AlCl3 B. HNO3
C. BeCl2 D. NaCl
Q.286 The rate of E1 reac on depends upon:
✓ A. the concentra on of substrate B. the concentra on of nucleophile
C. the concentra on of substrate as well as D. none of above
nucleophile
Q.287 The benzene molecule contains
A. three double bonds B. two double bonds
C. one double bond ✓ D. delocalized pie-electron charge
Q.288 Hydrocarbons are divided into alopha c, alicyclic and aroma c which structure among the following show an alicylic
hydrocarbon
A. B.
✓
C. D.
Q.289 Ethylene can be prepared in the laboratory by hea ng together ethyl alcohol and
A. HCl B. phenol
C. HF ✓ D. H2SO4
Q.290 A nucleophile must have overall
A. Rich system electron ✓ B. Lone pair of electron
C. Nega ve charge D. All of them
Q.291 Actual structure if benzene is resonance hybrid of other structures
A. 02 B. 03
C. 04 ✓ D. 05
Q.292 Which molecule is planner
_______________________________________________________________________________________
A. Diethyl ether B. Ethyl alcohol
✓ C. Benzene D. Toluene
Q.293 Which gas is used for welding purposes?
A. butane B. nitrogen
Q.294 To differen ate isomers we use
A. n- B. iso-
C. neo ✓ D. All of them
Q.295 Structure of benzene is:
A. Planar B. Regular coplanar
C. Hexagonal ✓ D. Planar hexagonal
Q.296 Benzene gives reac ons generally:
A. Electrophilic subs tu on B. Addi on
C. Synthesis ✓ D. Addi on and electrophilic subs tu on
Q.297 The substance having garlic like odour is
✓ A. Acetylene B. Ethylene
C. Formic acid D. Methanol
Q.298 1-bromopropane on hea ng with aqueous KOH produce
A. Propene B. Propane+ H2O
C. 1-Propanol+H2O ✓ D. None of these
Q.299 The electron density is present ______ of the benzene ring
A. Side wise B. Above
C. Below ✓ D. Both b and c
Q.300 In which of the following compound benzene rings are isolated
A. Napthene B. Cumene
C. a-naphthol ✓ D. Biphenyl
Q.301 Which term describes the ac on of NaOH(aq) on a bromoalkane?
A. acid-base reac on B. electrophilic subs tu on
✓ C. elimina on of HBr D. nucleophilic subs tu on
Q.302 All C-H bond lengths of benzene ring is
A. 1.07 A° ✓ B. 1.09 A°
C. 1.08 A° D. None
Q.303 Subs tu on of hydrogen with chlorine during the chlorina on is an example of subs tu on
✓ A. Electrophilic B. Nucleophilic
C. Free radical D. None
Q.304 Which compound is the most reac ve one
A. benzene ✓ B. ethene
C. ethane D. ethyne
Q.305 When 1 mole of Methane is burn completely, the energy release is
A. 981 KJ ✓ B. 891 KJ
C. 150 KJ D. 350 KJ
Q.306 Which of the following substances is used as an an knock compound?
✓ A. Tetraethyl lead B. Lead tetrachloride
C. Lead acetate D. Ethyl acetate
Q.307 Which of the following is a benzyl group
A. C6H5- ✓ B. C6H5-CH2-
C. C6H5-CH1
Q.308 Which group has least priority?
A. ---COOH B. ---CN
C. ---NH2 ✓ D. ----R
_______________________________________________________________________________________
Q.309 Nephthalene has two fused aroma c ring of carbon atom the molecular formula is
✓ A. C10H8 B. C10H10
C. C10H14 D. C12H12
Q.310 Most common reac ons of benzene and its deriva ves are
A. Electrophilic addi on reac ons ✓ B. Electrophilic subs tu on reac ons
C. Nucleophilic addi on reac ons D. Nucleophilic subs tu on reac ons.
Q.311 Which compounds would not be formed in the reac on of ethene with aqueous bromine in the presence of sodium
chloride
A. CH2CICH2Br B. CH2BrCH2Br
C. CH2OHCH2Br ✓ D. CH2OHCH2Cl
Q.312 Solvent which is used during the hydrogena on of benzene is
A. Neutral solvent ✓ B. Acidic
C. Basic D. Vola le
Q.313 Which terms was derived from atomos?
✓ A. Atom B. Hydrocarbons
C. Aroma c D. Alipha c
Q.314 Alkynes are colourless & odourless except
✓ A. Acetylene B. Propyne
C. Butyne D. Pentyne
Q.315 When an aqueous of potassium salt of monocarboxylic acid is subjected to electrolysis, corresponding alkane is
formed. This reac on is known as
A. Cannizaro reac on B. Saba er-senderens reac on
C. alkyla on ✓ D. Kolbe's reac on
Q.316 The compd. used to dis nguish the ethyne and ethane is
A. Alkaline KMnO4 ✓ B. Ammonical AgNO3
C. Bromine water D. Both a and b
Q.317 Toluene can be converted into benzoic acid by
A. Dil.NaOH ✓ B. Acidicfied KmnO4
C. dil.HCI D. Alkaline KMnO4
Q.318 Mustard gas is
A. Gaseous substance ✓ B. Liquid
C. Solid D. None
Q.319 How many isomeric disubs tuted products are obtained by the introduc on of second group in the ring
A. Two ✓ B. Three
C. Four D. None
Q.320 Which substances do not react immediately with bromine water?
A. phenol B. benzene
✓ C. ethane D. ethene
Q.321 Which of the following may be waxy solid odorurless & colorless
A. Decane B. Isopentane
C. Butane ✓ D. None of these
Q.322 alkyla on of benzene gives:
A. benzene sulphonic acid B. nitrobenzene
✓ C. maleic anhydride D. bebziogebibe
Q.323
_______________________________________________________________________________________
A. B.
✓
C. D.
Q.324 How many oxygen atoms are added to benzene during ozonolys is
A. 03 B. 06
✓ C. 09 D. 12
Q.325 What is not a common use of methane
A. as a fuel B. for the prepara on of haloalkanes
C. for the prepara on of methyl alcohol ✓ D. for the prepara on of sulphuric acid
Q.326 Which one of the following reac ons is not given by formaldehyde?
A. reac on of Fehling solu on ✓ B. iodoform reac on
C. recuc on of Tollen's solu on D. Phenol complexes
Q.327 The no of isomers of tribromobenzene are
A. 1 B. 2
✓ C. 3 D. 4
Q.328 The process in which orbitals of different energies and shapes mix with each other to give equivalent orbitals is called
A. isomeriza on B. polymeriza on
✓ C. hybridiza on D. resonance
Q.329 Which of the following is not a electrophile
✓ A. Ammonia B. Boron triflouride
C. Aluminum chloride D. Zinc chloride
Q.330 Prepara on of vegetable ghee involves
A. halogena ons ✓ B. hydrogentaion
C. hydroxyla on D. dehydrogena on
Q.331 Which one of the following belongs to meta direc ng groups?
A. Halogens B. alkyl group
✓ C. phenyl group D. no such group exists
Q.332 Which class of compound is more reac ve
C. Alkyne D. None
Q.333 Benzene reacts with n-propyl chloride in presence of anhydrous AICI3, major product should be
A. Chloro benzene B. Propane
✓ C. Cumene D. N-proplybenzene
Q.334 AgC=CAg+H2SO4→Ag2SO4 + x What is x
A. Ethane B. Ethene
✓ C. Ethyne D. Propyne
Q.335 Which of the following is explosive?
✓ A. Trinitrophenol B. Nitrophenol
C. Nitromethane D. Nitrobenzene
Q.336 The benzene molecule contains:
A. Three double bond B. Two double bond
_______________________________________________________________________________________
C. One double bond ✓ D. Delocalized pai electron charge
Q.337 Benzene has a----structure
A. Pentagonal ✓ B. Hexagonal
C. Heptagonal D. Tetragonal
Q.338 Octane number is zero for
✓ A. n-Heptane B. Isooctane
C. n-Hexane D. Isoheptane
Q.339 The reac on/method that does not give an alkane is
A. Cataly c hydrogena on of alkanes B. Wurtz reac on
C. Hydrolysis of alkyl magnesium bromide ✓ D. Dehydrohalogena on of an alkyl halide.
Q.340 Nitrobenzene is treated with CI2 in the presence of FeCI3 Which product is formed
A. o-Nitrochlorobenzene ✓ B. m-Nitrochlorobenzene
C. P-Nitrochlorobenzene D. Both a and c
Q.341 Hydrazine is used in the
A. Clemmenson's reduc on ✓ B. Wolf-kishner reduc on
C. Wurtz reac on D. Sabateir's reac on
Q.342 Traichloroethanoic acid, CCI3CO2H,is used in cosme c surgery to perform a chemical peel to remove dead skin.
Trichloroethanoic acid can be made by reac on chlorine with ethanoic acid.What is the mechanism of this reac on?
A. electroppilic additon B. electrophilic subs tu on
C. free radical addi on ✓ D. free radical subs tu on
Q.343 Which of the following will not react with Alcoholic KOH
A. 1.Chloropropane B. 2-Chlorppropane
✓ C. 2-Chloto-2-methyl propane D. None of these
Q.344 The addi on of unsymmetrical reagent to and unsymmetrical alkene is in accordance with
A. Hund's rule ✓ B. Markownikov's rule
C. Pauli's Exclusion principle D. Auf ban principle
Q.345 Which reac on sequence would be best to prepare 3-chloro-aniline from benzene?
A. Chlorina on,nitra on,reduc on ✓ B. Nitra on,chlorina on,reduc on
C. Nitra on,reduc on,chlorina on D. Nitra on,reduc on, acyla on chlorina on,
hydrolysis.
Q.346 Benzene cannot undergo reac on
A. Addi on B. Subs tu on
C. Oxida on ✓ D. Elimina on
Q.347 Alkanes may be prepared by the reac on of alkylhalides with:
✓ A. alcohol B. alkenes
C. ketones D. ethers
Q.348 C18and onwards hydrocarbons are normally
A. Gases B. Liquids
C. Solids ✓ D. Plasma
Q.349 Which reac on is too vigorous to control
A. Chlorina on B. Bromina on
C. Iodina on ✓ D. Fluorina on
Q.350 Methane reacts with steam at 900 C° in the presence of Ni catalyst to form
A. CH3OH ✓ B. (CO+H2)
C. CO2+H2O D. None of these
Q.351 Which of the following is not an ortho & Para direc ng group
A. -N(CH3)2 B. -NH2
C. -OCH3 ✓ D. None of them
Q.352 In Friedel-Cra 's alkyla on besides AICI3 the other reactants are
A. C6H6 + NH3 B. C6H6 + CH4
✓ C. C6H6 + CH3CI D. C6H6 + CH3COCI
_______________________________________________________________________________________
Q.353 Alkyl benzenes are readily oxidized by acidified
✓ A. KMnO4 B. K2CO3
C. MnO4 D. H2SO4
Q.354 Which of the following reac on is characteris c of benzene
✓ A. electrophilic subs tu on reac on B. reduc on
C. oxida on D. ozonolysis
Q.355 Which is formed when C2H2 is passed through Cutbe at C°
A. Butyne B. Vinyl acetylene
✓ C. Benzene D. Polythene
Q.356 Benzene is more stable than hypothe cal compound 1,3,5-Cyclohexatriene by
A. 119.5 KJ/mole B. 208 KJ/mole
✓ C. 150.5 KJ/mole D. 238 kj/mole
Q.357 The stability of aroma c compounds decreases with ---in the no,of its resonance structure
✓ A. Decrease B. Increase
C. Remain constant D. Par ally decreases
Q.358 Carboca on is formed as a result of
A. Hemoly c fission ✓ B. heteroly c fission
Q.359 Which of the following is not aroma c hydrocarbon
A. benzene B. naphthalene
C. toluene ✓ D. cyclohexene
Q.360 Benzene is obtained from benzene sulphonic acid by trea ng with
A. HCI B. NaOH
✓ C. H 2O D. NaHCO3
Q.361 Ra o of carbon to hydrogen in aroma c compound is:
✓ A. Low than alkanes B. High than alkanes
C. Low than alkenes nit high than alkanes D.
High than alkenes
Q.362 Which of the following is most reac ve
C. Akyne D. Benzene
Q.363 An alkane is produced when an alkyle halide reacts with zinc in the presence of
A. HCI B. CH3COOH
✓ C. Both a & b D. None
Q.364 Which alkane on chlorina on produces only one isomer of monochloro alkane
A. n-pentane B. n-hexane
C. 2-methyl butane ✓ D. Neopentane
Q.365 Mono-subs tuted benzene deriva ves are named by wri ng benzene as:
A. Prefix ✓ B. Suffix
C. Main item D. Both prefix and suffix
Q.366 In which one of the following compound rings are not fused together at ortho posi ons
A. Phenanthrene B. Naphthalene
✓ C. Diphenymethane D. Anthracene
Q.367 The order of the reac vity of an alkyl halide (R-x) for par cular alkyl group is:
✓ A. iodide > bromide > chloride B. chloride > bromide > lodide
C. bromide > chloride > chloride D. bromide > iodide > chloride
Q.368 Dehydrohalogena on of alkyl halides gives:
A. alkanes ✓ B. alkenes
C. alkynes D. aldehyde
Q.369 Alkyl healide can be prepared by trea ng halogen acids with:
A. ethane B. ethene
_______________________________________________________________________________________
✓ C. ethanol D. ehtene and ehanol
Q.370 During nitra on of benzene, the ac ve nitra ng agent is
✓ A. NO+2 B. NO+
-
C. NO D. HNO3
Q.371 The reac on of alcohol with SOCl2 in the presence of pyridine as catalyst gives:
A. acids B. acids
✓ C. alkyl halide D. benzene
Q.372 Alkyl deriva ves of benzene can be prepared by
A. Fridal cra reac on B. Aroma zaion
C. Warts fi ng reac on ✓ D. All of these
Q.373 Write the name of following alkene CH2 = CH - CH = CH2
A. 1,3 butadiene B. Buta - 1,3-diene
✓ C. Both a & b D. None
Q.374 Prepara on of ethylbenzene by the reac on of bromobenzene, ethylbromide and sodium is called
A. Wurtz reac on B. Fi ng reac on
✓ C. Wurtz Fi g reac on D. none of these
Q.375 The compound prepared by a subs tu on reac on of benzene is
✓ A. Acetophenone B. Glyoxal
C. Cyclohexane D. Hexabromo cyclohexane
Q.376 Benzene molecule contains
A. 4πand 9σbond B. 6πand 12σbond
C. 6πand 6σbond ✓ D. 3πand 12σbond
Q.377 During the nitra on of benzene the nitra ng agen s
A. NO3 ✓ B. NO2+
C. NO-2 D. HNO3
Q.378 Use of the bate booklet is relevant to this ques on.
In which reac on is the rela ve molecular mass of he organic product the largest?
A. bromoethane + aqueous sodium hydroxide B. bromoethane + alcoholic sodium hydroxide
✓ C. ethane + bromine D. ethanol + phosphorus pentachloride
Q.379 The electrophile in aroma c sulphona on is
A. H2SO4 B. HSO4-
✓ C. SO3 D. SO+3
Q.380 Benzene reacts with Cl2in sunlight to give the end product:
A. C6H6Cl6 ✓ B. C6H6Cl
C. O-C6H4Cl2 D. P-C6H4Cl2
Q.381 The nomenclature of aroma c hydrocarbons is then alipha c hydrocarbons:
A. Simple B. Easy
✓ C. Complex D. Simplest
Q.382 Which one of the following gases is used for ar ficial ripening of fruits?
A. ethene ✓ B. ethane
C. methane D. propane
Q.383 Second subs tuent in benzene gives isomeric products:
A. One B. Two
Q.384 Kolb's method of alkanes produc on is actually
A. Hydrolysis B. Catalysis
✓ C. Electrolysis D. Hydrogena on
Q.385 Kolb's method has limited synthe c applica on due to
A. Expensive catalysis B. Slow reac on
✓ C. Number of side products produced D. Salts used are very expensive
_______________________________________________________________________________________
Q.386 Exact posi on of double band in alkene is determined by
A. Br2Water B. Acidified KMnO4
✓ C. O3 D. All
Q.387 A salt producing hydrocarbon among these compounds is
✓ A. Ethyne B. Ethene
C. Methane D. Ethane
Q.388 Which pair of substances is not suitable for the direct prepara on
A. ethanol and ace c acid B. ethanol and acetyl chloride
C. ethanol and benzoic acid ✓ D. phenol and benzoic acid
Q.389 Benzene can react with ______ easily to produced subs tuted product
A. Nucleophile B. Base
C. Weak electrophile ✓ D. Strong electrophile
Q.390 x-ray studies of benzene confirm its structure as:
A. Cubic B. triangular
C. regular planner ✓ D. octahedral
Q.391 Formula of methylene chloride is
A. CH3Cl ✓ B. CH2Cl2
C. CHCl D. CCl4
Q.392 C - H bond length in the benzene is
A. 0.99A° ✓ B. 1.09A°
C. 1.12A° D. 1.34A°
Q.393 Benzene was developed by :
✓ A. Michael Faraday B. Lavoiser
C. Hoffmann D. Proust
Q.394 Number of π-elements in styrene are
A. 04 B. 06
✓ C. 08 D. 10
Q.395 Alkyl halides when reduced with nascent hydrogen in the presence of Zn + HCl, are converted to
✓ C. alkanes D. alcohol
Q.396 Which of the following ions is most stable
A. CH+3 B. CH3- CH+2
C. (CH3)2 CH+ ✓ D. (CH3)3CH+
Q.397 The presence of a double bond in a compound is the sign of
A. Satura on ✓ B. Unsatura on
C. Subs tu on D. None of above
Q.398 Benzene was discovered by Micheal Faraday in the gas produced by the
A. Steam dis lla on ✓ B. Destruc ve dis lla on
C. Frac onal dis lla on D. None
Q.399 Formula of chloroform is
A. CH3CI B. CH2CI2
✓ C. CHCI3 D. CCI4
Q.400 What always applies to a nucleophile?
A. it a acks a double bond ✓ B. it has a long pair of electrons
C. it is a single atom D. it is nega vely charged
Q.401 Which of the following has only primary hydrogen
A. n-pentane B. Iso pentane
✓ C. Neo pentane D. All of them
Q.402 The benzene and its deriva ves are called:
✓ A. Aroma c hydrocarbons B. Alipha c hydrocarbons
_______________________________________________________________________________________
C. Organic compounds D. Inorganic compounds
Q.403 Chemist gave structure of benzene:
✓ A. Kekule B. Dewar
C. Thomson D. Wholar
Q.404 Reac on of bromobenzene with ethyl bromide in the presence of sodium in an insert medium like ether gives.
A. Benzene B. Toluene
C. aniline ✓ D. Ethyl benzene
Q.405 Enthalpy of combus on of CH4 is
✓ A. -891 KJ/Mole B. -119.5 KJ/mole
C. -200/mole D. -151 Kj/mole
Q.406 Decreasing order of reac vity of alkyl halide is:
A. RI > RCI > RBr ✓ B. RI > RBr > RCI
C. Rbr > RCI > RI D. RCI > RBr > RI
Q.407 The electrophila on aroma c sulphona on is:
A. H2SO4 B. HSO4-
✓ C. SO3 D. SO3+
Q.408 The electron releasing effect of methyl group is significant and it makes ring a good
A. Electrophilic ✓ B. Nucleophilic
C. Nucleophobic D. Hydrophobic
Q.409 Which of the following is not an ortho-para direc ng group
A. - NH2 B. - OH
C. - OCH3 ✓ D. - CHO
Q.410 Toluene is also called
A. Hydroxyl benzene ✓ B. Methyl benzene
C. Ethyl benzene D. None
Q.411 The compound which reacts with HBr obeying Markownikoff's rule is
A. B.
✓
C. D.
Q.412 Boiling point of alkanes increases by ______°C for each addi on of a-CH2group
A. 20 B. 40
C. 30 - 40 ✓ D. 20 - 30
Q.413 Benzoic acid can be prepared from the oxida on of:
A. Benzene B. Thyl benzene
C. Benzoic acid ✓ D. Toluene
Q.414 Raney - nickel is the alloy of Ni with
A. Pt ✓ B. AI
C. Cu D. Pd
Q.415 Chlorohydrin is produced by the reac on of ethene and
A. HCi B. HCI+H2O
✓ C. CI2+H2O D. CI2
Q.416 Aroma c hydrocarbons are the deriva ves of:
A. Normal series of paraffins B. Alkane
✓ C. Benzene D. Cyclohexane
Q.417 Compound with lowest Hydrogen to carbon ra o is
A. Alkene B. Alkane
C. Alkyne ✓ D. Benzene
Q.418 3-Methyl-1-Butane on hydrogena on with Ni at 100 C° and 3 atom pressure produces
A. n-pentane ✓ B. Iso pentane
_______________________________________________________________________________________
C. Neopentaner D. All of these
Q.419 Acetylene when treated wit 10% H2SO4in the presence of HgSO4adds one molecule of water to form
✓ A. aldehydes B. esters
C. alcohols D. acids
Q.420 The reac on of alcohol with SOCI2 in the presence of pyridine as catalyst gives:
Q.421 The method in which alkanes prepared by alkyl halides in the presence of palladium - charcoal is
A. Hydrolysis B. Electrolysis
C. Hydrogena on ✓ D. Hydrogenolysis
Q.422 Octane number can be changed by
A. Isomerisa on B. Alkyla on
C. Cyclisa on ✓ D. All of these.
Q.423 Introduc on RCO group to a compound is called
A. Dehydra on ✓ B. Acyla on
C. Caboxyla on D. Hydrogena on
Q.424 Which of the following can discharge the color of acidified KMnO4
A. Benzene ✓ B. Toluene
C. Paraffins D. None
_______________________________________________________________________________________
15 Alkyl Halides
Q.1 Each of the following compounds is effec ve as a refrigerant. The release of which one of these causes the greatest
deple on of the ozone layer
✓ A. CCl2F2 B. CH3OCH3
C. CH3CHF2 D. CH3CH2CH3
Q.2 2-Methylbuta-1,3-diene, Ch2=C(CH3)-CH=CH, is used as a monomer in the manufacture of synthe c rubbers.
Which compound would not produce this monomer on treatment with concentrated sulfuric acid at 170°C?
A. (CH3)2C(OH)CH(OH)CH3 B. HOCH2CH(CH3)CH2CH2OH
C. HOCH2CH(CH3)CH(OH)CH3 ✓ D. HOCH2C(CH3)(OH)CH2CH3
Q.3 Elimina on bi-molecular reac ons involve:
A. First order kine cs ✓ B. Second order kine cs
C. Third order kine cs D. Zero order kine cs
Q.4 The final formed by dis lling ethyl alcohol with excess of CI2 and Ca (OH)2 is
A. CH3CHO B. CCI3CHO
✓ C. CHCI3 D. (CH3)2O
Q.5 The general formula of alkyl halides is
A. CnH2nX B. CnH2n-1X
✓ C. CnH2n+1X D. CnH2n-2X
Q.6 Which enzyme is not involved in fermenta on of starch?
A. diastase B. zymase
✓ C. urease D. invertase
Q.7 SN2 reac ons are given by alkyl halides:
✓ A. Primary B. Secondary
C. ter ary D. Monohaloakane
Q.8 The compounds or species in search of electrons are called
✓ A. electrophiles B. nucleophile
C. nitri es D. bases
Q.9 Tetrahaloalkanes have halogen atoms:
A. One B. Two
Q.10 Alkanes may be prepared by the reac on of alykyhalides with
✓ A. Alcohol B. Alkenes
C. Ketones D. Ethers
Q.11 Which of the following is known as wood spirit?
✓ A. methyl alcohol B. ethyl alcohol
C. prophyl alcohol D. butyl alcohol
Q.12 Unpleasant smell of carbylamine is obtained when chloroform and alcoholic KOH are heated with
A. Any aroma c amine ✓ B. Any primary amine
C. Any amine D. Any alipha c amine
Q.13 Rec fied spirit contains alcohol about:
A. 80% B. 85%
C. 90% ✓ D. 95%
_______________________________________________________________________________________
Q.14 Which of the following does not give nucleophilic subs tu on reac on
A. CH3CH2Br + OH- B. CH3l + H2O
C. CH3CH2CH2Cl + NH3 ✓ D. C6H6+ Cl2
Q.15 The fat soluble vitamins are
A. A and B ✓ B. B and C
C. C and D D. Aand D
Q.16 Reac on of ethylamine with chloroform in alcoholic KOH produces
A. CH3OH B. CH3NC
✓ C. C2H5NC D. C2H5CN
Q.17 CFCs undergo homoly c fission by uv light in the stratosphere which radical could result from this irradia ons of
CHFCICF2Cl.
A. CHF Cl C FCl B. CH Cl CF2Cl
✓ C. CHF CF2Cl D. C FCl CF2Cl
Q.18 Glucose is a
A. Ketohexose ✓ B. Aldohexose
C. Monosacharide D. B and C
Q.19 Which one of the following reac ons is not given by formaldehyde
A. Reac on of Fehling solu on ✓ B. Iodoform reac on
C. Recuc on of Tollen's solu on D. Phenol complexes
Q.20
One radian is defined to be the angle subtended where the arc length “S” is exactly equal to the?
A. Circumference of the circle. ✓ B. Radius of the circle.

C. Diameter of the circle. D. Half of radius of the circle.
Q.21 SN2reac on has order of reac on:
✓ A. First B. Second
C. Third D. Zero
Q.22 What happens when CCI4 is treated with AgNO3 solu on?
A. NO2 will evolved B. A while ppt.of AgCI will form
C. CCI4will dissolve in AgNO3solu on ✓ D. Nothing will happen
Q.23
An alkyl halide in which halogen bearing C atom is directly linked to one more carbon atoms is called?
✓ A. Primary, 1° B. Secondary, 2°
C. Tertiary, 3° D. None of the above
Q.24 Methyl butyrate has a smell of
A. Apple ✓ B. Pine apple
C. Banana D. Winter green
Q.25 By simply reac ng Grignand's reagent with water we get
✓ A. an alkane B. higher alkane
C. an alkene D. amide
Q.26 Chloromathane reacts with x to form methyl ethyl ether what is X
A. NaOH B. H2SO4
✓ C. C2H5ONa D. Sodium metal
Q.27 Both E1and E2mechanism can be shown by
A. 10- RX ✓ B. 20- RX
C. 30- RX D. None of these
Q.28 If C2H5MBr reacts with CNCI and product is hydrolyzed in presence of Acid then final product
A. 2-Propanol ✓ B. Propanoic acid
C. Ethylnitrile D. None
Q.29 The func onal group in a primary alcohol is -CH2OH.
_______________________________________________________________________________________
Which reagent react with a primary alcohol under suitable condi ons to give an organic product with the same
number of oxygen atoms as the alcohol?
A. AI2O3 B. CH3CO2H
C. HBr ✓ D. Na
Q.30 The rate of SN1 reac on is not affected by
✓ A. Conc. of nucleophile B. Solvent used
C. Nature of leaving group D. Stability of carboca on
Q.31 The most reac ve compound for electrophilic nitra on will be
✓ A. Benzyl chloride B. Benzoic acid
C. Nitrobenzene D. Chlorobenzene
Q.32 When alkyl halides are heated with aqueous solu on of ammonia at about 100°C, amines are formed. This reac on is
known s
A. Williamson's synthesis ✓ B. Hoffmans reac on
C. Wurtz reac on D. Clemensen reac on
Q.33 Rate of E1 reac on depends upon
✓ A. Conc. of substrate B. Conc of nucleophile
Q.34 Which compound is called a universal solvent?
✓ A. H 2O B. CH3OH
C. C2H5OH D. CH3____O____CH3
Q.35 The elimina on of hydrogen halide from adjacent carbon atoms is called
A. Dehydrogena on B. Hydrogena on
✓ C. Dehydrohalogena on D. Hydrohalogena on
Q.36 Grignard reagent reacts with Propanol to form
A. P°-Alcohol ✓ B. S°-Alcohol
C. T°-Alcohol D. Carboxylic acid
Q.37 E2 reac ons are given by alkyl halides:
C. Ter ary D. Monohaloakane
Q.38 The best method to prepare alkyl halide is from:
✓ A. Alcohols B. Alkane
C. Alkene D. Alkynes
Q.39 In the cyclic structure of the glucose when the posi on of atoms on carbon 1 is called one isomer changes to other.
These isomers of glucose are called
A. Metamers B. Posi ve isomers
C. Cis-trans ✓ D. Annomers
Q.40 For which mechanism, the first step involved is the same
C. W1and E2 ✓ D. E1and SN1
Q.41 Steps in SN1reac ons are:
A. One ✓ B. Two
C. Three D. Four
Q.42 Elimina on bimolecular reac on usually obey
C. Third order kine cs D. Zero order kine cs
Q.43 the pathway through which reactants are converted to products is called:
A. Order B. Molecularity
C. Rate ✓ D. Mechanism
Q.44 Alkyl halides are prepared from:
A. Hydrogena on of alkane B. Hydrogena on of alkene
C. Hydrogena on of alkyne ✓ D. By hydrogena on of alkane and HX to
_______________________________________________________________________________________
alkanes
Q.45 Alkanes may be prepared by the reac on of alkyl halides with
A. alcohol ✓ B. carboxylic acid
C. Grignard reagents D. none of these
Q.46 Which responds to +ve iodoform test?
A. Butano1-1 B. Butan-1-a1
✓ C. Butano-2 D. 2-pentanone
Q.47 Which halide is hydrolysed faster
A. CH3CH2F B. CH3CH2Cl
C. CH3CH2Br ✓ D. CH3CH2I
Q.48 Alcohols phenois and ether may be considered as deriva ve of:
A. carboxylic acids B. hydro carbons
✓ C. water D. benzene
Q.49 Benzene reacts with chlorine to form benzene hexachloride in presence of
A. Nickel B. AICI3
✓ C. Bright sunlight D. Zinc
Q.50 The sum of coefficients of reactants in rate determining steps is called.
✓ A. Order B. Molecularity
C. rate D. Mechanism
Q.51 Which alcohol give only one oxida on product when warmed with dilute acidified potassium dichromate (VI)?
A. butan-1-ol ✓ B. butan-2-ol
C. 2-methylpropan-1-ol D. 2-methylpropan-2-ol
Q.52 The reac on of alcohol with SOCl2in the presence of pyridine as catalyst gives
A. Acids B. Acid chloride
✓ C. Alkyl halide D. Benzene
Q.53 Which of the following reagent cannot be used for preparing alkyl chloride from alcohol?
A. HCI + anhyd. ZnCI2 ✓ B. NaCI
C. PCI5 D. SOCI2
Q.54 Reduc on of alkyl halides give
✓ A. alkanes B. alkenes
C. ketones D. ether
Q.55 Gammexane is
A. Chlorobenzene B. Benzyl chloride
C. Bromobenzene ✓ D. Benzene hexachloride
Q.56 Methanol is manufactured by:
A. fermenta on B. dis lla on
✓ C. both a and b D. none of above
Q.57 If Grignard reagenet is allowed to react with another alkyl halide the main product is
✓ A. an alkane B. cyclo alkane
C. alkyne D. an alkene
Q.58 Sponifica on is the hydrolysis of fats or oils with an/a
A. Acid ✓ B. Alkali
C. Enzyme D. Metallic ion
Q.59 Primary carbon a aches with other hydrogen atoms directly:
A. One B. Two
C. Three ✓ D. At least one or more than it
Q.60 Ter ary alkyl halides are prac cally inert to subs tu on by SN2 mechanism because of
A. Insolubility B. Instability
C. Induc ve effect ✓ D. Steric hindrance
Q.61 For like carbylamine reac on we need hot alc.KOH and
_______________________________________________________________________________________
A. Any amin and chloroform B. Chloroform and Ag powder
✓ C. A primary amine and chloroform D. A mono alkyl amine and trichlorom-ethane
Q.62 Alkyl halide can be prepared by trea ng halogen acids with
A. Ethane B. Ethene
✓ C. Ethanol D. Ethene and ethanol
Q.63 The rate of SN2reac on depends upon the
A. concentra on of alkyl halides B. concentra on of nucleophile
✓ C. concentra on of alkyl halides and D. none of the above
nucleophile
Q.64 Reac on of Grignard's reagent with CO2gives:
✓ A. Aldehyde B. Pri-alcohol
C. Sec-alcohol D. Carboxylic acid
Q.65 Which of the following has highest nucleophilcity
A. F- B. OH-
✓ C. CH-3 D. NH2
Q.66 Hydrolysis of Grignard's reagent yields
A. alcohol B. aldyhyde
C. ester ✓ D. alkane
Q.67 Grignard reagent is not prepared in aqueous medium but prepared in ether medium because
A. The reagent is highly reac ve in ether B. The reagent does not react with water
C. The reagent becomes inac ve in water ✓ D. The reagent reacts with water
Q.68 When alkyl halides are heated with aqueous solu on of ammonia at about 100°C, amines are formed.This
reaction is known as
A. Williamsons synthesis ✓ B. Hoffmans reac on
C. Wurtz reac on D. Clemensen, reac on
Q.69 When phenol is reduced in the presence to zinc dust we get:
A. cyclohexane B. benzyl alcohol
✓ C. benzene D. cyclohexene
Q.70 Which one has least value of dipole moment
A. CH3F B. CH3CI
C. CH3Br ✓ D. CH3I
Q.71 Which is a good nuclophile as well as a good leaving group
A. F- B. Cl-
C. Br- ✓ D. l-
Q.72 Ethyl bromide is formed by the reac on of HBr with
A. ethane ✓ B. ethene
C. ethyne D. propane
Q.73 A nucleophile is a specie:
A. neutral radical B. posi vely changed
C. Ca on ✓ D. Both neutral as well as nega vely changed
Q.74 Which one is non-reducing sugar
✓ A. Sucrose B. Glucose
C. Fructose D. Galactose
Q.76 The order of the reac vity of an alkyl halide (R - x) for a par cular alkyl group is
✓ A. Iodide > bromide > chloride B. Chloride > bromide > Iodide
C. Bromide > chloride > chloride D. Bromide > iodide > chloride
Q.77 When ethyl magnesium bromide is made to react with acetone in presence of ether and HCI + H2O the product formed
is
_______________________________________________________________________________________
A. Ethanol B. 2-Butanol
C. 2-Methyl-1-butanol ✓ D. 2-Methyl-2-butanol
Q.78 Oxida on of secondary alcohol gives
A. Organic acid B. Ether
C. Aldehyde ✓ D. Ketone
Q.79 Which of the following compounds will form a hydrocarbon on reac on with Grignard reagent
A. a ketone B. an aldehyde
C. an ether ✓ D. water
Q.80 Which of the following with aqueous KOH will give acetaldehyde?
A. 1,2-DIchloroethane ✓ B. 1,1-Dichloroethane
C. Chloroace c acid D. Ethyl chloride
Q.81 A carbon atom carrying a posi ve charge and a ached to three other atoms or groups is called
✓ A. caronium ion B. carbanion
C. oxonium ion D. carba ion
Q.82 IUPAC name of diethy ether is
A. methoxy B. methoxy ethyne
✓ C. ethoxy ethane D. ethoxy methane
Q.83 Which is good electrophile as well as good leaving group
A. F- B. CI-
C. Br - ✓ D. I-
Q.84 Electronega vity of fluorine is:
A. 2.1 B. 2.5
C. 2.8 ✓ D. 4.0
Q.85 Which compound contains OH in their molecule:
A. ether B. ether
C. phenol ✓ D. alcohol and phenol
Q.86 Reac vity of alkyl halides with magnesium is of the order:
✓ A. Rl>BRr>RCl>RF B. BRr>RCl>RF>Rl
C. RCl>RF>Rl>RBr D. RF>Rl>RBr>RII
Q.87 Ethyl bromide on treatment with alcoholic KOH gives
✓ A. Ethylene B. Ethanol
C. Ace c acid D. Ethane
Q.88 Which of the following alkyl halide is the most reac ve towards the a acking nucleophile
A. CH3F B. CH3Cl
C. CH3Br ✓ D. CH3l
Q.89 According to Lewis concept ethers behave as
A. acid ✓ B. base
C. acid as well as a base D. none of them
Q.90 Chloroform (CHCl3) is
A. Primary alkyl halide B. Secondary alkyl halide
C. Ter ary alkyl halide ✓ D. None of these
Q.91 Diethyl ether is obtained by william son's synthesis using
A. methanol + NA + CH3Br B. methanol + Mg + CH3Br
✓ C. ethanol + Na + C2H5Br D. ethanol + Mg + C2H5H5Br
Q.92 Benzyl chloride can be prepared from Toluene chlorina on with
A. SO2CI2 B. CI2
C. SOCI2 ✓ D. Both a and b
Q.93 Names of more than are different groups or branches are wri en:
A. As given in the formula B. In molecule w.r.t. posi on
C. w.r.t. increasing atomic number ✓ D. Alphabe cally
_______________________________________________________________________________________
Q.94 SN1 reac on of alkylhalides leads to
A. Reten on of configura on ✓ B. Recemisa on
C. Inversion of configura on D. None of these
Q.95 How many hydrogen atoms in a molecule of glycerol ,HOCH2CH(OH)CH2OH
be subs tuted by deuterium on dissolving in an excess of D2O?
A. 2 ✓ B. 3
C. 5 D. 8
Q.96 Alkanes with same number of carbons as in Grignard's regent can be prepared by its reac on with:
A. Water B. HCN
C. NH3 ✓ D. All
Q.97 A subs tuent in the compound is given posi on always:
✓ A. Lowest B. First
C. Second D. Maximum
Q.98 Alkanes can be prepared from Grignard's reagent with:
A. Water B. HCN
C. NH3 ✓ D. All
Q.99 A primary alkyl halide is:
A. Ethyl chloride B. Propyl chloride
C. Methyl chloride ✓ D. 1-chlorobutane
Q.100 CI2 reacts with CS2 in presence of AICI3 to form
A. CHCI3 ✓ B. CCI4
C. C2H5CI D. C 2H 6
Q.101 Alkyl halides show reac on types:
A. SN reac ons B. E-reac on
✓ C. SN & E-reac ons D. Addi on reac on
Q.102 Which of the following is a liquid at room temperature
A. C2H5Cl B. CH3Cl
✓ C. CH2= CH = CH2Cl D. (CH3)3C-Cl
Q.103 Aryl halides are less reac ve towards nucleophilic subs tu on reac on as compared to alkyl halides due to
A. The forma on of less stable carbonium ion ✓ B. Resonance stabiliza on
C. Larger carbon-halogen bond D. The induc ve effect
Q.104 Aniline is a deriva ve of
A. Alkane B. Alkene
✓ C. Aroma c hydrocarbon D. Alicyclic
Q.105 Wurtz reac on is used to prepare:
A. Alcohol B. alkyl halide
C. Ether ✓ D. alkanes
Q.106
Those reagents or groups which are electrons deficient, are called?
A. Nucleophiles ✓ B. Electrophiles
C. Substrate D. Lewis base
Q.107 Chemical formulas of chloramines is
A. CICN B. CICN2
✓ C. CINH2 D. CINH
Q.108 Which compound shows hydrogen bonding?
A. C 2H 2 B. C2H5CI
C. CH3___O___CH3 ✓ D. C2H5OH
Q.109 Among the following the most reac ve towards alcoholic KOH is
A. CH2= CHBr B. CH3COCH2CH2Br
_______________________________________________________________________________________
C. CH3CH2Br ✓ D. CH3CH2CH2Br
Q.110 If carbon dioxide is bubbled through solu on of Grignard's reagent in ehter and the resultant product is reacted with
hydrochloric acid, it gives
A. an alkane B. an alcohol
✓ C. a carboxylic acid D. an aldehyde
Q.111 Which of the following is not an electrophile
✓ A. NH3 B. H+
C. Br+ D. BF3
Q.112 Methanol and ethanol can be dis nguished by:
A. lucaus test B. flame test
✓ C. iodoform test D. dichromate/H2SO4oxida on test
Q.113 Bakelite is a polymer obtained from two monomers:
A. phenol and acetone ✓ B. phenol and methanol
C. phenol and ethanol D. phenol and methanol
Q.114 C - X bond is strong in:
A. CH3CI B. CH3Br
✓ C. CH3F D. CH3I
Q.115 A maltose molecule is formed by the combina on of
✓ A. Two glucose molecules B. One glucose and one fructose molecule
C. Two fructose molecules D. One glucose and one galactose molecules
Q.116 Alcohol reacts with halogen acid in presence of ZnCI2 It gives
A. Aldehyde ✓ B. Alkyl Halide
C. Ketone D. Aldol
Q.117 SN2 reac on can be best carried out with
✓ A. primary alkyl halides B. secondary alkyl halides
C. ter ary alkyl halides D. all the three
Q.118 Which of the following is used as anesthe c?
✓ A. phenol B. dimethyl ether
C. diethyl ether D. alcohol
Q.119 Enzymes that catalyst the transfer of groups within the molecules are called
✓ A. Transferases B. Isomerases
C. Ligases D. Lyases
Q.120 The rate of E1reac on depends upon
✓ A. The concentra on of substrate B. The concentra on of nucleophile
C. The concentra on of substrate as well as D. None of the above
nucleophile
Q.121 Dehaloalkanes have halogen atoms in it:
A. One ✓ B. Two
C. Three D. Four
Q.122
For one complete revolution θ =?
A. 45° B. 180°
C. 90° ✓ D. 360°
Q.123 What will react differently with the two isomeric pentanois, (CH3)3 CCH2OH and (CH3)2CHCH2CH2OH?
A. acidified aqueous potassium manganate(vll) ✓ B. concentrated sulphuric acid
C. phosphorus pentachloride D. sodium
Q.124 The reac on between primary amine chloroform and alcoholic caus c potash is called
A. Wurtz reac on B. Frankland reac on
C. Cannizzaro's reac on ✓ D. Carbylamine reac on
Q.125 Tetrabromoethane on treatment with alcoholic zinc gives
A. Ethylbromide B. Ethane
_______________________________________________________________________________________
C. Ethene ✓ D. Ethyne
Q.126
Organic compounds having general formula Cn H2n+1 X are?
✓ A. Alkyl halides B. Aryl halides

C. Alcohols D. Alkanes
Q.127 The reac on of 4-bromobenzyl chloride with NaCN in ethanol leads to
✓ A. 4-Bromobenzyl cyanide B. 4-Cyanobenzyl chloride
C. 4-Cyanobenzyle cyanide D. 4-Bromo 2-cyanobenzyl chloride
Q.128 Reac on of R-X with nascent hydrogen gives:
A. Alcohol B. Alkyl halide
C. Ether ✓ D. Alkanes
Q.129 Alkyl halides are considered to be very reac ve compounds towards nucleophiles, because:
A. They have an electrophilic carbon ✓ B. They have an electrophilic carbon and good
leaving group
C. They have an electrophilic carbon and a bad D. They have a nucleophilic carbon and a good
leaving group leaving group
Q.130
A positively charged ion in which a carbon atom is bonded with three other atoms or groups of atoms is called?
A. Oxonium Ion B. Carbon ion

✓ C. Carbionium Ion D. None of above
Q.131 By reac ng Grignard's reagent with the HCHO we get
✓ A. 1° - alcohol B. 2° - alcohol
C. 3° - alcohol D. All of these
Q.132 Replacement of a acking and leaving nucleophile occurs in alkyl halide gives inverted molecules of types:
A. One ✓ B. Two
C. Three D. Four
Q.133 Cyclonite is a powerful
✓ A. Explosive B. An sep c
C. Analgesic D. An -inflammatory
Q.134 General formula of alkyl halide is:
✓ A. R-x B. R - OH
C. R - COH D. R - COOH
Q.135 When alcoholic KOh reacts with bromoethane it produces
A. Ethanol B. Ethanal
C. Ethane ✓ D. Ethene
Q.136 A carbon a ached at least with two carbon atoms is called a carbon:
A. Primary ✓ B. Secondary
C. Ter ary D. All of these
Q.137 Poly haloalkanes have halogen atoms:
A. One B. Two
C. Three ✓ D. Many
Q.138 Strach gives ______ color with iodine
✓ A. Blue B. Red
C. Yellow D. Green
Q.139 Ethanol is converted into ethanoic acid by
A. hydra on B. hydrogena on
C. fermenta on ✓ D. oxida on
Q.140 Carbon atom carrying posi ve charge and a ached to three more atoms or groups is called as
✓ A. Carboca on B. P° -Carboca on
C. S° -Carboca on D. t° -Carboca on
Q.141
_______________________________________________________________________________________
Ethene adds a molecule of HI to form?
✓ A. Todo-Ethane B. Jodo-ethene
C. di-iodo ethane D. None of the above
Q.142 Grignard reagent is prepared by the reac on of magnesium metal with alkyl halide in the presence of
A. alcohol B. water
C. suephuric acid ✓ D. dry ether
Q.143 Which one of the following will have the maximum dipole moment
A. CH3F ✓ B. CH3CI
C. CH3Br D. CH3I
Q.144 SN1 reac on are bit similar in mechanism with
A. SN2 ✓ B. E1
C. E2 D. None
Q.145 Reac on of Grignard's reagent with cyanogens chloride gives:
A. Primary alcohol B. Secondary alcohol
C. Ter ary alcohols ✓ D. Ethanoic acid
Q.146 What type of alkyl halides are difficult to obtained by direct combina on
✓ A. Iodides B. Bromides
C. Chlorides D. Fluorides
Q.147 Which one of the following is not monohaloalkane
A. 2-chloropropane ✓ B. 1, 2-dibromoethane
C. 2-bromobutane D. 3-chloro pentane
Q.148 SN2 - reac ons can be usually observed in
✓ A. Primary alkyl halide B. Secondary alkyl halide
C. Ter ary alkyl halide D. Both A and B
Q.149
A substitution reaction in which one nucleophile displace another nucleophile is called?
✓ A. SN reaction B. SN1 reaction

C. SN2 reaction D. Beta-elimination reaction
Q.150 Halogens on trea ng with silver salts of acids give
A. alcohol B. ester
C. phenol ✓ D. alkyl halide
Q.151 Which of the following is not a nucleophile
A. OH- B. NH3
C. C 2H 5O - ✓ D. Br2
Q.152 Alkyl Halide can be converted into alcohol by
A. Addi on reac on ✓ B. Subs tu on
C. Dehydra on D. None
Q.153 The percentage of reten on and inversion configura on in SN1 is:
✓ A. 50% each B. 40% & 60%
C. 70% & 30% D. 20% & 80%
Q.154 When chloroform is boiled with NaOH, it gives
A. Formic acid B. Trihydroxymethane
C. Acetylene ✓ D. Sodium formate
Q.155 Grignard's reagent is
A. alkyl halide B. magnesium halide
✓ C. alkyl magnesium halide D. ethereal solu on of an alkyl halide
Q.156 Elimina on bimolecular reac ons usually obey
A. first order kine cs ✓ B. second order kine cs
C. third order kine cs D. zero order kine cs
_______________________________________________________________________________________
Q.157 Monohaloalkanes have halogen atoms in it:
✓ A. One B. Two
C. Three D. Four
Q.158 5, 3-Dibromopropane reacts with metallic zinc to form
A. Propene B. Propane
✓ C. Cyclopropane D. Hexane
Q.159 Starch give________colour with codine
✓ A. blue B. green
C. red D. yellow
Q.160 Rancidifica on of fats and oils is due to
A. Hydrolysis reac on B. Oxida on reac on
✓ C. Both a and b D. Hydrogena on reac on
Q.161 Isozymes are the enzymes which
A. Have similar chemical proper es B. Have similar physical proper es
✓ C. Have different physical and chemical D. None of these
proper es
Q.162 Alkyl halides on treatment with aqueous KOH give
A. phenol ✓ B. alcohol
C. aldehyde D. ketone
Q.163 Electronega vity of chlorine is:
A. 4.0 ✓ B. 3.0
C. 2.8 D. 2,5
Q.164 Ac on of Zn with halides in the presence of an inert solvent forms higher alkanes. This reac on is known as
A. Wurtz reac on ✓ B. Frankland's reac on
C. Cannizaro reac on D. Kolbe's reac on
Q.165 Which of the following is the best nucleophile
A. Cl B. Br
✓ C. I D. F
Q.166 Oxida on of methyl alcohol gives:
A. acids ✓ B. formaldehyde
C. acetone D. ester
Q.167 E2has molecularity:
A. One ✓ B. Two
C. Three D. Half
Q.168 Most reac ve halide towards SN1 reac on is
A. n-Butyl chloride B. Sec-Butyl chloride
C. Tert-Butyl chloride ✓ D. Allyl chloride
Q.169 To get DDT, chlorobenzene has to react with one of the following compound in the presence of conc. H2SO4
A. Trichloroethane B. Dichloroacetone
✓ C. Trichloroabetealdehyde
Q.170 Chlorine is least reac ve in
A. Methyl chloride ✓ B. Vinyl chloride
C. Allyl chloride D. Ethyl chloride
Q.171 Which of the following is nucleophile
A. CH+3 B. (CH3)3C+
C. BF3 ✓ D. OH-
Q.172 Glycol, used in an -freeze, has the formula HOCH2CH2OH.It can be oxidized to give a number of product,
What is the molecular formula of an oxida on product of glycol that will not react with sodium?
✓ A. C 2 H 2O 2 B. C 2H 2O 3
C. C 2H 2O 4 D. C 2H 4C 2
Q.173
_______________________________________________________________________________________
Which compound reacts with it own oxida on product (an oxida on which involves no less of carbon)to give a sweet-
smelling liquid?
A. propanal B. propanoic acid
C. propanone ✓ D. propan-1-ol
Q.174 Which of the following alkyl halides is used as a mathyla ng agent
A. CH2H5I ✓ B. CH3I
C. C2H5Pr D. C2H5Cl
Q.175 Methyl magnesium iodide on hydrolysis forms
A. Methyl alcohol ✓ B. Methane
C. Methanal D. Methanoic acid
Q.176 Mechanism of elimina on reac ons followed are:
A. addi on ✓ B. subs tu on
C. elimina on D. Redox
Q.177 an alcohol of molecular formula C4H10O2 contains two OH groups and
has an unbranched carbon atom chain.
On reac on with an excess of hot MnO-4/H+ this alcohol is converted into a compound of molecular formula C4H6O4
To which two carbon atoms in to the chain to the alcohol are the tow OH groups a ached?
A. 1stand 2nd B. 1stand 3rd
✓ C. 1stand 4th D. 2ndand 3rd
Q.178
✓ A. 2-brome-3-methylbutne B. 3-methyl-2-bromobutane
C. 2-methyl-3-bromobutane D. All of these
Q.179 Benzene hexachloride is used as
A. Dye B. An malerial drug
C. An bio c ✓ D. Insec cide
Q.180 Alcohol reacts with halogen acid to produce:
A. alkanes ✓ B. alkyl halides
C. ketones D. aldehyetes
Q.181 When primary amine reacts with chloroform in ethanolic KOH, then the product is
✓ A. An isocyanide B. An aldehyde
C. A cyanide D. An alcohol
Q.182 Which bond is most stable?
A. C - Cl ✓ B. C-F
C. C - Br D. C-I
Q.183 IUPAC name of methylene chlorideis
A. Chloromethane ✓ B. Dichcloromethane
C. Dichcloromethane D. None of these
Q.184 Ethyl chloride reacts with alc, KOH to give
✓ A. C 2H 4 B. C2H5Cl
C. CH3I D. C2H5OH
Q.185 Reac vity order of alkyl halides is:
✓ A. RI>RBr>RCI>RF B. RBr>RCI>RF>RI
C. RCI>RF>RI>RBr D. RF>RI>RBr>RII
Q.186 Aniline is a deriva ve of:
A. alkene B. alkane
C. alicyclic hydrocarbon ✓ D. aroma c hydrocarbon
Q.187 A carbon a ached at least with three carbon atoms is called a carbon:
A. Primary B. Secondary
_______________________________________________________________________________________
✓ C. Ter ary D. All of these
Q.188 How many alcohols (including both structural isomers and steroisoners) can have the molecular formula:
A. 3 B. 4
✓ C. 5
Q.189 Oxida on of a secondary alcohol gives:
✓ A. keton B. ether
C. aldehyde D. organic acid
Q.190 Iodine number of an oil indicates its
A. Molecular weight B. Purity
✓ C. Degree of unsatura on D. Acidic strength
Q.191 Nitra on of phenol gives:
A. o-Nitrophenol B. m-Nitrophenol
C. p-Nitrophenol ✓ D. bothoandp-Nitrophenol
Q.192
The angular velocity depends upon the rate of change of the?
A. Angular Distance. ✓ B. Angular Displacement.

C. Angular acceleration D. Torque
Q.193 Metylene chloride has molecular formulas
A. CH3CI ✓ B. CH2CI2
C. CHCI3 D. Both a and b
Q.194 The rate of E1reac ons depends upon:
✓ A. The concentra on of substrate B. The concentra on of nucleophilic
C. The concentra on of substrate as well as D. None of above
nucleophilic
Q.195 Organic compounds containing halogen atom are called:
A. R - OH ✓ B. R-X
C. R - NH2 D. R - COH
Q.196 Reac on of CO2with Grignard's reagent gives:
A. Ethanal B. Ethanol
C. Ethanone ✓ D. Ethanoic acid
Q.197 Reac on of which with Grignard's reagent gives primary alcohol:
A. Formaldehyde ✓ B. Aldehyde
C. Ketones D. Acetone
Q.198 Keratomalacia is caused due to the deficiency of vitamin
✓ A. A B. B
C. D D. K
Q.199 In the transi on state of SN2 mechanism reac on with alkl halides, which of the following orbital hybridiza on is
involved
A. sp3 ✓ B. sp2
C. sp D. dsp3
Q.200 Wurtz reac on is used to prepare
✓ A. Symmetrical Alkanes B. Unsymmetrical alkanes
C. Both Symmetrical and unsymmetrical alkane D. None
Q.201 SN2reac on can be best carried out with
✓ A. Primary alkyle halides B. Secondary alkyle halides
C. Ter ary alkyle halides D. All the three
Q.202
Large angle produces?
A. Curve trajectory ✓ B. High trajectory

C. Flat trajectory D. Straight trajectory
Q.203
_______________________________________________________________________________________
A reac on in which an atom or a group of atoms replaces an atom or a group of atoms in the molecule of a substance
in known as
A. addi on reac on B. condensa on reac on
C. elimina on reac on ✓ D. subs tu on reac on
Q.204 Which one of the following organic acids is made from methanol
A. Ace c acid B. Bothanic acid
✓ C. Formic acid D. Propanoic acid
Q.205 Alkyl Halides reacts with excess of Ammonia to give
A. 1°-amine B. 2°-amine
C. 3°-amine ✓ D. All
Q.206 In primary alkyl halides, the halogen atom is a ached to a carbon which is a ached to how many carbon atoms?
A. Two B. Three
✓ C. One D. Four
Q.207 An electrophile may be
A. Posi ve B. Nega ve
C. Neutral ✓ D. Both c and a
Q.208 Benedict solu on gives a posi ve test with but catalyze the same reac on
A. Fructose ✓ B. Glucose
C. Starch D. Sucrose
Q.209 The alkyl halide is converted into an alcohol by
A. Addi on ✓ B. Subs tu on
C. Dehydrohalogena on D. Elimina on
Q.210 A compound or specie in search of electrons is called
A. Radical ✓ B. Electrophile
C. Nucleophile D. Electrolyte
Q.211 The op mum pH value for the enzyme "pepsin" is
A. 2 B. 8
C. 10 ✓ D. 1.4
Q.212 The organic compounds having halogen atom in them are called:
A. Alkyl halides B. Haloalkanes
C. Alcohols ✓ D. A&B
Q.213 Ethanol can be converted into ethanoic acid by:
A. hydrogena on B. hydra on
✓ C. oxida on D. fermenta on
Q.214 Deposi on of cholesterol in arteries is responsible for
✓ A. Heart a ach B. Diabetes
C. Hepa s D. Cancer
Q.215 Which of the following factors does not affect the SN1 rate is
✓ A. Nucleophilicity of the a acking nucleophile B. Stability of the carbonium ion
C. Solvent system D. The nature of leaving group
Q.216 Alkyl halides undergo a type of reac on
A. Nucleophilic subs tu on B. Nucleophilic addi on
C. Elimina on ✓ D. Both A and C
Q.217
Formula of Grignard’s reagent?
A. R-Na-X B. R—K-X.
✓ C. R—Mg-X D. None of the above
Q.218 On warning with silver powder, chloroform is converted into
✓ A. Acetylene B. Hexachloroethane
C. 1, 1, 2, 2-tetrachlotoethane D. Ethylene
_______________________________________________________________________________________
Q.219 Elimina on of molecular reac ons usually obey
C. Third order kine c D. Zero order kine c
Q.220 Best method for the prepara on of alkyl halides is the reac on of alcohols with
A. HX ✓ B. SOCI2
C. PX3 D. PX3
Q.221 Haloalkanes are :
A. Monohaloalkanes B. Dihaloalkanes
C. Trihaloalkanes ✓ D. All
Q.222 Reac on of alkyl halide with a base follow mechanism.
A. Sub tu on B. Elimina on
C. Free radical ✓ D. Subs tu on and elimina on
Q.223 Grinard reagent is reac ve due to
A. Presence of Halogen atom B. Presence of Mg atom
✓ C. Polar y of C-Mg bond D. Polarity of Mg-X bond
Q.224
One radian is equal to ?
A. 53.7° ✓ B. 57.3°
C. 57.7° D. 59.3°
Q.225
An alkyl halide in which the halogen bearing C atom is attached to two more carbon atoms is called?
A. Primary, 1° ✓ B. Secondary, 2°
C. Tertiary, 3° D. None of the above
Q.226 Alcohol can be prepared from Grignard's reagent with an aldehyde. If we start with formaldehyde the product alcohol
with be
✓ A. primary B. secondary
C. territory D. aroma c
Q.227 Which of the following compounds gives trichloromethane on dis lling with bleaching power?
A. Methanal B. Phenol
✓ C. Ethanol D. Methanol
Q.228 Treatment of a secondary alcohol with a suitable oxidizing (K2Cr2O7) result in the forma on of:
A. aldehyde B. alkyl halide
✓ C. ketone D. ether
Q.229
When methane is treated with chlorine in the presence of sunlight it forms?
A. CH3C1 B. CH2C12
C. CH2C13 ✓ D. A mixture of various halogenated
derivatives of methane
Q.230 Trihaloalkanes have number of halogen atom(s):
A. One B. Two
Q.231 Formula of methylene chloride is:
✓ A. CH2Cl2 B. CH3Cl
C. CHCl3 D. CCl4
Q.232 Glucose forms a polymer, which is stored in liver. The name of this polymer is
✓ A. Glycogen B. Starch
C. Cellulose D. Arnylose
Q.233 SN1 reac ons are given by alkyl halides
A. primary ✓ B. secondary
C. ter ary D. Monohaloakane
Q.234 Grignard's reagent on treatment with carbonyl compounds yield
_______________________________________________________________________________________
A. phenol ✓ B. alcohol
C. alkane D. none of these
Q.235
In alkyl halides R — CH2 — X?
A. Carbon atom is partially negatively ✓ B. Halogen atom is partially negatively

charged. charged.
C. Alkyl group is partially negatively charged D. There is no polarity in the molecule.
Q.236 Sex harmones belong to a group of organic compounds called
A. Heterocyclies ✓ B. Steroids
C. Amino acids D. Amines
Q.237 Only two isomeric monochloro deriva ves are possible for
A. n-Octane B. Benzene
✓ C. 2-methyl propane D. 2,4-dimethyl pentane
Q.238 The reac vity of halogen atom is minimum in
A. Propyl iodide ✓ B. Propyl chloride
C. Isopropyl chloride D. Isopropyl bromide
Q.239 Grignard reagent is reac ve due to
A. the presence of halogen atom B. the presence of Mg atom
✓ C. the polarity of C - Mg bond D. none of the above
Q.240 Best method of prepara on of alkyl halide from alcohols is by its reac on with:
✓ A. HX B. SOCI2
C. PX5and PX3 D. All
Q.241 Alkyl halides react with lithium dialkyl copper reagents to give
A. Alkenes B. Alkyl copper halides
✓ C. Alkanes D. Alkenyl halides
Q.242
Which of the following is an alkyl halide?
✓ A. CH3C1 B. CH2Br2
C. CHI3 D. None of the above
Q.243 DDT is formed from
A. Benzene and Chlorobenzene ✓ B. Chloral and Chlorobenzene
C. Chloral and Benzene D. Chlorobenzene and chlorine
Q.244 What is the total number of different chloroethanes, formula C2H6-nCln. Where in can be any integer from 1 to 4
A. 4 B. 6
✓ C. 7 D. 8
Q.245 Allyl chloride on dehydrochlorina on gives
✓ A. Propadiene B. Propylene
C. Allyl alcohol D. Acetone
Q.246 An acid can decompose Grignard reagent into alkane it
A. It can yield proton B. It is more ionized than hydrogen
✓ C. Both are correct D. Both are incorrect
Q.247 Which is a good necleophile?
A. F-1 B. Cl-1
C. Br-1 ✓ D. I-1
Q.248 Monohaloalkanes are also called :
✓ A. Alkyl halides B. Haloaknes
C. Alcohols D. Ester
Q.249 Alkyl halides on treatment with Zn and HCl gives
✓ C. alkanes D. alcohols
_______________________________________________________________________________________
Q.250 Compounds of hydrocarbons with halogens are called :
Q.251
The motion on a curved path, when one component of velocity is constant and the other is variable is called?
✓ A. Projectile motion B. Circular motion

C. Vibratory motion D. Spin motion
Q.252 A compound C5H10 does not react with CI2 in dark but yield single produce C5H9CI in bright sunlight compound is
A. Alkene ✓ B. Cycloalkane
C. Alkane D. Both a and b
Q.253
Those reagents or groups which have excessive electrons are called?
✓ A. Nuelophile B. Electro philes

C. Substrate D. None
Q.254 Alkyl halides are reac on:
✓ A. high B. medium
C. less D. least
Q.255 The order of reac vity of an alkyl halide (R - X) for a par cular alkyl group is
✓ A. iodide > bromide > chloride B. chloride > bromide > iodide
C. bromide > chloride > iodide D. bromide > iodide > chloride
Q.256 An alkyl halide with two halogen atoms at two adjacent carbon atoms is called:
✓ A. Vic-dilahide B. Gem-dilahide
C. Poly haloalkanes D. Primary alkyl halides
Q.257 One gram of carbohydrate yields energy
✓ A. 4 Kcal B. 9Kcal
C. 10 Kcal D. 100 Kcal
Q.258 2-Bromopentane is heated with potassium ethoxide in ethanol. The major product obtained is
A. 2-Ethoxypentane B. Pent-1-ene
C. Cis-Pent-2-ene ✓ D. Trans-Pent-2-ene
Q.259 Compounds of aldehydes are named by replacing "-----e" of alkanes with:
A. Halo B. ----cl
✓ C. Al--- D. ----one
Q.260 Which compound
is unaffected by hot alkaline postassium manganate (VII):
gives hydrogen when treated with sodium?
A. (CH3)2CHCOCH ✓ B. (CH3)3CHO
C. CH3CH2CH(OH)CH3 D. CH3CO2CH(CH3)2
Q.261 Electronega vity of bromine is:
A. 4.0 B. 3.0
✓ C. 2.8 D. 2.5
Q.262
The work done by the centripetal force is always?
A. Positive B. Negative
✓ C. Zero D. None of these
Q.263 More than similar branches are wri en in IUPAC names:
A. Using prefix di, tri etc B. Wri ng each me name with posi on
✓ C. Using prefix with posi on D. Using suffix
Q.264
Chemical name of Grignard’s reagent is?
A. Alkyl sodium halide B. Alkyl potassium halide
_______________________________________________________________________________________
✓ C. Alkyl magnesium halide D. None of the above
Q.265 For SN2 reac on reac vity order of alkyl Halide is
A. RF>RCI>RBr>RI B. RF>RBr>RCI>RI
✓ C. RI>RBr>RCI>RI D. None
Q.266
In projectile a body moves with?
A. Constant vertical component of velocity ✓ B. Constant horizontal component of

velocity
C. Both changing horizontal and vertical D. Horizontal component changing but
components of velocity vertical component of velocity constant.
Q.267 Which substances do not react immediately with bromine water
A. Phenol B. Benzene
✓ C. Ethane D. Ethene
Q.268 An amino acid exists in the form of Zwi er-ion which has
A. One +ve charged B. One -ve charged
✓ C. One +ve and -ve charged D. Two +ve charged
Q.269 When an alcohol reacts with SOCl2an alkyl halide is formed.What are two other products
✓ A. SO2and HCl B. SO2and H2O
C. HCl and H2O D. H2S and HCl
Q.270 Which of the following does not give iodoform test?
C. Acetophenone ✓ D. Benzophenone
Q.271 An ester is prepared by
A. Two alcohols ✓ B. Carboxylic acid and alcohol
C. Ketone and alcohol D. Aldehyde and alcohol
Q.272 When CO2is made to react with ethyl magnesium iodide, followed by hydrolysis, the product formed is:
A. Propane ✓ B. Propanoic acid
C. Propanal D. Propanol
Q.273 How many monochlorobutanes will be possible on chlorina on of n-butane?
A. 1 ✓ B. 2
C. 3 D. 5
Q.274 The alkyl halide molecule on which a nucleophile a acks is called
✓ A. Substrate B. Subsituent
C. Subs tuted D. All of these
Q.275 In a primary alkyl halide, the halogen atom is a ached to a carbon which is further a ached to
A. Only one carbon atom B. Two carbon atoms
C. Three carbon atoms ✓ D. One or no carbon atom
Q.276
One degree (1°) is equal to? (a) (b) (c) (d)
✓ A. 0.01745 rad B. 0.1745 rad

C. 0.001745 rad D. 7.1745 rad
Q.277
A. both S1N B. both SN2

✓ C. 1
(I) SN , (II) SN 2
D. None of these
Q.278 Methyl alcohol possesses:
A. poisonous B. burning taste
_______________________________________________________________________________________
C. causes blindness ✓ D. all above
Q.279
Chloro form (CHC13) is?
✓ A. B. Secondary alkvl halide

C. Tertiary alkyl halide D. None of these
Q.280 Which of the following is good leaving group
A. OH- B. NH-2
C. OR- ✓ D. CI-
Q.281 Which compound show maximum hydrogen bonding with water?
C. CH3___O___CH3 D. C6H5OH
Q.282 Hydrolysis of Grignard's reagent gives:
✓ A. Alkane B. Alkyl halide
C. Alcohol D. Carboxylic acid
Q.283 SN2Reac ons can be best carried out with:
✓ A. Pri. Alkyl halide B. Sec. Alkyl halide
C. Ter. Alkyl halide D. All of three
Q.284 Which will give a cream ppt. with AgNO3
A. C 2H 5F B. C2H5Cl
✓ C. C2H5Br D. C 2H 5I
Q.285 In elimina on bimolecular reac ons nucleophile a acks on
A. α-Carbon B. β-carbon
✓ C. β-Hydrogen D. None of these
Q.286 Monohalo deriva ves of alkanes are called
A. Amides B. Alkenes
✓ C. Alkyl halide D. Imide
Q.287 Malt sugar is converted into glucose by an enzyme invertase present in yeast. The process is known as
A. Dehydra on B. Condensa on
✓ C. Fermenta on D. Oxida on
Q.288 Cyanoform is _____ acid in nature than the chloroform. The missing word is
✓ A. Stronger B. Weaker
C. Amphoteric D. Neutral
Q.289 The compounds with general formula R---X are called:
Q.290 Which type of alcohol among the following are resistant to oxida on?
A. primary B. secondary
✓ C. ter ary D. all above
Q.291 Alkanes can be prepared an Grignard's reac on with:
A. Water B. Ammonia
C. R-X ✓ D. All
Q.292 Èlectronega vity value of fluorine is:
✓ A. 4.0 B. 3.0
C. 2.8 D. 2.5
Q.293 Compounds of alkanes are given names by replacing "e" of alkane with:
A. Halo B. ----ol
C. Al--- ✓ D. ----one
Q.294 Alkyl halides in which a halogen atom is bonded to that carbon atom which directly bonded with one hydrogen atom
is called
A. primary alkyl halides ✓ B. secondary alkyl halides
_______________________________________________________________________________________
C. ter ary alkyl halides D. quaternary alkyl halides
Q.295 Ethyl alcohol gives ethyl chloride with the help of
✓ A. SOCI2 B. NaCI
C. CI2 D. KCI
Q.296 A molecule of polysaccharide hydrolysis produces ______ molecules of
A. 2 B. 3
✓ C. 2-10 D. 100
Q.297 Which compound will have maximum repulsion with H2O?
✓ A. C 6H 6 B. C2H5OH
C. CH3CH2CH2OH D. CH3_____O_____CH3
Q.298 A molecule oligosacharide on hydrolysis produces ______ molecules of monosacharide
A. 1 B. 2
C. 4 ✓ D. 6
Q.299 An alkyl halide with two halogen atoms at same carbon is called:
A. Vic-dilahide ✓ B. Gem-dilahide
C. Poly haloalkanes D. Primary alkyl halides
Q.300 Which pair of substances is not suitable for the direct prepara on?
A. ethanol and acetyl chloride B. ethanol and ace c acid
✓ C. phenol and benzoic acid D. ethanol and benzoic acid
Q.301 Which one of the following is not associated with SN2 mechanism
A. 100% inversion of configura on B. 2nd order kine cs
✓ C. Te ary alkyl halides D. Change of hybridiza on 3to 2in transi on
from sp sp state
Q.302
Small angle produces?
✓ A. Flat trajectory B. Straight trajectory

C. High trajectory D. Steep trajectory
Q.303 Reac on of Grignard's reagent with acetaldehyde gives:
A. Primary alcohol ✓ B. Secondary alcohal
C. ter ary alcohols D. ethanolic acid
Q.304 The SN1 mechanism for the hydrolysis of an alkyl halide to an alcohol involves the forma on of
✓ A. Carboca on B. Carbanion
C. Free radical D. Pentavalent carbon in the transi on state
Q.305
An alkyl halide in which halogen bearing C atom is attached to three other carbon atoms is called?
A. Primary, 1° B. Secondary, 2°
✓ C. Tertiary, 3° D. None of the above
Q.306
When angular velocity changes with respect to time then?
A. A linear acceleration is produced ✓ B. An angular acceleration is produced

C. A linear velocity is produced D. It constitute a couple
Q.307 Grignard's reagent was prepared in:
✓ A. 1900 B. 1910
C. 1920 D. 1930
Q.308 E1 reac ons are given by alkyl halides:
✓ C. Te ary D. Monohaloalkane
Q.309 Which halide among the following is used as methyla ng agent?
✓ A. CH3I B. C2H5CI
C. C2H5Br D. C6H5CI
_______________________________________________________________________________________
Q.310 Primary alkyl halide have halogen atom a ached to carbon atom:
Q.311 Water soluble and crystalline carbohydrates are
A. Monosacharides B. Obiligosacharides
C. Polysacharides ✓ D. A and B
Q.312 Which compound reacts with its own oxida on product (an oxida on which involves no less of carbon) to give a
sweet-smelling liquid?
Q.313 Chlorobenzene on hea ng with aqueous NH3 under pressure in the presence of cuprous chloride gives
A. Benzamide B. Nitrobenzene
✓ C. Aniline D. Chloroaminobenzene
Q.314 Electronega vity of hydrogen is:
A. 4.0 B. 3.0
C. 2.8 ✓ D. 2.1
Q.315 Alkyl halides having halogen atom a ached to secondary carbon atom are called:
A. Primary ✓ B. Secondary
Q.316 The maximum electronega vity difference is between bond.
✓ A. R-F B. R-H
C. R-Cl D. R-Br
Q.317 E1mechanism is generally shown by
A. 10- RX B. 20- RX
✓ C. 30- RX D. None of these
Q.318 If ketone reacts with Grignard's reagent. It also produces alcohol, but it will be a
A. primary alcohol B. secondary alcohol
✓ C. ter ary alcohol D. aroma ce alcohol
Q.319 When CO2is made to react with ethyl magnesium iodide, followed by acid hydrolysis, the product formed is
A. propane ✓ B. propanoic acid
C. propanal D. propanol
Q.320 A set of compounds in which reac vity of halogen atom in the ascending order is
✓ A. Chlorobenzene, vinyl chloride, chloroethane B. Chloroethane, chlorobenzene vinyl chloride
C. Vinyl chloride, chlorobenzene, chloroethane D. Vinyl chloride chloroethane chlorobenzene
Q.321 Which of the following compounds on oxida on give benzoic acid?
A. Chlorophenol B. Chlorotoluene
C. Chlorobenzene ✓ D. Benzyl chloride
Q.322 The alkanes in which halogen is replaced by any halogen atom are called:
Q.323 When achiral alkyl 1 halide is subjected to SN1 reac on, inversion of configura on takes places
A. 40% ✓ B. 50%
C. 60% D. 80%
Q.324 Which alcohol my be oxidized to a product which reacts with 2,4- dinitrophenylhydraszine reagent but not with
Fehling's reagent?
A. butan-1-ol ✓ B. butan-2ol
Q.325 The number of molecules taking part in the rate determining steps is called:
✓ A. order B. molecularity
C. rate D. Mechanism
_______________________________________________________________________________________
Q.326 For which mechanism, the first step involved is the same
A. E1 and E2 B. E2 and SN2
C. E2 and E1 ✓ D. E1 and SN1
Q.327 Which of the following decides the reac vity of alkyl halides
A. C - C bond strength B. C - H bond strength
✓ C. C - X bond strength D. Electronega vity difference
Q.328 A carbon a ached with all three hydrogen or a carbon is called a carbon:
Q.329 When carbon dioxide is passed through the R - Mg - X is produced
✓ A. Any carboxylic acid B. Propanoic acid
C. Propanedioic acid D. None of these
Q.330
When CH3—I is treated with sodium methoxide CH3ONa, the product formed is?
✓ A. An ether B. Alcohol
C. Alkane D. None of the above
Q.331 Potency and turn over are terms related to
✓ A. Enzymes B. Proteins
C. Fats D. Oils
Q.332 Which one of the following organic acids is made form methanol?
✓ A. forming acid B. butanoic acid
C. ace c acid D. none of all
Q.333
Which of the following is a tertiary alkyl halide?
A. CH3C1 B. CHCl3
✓ C. (CH3)3 CC1 D. (CH3)2 CHC1
✓ A. the concentra on of substrate B. the concentra on of nucleophile
C. the concentra on of substrate as well as D. none of the above
nucleophile
Q.335 Order of reac vity for a given halogen in Gridnard's reagent is:
✓ A. CH3X>C2H5X>C3H4X>C4H4X B. C2H5X>C3H7X>C4H9X>CH3X
C. C3H7X>C4H7X>CH3X>C2H5X D. C4H4>C3H7X>C2H5X>CH3X
Q.336 Carbon atom holding halogen in aryl halides is
✓ A. sp2-hybridesed B. sp3-hybridesed
C. sp-hybridesed D. sp3 d-hybridesed
Q.337 Which compound is more soluble in water?
✓ A. CH5OH B. C6H5OH
C. CH3___O___CH3 D. n-Hexanol
Q.338 Which pair of the substances is not suitable for the direct prepara on
A. Ethanol and ace c acid B. Ethanol and acetyl chloride
C. Ethanol and benzoic acid ✓ D. Phenol and benzoic acid
Q.339 Frankland reac on is used to prepare:
A. alcohol B. Alkyl halide
C. Ether ✓ D. alkanes
Q.340 Which one of the following is not a nucleophile?
A. H 2O B. H 2S
✓ C. BF3 D. NH3
Q.341 Which is a weak nucleophile
A. OH- B. Br-
C. NH3 ✓ D. Cl-
_______________________________________________________________________________________
Q.342 As ester is prepared by the reac on of:
A. ketone and alcohol B. aldehyde and alcohol
C. two alcohols ✓ D. carboxylic acid and alcohol
Q.343 The chloroform reacts with NaOH to give
A. CH3COONa B. Sodium oxalate
C. CH3OH ✓ D. HCOONa
Q.344 Halogens are trea ng with silver salts of acids give
A. Alcohols B. Esters
C. Phenol ✓ D. Alkyl halide
Q.345 Grignard's reagent on treatment with chloramine give
A. acetamide ✓ B. primary amine
C. secondary amine D. urea
Q.346 Methyl alcohol is not used:
A. as solvent B. as an an freezing agent
✓ C. as a subs tute for petrol D. for denaturing of ethl alcohol
Q.347 Alkyl halides react with Mg in dry ether to form
A. Magnesium halide ✓ B. Grignard's reagent
C. Alkene D. Alkyne
Q.348 Alkyl Halides are
✓ A. Monohalo alkane B. Dihalo alkane
C. Trihalo alkane D. All of these
Q.349 Which one of the following is the least stable carbanion
A. CH3 B. CH3- CH2
C. (CH3)2CH - ✓ D. (CH3)3C-
Q.350 When formaldehyde is added to Grignard reagent we get
A. aldehyde B. acetone
✓ C. primary alcohol D. secondary alcohol
Q.351 Catalyst is the reac on ROH + SOCI2→ RCI + SO2+ HCI is:
A. ZnCI2 ✓ B. Pyridine
C. H2So4 D. Ether
Q.352 A molecule of polysaccharide on hydrolysis produces ______ molecules of monosacharides
✓ A. Many B. Few
C. 2 - 10 D. 100
Q.353 Which one of the following when reacts with C2H5MgBr does not alkane
A. NH3 B. H 2O
✓ C. CO2 D. CH3OH
Q.354 Electrophile is:
A. Electron loving B. Posi vely charges
C. Neutral ✓ D. All of these
Q.355 When alkyl halide is heated with aqueous solu on of ammonia at 100°C the major product is
A. primary amine B. secondary amine
C. ter ary amine ✓ D. mixture of amines and salt
Q.356 Alkyl halides on treatment with metallic Na give
A. Alkynes B. Alkenes
✓ C. Alkanes D. Alcohols
Q.357 SN2 reac on can be best carried out with
✓ A. Primary alkyl halide B. Secondary alkyl
C. Te ary alkyl halide D. All of above
Q.358 Phenol is a weak acid.The correct order of acid strength of carboxylic acid. phenol and alcohol is
A. alcohol > phenol > carboxylic acid ✓ B. carboxylic acid > phenol > alcohol
_______________________________________________________________________________________
C. carboxylic acid > alcohol > phenol D. phenol > carboxylic acid > alcohol
Q.359 Ethyl chloride on treatment with aqueous alkali gives
A. Ethane B. Ethene
C. Ethanal ✓ D. Ethanol
Q.360 Metal used in the prepara on of Grignard's reagent is:
A. Ca B. Na
✓ C. Mg D. Zn
Q.361 Reac on of Grignard's reagent with acetone gives:
✓ C. ter ary alcohol D. ethanoic acid
Q.362 Per hydro cyclopentano phenanthrene is the basic structure of all the
A. Proteins B. Vitamins
C. Waxes ✓ D. Steroids
Q.363 With the increase in size of halogen atom the reac vity of an alkyl halide
✓ A. increase B. decreases
C. remain constant D. none of these
✓ A. The concentra on of substrate B. The concentra on
C. The concentra on of substrate as well as D. None of these
nucleophile
Q.365 1-Chlorobutane on reac on with alcoholic potash gives
✓ A. But-1-ene B. Butan-1-01
C. But-2-ene D. Butan-2-ol
Q.366 The reac on of an alkyl halide with RCOOAg produces
✓ A. Ester B. Ether
C. Aldehyde D. Ketone
Q.367 Iodoethane reacts with sodium in ether the product formed is
A. Pentene B. Propyne
C. Butene ✓ D. Butane
Q.368 Butanenitrile is formed by reac on of KCN with
A. Propyl alcohol B. Butyl chloride
C. Butyl alcohol ✓ D. Propyl Chloride
Q.369 Which term describes the ac on of NaOH(aq)on a bromo alkane
A. Acid base reac on B. Electrophilic subs tu on
C. Elimina on of HBr ✓ D. Nucleophilic subs tu on
Q.370 Most animals can not digest
A. Starch ✓ B. Cellulose
C. Proteins D. Glucose
Q.371 When metallic sodium in ether is heated with ethyl chloride, which alkane is formed
A. propane B. ethane
C. iso-butane ✓ D. n-butane
Q.372 Which of the following undergoes uncleophilic subs tu on exculsively by SN1 mechanism?
✓ A. Benzyl chloride B. Ethyl chloride
C. Chlorobenzene D. Isopropyl chloride
Q.373 Which one of the following is mainly responsible for deple on of ozone layer?
A. Methane B. Carbon dioxide
C. Water ✓ D. Chlorofluorocarbons
A. Acids B. Acid chloride
✓ C. Alkyl halide D. Benzene
_______________________________________________________________________________________
Q.375 Alkyl halides having halogen atom a ached to ter ary carbon atom are called:
✓ C. Ter ary D. All of these
Q.376 C6H6CI6 can be obtained from:
A. HCI and Benzene B. CI2and Benzene and AICI3
✓ C. CI2and Benzene in diffused light D. NaOCI and Benzene.
Q.377 Which of the following is a nucleophile?
✓ A. OH- B. CH(CH3)3
C. CH3+ D. CH3CH2CH3
Q.378 Which of the following could be prepared by reac ng bromoethane with KCN and reducing the product
A. H3C - CH3 B. CH3- CH2- NH2
✓ C. H3C - CH2- CH2- NH2 D. HC3- CH2- CH3
Q.379
Other name of alkyl halides is?
✓ A. Monohalo-alkanes B. Dihalo — alkanes

C. Trihalo-alkanes D. Tetrahalo — alkanes
Q.380
A. Electrophilic addi on B. Electrophilic subs tu on

C. Nucleophilic addi on ✓ D. Nucleophilic subs tu on
Q.381 Alkyl halides can be prepared by trea ng halogen acids with
A. Ethane ✓ B. Ethanol
C. Ethane and ethanol D. Aldehyde
Q.382 The reac vity order of alkyl halides for a par cular alkyl group is
A. fluoride > chloride > bromide > iodide B. chloride > bromide > fluoride > iodide
✓ C. iodide > bromide > chloride > fluoride D. bromide > iodide > chloride > fluoride
Q.383
A car traveling at 70 Km/ hr east turns south without a change in speed. The car is moving with?
A. Uniform velocity B. Average velocity

✓ C. Acceleration D. None of these
Q.384 What is the total number of different chloroethanes of formula C2H6-nClnpossible (n may be 1 to 6)
✓ A. 9 B. 8
C. 6 D. 10
Q.385 Coenzymes are the species which increase the ac vity of enzymes. They are chemically
A. Organic bases B. Organic acids
✓ C. Metal ions D. Non-metals
Q.386 Which of the following reacts with chloroform and base to form phenyl isocyanide?
A. Nitrobenzene B. Phenol
C. Chlorobenzene ✓ D. Aniline
Q.387
A. Primary alkyl halide ✓ B. Secondary alkyl halide

C. Ter ary alkyl halide D. Normal alkyl halide
Q.388 1,2-Dibromobutane on reac on with alcoholic KOH produce
A. 1-Butanol B. 1-Butene
✓ C. 1-Butyne D. 2 Butene
_______________________________________________________________________________________
Q.389 Alkyl halides are given IUPAC names by changing halogen to:
A. Halo ✓ B. ---ol
C. Al---- D. ----one
Q.390 In Primary alkyl Halides Halogen atom is a ached to carbon which is futher a ached with_____carbon atom (s)
✓ A. One B. Two
C. Three D. Four
Q.391 For which mechanisms, the first step involved is the same:
C. E2and E1 ✓ D. E1and SN1
_______________________________________________________________________________________
16 Alcohols and Phenols
Q.1 Methanol reacts with I2 presence of NaOH to give

A. Yellow ppt B. White ppt
✓ C. No ppt D. Brick red ppt
Q.2 Phenol is also known as
A. ace c acid ✓ B. carbolic acid
C. tartaric acid D. trichloroace c acid
Q.3 Aldehydes are the oxida on product of:
✓ A. Primary alcohol B. secondary alcohol
C. ter ary alcohol D. carboxylic acids
Q.4 An organic compound will decolorise dil acidfied (aq) KMnO4on warming, but will not decolorise bromine water. What
is the compound
A. KMnO4 ✓ B. Ethanol
C. Ethene D. CH3CH2Cl
Q.5 Denaturing of alcohol is done by adding methanol in ethanol:
✓ A. 10% B. 20%
C. 30% D. 40%
Q.6 Methanol is prepared from CO and H2using catalyst:
A. ZnO B. Cr2O3
C. Pt ✓ D. Ni
Q.7 Treatment of a secondary alcohol with a suitable oxidizing agent (K2Cr2O7) results in the forma on of
✓ A. ketone B. aldehyde
C. ether D. alkyl halide
Q.8 The acid without carboxyl group is
✓ A. Picric acid B. Oxalic acid
C. Fumaric acid D. None of them
Q.9 Glucose forms a silver mirror with Tollen's reagent. This shows the presence of:
✓ A. Aldehyde group B. Carboxyl group
C. Keto group D. Hydroxyl group
Q.10 The formula of secondary alcohol is
A. R - OH B. R - CH2OH
✓ C. R2CHOH D. R3COH
Q.11 Ethanol can be converted into ethanoic acid by
A. Hydrogena on B. Hydra on
✓ C. Oxida on D. Fermenta on
Q.12 Methyl alcohol is not used
A. As a solvent B. For denaturing of ethyl alcohol
C. As an an -freezing agent ✓ D. As a subs tute for petrol
Q.13 When acetaldehyde is treated with hydroxylamine the medium should be:
A. Highly basic B. Moderately acidic
✓ C. Highly acidic D. Neutral
Q.14 Which one is primary alcohol?
_______________________________________________________________________________________
A. Buten-2-ol B. Propan-2-ol
✓ C. Butane-1-ol D. 2,3-Dimethylhexane-4-ol
Q.15 Aldol condensa on is a reac on of cold dilute solu on of alkali with:
A. all ketones B. all aldehydes
✓ C. aldehydes and ketones with D. aldehydes with α-hydrogen
Q.16 Aldol condensa on will bot be observed in:
✓ A. Chloral B. Hexanal
C. Phenyl acetaldehyde D. Ethanal
Q.17 Aldehyde is dis nguished from ketone by using:
A. tollen's reagent B. felling solu on
C. benedict regent ✓ D. all above
Q.18 Which one is not-reducing sugar
A. Glucose B. Fructose
✓ C. Sucrose D. Galactose
Q.19 Dow's process is used for the prepara on of
A. esters B. ethers
C. alcohols ✓ D. phenols
Q.20 The hydrolysis of sugar is called
A. Condensa on B. Polymeriza on
✓ C. Inversion D. Reduc on
Q.21 Alcohol of low molecular weight are
✓ A. Soluble in water B. Soluble in water on hea ng
C. Insoluble in water D. Insoluble in all solvents
Q.22 Which compound shows hydrogen bonding
A. C 2H 6 ✓ B. C2H5Cl
C. CH3- O - CH3 D. C2H2OH
Q.23 Which of the following compounds are compara vely inert
A. Alcohols ✓ B. Ethers
C. Phenols D. Carboxylic acids
Q.24 Use of ethanol as:
A. Drink B. Solvent and fuel
C. In beverage ✓ D. All of these
Q.25 The addi on of HCN to carbonyl compounds is an example of:
A. Nucleophilic subs u on ✓ B. Nucleophilic addi on
C. Electrophilic addi on D. Electrophilic subs tu on
Q.26 Phenol reacts with acetyl chloride to form
A. An aldehyde B. A ketone
C. An ether ✓ D. An ester
Q.27 Which is most acidic
✓ A. H 2O B. CH3OOH
C. C2H5OH D. CH3-CH2-CH2OH
Q.28 Alcohol used as drink is:
A. methanol ✓ B. ethanol
C. propanol D. butanol
Q.29 Starch is converted into sucrose in the presence of enzyme:
A. Invertase B. zynase
✓ C. Diastase D. Maltase
Q.30 the purity of alcohol obtained from fermenta on is:
A. 10-12% ✓ B. 12-14%
C. 14-16% D. 16-18%
_______________________________________________________________________________________
Q.31 2,3 dihdroxy butanedioc is the IUPAC name of
A. Lac c acid B. Citric acid
✓ C. Tartric acid D. Valeric acid
Q.32 Dehydra on of alcohols by conc. H2SO4 at 170 C° involves
A. Free radical inter mediate ✓ B. Carboca on intermediate
C. Carbanion D. Expulsion of OH-ion
Q.33 Reac on of ethanol with HCl gives water and:
✓ A. Ethyl chloride B. Methyl chloride
C. Propyl chloride D. Iso propyl chloride
Q.34 Iodoform crystals are of colour in iodoform test:
A. Orange B. Blue
C. Green ✓ D. Yellow
Q.35 An oxygen containing organic compound upon oxidation forms a carboxylic acid as the only organic
product with its molecular mass higher by 14 units. The organic compound is ______.
A. A ketone B. An aldehyde
✓ C. A primary alcohol D. A secondary alcohol
Q.36 Methanol can be prepared:
A. From water gas B. From dis lla on of wood
C. From oxida on of methane ✓ D. All
Q.37 Deposi on of Cholesterol in arteries is responsible for
A. Cancer B. Diabetes
✓ C. Heart a ack D. Hepa ts
Q.38 General formula of alcohol is:
✓ A. ROH B. Ar-OH
C. R-O-R D. Ph-OH
Q.39 Reac on in which phenol differs from alcohol is
A. Salt forma on B. Amine forma on
C. Ester forma on ✓ D. Iodoform forma on
Q.40 95% alcohol is called
✓ A. Rec fied spirit B. Spirit of wine
C. Spirit D. Methylated
Q.41 Alcohols are:
A. sweet in smell B. burning in taste
C. colourless liquids ✓ D. All of these
Q.42 The process in which alcohols are converted to aldehydes and ketone is of alcohols:
A. reduc on ✓ B. oxida on
C. addi on D. subs tu on
Q.43 Which compound is more soluble in water
✓ A. CH5OH B. C6H5OH
C. CH3- O - CH3 D. n-Hexanol
Q.44 Which of the following reagents is used to dis nguish between acetophenone and benzophenone?
✓ A. I2and Na2CO3 B. aqueous solu on of NaHSO3
C. benedict solu on D. 2,4-Dinitrophenyl hydrogen
Q.45 Dehydra on of an alcohol at 180°
✓ A. Alkene B. Ether
C. Ester D. An hydride
Q.46 Reac on of ter ary butyl bromide with sodium methoxide produces
A. Sod. Ter ary butoxide ✓ B. Ter ary butyl methyl ether
C. Secondary butyl methyl ether D. Isobutane
Q.47 Carbolic acid was first obtained from coal tar in 1834 by
_______________________________________________________________________________________
A. Haffman B. Faraday
✓ C. Runge D. Kekube
Q.48 Acetone is prepared by:
A. Oxida on of n-propyl alcohol ✓ B. Pyrolysis of calcium acetate
C. Oxida on of acetaldehyde D. Pyrolysis of calcium formate
Q.49 Trihydric alcohols have hydroxyl groups:
A. One B. Two
Q.50 Oxida on of ethanol gives:
A. Formaldehyde ✓ B. Acetaklehyde
C. Acetone D. Anyoldehyde or ketone
Q.51 Ethyl alcohol may be iden fied by
A. ring test ✓ B. Iodoform test
C. tollen's test D. Bazeyer's test
Q.52 Bakelite is a:
A. Monomer B. simple molecule
C. Minor molecules ✓ D. Macromolecule or adduct
Q.53 Acid catalysed hydration of alkenes except ethene leads to the formation
A. Mixture of secondary and tertiary alcohols B. Mixture of primary and secondary alcohols
✓ C. Secondary or tertiary alcohol D. Primary alcohol
Q.54 Which alcohol is resistant to oxida on?
A. Monohydric B. Primary
C. Secondary ✓ D. Ter ary
Q.55 The method to prepare ether is:
A. Dow's ✓ B. William son's synthesis
C. Markovnlkov's D. Frankland
Q.56 Which of the following aldehyde will undergo Cannizzaro's reac on?
A. Ethanol B. 2,2-dinethylpropanal
C. 2-methylpropanal ✓ D. Phenylacetaldehyde
Q.57 The equimolar quan es of methanol and ethanol are heated with conc,H2SO4 the product (s) formed is
A. CH3OCH3 B. CH3OC2H5
C. (C2H5)2O ✓ D. All of these
Q.58 Reac on between ethyl alcohol and Grignard's regent gives:
✓ A. Methane B. ethane
Q.59 Ethanole reacts with sodium metal to liberate
A. CO2gas ✓ B. H2gas
C. CO gas D. Steam
Q.60 Which of the following cannot be produced by acidic dehydra on of alcohols?
A. Ethers ✓ B. Aldehyde
C. Alkyl Hydrogen sulphate D. Alkene
Q.61 Carbolic acid is the other name for
A. Methanol B. Ethanol
C. Propanol ✓ D. Phenol
Q.62 Trivial name of 2-propanol is
A. Hydrenol ✓ B. Isopropyl alcohol
C. Tert-propanol D. None
Q.63 By products formed, when ethanol reacts with PCl5
A. H3PO4 B. H3PO3
C. POCl3+ H3PO4 ✓ D. POCl3+ HCl
_______________________________________________________________________________________
Q.64 Boiling point of phenol is
A. 41 C° B. 68.5 C°
✓ C. 182 C° D. None of these
Q.65 The enzyme not involving in the fermenta on is
A. Diastase B. Zymase
✓ C. Urease D. Invertase
Q.66 Aldehydes can be synthesized by the oxida on of:
A. Primary alcohols B. Secondary alcohols
✓ C. Hydrogen D. Oxygen
Q.67 Which of the following is known as wood spirit
✓ A. Methyl alcohol B. Ethyl alcohol
C. Prophyl alcohol D. Butyl alcohol
Q.68 Which compound would undergo undergo nucleophilic addi on?
A. ethene, C2H4+ B. bromoethane, C2H5Br
✓ C. ethanal, CH3CHO D. etane, C2H6
Q.69 Which of the following is capable of ac ng as hypno c?
✓ A. Acetaldehyde B. Paraldehyde
C. Metaldehyde D. Formaldehyde
Q.70 Which of the following compound has not unsatura on
A. Methanal ✓ B. Methoxy methane
C. Phenol D. Benzoic acid
Q.71 To prepare the ethanol by fermenta on the op mum temperature is
A. 10 - 20°C ✓ B. 25 - 30°C
C. 20°C D. 35°C
Q.72 Salol is prepared from
✓ A. Salicylic acid and phenol B. Salicylic acid and methyl alcohol
C. Both D. None
Q.73 2, 4, 6-Trinitrophenol is commonly called as
A. Phthalic acid B. Tartaric acid
C. Malonic acid ✓ D. Picric acid
Q.74 Per hydro cyclopentanone phenantherene is the basic structural of all the
A. Waxes B. Vitamins
C. Proteins ✓ D. Steroid
Q.75 One gram of Carbohydrate yields energy
✓ A. 4 K cal B. 9 K cal
C. 10 K cal D. 100 K cal
Q.76 Oxida on of Ter-alcohol gives:
A. Aldehyde B. Formaldehde
✓ C. Ketone D. Alenes
E. Alkanes
Q.77 The common industrial solvent is a mixture of propanone. CH3COCH3. and pentyl ethanoate CH3CO2(CH2)4CH3.
Which reagent would have no effect on this solvent?
✓ A. Na(s) B. NaBH4
C. NaOH(aq) D. 2,4-dinitrophenylhydrazine reagent
Q.78 Temperature required for the dehydra on of ethanol in the presence of H2SO4to get ethene
A. 160°C B. 170°C
C. 175°C ✓ D. 180°C
Q.79 Aldehydes a er cataly c reduc on change to
✓ A. P° alcohol B. S° alcohol
C. T° alcohol D. P° and S° alcohol
_______________________________________________________________________________________
Q.80 Which alcohol is most reac ve when electrophilic a acks occur
✓ A. CH3OH B. P°-alcohol
C. S°-alcohol D. t°-alcohol
Q.81 In Fehling's solu on test Aldehydes give_______precipitate:
✓ A. Red B. Black
C. Green D. White
Q.82 Rec fied spirit is re-dis lled in the presence of
A. Ca(OH)2 ✓ B. CaO
C. Cao + NaOH D. NaOH
Q.83 Absolute of alcohol is obtained by adding rec fied spirit in alcohol:
A. Water B. Na2CO3
C. NaOH ✓ D. CaO
Q.84 Propanal reacts Tollen's reagent to form:
A. Ag2O + C2H5COOH B. Ag + C3H7OH
✓ C. Ag + C2H5COOH D. Ag + CH3CHO
Q.85 Which is deriva ve of water
A. Phenol B. Ether
C. Alcohol ✓ D. ACl
Q.86 The vola le liquid is:
✓ A. Ethers B. Phenol
C. water D. alkalies
Q.87 When CO reacts with H2 in the presence of catalyst to produce:
A. Ethanol ✓ B. Methanol
C. Butanol D. Propanol
Q.88 Which of the following is an isomer of ethanol?
✓ A. CH3OCH3 B. C2H5OC2H5
C. CH3OH D. C2H5OH
Q.89 Point out the use of formaldehyde among the following:
A. for manufacturing of resins B. 40% aqueous solu on (Formaline) as
C. for manufacturing of days ✓ D. all above
Q.90 Which is not the enzyme involved in the prepara on of ethyl alcohol by fermenta on of starch
A. diastase B. maltase
C. zymase ✓ D. invertase
Q.91 Williamson's synthesis is used to prepare
✓ A. diethylether B. phenolphthalein
C. hydrogena on D. Bakelite
Q.92 Alcohols reacts with Grignard reagent to form
C. Alkynes D. All
Q.93 C2H5OH on reac on with CH3MG Br forms
✓ A. CH4 B. C 2H 6
C. C2H5OH D. C2H5OCH3
Q.94 Alcohols, phenols and ethers may be considered as deriva ve of
A. hydrocarbons B. benzene
C. carboxylic acids ✓ D. water
Q.95 The boiling points of alcohols are higher than the corresponding alkanes. This is because
✓ A. of hydrogen bonding exis ng between B. alkanes are dipolar compounds
molecules of alcohols
C. alcohols are sweet in taste
D. alcohols are soluble in water
Q.96 Which statement is incorrect for phenol
_______________________________________________________________________________________
A. It is par ally soluble in water B. It do not effect the litmus paper
C. It used as disinfectant ✓ D. None of these
Q.97 The compound used an an freeze in radiators of automobiles:
✓ A. methanol B. formaldehyde
C. acetaldehyde D. phenol
Q.98 Which is the general formula for aidehydes?
A. CnH2n+ 2O B. CnH2nOH
C. CnH2n + 1O ✓ D. CnH2nO
Q.99 How many secondary alcoholic groups are present in the structure of glucose, OHC CHOH CHOHCH OH CHOH CH2OH
A. 1 B. 2
C. 3 ✓ D. 4
Q.100 Which of the following undergoes easy dehydra on
A. 3-Methylbutan-2-ol B. Ethanol
✓ C. 2-Methylpropan-2-ol D. Methanol
Q.101 The weakest acidic characteris cs are of
A. carboxylic acid B. phenol
C. water ✓ D. alcohol
Q.102 The strongest acid among the given is:
✓ A. Carboxylic acid B. Phenol
C. Water D. Alcohol
Q.103 Which compound shows maximum hydrogen bonding with water?
✓ A. CH3OH B. C2H5Cl
C. CH3-O-CH3 D. C2H5OH
Q.104 Alcohols of low molecular weight are

✓ A. Soluble in water B. Soluble in water on hea ng
C. Insoluble in water D. Insoluble in all solvents
Q.105 Methyl alcohol possesses
A. Poisonous B. Burning taste
C. Cause blindness ✓ D. All above
Q.106 Phenoal is also known as
A. Hydroxy benzene ✓ B. Carbolic acid
C. Cumen D. Both A and B
Q.107 Ethanol reacts with ammonia in presence of THO2 it gives
A. Ethylamineq B. Diethylamine
C. Triethylamine ✓ D. All of the above
Q.108 Which enzyme is not involved in the fermenta on of starch
A. Zymase B. Maltse
C. Diastase ✓ D. Invertase
Q.109 Phenol reacts with Conc.HNO3 on hea ng to give?
A. o-Nitro phenol B. p-Nitro phenol
C. M-Nitro phenol ✓ D. Picric acid
Q.110 Alcohols are classified based upon :
A. Number of hydroxyl groups ✓ B. Nature of carbon to which ----OH group is
a ached
C. Type of hydroxyl group a ached D. Number of line pair in ----OH group
Q.111 CH3CH2COCH2CH3 reacts with hydrogen cyanide to form a cyanohydrin:
Which featured apply to the product?
A. it has one chiral center B. it is formed by electrophilic addi on
C. it is formed via a C-OH intermediate ✓ D. it is forma on requires the use of cyanide
ions as a catalyst
Q.112 The intermediate in acid catalysed dehydra on of alcohol is
_______________________________________________________________________________________
A. Carbene B. Carbanion
✓ C. Carboca on D. Free radical
Q.113 Diethyl ether is obtained by willian son's synthesis using
A. Methanol + Na + CH3Br B. Methanol + Mg + CH3Br
✓ C. Ethanol + Na + C2H5Br D. Ethanol + Mg + C2H5Br
Q.114 The test used for the detec on of ethanol in the mouth of a drunk driver is that the drunk driver is asked to blow air
from mouth into a solu on of K2Cr2O7and H2SO4. The colour changes, if the driver is drunk
✓ A. from orange to green B. from pink to green
C. from orange to colourless D. from pink to colourless
Q.115 Acetone reacts with HCN to form a cyanohydrin it is the example of:
✓ A. nucleophilc addi on B. nucleophilic subs tu on
C. electrophilic addi on D. electrophilic subs tu on
Q.116 Phenols are reac ve:
✓ A. Less B. Medium
C. Most D. Both less and more
Q.117 Anisole can be prepared by the action of methyl iodide on sodium phenate. The reaction is called
A. Fittig’s reaction ✓ B. Williamson’s reaction
C. Wurtz’s reaction D. Etard’s reaction
Q.118 Phenol reacts with alkalis forming salts in a type of reac on:
C. Sponifica on ✓ D. Neutraliza on
Q.119 As ester is prepared by the reac on of
A. Ketone and alcohol B. Aldehyde and alcohol
C. Two alcohols ✓ D. Carboxylic acid and alcohol
Q.120 Denatura on of alcohol can be done by the addi on of
A. Methanol B. Pyridine
C. Acetone ✓ D. All
A. as a solvent B. as an an -freezing agent
✓ C. as a subs tute for petrol D. for denaturing of ethyl alcohol
Q.122 Phenol is used in the prepara on of
A. Bakelite B. phenantherene
C. cellulose ✓ D. all of these
Q.123 Dow's method is used to prepare:
C. Ether ✓ D. Phenol
Q.124 Para aldehyde is a trimer of:
A. Formaldehyde B. Benzaldehyde
✓ C. Acetaldehyde D. Propionaldehyde
Q.125 Sponifica on is the hydrolysis of fats or oil with an
✓ A. Alkali B. Base
C. Enzyme D. Metallic ion
Q.126 Ethanol can be converted into ethanoic acid by:
A. Hydrogena on B. Hydra on
✓ C. Oxida on D. Fermenta on
Q.127 Phenol is a deriva ve and has a resemblance in structure to:
✓ A. Water B. Oxides of lithium
C. Oxides of magnisium D. Oxides of aluminium
Q.128 Rec fied alcohol may be denaturated by the addi on of
✓ A. methyl alcohol B. acetone
_______________________________________________________________________________________
C. pyridine D. any of the above reagent
Q.129 Which test can be used dis nguish primary, secondary & ter ary alcohol
A. Siluer minor test B. Iodoform test
C. Borax bead test ✓ D. Lucus test
Q.130 Alcohol fermenta on is brought about by the ac on of
A. CO2 B. O2
C. Invertase ✓ D. Yeast
Q.131 Which is not property in ether:
A. Very weak B. high b.p hydrogen bonding
C. Slightly soluble ✓ D. Inflammable
Q.132 Ethanal, CH3CHO, and be reduced using an aqueous methanolic solu on of naBH4 as the reducing agent.
This is a nucleophilic addi on reac on.
What could be the first step of this mechanism?
A. a ack of +ion at the carbon atom of the B. a ack of +ion at the oxygen atom of the
an H carbonyl group an H carbonyl group
✓ C. a ack of -ion at the carbon atom of the D. a ack of -ion at the oxygen atom of the
an H carbonyl group an H carbonyl group
Q.133 If the nucleophile a acks the alcohol then the bond first breaks
A. C-H B. O-H
✓ C. C-O D. None
Q.134 In Dow's method, phenol can be made from
✓ A. chlorobenzene B. benzene
C. toluene D. benzene sulphonic acid
Q.135 The reac on of sodium with ethanol gives
A. CH3OH B. NaH
C. H 2O ✓ D. H2
Q.136 In the light of IUPAC system aldehydes are named as:
A. alkanes B. alkenes
C. alkanols ✓ D. alkanals
Q.137 Methyl alcohol is not used:
A. As solvent B. As an an -freezing agent
✓ C. As a subs tute for petrol D. For denaturing of ethyl alcohol
Q.138 Which of the following alcohol is least soluble in water
A. CH3OH B. C2H5OH
C. C3H7OH ✓ D. C4H9OH
Q.139 Ketones are the first oxida on products of:
A. Primary alcohols B. Ter ary alochols
C. Carboxylic acid ✓ D. Secondary alcohols
Q.140 Methylated spirit is obtained by mixing in alcohol:
A. Methyl alcohol B. Pyridine
C. acetone ✓ D. All of these
Q.141 Which is a reagent for Lucas test?
✓ A. ZnCl2+ Conc. HCl B. Zn
C. Na D. Br
Q.142 Ethyl alcohol containing 10% methanol is known as
A. Rec fied spirit B. Spirit of wine
C. Spirit ✓ D. Methylated spirit
Q.143 Methanol is manufactured by
A. Fermenta on B. Dis lla on
✓ C. Both a and b D. None of above
Q.144 Dis lla on of fermented alcohol to rec fied spirit have purity:
A. 80% B. 85%
_______________________________________________________________________________________
C. 90% ✓ D. 95%
Q.145 The hydroxyl deriva ves of aroma c hydrocarbons which have the -OH group directly bonded to the ring C-atom are
called
A. alcohols B. ketones
C. esters ✓ D. phenols
Q.146 Which of the following alcohol is more soluble is H2O
✓ A. Propanol B. Butanol
C. Pentanol D. Hexanol
Q.147 An alcohol with molecular formula CnH2n+1OH has a chiral carbon atom but does not react with MnO4-/H+what is the
least number of carbon atoms such an alcohol could possess
A. 5 B. 6
✓ C. 7 D. 8
Q.148 Oxida on of a secondary alcohol gives
✓ A. Ketone B. Ether
C. Aldehyde D. Organic acid
Q.149 What will react differently with the two isomeric pentols, (CH3)3 CCH2OH and (CH3)2CH CH2CH2OH.
A. Acidified (aq) KMnO4 ✓ B. Concentrated H2SO4
C. PCl5 D. Sodium
Q.150 Denatured spirit is mainly used as
A. Good fuel B. Material in the prepara on of beverages
✓ C. Solvent for varnishes D. Durg
Q.151 2,4,6-trinitrophenol is also called:
A. Stearic acid ✓ B. Pictric Acid
C. Tartaric Acid D. Lac c Acid
✓ A. Forming acid B. Butanoic acid
C. Ace c acid D. None of all
Q.153 Oxida on of ter ary alcohol gives:
A. formaldehyde B. Acetaldehyde
C. acetone ✓ D. An alkene
Q.154 Which compound is called a universal solvent
C. C2H5OH D. CH3- o - CH3
Q.155 Baukelite is a polymer obtained from two monomers
A. phenol and ethanol B. phenol and methanol
✓ C. phenol and methanal D. phenol and acetone
Q.156 Primary and secondary alcohols on ac on of red hot copper give
✓ A. Aldehydes and ketones respec vely B. Ketones and aldehydes respec vely
C. Only aldehydes D. Only ketones
Q.157 Alcohol reacts with halogen acid to produce
A. Alkanes ✓ B. Alkyl halides
C. Ketones D. Aldehyetes
Q.158 Which alcohol may be oxidized to a product which reacts with 2,4- dinitrophenylhydrazine reagent but not with
Fehling's reagent?
C. 2-methylpropan-1-ol D. 2-methylropan-2-ol
Q.159 Methanol is used as solvent for:
A. Fats B. varnishes
C. Oils ✓ D. All of these
Q.160 In IUPAC system of naming alcohol "e" of alkane is replaced by:
_______________________________________________________________________________________
A. "al" ✓ B. "ol"
C. oic-acid D. "one"
Q.161 The residue obtained a er crystalliza on of sugar from concentrated sugar cane juice is:
A. Sugar B. Starch
✓ C. Molasses D. Carbohydrate
Q.162 The malt-sugar in the presence of yeast or invertase gives
A. fructose ✓ B. glucose
C. lignin D. alcohol
Q.163 Which of the following is used to make chloral hydrate?
✓ A. Acetaldehyde B. Formaldehyde
C. Alcohol D. Both a & b
Q.164 Ethyl alcohol is industrially prepared from ethylene by
A. Permanganate oxida on B. Cataly c reduc on
✓ C. Absorbing in H2SO4 followed by hydrolysis D. Fermenta on
Q.165 Acetaldehyde and formaldehyde differ from each other when react with:
A. Fehling solu on B. ammonical AgNO3
✓ C. ammonia D. shiff's reagent
Q.166 Fermenta on of sugar and starch yields:
✓ A. Ethanol B. Methanol
C. Butanol D. Propanol
Q.167 Which compound shows more hydrogen bonding?
A. C 2H 4 B. C2H5CI
C. CH3-O-CH3 ✓ D. C2H5OH
Q.168 alcohols are colourless:
A. gases B. liquids
C. solids ✓ D. only lower alcohols are liquids
Q.169 Ethanol in Pakistan is prepared from fermenta on of:
A. Starch B. Sugar
C. Glucose ✓ D. Molasses
Q.170 Which structure shows a ter ary alcohol
A. CH3CH2OH B. (CH3)2CHOH
✓ C. (CH3)3COH D. CH2OH
Q.171 The word 'al' is used for:
A. alkane B. alcohol
C. ketone ✓ D. aldehyde
Q.172 absolute alcohol is obtained from rec fied spirit by
✓ A. Redis lla on B. Recrystallisa on
C. Solvent extrac on D. Chromalography
Q.173 Acetaldehyde cannot exhibit:
A. Iodoform test B. Benedict's test
✓ C. Lucas test D. Tollen's test
Q.174 Compound x changes the colour of acidified sodium dichromate (Vl) from orange to green. 1 mol of x react with 2 mol
of HCN(g). what could x be?
A. CH3COCH2COCH3 B. CH3CH2CH2CHO
C. H2C = CHCH2CHO ✓ D. OHCCH2CH2CHO
Q.175 Which compound contains OH in their molecule
A. Ether B. Ether
C. Phenol ✓ D. Alcohol and phenol
Q.176 How many alcohols (including both structural isomers and stereoisomers) can have the molecular formula C4H10O.
A. 3 B. 4
_______________________________________________________________________________________
✓ C. 5 D. 6
Q.177 Reac on of ethyl alcohol with ammonia gives water and:
A. Ethyl chloride B. Methyl chloride
C. Propyle chloride ✓ D. Ethyle amine
Q.178 The product of the reac on between propanone and hydrogen cyanide is hydrolysed under acidic condi ons.
What is the formula of the final product?
A. CH3CH(OH)CO2H B. CH3CH2CH2CO2H
C. (CH3)2CHCONH2 ✓ D. (CH3)2C(OH)CO2H
Q.179 Which of the following compounds which will not give iodoform test on treatment with 1/2 NaOH?
A. Acetaldehyde B. Butanone
✓ C. 3-Pentanone D. Acetone
Q.180 100% pure alcohol is called
A. Methylated spirit B. Rec fied spirit
C. Power alcohol ✓ D. Absolute alcohol
Q.181 Nitra on of phenol gives
A. o-Nitrophenol B. m-Nitrophenol
C. p-Nitrophenol ✓ D. Both o and p-nitrophenol
Q.182 Which of the following is more reac ve where O - H bonds break
✓ A. P° alcohol B. S° alcohol
C. T° alcohol D. Cannot be predicated
Q.183 Reac on of 2-methyl-2-propanol is infect a type of reac on:
A. oxida on B. Reduc on
C. subs tuion ✓ D. elimina on
Q.184 Hept-4 enal is present in cow's milk.
CH3CH2CH=CHCH2CH2CHO
✓ A. with H2/Ni CH3(CH2)5CH2OH B. with H2/ Ni CH3(CH2)5CH3
C. with NaBH4 CH3(CH2)5CH2OH D. with NaBH4 CH3(CH2)5CHO
Q.185 Which one of the following reacts immediately with conc. HCl in the presence of ZnCl2?
A. primary alcohol B. secondary alcohol
✓ C. ter ary alcohol D. ether
Q.186 1-Propanol and 2-propanol can be best dis nguished by
A. Iodoform test B. Lucas test
✓ C. Both a and b D. Dehydra on
Q.187 Starch gives ______ color with codine
✓ A. Blue B. Green
C. Red D. Yellow
Q.188 Which enzyme is not involved in fermenta on of starch
Q.189 Mild oxida on of glycerol with H2O2/FeSO gives
A. Glyceraldehyde B. Dihydroxy acetone
✓ C. Glycerose D. None
Q.190 When phenol is reduced in the presence of Zn dust, we get
A. cyclohexene B. cyclohexane
✓ C. benzene D. benzyne
Q.191 The compound used as disinfectant in hospitals and washrooms:
A. Nacl B. ester
✓ C. Phenol D. Ethanol
Q.192 Which of the following is weakly acidic in nature
A. alcohol ✓ B. phenol
_______________________________________________________________________________________
C. aldehyde D. amide
Q.193 Cannizzaro's reac on is not give by:
A. Trimethyl acetaldehyde B. Benzaldehyde
✓ C. Acetaldehyde D. Formaldehyde
Q.194 Hydrogen passed through phenol at 150 C, in the presence of -----catalyst gives cyclohexanol..
A. Tin ✓ B. Nickel
C. Iron D. Sodium
Q.195 In alcohols, R- represents in general formula:
✓ A. Alkyl group B. Aryl group
C. Phenyl group D. Benzyl group
Q.196 When phenol is reduced in the presence of Zinc dust, we get
A. Cyclohexane B. Benzyl alcohol
✓ C. Benzene D. Cyclohexene
Q.197 Cannizzaro reac on involves:
A. Oxida on of aldehydes ✓ B. Oxida on as well as reduc on of aldehyde
molecule
C. Reduc on of aldehyde molecule D. Rearrangement in aldehyde molecule
Q.198 Phenol is:
A. colourless B. crystalline solid
C. Deliquescent solid ✓ D. All of these
Q.199 The poisonous compound is
A. NaCl B. Ester
✓ C. Phenol D. Ethanol
Q.200 Ter ary alcohols produces ______ with acidified KMnO4
A. Ketones B. Aldehydes
C. Malonic acid ✓ D. Alkene
Q.201 Which of the following is a strong acid
A. CH3COOH ✓ B. Cl - CH2COOH
C. C2H5OH D. Phenol
Q.202 Which is possible in ethers:
A. Reac vity high B. Oxida on and reduc on
C. Reac vity towards bases ✓ D. Towards acids
Q.203 Which molecule has not hydrogen bonding in them?
A. alcohol B. water
C. HF ✓ D. Eathers
Q.204 In alcohols, hydrogen of water is replaced by:
C. Alkyl or aryl group D. Phenyl group
Q.205 Which compound will have the repulsion with water?
✓ A. C 6H 6 B. C2H5OH
C. CH3CH2CH2OH D. CH3-O-CH3
Q.206 The organic compounds, alcohols are much closer to, in structure and hence is also called its deriva ve:
Q.207 What is link between m.p & b.p of alcohols with corresponding alcohols?
A. Similar B. Lower
✓ C. Higher D. No regular behaviour
Q.208 Dehydra on of ethyl alcohol yields
A. aldehyde B. ketone
C. acid ✓ D. alkene
_______________________________________________________________________________________
Q.209 Which of the following alcohol is commonly used as anit-freeze
✓ A. Methanol B. Ethanal
C. Propanal D. 2-hexanone
Q.210 Different types of alcohols (pri,sec,ter) are tested by test:
A. Boyer ✓ B. Lucas
C. Iodine D. Starch
Q.211 Solubility of alcohols in water is in:
✓ A. lower alcohols B. medium alcohols
C. high alcohols D. higher alcohols
Q.212 Which compound shows maximum hydrogen bonding with water
C. CH3- O - CH3 D. C6H5OH
Q.213 Bakelite is a polymer obtained from two monomers
A. Phenol and acetone ✓ B. Phenol and methanol
C. Phenol and ethanol D. None of above
Q.214 Which of the following compounds will not react with sodium metal to release hydrogen?
✓ A. CH3CH2CH3 B. CH3CH2OH
C. C6H5OH D. C6H5CH2OH
Q.215 CH3 CH2 COCH2CH3 reacts with hydrogen cyanide to form a cyanohydrin. Which features apply to he product?
A. it has one chiral center B. it is formed by eletrophilic addi on
C. it is forma on requires the use of caynide ions ✓ D. its forma on requires the use of caynide
as a catalyst ions as a catalyst
Q.216 Phenol is heated with CCI4 and alkaline KOH when salicylic acid is produced.The reac on is known as
A. Frledel-Cra reac on ✓ B. Riemer-Tiemann's reac on
C. Rosenmund's reac on D. Sommelet reac on
Q.217 Alcohol used as fuel in some countries:
Q.218 Which of the following will not form when the mixture of calcium acetate and calcium formate is dis lled?
A. Acetone B. Ethanal
✓ C. Propanal D. Methanal
Q.219 Which reagent gives the same visible result propanal and with propan-2-ol?
A. 2,4-dinitrophenylhydrazine reagent ✓ B. acidified potassium dichormate (VI)
C. sodium D. tollens' reagent
Q.220 Which of the following is produced when an aqueous solu on of butan-2-ol is refluxed with dil acidified KMnO4?
A. Butanol B. butanoic acid
✓ C. butanone D. butane
Q.221 Dis lla on of calcium salts of ace c acid and formic acid gives acetaldehyde. What compound would be obtained if
any calcium salt of ace c acid is dis lled?
✓ A. acetone B. propionaldehyde
C. butyraldehyde D. formaldehyde
Q.222 Alcohols react with carboxylic acids to produce the class of compounds known as
A. Grignard's reagent B. esters
✓ C. amides D. none of these
Q.223 According to Lewis concepts the func on of the func on of ZnCI2 in Lucas test
✓ A. Stronger acid than HCI B. Weaker acid than HCI
C. To form RCI D. To foem ROH+2
Q.224 Glucose in the presence of zymase is converted into
A. alcohol B. acid
✓ C. ethyl alcohol D. ketone
Q.225 The IUPAC name of acetone is:
_______________________________________________________________________________________
A. Ethanol B. Butanone
✓ C. Propanone D. Propanal
Q.226 Which type of alcohol among the following are resistant to oxida on
✓ C. Ter ary D. All above
Q.227 Ketones are prepared by the oxida on of:
A. primary alcohol ✓ B. secondary alcohol
C. ter ary alcohol D. none of above
Q.228 Aldehydes and ketones are carbonyl compounds.
Which of them react both with NaBH4 and with Tollens reagent?
A. both aldehydes and ketones ✓ B. aldehydes only
C. ketones only D. neither aldehydes nor ketones
Q.229 Which compound is more soluble in water?
A. C2H5OH ✓ B. C6H5OH
C. CH3OCH3 D. n-Hexanol
Q.230 Phenol is a weak acid. The correct order of acid stength of carboxylic acid, phenol and alcohol is
✓ A. carboxylic acid > phenol > alcohol B. carboxylic acid > alcohol > phenol
C. phenol > carboxylic acid > alcohol D. alcohol > phenol > alcohol
Q.231 Denaturing of alcohol is done with:
✓ A. Methanol B. ethanol
Q.232 Silver mirror test on used for iden fica on of:
A. alcohols B. ester
✓ C. aldehyde D. amines
Q.233 Effect of phenol on litmus paper:
A. Have effect ✓ B. No effect
C. may have effect D. may not have effect
Q.234 Which is not essen al condi on for fermenta on
A. Proper aera on B. Dilu on of solu on
✓ C. Use of preserva ves D. Op mum temperature is 35C°
Q.235 Ethyl alcohol prepared during fermenta on is pure:
A. 10% B. 11%
✓ C. 12% D. 13%
Q.236 General formula of alcohols is:
✓ A. R---H B. R----X
C. R-----COH D. R----CO---R
Q.237 Oxida on of 2-propanol vies:
A. formaldehyde B. Acelaldehyde
✓ C. Acetone D. anyoldehyde or ketone
Q.238 Which of the following undergo reac on with 50% NaOH solu on to give the corresponding alcohol and acid?
A. Phenol B. Butanal
✓ C. Benzaldehyde D. Benzoic acid
Q.239 Which one of the following correctly describes the acid proper es of phenol?
A. stronger than HCl B. stronger than carboxylic acid
C. an acid stronger than carbonic acid ✓ D. an acid weaker than carboxylic acid
Q.240 Denaturing of alcohol is done by adding methanol in the alcohol:
A. 6% B. 7%
C. 8% ✓ D. 10%
Q.241 When phenol is dis lled with zinc dust, it is reduced to
✓ A. benzene B. benzaldehyde
_______________________________________________________________________________________
C. toluene D. hexanol
Q.242 Phenol was discovered by:
A. Hofmann ✓ B. Runge
C. Henderson D. Bakelite
Q.243 Iodoform test is not given by:
✓ A. Methanol B. Ethanol
C. Ethanal D. Ethanone
Q.244 Fermented alcohol is
✓ A. 12% B. 20%
C. 95% D. 100%
Q.245 Ether, an organic compound has close resemblance in structure and thus a deriva ve of:
Q.246 Fermenta on of ethanol is done by enzyme:
A. Invertase ✓ B. zymase
C. Diastase D. Maltase
Q.247 Among the following, which is least acidic?
A. phenol ✓ B. o-cresol
C. p-nitrophenol D. p-chlorophenol
Q.248 Which compound will have maximum repulsion with H2O
✓ A. C 6H 6 B. C2H5OH
C. CH3CH2CH2OH D. CH3- 0 - CH3
Q.249 With the increase in carbon number the solubility of an alcohol
A. increases ✓ B. decreases
C. remains unaffected D. none of these
Q.250 Which compound contains - OH in their molecule
A. alcohol B. phenol
✓ C. alcohol and phenol D. ether
Q.251 Keeping in view the reac ons of aldehydes and ketones choose the incorrect statement:
A. they react with hydroxylamine to from oximes B. they react with to from addi on
4
NaHSO product
✓ C. they reduce with ammonical 3to give D. they react with hydrazine to form hydrazones
AgNO silver
Q.252 Phenol is a weak acid. The correct order of acid strength of carboxylic acid, phenol and alcohol is
A. Alcohol > phenol > carboxylic acid ✓ B. Carboxylic acid > phenol > alcohol
C. Carboxylic acid > alcohol > phenol D. Phenol > carboxylic acid > alcohol
Q.253 Alcohol, phenols and ethers may be considered as deriva ve of
A. Carboxylic acids B. Hydro carbons
✓ C. Water D. Benzene
Q.254 An organic compound A(C4H9Cl) on reaction with Na/diethyl ether gives a hydrocarbon which on
monochlorination gives only onechloro derivative then, A is:
A. Iso-butyl chloride B. Secondary butyl chloride
✓ C. T-butyl chloride D. N-butyl chloride
Q.255 Deriva ve of water is:
A. Alcohols B. Phenols
C. Ether ✓ D. All of these
Q.256 Alcohol used in pharmaceu cal prepara ons and preserva ve for biological specimens is:
Q.257 Alcohol can prepared from alkene by treac ng it with
A. H 2O B. H2SO4
_______________________________________________________________________________________
✓ C. H2SO4+ H2O D. NaOh
Q.258 Most convenient method of removing phenol from a compound is
A. Hea ng strongly with Cu B. Reac on with Zn + HCi
✓ C. Dis lling with Zn dust D. Dry hea ng
Q.259 The organic compounds, not deriva ve of oxygen is:
A. Phenol B. Alcohol
✓ C. Alkyl halide D. Ether
Q.260 Alcohols are hydroxy deriva ves of
✓ A. Alkane B. Benzene
C. Alkene D. Both a and b
Q.261 Methyl alcohol in not used
A. As a solvent B. As an an -freezing agent
Q.262 2-propanol on oxida on yield
A. Propianoldehyde ✓ B. Propanone
C. Propanal D. Both b and c
Q.263 2,4,6 tribromophenol forms when phenol directly reacts with:
A. Hydrogen B. Formaldehyde
C. Nitric Acid ✓ D. Bromine
Q.264 The order of reac vity of HX(X = Cl, Br, I) with ROH is
A. HI < BHr > HCl B. HI > HBr < HCl
C. HI < HBr < HCl ✓ D. HI > HBr > HCl
Q.265 Treatment of a secondary alcohol with a suitable oxidizing (K2Cr2O7) results in the forma on of
A. Aldehyde B. Alkyl halide
✓ C. Ketone D. Ether
Q.266 Which alcohol is most reac ve towards sodium metal
A. ter.Butyl alcohol B. Isopropyl alcohol
✓ C. n-propyl alcohol D. Have same reac vity
Q.267 Ethyl alcohol reacts with PCl3and produces
A. Haloalkane ✓ B. Alkyl halide & H3PO3
C. Alkyl halide & POCl3 D. None of these
Q.268 The compound showing hydrogen bonding is
A. Ethane B. Ethyl chloride
C. Di methyl ether ✓ D. Ethanol
Q.269 Which of the following is the weakest acid
A. Phenol ✓ B. Alcohol
C. Carboxylic acid D. Water
Q.270 The product acetal is produced by reac ng alcohol in the presence of dry HCI with:
✓ A. Acetaldehyde B. Carboxylic acid
C. Ketone D. Ether
Q.271 If a nucleophile a acks alcohol the bond which breaks is
A. O-H ✓ B. C-O
C. Both O-H and C-O D. None of the above
Q.272 Hydroly c conversion of sucrose into glucose and fructose is known as
A. Induc on ✓ B. Inversion
C. Inser on D. Inhibi on
Q.273
Which enzyme is not involved in the fermenta on of starch?
_______________________________________________________________________________________
Q.274 Oxida on of methyl alcohol gives
A. Acids ✓ B. Formaldehyde
C. Acetone D. Ester
Q.275 Forma on is _________ solu on of formaldehyde in water:
A. 20% B. 60%
C. 10% ✓ D. 40%
Q.276 The compound having least solubility in water is:
A. Methanol ✓ B. Acetone
C. Acetaldehyde D. Acetophenone
Q.277 Dehydra on of glycerol give
A. Propane B. Propene
✓ C. Acrolein D. Benzene
Q.278 Rec fies spirit contains concept ethers behave as
✓ A. Acid and base B. Acid
C. Base D. None of these
Q.279 In Lucas test ter ary alcohol make an oily layer
✓ A. Immediately B. In 10 mins
C. On hea ng D. Not
Q.280 An ether is more volatile than an alcohol having the same molecular formula. This is due to
A. Dipolar character of ethers B. Alcohols having resonance structures
C. Inter-molecular hydrogen bonding in ✓ D. Inter-molecular hydrogen bonding in
ethers alcohols
Q.281 Oxida on of methanol gives:
✓ A. formaldehyde B. acetaldehyde
C. Acetone D. anyoldehyde or ketone
Q.282 Compound x will decolourize a worm acidified solu on of manganate (VII) ions and forms orange crystals on reac on
with 2,4-dinitrophenylhydrazine.
What is X?
A. CH3CH=CHCH2OH B. CH3CHOCH2CH3
✓ C. CH3CH2CH2CHO D. CH3CH(OH)CH2CO2H
Q.283 Which of the following compound has maximum solubility with water
A. CH3OH ✓ B. Ethanol
C. C6H5OH D. CH3-CO-CH3
Q.284 Acetone is easily oxidized with:
A. Tollen's reagent ✓ B. Acidic dichromate solu on
C. Fehling solu on D. Benedict's solu on
Q.285 Ethanol can be denatured by the addi on of
✓ A. Methanol B. Pyridine
C. Acetone D. All of these
Q.286 Haloform (iodoform) test is given by
A. Methanol ✓ B. Ethanol
C. 3-pentanone D. 1-propanol
Q.287 In Lucas test primary alcohol make an oily layer
A. Immediately B. In 10 mins
✓ C. On hea ng D. Not
Q.288 According to Lewis concept ethers behave as:
A. Acid ✓ B. Base
C. Acid as well as base D. None of them
Q.289 Sugar cane industry can provide raw material for alcohol and
A. Oxalic acid ✓ B. Paper
C. Plas c D. Fibre
_______________________________________________________________________________________
Q.290 When the 2-pentanol undergoes the oxida on it produces
A. Pentanal B. 3-pentanone
✓ C. 2-pentanone D. Pentanoic acid
Q.291 Picric Acid forms when phenol reacts with:
A. Hydrogen B. Formaldehyde
✓ C. Nitric acid D. Sulphuric acid
Q.292 The carbon atom of a carbonyl group is:
A. Sp-hybridized ✓ B. Sp2- hybridized
3
C. Sp - hybridized D. Unhybridized
Q.293 Hydroxly deriva ve of alkanes is:
A. Phenols ✓ B. Alcohols
C. Ethers D. Alkanes
Q.294 Rancidifica on of fats and oils is due to
A. Oxida on reac on B. Hydrolysis reac on
✓ C. Both a and b D. Hydrogena on reac on
Q.295 Which of the following is used as anesthe c
✓ A. Phenol B. Dimethyl ether
C. Diethyl ether D. Alcohol
Q.296 Which alcohol gives only one oxida on product when wormed with dil acidified K2Cr2O7
A. Butan-1-ol ✓ B. Butan-2-ol
C. 2-methyl propan-1-ol D. 2-methyl propane-2-ol
Q.297 Alcohols are named by replacing 'e' of alkane with:
A. Al B. Ene
✓ C. Ol D. One
Q.298 Alcohol can be denatured by adding:
A. Acetone B. Methanol
C. Pyridine ✓ D. All
Q.299 Oxida on of 2-propanol gives
✓ A. propanone B. butanone
C. pentanone D. none of these
Q.300 Phenol becomes completely soluble in water at
A. 25°C B. 49.1°C
✓ C. 65.9°C D. 100°C
Q.301 Which of these reac on s is shown by butanone,CH3COCH2CH3?
A. On warming with acidified potassium B. On hea ng with Fehling's reagent a red
dichromate(VI) the solu on turns green precipitate is formed
✓ C. With 2,4-dinitrophyendrazine regent an D. with hydrogen cyanide an aldehyde id formed.
orange precipitate is formed
Q.302 If an electrophile a acks then ________ bond breaks first
A. C-H ✓ B. O-H
C. C-O D. None of these
Q.303 The formula of urotropine is:
A. (CH2)4N6 ✓ B. (CH2)6N4
C. (CH2)6N4 D. (CH2)5N5
Q.304 Best halogena ng agent for the conversion of ROH to RCi
A. NCI3 B. HCI
C. PCI5 ✓ D. SOCI2
Q.305 Among the alkenes which one produces tertiary butyl alcohol on acid hydration
✓ A. (CH3)2C = CH2 B. CH3– CH = CH – CH3
C. CH3– CH2– CH = CH2 D. CH3– CH = CH2
Q.306 Which of the following will have the highest boiling point:
_______________________________________________________________________________________
A. methanal B. ethanal
C. propanal ✓ D. 2 - Hexanone
Q.307 An ether is more volatile than an alcohol having the same molecular formula. This is due to
A. Dipolar character of ethers B. Alcohols having resonance structures
C. Inter-molecular hydrogen bonding in ✓ D. Inter-molecular hydrogen bonding in
ethers alcohols
Q.308 The conversion of acetaldehyde into lac c acid takes place by:
A. treatment with HCN followed by oxida on B. reac on with HCN followed by reduc on
✓ C. reac on with HCN followed by acid D. oxida on of acetaldehyde followed by acid
hydrolysis hydrolysis
Q.309 Hydrogen bonding is maximum in
A. Triethylamine B. Diethyl ether
C. Ethyl chloride ✓ D. Ethanol
Q.310 The correct name of H2C = CH-CH2-CH2-OH is
A. 1-butene-4-ol B. 2-butene-1-ol
✓ C. 3-buten-1-ol D. None of these
Q.311 Methanol and ethanol can be dis nguished by
A. Lucaus test B. Flame test
✓ C. Iodoform test D. Dichrometer / H2SO4oxida on test
Q.312 Ethanol can be converted into ethanoic acid by
A. Hydrogena on B. Dehydra on
✓ C. Oxida on D. Hydra on
Q.313 The compound which reacts fastest with Lucas reagent at room temperature is
A. 2-methylpropan-1-o1 ✓ B. 2-methylpropan-2-ol
C. Propan-1-ol D. Propan-2-ol
Q.314 Which of the following can react with Br2 water
A. Alcohol ✓ B. Phenol
C. Ether D. Alkane
Q.315 The hybridiza on state of oxygen in the ether is
A. sp2 B. Sp
C. dsp 2 ✓ D. sp3
Q.316 Which are much closer to each other?
A. Alcohols and alkyl halides ✓ B. Alcohols & Phenols
C. Phenols and ethers D. Phenols and alkyl halides
Q.317 Taste of lower alcohols is:
A. Sweet B. Bi er
C. Our ✓ D. Salty
Q.318 For which of pair of compounds can the members be dis nguished by means of Tollens' test the use of a solu on
containing Ag (NH3)+2)?
✓ A. CH3CHO and CH3COCH3 B. CH3CHOCH3and C2H5COCH3
C. CH3COCH3and CH3CO2CH3 D. CH3CO2and CH3CO2CH3
Q.319 Which of the following reagents will react with the aldehyde and ketones?
A. Tollen's reagent ✓ B. grignard's reagent
C. Fehling reagent D. Benedict's regent
Q.320 The organic compounds which are deriva ve of hydrocarbons due to oxygen are:
A. Aldehydes B. Ketones
C. Carboxylic acid ✓ D. All of these
Q.321 The compound having general formula RCHOR is called:
A. aldols B. diesters
✓ C. acetals D. hemiacetals
Q.322 Rec fied spirit contains alcohol about:
_______________________________________________________________________________________
A. 80% B. 85%
C. 90% ✓ D. 95%
Q.323 In phenol, hydrogen of water is replaced by :
A. Alkyl group B. Aryl group
C. Alkyl or aryl group ✓ D. Phenyl group
Q.324 The reac on in which acetaldehyde is formed from ethanol is called:
A. addi on reac on B. subs tu on reac on
✓ C. oxida on reac on D. reduc on reac on
Q.325 Alcohols can be dis nguished using test:
✓ A. Lucas B. Tollen's
C. Kolb's D. William's
Q.326 Almond essence is used to flavour food. A student tested a sample of almond essence using 2, 4 -DNP reagent and
obtained decoloured crystals which had sharp mel ng point. Which class of compounds gives the test?
A. alcohols ✓ B. aldehydes with α - hydrogen
C. carboxylic acid D. amines
Q.327 Which compound does not show hydrogen bonding with water?
A. CH3OH B. C2H5OH
✓ C. CH3- O - CH3 D. C6H5OH
Q.328 Which one is used as a fuel for internal combus on engines in many European countries and Brazil?
✓ A. C2H5OH B. CH3OH
C. CH3COOH D. C 2H 2
Q.329 Concentra on of ethanol is not possible beyond 95% beacuse
A. Alcohol and water react ✓ B. Azeotrope is formed
C. Hydrogen bonoing accurs D. None of these
Q.330 Phenols are deriva ve of:
C. Alkynes ✓ D. Benzene
Q.331 When 2-pentanol undergoes oxida on the product is
A. Pentanol B. 3-pentanone
✓ C. 2-pentanone D. Pentatnoic acid
Q.332 IUPAC name of diethyl ether is
A. Methoxy B. Methoxy ethyne
C. Ethoxy ethane ✓ D. Ethoxy methane
Q.333 Alcohol are deriva ve of:
✓ A. alkanes B. Alkenes
C. Alkynes D. Benzene
Q.334 Rec fied spirit contains alcohol about
A. 80% B. 85%
C. 90% ✓ D. 95%
Q.335 Higher alcohols are:
✓ A. Least soluble B. less soluble
C. best soluble D. Normal in solubility
Q.336 An adduct forms when phenol reacts with:
A. Hydrogen ✓ B. Formaldehyde
C. nitric acid D. suphuric acid
Q.337 Monohydric alcohols are classified into ______ classes
A. 2 ✓ B. 3
C. 4 D. 5
A. As a solvent B. As an an freezing agent
_______________________________________________________________________________________
Q.339 Acetaldehyde reacts with Felling solu on on hea on for the Precipita on of:
A. CuO B. CH3COOH
✓ C. Cu2O D. CU
Q.340 To prepare ethanol by fermenta on the op mum temp is
A. 10 - 20°C ✓ B. 25 - 35°C
C. 20°C D. 35°C
Q.341 Fermenta on is
C. Reversible D. None of these
Q.342 Which compound is called a universal solvent?
C. C2H5OH D. CH3-O-CH3
Q.343 Phenol dissolves aikalies:
A. slowly B. difficult
C. hard ✓ D. readlly
Q.344 connizzaro's reac on is not given by:
A. trimethlylacetaldehyde B. benzaldehyde
C. formaldehyde ✓ D. acetaldehyde
Q.345 Purifica on of alcohol above 14% is done by:
✓ A. Dis la on B. Crystaliza on
C. Solvent extrac on D. Fitra on
Q.346 The oxida on of which of the following will give ethyl methyl ketone?
A. Propan-2-ol ✓ B. Butan-2-ol
C. Butan-1-ol D. 2-Methylbutane-2-ol
Q.347 Diethyl ether is obtained by Williamsons synthesis using
✓ A. ethanol + Na + C2H5Br B. ethanol + Mg + C2H5Br
C. methanol + Na + CH3Br D. methanol + Mg + CH3Br
Q.348 Propan-1-ol and propan-2-ol can be dis nguished by
A. Oxida on with
4
followed by reac on with ✓ B. Oxida on
2Cr2O7
followed by reac on
alkaline KMnO Fehling solu on with acidic K with Fehling solu on
C. Oxida on by hea ng with Cu followed by D. Oxida on followed by reac on with
2SO4
reac on with Fehling solu on with conc. H Fehling solu on
Q.349 Which enzyme is not involved in fermenta on of starch
✓ A. Urease B. Invertase
C. Diastase D. None of the above
Q.350 Carbolic acid was first of all obtained from coal tar by Runge in:
A. 1830 B. 1831
C. 1832 ✓ D. 1834
Q.351 Oxida on of Ethyl alcohol may produce
A. CH2 = CH2 and CH3CHO B. CH3 - CH3 and CH2=CH2
C. CH2 = CHCOOH and (CH2)2(OH)2 ✓ D. CH3CHO and CH3COOH
Q.352 The organic compounds which are deriva ve of hydrocarbons of oxygen are:
A. Carbohydrates B. Phenols
C. Alcohols ✓ D. All of these
Q.353 Amount of methanol in formalin is
✓ A. 8% B. 52%
C. 40% D. 95%
Q.354 Concentra on of rec fied spirit is:
A. 12% B. 14%
C. 90% ✓ D. 95%
_______________________________________________________________________________________
E. 100%
Q.355 Which of the following is used as anesthe cs?
A. alcohol ✓ B. diethylether
C. phenol D. dimethyl ether
Q.356 When sodium metal reacts with alcohols
✓ A. hydrogen gas evolves B. sodium hydroxide is obtained
C. alcohol is reduced D. alcohol is polymerised
Q.357 Which reagent colud be used to dis nguish between
CH3CH(OH)CH2CHO and CH3COCH2CH2OH?
A. acidified potassium dichromate(VI) B. dilute sulphuric acid
C. 2,4-dinitrophenylhydrazine ✓ D. Fehling's reagent
Q.358 Alcohol are reacted with metallic sodiium to form:
A. Ether B. Phenol
✓ C. Alkoxides D. benzene
Q.359 Monohydric alcohols have hydroxyl groups:
✓ A. One B. Two
C. Three D. Four
Q.360 Iodine number of an oil indicates its
A. Purity B. Acid strength
C. Molecular weight ✓ D. Degree of unsatura on
Q.361 Aniline is a deriva ve of
A. Alkene B. Alkane
C. Alicyclic hydrocarbon ✓ D. Aroma c hydrocarbon
Q.362 CH3CH2COCH2CH3 reacts with hydrogen cyanide to from a cyanohydrin: which features apply to the product?
A. it has one chiral center B. it is formed by eletrophilic addi on
C. it is formed via a C -Oh intermediate ✓ D. its forma on requires the use of caynide ions
as a catalyst
Q.363 Which of the following reagents can give urotropine?
A. Ethanol and ethylamine ✓ B. Methanol and ammonia
C. Methanol and H2SO4 D. Methanol and 50% NaOH
Q.364 A compound 'z' decolorizes bromine water and produces white ppt. The compound 'z' is
A. Alkane B. Alcohol
✓ C. Phenol D. Benzene
Q.365 Ethanol containing some methanol is called
A. Absolute spirit B. Rec fied spirit
C. Power alcohol ✓ D. Methylated spirit
_______________________________________________________________________________________
17 Aldehydes and Ketones
Q.1 Which one of the following is a product of the reac on between C6H5CH2OH and CH3COCl?
A. C6H5OCOCH3 B. C6H5CH2Cl
✓ C. C6H5CH2OCOCH3 D. C6H5CH2COCl
Q.2 Formalin contains ______% alcohol
A. 80 B. 37
✓ C. 8 D. 52
Q.3 An equeous solu on of an organic compound reacts with sodium carbonate to produce carbon dioxide gas. Which one
of the following could be the organic compound?
A. CH2= CH - CH3 B. CH3- CHO
C. CH3COOC2H5 ✓ D. CH3- CH2- COOH
Q.4 Which of the following tests is shown by ketones
A. Fehling solu on test B. Tollen's reagent test
C. Schiff reagent test ✓ D. Sodium nitroprousside test
Q.5 Reac on with Grignard's reagent with a;dehydes other than formaldehyde gives: Reac on with Grignard's reacgent
with formaldehyde gives:
A. Pri-alcohol ✓ B. Sec-alcohol
C. Ter-alcohol D. Carboxylic
Q.6 What is main reason for the fact that carboxylic acids can undergo ioniza on?
A. high reac vity of α-hydorgen B. absence of α-hydrogen
C. H-bonding ✓ D. resonance stabiliza on of the carboxylic ion.
Q.7 Forces which explain B.P of aldehydes and Ketones
A. London forces B. Dipole dipole forces
C. Debye forces ✓ D. Both a & b
Q.8 Carboxylic acids can generally be prepared buy various methods. Which of the following methods is not suitable for
making carboxylic acids:
A. by the carbona on of Grignard reagent B. by the oxida on of primary alcohols
✓ C. by the hydrolysis of p-amines D. by the hydrogen of nitrites
Q.9 Ketones are prepared by the oxida on of:
A. Primary alcohol ✓ B. Secondary alcohol
C. Ter ary alcohol D. None of these
Q.10 aldehydes is dis nguished from ketones by using
A. Tollen's reagent B. Benedict reagent
C. Fehling solu on ✓ D. all of the above
Q.11 The carbon of a carbonyl group is:
A. sp hydribized ✓ B. sp2hydribized
C. sp3hydribized D. None of these
Q.12 In which of the following reactions new carbon-carbon bond is not formed[WB JEE 2009]
✓ A. Cannizzaro reaction B. Wurth reaction
C. Aldol condensation D. Friedel-Crafts reaction
Q.13 The carbon atom of a Carbonyl group is
A. Sp-hybridized ✓ B. Sp2-hybridized
_______________________________________________________________________________________
C. Sp3-hybridized D. Unhybridized
Q.14 Which of the following Compounds which will not give iodoform test on treatment with 1/2 NaOH
A. Acetaldehyde B. Butanone
✓ C. 3-Pentanone D. Acetone
Q.15 Aldehyde is dis nguished from ketone by using
A. Tollen's reagent B. Felling solu on
C. Benedict reagent ✓ D. All above
Q.16 A compound Y has the following proper es.
it is a liquid at room temperature and atmospheric pressure
it does not mix completely with water
it does not decolourize acidified potassium manganate(VII)
What could Y be?

A. ethane B. ethanoic acid
C. ethanol ✓ D. ethyl ethanoate
Q.17 Formaldehyde is used to make
A. Plas cs B. Medicine
C. An sep c ✓ D. All of these
Q.18 Acetone one cataly c hydrogena on produces
C. n-Propanol ✓ D. iso propyl alcohol
Q.19 Which pair of compounds is formed when the ester C2H5CO2CH is boiled with aqueous sodium hydroxide?
A. C2H5CO2H CH3OH B. C2H5CO2Na CH3ONa
✓ C. C2H5CO2Na CH3OH D. C2H5OH CH3CO2Na
Q.20 When aldehyde reacts with Tollen's reagent
A. A ketone is produced B. An alcohol is produced
C. Ag+ions are produced ✓ D. Ag+ions are reduced
Q.21 Which one of the following deriva ves an not be prepared directly from ace c acid?
✓ A. acetamide B. acetyl chloride
C. ace c anhydride D. ethyl acetate
Q.22 Which is more reac ve towards nucleophilic addi on reac ons
✓ A. HCHO B. CH3CHO
C. CH3-CO-CH3 D. CH3CH2CHO
Q.23 C = O and C = C bonds are differen ated by
A. Hybridiza on of C-atom B. Planar structures
✓ C. Bond length D. Bond angles
Q.24 Carbonyl compounds undergo nucleophilic addi on because of
A. More stable anion with nega ve charge on B. Electrometric effect
oxygen and less stable carboca on
✓C. Electro nega vity difference of carbon and
oxygen atoms
D. None of these
Q.25 Which is used for the reduc on of aldehydes and ketones
✓ A. NaBH4 B. Pt/Pd
C. Ni D. All of these
Q.26 Which of the following is used in baking powder:
A. Citric acid B. Lac c acid
✓ C. Tartaric acid D. Oxalic acid
Q.27 During the mechanism of aldol condensa on a/an _______ is formed
A. Oxide B. Alkali
✓ C. Alkoxide ion D. None of these
Q.28 Suitable reducing agent for aldehyde is
A. Na2CO3 B. KMnO4
_______________________________________________________________________________________
✓ C. NaBH4 D. Na BH2
Q.29 Acetaldehyde ammonia is used as
A. As fungicides B. Making formamint
✓ C. Rubber accelerator D. Decolorizing agent
Q.30 Aldehyde and ketone have higher boiling point than corresponding compounds of the following except
A. Alkeanes B. Alkenes
C. Ethers ✓ D. Alcohols
Q.31 Aldehydes give reac ons:
A. Oxida on and reduc on B. Base-catalysed nucleophilic
✓ C. Acid catalysed nucleophilic D. All of these
Q.32 The compound with maximum boiling point is
A. Mathanal B. Ethanal
C. Propanal ✓ D. 2-Hexanone
Q.33 The red brown ppt. of Fehling solu on and benedict solu on test are of
A. Ag B. CuO
✓ C. Cu2O D. AgBr
Q.34 The name glacial ace c acid is given to pure ace c acid:
A. Blew 16.6 C it is white liquid ✓ B. It forms ice like solid below 17 C
C. It is mixed with methanol D. Pure ace c acid above 16.6 C
Q.35 The product of the reac on between propanone and HCH is hydrolysed under acidic condi ons. What is the formula of
the final product?
A. CH3CH(OH)COOH B. CH3CH2CH(OH)COOH
✓ C. (CH3)2C(OH)COOH D. CH3CH2CH2COOH
Q.36 Clemmensen reduction of a ketone is carried out in the presence of which of the following?[CBSE
AIPMT 2011]
A. H2and Pt as catalyst B. Glycol with KOH

✓ C. Zn-Hg with HCl D. LiAlH4
Q.37 Iodoform test is not given by
A. 2-Pentanone ✓ B. 3-pentanone
C. CH3CHO D. Ethanol
Q.38 Which of the following compound will have highest boilling point
C. Propanal ✓ D. 2-hexannone
Q.39 Ethyl alcohol is converted into ace c acid by;
A. reduc on ✓ B. oxida on
C. fermenta on D. hydrogena on
Q.40 Ace c acid exists as dimer in benzene due to:
✓ A. H-bonding B. condensa on
C. presence of carboxylic group D. presence of hydrogen at alpha-carbon.
Q.41 Point out the use of formaldehyde among the following
A. For manufacturing of resins B. 40% aqueous solu on (Formaline) as
C. For manufacturing of dyes ✓ D. All above
Q.42 Carbon of carbonyl group is hybridized
A. SP3 ✓ B. SP2
C. SP D. Unhybridized
Q.43 Which is used to removed ink and rust stains on cloth:
✓ A. Oxalic acid B. Alcohol
C. Ether D. Kerosene oil
Q.44
_______________________________________________________________________________________
Compound 'A' undergoes formation of cyanohydrins which on hydrolysis gives lactic acid
(CH3CHOHCOOH). Therefore, compound 'A' is[DELHI PMT 2010]
A. Formaldehyde ✓ B. Acetaldehyde
C. Acetone D. Benzaldehyde
Q.45 An organic compound X is oxidized by using acidified K2Cr2O7. The product obtained reacts with
phenyl hydrazine but does not answer silver mirror test. The possible structure of X is[Karnataka CET
2009]
✓ A. (CH3)2CHOH B. CH3CHO
C. CH3CH2OH
D.
Q.46 The colour of ppts formed by Fehling's test is
✓ A. Brick red B. Red
C. Yellow D. Orange
Q.47 Which one of the following is resistant to oxida on under normal condi ons
A. Methyl alcohol B. Ethyl alcohol
C. Acetaldehyde ✓ D. Acetone
Q.48 The cataly c promoter used for the industrial prepara on of acetaldehyde is
A. PdCl2 ✓ B. CuCl2
C. Pd + CaCl2 D. None of these
Q.49 Common names of aldehydes are given by corresponding:
A. Ketones B. Alcohol
✓ C. Carboxylic acid D. Ester
Q.50 Which Compounds reacts with its own oxida on product (an oxida on which involves no less of carbon) to give a
sweet-smelling liquid?
Q.51 The conversion of acetaldehyde into lac c acid takes place by
A. Treatment with HCN followed by oxida on B. Reac on with HCN followed by reduc on
C. Reac on with HCN followed by acid hydrolysis ✓ D. Oxida on of acetaldehyde followed by basic
hydrolysis
Q.52 Which of the following contain ketonic group
A. Menthone B. Methanol
C. Comphore ✓ D. Both a and c
Q.53 Calcium acetate on hea ng will produce
A. CH3CHO B. HCHO
✓ C. CH3COCH3 D. All of these
Q.54 Dehydra on of alcohol gives:
A. Alkane B. Alkene
C. Aldehyde ✓ D. Ketone
Q.55 Which of the following reagents will react with the aldehyde and ketones
A. Tollen's reagent ✓ B. Grignard's reagent
C. Fehling reagent D. Benedict's reagent
Q.56 Formaldehyde react react with NH3 to give
A. Tetra ethylene hexamine B. Tetra ethylene tetra mine
✓ C. Hexa methlene tetra amine D. Cyclonite
Q.57 The solu on of with acid is used for seasoning of food:
A. formic acid ✓ B. ace c acid
C. benzoic acid D. butanoic acid
Q.58 Aldol condensa on is actually
A. electrophilic addi on of carbona on B. electrophilic addi on of carbonium ion
_______________________________________________________________________________________
✓ C. nucleophillic addi on of carbona on D. nuclephillic addi on of

Q.59 Acetone reacts with HCN to form a cyanohydrin. It is an example of
A. Electrophilic addi on ✓ B. Nucleophilic addi on
C. Eletrophilic subs tu on D. Nucleophilic subs tu on
Q.60 Which is a mixed ketone
A. Acetone B. Benzophenone
C. Diethyl ketone ✓ D. Acetophenone
Q.61 2-butanol reacts with I2 in presence of NaOH produce
✓ A. CHI3 B. CH2I2
C. CH3I D. All of these
Q.62 Identify the product in the reaction
?[DELHI PMT 2010]
A. PhCH2CH2CHO ✓ B. PhCOCH2CH3
C. PhCH2COCH3 D. PhCOCOMe
Q.63 Which one of the following contains carboxylic groups:
A. picric acid B. carbolic acid
✓ C. glutamic acid D. all above
Q.64 Aldehyde group is protected against alkaline oxidizing agent reac ng with
A. C2H5OH B. NH2OH
C. NH2-NH-C6H5 ✓ D. Ethanol + HCI
Q.65 In Tolten's test, the end product is _________ formed
A. White ppts B. Red ppts
C. yellow ppts ✓ D. Silver mirror
Q.66 Compound X, C6H12O, is us oxidized by acidified sodium dichromate (VI) to compound Y,
Compound Y reacts with ethanol in the presence of a li le concentrated sulphuric acid to give liquid Z.
What is the formula of Z?
A. CH3(CH2)2CH=CHCO2H B. CH3(CH2)4CH2COCH2CH3
✓ C. CH3(CH2)4CO2CH2CH3 D. CH3CH2CO2(CH2)4CH3
Q.67
A. Aldols B. Diesters
✓ C. Acetals D. Hemiacetals
Q.68 Which of the following compounds will not give iodoform test treatment with l2/NaOH
A. Acetaldehyde B. Acetone
C. 2-butanone ✓ D. 3-pentanone
Q.69 the number of carbon atoms in aldehydes and carboxylic acids formed form them are:
✓ A. Same B. Different
C. Unequal D. Unsymmentrical
Q.70 Ketones on reduc on produce
A. P° alcohol ✓ B. S° alcohol
C. T° alcohol D. None
Q.71 What is formed when propanone is refluxed with an anhydrous solu on of NaBH4?
A. Propanal B. Propan-1-ol
✓ C. Propan-2-ol D. Propane
Q.72 Propanal reacts Tollen's reagent to form
_______________________________________________________________________________________
A. Ag2O + C2H5COOH B. Ag + C3H7OH
✓ C. Ag + C2H5COOH D. Ag + CH3CHO
Q.73 Ace c acid is categorized as a weak acid.The reason is that it:
A. has less density B. is less vola le
✓ C. has less dissocia on D. is less viscous
Q.74 Which of the following will have the highest boiling points?
A. Methanol B. Ethanal
Q.75 Which of the following statement is true about formic acid?
✓ A. it is a reducing agent B. it is an oxidizing agent
C. it is weaker than ace c acid D. on hea ng is calcium salt is converted into
ketone
Q.76 Aldehydes react with tollen's reagent forming:
A. Yellow of red ppt B. white ppt
✓ C. Silver mirror D. Brick red
Q.77 Silver mirror test in used for iden fica on of
A. Alcohols B. Ester
✓ C. Aldehyde D. Amines
Q.78 Cannizzarp's reac on is type of reac on:
A. Ketone B. Alcohol
✓ C. Carboxylic acid D. Ester
Q.79 Of the following reac on formic and ace c acid differ in which respect?
A. blue litmus reac on B. forma on of ester with alcohol
C. replacement of hydrogen by sodium ✓ D. reduc on of fehling solu on
Q.80 Which of the following is resistant to oxida on under normal condi on
A. CH3OH B. C2H5OH
C. CH3CHO ✓ D. CH3COCH3
Q.81 Acetone reacts with HCN to form a cyanohydrin. It is the example of
✓ A. Nucleophilic addi on B. Nucleophilic subs tu on
C. Electrophilic addi on D. Electrophilic subs tu on
Q.82 Acetamide is prepared by:
A. the hydrolysis of methyl cyanide B. hea ng ethyl acetate
C. hea ng methyl acetate ✓ D. hea ng ammonium acetate
Q.83 Dis lla on of calcium salts of ace c acid and formic acid gives acetaldehyde. What compound would be obtained if
any calcium salt of ace c acid is dis lled
✓ A. Acetone B. Propionaldehde
C. Butyraldehde D. Formaldehyde
Q.84 Conversion of ethanol into iodoform is
✓ A. Oxida on B. Reduc on
C. Hydrolysis D. Iodina on
Q.85 Silver mirror test is applied for
✓ A. aldehydes B. alcohols
C. acids D. esters
Q.86 The product formed in Aldol condensation is[CBSE AIPMT 2007]
✓ A. A beta-hydroxy aldehyde or a beta- B. An alpha-hydroxy aldehyde or keton
hydroxy ketone
C. An alpha, beta unsaturated ester
D. A beta-hydroxy acid
Q.87 Which of these reac on is shown by butanone, CH3COCH2CH3?
A. On warming with acidified potassium B. On hea ng with Fehling's reagent a red
dichroma ve (VI) the solu on turns green precipitate is formed
✓ C. With 2,4-dinitrophenlhydrazine reagent an D. With hydrogen cyanide an aldehyde is formed
orange precipitate is formed
_______________________________________________________________________________________
Q.88 Which one of the following acids does not contain carboxylic group:
A. lac c acid B. ethanoic acid
C. palmi c acid ✓ D. p-Toluenesulphonic acid
Q.89 Which of the following is semicarbazide
A. NH2NH2 B. NH2OH
✓ C. NH2NHCONH2 D. NH2-NH-C6H3-(NO2)2
Q.90 Acetone reacts with hydrazine in the presence of an acid it gives
A. Acctaldehyde and hydrazone ✓ B. Acetone hydrazine
C. Propanal Hydrazone D. None of these
Q.91 Tollen s reagent will not react with
A. Formaldehyde B. Acetaldehyde
✓ C. Acetone D. Glucose
Q.92 Which of the following can produce ketone
A. Secondary alcohol B. Propyne
C. Calcium acetate ✓ D. All of these
Q.93 Cyanihydrins are formed from carbonyl compounds by ______ reac ons mechanism
A. Free radical B. Nucleophilic subs tu on
✓ C. Nucleophilic addi on D. Electrophilic addi on
Q.94 Ace c acid is manufactured by;
A. fermenta on B. esterifica on
✓ C. dis lla on D. ozoholysis
Q.95 K2Cr2O7 + H2SO4 converts butane into
A. CH3-CH2 COOH B. CH2CH2CH2COOH
✓ C. CH3COOH D. CH3COOH + HCOOH
Q.96 Which of the followings compounds is least reac ve
A. HCHO B. CH3CHO
C. CH3COCH3 ✓ D. C6H5CHO
Q.97 Reac on of Grignard's reagent with formaldehyde gives:
A. Pri-alcohol ✓ B. Sec-alcohol
C. Ter-alcohol D. CArboxylic
Q.98 For making distinction between 2-pentanone and 3-pentanone the reagent to be employed is[WB JEE
2009]
A. K2Cr2O7/H2SO4 B. Zn-Hg/HCl
C. SeO2 ✓ D. Iodine/NaOH
Q.99 aroma c ketones are not given names:
✓ A. IUPAC B. La n
C. Trivial D. English
Q.100 Acetaldehyde is used to make
A. Rubber B. An sep cs
C. Phenolic resin ✓ D. All of these
Q.101 Connizzaro's reac on is not given by
A. Trimethylacetaldehyde B. Benzaldehyde
C. Formaldehyde ✓ D. Acetaldehyde
Q.102 Forma on is ______ solu on of formaldehyde in water
A. 20% B. 60%
C. 10% ✓ D. 40%
Q.103 Ethyl acetate an ester when allowed to react with water in acidic media it produces ace c acid and ethyl alcohol. This
process is called;
✓ A. hydrolysis B. solva on
C. solvolysis D. hydra on
_______________________________________________________________________________________
Q.104 Which of the following is least reac ve
A. HCHO B. CH3CHO
✓ C. C6H5CHO D. CH3CH2CHO
Q.105 Which are oxidizing agents for aldehydes
A. K2Cr2O7 B. KMnO4
C. Conc. HNO3 ✓ D. All three
Q.106 Point out the compound whose oxida on is the most difficult
✓
A. B.
C. D.
Q.107 Formaline is used as
A. Fungicide B. Germicide
C. Sterilizing of surgical instruments ✓ D. All three
Q.108 Which compound would undergo nucleophilic addi on?
A. ethene, C2H4 B. BRomoethane, C2H5Br
✓ C. Ethanl, CH3CHO D. Ethane, C2H6
Q.109 Which of the following will have the highest boiling point
Q.110 Which test is given by both aldehydes and ketones:
✓ A. 2,4 DNPH B. Fehling solu on
C. Tollen's reagent D. Benedict solu on
Q.111 CH3CHO reacts with NH2OH to form oxime Type of isomerism shown by oxime is
✓ A. Geometrical B. Posi on
C. Func onal group D. Metamerism
Q.112 The general formula of homologous series of both aldehydes and ketones is
A. C2nHnO B. C2H2nOH
✓ C. CnH2nO D. CnHnO2n
Q.113 Which of the following group is present in most sugars
✓ A. -CHO B. -CO-R
C. -COOH D. -NH2
Q.114 Common names of aldehydes are obtained from carboxylic acids by replacing with aldehydes:
A. al B. ol
C. ane ✓ D. air acid
Q.115 Which of following organic compounds have fruity smell?
A. ethers ✓ B. esters
C. carboxylic acids D. alcohols
Q.116 Which of the following is not ta y acids:
✓ A. phthalic acid B. butanoic acid
C. ace c acid D. Propanoic acid
Q.117 Silver mirror test is used for
A. Alcohols B. Esters
✓ C. Aldehydes D. Acids
Q.118 Which one of the following reagents will dis nguish between C6H5CHO and C6H5CHO3?
A. aqueous bromine B. phosphorus pentachloride
C. 2, 4 DNPH ✓ D. Tollen's reagent
Q.119 Ethanal is reduced to
A. Methane B. Alcohol
C. Methanol ✓ D. Ethanol
_______________________________________________________________________________________
Q.120 Which of the following test is not given by aldehyde
A. 2, 4 DNPH test B. NaHSO3test
C. Tollen's test ✓ D. Sodium nitroprouside test
Q.121 In the light of IUPAC system, aldehydes are named as
C. Alkanols ✓ D. Alkanals
Q.122 Which reagent is used to reduce a carboxylic group to an alcohol:
A. N2/Ni B. H2/Pt
C. NaBH4 ✓ D. LiAH4
Q.123 In the reac on with sodium, 1 mol of a compound X gives 1 mol of H2 (g).
A. CH3CH2CH2CH2OH B. (CH3)3COH
C. CH3CH2CH2CO2H ✓ D. CH3CH(OH)CO2H
Q.124 The most probable compound with empirical formula C3H6O and which can react with Benedict solu on is
A. CH3-O-CH=CH2 B. CH3COCH3
C. CH2=CH-CH2OH ✓ D. CH3CH2-CHO
Q.125 Aqueous AgNO3 solu on containing an excess of NH4OH is called
A. Fehling solu on ✓ B. Tollen s solu on
C. Benedict solu on D. Baeyer solu on
Q.126 Connizzaro's reac on is a type of reac on:
A. Self oxida on reduc on reac on B. Dispropor on reac on
C. Addi on ✓ D. a and b
Q.127 Acetone is treated with excess of ethanol in the presence of hydrochloric acid. The product obtained
is:[CBSE AIPMT 2012]
✓
A. B.
D.
C.
Q.128 Aldehyde func onal group is present is
✓ A. Glucose B. Fructose
C. Menthone D. None
Q.129 Mild oxidizing agent among the following is
A. K2Cr2O7 ✓ B. KMnO4
C. Ammonical AgNO3 D. All of above
Q.130 Which compound is a product of the hydrolysis of CH3CO2C3H7 by boiling aqueous sodium hydroxide?
C. C3H7CO2H D. C3H7CO2Na+
Q.131 Correct statement about Fehling's solu on test
A. Brick red ppt with aroma c aldehyde B. Aldehydes not give this test
✓ C. Ketone do not give this test D. Both a and c
Q.132 Which of the following compounds does not have carboxyl group.
A. Methanoic acid B. Ethanoic acid
✓ C. Picric acid D. Benzoic acid
Q.133 Formaline contains __________ % alcohol
A. 80 B. 37
✓ C. 8 D. 52
Q.134 Formula of acetone is:
A. HCHO B. CH3ChO
✓ C. CH3OCH3 D. CH3OC2H5
_______________________________________________________________________________________
Q.135
The appropriate reagent for the transformation:[IIT JEE 2000]
✓ -
A. Zn (Hg), HCl B. NH2NH2, OH
C. H2, Ni D. NaBH4
Q.136 Which is not iden fying test of aldehydes
A. Fehling test B. Benedict test
✓ C. Baeyer test D. Tollen s test
Q.137 Which carboxylic acid is reacted with soda lime and alkali it produces carbon dioxide and simple hydrocarbon which of
the following is that:
✓ A. alkanes B. alkenes
C. alkynes D. none of above
Q.138 Cannzzaro's reac on is not given by
A. formaldehyde ✓ B. acetaldehyde
C. benzaldyhyde D. trimethylacetaldehyde
Q.139 In aldol condensa on reac on, a double bond is formed between _________ and __________ carbon atoms
A. alpha and alpha ✓ B. alpha and beta
C. alpha and gamma D. None of these
Q.140 Formic acid and ace c acid may be dis nguished by reac on with:
A. Sodium ✓ B. Dilute acidic permanganate
C. 2, 4 dinitrophenyl hydrazine D. Sodium ethaoxide
Q.141 Product formed when formaldehyde reacts with dilute alkalis is
A. CH3OH B. HCOONa
C. CH3CH(OH)CHO ✓ D. Both a and b
Q.142 In carboxyl group the bond between C and oxygen is:
A. Sigma bond B. Single bond
✓ C. Double bond D. Triple bond
Q.143 Which of the following will react with both aldehydes and ketones
A. Grignard reagent B. NaHSO3
C. NH2OH ✓ D. All of above
Q.144 Acetaldehyde reacts with Felling solu on on hea ng for the precipita on of
A. CuO B. CH3COOH
✓ C. Cu2O D. Cu
Q.145 Which one of the following is the strongest reduc ng agent
A. C 3H 5 ✓ B. CH2O
C. C3H7OH D. CH3COCH3
Q.146 Which of the following will not give iodoform test
✓ C. Pentan-3-one D. Pentan-2-one
Q.147 Chromic acid is used to oxidize
✓ A. Aldehyde B. Ketone
Q.148 Which of the following reagent will react with both aldehyde and ketones?
✓ A. Grignard's reagent B. Tollen's reagent
C. Fehling's reagent D. Benedict's reagent
Q.149 Which is mild oxidizing agent?
_______________________________________________________________________________________
✓ A. Tollen's reagent B. KMnO4/H2SO4
C. K2Cr2O7/H2SO4 D. Dil HNO3
Q.150 Which of the following reagents will react with both aldehydes and ketones
✓ A. Grignard reagent B. Tollen's reagent
C. Fehling's reagent D. Sodium nitroprosside
Q.151 Cannizzaro s reac on is not given by
A. Methanal B. Benzaldehyde
✓ C. Propanal D. Trichloro acetaldehyde
Q.152 Which of the following compounds will react with Tollen's reagent?
A. CH3CO H B. CH3CO CH3
C. CH3COOH ✓ D. CH3CO CH2CH3
Q.153 The incorrect IUPAC name is[CBSE AIPMT 2001]
✓
A. B.
C.
D.
Q.154 The compound which forms acetaldehyde when heated with dilute NaOH is[Karnataka CET 2009]
A. 1 chloro ethane ✓ B. 1, 1 dichloro ethane
C. 1, 2 dichloro ethane D. 1, 1, 1 trichloro ethane
Q.155 Formamint is a mixture of
A. Formaldehyde + glucose ✓ B. Formaldehyde + Iactose
C. Formaldehyde + fructose D. Formaldehyde + sucrose
Q.156 Ethanol on reac ng with dil NaOH produces
A. 2-hydroxyl butanal ✓ B. 3-hydroxy butanol
C. 3-hydroxy butanal D. 2-butanone
Q.157 The word 'al' is used for
A. Alkane B. Alcohol
C. Ketone ✓ D. Aldehyde
Q.158 Which of the following reagents is used to dis nguish between acetophenone and benzophenone
✓ A. I2and Na2CO3 B. Aquueous solu on of NaHSO3
C. Benedict solu on D. 2, 4-Dinitrophenyl hydrogen
Q.159 Monocarboxylic acids exist as dimer because of:
A. cohesive forces ✓ B. hydrogen bonding
C. van der waal's forces D. dipole-dipole a rac on
Q.160 Which of the following statements is not correct? [DELHI PMT 2010]
A. Aldehydes and ketones undergo ✓ B. Aldehydes and ketones undergo
nucleophilic addition electrophilic substitution
C. Aldehydes and ketones contain polar D. Lower members of aldehydes and
carbonyl group ketones are soluble in water due to
hydrogen bonding
Q.161 The base used in Cannizzaro's reac on is
✓ A. NaOH B. KOH
C. CHI3 D. All of these
Q.162 Cannizaro's reac on is not given by
A. formaldehyde ✓ B. acetaldehyde
_______________________________________________________________________________________
C. benzaldehyde D. trimethylacetaldehyde
Q.163 Hydroxyl amine is a deriva ve of:
A. Alcohol B. Aldehyde
✓ C. Ammonia D. Ketone
Q.164 Cannizaro's reac on is given by
A. Benzaldehyde ✓ B. Formaldehyde
C. Acetaldehyde D. Trimethlacetaldehyde
Q.165 Aldehydes and ketones can be prepared from alcohols by their:
C. Decomposi on D. Synthesis
Q.166 Which of the following reac on is/are shown by carboxylic acid:
A. Acid base reac on B. Nucleophilic subs tu on reac on
C. Reac on involving carboxyl group as a whole ✓ D. All of the above
Q.167 When acetyl chloride reacts with any amine, the reac on is known as:
A. Saponifica on B. Esterifica on
✓ C. Acetyla on D. Condensa on
Q.168 Trichloroacetaldehyde, CCl3CHO reacts with chlorobenzene in the presence of sulphuric acid and
produces[CBSE AIPMT 2009]
✓
A.
B.
C.
D.
Q.169 On adding sodium nitroprusside ketones give

A. Red ✓ B. Wine Red
C. White D. Orange
Q.170 Which alcohol may be oxidised to a product which react with 2,4-dintorphenylhydrazine reagent but not with
Fehkubg's reagent?
Q.171 Which of the following is halo form
A. CHBr3 B. CHCl3
C. CHl3 ✓ D. All of these
Q.172 Which of the following compound will not give iodoform test on treatment with I2/NaOH?
A. Acetaldehyde B. Acetone
C. Butanone ✓ D. 3-Pentanone
Q.173 Cannizaro's condensa on occurs in the presence of:
A. weak acid B. weak base
C. strong acid ✓ D. strong base
Q.174 Which of the following will have the highest boiling point?
A. methanol B. ethanol
_______________________________________________________________________________________
C. propanol ✓ D. 2-hexanone
Q.175 A compound X has all of the proper es below:
it is a liquid at 25°C
It mixes comple5elyt with water
It reacts with aqueous sodium hydroxide
What could X be?

✓ A. ethanoic acid B. ethanol
C. ethyl ethanoate D. ethyl ehanoate
Q.176 An ar ficial smell of banana is produced in many ar cles by suing esters which of the following is that?
A. isoaml valerate B. menthyl butyrate
C. octyl acetate ✓ D. amyl acetate
Q.177 Which of the following will undergo nucloophilic addi on reac on more easily
✓ A. Aldehyde B. Aldehyde & ketone equally
C. Alkene D. Neither aldehyde nor alkenes
Q.178 Common names of ketones are given:
A. by wri ng alkane at the end B. by wri ng alkyl name
✓ C. by wri ng alkyl groups and all the end D. by wri ng alkyl group at the end of name
ketone
Q.179 The homologeous series of aldehydes and ketones have general formula:
✓ A. CnH2nO B. C nH nO
C. CnH2n-1O D. C nH nO n
Q.180 Aldol condensa on is a reac on of cold debute solu on of alkali with
A. All ketones B. All aldehydes
✓ C. Aldehydes and ketones withβ-hydrogen D. Aldehydes withα-hydrogen
Q.181 Reac vey of carbonyl compounds is due to
✓ A. Electrophilic carbon B. Less stearic hindrance
C. Unsatura on of C-O D. All of above
Q.182 Which acid is used in the manufacture of synthe c fibre:
A. formic acid B. oxalic acid
✓ C. carbonic acid D. ace c acid
Q.183 Which of the following compounds will react with Tollen's regent
✓
A. B.
C. D.
Q.184 Aldehydes are reduced to:
✓ A. Pri-alcohol B. Sec-alcohol
C. Ter-alcohol D. All of thee
Q.185 Essen al amino acids are those amino acid which:
A. body can synthesis ✓ B. body can not synthesize
C. α-amino acids D. β-Amino acids
Q.186 Vinegar contains:
A. 10 to 20 % ace c acid B. 10 % ace c acid
✓ C. 6 to 10% ace c acid D. 100% ace c acid
Q.187 A carboxylic acid contains:
A. a hydroxyl group B. a carbonyl group
✓ C. a hydroxyl and carbonyl group D. a carbonyl and an aldehyde group
Q.188 Aldehydes are the oxida on product of
✓ A. Primary alcohol B. Secondary alcohol
C. Ter ary alcohol D. Carboxylic acids
Q.189 Keeping in view the reac ons of aldehydes and ketones, choose the incorrect statement
_______________________________________________________________________________________
A. They react with hydroxylamine to form oximes B. They react with to form addi on
4
NaHSO product
✓ C. They reduce ammonical AgNO3to give silver D. They react with hydrazine to form hydrazones
Q.190 Condensa on of aldehydes with α-hydrogen gives:
A. Acetal B. Ketal
C. Aldol ✓ D. Cannizzaro product
Q.191 Chemically formamint is
A. Formaldehyde B. Lactose
✓ C. Mix of a and b D. None of these
Q.192 An organic compound has the following proper es;
It gives a posi ve tri-iodomethane test; it gives a yellow ppt. with 2, 4-DNP reagent, it does not react with Tollen's
reagent
Which compound would give these results?
A. CH3CHO B. CH3CH2OH
✓ C. CH3CH2COCH3 D. CH3CH2COOH
Q.193 Ketones can be oxidized by:
A. Tollen's reagent B. Benedict solu on
C. Fehling solu on ✓ D. Dil HNO3
Q.194 Aldelydes are the oxida on product of
✓ A. p-alcohols B. s-alcohols
C. ter-alcohols D. carboxylic acids
Q.195 Reac on with Grignard's reagent with ketones gives: Reac on of Grignard's reagent with formaldehyde gives:
A. Pri-alcohol B. Sec-alcohol
✓ C. Ter-alcohol D. Carboxylic
Q.196 Some amino acids are most important because they are the final producer of hydrolysis of pep de and proteins and
they are:
✓ A. α-amino acid B. β-amino acids
C. γ-amino acids D. All of the above
Q.197 Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc .
(http://www.questionpapers.net.in/) HCl is called[CBSE AIPMT 2007]
A. Cope reduction B. Dow reduction
C. Wolff-Kishner reduction ✓ D. Clemmensen reduction
Q.198 Ester has peculiar smell.Which of following is used as an essence of orange:
✓ A. octyl acetate B. methyl butyrate
C. isoami valerate D. isoaml acetate
Q.199 For which one of the following pairs of compounds can the members be dis nguished by means of Tollen's test
A. HCHO and CH3CHO ✓ B. CH3CHO and CH3COCH
C. CH3COCH3and C6H5COCH3 D. CH3COOH and CH3COOCH3
Q.200 Acetaldehyde and formaldehyde differ from each other when react with
A. Fehling solu on B. Ammonical AgNO3
✓ C. Ammonia D. Shiff's reagent
Q.201 Ketons is given test with:
A. fehling solu on B. tollen's reagent
C. Benedic solu on ✓ D. Sodium nitroprusside test
Q.202 Which is the general formula for aldehydes
A. CnH2n+2O B. CnH2nOH
C. CnH2n+1O ✓ D. CnH2nO
Q.203 Cyanohydrin of which of the following will yield lac c acid
A. HCHO B. CH3COCH3
C. CH3CH2CHO ✓ D. CH3CHO
Q.204 Which reac on is of condensa on or addi on elimina on reac on:
_______________________________________________________________________________________
A. Ketol B. Aldol
C. Cannizzaro ✓ D. All of these
Q.205 Common names of aldehydes are obtained from the common names of
A. Ethers B. Ketones
✓ C. Carboxylic acid D. Acid amide
Q.206 Which compound on reac on with hydrogen cyanide produces a compound with a chiral centre?
✓ A. CH3CHO B. CH3CH2COCH2CH3
C. CH3CO2CH3 D. HCHO
Q.207 Actaldehyde cyanohydrin upon hydrolysis produces
A. Tertaric acid B. Formic acid
C. Malonic acid ✓ D. Lac c acid
Q.208 Which is most difficult to oxidize
A. HCHO ✓ B. CH3COCH3
C. CH3CHO D. CH3CH2CHO
Q.209 Which one of the following statement is wrong regarding difference between aldehydes and ketones?
A. aldehydes undergo reduc on to form primary ✓ B. aldehydes undergo oxida on to form acids
alcohols while ketones undergo reduc on to having less number of carbon atoms while
form secondary alcohols ketones undergo oxida on to form acids
having same number of carbon atoms
C. aldehydes give posi ve silver mirror test while D. aldehydes can undergo polymeriza on while
ketones give nega ve-mirror rest ketones cannot undergo polymeriza on
Q.210 Aldehyde give precipitate with Fehling solu on on
A. Cooling ✓ B. Hea ng
C. Room temperature D. Do not give ppt
Q.211 The colour of ppts formed by Benedict's test is
✓ A. Brick red B. Wine red
C. Yellow D. Orange
Q.212 Aldehydes are oxidized to give:
C. Ter-alcohol ✓ D. Carboxylic
Q.213 Ethanal may be converted into a three-carbon acid in a two-step process.
Which compound ins the intermediate?
A. CH3CO2H B. CH3CN
C. CH3CH2CN ✓ D. CH3CH(OH)CN
Q.214 Cannizzaro's reac on is not given by:
A. Formaldehyde ✓ B. Acetaldehyde
C. Benzaldehyde D. Trimethy acetaldehyde
Q.215 Acetone reacts with HCN to form a cyanohydrin. It is an example of:
A. Electrophilic addi on B. Electrophilic Subs tu on
✓ C. Nucleophilic add on D. Nucleophilic subs tu on
Q.216 Formalin is:
A. 10% solu on of formaldehyde in water. B. 20% solu on of formaldehyde in water.
✓ C. 40% solu on of formaldehyde in water. D. 60% solu on of formaldehyde in water.
Q.217 Aldehydes and Ketones react with 2,4-DNPH t form
✓ A. Red ppt B. Orange ppt
C. White ppt D. Black ppt
Q.218 Esters are pleasant smelling compounds which one of the following esters possesses odour like pineapple?
A. Benzylacetate ✓ B. ethylbutyrate
C. amylacetate D. amylbutrate
Q.219 Lodoform test is given by:
A. Formaldehyde and higher ketones B. Formaldehyde
✓ C. Acetaldehyde and methyl ketones D. Acetaldehyde
_______________________________________________________________________________________
Q.220 The formula of urotropine is
A. (CH2)4N6 ✓ B. (CH2)6N4
C. (CH2)6N5 D. (CH2)5N5
Q.221 Aldehydes which do not have alpha - hydrogen undergo
A. Aldol combina on ✓ B. Cannizzaro's reac on
C. Subs tu on D. Elimina on
Q.222 Addi on reac on between ethanal and NH3 can be said
A. Electrophilic addi on ✓ B. Nucleophilic addi on
C. Free radical addi on D. None of these
Q.223 Which of the following ester give is the flavor of jasmine:
A. Amyl Acetate ✓ B. Benzyl Acetate
C. Ethyl butyrate D. Amyl butyrate
Q.224 Aldehydes can be dis nguished from ketones
A. 2,4-DNPH test B. NaHSO3test
C. N2H4test ✓ D. Tollen's test
Q.225 Fehling solu on is a complex of
A. Cupric and oxalate B. Cupric amine
C. Cuprous tartrate ✓ D. Cupric tartrate
Q.226 Ketones are prepared by the oxida on of
✓ C. Ter ary alcohol D. None of above
Q.227 Carboxyl compounds have func onal groups:
A. R-C-X B. R-CH=O
C. RCOR ✓ D. All
Q.228 Alkoxide remove proton from
✓ A. H 2O B. NH3
C. HCI D. All of these
Q.229 Aldehydes are oxidized to:
A. alcohol B. ketones
C. carboxylic acids ✓ D. ace c acid
Q.230 Ketones are reduced to
A. Primary alcohol ✓ B. Secondary alcohol
C. Ter ary alcohol D. All of these
Q.231 How many structural isomers with molecular formula C4H8O can reduce a solu on containing Ag(NH3)+2 ions to form a
silver mirror
A. 01 ✓ B. 02
C. 03 D. 04
Q.232 CH3CHO and C6H5CH2CHO can be distinguished chemically by:[CBSE AIPMT 2012]
A. Tollen's reagent test B. Fehling solution test
C. Benedict test ✓ D. Iodoform test
Q.233 The acid used to remove rust stains on cloth is:
A. fumaric acid B. HCI
C. formic acid ✓ D. oxalic acid solu on
Q.234 In 1903 Arthur Lapeworth became the first chemist to inves gate a reac on mechanism.The reac on he inves gated
was that of hydrogen cyanide with propane.
What do we now call the mechanism of this reac on?
✓ C. Nucleophilic addi on D. Nucleophilic subs tu on
Q.235 Which of the following acids does not exhibit optical isomerism?[CBSE AIPMT 2012]
A. Lactic acid B. Tartaric acid
✓ C. Maleic acid D. α-amino acids
_______________________________________________________________________________________
Q.236 Which is correct regarding the cannizzaros reac on

✓ A. DIspropor ona on occurs B. Alcohol is oxidized product
C. Salt is reduced produced D. All are correct
Q.237 Aldehyde and small methyl ketones form crystalline _________ ppts with saturated sodium bisulphate solu on
✓ A. White B. Red
C. Yellow D. None of these
Q.238 Which of the following will undergo nucleophilic addi on reac on more easily
✓ A. Aldehyde B. Alkene
C. Aldehyde and Ketone D. All of these
Q.239 The alanine is __________ in nature.
A. weakly acidic B. acidic
✓ C. neutral D. basic
Q.240 Dis lla on of calcium salts of ace c acid and formic acids gives acetaldehyde. What compound would be obtained if
only calcium salt of ace c acid is dis lled
A. formaldehyde B. butyraldehyde
C. propionaldehyde ✓ D. acetone
Q.241 Which of the following reagent will react with both aldehydes and ketones
A. Fehling reagent ✓ B. Hydrazine
C. Tollen reagent D. Sodium nitroprusside
Q.242 A strong base can abstract ana-hydrogen from[CBSE AIPMT 2008]
A. Amine B. Alkane
C. Alkene ✓ D. Ketone
Q.243 S nges of bees and wasps contain:
A. Formalin ✓ B. Formic acid
C. Ace c acid D. Formaldehyde
Q.244 Which reagent will dis nguish a ketone from an aldehyde
A. Br2(aq) B. 2,4-dintrophenylthydrazine
C. NaBH4 ✓ D. Tollen's reagent
Q.245 The reac on of alcohol with ace c acid is called as:
A. hydrolysis ✓ B. esterifica on
C. ammonolysis D. sponifica on
Q.246 General formulas of aldehyde & ketone is
✓ A. CnH2nO B. CnH2n+1O
C. CnH2n+2O D. CnHnO
Q.247 Which is strong oxidizing agent?
A. KMno4in H2SO4 B. K2Cr2O7in H2SO4
C. Dill HNO3 ✓ D. All of these
Q.248 The % age of ace c acid in vinegar is about:
A. 20% B. 30%
C. 20 - 50% ✓ D. 6 - 10%
Q.249 A common industrial solvent is a mixture of propanone, CH3COCH3, and pentyl ethanoate CH3CO2(CH2)4CH3
Which reagent would have no effect on this solvent
✓ A. Na(s) B. NaBH4
C. NaOH(aq) D. 2,4-dinitrophenylhydrazine reagent
Q.250 Aldehydes and ketones are carbonyl compounds.
Which of them react both wiht NaBH4and with Tollen's reagent?
A. Both aldehydes and ketones ✓ B. Aldehydes only
C. Ketones only D. Neither aldehydes nor ketones
Q.251 Which of the following will not show haloform reac on
✓ A. C6H5CHO B. CH3CHO
_______________________________________________________________________________________
C. CH3COCH3 D. C6H5COCH3
Q.252 The acid present in the s ngs of bees and wasps is:
A. ace c acid B. formaldehyde
✓ C. formalin D. formic acid
Q.253 The reac on in which acetaldehyde is formed from ethanol is called
A. Addi on reac on B. Subs tu on reac on
✓ C. Oxida on reac on D. Reduc on reac on
Q.254 One of the following is applica on of idoform reac on
A. Iodine is separated from reac on mixture B. Ketone are formed from this reac on
✓ C. Carboxylic acid are formed from methyl D. None
ketones
Q.255 Glucose reacts with Fehling reagent and form reddish brown ppt of
A. Cu B. CuO
✓ C. Cu2O D. Cu2O + Cu2O3
Q.256 In amino proton is transferred from on point to the other point and this dipolar ion is called:
A. Oxonium ion B. Carbonium ion
✓ C. Zwi erion D. Carbanion
Q.257 Acetyl chloride is converted into ace c anhydride when treated with:
A. acetone B. sulphuric acid
C. phosphours pentaoxide ✓ D. sodium acetate
Q.258 Which formula represents the organic compound formed by the reac on of propanoic acid with methanol in the
presence of concentrated sulphuric acid as a catalyst?
A. CH3CH2COCH3 ✓ B. CH3CH2CO2CH3
C. CH3CO2CH2CH3 D. CH3CH2CH2CO2CH2
Q.259 Almond essence is used to flavour food. A student tested a sample of almond essence using 2, 4-DNP reagent and
obtained decoloured crystals which had sharp mel ng point. Which class of compounds gives the test
A. Alcohols ✓ B. Aldehydes withα-hydrogen
C. Carboxylic acid D. Amines
Q.260 Aldol condensa on occurs in the presence of :
A. weak acid ✓ B. weak base
C. strong acid D. strong base
_______________________________________________________________________________________
18 Carboxylic Acid
Q.1 Due to presence of excess carboxylic acids shows all typical reac ons
✓ A. H+ions B. OH-ions
Q.2 Which one of the following has both hydroxyl and carboxylic acid groups?
A. phenols B. picric acid
C. phthalic acid ✓ D. salicylic acid
Q.3 Esters are mostly
A. Solids B. Gases
C. Non-vola le liquids ✓ D. Colorless liqiud
Q.4 Mel ng point of carboxylic acids increases with increasing molecular mass:
A. regularly B. Commonly
C. always ✓ D. Irregularly
Q.5 Reac on of ace c acid with LiAlH4gives
✓ A. Ethanol B. Ethane
C. Ethanal D. Ethyl acetate
Q.6 Ace c acid is used as co-angular for latex in?
A. Glass industry B. Paper industry
C. Plas c industry ✓ D. Rubber industry
Q.7 If TEL is added to iso-octane, octane number will be:
A. 100 B. <100
✓ C. > 100 D. None of all
Q.8 Par al reduc on of ace c acid happens with
A. NH3 ✓ B. LiAH4
C. P + HI D. PCl5
Q.9 The term of an element is the:
A. Charged par cle ✓ B. Smallest par cle
C. Fundamental par cle D. Independent par cle
Q.10 A carboxylic acid with one carboxyl group:
✓ A. Monoarboxylic acid B. Dicarboxylic acid
C. Tricarboxylic acid D. Polycarboxylic acid
Q.11 Ace c acid is manufactured by
A. Fermenta on B. Esterifica on
✓ C. Dis lla on D. Ozonolysis
Q.12 Which of the following is not a fa y acid?
✓ A. Propanoic acid B. Ace c acid
C. Phthalic acid D. Butanoic acid
Q.13 The organic compounds containing Ph-OH group are called:
✓ A. Phenol B. Aldehyde
C. Ketones D. Carboxylic acids
Q.14 Which of the following acid is unsaturated carboxylic acid
A. Malonic acid B. Oxalic acid
_______________________________________________________________________________________
C. Succinic acid ✓ D. Maleic acid
Q.15 Ethanoic acid reacts with PCl5to give ethanoyl chloride, HCl and a third compound. What is the third compound
A. H3PO3 ✓ B. POCl3
C. SO2 D. COCl2
Q.16 Esters have pecullar smell, which of the following is used as an essence of orange
A. isoamyl acetate B. iosamyl valerate
✓ C. octyl acetate D. methyl butyrate
Q.17 For synthesis of carboxylic acid intermediate product needed is
✓ A. Acyl chloride B. Aryls
C. Benzene D. Carboxylic acid
Q.18 Of the following reac ons, formic and ace c acid differ in which respect
A. Blue litmus reac on B. Forma on of ester with alcohol
C. Replacement of hydrogen by sodium ✓ D. Reduc on of fehling solu on
Q.19 Ethyl alcohol on________ gives ethane:
A. Hydra on B. Dehydra on
C. Hydrogena on ✓ D. Dehydrogena on
Q.20 Which compound is a product of the hydrolysis of CH3CO2C3H7by boiling aqueous sodium hydroxide
C. C3H7CO2H D. None of these
Q.21 The acids obtained by the hydrolysis of fats and oils are called
A. Ac ve compound ✓ B. Fa y acids
C. Func onal groups D. None
Q.22 An ar ficial smell of banana is produced in many ar cles by using esters which of the following is that
✓ A. amyl acetate B. isomyl valerate
C. octyl acetate D. methyl butyrate
Q.23 Aldehydes are the oxida on products of:
✓ A. p-Alcohols B. Sec-Alcohols
C. Tert-Alcohols D. Carboxylic acid
Q.24 Those amino acids which contain two carboxylic groups are called ______ amino acids
Q.25 Amino acid contain func onal groups in it:
A. -CO- B. -OH
C. -NH2 ✓ D. a,b,c
Q.26 When carboxylic acid is reacted with soda lime and alkali, it produces carbon dioxide and simple hydrocarbon. Which
of the following is that
C. Alkynes D. None of above
Q.27 Some amino acids are most important because they are the final product of hydrolysis of pep de and protein they are
✓ A. α-amino acid B. β-amino acid
C. γ-amino acid D. All of the above
Q.28 Boiling point of formic acid is (In oC)
✓ A. 100 B. 118
C. 151 D. 160
Q.29 Which is the nature of Al2O3 ?
A. Neutraliza on B. Acidic
C. Basic ✓ D. Amphoteric
Q.30 Acyl chlorides are made by reac ng carboxylic acids with
A. PCl5 B. PCl3
C. SOCl2 ✓ D. All of them
_______________________________________________________________________________________
Q.31 Bleaching powder may be produced by passing chlorine over:
✓ A. Calcium hydroxide B. Anhydrous calcium sulphate
C. Calcium carbonate D. Hydrate calcium sulphate
Q.32 PCI5 exist but NCL5 does no. It is due to the reason that:
A. NCI5 is unstable ✓ B. Nitrogen has no vacant d-orbital
C. Nitrogen is inert D. Nitrogen atom is much smaller
Q.33 With amino acids ninhydrin solu on gives
A. Blue B. Violet
✓ C. Bluish violet D. White
Q.34 Monocarboxylic acids exist as dimer because of
A. dipole-dipole a rac on ✓ B. hydrogen bonding
C. Van der Waals forces D. cohesive forces
Q.35 The fer lizer contains 33-35% N is
✓ A. Ammonium nitrate B. Potassium nitrate
C. Urea D. Ammonia
Q.36 CH3COONa on reac on with CH3COCl gives
✓ A. Ace c anhydride B. Methyl acetate
C. Acetyl chloride D. None of these
Q.37 Carboxylic acids reacts with sodium carbonate & gas evolved in this reac on
A. CO ✓ B. CO2
C. H2 D. Both a and b
Q.38 Dilute solu on of ace c acid is known as ______
A. Molasses B. Pep de bond
C. Amino acid ✓ D. Vinegar
Q.39 O-hydroxy benzoic acid is also called
A. Malonic acid ✓ B. Salicylic acid
C. Adipic acid D. Glutaric acid
Q.40 Carboxylic acids generally exists in cyclic
A. Monomers ✓ B. Dimers
C. Trimers D. Tetrameter
Q.41 Ester with raspberry flavour is
A. Anylautate ✓ B. Isobutyl formate
C. Amyl butyrate D. Octyl acetate
Q.42 Etherifica on is catalyzed by
✓ A. Acids B. Gases
C. Salts D. None of these
Q.43 Amino acids are classified into following types
A. Acidic B. Basic
C. Neutral ✓ D. All
Q.44 Ethyl acetate, an ester when allowed to react with water in acidic media, it produces ace c acid and ethyl alcohol. This
process is called
✓ A. Hydrolysis B. Solva on
C. Solvalysis D. Hydra on
Q.45 In prepara on method of carboxylic acids from alkyl halide always carboxylic acids formed which have carbon atoms:
A. One less than in R-X ✓ B. One more than in R-X
C. Equal to R-X D. Double to R-X
Q.46 Cyclic anhydrides are obtained from
A. Mono carboxylic acids ✓ B. Dicarboxylic acids
C. Unsaturated carboxylic acid D. All of above
Q.47 Ace c acid is categorized as a weak acid. The reason is that it
_______________________________________________________________________________________
A. Has less density B. Is less vola le
✓ C. Has less dissocia on D. Is less viscous
Q.48 Why is ethanoic acid a stronger acid in liquid ammonia than in aqueous solu on
✓ A. Ammonia is a stronger base than water B. Ammonium ethanoate is completely ionized
in aqueous solu on
C. Ammonium ethanoate is strongly acidic in D. Liquid ammonia is a more polar solvent than
aqueous solu on water
Q.49 CCl3COOH is strongest of
✓ A. Acids B. Bases
C. Alkalis D. Compounds
Q.50 Esters are pleasant smelling compounds. Which one of the following esters possesses odour like pineapple
A. Benzylacetate ✓ B. Ethlbutyrate
C. Amylacetate D. Amylbutyrate
Q.51 The weakest carboxylic acid
A. HCOOH ✓ B. CH3CH2COOH
C. CH3COOH D. CICH2COOH
Q.52 Which acid is responsible for the odour of goat
A. Valeric acid ✓ B. Caproic acid
C. Butyric acid D. Stearic acid
Q.53 Complete reduc on of a carboxylic acid happens with
A. NH3 B. LiAIH4
✓ C. P D. PCl5
Q.54 Which is the correct statement among the following for 20 moles of hydrogen peroxide?
A. It has 20 moles of hydrogen atoms ✓ B. It h as 80 moles of atoms
C. It has 30 moles of oxygen D. it has 30 moles of hydrogen atoms
Q.55 Alipha c carboxylic acids have carboxyl group a ached to:
Q.56 Which of the following is not fa y acids
✓ A. Phthalic acid B. Butanoic acid
C. Ace c acid D. Propanoic acid
Q.57 Hydrolysis of ester gives Acid A and alcohol B The acid reduces Fehling solu on while oxida on of B gives acid A The
ester is
A. Methyl acetate B. Ethyl acetate
✓ C. Methyl formate D. Ethyl formate
Q.58 Carboxylic acids react with acids releasing gas from it:
A. H2O as steam B. CO
✓ C. CO2 D. O2
Q.59 The formula C6H5 represents:
A. Vinyl group B. Benzyl group
✓ C. Phenyl group D. No such group exists
Q.60 Types of reac ons, carboxylic acids undergo:
A. reac ons due to hydrogen B. reac on due to OH group
C. reac ons due to carboxyl group as a whole ✓ D. All of these
Q.61 The acid present in vinegar is
✓ A. CH3COOH B. HCl
C. H2SO4 D. HCOOH
Q.62 Carboxyl group has func onal group in it:
A. One ✓ B. Two
C. Three D. Four
Q.63 Equal masses of methnane and oxygen are mixed in a empty container at 25°C.
_______________________________________________________________________________________
A. 1/3 B. 8/9
C. 1/9 ✓ D. 2/3
Q.64 Which of the following deriva ve cannot be prepared directly from carboxylic acid
A. Acetyl chloride ✓ B. Acetamide
C. Ace c anhydride D. Ethyl acetate
Q.65 Ethyl alcohol is converted into ace c acid by
C. Fermenta on D. Hydrogena on
Q.66 Which one of the following acids does not contain carboxylic group
A. Lac c acid B. Ethanoic acid
C. Plami c acid ✓ D. p-Toluenesulphonic acid
Q.67 Ace c acid can be produced by the reac on of "A" with CH3Cl followed by acid hydrolysis. The "A" is
A. CICN ✓ B. KCN
C. KCl D. None of these
Q.68 Essen al amino acids are those amino acids which
✓ A. body can not synthesize B. body can synthesize
C. alpha-amino acids D. beta-amino acids
Q.69 The reac on of chlorine with cold and hot sodium hydroxide to give VaCi and NaCIO is an example of:
A. Reduc on reac on B. Oxida on reac on
C. Neutraliza on reac on ✓ D. Dispropor on reac on
Q.70 Jasmine flavour is due to ester
A. Octyl acetate B. Ethyl butyrate
C. Amylacetate ✓ D. None of these
Q.71 Which of the following is the strongest acid
A. HCOOH B. CH3COOH
C. CH3- CH2- COOH ✓ D. Cl-CH2- COOH
Q.72 Carboxylic Acids are reduced to in the presence of NaAIH4:
A. Esters B. Acetyl chloride
✓ C. Alcohol D. Aldehydes
Q.73 Ace c acid is used as co-angular for latex in
A. Glass industry B. Paper industry
C. Plas c industry ✓ D. Rubber industry
Q.74 A sulphur containing amino acid is
A. Glycine ✓ B. Cysteine
C. Alanine D. Leucine
Q.75 Which of the following is not a fa y acid?
A. propanoic acid B. ace c acid
✓ C. phthalic acid D. butanoic acid
Q.76 Reac on of Acyl chlorides with alcohols and phenols will give
✓ A. Esters B. Ketones
C. Aldehydes D. Haloalkanes
Q.77 Reac on with high ac va on energy are:
A. Fast B. Moderate
✓ C. Slow D. does not occur
Q.78 Ace c acid reacts with thionyl chloride to form acetyl chloride, which species acts a snucleophile in the reac on
A. SO2 B. SO3
✓ C. Cl -1
D. No nucleophile is formed
Q.79 Which of the compound is not formed as a result of reac on between ace c acid & Hl & red phosphorous
✓ A. Ethanol B. Water
C. Iodine D. Ethane
_______________________________________________________________________________________
Q.80 The acid present in the s ngs of bees and wasps is:
A. Formaldehyde ✓ B. Formalin
C. Formic acid D. Ace c acid
Q.81 Ace c acid reacts with PCI3Giving:
A. Acetamide B. Acetyl chloride
C. Alcohol ✓ D. Esters
Q.82 The deriva ves that cannot be prepared directly from the ace c acid
✓ A. Acetamide B. Acetyl chloride
Q.83 Lysine is ________ amino acid
C. Natural D. None of these
Q.84 Which one of the following element is not present in all proteins
A. Carbon B. Hydrogen
C. Nitrogen ✓ D. Sulphur
Q.85 The ra o between the mass of proton to the mass of electron is:
A. 1 : 1000 ✓ B. 1836 : 1
C. 1 : 1836 D. 1000 : 1
Q.86 An equeous of an organic compound reacts with sodium carbonate to produce carbon dioxide gas. Which one of the
following could be the organic compound
A. CH2= CH - CH3 B. CH3- CHO
C. CH3COOC2H5 ✓ D. CH3- CH2- COOH
Q.87 Acetyl chloride is converted into ace c anhydride when treated with
A. Acetone B. Sulphuric aicd
C. Phosphorous epentaxoide ✓ D. Sodium acetate
Q.88 A carboxylic acid containing Ar group in it is called:
✓ A. Aroma c carboxylic acid B. Alipha c carboxylic acid
C. Dicarboxylic acid D. Carboxylic acid
Q.89 Which one of the following is different from others
A. Valeric acid B. Caproic acid
C. Propionic acid ✓ D. Adipic acid
Q.90 Fruits are preserved using
A. Aldehydes ✓ B. Na.benzoate
C. HCOOH D. Salicylic acid
Q.91 The human body can synthesize _________ amino acids
A. 1 ✓ B. 10
C. 20 D. 19
Q.92 Essen al amino acids are those amino acid which
A. Body can synthesis ✓ B. Body can not synthesize
C. α-Amino acids D. β-Amino acids
Q.93 The major por on of natural gas is:
A. Butane ✓ B. Methane
C. Propane D. Ethane
Q.94 Boiling point of formic ace c acid is (In oC)
A. 100 ✓ B. 118
C. 151 D. 160
Q.95 The solu on of which acid is used for seasoning of food?
A. Formic acid ✓ B. Ace c acid
C. Benzoic acid D. Butanoic acid
Q.96 The Zwi er ion is also called
_______________________________________________________________________________________
A. Interna onal salt ✓ B. Internal salt
C. No salt D. None of these
Q.97 Op cal ac vity is possible in
A. oxalic acid B. ace c acid
✓ C. tartaric acid D. formic acid
Q.98 Alkenes combine readily with electrophilc reagents giving:
A. Haloakanes B. Vinyl halide
✓ C. Vicinal Dihalides D. Gen dihalides
Q.99 Which of the following can convert an acid to acid chloride
A. PCl5 B. PCl3
C. SOCl2 ✓ D. All of these
Q.100 First three carboxylic acids(C1 to C3) have smell like:
A. Impleasant B. Flowers
C. Fruites ✓ D. Purgent
Q.101 A compound always consists or the same element combined in the same fixed ra o." The statement is:
✓ A. A law B. A hypothesis
C. A fact D. An observa on
Q.102 A professor told his students that air is a mixture because a students raised hand and said:
A. It is colorless B. It has different proper es form it cons tuents
✓ C. It composi on is different at different D. Oxygen can be remove form it
al tudes
Q.103 Acton reacts with HCN to form a cyanohydrin, It is an example of:
✓ C. Nucleophilic addi on D. Nucleophilic subs tu on
Q.104 The amino acid which body can synthesize are called
A. Essen al ✓ B. Non-essen al
C. Acidic D. Basic
Q.105 The solu on of which acid is used for seasoning of food
Q.106 Acetamides are formed by the reac on of carboxylic acids with
A. Acids B. Bases
C. salts ✓ D. NH3
Q.107 The alanine is ______ in nature
A. Weakly acidic B. Acidic
✓ C. Neutral D. Basic
Q.108 When acetamide is hydrolyzed by boiling with acid, what is produced
✓ A. CH3COOH B. HCOOH
C. Aspirin D. None of these
Q.109 Formic acid reduces Tollen' reagent because
A. It is very strong B. It is carboxylic acid
✓ C. It has aldehydic group in its structure D. None of these
Q.110 Ester has peculiar smell. Which of following is used as an essence of orange
✓ A. Octyl acetate B. Methyl butyrate
C. Isoaml valerate D. Isoaml acetate
Q.111 Boiling point of ace c acid is°C:
A. 116 B. 117
✓ C. 118 D. 119
Q.112 Which of the following is strongest acid
✓ A. HCOOH B. CH3COOH
C. CH3CH2COOH D. All are equally strong
_______________________________________________________________________________________
Q.113 Ace c acid exists as dimer in benzene due to

✓ A. H-bonding B. Condensa on
C. Presence of carboxylic group D. Presence of hydrogen at alpha-carbon
Q.114 Amino acids are building blocks of:
✓ A. Protein B. Carbohydrates
C. Lipids D. Fats
Q.115 Ketone are prepared by the oxida on of:
✓ C. Ter ary alcohol D. None of all
Q.116 Which of the following is deriva ve of carboxylic acid
A. Ester B. Acid halide
C. Acid amide ✓ D. All
Q.117 When a piece of paper in burnt in air the gas produced is passed through dis lled:
A. 7 B. 2.1
C. 1 ✓ D. 6.8
Q.118 In amino acid proton is transfereed from one point to the other point and this dipolar ion is called
A. Oxonium ion B. Carbonium ion
✓ C. Zwi er ion D. Carbanion
Q.119 Hydrolysis of acetamide with dil.acid produces
A. Acetaldehyde ✓ B. Ace c acid
C. Ethanol D. Ethyl amine
Q.120 Boiling point point of propanoic acid is (In oC)
A. 100 B. 118
✓ C. 151 D. 160
Q.121 Salts of ________are colourless:
A. Copper B. Mn
C. Cr ✓ D. Zn
Q.122 Monohalo deriva ves of alkanes are called:
A. Alkenes B. A hypothesis
C. Amides ✓ D. Alkyl halides
Q.123 Which of the following derivates can not be prepared directly from ace c acid
✓ A. acetamide B. acetyl chloride
C. ace c anhydride D. ethyl acetate
Q.124 Carboxylic acid which shows highest M.P and B.P us
A. Ace c acid B. Acetamide
✓ C. Butyric acid D. Valeric acid
Q.125 Slight oxida on of primary alcohol gives
A. Ketones B. Organic acid
✓ C. Aldehyde D. An ester
Q.126 Which is not carboxylic acid with pungent smell?
A. Formic acid B. Ace c acid
C. Ethanoic acid ✓ D. Butyric acid
Q.127 Gluma c acid, aspar c acid are
Q.128 Carboxylic acids on complete reduc on in the presence if HI red phosphorus gives:
A. Esters B. Alcohols
✓ C. Alkanes D. Aldehydes
Q.129 Ace c acid is miscible in:
A. Water B. Alcohol
_______________________________________________________________________________________
C. Ether ✓ D. a, b, c
Q.130 Which reagent is used to reduce a carboxylic group to an alcohol?
A. H2/Ni B. H2/Pt
C. NaBH4 ✓ D. LiAIH4
Q.131
✓ A. III < II < I B. I < II < III

C. II < I < III D. Equal
Q.132 The rate of reac on determined at a given me is called:
✓ A. Specific rate B. Instantaneous rate
C. Average rate D. Overal rate
Q.133 Glacial ace c acid freezes to ice like solid at (°C):
A. 07 ✓ B. 17
C. 27 D. 37
Q.134 Acetamide acts as
A. Acidic B. Basic
✓ C. Amphoteric D. None of these
Q.135 The human body can synthesize _______ amino acids
A. 1 ✓ B. 10
C. 20 D. 19
Q.136 A compound X has all of the proper es below. It is a liquid at 25°C it mixes completely with water it reacts with
aqueous sodium hydroxide. What could X be
✓ A. Ethanoic acid B. Ethanol
C. Ethene D. Ethyl ethanoate
Q.137 C17H35COOH is the chemical formula of
✓ A. Stearic acid B. Palmi c acid
C. Malonic acid D. Oleic acid
Q.138 Vinegar contains a carboxylic acid known as
A. Citric acid ✓ B. Ethanoic acid
C. Nitric acid D. All of them
Q.139 When a carboxylic acid reacts with a metal __________ gas is evolved
✓ A. H2 B. CO2
C. Cl2 D. None of these
Q.140 Ace c acid forms dimmer in liquid phase due to
A. Great polarity ✓ B. Hydrogen bonding
C. High solubility D. Low ionizing constant
Q.141 Amylacetate flavor is present in:
✓ A. Banana B. Apple
C. Jasmine D. Orange
Q.142 The process of electrical coa ng of one metal on another to protect, decorate or to have a greater resistance to
corrosion is called:
A. Induc on ✓ B. Electropla ng
C. Electrolysis D. Conduc on
Q.143 The % age of ace c acid in vinegar is about
A. 20% B. 30%
C. 20 - 50% ✓ D. 6 - 10%
_______________________________________________________________________________________
Q.144 Carboxylic acids can generally be prepared by various methods. WHich of the following methods is not suitable for
making carboxylic acids
A. By the carbona on of Grignard reagent B. By the oxida on of primary alcohols
✓ C. By the hydrolysis of p-amines D. By the hydrolysis of nitrites
Q.145 Which of the following metal cannot evolve the hydrogen from the ace c acid
A. Sodium B. Potassium
C. Magnesium ✓ D. Copper
Q.146 Which of following organic compounds have fruity smell
A. Ethers ✓ B. Esters
C. Carboxylic acids D. Alcohols
Q.147 Which are used as essences(Flowers)?
C. Alcohols ✓ D. Esters
Q.148 Molecular mass of ace c acid in non-polar solvent like benzene should be
A. 30 g/mole B. 60 g/mole
C. 90 g/mole ✓ D. 120 g/mole
Q.149 Methyl cyanide on alkaline hydrolysis gives
A. HCOOH ✓ B. CH3CONH2
C. CH3OH D. CH3COOH
Q.150 A carboxylic acid contains
A. A hydroxyl group B. A carbonyl group
✓ C. A hydroxyl and carbonyl group D. A carbonyl and an aldehyde group
Q.151 Formic acid is stronger than ace c acid because of
A. Strong + l-effect in formic acid B. Stronger +R-effect in formic acid
✓ C. Stronger + l-effect in ace c acid D. Weaker +l-effect in ace c acid
Q.152 Organic compounds X and Y react together to form organic compound Z. What types of compounds can X, Y, and Z be
A. X Y ZAlcohol Ester Acid B. Acid Ester Alcohol
C. Ester Alcohol Acid ✓ D. Alcohol Acid Ester
Q.153 The acid present in the s ng of bees and wasps is
A. ace c acid ✓ B. formic acid
C. Formalin D. formaldehyde
Q.154 If a large number of amino acids (hundreds to thousands) are joined by pep de bonds, the resul ng product is called
A. dipe de B. tripep de
✓ C. polypep de D. none of these
Q.155 The OH group present in acids may be replaced by Cl atom on treatment with
A. PCl5 B. SOCl2
✓ C. both of them D. none of the above
Q.156 Mnocarboxylic acids exist as dimer decause of
A. Cohesive forses ✓ B. Hydrogen bonding
C. Van der Waal's forces D. Dipole-dipole a rac on
Q.157 Which reagent reduces carboxylic acid to alkane
✓ A. HI/P B. NaBH4
C. LiAIH4 D. H2/Pt
Q.158 In the esterifica on, first a ack is due to ______ on carboxylic acid
✓ A. Hydrogen ion B. Alcohols
C. Water D. All
Q.159 What is main reason for the fact that carboxylic acids can undergo ioniza on
A. High reac vity or alpha hydrogen B. Absence of alpha hydrogen
✓ C. Resonance stabiliza on of the carboxylate D. H-bonding
ion
Q.160 First six numbers (C1 to C6) of aliphateic carboxylic acids are in state:
_______________________________________________________________________________________
A. gas ✓ B. liquid
C. solid D. Semisolid
Q.161 Which of the following acid does not form anhydride when treated with P2O5
✓ A. HCOOH B. CH3COOH
C. CH3CH2COOH D. C6H5COOH
Q.162 With the increase in carbon no the solubility of carboxylic acids
C. Remains same D. None of these
Q.163 Ace c acid is synthesized on commercial scale from
✓ A. Acetylene B. Ethylene
C. Alcohols D. None
Q.164 The acid present in the s ngs of bees and wasps is
A. Ace c acid B. Formaldehyde
✓ C. Formalin D. Formic acid
Q.165 Which reagent is used to reduce a carboxylic group to an alcohol
A. N2/Ni B. H2/Pt
C. NaBH4 ✓ D. LiAlH4
Q.166 Mel ng point of carboxylic acids having even number of carbon atoms is then next and previous ood number of
carbon atoms:
A. 100 B. lower
C. the lowest ✓ D. higher
Q.167 Which method is not used for prepara on of alkenes:
A. Dehydra on of alcohols B. Dehalogena on of Vicinal dihalides
C. Dehydrohalogena on of alkyl halides ✓ D. Par al hydrogena on of alkanes
Q.168 When ace c acid and ethanol react together, an ester is formed which is called
A. ethyl ester B. ethanoic acid
C. ethanoic acid ✓ D. ethyl acetate
Q.169 Which following deriva ve cannot be prepared directly from ace c acid?
C. Ace c anhdride D. Ethyl acetate
Q.170 Acidic acid is manufactured by:
A. Dis lla on ✓ B. Fermenta on
C. Ozonolysis D. Esterifica on
Q.171 Oild and fats belong to the class of
A. Alcohols B. Acids
C. Hydrocarbons ✓ D. Esters
Q.172 Ethylbutyrate has flavour like
A. Banana B. Jasmine
✓ C. Pineapple D. Orange
Q.173 Which of the following is neutral amino acid
✓ A. Glycine B. His dine
C. Lysine D. Aspar c acid
Q.174 Which of the following is used as an essence of pineapple
A. Benzyl acetate ✓ B. Ethyl butyrate
C. Isobutyl formate D. Octyl acetate
Q.175 Which acid is used in the manufacture of synthe c fibre
A. Formic acid B. Oxalic acid
C. Carbonic acid ✓ D. Ace c acid
Q.176 Acetamide is prepared by
A. The hydrolysis of methyl cyanide B. Hea ng ethyl acetate
_______________________________________________________________________________________
C. Hea ng methyl acetate ✓ D. Hea ng ammonium acetate
Q.177 Which of the following statement is true about formic acid
✓ A. It is a reducing agent B. It is an oxidizing agent
C. It is weaker than ace c acid D. On hea ng its calcium salt it is converted into
ketone
Q.178 Those amino acids which contains two amino groups are called
Q.179 Which one of the following will react with both ethanol and ethanoic acid at room temperature
A. CaCO3 B. CuO
✓ C. Na-metal D. CH3OH
Q.180 A compound containing carboxyl group in them are called:
A. Ketone B. Ether
✓ C. Carboxylic acid D. Aldehyde
Q.181 Oxida on of 2-butene gives:
A. Ethanaol B. Ethanal
C. Ethanone ✓ D. ethanoic acid
Q.182 Ninhydrin reacts with amino acid to form product which has colour
A. Blue B. Violet
✓ C. Bluish violet D. Red
Q.183 The general formula of monocarboxylic acid
A. CnH2nO ✓ B. CnH2n+1COOH
C. CnH2nCOOH D. CnH2n-2COOH
Q.184 Carboxylic acids func onal group is:
✓ A. -COOh B. -COH
C. -CO- D. -OH
Q.185 The solu on of which acid is used for seasoning of food
Q.186 Pro stands for
A. Valine B. Alamine
C. Glycine ✓ D. Proline
Q.187 Which of the following statements about ace c, anhydride is not correct
A. it is immiscible with water but is hydrolysed to B. It is prepared by the ac on of acetyl chloride
give ace c acid on the sodium salt of ace c acid
C. it reacts with ammonia to give acetamide ✓ D. it is a strong acid
Q.188 The M.P. of carboxylic acids containing even number of carbon atoms is __________ than the next
✓ A. Higher B. Low
C. Equal D. None
Q.189 Compound X and Y give effervences with Na2CO3solu on, X gives a white ppt with ammonical AgNO3while Y gives
sweet smell compound on hea ng with alcohol X and Y are
✓ A. Formic acid and ace c acid B. Acetone and formic acid
C. Acetaldehyde ace c acid D. Ace c acid and acetone
Q.190 Boron, carbon, nitrogen and oxygen have the following order of increasing ioniza on energy:
✓ A. B,C,O and N B. B,C,N and O
C. B, O, C and N D. O, B, C and N
Q.191 An ar ficial smell of banana is produced in many ar cles by using esters. Which of the following is that
A. Isoal valerate B. Methyl butyrate
C. Octyl acetate ✓ D. Amyl acetate
Q.192 Which one of the following deriva ves can not be prepared directly from ace c acid
_______________________________________________________________________________________
Q.193 The common name of propanoic acid is
A. ace c acid B. formic acid
✓ C. propionic D. butyric acid
Q.194 Carboxylic acids on reduc on with LiAIH4 are converted to
A. Alkanes ✓ B. Primary alcohols
C. Esters D. None
Q.195 The most used medicinal ester is
A. HCOOCH3 B. CH3COOC2H5
✓ C. Aspirin D. None of these
Q.196 In the forma on of pep de bond water is remove, the H is provide by
✓ A. Amino group B. Carboxylic acid
C. Alcohols D. Both A and B
Q.197 Tryosine was isolated from
A. Bu er ✓ B. Cheese
C. Oils D. Fats
Q.198 Acetamide is prepared by:
✓ A. Hea ng ammonium acetate B. Hea ng methyl cyanide
C. Hea ng ethyl acetate D. The hydrolysis of methyl cyanide
Q.199 The acid used to remove rust stains on cloth is
A. Fumaric acid B. HCl
C. Formic acid ✓ D. Oalic acid solu on
Q.200 The process of filtra on is used to separate:
A. Solute from solu on B. Two immiscible liquids
✓ C. Insoluble par cles from liquids D. Two miscible liquids
Q.201 When hydrogen cyanide is added to an Aldehyde in the presence of ammonia it is called
✓ A. Strecker synthesis B. Corey house synthesis
C. Williamson's synthesis D. None of these
Q.202 By conven on a pep de having molecular mass upto 10,000 is called
A. Pep de ✓ B. Polypep de
C. Protein D. Dipep de
Q.203 Sulphuric acid in a anhydride of:
A. Sulphurous acid B. Sulphuric acid
C. Hudrosulphuric acid ✓ D. Hypo sulphuric acid
Q.204 Glucose form a polymer which is stored in liver name of this polymer is:
A. Cellulose B. Starch
C. Amylose ✓ D. Glycogen
Q.205 Which one of the following contains carboxylic group
A. Picric acid B. Carbolic acid
✓ C. Glutamic acid D. All above
Q.206 Carboxylic acids react with metals to form salts with the evolu on of
A. CO2 ✓ B. H2
C. CO D. CH4
Q.207 Acid which can decolorizes acidified KMnO4 is
A. Salicylic acid B. Benzonic acid
✓ C. Formic acid D. All
Q.208 The reac on of alcohol with ace c acid is called as
A. Hydrolysis ✓ B. Esterifica on
C. Ammonolysis D. Sponifica on
Q.209 When a carboxylic acid reacts with alcohol, it produces a new class of compounds
_______________________________________________________________________________________
A. ethers ✓ B. esters
C. anhydride D. amides
Q.210 Which is the following is not use of ace c acid
A. As coagulant for latex B. In medicin as a local irritant
C. In the manufacture of pickle ✓ D. None of these
Q.211 Which of the following method is the most suitable to a ain a pure and dry sample of NaCI from a mixture of solid
NaCl and sand?
✓ A. Shake the mixture with 2O and dis l the B. Shake the
2
O fiter and dry the
H liquid mixture with H substance on the filter
C. Heat the mixture gently and collect the D. Shake the mixture O filter and evaporate the
2
substance which melts with H filtrate
Q.212 Ester are pleasant smelling compounds.Which ester posseses odour pineapple
A. amylacetate B. amylbutyrate
✓ C. ethylbutyrate D. benzylacetate
Q.213 Molecular mass determina on analysis shown that carboxylic acids exist as:
A. Simple molecules B. Simple monomers
C. Cyclic monomer ✓ D. Cyclic dinner
Q.214 Acyl chlorides are highly
A. Unreac ve ✓ B. Reac ve
C. Stable D. All of them
Q.215 Rec fied spirit contains concept that ether behave as:
A. Acid B. Base
✓ C. Acid and base D. None these
Q.216 During esterifica on, protona on of carboxylic acid occurs at
✓
A. B.
C. D.
Q.217 Carboxylic acids can generally be prepared by various methods. Which of the following methods is not suitable for
making carboxylic acids.
A. by the oxida on of primary alcohols B. by the hydrolysis of nitries
C. by the carbona on of Grignard, reagent ✓ D. by the hydrolysis of p-amines
Q.218 Stronger acid is
A. CH3COOH B. CCI3COOH
C. CBr3COOH ✓ D. CF3COOH
Q.219 The most reac ve deriva ve of carboxylic acid is
A. Acid amide B. Acid chloride
✓ C. Acid anhydride D. Ester
Q.220 Which one is the formula of borax?
A. Na2B4O7, 4H2O B. Na2B4O7. 7H2O
C. Ca2B6O11, 5H2O ✓ D. Na2B4O7, 10H2O
Q.221 A carboxylic acid contains:
A. A hydroxyl group ✓ B. A carboxyl group
C. A hydroboxyl and carboxyl group D. A carboxyl and aldehyde group
Q.222 Solubility of carboxylic acids in water are due to bonding:
C. Coordinate covalant ✓ D. Hydrogen
Q.223 Esters have peculiar smell. Which of the following is used as an essence of orange:
✓ A. Octylacetate B. Methly butyrate
C. Isoami valerate D. Isoami acetate
Q.224 Ac ve metals react with carboxylic acids releasing gas:
A. CO B. CO2
_______________________________________________________________________________________
C. H2O as steam ✓ D. H2
Q.225 A compound reacts with Mg in presence of ether the product upon reac on with CO2and on hydrolysis gives an
organic compound. The product is
A. Primary alcohol ✓ B. An organic acid
C. Aldehyde D. Ketone
Q.226 Pep de bonds in tripep de are
A. 01 ✓ B. 02
C. 03 D. 04
Q.227 Which acid is used in the manufacture of synthe c fibre?
A. Formic acid B. Oxalic acid
C. Carbonic acid ✓ D. Ace c acid
Q.228 A pep de having molecular mass upto 10,000 is called a
A. vitamin ✓ B. protein
C. polypep de D. dipe de
Q.229 Ace c acid is manufactured commercially By
A. Dis lla on ✓ B. Fermenta on
C. Etherifica on D. Ozonolysis
Q.230 The simplest of all amino acid
A. Lysine ✓ B. Glycine
C. Alanine D. Aspar c acid
Q.231 Vinegar is dilute solu on if:
✓ A. Ace c acid B. Formic acid
C. Butyric acid D. Propionic acid
Q.232 Vinegar is
✓ A. 7 - 8 CH3COOH B. Glacial ace c acid
C. Pure ace c acid D. Any one of these
Q.233 The Solvent is selected for crystalliza on process of a substance on the basis of:
A. IT non-polar nature B. Its polar nature
C. It should react chemically ✓ D. On hit and trial basis
_______________________________________________________________________________________
19 Amino Acids
Q.1 On electrophoresis for plasma proteins using buffer of pH 8.6

A. The proteins are neutral ✓ B. The proteins carry nega ve charge
C. The proteins carry posi ve charge D. The proteins are easily precipitated
Q.2 Second order of protein structure refers to
A. Number and sequence of amino acids B. Three dimensional structure of protein
C. Proteins formed of more than one monomer ✓ D. Bending of protein molecule
Q.3 Glucose is a:
A. ketohexose B. aldohexose
✓ C. meonosacharide D. 'b' and 'c'
Q.4 Fa y acids are:
✓ A. Alipha c mono-carboxylic acids B. Di-carboxylic acids
C. Tri-carboxylic acids D. Tetra carboxylic acids
E. Poly carboxylic acids
Q.5 Which method is not used in prepara on of ace c acid?
A. Oxida on of ethane B. Hydrolysis of ethyl acetate
C. Reac on of CO2with CH3MgX ✓ D. Oxida on of methane
Q.6 In which of these processes are small organic molecules changed into macromolecules?
A. the frac onal dis lla on of crude oil B. the cracking of petroleum frac ons
C. the hydrolysis of proteins ✓ D. the polymeriza on
Q.7 An amion acid exists in the form of Zwi er-ioin which has:
A. one + ve charge B. one - ve charge
C. one +ve and -ve charge ✓ D. two +ve charge
Q.8 Amino acid produce α-hydroxy carboxylic acid when treated with
A. KNO3/HBr B. Zn/HCI
✓ C. NaNO2/HCI D. Pd/BaSO4
Q.9 On hydrolysis sucrose gives:
A. glucose and maltose B. fructose and lactose
C. fructose and maltose ✓ D. glucose and Fructose
Q.10 Globulin is
A. A basic protein B. A protein of low molecular weight
✓ C. Heat coagulable protein D. Easily soluble in water e.A fibrous protein
Q.11 Zwi er ion are
A. Basic B. Acidic
C. Neutral ✓ D. Carry both -ve and +ve charges
Q.12 Hydrolysis of alkyl nitriles gives:
A. Alkane B. Alkyl halide
C. Alkyl nitride ✓ D. Minerals acids & Alkalies
Q.13 The energy produced by a carbohydrate is:
A. 3 kcal/gm B. 2kcal/gm
C. 6kcal/gm ✓ D. 4kcal/gm
Q.14
_______________________________________________________________________________________
The structure of a polymer depends upon how the monomer-repea ng unit joins to makes a polymer, What is not the
type of structure of a polymer?
✓ A. synthe c polymer B. linear polymer
C. branched D. cross linked or inter connected polymer
Q.15 Enzymes that catalyse the transfer of groups within the molecules are called:
✓ A. transferases B. isomerases
C. ligases D. lyases
Q.16 Plas cs are a pollu on problem because may plas cs:
A. burn to produce toxic fumes ✓ B. decompose to produce tocxic products
C. are made from petroleum D. are very inflammable
Q.17 Aldehydes are easily oxidized to corresponding carboxylic acids in the presence of:
A. Strong oxidizing agents B. Highly strong oxidizing agents
C. Tollen's reagent ✓ D. Tollen's reagent and Fehling solu on
Q.18 One gram of Carbohydrate yield energy:
✓ A. 4Kcal B. 9Kcal
C. 10Kcal D. 100Kcal
Q.19 Methyl butyrate has an smell of:
A. apple ✓ B. pine apple
C. banana D. winter green
Q.20 Plasma proteins are separated by
A. Dialysis ✓ B. Electrophoresis
C. Filtra on D. Alcohol precipita on
Q.21 Rancidifica on of fast and oils is due to:
A. hydrolysis reac on B. oxida on reac on
C. both a and b ✓ D. hydrogena on reac on
Q.22 Which woody raw material is used of the manufacture of paper pulp?
A. co on B. bagasse
✓ C. poplar D. rice straw
Q.23 Which of the following is most found in protein molecule
✓ A. Carbon B. Hydrogen
C. Oxygen D. Nitrogen
Q.24 The op mum pH value for the enzyme ''Pepsin'' is:
A. 2 B. 8
C. 10 ✓ D. 1.4
Q.25 Amino acids are bifunc onal organic compounds what are the two func on groups
A. Carboxylic acid and alcohol B. Acohol and aldehyde
C. Carboxylic acids and ketone ✓ D. Amino group and carboxylic acid
Q.26 All of the following are non covalent except
A. Hydrophobic interac ons ✓ B. Disulphide bond
C. Hydrogen bond D. Electrosta c bond
Q.27 Which of the following is precursor of T3 and T4
A. Gaba B. Dopa
C. B-Alanine ✓ D. Di-iodotyrosine
Q.28 Formic acid is given name from La n word a "formic" which means:
✓ A. Red out B. Vinegar
C. Bu er D. Milk
Q.29 Steroid belong to the family of:
A. protein B. enzyme
✓ C. lipids D. carbohydrates
Q.30 The pep de bond is
_______________________________________________________________________________________
✓ A. Glycine B. Non-covalent bond
C. Weak bond D. Responsible for secondary structure of protein
Q.31 Amino acids are building material of:
A. lipids ✓ B. protein
C. carbohydrates D. fats
Q.32 N terminal of glutathione is
A. Glycine B. Cysteine
✓ C. Glutamate D. Aspartate
Q.33 The development of industries was a direct result of which major factor
A. popula on B. living standards
C. deple on of resources ✓ D. all of these
Q.34 Condensa on occurs between amino acids with the elimina on of
✓ A. H 2O B. H2
C. O2 D. NH3
Q.35 Which substances do nto react immediately with bromine water:
✓ A. ethane B. benzene
C. ethene D. phenol
Q.36 Silk is an example of
✓ A. animal fiber B. vegetable fibre
C. mineral fibre D. none of these
Q.37 Always carboxylic acid produced will have number of carbon atoms from carbon atom in alkyl nitriles:
A. One more B. Two more
C. Equal & same ✓ D. One less
Q.38 Albumins and globulins are defined as
A. Derived protein B. Conjugated protein
C. Fibrous protein ✓ D. Globular protein
Q.39 Malt sugar is converted into glucose by an enzyme invertase present in yeast. The process is known as:
A. dehydra on B. condensa on
✓ C. fermenta on D. oxida on
Q.40 One of the following is po cally non ac ve amino acid
A. Valine B. Tyrosine
✓ C. Glycine D. Theronine
Q.41 Amino acid α-hydroxy carboxylic acid and
A. CO2gas B. H2gas
✓ C. N2gas D. NH3gas
Q.42 Which one of the following is a water soluble vitamin?
A. niacin B. rioflavin
✓ C. trypsin D. ascorobic acid
Q.43 Rancidifica on of facts and oils is due to:
A. oxida on reac on B. hydrolysis reac on
✓ C. both a and b D. hydrogena on reac on
Q.44 At present the number of cement factories is Pakistan are
A. 20 ✓ B. 22
C. 25 D. 30
Q.45 All of the following are hydroxy containing amino acids except
A. Serine B. Threonine
✓ C. Valine D. Tyrosine
Q.46 The reac on between fat and NaOH is called:
A. esterifica on B. hydrogenolysis
C. fermenta on ✓ D. sponifica on
_______________________________________________________________________________________
Q.47 The op mum PH value fro the enzyme pepsin is:
A. 10 ✓ B. 1.4
C. 2 D. 8
Q.48 Example of non-protein amino acid
A. Alanine ✓ B. Citrulline
C. Phenylalanine D. Leucine
Q.49 General formula of alipha c carboxylic acids:
A. R-OH B. R-COH
C. R-CO-R ✓ D. RCOOH
Q.50 Carboxylic acids can be prepared from:
A. Oxida on of alkane B. Oxida on of alcohols
C. Oxida on of aldehydes ✓ D. All of these
Q.51 The fat soluble vitamins are:
A. A and B ✓ B. B and C
C. C and D D. A and D
Q.52 Which of the following is an example of aldohexose?
A. Ribose B. Sucrose
C. Fructose ✓ D. Glucose
Q.53 Iodine number of an oil indicates its:
A. molecular weight B. purity
C. degree of unsatura on ✓ D. acidic strength
Q.54 Which of these polymers is an addi on polymer?
A. nylon 6,6 ✓ B. Polystyrene
C. terylene D. epoxy resin
Q.55 Ace c acid is obtained from:
A. Red out ✓ B. Vinegar
C. Bu er D. Milk
Q.56 Polypep des are formed from amino acids by
A. Oxida on B. Addi on
✓ C. Condensa on D. Reduc on
Q.57 A fat or oil is characterized for extent of unsatura on by one of the following number. Which one is:
A. acid number B. saoilucfuca on umber
C. rancidity number ✓ D. iodine number
Q.58 Glycine is characerized by
A. Absence of an asymmeteric carbon B. Absence of op cal ac vity
C. The shortest amino acid ✓ D. All of these
Q.59 A molecule oilgosacharide on hydrolysis produces _____ molecules of monosacharide:
A. 1 B. 2
C. 4 ✓ D. 6
Q.60 The mechanism of polymeriza on involves free addi on Polymeriza on or condensa on polymeriza on, Choose the
correct statement:
A. Polyester is an addi on polymer ✓ B. polythene is an addi on polymer
C. polyviny chloride (PVC) is a condensa on D. Polystyrene
polymer
Q.61 one gram of carbohydrate yields energy:
A. 10kcal B. 100kcal
✓ C. 4kcal D. 9kcal
Q.62 Which of the following pro en is found in bone
A. Kera n ✓ B. Ossein
C. Mucin D. Ac n
Q.63 All of the following are polar amino acids except
_______________________________________________________________________________________
A. Serine B. Glutamate
C. Arginine ✓ D. Alanine
Q.64 All of the following are alipha c amino acids except
A. Glycine B. Alanine
✓ C. Proline D. Lysine
Q.65 Which one of the following organic acids is made fork methanol?
A. propanoic acid B. butanoic acid
✓ C. formic acid D. ace c acid
Q.66 A molecule of polysaccharide hydrolysis produces __________ molecules of:
A. 2 B. 3
✓ C. 2-10 D. 100
Q.67 A polymeric substance that is formed in the liquid state and then hardened to a rigid solid is called:
A. fiber ✓ B. plas c
C. varnish D. polyamide resin
Q.68 Keratomalacia is caused due to the deficiency of vitamin:
A. A ✓ B. B
C. C D. K
Q.69 Water soluble and cyrstalline carbohydrrates are:
A. monosacharides B. obiligoseacharides
✓ C. polysacharides D. a and b
Q.70 Which one of the following element is not present in all proteins?
C. nitrogen ✓ D. sulphur
Q.71 Aspar c acid is a (an)
✓ A. Monoamino dicarboxylic acid B. Diamino Monocarboxylic acid
C. Aroma c amino acid D. Imino acid
Q.72 Which woody raw material is used for the manufacture of paper pulp?
A. co on B. bagasse
✓ C. poplar D. rice staw
Q.73 NO. of naturally occuring aminoacids is
A. 10 ✓ B. 20
C. 30 D. 40
Q.74 The molecular mass of a polymer is obtained by mul plying mass of the monomer unit with the degree of
polymeriza on, The degree of polymeriza on of PVC is 1000.What is molecular mass?
A. 65000 ✓ B. 63000
C. 62000 D. 60000
Q.75 pH value of pepsin is:
A. 3 B. 2
C. 4 ✓ D. 1.4
Q.76 Detergents are
✓ A. synthe c products B. natural products
C. both a and b D. none of the above
Q.77 The amino group in 19 alpha-amino acids is primary; only one alpha-amino acid has secondary amino group which one
is that
A. Alanine B. Glutamic acid
C. Glycine ✓ D. Proline
Q.78 Common names of carboxylic acids are given by then:
✓ A. Source B. Person discovered
C. Place D. Habit
Q.79 Which one of the following statements about glucose and sucrose is incorrect:
_______________________________________________________________________________________
A. both are soluble in water B. both are naturally occurring
C. both are carbohydrates ✓ D. both are disacharides
Q.80 Formula of stearic acid is:
A. C11H23COOH B. C13H27COOH
C. C15H31COOH ✓ D. C17H35COOH
Q.81 Which is not an amino acid
A. Lysine B. Gylcine
C. Alanine ✓ D. Aniline
Q.82 Which of the following is basic amino acid
A. Lysine B. His dne
C. Proline ✓ D. Both a and b
Q.83 In the body carbohydrates are broken down into:
✓ A. glucose B. fa y acids
C. amino acids D. nucleic acid
Q.84 Which is not a calcareous material?
A. lime ✓ B. clay
C. marble D. marine shell
Q.85 Which one is non-reducing sugar?
A. sucrose B. glucose
C. fructose ✓ D. galactose
Q.86 Cholesterol is a precursor of steroid hormones, Choose the class of steroid:
A. a carbohydrate B. a hydrocarbon
✓ C. a natural lipid D. a protein a hydrocarbon
Q.87 Starch is a polymer is of:
A. sucrose B. fructose
C. α-D-Glucose ✓ D. lactose
Q.88 Which of these polymers is a synthe c polymer?
A. animal fat B. starch
C. cellulose ✓ D. polyester
Q.89 Thermoplas c polymer can be so ened and hardened when cool repeatredly, Which one is not a thermoplas c among
he following?
✓ A. epoxy resin B. PVC
C. Plas c toys D. none of all
Q.90 Sponifica on is the hydrolysis of fats or oil with an:
✓ A. alkali B. base
C. enzyme D. metallic ion
Q.91 Per hydro cyclopentanone phenantherene is the basic structural of all the.
A. Waxes B. vitamins
✓ C. proteins D. steroids
Q.92 Separa on of low molecular weight protein from high one is
✓ A. Dialysis B. Cromotography
C. Electrophoiesis D. Ultracentrifuga on
Q.93 The unit of pep des is
A. Moiety B. Residue
C. Polypep de ✓ D. Both A and B
Q.94 Increase viscosity of proteins is due to
✓ A. Denatura on B. Isoelectric point
C. Both D. None
Q.95 Ornithine is
✓ A. A basic amino acid B. An essen al amino acid
_______________________________________________________________________________________
C. Present in protein structure D. All of these
Q.96 Plas cs are pollu on problem because many plas cs:
A. are made from petroleum B. are very inflammable
C. burn to produce toxic fumes ✓ D. decompose to produce toxic products
Q.97 Benedict solu on gives a posi ve test with but catalyze the same reac on:
A. fructose B. glucose
C. starch ✓ D. sucrose
Q.98 How many zones through which the charge passes in a rotary kiln?
A. 4 B. 3
✓ C. 2 D. 5
Q.99 Which method is used to prepare carboxylic acid?
A. Hydrolysis of AI4C3 B. Hydrolysis of CaC2
✓ C. Hydrolysis of alkyl nitrites D. Hydrolysis of alkenes
Q.100 Palmi c acid & steanic acid are obtained from process of fats & oils:
A. Reducing B. Neutraliza on
C. Oxida on ✓ D. Hydrolysis
Q.101 Example of essen al aroma c amino acids
A. Theronine B. Alanine
✓ C. Phenyl alanine D. Glycine
Q.102 polymerisa on of vinyl chloride gives PVC:
How does the carbon-carbon bond in PVC compare with that in chloroethene?
✓ A. longer and stronger B. fructose
C. sucrose D. starch
Q.103 Collagen contains high percentage of
✓ A. Glycine B. Tryptophan
C. Phenyl Alanine D. Serine
Q.104 Fourth structure of protein structure refers to
✓ A. Proteins formed of more than one monomer B. Myoglobin is an example
C. Depends on covalent bonds D. None of these
Q.105 Which process of ester will yield carboxylic acid?
A. Hydra on ✓ B. Hydrolysis
C. Oxida on D. Reduc on
Q.106 The ac ve group of glutathione is
A. Amino group ✓ B. Sul ydryl group
C. Carboxylic group D. Imino group
Q.107 All amino acids are op cally ac ve except
A. Amino acid ✓ B. Series
C. Threonine D. Tryltophan
Q.108 A maltose molecule is formed by the combina on of:
✓ A. two glucose molecules B. one glucose and one fructose
C. molecule D. one glucose and one galactose
Q.109 Which one of the following enzymes brings about the hydrolysis of fats?
A. urease B. maltase
C. zymase ✓ D. lypase
Q.110 Which of the following is BLOOD iron carrier
A. Haemoglobin B. Albumin
✓ C. Transferrin D. Globulin
Q.111 During the manufacturing process of cement the temperature of the decomposi on zone goes up to
A. 600°C ✓ B. 800°C
C. 1000°C D. 1200°C
_______________________________________________________________________________________
Q.112 Albumins are separated by
A. 1/2 saturated ammonium sulfate ✓ B. Full saturated ammonium sulfate
C. 20% saturated ammonium sulfate D. 60% saturated ammonium sulfate
Q.113 Ter ary structure of proteins involves EXCEPT
A. Domains B. Globular
C. Fibrous ✓ D. Beta sheets
Q.114 Example of basic essen al amino acids
A. Arginine B. His dine
C. Lysine ✓ D. All of the above
Q.115 Primary structure of proteins refers to
A. Coiling and folding in form of specific ✓ B. Number of amino acids in a chain
structure
C. 3d structure
D. Alpha and Beta sheets
Q.116 Types of bonds between C terminal and N terminal is
✓ A. Covalent B. Disulphide bond
C. Pep de D. Ionic
Q.117 Lecithin is an example of:
A. A simple lipid ✓ B. Phospholipids
C. Waxes D. Proteins
Q.118 Carboxylic acid having more than one carboxyl group are called:
A. Mono-carboxylic acid B. Di-carboxylic acid
C. Tri-carboxylic acid ✓ D. Poly carboxylic acid
Q.119 A molecule of polysacharide on hydrolysis produces __________of molecules of monosacharide,
✓ A. 2 - 10 B. 3
C. >10 D. 2
Q.120 Nylon 6,6 is a condensa on polymer of:
A. Phthalic acid and hexa ethylene diamine ✓ B. adipic acid and hexaethylene diamine
C. phthalic acid and glycerol D. phthalic acid and glycerol
Q.121 Elimina on of molecular reac ons usually obey:
✓ A. first order kine cs B. second order kine cs
C. third order kine c D. zero order kine c
Q.122 Monosacharides belong to the group:
A. fats B. lipids
✓ C. carbhohydrates D. proteins
Q.123 Starch gives ________ color with iodine:
✓ A. blue B. red
C. yellow D. green
Q.124 Keratomalacia is caused due to the d3eficiency of vitamin:
✓ A. A B. B
C. K D. D
Q.125 Which one of the following organic acids is made form methanol?
A. ace c acid B. bothanic acid
✓ C. formic acid D. propanoic acid
Q.126 Chloroethene, CH2 = CHC/ is the monomer of PVC.
What are the C-C-C bond angles along the polymeric chain in PVC?
✓ A. They are all 109.5° B. half are 109.5° and half are 120°
C. They are all 120° D. They are all 180°
Q.127 Deposi on of cholesterol in arteries is responsible for:
✓ A. Heart a ach B. diabetes
C. hepa s D. cancer
_______________________________________________________________________________________
Q.128 Denatura on of protein means the structure of protein is disrupted indicate which factor does not denature protein
A. oxidizing agent B. heat protein
✓ C. keeping pH 7.35 D. pH changes
Q.129 Monosacharide belongs to the groups:
A. fats B. carbohydrates
C. lipids ✓ D. proteins
Q.130 The buffering property of proteins is due to the presence of
✓ A. Acidic and basic group B. Hydrogen bonds
C. Indole group D. Hyrophobic
Q.131 Amino acids ionize in water to form
A. Zwi erion B. Internal saH
C. Dipolar ion ✓ D. All of these
Q.132 Sponifica on is the hydrolysis of fast or fats or4 oils with an/a:
✓ A. acid B. alkali
C. enzyme D. metallic ion
Q.133 Macro-nutrients are required in quan es ranging from
✓ A. 5 kg - 200 kg B. 2 kg - 100 kg
C. 1 kg - 50 kg D. 10 kg - 100 kg
Q.134 Sex harmones belong to a group of organic compounds called:
A. heterocyclics B. steroids
C. amino acids ✓ D. amines
Q.135 Formic acid is obtained from red out by:
✓ A. Dis lla on B. Crystalliza on
C. Filtra on D. Sublima on
Q.136 Butyric acid was named from butyrum means:
A. Red out B. Vinegar
✓ C. Bu er D. Milk
Q.137 An amino acid exists in the form of Zwi er-ion Which has:
A. one - ve charge B. one + ve charge
C. two + ve carges ✓ D. one + ve and one -ve
Q.138 Which is the op mum temperature for the ac vity of enzyme?
A. 20 - 35°C B. 10 -15°C
C. 55 - 70°C ✓ D. 35 - 55°C
Q.139 The destruc on of the biological nature and ac vity of proteins by heat or chemical agent is called:
A. Dehydra on B. Oxida on
✓ C. Denatura on D. Polymeriza on
Q.140 Lac c acid is buffered by
✓ A. L. Carnosine B. Glutathione
C. Casenogin D. Dopa
Q.141 Kera n is
A. Protein of tendons ✓ B. Rich in sulfur
C. Poor in cysteine D. Conjugated protein
Q.142 CH3CH2COOH is also named as:
A. Propionic acid B. Propanoic acid
C. Ace c acid ✓ D. Both (a) & (b)
Q.143 Isozymes are the enzymes which:
A. have similar chemical proper es B. have similar physical proper es
C. have different physical and chemical ✓ D. have different physical and chemical
proper es proper es
Q.144 Hydrolysis of protein by 6M HCl gives pep des and then alpha-amino acids. How many alpha-amino acids molecules
are obtained on the hydrolysis of a tetrapep de
_______________________________________________________________________________________
A. 2 B. 3
✓ C. 4 D. 5
Q.145 Aroma c carboxylic acids have corboxyl group a ached to group:
A. Alkyl group ✓ B. Aryl group
Q.146 Lipids are naturally occurring compounds produced in cell and are water insoluble but soluble in organic solvent one of
the following is not a lipid, Select among the following:
✓ A. nucleic acid B. atriglceride
C. sterol D. vitamin D
Q.147 Which of the following alpha-Amino acids has basic R-group
A. Proline B. Glutamic acid
✓ C. His dine D. Valine
Q.148 Amino acid which has cyclic structural is
✓ A. Proline B. Valine
C. Alanine D. Glutamic acid
Q.149 Caseinogen is
A. Simple protein B. Derived protein
✓ C. Phosphoprotein D. Rich in sulfur containing amino acids
Q.150 Potency and turn over are terms related to:
✓ A. enzymes B. proteins
C. fats D. oils
Q.151 Carboxylic acids having carboxyl group one is called:
✓ A. Mono carboxylic acid B. Di-carboxylic acid
C. Teri-carboxylic acid D. Tetra carboxylic acid
Q.152 A pep de having molecular mass of more than 10,000 is called as
A. Fat B. Vitamin
C. Carbohydrate ✓ D. Proteins
Q.153 The number of paper industries in Pakistan are
✓ A. 30 B. 25
C. 35 D. 20
Q.154 Macromolecules or polymers are large molecules built up from small m0lecules known as monomers.This hypothesis
put forward by:
A. Newton B. schrodinger
✓ C. Lewis D. Stadinger
Q.155 Per hydro cyclopentano phenathrene is the basic structure of all the:
A. Proteins B. vitamins
✓ C. waxes D. amines
Q.156 Carboxylic acid is given name by replacing "a" of alkane by:
✓ A. "oic" acid B. "one"
C. "al" D. "ol"
Q.157 The fiber which is made from acrylonitrile as monomers:
A. PVC B. rayon fiber
✓ C. acrylic fiber D. Polyester fiber
Q.158 Which one of the following is not type of polymer:
A. copolymer B. homopolymer
C. terpolymer ✓ D. hereropolymer
Q.159 Arginine, lysine and ornithine are
A. Obtained by hydrolysis of proteins B. Essen al amino acids
✓ C. Basic amino acids D. Derived from butyric acid
Q.160 The word paper is derived from the name of which reedy plant
_______________________________________________________________________________________
A. rose B. sun flower
✓ C. papyrus D. water hyacinth
Q.161 Choose an addi on polymer among the following:
✓ A. terylone B. nylon 6,6
C. polystyrene D. epoxy resin
Q.162 A molecule of polysaccharide on hydrolysis produces _________ molecules of monosacharides:
✓ A. many B. Few
C. 2-10 D. 100
Q.163 Diges on of carbohydrates begins in the:
A. large intes ne B. small intes ne
C. duuoderium ✓ D. beccal cavity/mouth
Q.164 Albumin, globin and casein are
✓ A. Milk proteins B. Plasma proteins
C. Egg proteins D. Meat proteins
Q.165 Carboxylic acid having two carboxyl group are:
A. Mono-carboxylic acid ✓ B. Di-carboxylic acid
C. Tri-carboxylic acid D. Tetra carboxylic acid
Q.166 Essen al alpha-amino acids are those which are necessary in the diet.
Which one is an essen al alpha-amino acids
A. Alanine B. Aspar c acid
C. Glycine ✓ D. Tryptophan
Q.167 Type of bond between nitrogen and carbonyl group
✓ A. Hydrogne bonds B. Covalent bond
C. Pep de bond D. Disulphide bond
Q.168 Ace c acid is also named:
A. Methanoic acid ✓ B. Ethanoic acid
C. Propanoic acid D. Butanoic acid
Q.169 Which one among the following is not a natural polymer?
A. protein B. cellulose
✓ C. nylon D. nucleic acid
Q.170 Which of the following represents pep de linkage
A. -C=N- ✓ B. -CO-NH-
C. -CH2-NH- D. -CH-NH-
Q.171 Carboxylic acid having three carboxyl groups are:
A. Mono carboxylic acid ✓ B. Di-carboxylic acid
C. Tri-carboxylic acid D. Tetra carboxylic acid
Q.172 All of the following are essen al amino acids except
A. Lysine ✓ B. Aspartate
C. Tryptophan D. Hisi dine
Q.173 Which of the following is not a carbohydrate?
✓ A. nuclic acid B. strach
C. glycoyen D. cellulose
Q.174 Amino acids which contain two amino groups are called
A. Acidic amino acids ✓ B. Basic amino acids
C. Neutral amino acids D. Amphoteric amino acids
Q.175 Benedict solu on gives a posi ve test with:
✓ A. glucose B. frutose
C. sucrose D. starch
Q.176 Nihydrin reacts with amino acid to give product of
A. Bluish color B. Violet color
_______________________________________________________________________________________
✓ C. Bluish violet color D. No color
Q.177 Coenzymes are the species which increase the ac vity of enzymes. They are chemically:
✓ A. metal ions B. none - metals
C. organic acids D. organic bases
Q.178 Third structure of protein structure refers to
A. Number and sequence of amino acids ✓ B. Three dimensional structure of protein
C. Proteins formed of more than one monomer D. Bending of protein molecule
Q.179 Carboxylic acid can be prepared from the reac on of Grigard's reagent with:
C. Formaldehyde ✓ D. CO2
Q.180 Protein of high biological value
✓ A. Contains essen al amino acids B. Is poor in essen al amino acids
C. Is of plant source D. Contains amino acid glycine e. Is a basic
protein
Q.181 Sponifica on is the hydrolysis of fats or oil with an/a:
A. enzyme B. me5tallic ion
C. acid ✓ D. alkali
Q.182 Cyclonite is a powerful:
✓ A. explosive B. an sep c
C. analgesic D. an -inflammatory
Q.183 Vegetables oils are:
A. unsaturated fa y acids ✓ B. glycerides of unsaturated fa y acids
C. glycerides of saturated fa y acids D. essen al oils obtained from plants
Q.184 A complete food contains at least:
A. three nutrients B. ten nutrients
✓ C. six nutrients D. eight nutrients
Q.185 A protein rich in proline and hydroxy proline is
A. Globin ✓ B. Collagen
C. Casein D. Histone
Q.186 In the body fats are hydrolysed into:
A. fa y acid and water B. fa y acid
C. glycerol and water ✓ D. acid and glycerol
Q.187 The chemical reac vity of glass is reduced by the use of
A. fluxes B. formers
✓ C. stabilizers D. none of the above
Q.188 Casenogen is
A. Chromoprotein ✓ B. Phosphoprotein
C. Glycoprotein D. Lipoprotein
Q.189 Which is not an essen al amino acid
A. Leucine B. Methionine
✓ C. His dine D. Lysine
Q.190 Reac on of alkyl halides with potassium cyanide in the presence of alcohols give:
A. Carboxylic acids B. Aldehydess
✓ C. Alkyl nitriles D. Acid amides
Q.191 Carboxylic acid can be prepared from:
A. Hydrolysis of alkyl nitrites B. Reac on of CO2with Gringard's reagent
C. Hydrolysis of esters ✓ D. All of these
Q.192 Most animals can not digest:
A. starch ✓ B. cellulose
C. proteins D. glucose
_______________________________________________________________________________________
Q.193 One of the following is not a biopolymer,Point out that one:
A. lipid B. starch
✓ C. diamond D. protein
Q.194 Which of the following is sulphur highly containing protein
A. Collagen ✓ B. Kera n
C. Ossein D. Re culin
Q.195 One of the following is neutral amino acid
A. Arginine B. Lysine
✓ C. Glutamine D. Valine
Q.196 Daily protein intake for normal adults should be:
A. 0.2g/kg B. 0.5g/kg
✓ C. 0.8g/kg D. 1.1g/kg
Q.197 Glucose forms a polymer which is stored in liver the name of this polymer is:
A. glycogen B. starch
C. cellulose ✓ D. arnylose
Q.198 Amino acid which synthesized many hormones is
✓ A. Valine B. Phenylalanine
C. Alanine D. His dine
Q.199 Anline is a deriva ve of:
A. alkane B. alkene
✓ C. aroma c hydrocarbon D. alicyclic
Q.200 Which of the following amino acid is named due to its taste
A. Alanine B. Lysine
C. Valine ✓ D. Glycine
Q.201 Formula of pal mic acid is:
A. C11H22COOH B. C13H27COOH
C. C15H31COOH ✓ D. C17H35COOH
Q.202 In the cyclic structure of the glucose when the posi on of atoms on carbon 1 is called one isomer changes to other.
These isomers of glucose are called:
A. metamers B. posi on isomers
C. cis-trans ✓ D. annomers
Q.203 Lysine
A. Basic Only ketogenic ✓ B. Ketogenic glucogenic
C. Acidic glucogenic D. Non essen al
Q.204 Surfactants are organic compounds; used in detergents which reduce the
A. viscosity of water ✓ B. surface tension of water
C. boiling point of water D. we ng ability of water
Q.205 Substances that tend to decrease the ac vity of enzymes are called
A. coenzyme B. ac vators
✓ C. inhibitors D. apoenzyme
Q.206 First order of protein structure refers to
A. Bending of protein chain ✓ B. Number and sequence of amino acids
C. Three dimensional structure of protein D. Site of disulfide bonds
Q.207 An ester is prepared by:
A. two alcohols ✓ B. carboxylic acid and alcohol
C. ketone and alcohol D. aldehyde and alcohol
Q.208 An example of neutral amino acid is
✓ A. Gylcine B. Lysine
C. Aspar c acid D. Glutamic acid
Q.209 The element which is not present in all proteins is
_______________________________________________________________________________________
A. C B. H
C. O ✓ D. S
A. starch B. animal fat
C. polyester in an addi on polymer ✓ D. cellulose
Q.211 Albumin is
A. Insoluble in water ✓ B. Heat coagulable protein
C. A plant protein D. A protein of low biological value
Q.212 Which one is monosacharide?
A. starch ✓ B. glucose
C. maltose D. sucrose
Q.213 All of the following are simple proteins except
A. Histones B. Albumin
C. Kera ns ✓ D. Glycoprotein
Q.214 All of the following are primary aminoacids except
A. Cysteine ✓ B. Cys ne
C. Alanine D. Arginine
Q.215 Primary alcohols and aldehydes are oxidized to corresponding:
C. Alkynes ✓ D. Carboxylic acids
Q.216 Covalent bond is
A. A weak bond ✓ B. A true chemical bond
C. A hydrogen bond D. Responsible for secondary structure of protein
Q.217 Storage form of iron
A. Transferrin ✓ B. Ferri n
C. Myosin D. Ac n
Q.218 Monohalo deriva ves of alkanes are called:
A. two glucose molecules B. alkyl halide
✓ C. alkenes D. imide
Q.219 The bonds present in the primary structure of proteins are by
✓ A. Dialysis B. Electrophoresis
C. Filtra on D. Alcohol precipita on
_______________________________________________________________________________________
20 Macromolecules
Q.1 The product of the molecular mass of repea ng units and the D.P is called of polymer:
A. Molecular formula B. Empirical formula
✓ C. Molecular mass D. Empirical mass
A. animal fat B. starch
C. cellulose ✓ D. polyester
Q.3 Which of the following is NOT thermoplas c
A. PVC pipes B. Plas c toys
✓ C. Varnish D. Both A and B
Q.4 Nylon 6, 6 is a condensa on polymer of
A. Phthalic acid and hexa ethylene diamine ✓ B. Adipic acid and hexaethylene diamine
C. Phthalic acid and glycerol D. Adipic acid and glycerol
Q.5 Op mum temperature for enzyme ac vity is
A. 125°C ✓ B. 37°C
C. 40°C D. 100°C
Q.6 Raffinose is a trisacharirde composed of monosaccharide is
A. Glucose B. Glactose
C. Fructose ✓ D. All
Q.7 Which one of the following is co-polymer
A. PVC B. PVA
C. Polystyrene ✓ D. Terylene
Q.8 Se ng process of cement is based on:
A. Hydrolysis ✓ B. Dehydra on
C. Hydra on D. Oxida on
Q.9 The substances which so en the polymer are called
A. stabilizers ✓ B. plas cizers
C. retarders D. pigments
Q.10 A molecule of polysacharide on hydrolysis produces ______ molecules of monosacharide
✓ A. 2 - 10 B. 3
C. 10 D. 2
Q.11 Polysaccharides are also called
A. Crystals B. Sugars
C. Liquids ✓ D. Non Sugars
Q.12 The structure of a polymer depends upon how the monomer-repea ng unit joins to make a polymer. What is not the
type of structure of a polymer
✓ A. Synthe c polymer B. Linear polymer
C. Branched D. Cross linked or inter connected polymer
Q.13 The substance upon which an enzyme acts is known as its
A. domain B. field
✓ C. substrate D. reactant
Q.14 Which of the following species is used to forma on of glycerol fa y acid from triglyceride
_______________________________________________________________________________________
A. NaOH ✓ B. Ni
C. Lipase D. All
Q.15 C6H12O6is molecular formula of:
A. Glucose B. Dextrose
C. Fructose ✓ D. All of these
Q.16 Which one of the following enzymes brings about the hydrolysis of fats
A. Urease B. Maltase
C. Zymase ✓ D. Lypase
Q.17 Polymer formed by the combining of three different monomers is called:
A. Homopolymer B. Copolymer
✓ C. Ter polymer D. Thermoplas c polymers
Q.18 The nitrogen present in some fer lizer helps plants:
A. to fight against diseases B. to produce fat
C. to undergo photosynthesis ✓ D. to produce protein
Q.19 CFCs destroy ozone layer, How many ozone molecule a chlorine free radical can destroy:
A. 50,000 ✓ B. 100,00
C. 20,000 D. 10,000
Q.20 Large molecules with high molecular mass formed due to smaller units ae called:
A. polymer B. macromolecule
C. micromolecule ✓ D. a&b
Q.21 Cane sugar on hydrolysis gives
A. Glucose+Glucose ✓ B. Glucose+Fruclose
C. Glucose+Galactose D. Glucose+Gacatose
Q.22 The % age of nitrogen in ammonia is:
A. 80% B. 92%
✓ C. 90% D. 50%
Q.23 A complete food contains at least
A. Three nutrients B. Ten nutrients
✓ C. Six nutrients D. Ten nutrients
Q.24 Which one of following elements is not present in all proteins?
✓ C. Nitrogen D. Sulphur
Q.25 What is clinker?
A. Roasted calcareous material B. Roasted calcareous & argelarious material
✓ C. Roasted argillaceous material D. Roasted gypsum
Q.26 Ecosytem is a smaller unity of:
A. nydosphere B. biosphere
C. lithosphere ✓ D. atmosphere
Q.27 Substances that tend to decrease the ac vity of enzymes are called:
A. coenzymes B. ac vators
✓ C. inhibitors D. apoenzyme
Q.28 Plas c are a pollu on problem because many plas cs
A. Burn to produce toxic fumes ✓ B. Decompose to produce toxic products
C. Are made from petroleum D. Are very inflammable
Q.29 Cement is mixture of so many compounds roasted in rotary kiln.Which substance has greater percentage:
✓ A. Lime B. Alumina
C. Silica D. Magnesia
Q.30 In macromolecules DP stands for
A. Dissocia on parameter B. Dissocia on polymer
✓ C. Degree of polymeriza on D. None of these
_______________________________________________________________________________________
Q.31 The composi on mixture of clay and lime stone in a raw material is:
✓ A. 75% limestone & 25% clay B. 15% limestone & 55% clay
C. 25 limestone & 75% clay D. 55% limestone & 15% clay
Q.32 At present the number or cement factories in Pakistan are:
A. 20 B. 22
✓ C. 25 D. 30
Q.33 Polymerisa on of vinyl acetate is a type of:
✓ A. homopolymer B. copolymer
C. ter polymer D. All of these
Q.34 The fibre which is obtained from naturally occuring protein is called
A. saran ✓ B. azlon
C. rayon D. nylon
Q.35 Silk is an example of:
✓ A. animal fiber B. vegetable fiber
C. mineral fiber D. none of all
Q.36 Keratomalacia is caused due to the deficiency of vitamin
✓ A. A B. K
C. B D. D
Q.37 Surface and ground water sources are contaminated by various human ac vi es. Which of the following is not a
human ac vity that cause contamina on of fresh water?
✓ A. Rain B. Oil leaks-& spills
C. Livestock waste D. Disposal of industrial effluents
Q.38 Which of these polymers is and addi on polymer?
A. Nylon-6, 6 ✓ B. Polystyrene
C. Terylene D. Epoxy resin
Q.39 The pH range of acid rain is:
A. 6.5 -6 ✓ B. 8-7.5
C. Less than 5 D. 7- 6.5
Q.40 The %age composi on of the auxiliary agent in a detergent is:
A. 10% ✓ B. 30%
C. 50% D. 70%
Q.41 Which of the following polymers is used for weather resistant paints
✓ A. acrylic resins B. polyvinyl acetate
C. polystyrene D. PVC
Q.42 Which of the following protein is used to make bu ons
A. Gela n B. Callogen
C. Albumin ✓ D. Casein
Q.43 The temp. and pressure used for PVC polymeriza on is
A. 10°C and 10 atm B. 20°C and 20 atm
✓ C. 52°C and 9 atm D. 100°C and 10 atm
Q.44 Classifica on of polymeriza on into two types was suggested by
✓ A. W.H Carothers B. Staudinger
C. OSwald D. Aspdin
Q.45 Which is the polymer that has amide linkage in its structure
A. PVC B. Poly ethene
C. Polyester ✓ D. Nylon
Q.46 The main source of natural fibre is
A. animal fibres B. vegetables fibres
C. mineral fibres ✓ D. all of the above
Q.47 Plas c, rubber, synthe c fibers belong to macromolecules:
_______________________________________________________________________________________
A. Inorganic B. organic
C. Biopolymer ✓ D. synthe c
Q.48 Which behaves as insulator for animals body?
A. Carbohydrates B. Proteins
✓ C. Fats D. Skin
Q.49 In which of these processes are small organic molecules made into macro-molecules?
A. The cracking of petroleum frac ons B. The frac onal dis lla on of crude oil
✓ C. The polymeriza on of ethane D. The hydrolysis of proteins
Q.50 Which of the following is a thermose ng plas c?
A. PVC B. polyethylene
C. polystyrene ✓ D. melamines
Q.51 Proteins are the polymers of amino acids having
A. NH2group only B. OH- group only
C. NH2andOH-group ✓ D. NH2and COOH group
Q.52 Which of the following ac vates phosphatase enzyme
A. Ca2+ B. K+1
✓ C. Mg2+ D. Zn2+
Q.53 Which of the following are thermoplas c materials?
A. PVC B. polystyrenes
C. polyethylene ✓ D. all these
Q.54 How many fer lizer plants are now in Pakistan?
A. 20 ✓ B. 14
C. 12 D. 10
Q.55 Detergents are:
✓ A. synthe c products B. natural product
C. both a and b D. none of the above
Q.56 Vegetable oil are
A. unsaturated fa y acids ✓ B. glycerides of unsaturated fa y acids
C. glycerides of saturated fa y acids D. essen al oil obtained from plants
Q.57 Which func onal group is present in glycerol tristearate
A. Carboxylic acid B. Alcohol
C. Aldehyde ✓ D. Ester
Q.58 In which of these processes are smell organic molecules changed into macromolecules
A. The frac onal dis lla on of crude oil B. The cracking of petroleum frac on
C. The hydrolysis of proteins ✓ D. The polymeriza on
Q.59 Monosacharide belong to the group
A. Fats B. Carbohydrates
C. Lipids ✓ D. Proteins
Q.60 How many zones through which charge passes in a rotary kiln.
A. 3 B. 4
✓ C. 5 D. 6
Q.61 Type of polymer formed by the polymeriza on of two monomers is:
A. homopolymer ✓ B. copolymer
C. ter polymer D. All of these
Q.62 Calendar stock is process in paper making in which
A. Moisture is removed ✓ B. Pulp is spreaded over fabric or screen
C. Paper thickness is removed D. Paper is wounded in the form of reel
Q.63 Which woody raw material is used for the manufacture of paper pulp?
A. co on B. bugases
✓ C. poplar D. rice straw
_______________________________________________________________________________________
Q.64 Thrombin is locally used to stop
A. Heart disease ✓ B. Bleeding
C. Blood D. None of these
Q.65 What is effect of polluted air on enviroment:
A. Ozone B. Global warming
✓ C. Acid rain D. Smog
Q.66 One of the following is not type of polymer
A. homopolymer B. copolymer
✓ C. heteropolymer D. terpolymer
Q.67 When a nitrogeneous base combine with a sugar it is called
A. Ribose ✓ B. Nucleo des
C. Nucleoside D. None
Q.68 How many zones through which the charge passes in a rotary kiln?
A. 4 B. 3
✓ C. 2 D. 5
Q.69 Hexamethylene reacts with _______ to prepare nylon 6,6
A. ace c acid ✓ B. adipic acid
C. formic acid D. none of above
Q.70 Which one of the following substances is a synthe c polyester?
A. co on B. nylon
C. rayon ✓ D. terylene
Q.71 The temp and pressure used for PVC polymeriza on is
A. 10°C and 10 atm B. 20°C and 20 atm
✓ C. 52°C and 9 atm D. 100°C and 10 atm
Q.72 The fibre which contains polymers of vinylidine chloride as fibre forming substance is known as
✓ A. saran fibre B. nylon
C. polyester D. acetate fibre
Q.73 Which of the following is woody raw material used for making pulp and paper:
✓ A. Eucalyptus B. Bagasse
C. Wheat straw D. Co on linter
Q.74 Diges on of carbohydrates begins in the
A. large intes ne B. Small intes ne
C. Duoderium ✓ D. Buccal cavity / mouth
A. Urease B. Maltase
C. Zymase ✓ D. Lypase
Q.76 Which of the following statement about ribose is incorrect
A. Poly hydroxyl compound B. It is an aldo sugar
✓ C. Contain six carbon atoms D. It exhibit op cal ac vity
Q.77 The reason of acid rain is:
A. release of CO in excess by in complete ✓ B. excess release
2
and from burning of fossil
combus on of NO SO 2fuels
C. Forma on of in excess form industry and D. Forma on of due to combus on and
3 2
NH coal gas excess CO respira on
Q.78 Cane sugar on hydrolysis gives
A. Glucose and glucose B. Glucose and lactose
C. Fructose and fructose ✓ D. Glucose and fructose
Q.79 A sing chlorine free radical can destroy how many ozone molecules:
A. 10 B. 100
C. 1000 ✓ D. 10000
Q.80 The substances added in paints for improving the mechanical proper es is called:
_______________________________________________________________________________________
A. pigmein B. filter
✓ C. stabilizer D. binder
Q.81 Which one of the following elements is not present in all proteins?
C. nitrogen ✓ D. sulphur
Q.82 Sterols, vitamin D and terpenese belong to
A. Simple lipids B. Complex lipids
✓ C. Derived lipids D. None
Q.83 Plas cs are a pollu on problem because many plas cs:
A. Are made from petroleum B. Are very inflammable
✓ C. Burn to produce toxic fumes D. Decompose to produce toxic products
Q.84 Two or more similar monomers combine to form:
✓ A. Homopolymer B. Copolymer
C. Ter polymer D. Thermoplas c polymer
Q.85 Newspaper can be recycled again and again by how many mes
✓ A. 5 B. 4
C. 2 D. 3
Q.86 Which one of the pollutants of automobile exhausts affects the nervous system or produces mental diseases?
A. NO2 B. SO2
C. Hg ✓ D. Pb
Q.87 Which is biopolymer?
A. Plas c B. Rubber
C. synthe c fiber ✓ D. Lipid
Q.88 Choose the correct statement:
A. SO2affects the nucleus B. SO2affects plasmodesmate
C. SO2affects cell wall ✓ D. SO2affects all membrane systems
Q.89 Which of the following is derived lipid
A. Sterols B. Vit D
C. Terpenes ✓ D. All
Q.90 Which of the following folymer is used as binder
A. PVC B. PVA
✓ C. Acrylic resins D. Polyester
Q.91 Coenzymes are the species which increase the ac vity of enzymes. They are chemically
✓ A. Metal ions B. non-metals
C. Organic acids D. Organic bases
Q.92 Select the name of reedy plant from which word paper is derived:
A. Sunflower ✓ B. Water hyacinth
C. Papyrus D. Rose
Q.93 Which is inorganic polymer?
A. Plas c B. Rubber
C. synthe c fiber ✓ D. Lipids
Q.94 Oceans, rivers, streams, lakes, polar ice caps, glaciers and group water reservoirs are included in:
✓ A. atmosphere B. lithosphere
C. hydrosphere D. biosphere
Q.95 The substance which adversely affects the human health is:
A. Ecosystem ✓ B. Ecosphere
C. Atmosphere D. Pollutant
Q.96 Which one of the following does not act as pollutant?
A. carbon monoxide B. sulphur dioxide
C. hydrocarbons ✓ D. carbon dioxide
_______________________________________________________________________________________
Q.97 Primary pollutant is that:
A. Waste product of an industry B. Which causes cancer
C. Whose concentra on cannot be controlled ✓ D. Which corrode the metal only
Q.98 Ammonia gas used directly as a fer lizer injected into the soil at a depth of about:
A. two inches B. three inches
C. five inches ✓ D. six inches
Q.99 Which one of the following elements is not present in all protens
Q.100 Polysaccharides are
A. Polyester B. Polyamides
✓ C. Poly ethers D. Polynucleo de
Q.101 Which of these is a synthe c polymer
A. Polypep de B. Cellulose
✓ C. Polyester D. Starch
Q.102 Which of the following are characteris cs of oxidizing smog?
A. It is yellow brownish grey haze B. It has unpleasant odour
C. Its main reactant are nitric oxide & unburnt ✓ D. All of the above
hydrocarbon
Q.103 Most of high molecular mass polymers, used to make plas c rubbers or fibers have molecular masses between:
A. 1000-10000 B. 1000-100000
C. 10000-100000 ✓ D. 10000-1000000
Q.104 Which of the following is thermose ng polymer
A. Synthe c varnishes B. Epoxy resins
C. PVC ✓ D. Both A and B
Q.105 An oil of fat with no double bond have iodine number:
✓ A. Zero B. 100%
C. 50% D. Minimum
Q.106 The substance used in the soil to provide element.Which are essen al for plant growth are known as:
A. manures ✓ B. fer lizers
C. pes cides D. addi ve
Q.107 The forma on of PVC from vinyl chloride is an example of
A. subtsitu on reac on ✓ B. addi on polymeriza on
C. condensa on polymeriza on D. condensa on reac on
Q.108 The main pollu on leather tanneries in the waste water is due to the salt of:
✓ A. chromium B. copper
C. calcium D. lead
Q.109 In many countries plas c waste is collected separetaly and sorted.Some of this is incinerated to provide heat for
power sta ons.
Why is pvc polyvinylchloride,removed from any waste that is to be incinerated?
A. It can be melted down and re-used ✓ B. its combus on products are harmful
C. it destroys the ozone layer D. it does not burn easily
Q.110 SO2 and NO2 cause pollu on due to increase in:
A. buffer ac on B. basicity
✓ C. acidity D. neutrality
Q.111 Cholesterol is a precursor of steroid hormones. Choose the class of steroid
A. A carbohydrate B. A hydrocarbon
✓ C. A natural lipid D. A protein a hydrocarbon
Q.112 RNA is a polymer of a nucleo de which consist of three components. Which one is not the component in the
nucleo de of an RNA
A. D-Ribose B. wracil base
_______________________________________________________________________________________
C. prosphate group ✓ D. thyamine base
Q.113 Potassium fer lizers are especially useful for:
A. Tobacco B. Potato
C. Coffee ✓ D. All of these
Q.114 Fine powder gypsum is mixed with clinker up to:
A. 4% ✓ B. 6%
C. 5% D. 7%
Q.115 Poly hydroxyl compounds of aldehyde and ketones are?
A. Carbohydrates B. Proteins
C. Fats ✓ D. Lipids
Q.116 Thermoplas c polymer can be so ened and hardened when cool repeatedly. Which one is not a thermoplas c among
the following
✓ A. Epoxy resin B. PVC
C. Plas c toys D. None of all
Q.117 Choose the crop for which ammonium nitrate is not used:
✓ A. paddy rise B. co on
C. wheat D. sugar cane
Q.118 Ammonium nitrate fer lizer is not used for which crop:
A. co on B. wheat
Q.119 Macromolecules or polymers are large molecules built up from small molecules known as monomers. This hypothesis
put forward by
A. Newton B. Schrodinger
✓ C. Lewis D. Stadinger
Q.120 Ketones are less reac ve than aldehydes because:
A. alkyl groups electorn dona on B. steric hindrance is greater in ketone
✓ C. both a and b D. ketones are non-polar
Q.121 Which one among the following is not a natural polymer
A. Protein B. Cellulose
✓ C. Nylon D. Nucleic acid
Q.122 What is the most common catalyst used in hydrogena on of oils?
A. cobalt ✓ B. nickel
C. tungsten D. copper
Q.123 Cholesterol is an important precursor in the biosynthesis of
A. Adrenal hormones B. Sex hormones
C. Vitamin-D ✓ D. All of these
Q.124 The reac on between fat and NaOH is called
A. Esterifica on B. Hydrogenolysis
C. Fermenta on ✓ D. Sponifica on
Q.125 Industrial materials and thermal power sta ons are coated by
A. PVC B. Polyester
✓ C. Epoxy resin D. PVA
Q.126 Polymeriza on process was classified in
A. 1926 ✓ B. 1927
C. 1929 D. 1931
Q.127 Choose a point which is not included in the components of environment:
✓ A. stratosphere B. hydrosphere
C. lithosphere D. biosphere
Q.128 Polymers class is:
A. homopolymer B. copolymer
_______________________________________________________________________________________
C. ter polymer ✓ D. All of these
Q.129 Plas cs are pollu on problem because many plas cs
C. Burn to produce toxic fumes ✓ D. Decompose to produce toxic products
Q.130 Which one of the following is not a component of environment:
A. biosphere ✓ B. stratosphere
C. hydrosphere D. lithosphere
Q.131 Phosphorus is very useful in the growth of:
A. leave B. stem
✓ C. seed D. root
Q.132 Empirical formula of monosaccharide is
A. (CHO)n B. CHnOn+1
C. C n H 2O ✓ D. (CH2O)n
Q.133 Potable water is considered to be:
✓ A. safe for human consump on B. the ground water
C. the Surface water D. now water is due to the salt of:
Q.134 The proteins which are derived by conjugated proteins are called as
A. Simple protein B. Complex protein
✓ C. Derived protein D. None
Q.135 The cause of minamate disease is the pollu on of:
A. arsenic (As) into atmosphere ✓ B. industrial waste having Hg
C. organic waste in drinking H2O D. oil spills in H2O
Q.136 In FWFP the phosphate fer lizers are produced at:
A. D.I. Khan ✓ B. Haripur
C. Nowshera D. Dargai
Q.137 Glycogen is stored in
✓ A. Animals B. Plants
C. Soil D. None of these
Q.138 α and β Glucose differs in orienta on of hydroxyl group around
✓ A. C1 B. C2
C. C3 D. C4
Q.139 Biochemical oxygen demand (BOD) is the capacity of organic ma er in natural water to consume oxygen with in a
period of:
A. 2 days ✓ B. 6 days
C. 5 days D. 7 days
Q.140 Glycogen on hydrolysis give
✓ A. Glucose B. Lactose
C. Fructose D. None
Q.141 Type of polymer formed by teh polymeriza on of single type of monomer is:
✓ A. Homopolymer B. Copolymer
C. terpolymer D. All of these
Q.142 A polymeric substance that is formed in the liquid state and then hardened to a rigid solid is called
A. Fibre ✓ B. Plas c
C. Varnish D. Polyamide resin
Q.143 In Pakistan consump on per person is:
A. 8kg ✓ B. 5kg
C. 10kg D. 6kg
Q.144 Nylon, 6,6 is a condensa on polymer of
A. adipic acid and glycol B. phthalic acid and glycol
✓ C. adipic acid and hexaethylene diamine D. phthalic acid and hexaethylene diamine
_______________________________________________________________________________________
Q.145 Enzymes are chemically
A. carbohydrates ✓ B. proteins
C. fa y acids D. phospholipids
Q.146 Which of the following is an addi on polymer
A. Nylon-6, 6 ✓ B. Polystyrene
Q.147 On hydrolysis sucrose gives
A. Glucose and maltose B. Fructose and lactose
C. Fructose and maltose ✓ D. Glucose and fructose
Q.148 A fat with 18 carbon & no double bond will be
✓ A. Solid B. Liquids
C. Gel like D. None
Q.149 DNA is a polynucleic acid. The monomer is known as a nucleo de. What is not the component of the nuleo de
A. Phosphate group B. Deoxy ribose sugar
✓ C. Uracil base D. Adenine base
Q.150 Which of the following is the element not present in all proteins
Q.151 Macromolecules are classified:
A. inorganic B. organic
C. biopolymer ✓ D. synthe c
Q.152 The word paper is derived form the name of which reedy plant:
A. rose B. sun flower
✓ C. papyrus D. water hyacinth
Q.153 Fumaric acid converted into malic acid in the presence of
A. Lyases B. Glyceomutases
✓ C. Fumarase D. Hydrolases
Q.154 The development of disagreeable odour in fats or oil is called
A. fragrance B. perfume
✓ C. rancidity D. smell
Q.155 Carbohydrate that cannot be digested by human diges ve system is
✓ A. Cellulose B. Glycogen
C. Starch D. All of these
Q.156 Which of the following is synthe c thermoplas c polymer
✓ A. PVC B. Bakelite
C. Synthe c varnishes D. Both b & c
Q.157 Which one of the following is used as coagulant for purifica on potable water:
A. copper sulphate ✓ B. alum
C. barium D. nicket sulphate
Q.158 Which is the chemical formula of calcium super phosphate:
A. CaH2PO4 B. CaHPO4
✓ C. Ca(H2PO4)2 D. none of above
Q.159 The pH range of the acid rain is:
A. 6.5 __ 6 ✓ B. Less than 5
C. 8 __ 7.5 D. 7 __ 6.5
Q.160 Select the name of ready plant from which word ''Paper'' is derived:
A. sun flower ✓ B. papyrus
C. water hyacinth D. rose
Q.161 Which one of the following statements about glucose and sucrose is incorrect
A. Both are soluble in water B. Both are naturally occurring
_______________________________________________________________________________________
C. Both are carbohydrates ✓ D. Both are disacharides
Q.162 The word polymer is derived from words poly mean many and mer means unit.
A. La n ✓ B. Greek
Q.163 Which is the op mum temperature for the ac vity of enzyme
A. 20 - 35°C B. 10 - 15°C
C. 55 - 70°C ✓ D. 35 - 55°C
Q.164 A solid nitrate fer lizer reacts with an alkali to produce a gas which turns damp pH paper blue:
A. NO3 B. NHO3
C. NH2O ✓ D. N 2 H 4O 3
A. Propanoic acid B. Butanoic acid
✓ C. Formic acid D. Ace c acid
Q.166 Reason for the rancidity of fat is
A. Low sponifica on B. High reac vity of fat
✓ C. Oxida on of fat D. All
Q.167 Which fiber contains 85% acrylonitrile by weight:
✓ A. Acrylic fiber B. Azlon fiber
C. Saran fiber D. Rayon fiber
Q.168 A polymer may be
A. Linear B. Branched
C. Cross linked ✓ D. All of these
Q.169 Protein may have
A. Primary structure B. Secondary structure
C. Ter ary structure ✓ D. All of these
Q.170 Diamond, graphite and sand grant molecules are belonged to:
✓ A. Inorganic B. Organic
C. biopolymer D. synthe c
Q.171 CFCs destroy ozone layer. How many ozone molecule a chlorine free radical can destroy?
A. 50000 ✓ B. 20000
C. 100000 D. 10000
Q.172 Which is the drived lipid?
A. Common fats ✓ B. Vitamin-D
C. Common oils D. Spinolipids
Q.173 The degree of unsatura on in fats or oils is usually measured by numbers of grams of iodine required by 100 grams of
fat, this is called
A. oil number B. satura on number
✓ C. iodine number D. un satura on number
Q.174 The polymers which can not be re-so ened again and again are called
A. Thermoplas c ✓ B. Thermose ng
Q.175 Silk is the example of:
A. mineral fiber B. vegetable fiber
✓ C. animal fiber D. none of above
Q.176 Micronutrients are required in quan ty ranging from:
A. 4----40g ✓ B. 6------200kg
C. 6-----200g D. 4-------40kg
Q.177 New3spapers can be recycled again and again by how many mes?
✓ A. 5 B. 3
C. 2 D. 4
_______________________________________________________________________________________
Q.178 Which of the following are thermoplas c materials?
A. PVC (poly vinyl chloride) B. polystryences
C. polyethylene ✓ D. all above
Q.179 The polymers which can be re-so ened again and again are called
✓ A. Thermoplas c B. Thermose ng
Q.180 Macromolecules or polymers are large molecules built up from small molecules called monomers. This hypothesis put
forward by
A. schrodixger ✓ B. standinger
C. Lewsi D. newton
Q.181 Which is not a calcareous material?
A. line B. clay
✓ C. marble D. marine shell
Q.182 The molecular mass of a polymer is obtained by mul plying mass of the monomer unit the degree of polymeriza on.
The degree of polymeriza on of PVC is 1000. What is molecular mass
A. 65000 ✓ B. 63000
C. 62000 D. 60000
Q.183 The simplest separa ng unit of a polymer is called:
✓ A. Monomer B. Dimer
C. Trimer D. Macromer
Q.184 Which of the following statement is not correct for glycogen
A. It is main storage of carbohydrates ✓ B. It structure does not resemble Amylopec n
C. It has 1 → 4 and 1 → 6 glycosidic linkage D. On hydrolysis it yields glucose units
Q.185 Which of the following is a simple protein
A. Albumins B. Legumin
C. Callogen ✓ D. All
Q.186 The high molecular weight materials which yield on hydrolysis the amino acids is called:
A. Carbohydrates B. Lipids
C. Fa y acids ✓ D. Proteins
Q.187 The fibre which is made from vinylidine chloride polymer is called
A. rayon fibre B. azlon fibre
C. acetate fibre ✓ D. all of the above
Q.188 Why is CO called as pollutant? reason is:
A. It combines with oxygen ✓ B. It inac vates glycoblysis
C. It combines with hemoglobin D. Inac vates nerves
Q.189 The op mum pH value for the enzyme pepsin is
A. 10 ✓ B. 1.4
C. 8 D. 6
Q.190 Tasteless sugars are:
A. monosaccharides B. trisaccharides
C. oligo saccharides ✓ D. poly saccharides
Q.191 Lithosphere has amount of silicon:
A. 35.30% ✓ B. 27.72%
C. 40.01% D. 21.13%
Q.192 Ac vity of the enzyme is reduced by
A. temperature B. concentra on
C. pH ✓ D. inhibitors
Q.193 In big/metropolitan ci es, atmosphere is mostly polluted due to:
A. radioac ve fall out B. household waste
C. pes cide residue ✓ D. automobile exhausts
_______________________________________________________________________________________
Q.194 Which substances do not react immediately with bromine water
✓ A. Wthane B. Benzene
C. Ethene D. Phenol
Q.195 A chemical inert and heat resistant plas c, that is made from tetrafluoroethylene, is called
✓ A. teflon B. PVC
C. Bakelite D. polyamide
Q.196 Which of the following is a steroid?
A. vitamin A B. vitamin B
C. vitamin C ✓ D. vitamin D
Q.197 Nucleic acid contain elements like N,H,O,C and
A. Ca B. S
✓ C. P D. F
Q.198 Zwi erion is formed by
✓ A. Lysine B. Benzoic acid
C. Aniline D. Acetamide
Q.199 The charring of glucose when it is heated with conc.H2SO4 is due to
✓ C. Dehydra on D. Dehydrogena on
Q.200 Enzymes catalyse all biological reac ons occuring in the cell. What is true about an enzyme?
A. Enzyme is a small molecule B. Enzyme is acidic in nature
✓ C. Enzyme is a protein D. Enzyme is a lipid
Q.201 Steroids belong to the class
A. Waxes B. Glycosides
C. Phospholipids ✓ D. Lipids
Q.202 Surface and ground water sources are contaminate by various human ac vity. which of the following is not a human
ac vity that causes contamina on in fresh water?
✓ A. rain B. live stock waste
C. oil leaks and spills D. disposal of industrial effluents
Q.203 To become a carbohydrate a compound must contain
A. 2-carbon ✓ B. 3-carbon
C. 4-carbon D. 5-carbon
Q.204 Which of the following polymer has applica on in paper industry
✓ A. Starch B. Glycogen
C. Protein D. All
Q.205 Benedict solu on gives a posi ve test with
✓ A. Glucose B. Fructose
C. Sucrose D. Starch
Q.206 Terylen fibre is made by reac on of terephthalic acid with
A. ethylene ✓ B. ethylene glycol
C. glycol D. terylene
Q.207 A polymer of polyvinyl chloride with DP 1000 has molecular or molar mass:
A. 630 B. 6300
✓ C. 63000 D. 630000
Q.208 Natural fer lizers are materials derived form:
A. plants B. animals only
✓ C. both plant and animals D. none of all
Q.209 Which of these polymers is an addi on polymer?
A. nylon 6,6 ✓ B. polystyrene
C. terylene D. epoxy resin
Q.210 Which one of the following is a water soluble vitamin
_______________________________________________________________________________________
A. Niacin B. Riboflavin
✓ C. Trypsin D. Ascobic acid
Q.211 Proteins are classifies into ______ classes based on physic-chemical proper es
A. 2 ✓ B. 3
C. 5 D. 9
Q.212 Micro nutrients are required in quality ranging from:
A. 4g - 40g B. 6g - 200g
✓ C. 6dg - 200kg D. 4kg - 40kg
Q.213 Choose the chief air pollutant among the following which depletes ozone layer:
A. carbon monoxide B. carbon dioxide
✓ C. chloroflurocarbons and nitrogen oxides D. sulphur dioxide
Q.214 Ricket is caused due to the deficiency of vitamin
A. A ✓ B. D
C. B D. E
Q.215 The three dimensional folding and twis ng of a polypep de chain give rise to
A. Primary structure B. Secondary structure
✓ C. Ter ary Structure D. All of these ter ary
Q.216 Soap is formed when triglyceride reacts with
A. Caus c soda B. Soda lime
C. Lime ✓ D. Caus c potash
Q.217 The fer lizer contains 33___35%n is:
✓ A. ammonium nitrate B. potassium nitrate
C. urea D. ammonia
Q.218 Sponifica on number of a fat which requires 178,000 mg of KOH for saponifica on is (mol wt = 1240)
A. 120 ✓ B. 143
C. 208 D. 210
Q.219 The mechanism of polymeriza on involves free radical addi on polymeriza on or condensa on polymeriza on.
Choose the correct statement
A. Polyester is an addi on polymer ✓ B. Polythene is an addi on polymer
C. Polyvinyl chloride (PVC) is a condensa on D. Polystyrene
polymer
Q.220 Which of the following statements is incorrect about vitamins
A. o en func on as coenzymes ✓ B. molecules contain at least one ring structure
C. are o en synthesized by the body D. are polyfunc onal compounds
Q.221 Which of the following brings about the conversion of starch into maltose?
✓ A. maltase B. zymase
C. diastase D. invertase
Q.222 Which of these polymers is an addi on polymer
A. Nylon 6, 6 ✓ B. Polystyrene
Q.223 Vegetable oils are:
A. Unsaturated fa y acids ✓ B. Glycerides of unsaturated fa y acids
C. Essen al oils obtained from plants
Q.224 Denatura on of protein means the structure of protein is disrupted indicate which factor does not denature protein
A. Oxidizing agent B. Heat protein
✓ C. Keeping pH 7.35 D. pH changes
Q.225 Polumeriza on process was classified by
A. W.H. Garold ✓ B. William Hackel
C. W.H. Carothers D. H. Carothers
Q.226 Amount of cellulose produced by plants every year is _____ approximately
✓ A. 100 billion tons B. 90billion tons
_______________________________________________________________________________________
C. 80 billion tons D. 70 billion tons
Q.227 Monomer for acrylic resins is
A. Acrylic acid B. Methylmethacrylate
C. Acryloritrile ✓ D. All
Q.228 Cellulose is the polymer of
A. α-D-glucose ✓ B. β-D-glucose
C. Fructose D. None
Q.229 Molar mass of repea ng unit of PVC monomer is:
A. 43 B. 53
✓ C. 63 D. 73
Q.230 Which of the following carbohydrates is used in silvering of mirrors
A. Sucrose B. Cellulose
C. Fructose ✓ D. Glucose
Q.231 When equal propor on of DH3_ l and C2H5 ___ l are treated with Na metal in preasence4 of dry ether, the number of
possible hydrocarbons obtained will be:
A. 5 B. 4
✓ C. 3 D. 2
Q.232 A combina on of glucose and fructose is called
A. sucrose B. table sugar
✓ C. a&b D. Lactose
Q.233 Which property is not present in lipids?
A. Liquid B. Solid and semi solid
✓ C. Soluble in water D. Form emulsion
Q.234 Which of following is NOT use the polyvinylacetate (PVA)
A. An adhesive material B. Binder for emulsion
✓ C. Used as gramophone D. None as these
Q.235 Monosaccharides belong to the group
A. lipids B. fats
C. proteins ✓ D. carbohydrates
Q.236 Simple sugars are:
A. Monosaccharides B. Disaccharides
C. Oligo saccharides ✓ D. Trisaccharides
Q.237 Daily protein intake for normal adults should be
A. 0.2 g/kg B. 0.5 g/kg
✓ C. 0.8 g/kg D. 1.1 g/kg
Q.238 Acceptance of macromolecular hypothesis was due to efforts of:
A. Kekule B. Gibbs
✓ C. Standiger D. anderson
Q.239 Which is unnecessary for purifica on of water for drink purposes:
A. coagula on B. aera on
✓ C. treatment with lodine D. treatment with chlorine
Q.240 General formula of carbohydrate is
A. Cx(H2O)y+x ✓ B. Cx(H2O)y
C. Cx(H2O)y-1 D. Cx(H2O)y+1
Q.241 For be er or worst we are living in society:
A. wood B. food
C. diseased ✓ D. plas c
Q.242 Cellulose is formed from
A. D-galactose units B. 50% of D-glucose and 50% of L-glucose units
C. L-glucose units ✓ D. D-glucose units
_______________________________________________________________________________________
Q.243 Which one of the following is a water soluble vitamin?
A. niacin B. riboflavin
C. tyrosine ✓ D. ascorbic acid
Q.244 Which of the following wast material is not recycled for use again?
A. glasses B. paper
C. plas c toys ✓ D. hides of animals
Q.245 Irreversible precipita on of protein caused by hea ng is called
A. Polymeriza on ✓ B. Denaturing
C. Inversion D. Co-angular
Q.246 Amylose and Amylopec n are two frac on of starch which of them gives violet colour with I2
✓ A. Amloase only B. Amylopec n only
C. Both amlose & amylpec n D. None of thses
Q.247 Helical structure of protein is stabilized by
A. Pep de bond B. Dipep de bond
C. Van der wall's forces ✓ D. Hydrogen bonding
Q.248 Which of the following is correct statement about cellulose
A. It is sweet is taste B. It contain 20% amylose
C. It is used in laundering ✓ D. It containsβ1-4-linkage
Q.249 Which one of the following is the most abundant organic substance found in nature?
A. fructose B. starch
C. glucose ✓ D. cellulose
Q.250 A fibre which is made from acrylonitrile as monomer
A. PVC B. rayon fibre
✓ C. acrylic fibre D. polyester fibre
Q.251 Factors affected denatura on of proteins:
A. Change in temp and pH B. Strong reducing agent
C. Strong oxidizing agent ✓ D. All of these
Q.252 Which of the following is not an inorganic macromolecule
A. Graphite B. Sand
✓ C. Strach D. Diamond
Q.253 One of the following is not a biopolymer. Point out that one
A. Lipid B. Starch
✓ C. Diamond D. Protein
Q.254 Which products are formed when triglyceride is hydrolysed
A. Glycerol B. Fa y acid
C. Glycerin ✓ D. Both A and B
Q.255 Proxy acetyl nitrat5e (PAN) is an irritant to human beings and it affects:
A. nose B. stomach
✓ C. eyes D. ears
Q.256 Which is not a steroid
A. Cholesterol B. Ergosterol
✓ C. Phospholipids D. None of these
Q.257 During the manufacturing process of cement the temperature of the decomposi on zone goes up to:
A. 600°C B. 800°C
✓ C. 1000°C D. 1200°C
Q.258 Lipids are naturally occurring compounds produced in cell and are water insoluble but soluble in organic solvents. One
of the followings is not a lipid. Select among the following
✓ A. Nucleic acid B. A triglyceride
C. Sterol D. Vitamin D
Q.259 In the body, carbohydrates are broken down into
_______________________________________________________________________________________
✓ A. Glucose B. Fa y acids
C. Amino acids D. Nucleic acid
Q.260 Nylon 6 6 is prepared by the reac on of hexamethylene with
A. formic acid B. ace c acid
✓ C. adipic acid D. none of these
Q.261 Substances that render enzymes cataly cally inac ve are called
A. coenzymes B. substrates
✓ C. inhibitors D. apoezymes
Q.262 Protein are classified into
A. Simple protein B. Complex proteins
C. Derived proteins ✓ D. All of these
Q.263 The thickness of ozone layer is:
A. 25----50 km ✓ B. 3km only
C. 25---28 km D. 1 km only
Q.264 Lipids, proteins, carbohydrates and nucleic acids belong to macromolecules:
A. inorganic B. organic
✓ C. Biopolymer D. synthe c
Q.265 The %age of nitrogen in urea is:
✓ A. 46 B. 60
C. 70 D. 80
Q.266 The fibre which is made from acrylonitrile as monomers
A. PVC B. Rayon fibre
✓ C. Acrylic fibre D. Polyester fibre
Q.267 Each of the following compounds is effec ve as a refrigerant.
The release of which one of these cause the greatest deple on of the ozone layer?
✓ A. CC2/F2 B. CH3OCH3
C. CH3CHF2 D. CH3CH2CH3
Q.268 The fibre which is made from acrylonitrile as monomer:
A. PVC B. Rayon fibre
✓ C. Acrylic fibre D. Polyester fibre
Q.269 What element is not essen al for the growth of plants and not required in the fer lizers?
A. nitrogen B. potassium
C. phosphorus ✓ D. barium
Q.270 Which is not a calcareous material:
A. Lime ✓ B. Marble
C. Clay D. Marine shel
Q.271 What is the effect of polluted air on environment:
A. ozone B. acid rain
✓ C. global warming D. smog
Q.272 Naturally occuring lipids are called
A. Fats B. Protein
✓ C. Steroids D. None
Q.273 Which process of pulp making is mostly used in Pakistan?
A. Kra process B. Sulphite process
✓ C. Neutral sulphite semi chemical process D. All of these
(NSSC)
Q.274 The alternate name of Glucose is
A. Dextrose B. Grape sugar
C. Blood sugar ✓ D. All
Q.275 Which of the following is not a charbohydrate
✓ A. Nuclic acid B. Starch
_______________________________________________________________________________________
C. Glycoyen D. Cellulose
Q.276 Cellulose does:
A. Sa sfy human appe te B. S mulates intes nal peristalsis
C. Fives fibre and bulk to the food ✓ D. All of these
Q.277 Which substance among the following used in points to improve the mechanical proper es?
✓ A. filter B. binder
C. pigment D. stablizer
Q.278 Op mum PH for enzyme pepsin is
A. 01 ✓ B. 2
C. 05 D. 6.5
Q.279 Vegetables oils are
A. Unsaturated fa y acids ✓ B. Glycerides of unsaturated fa y acids
C. Glycerides of saturated fa y acids D. Essen al oils obtained from plants
Q.280 Which of the following alkyl halides shows higher reac vity?
A. R __ F B. R __ CI
C. R __ Br ✓ D. R __ I
Q.281 be a-D-glucose is a monomer for
A. Starch ✓ B. Cellulose
C. Glycogen D. Protein
A. Animal fat B. Starch
C. Cellulose ✓ D. Polyester
Q.283 Monosaccharides adn oligosacchardies are generally called as
A. Crystal ✓ B. Sugars
C. liquids D. Non-sugars
Q.284 The gasses in the atmosphere are essen al for sustaining life on earth; Thus oxygen is required for breathing, What
for is carbon dioxide required?
✓ A. to help plant to under go photosynthesis B. to destroy nitrogen oxide form the
atmosphere
C. to help to clean to atmosphere D. to help in fixing of bacteria
Q.285 The substance added to the soil to provide one or more nutrient elements which are necessary plant growth are
known as:
A. Harmones B. minerals
✓ C. fer lizers D. none of above
Q.286 In which of the following processes are small organic molecules made into macromolecules
A. The cracking of petroleum frac ons B. The frac onal dis lla on of crude oil
✓ C. The polymeriza on of ethene D. The hydrolysis of protein
Q.287 Which of the following is not macromolecule?
A. Proteins B. Carbohydrates
C. Acryloni rle ✓ D. Lipids
Q.288 Plas c are pollu on problem because many plas cs
C. Burn to produce toxic fumes ✓ D. Decompose to produce toxic product
Q.289 Which of these polymer is synthe c polymer
A. Animal fat B. Starch
Q.290 Soaps are basically salts of
A. Glycerol B. Triglyceride
✓ C. Fa y acid D. Fat
Q.291 Which of the following is addi on polymeriza on
A. PVA ✓ B. Polystyrene
_______________________________________________________________________________________
C. Both D. None
Q.292 Large molecule formed by combina on of smaller units these smaller units are called:
A. Polymers B. Macromolecule
C. Micromolecule ✓ D. a&b
Q.293 Which one is nitrogen fer lizer among the following:
A. calcium sulphate ✓ B. urea
C. magnesium carbonate D. potassium phosphate
Q.294 Steroids belong to the family of
A. Protein B. Enzyme
✓ C. Lipids D. Carbohydrates
Q.295 How is the secondary structure of protein stabilized
✓ A. Through hydrogen bonding B. Through ionic bonding
C. Through van der wall forces D. Through covalent bonding
Q.296 RNA regulate the synthesis of
A. Vitamis B. Carbohydrate
✓ C. Proteins D. Lipids
Q.297 Which factor is helping to reduce the environmental pollu on:
A. urbaniza on B. industrializa on
✓ C. increases of planta on D. rapid growth of popula on
Q.298 Water soluble component of starch is
✓ A. Amylose B. Amylopec n
C. Both D. Cellulose
Q.299 Plas c toys are
A. Copolymer ✓ B. Thermoplas c polymer
C. Thermose ng polymer D. Homopolymer
Q.300 Methyl mercaptan, CH3SH, is one of the substances responsible for bad breath and is o en used to impart a smell to
natural gas in a pipeline.
What will be formed when CH3SH is burned in an excess of air?
A. CO CO2 H 2S B. CO H2O SO3
✓ C. CO2 H2O SO2 D. CO2 H 2O SO3
Q.301 Nucleic acid fist descovered in
✓ A. 1868 B. 1869
C. 1900 D. 1905
Q.302 There are 20 amino acids found in protein which is not the property of these amino acids
A. They are all alpha-amino acids ✓ B. They are all op cally ac ve
C. They have high decomposi on point D. They are water soluble
period of:
A. 2 days B. 5 days
✓ C. 6 days D. 7 days
Q.304 Which of the following is sweetest sugar
A. Glucose B. Maltose
✓ C. Fructose D. Sucrose
Q.305 Which is unnecessary for purifica on of water for drinking purpose?
A. Coagula on B. Treatment with iodine
✓ C. Aera on D. Chlorina on
Q.306 organic synthe c or man made polymers are plas cs, rubber and fibre, Which is not a synthe c polymer
✓ A. silk B. polyester
C. polyvinyl chloride (PVC) D. nylon
Q.307 The main pollutant of leather tanneries in the waste water is due to:
_______________________________________________________________________________________
A. Lead ✓ B. Copper
C. Chromium (VI) D. Chromium (III)
Q.308 A polymeric substance that is formed in the liquid state and then hardened to a rigid solid is called a
A. fibre ✓ B. plas c
C. varnish D. polyamide resin
Q.309 Triglyceride have iodine number ______ having no double bond
✓ A. 0 B. 2
C. 3 D. 4
Q.310 Iodine value of an oil or fat may be defined as
A. the number of grams of iodine taken up by 1 g B. the number of grams if iodine taken by 10 g of
of the oil or fat the oil or fat
✓ C. the number of grams of iodine taken by 100 D. none of the above
g of the oil or fat
Q.311 A fat or oil is characterized for extent of unsatura on by one of the following number. Which one is
A. Acid number B. Saoilucfuca on number
C. Rancidity number ✓ D. Iodine number
Q.312 Which of the following is not glyceride
✓ A. Soap B. Phospholipids
C. Oil D. Fat
Q.314 If a polymer has mass 63000, and the molar mass of repea ng unit is 63 what is its degree of polymeriza on is
✓ A. 103 B. 102
Q.315 The steroids of fungi and yeast are called:
A. Vitamin D B. Vitamin D2
✓ C. Ergosterol D. Cholesterol
Q.316 Forma on of PVC form vinyl chloride is an example of
A. subs tu on reac on ✓ B. addi on polymeriza on
C. condensa onal reac on D. Aldol condensa on
Q.317 The primary building blocks of lipids are
A. Fa y acid B. Glycerol
C. Sterols ✓ D. All
Q.318 C6H12O6is molecular formula of:
A. Glucose B. Dextrose
C. Fructose ✓ D. All of these
Q.319 (CH2O)nis general formula for
✓ A. Monosacchardies B. Oligosaccharides
C. Polysaccharides D. None of these
Q.320 Which of these polymers is a synthe c polymer
A. Animal fat B. Strach
Q.321 Which fiber contains 85% acrylonitrile by weght?
A. azlon fiber B. saran fiber
✓ C. acrylic fiber D. rayon fiber
Q.322 The temperature in the incinera on of industrial and hazardons waster process had a range:
A. 950 to 1300°C B. 500 to 900°C
C. 250 to 500°C ✓ D. 900 to 1000°C
Q.323 Which of the following is Homopolymer
A. Polyvinyl acetate B. Acrylic resin
_______________________________________________________________________________________
C. Polyester resins ✓ D. Both A and C
Q.324 Co on is __________ % cellulose
A. 90 B. 100
✓ C. 99 D. 30
Q.325 Iden fy the linear polymer out of following
✓ A. Amylose B. Amylopec n
C. Starch D. Glycogen
Q.326 Surfactants are organic compounds used in detergents which reduce the:
A. viscosity of water ✓ B. surface tension of water
C. boiling points of water D. surface ability of water
Q.327 Molecular mass of PVC is (DP = 1200)
A. 63000 ✓ B. 75000
C. 75600 D. 80,000
Q.328 For every reac on occurring in the body three is at least one type of
✓ A. enzyme B. vitamin
C. protein D. reactant
Q.329 Which one of the following is water soluble vitamin?
A. Niacin B. Riboflavin
✓ C. Trypsin D. Ascorbic acid
Q.330 Co on is an example of
A. animal fibre B. mineral fibre
✓ C. vegetable fibre D. synthe c fibre
Q.331 Vegetable oils are
A. Unsaturated fa y acids B. Glycosides of unsaturated fa y acids
C. Glycosides of saturated fa y acids ✓ D. None
Q.332 Which of the following substance is used as filler or addi ve in paper making:
A. Glucose B. Starch
✓ C. Fructose D. Cellulose
Q.333 Which of the following is the repea ng monomeric unit in cellulose?
A. sucrose B. maltose
C. cellobiose ✓ D. glucose
Q.334 When enzyme fumarase is exposed to UV light, then
A. Its ac vity is enhanced B. It converts into Glucokinase
✓ C. It is inac vated D. None
Q.335 Amides are
A. Strongly basic ✓ B. Weakly basic
C. Acidic D. Strongly
Q.336 The conversion of an halide of an alkene is an example:
A. addi on reac on B. subs tu on reac on
✓ C. elimina on reac on D. oxida on reac on
Q.337 Purines include
A. Adenine B. Guanine
Q.338 Enzymes are catalysts which contain other than carbon and hydrogen one other element
✓ A. oxygen B. sulphur
C. phosphorus D. iodine
Q.339 The concentra on of dissolved molecular oxygen in water which acts as the most important oxidizing agent ranges
form:
A. 2ppm - 6ppm B. 2ppm - 4ppm
✓ C. 4ppm - 8ppm D. 2ppm - 3ppm
_______________________________________________________________________________________
Q.340 A nucleoside may be
A. Ribonucleoside B. Deoxyribonucleoside
Q.341 What is not true about DNA?
A. it preserves gene c informa on B. Synthesizes protein
✓ C. it has a linear structure D. To replicates
Q.342 One gram of carbohydrate yields energy
A. 10 kcal B. 100 kcal
✓ C. 4 kcal D. 9 kcal
Q.343 Sugar are polyhydroxy compounds of
A. Carboxylic acid B. Ketones
C. Aldehyde ✓ D. Both B and C
Q.344 The energy produced by a carbohydrate is
A. 3 kcal/gm B. 2 kcal / gm
C. 6kcal / gm ✓ D. 4 kcal/ gm
Q.345 Molar mass of high molecular w.f. polymers ranges from:
A. 1000 to 10000 B. 10000 to 100000
✓ C. 100000 to 1000000 D. 1000 to 1000000
Q.346 The compound which does not form iodoform:
✓ A. methyl alcohol B. ethyl alcohol
C. acetone D. acetaldehyde
Q.347 The helical structure of protein is stabilized by
A. Pep de bond B. Covalent
✓ C. Hydrogen bond D. Glycoside bond
Q.348 Which of the following is incorrect for glucose & sucrose
A. Both are water solube ✓ B. Natural polymers
C. Source of energy D. Carbohydrate in nature
Q.349 Cyclone collector is used to reduce:
A. noise pollu on ✓ B. air pollu on
C. water pollu on D. radioac ve pollu on
Q.350 Which of the following protein has applica on is food industry
A. Globulin ✓ B. Gela n
C. Casein D. All
Q.351 Which of the following is correct for epoxy resin
A. Coa ng material for thermal power sta ons B. It give chemical resistance
C. Epichlorohydrin is monomer ✓ D. All of these
Q.352 Which of the following is obtained by the hydrolysis of starch in the presence of diastase enzyme
A. Lactose ✓ B. Maltose
C. Sucrose D. All of them
Q.353 The fibre which is made form acrylonitrile as monomer
A. PVC B. rayon fibre
✓ C. acrylic fibre D. polyester fibre
Q.354 Major food factors are?
A. Fats and oils B. Carbohydrates
C. Proteins ✓ D. All of these
Q.355 Which of these the most widely used nitrogen fer lizer in Pakistan?
✓ A. urea B. ammonium nitrate
C. ammonium sulphate D. ammonium chloride
Q.356 Denatura on of protein means the structure of protein is distrupted. indicate which factor does not denature protein
A. hea ng protein B. pH changes
_______________________________________________________________________________________
C. oxidising agent ✓ D. keeping pH 7.35
Q.357 The other name for cross linked polymers is
A. Linear polymer B. Branched polymers
✓ C. Inter connected polymers D. None of these
Q.358 Which is not an enzyme
A. Transverses B. Lipase
C. Lyase ✓ D. None of these
Q.359 Which one of the following is a disaccharide?
A. glucose ✓ B. sucrose
C. fructose D. starch
Q.360 Fungicides re the pes cides which:
A. kill plants B. kill herbs
C. kill insects ✓ D. control the growth of fungus
Q.361 Which three element are needed for the health growth of plants:
A. S,S,P B. N,Ca,P
✓ C. N,P,K D. N,K,C
Q.362 The clo ng me of blood is increased due to the deficiency of
A. vitamin A ✓ B. vitamin K
C. vitamin D D. vitamin C
Q.363 Which of the following does not obey general formulas of monosaccharide
A. Mannose B. Fructose
C. Glucose ✓ D. Deoxyribose
Q.364 The number paper industries in Pakistan are:
✓ A. 30 B. 25
C. 35 D. 20
Q.365 Proper es of polymeric material depends upon
A. Chemical composi on B. Structure of molecule
C. Boiling point ✓ D. Both A and B
Q.366 Most complex structure of protein is
A. Primary protein B. Secondary protein
C. Ter ary protein ✓ D. Quaternary protein
Q.367 Amylum is another name of
✓ A. Starch B. Amylose
C. Amylopec n D. Cellulose
Q.368 Which of the following is a molecular formula of vinyl acetate
✓ A. C 4 H 6O 2 B. C 2H 4O 2
C. C 4H 6O 3 D. None of these
Q.369 The conc.of dissolved molecular oxygen in water which act as the most important oxidizing agent ranges from:
A. 2ppm- 6ppm B. 4ppm--8ppm
✓ C. 2ppm--- 4ppm D. 2ppm --3ppm
Q.370 Dichlorodifluoromethane, CC/2F2 has been used in aeroso propellants and as a refrigerant.
Which statement helps to explain why dichlorodifluromethane is chemically inert ?
✓ A. The carbon-fluorine bond energy is large B. The carbon-fluorine bond has a law polarity
C. Fluorine is highly electronega ve D. Fluorine compound are non-flammable
Q.371 Which one of the following statements about Glucose and sucrose is incorrect?
A. Both are soluble in water B. Both are naturally occurring
C. Both are carbohydrates ✓ D. Both are disaccharides
Q.372 The temperature in the incinera on of industrial and hazardous waste process has a range of:
✓ A. 950-1300C B. 250-500C
C. 500-900C D. 900-1000C
_______________________________________________________________________________________
Q.374 Fungicides are the pes cides which:
A. Kill plants B. Kill insects
C. Kill herbs ✓ D. Control the growth of fungus
Q.375 The elements like N,P,K added into the large amount in soil are called:
A. Basic elements ✓ B. Addi ves
C. Macronutrients D. Micronutrients
Q.376 Photochemical smog contains----as main reactants
A. Nitrous oxide & unburnt hydrocarbons ✓ B. NO & brunt hydrocarbons
C. Nitric oxide & unburnt hydrocarbons D. N2O & burnt hydrocarbons
Q.377 Adipic acid and Hexamethylenediammine polymerize to give
A. Acrylic resins B. Plas c fiber
✓ C. Nylon-6, 6 D. None
Q.378 Which of the following is used as coagulant for purifica on potable water?
A. Copper sulphate ✓ B. Barium sulphate
C. Alum D. Nickel sulphate
Q.379 Co on has cellulose in it:
A. 96% B. 97%
C. 98% ✓ D. 99%
Q.380 When gaseous chemicals are transported y road or by rail they are classified as follows:
flammable non-flammable poisonous
which gas is poisonous:
A. butane ✓ B. non-flammable
C. hydrogen D. sulphur dioxide
Q.381 Which oxide when mixed with water, will produce the most acidic solu on?
A. CO B. CO2
C. SiO2 ✓ D. P 2O 5
Q.382 The protein which only yield amino acids and their deriva ves
✓ A. Simple proteins B. Complex proteins
C. Derived protein D. All of these
Q.383 Phosphorous is very useful in growth of:
A. Leave B. Root
C. Stem ✓ D. Seed
Q.384 Usually the % of moisture in paper is:
A. 1---3% B. 6---8%
✓ C. 4---6% D. 5%
Q.385 The word "Lipids" derived from the language
✓ A. Greek B. La n
C. German D. English
Q.386 The elements like calcium nitrogen and phosphorus added into the soil in large amounts are called:
A. basic elements B. trace elements
C. addi ves ✓ D. nutrient element
Q.387 Choose the difference between natural and synthe c fer lizers:
A. shapes B. usage
C. crop applica on ✓ D. raw material
Q.388 In cyclic structure of glucose when the posi on of atoms on Carbon 1 is altered one isomer changes to other. These
isomers of glucose are called
✓ A. Annomers B. Posi on isomers
C. Meta-mess D. Cis-trans isomers
_______________________________________________________________________________________
Q.389 Which sequence of step is correct for the manufacture of cement:

A. Crushing, mixing, hea ng, grinding ✓ B. Crushing, hea ng, mixing, grinding
C. Crushing, grinding, mixing, hea ng D. Mixing, hea ng, grinding, crushing
Q.390 Starch is a polymer of
A. Sucrose B. Fructose
✓ C. α-D-Glucose D. Lactose
Q.391 The reac on between fat and NaOH is called?
A. Esterifica on B. Hydrogenolysis
C. Fermenta on ✓ D. Sponifica on
Q.392 The basic difference between synthe c and natural fer lizer is in their
✓ A. raw material B. crop applica on
C. usage D. shapes
Q.393 Polyesters resins have special use in:
✓ A. Clothing B. Paints
C. Emulsion D. Floor covering
Q.394 A polymeric substance that is formed in the liquid state and then hardened to a liquid solid us called as:
A. Fibre ✓ B. Plas c
C. Varnish D. Polyamide resin
Q.395 A fat or oil is characterised for extent of unsatura on by one of the following number,which one
A. rancidity number B. acid number
✓ C. iodine number D. saponicfica on number
Q.396 Oxida on reduc on is done by
✓ A. Oxidoreductase B. Lipases
C. Lyase D. None of these
Q.397 Which of the following category of enzyme catalyze addi on of Ammonia
A. Ligases ✓ B. Lyases
C. Isomerases D. Pepsinogen
Q.398 Which polymeriza on is free radical mechanism based
A. Addi on B. Condensa on
Q.399 Choose an addi on polymer among the following
✓ A. Terylone B. Nylon 6, 6
C. Polystyrene D. Epoxy resin
Q.400 Plas cs are a pollu on problem because many plas cs
A. are made from petroleum B. are very inflammable
C. burn to produce toxic fumes ✓ D. decompose to produce toxic products
Q.401 Macromolecular hypothesis acceptance due to efforts of standinger came about in:
A. 1910 ✓ B. 1920
C. 1930 D. 1940
Q.402 Op mum PH rang for amylases is
A. 6 - 6.4 B. 6.4 - 6.6
✓ C. 6.4 - 6.9 D. 6.6 - 6.9
Q.403 Which of these polymers is a synthe c polymer
A. Starch B. Animal fat
C. Polyester in an addi on polymer ✓ D. Cellulose
Q.404 A polymer of PVC having D.P 500 has molar mass:
✓ A. 6300 B. 63000
C. 3150 D. 31500
A. urease B. maltase
_______________________________________________________________________________________
C. zymase ✓ D. lypase
Q.406 Alkaline phosphatese is associated with ______ disease
A. Heart disease ✓ B. Rickets
C. Diabtese D. None
Q.407 The trade name of polytereafluoroethylene (PTFE) is
✓ A. Teflon B. PVC
C. terelene D. polyester
Q.408 Photo chemical smog contains _________ as main reactants:
A. nitrons oxide and unburnt hydrocarbons ✓ B. niliric oxide and unburnt hydrocarbons
C. NO and burnt hydrocarbons D. N2O and burnt hydrocarbons
Q.409 Which one of the following is not type of polemer
A. Copolymer B. Homopolymer
C. Terpolymer ✓ D. Heteropolymer
Q.410 Glucose and gulose are ____ for each other
A. Geometrical isomers B. Metamers
✓ C. Apimers D. None
_______________________________________________________________________________________
21 Environmental Chemistry
Q.1 HOCl is a compound:

A. Polor inorganic B. organic
C. Ionic ✓ D. covalant
Q.2 Ozone layer is
✓ A. 25 - 28 km high B. 26 - 29 km high
C. 24 - 27 km high D. 20 - 28 km high
Q.3 White marble buildings are effected by?
A. O2 ✓ B. SO2
C. CI2 D. CFCs
Q.4 In big/metropolitan ci es, atmosphere is mostly polluted due to
A. Radioac ve fall out B. Household waste
C. Pes cide residue ✓ D. Automobile exhausts
Q.5 The smog having high contents of SO2is
A. Neutral smog ✓ B. Reducing smog
C. Oxidizing smog D. Ar ficial smog
Q.6 Boron, aluminium, gallium, indium and thallium belong to group lll-A of the periodic table show a decrease with
increasing rela ve atomic mass:
A. Ionic character of the compounds ✓ B. The first ioniza on energy
C. The basic character of the oxides D. The stability of +2 oxida on
Q.7 99.5% mass of lithosphere is made of
A. 03 elements B. 8 elements
✓ C. 11 elements D. 15 elements
Q.8 Water is purified by the process:
A. Aera on B. Coagula on
C. Chlorina on ✓ D. All of these
Q.9 A single chloride free redical can destroy bow many ozene molecules?
A. 100 ✓ B. 100000
C. 10000 D. 10
Q.10 Which is the following is true about galvanic cell:
✓ A. Reduc on occurs at cathode B. Reduc on occurs at anode
C. Anode is nega vely charged D. Chathode is posi vely charged
Q.11 In purifica on of potable water the coagulant used is:
A. Nickel sulphate B. Copper sulphate
C. Barium sulphate ✓ D. Aluminium sulphate
Q.12 Which of the following is not a heavy industry?
A. Iron B. Fertilize
C. Paper ✓ D. None
Q.13 Why is carbon monoxide called as pollutant? The reason is that
A. It combines with oxygen ✓ B. It combines with haemoglobin
C. It inac vates glycolysis D. It inac vates nerves
Q.14 Water which his considered to be safe for human consump on is known as
_______________________________________________________________________________________
A. dis lled water B. contaminated water
✓ C. potable water D. rain water
Q.15 Choose the correct statements
A. SO2affects the nucleus B. SO2affects plasmodesmata
C. SO2affects cell wall ✓ D. SO2affects all membrane systems
Q.16 Water is considered pollutant when value of Do is
A. 6 PPM B. 8 PPM
✓ C. 03 PPM D. 10 PPM
Q.17 Ground and surface waters are contaminated and become polluted due to the human ac vity. Which human ac vity
will not cause water pollu on
A. live stock waste B. agricultural pes cides
C. oil beaks and spills ✓ D. all of the above
Q.18 Which of the following factors is not used to determine the quality of water
A. COD B. BOD
C. DO ✓ D. Available chlorine
Q.19 Industrial effluents have toxic synthe c organic compounds as well as heavy metals like
A. Pb B. Cr
C. Hg ✓ D. All of these
Q.20 Forms of waste products:
A. Heat B. Smoke
C. Solid ✓ D. All of these
Q.21 Why a C - Cl bond breaks by uv light
A. Cl is most electronega ve B. Cl is vola le
C. C - Cl bond energy is smaller than that of C - H ✓ D. Uv light provides energy which is sufficient to
bond energy break C - Cl bond and not C - H bond
Q.22 NO and NO2gases in atmosphere are represented by
A. NO B. NO4
✓ C. NOx D. Nx O y
Q.23 Increased awareness of environment issues has led chemist to develop products and processes that do not impact on
the environment in terms of pollu on or deple on of sources. To help chemist to achieve this aim, some principles are
drawn, which one is not the guiding principle
A. avoid waste produc on B. use no solvent
C. use a catalyst ✓ D. devise a mul step procedure for synthesis of
new compounds
Q.24 Fungicides are the pes cides which
A. Kill plants B. Kill herbs
C. Kill insects ✓ D. Control the growth of fungus
Q.25 Phenomenon of acid rains gain importance in:
A. 1930s B. 1940s
✓ C. 1950s D. 1960s
Q.26 Chemistry related to the study of environment affected by the chemicals and pollutants is called:
A. Biochemistry B. Physically chemistry
C. Pharmaceu cal chemistry ✓ D. Environmental chemistry
Q.27 The disposal of domes c refuse, commercial and industrial solid wastes are studied under the tle
✓ A. Solid waste management B. Waste management
C. Solid management D. Semisolid management
Q.28 Hard water can block radiators due to forma on of
✓ A. Insoluble calcium and magnesium salts B. Insoluble sodium salts
C. In soluble phosphate salts D. Insoluble potassium salts
Q.29 The pH of the rain water in areas where acid rain is the cause of pollu on may be
A. 6.5 B. 5.6
✓ C. 4.5 D. 2.2
_______________________________________________________________________________________
Q.30 Surface and ground water sources are contaminated by various human ac vi es which of the followings is not a
human ac vity that causes contamina on in fresh water
A. live stock waste B. oil leaks and spills
C. disposal of industrial effluents ✓ D. rain
Q.31 Acid rain is caused when various atmospheric gases dissolve in rain water. What are the gases that cause rain water
A. SO2 B. NO2
C. CO ✓ D. a and b only
Q.32 The pH rain of acid rain is
A. 8-7 B. 7 - 6.5
C. 6.5 - 6 ✓ D. less than 5
Q.33 The scope of environmental chemistry is to study:
A. Source of chemicals B. Transporta on of chemicals
C. Transporta on of toxic chemical ✓ D. All of these
Q.34 Region of earth capable of suppor ng life is called:
A. Atmosphere B. Hydrosphere
C. Lithosphere ✓ D. All of these
Q.35 Which of the following air pollutant is called quiet killer
A. PAN ✓ B. CO
C. NO3 D. SO3
Q.36 The yellow color present in the photo chemical smog is due to presence of the
A. Carbon dioxide ✓ B. Nitrogen dioxide
C. Chlorine D. All
Q.37 Oxides of sulphur react in atmosphere by various reac ons to form:
A. sulphates B. sulphites
C. sulphides ✓ D. sulphate aerosols
A. 6.5 - 6 ✓ B. Less than 5
C. 8 - 7.5 D. 7 - 6.5
Q.39 CFC's are known to cause deple on of ozone layer therefore their use has been banned in refrigerators and air
condi oners. Which alternate compound may be suitable to replace CFC
A. CCl4 B. CHCl3
C. CH3- CH2- CH2- CH3 ✓ D. CHCl2- CHF2
Q.40 Which is not the affect of polluted air on environment
A. acid rain B. smog
C. ozone ✓ D. global warming
Q.41 Leaching of nutrients is due to
A. Drying of soil B. Combus on of soil
✓ C. Acidifica on of soil D. Neutraliza on of soil
Q.42 The toxic organic compounds and heavy metals and metalloids results in contamina on of
A. surface water B. ground water
✓ C. both surface and ground water D. neither surface nor ground waters
Q.43 The temperature in the incinera on process has a range:
✓ A. 900 to 1000°C B. 650 to 1100°C
C. 950 to 1300°C D. 500 to 900°C
Q.44 Ecosystem is a smaller unit of
A. Hydrosphere B. Lithosphere
✓ C. Biosphere D. Atmosphere
Q.45 Chose a point which is not included in the components of environment
✓ A. Stratosphere B. Hydrosphere
C. Lithosphere D. Biosphere
_______________________________________________________________________________________
Q.46 Contamina on of Hg comes into surface water from chlor industrial wastes. Why is Hg Toxic.
✓ A. It a aches to sulphur of the disulphide link B. Hg is a heavy metal
C. Hg is liquid at room temperature D. Hg is non reac ve chemically
Q.47 Lanthanides an ac nides belong to following group of periodic table:
A. IB B. VIIIB
✓ C. IIB D. IIIB
Q.48 Nitrogen in the atmosphere is:
✓ A. 78% B. 21%
C. 0.9% D. 0.03%
Q.49 Ozone in stratosphere extends upto km:
A. 0-15 km B. 10-15 km
✓ C. 15-40 km D. 15-25 km
Q.50 Chemicals used to kill fungi are:
A. Herbicides B. Insec cides
C. Pes cides ✓ D. fungicides
Q.51 Which one is more toxic?
A. Fe B. C
✓ C. Hg D. Ag
Q.52 Sea gets polluted bu accidental oil spills and
A. Atmospheric pressure B. Nitrogen gas
✓ C. Cargo oil tankers D. Aero plane
Q.53 The percentage of SO2 produced by volcanoes is:
A. 47% B. 57%
C. 67% ✓ D. 77%
Q.54 By the mid of 1980s deple on of total overhead ozone in antarc c region is
A. 20% B. 30%
C. 40% ✓ D. 50%
Q.55 BOD is the oxygen demand with in day(s):
A. Four B. Two
C. Three ✓ D. Five
Q.56 Heat balance of earth is maintained by
✓ A. Atmosphere B. Hydrosphere
C. Lithosphere D. Stratosphere
Q.57 Water is essen al for life on
A. Moon B. Space
✓ C. Earth D. Sun
Q.58 Solid waster of the city is disposed off by dumping in a landfill. Which of the following gas is produced in the landfill
A. Oxygen B. Chlorine
✓ C. Hydrogen sulphide D. Hydrogen chloride gas
Q.59 Ozone is a gas having boiling point
A. Unstable B. High
✓ C. Low D. Moderate
Q.60 To purify water which has mud dissolved in it, a substance which coagulates the suspended par cles is used.
The coagulant may be
A. Ag+ B. Cu2+
✓ C. Al3+ D. Si4+
Q.61 The largest item which is recycled is
✓ A. newspaper B. plas c
C. aluminium D. oil
Q.62 Coagula on removes suspended par cles in ran water:
_______________________________________________________________________________________
A. 60% B. 70%
✓ C. 80% D. 90%
Q.63 Potable water is considered to be
✓ A. Safe for human consump on B. The ground water
C. The surface water D. Now safe for human consump on
Q.64 The amount of oxygen in the lithosphere is about
A. 35.50% B. 40.60%
✓ C. 46.60% D. 50.50%
Q.65 Which is unnecessary for purifica on of water for drinking purposes
A. Coagula on B. Aera on
✓ C. Treatment with Iodine D. Treatment with chlorine
Q.66 Coal contains sulphur in it:
A. 1-3% B. 1-6%
✓ C. 1-9% D. 1-12%
Q.67 The respira on process taking place in animals depends on a difference in
✓ A. Par al pressure B. Osomo c pressure
C. Vapour pressure D. Atomospheric pressure
A. 7 - 6.5 B. 6.5 - 6
C. 6 - 5.6 ✓ D. Less than 5
Q.69 The words smog is a combina on of smoke and:
✓ A. fog B. foke
C. fork D. fizzy
Q.70 Which is not considered as pollutant
A. O3 ✓ B. CO2
C. NO2 D. SO2
✓ A. 350 DU B. 450 DU
C. 400 DU D. 300 DU
Q.72 BOD is the oxygen demand with in day(s):
A. Four B. Two
C. Three ✓ D. Five
Q.73 Incinera on is a process in which solid waste is burned at high temperature ranging from
A. 500 to 600°C ✓ B. 900 to 1000°C
C. 1000 to 1100°C D. 600 to 700°C
Q.74 The rigid rocky part of earth crust called lithosphere extends upto a depth of:
A. 10 km ✓ B. 100 km
C. 1000 km D. 1500 km
Q.75 The semi solid wastes in landfills is called:
A. Landfill B. effluents
✓ C. Leachate D. Incinera on
Q.76 Lead pollu on is mainly due to
A. Metallic pollu on B. Space pollu on
✓ C. Acid rain D. Cd pollu on
Q.77 The process of coagula on can remove suspended solids in raw water about
A. 50% B. 60%
C. Less than 40% ✓ D. More than 80%
Q.78 COD of water can be measured by
A. Cr2O3 B. Cr2O4-2ions
✓ C. Cr2O7-2ions D. None of these
_______________________________________________________________________________________
Q.79 The main pollu on of leather tanneries in the waste is due to the salt of
✓ A. Chromium B. Copper
C. Chromium D. Lead
Q.80 BOD means
A. Boron oxygen deuterium ✓ B. Biochemical oxygen demand
C. Biochemical oxygen dissolved D. Biochemical oxygen death
Q.81 Components of environment is (in km) around the earth:
A. 10 km B. 100 km
✓ C. 1000 km D. 1500 km
Q.82 Materials suspended in water or present as colloidal form in raw water are removed by:
A. aera on ✓ B. coagula on
C. chlorina on D. treatment
Q.83 Dissolved impuri es of potable water can be separated by the process of
A. reduc on ✓ B. Aera on
C. Electrolysis D. Co-angula on
Q.84 The suspended par cles in the raw water can be removed by the
✓ A. Coagula on B. Aera on
C. Hydra on D. Dehydra on
Q.85 Which step is unnecessary for purifica on of water for drinking purposes
A. aera on B. coagula on
C. treatment with chlorine ✓ D. treatment with iodine
Q.86 Which one of the pollutants of automobile exhausts affects the nervous system or produces mental diseases
A. NO2 B. SO2
C. Hg ✓ D. Pb
Q.87 Term ozone hole is used for deple on of ozone during months of:
A. Jan-Feb B. March - Sep
✓ C. Sep- Nov D. Dec-Feb
Q.88 CFCs destroy ozone layer. How many ozone molecule a chlorine free radical can destory
A. 50,000 ✓ B. 10,000
C. 20,000 D. None of these
Q.89 Leachate contains:
A. fa y acids B. Bacteria
C. Heavy metals ✓ D. All of these
Q.90 The bonding occurs among polar covalent molecules containing H and one of the small electronega ve element such
as O,F or N is called:
A. Ionic bonding B. Metallic bonding
C. Bridge bonding ✓ D. H-bonding
Q.91 Biological oxygen demand (BOD) is associated with
A. Organic ma er B. Micro organisms
Q.92 Exhaust fumes of cars contain which poisonous gas
A. CH4 B. C 2H 6
✓ C. CO D. All of these
Q.93 A single chloride free radical can destroy the ozone molecules
A. 100 ✓ B. 100000
C. 10000 D. 10
Q.94 The % of CO2in the atmosphere is
A. 3.0% ✓ B. 0.03%
C. 0.3% D. 0.5%
Q.95 Water cover earth surface more than:
_______________________________________________________________________________________
A. 50% B. 60%
✓ C. 70% D. 80%
Q.96 Transporta on causes to produce CO2 in atmosphere:
A. 72% B. 73%
C. 74% ✓ D. 75%
Q.97 Which of spectral lines when atoms are subjected to strong electric field is called:
A. Compton effect ✓ B. Stark effect
C. Zeeman effect D. Photoelectric effect
Q.98 Which of the following is not a secondary pollutant
A. Ozone B. Carbonic acid
C. Sulphuric acid ✓ D. Carbon dioxide
Q.99 Air pollu on causes
A. Acid rain B. O3 deple on
C. Green House Effect ✓ D. All
Q.100 Residence time of methane in the atmosphere is
A. 3 - 7 days B. 2 -3 days
✓ C. 3 - 7 years D. 2 - 3 years
Q.101 Chemical like Al2(SO4) or alum are used in purifica on of water druing step:
A. aera on ✓ B. coagula on
Q.102 Test of incomplete combus on of petrol in the presence of
A. CO2 B. SO2
C. NO2 ✓ D. Co
Q.103 Augus smith discovered in the mid of seventeenth century:
A. acid B. Base
✓ C. Acid rain D. Fer lizer
Q.104 Exposure to CO results in
A. Headche B. Fa gue
C. Unconsciousness ✓ D. All of these
Q.105 Part of fresh water consumed in industry is:
A. 1% B. 2%
C. 69% ✓ D. 23%
Q.106 In the atosphere, CO2is about
A. 0.01% ✓ B. 0.03%
C. 0.05% D. 0.09%
Q.107 Sulphate aerosols cause severe respiratory problems par cularly among
A. Infants B. Women
C. Young people ✓ D. Old people
Q.108 Proxy acetyl nitrate (PAN) is an irritant to human beings and it affect
A. Nose B. Stomach
✓ C. Eyes D. Ears
Q.109 In incinera ng the waste is burnt at
✓ A. 1000°C B. 100°C
C. 2000°C D. 1500°C
Q.110 Which heavy metals do not have any safe limits
A. As B. Hg
C. Cr ✓ D. All of these
Q.111 The reason of acid rains is
A. Release of CO in excess by in complete ✓ B. Excess release of and from buring of fossil
2 2
combus on NO SO fules
C. Forma on of due to combus on and D. Forma on of in excess from industry and
2 3
_______________________________________________________________________________________
2 3
excess CO respira on NH coal gas
Q.112 DDT is a:
A. Fungicide ✓ B. Insec cide
C. Herbicide D. All
Q.113 Which not a method for solid waste management>
A. Landfill B. Incinera ng
C. Recycling ✓ D. None of these
Q.114 Chemicals used to kill insects are:
A. Herbicides ✓ B. Insec cides
C. Pes cides D. Fungicides
Q.115 Oceans, rivers, streams, leaks, polar ice caps, glaciers and group water reservoirs are included in
✓ A. Atmosphere B. Lithosphere
C. Hydrosphere D. Biosphere
Q.116 In the atmosphere, O2is about
A. 10% B. 15%
✓ C. 21% D. 25%
Q.117 The temperature of in the incinera on of industrial and hazardous waste process has range
A. 900 - 1000°C B. 250 - 500°C
✓ C. 950 - 1300°C D. 500 - 900°C
Q.118 Contaminated soil can be cleaned by various methods. Which method is not used to clean the soil
A. diffusion B. convec on
C. electrophoresis ✓ D. chromatography
Q.119 Ozone in most of the tropical regions acts as a pollutant and cause
A. damages to eyes B. aggravates asthma
C. chest discomfort ✓ D. all of these
Q.120 What is the morality of a solu on containing 15g of urea is 500cm3 of solu on?
A. 1M ✓ B. 0.5M
C. 2M D. 1.5M
Q.121 Soil remedia on means
✓ A. to make it suitable for cul va on of crops B. to make it acidic
C. to make it alkeline D. to add manure into it
Q.122 Photo chemical smog contains ______ as main reactants
A. Nitrons oxide and unburnt hydrocarbons ✓ B. Nilric oxide and unburnt hydrocarbons
C. No and burnt hydrocarbons D. N2O and burnt hydrocarbons
Q.123 A single free chlorine redical can destroy ozone molecules upto:
✓ A. 100000 B. 100
C. 1000 D. 10000
A. Compton effect ✓ B. Stark effect
C. Zeeman effect D. Photoelectric effect
Q.125 How much pes cides have been synthesized at present?
A. Four thousand B. Six thousand
C. Eight thousand ✓ D. Ten thousand
Q.126 Most harmful of biosphere is
A. Deforesta on ✓ B. Nuclear fail out
C. Salinity D. Water logging
Q.127 The Catalyst used in the contact tower for the manufacture of H2SO4 is easily poisoned by:
A. Nitrous oxide B. Nitrogen gas
✓ C. Arsenic oxide D. Carbon dioxide
Q.128 The cause of minamata disease is the pollu on of
_______________________________________________________________________________________
A. Arsenic (As) into atomosphere ✓ B. Industrial waste having Hg
C. Organic waste in drinking H2O D. Oil spills in H2O
Q.129 Pathogens in raw water are killed in step:
✓ C. chlorina on D. treatment
Q.130 alum or aluminium sulphate used as coagulant in alkaline medium change into precipitate of radicals of alumimium.
A. sulphates B. oxides
✓ C. hydroxides D. chlorides
Q.131 A chemist says that glass must be a super cooled liquid. the reason that he might have in his mind is that glass has:
A. Definite shape B. Definite volume
C. Crystalline structure ✓ D. No crystalline structure
Q.132 Unit of ozone is?
A. Debye ✓ B. Dobson
C. Esu D. Coulumb
Q.133 Which of the following waster material is not recycled for use again
A. paper B. plas c
✓ C. hides of animals D. glass
Q.134 Poisoning of CO can be reveresed by giving oxygen at pressure:
A. low B. least
C. medium ✓ D. High
Q.135 Elevated concentra on of ______________ is harmful for fish as it clog the gills causing suffoca on
✓ A. AI B. Hg
C. As D. Cr(vi)
Q.136 Which gas is not a cons tuent of atmosphere?
A. Xe B. O3
C. H2 ✓ D. F2
Q.137 Ozone layer is high:
A. 20-23 km ✓ B. 22-25 km
C. 23-26 km D. 25-28 km
Q.138 Water is made disinfectant during purifica on of water to the step:
✓ C. chlorina on D. treatment
Q.139 Addi on of washing soda removes
A. So ness of water B. Temporary hardness of water
✓ C. Permanent hardness of water D. Hydrogen from water
Q.140 Choose the chief air pollutant among the following which depletes ozone layer
A. Carbon monoxide B. Carbon dioxide
✓ C. Chloroflurocarbons and nitrogen oxides D. Sulphur dioxide
Q.141 Why a C- C bond breaks by uv light
A. Cl is most electronega ve B. Cl is vola le
C. C - Cl bond energy is smaller than that of C - H ✓ D. uv light provides energy which is sufficient to
bond energy break C - Cl bond and not C - H bond
Q.142 Which one of the following is not air pollutant gas
A. CO ✓ B. CO2
C. NO D. SO2
Q.143 Ozone acts as:
A. Pollutant B. saver
C. oxidatant ✓ D. All of these
Q.144 The force which hold the atoms together to form a compound is called:
A. Dispersion forces B. London forces
✓ C. A chemical bond D. Ven der wall's forces
_______________________________________________________________________________________
Q.145 Water in swimming pools is purified by adding

A. Sodium ✓ B. Chlorine
C. Phosphorus D. Potassium
Q.146 Water exist in only
A. One state B. Two state
✓ C. Three states D. 4 states
Q.147 SO2and NO2cause pollu on due to increase in
A. Buffer ac on B. Basicity
✓ C. Acidity D. Neutrality
Q.148 How can heavy metal contamina on like the presence of Hg or Pb may be removed from the soil
A. by using water spray B. by blowing air
✓ C. by trea ng with EDTA and then flushing the D. by adding CaO
heavy metal complex out of the soil
Q.149 A single chlorine free radical can destory how many ozone molecules
A. 10 B. 100
C. 1000 ✓ D. 10000
Q.150 The normal amount of overhead ozone is about
A. 250 Du B. 300 DU
✓ C. 350 DU D. 400 DU
Q.151 A single chloride free radical of CFCs can destroy upto ozone molecules:
A. 10 B. 100
C. 1000 ✓ D. 100000
Q.152 Ozone is effec vely removed by
A. TNT ✓ B. CFCs
C. PVC D. CNG
Q.153 Which gas produces air pollu on?
A. oxides of sulphur B. oxides of carbon
✓ C. all of these
Q.154 Which is not a component of environment?
A. Biosphere B. Lithosphere
C. Hydrosphere ✓ D. None of these
Q.155 The layer of earth around the earth is called:
C. Lithosphere D. Biosphere
Q.156 Photochemical smog consists of higher concentra on of:
A. Oxidants B. Ozone
✓ C. a&b D. NO3
Q.157 In water the most important oxidizing agent is dissolved molecular oxygen which ranges form
A. 2 - 4 ppm B. 4 - 6 ppm
C. 2 - 5 ppm ✓ D. 4 - 8 ppm
✓ A. 350 DU B. 450 DU
C. 400 DU D. 300 DU
Q.159 SO2makes ___________ acid rains
A. carbonic acid B. Sulfuric
C. Nitric acid ✓ D. All of these
Q.160 What change in plants indicates toxic effect of SO2
A. Weathering of leaves B. Darkening of leaves
C. Falling of leaves ✓ D. Bleaching of leaves
Q.161 Elements in lithosphere exist generally as:
A. metals B. non-metals
_______________________________________________________________________________________
C. metalloids ✓ D. minerals
Q.162 What is the effect of polluted air on environment
A. Ozone B. Acid rain
✓ C. Global warming D. Smog
Q.163 Site of land for landfill is selected based upon.
A. topography B. loca on of ground
C. water table ✓ D. All of these
Q.164 The film forming components of paints are
✓ A. resins B. thinners
C. pigments D. driers
Q.165 Temporary hardness can be removed by adding
A. Lime B. Carbon
C. Oxygen ✓ D. Slaked lime
Q.166 Which is not the condi on for the forma on of smog
A. there must be sufficient NO gas B. there must be sunlight to help photo chemical
reac ons to take place
✓ C. air must be blowing swi y D. there must be SO2in the air
Q.167 Three elements needed for the healthy growth of plants are
✓ A. NPK B. NKC
C. NSP D. N Ca P
Q.168 Ozone is usually produced in the
A. South polar region B. North pole region
✓ C. Tropical region D. Thermosphere zone
Q.169 Leather tanneries use big auan es of:
✓ A. Cr Vi salts B. Cr III salts
C. Mn-salts D. Pb-salts
Q.170 The destruc ve dis lla on of coal gives three products. which of following is not the product of destruc ve dis lla on
of coal?
✓ A. Coal tar B. CO2
C. Coal gas D. Coke
Q.171 Increased awareness of environmental issues has led chemists to develop products and processes that do not impact
on the environment in terms of pollu on or deple on of sources. To help chemist to achieve this aim, some principles
are drawn. Which one is not the guiding principle
A. Avoid waste produc on B. Use no solvent
C. Use a catalyst ✓ D. Devise a mul step procedure for synthesis of
new compounds
Q.172 Fungicides are the pes cides which:
✓ A. Control the growth of fungus B. Kills insects
C. Kills plants D. Kill herb
Q.173 Ph of unpolluted rain water is
A. 07 B. Less than 6
✓ C. 5.6 D. Less than 5
Q.174 Amount of ozone in atmosphere is expressed in units:
A. Kilograms B. cm
C. molarity ✓ D. DU
Q.175 The overall effect of the photochemical smog in the a er noon is built up of
A. Neutraliza on ✓ B. oxidizing agent
C. Reducing agent D. Ac va ng agent
Q.176 Ra o of hydrogen (H) and oxygen (O) in water molecule by volume is
✓ A. 2: 1 B. 1: 2
C. 3: 1 D. 4: 1
Q.177
_______________________________________________________________________________________
The concentra on of dissolved molecular oxygen in water which acts as the most important oxidizing agent ranges
from
A. 2 ppm - 6 ppm B. 2 ppm - 4 ppm
✓ C. 4 ppm - 8 ppm D. 2 ppm - 3 ppm
Q.178 Pan is an irritant to human beings and it affects
✓ A. Eyes B. Nose
C. Hair D. Skin
Q.179 Atmosphere consists of gasses:
A. N2 B. O2
C. Ar ✓ D. All
Q.180 A single chlorine free radical can destroy how many ozone molecules
A. 100 ✓ B. 100000
C. 10000 D. 10
Q.181 Smaller unit of biosphere is:
A. specie ✓ B. ecosystem
C. plankton D. troposphere
Q.182 Global warming is mainly caused by ______ radia ons
A. UV ✓ B. I.R
C. gama D. X-rays
Q.183 Surface and ground water sources are contaminated by various human ac vi es. Which of the following is not human
ac vity that causes contamina on in fresh water
A. Live stock waste B. Oil leaks and spills
C. Desposal of industrial effluents ✓ D. Rain
Q.184 Ecology is a science of environment and deals specially with
A. stratosphere ✓ B. biosphere
C. lithosphere D. hydrosphere
Q.185 CFCs are mainly used in industries due to
✓ A. Low cost B. Gaseous nature
C. High reac vity D. Un stability
Q.186 Reason of pollu on are:
A. Popula on and urbaniza on B. Transporta on
C. Industrializa on ✓ D. All of these
Q.187 Which one of the following is used as coagulant for purifica on potable water
A. Copper sulphate ✓ B. Alum
C. Barium sulphate D. Nickel sulphate
Q.188 Which of the following is a macronutrient?
A. Boron B. Iron
C. Copper ✓ D. Carbon
Q.189 The pH range of acid rain is?
A. 7-6.5 B. 6.5-6
C. 6-5.6 ✓ D. Less than 5
Q.190 Which is used as a coagulant:
A. Ferric salts B. Potash alum
✓ C. a and b both D. Chlorine
Q.191 The branch of chemistry interlinked with biology, physics, medicines, agriculture, public health and sanitary
engineering etc. is:
A. Biochemistry B. Physical chemistry
C. Pharmaceu cal chemistry ✓ D. Environmental chemistry
Q.192 Cyclone collector is used to reduce
A. Noise pollu on ✓ B. Air pollu on
C. Water pollu on D. Radioac ve pollu on
_______________________________________________________________________________________
Q.193 Chlorina on of water is effec ve for

✓ A. Killing pathogens B. Removing dust
C. Removing hardness D. Increasing oxygen content
Q.194 Ozone is present in layer around earth:
A. atmosphere B. tropospher
✓ C. stratosphere D. thermosphere
Q.195 Chemical equilibrium involving reactants and products in more than one phase is called:
A. Homogeneous ✓ B. Heterogeneous
C. Dynamic D. Sta c
Q.196 Half of the mass of atmosphere is concentrated above earth at the hieght of
A. 40 Km B. 25-28 Km
✓ C. 5-6 Km D. 100 Km
Q.197 Petroleum or crude oil is a complex mixture of compounds mainly:
A. benzene B. minerals
✓ C. hydrocarbons D. phenols
Q.198 Chromium (VI) is highly toxic and can cause
A. Blindness ✓ B. Cancer
C. Liver problems D. Blood problems
Q.199 Diseases like dysentery, typhoid and hepa s are caused by mixing of in water:
A. Live stock wastes B. Oil spilage
C. detergents ✓ D. pes cides
Q.200 Ozone is most of the tropical regions acts as a pollutant and causes
A. Damages to eyes B. Aggravates asthma
C. Chest discomfort ✓ D. All of these
Q.201 Amount of fresh water used by agriculture is
A. 2% B. 23%
✓ C. 69% D. 97%
Q.202 Hydrosphere includes
A. Seas and rivers B. Ocean & polar ice caps
C. Ground water ✓ D. All of above
Q.203 Troposphere extends upto km:
✓ A. 0-15 km B. 10-15 km
C. 15-40 km D. 15-40 km
Q.204 The region of earth capable of suppor ng life is
A. Hydrosphere B. Lithosphere
✓ C. Biosphere D. Atmosphere
Q.205 Contamina on of Hg comes into surface water from chlor industrial wastes. Why is Hg toxic
✓ A. It a aches to sulphur of the disulphide link B. Hg is a heavy metal
C. Hg is liquid at room temperature D. Hg is reac ve chemically
Q.206 Surface and ground water sources are contaminated by various human ac vi es. Which of the following is not a
human ac vity that causes contamina on in fresh water
✓ A. Rain B. Live stock waste
C. Oil leaks and spills D. Disposal of industrial effluents
Q.207 Newspaper can be recycled again and again by how many mes?
A. 2 B. 3
C. 4 ✓ D. 5
Q.208 The eleventh concentra on of metal cause clogs of gills in fish:
✓ A. Al B. He
C. Pb D. Ca
Q.209 Hydrosphere covers the surface of erath:
_______________________________________________________________________________________
✓ A. 70.8% B. 71.8%
C. 72.8% D. 73.8%
Q.210 Detergents are surfactants and they reduce the
A. B.P. of water ✓ B. Surface tension of water
C. We ng ability of water D. None of these
Q.211 Chloroform is carcinogenic:
A. Heart B. Lungs
✓ C. Liver D. Kidney
Q.212 In Purifica on of potable water the coagulant used is
A. nickel sulpahte B. copper sulpahte
C. barium sulphate ✓ D. alum
Q.213 The most important pes cides are:
C. Fungicides ✓ D. All
Q.214 Density of water becomes maximum at
A. 10°C ✓ B. 4°C
C. 5°C D. 12°C
Q.215 Any substance in the environment which adversely affects the human health and natural func oning of the Ecosystem
is known as
A. environment B. hydrosphere
✓ C. pollutant D. biosphere
Q.216 The incinera on may reduce volume of wastes upto:
A. 1/4th B. 1/2nd
✓ C. 2/3rd D. 3/4th
Q.217 Detergent greatly effects the
✓ A. Aqua c life B. Modern life
C. Terrestrial life D. Plants life
Q.218 Out of total amount of water available for human use is
A. 0.30% ✓ B. 0.2%
C. 40% D. 50%
Q.219 Ocean contains part earth's water:
A. 95% B. 96%
✓ C. 97% D. 98%
Q.220 The gases in the atmosphere are essen al for sustaining life on earth. Thus oxygen is required for breathing. What for
is carbon dioxide required
✓ A. To help plant to under go photosynthesis B. To destroy nitrogen oxide from the
atmosphere
C. To help to clean the atmosphere D. To help in fixing of bacteria
Q.221 A large hole in the ozone layer over antarc ca region was discovered in:
A. 1960s B. 1970s
✓ C. 1980s D. 1990s
Q.222 It is a biodegradable pollutant
A. Salts of HG B. DDt
C. Aluminum foil ✓ D. Domes c fuel
Q.223 Lithosphere extends upto kilometer of earth crust in depth:
A. 10 km ✓ B. 100 km
C. 1000 km D. 10000 km
Q.224 Volcanoes produce SO2:
A. 47% B. 57%
✓ C. 67% D. 77%
Q.225 Which one of the following does not act as pollutant
_______________________________________________________________________________________
A. Carbon monoxide B. Sulphur dioxide
C. Hydrocarbons ✓ D. Carbon dioxide
Q.226 Chlorofluorocarbons and aerosols are inert in sphere:
✓ A. troposphere B. stratosphere
C. lithosphere D. hydrosphere
Q.227 Fresh water of total earth water is:
✓ A. 1% B. 2%
C. 3% D. 4%
Q.228 How much quan ty of total water is available as fresh water
A. 3% ✓ B. 1%
C. 10% D. 21%
Q.229 A pollutant affects
A. Human affects B. Quality of life
C. Func oning of ecosystem ✓ D. All of these
Q.230 The water is considered to be polluted when the concentra on of oxygen in it is
A. 6 - 9ppm B. 6 ppm
C. 8 ppm ✓ D. Less than 4pm
Q.231 Polar ice caps can melt due to
A. Acid rain ✓ B. Green House Effect
C. Smog D. Chlorofluorocarbons
Q.232 Which is not an air pollutant
✓ A. N2 B. CO
C. NO D. N 2O
Q.233 Men residence me of methane in atmosphere in years is:
A. 1-7 B. 2-7
✓ C. 3-7 D. 4-7
Q.234 Coal contains percentage of sulphur:
✓ A. 1-9% B. 5-9%
C. 6-9% D. 7-9%
Q.235 The temperature in the incinera on of industrial and hazardons waster process had a range
A. 950 to 1300°C B. 500 to 900°C
C. 250 to 500°C ✓ D. 900 to 1000°C
Q.236 Which is the most toxic among the given?
✓ A. heavy metals B. non-metals
C. Metals D. Metalloids
Q.237 What is the cause of water pollu on
A. Chemical and bacterial constants in live stock B. The spilled oil in rivers and ponds
C. Wide spreads used of pes cides ✓ D. All of these
Q.238 The main pollutant of leather in the waste water is due to the salt of:
A. Lead ✓ B. Chromium (VI)
C. Copper D. Chromium (III)
Q.239 Ecosystem is a smaller unity of
A. Nydosphere B. Biosphere
C. Lithosphere ✓ D. A mosphere
Q.240 Chlorofluorocarbon, CF2Cl2, plays an effec ve role in removing O3(ozone) in the stratosphere. Which reac on does not
cause the deple on of ozone
✓
A. B.
C. D.
_______________________________________________________________________________________
Q.241 Ozone is an allotropic form of:
A. Carbon B. Phosphorus
✓ C. Oxygen D. Sulfur
Q.242 Hydrocarbons, SO2, CO, NH3nitrogen oxides and compounds of fluorine are called
✓ A. Primary pollutant B. Secondary pollutant
C. Ter ary pollutant D. None of these
Q.243 Suspended ma er is se led in purifica on of water by:
✓ A. aera on B. coagula on
Q.244 Many petroleum products are:
A. coloured B. colourless
C. testy ✓ D. poisoinous
Q.245 Deple on of ozone is more during the month:
A. Jan-March B. April-Jun
C. July-Aug ✓ D. Sept-Nov
Q.246 CFCs destroy ozone layer. How many ozone molecule a chlorine free radical can destroy
A. 10,000 B. 20,000
✓ C. 100,000 D. 50,000
Q.247 During thunderstorms, water dissolves
A. Dust par cles B. HCl
✓ C. Nitric acid D. Clouds
Q.248 Which factor is helping to reduce the environment pollu on
A. rapid growth popula on B. urbaniza on
C. idustrializa on ✓ D. increase of planta on
Q.249 Which of the following substance is not present in acid rain?
A. Sulphuric acid B. Nitric acid
C. Sulphurous acid ✓ D. Ace c acid
Q.250 Primary pollutants are:
A. oxides of sulphur B. oxides of carbon
C. oxides of nitrogen ✓ D. All of these
Q.251 Which of the following waste material is not recycled for use again
A. Glasses B. Paper
C. Plas c toys ✓ D. Hides of animals
Q.252 Hardness which can be removed by boiling is called
A. Permanent hardness ✓ B. Temporary hardness
C. S ffness D. Toughness
period of
A. 2 day ✓ B. 6 day
C. 5 day D. 7 day
Q.254 As the number of carbon atoms increase the number of isomers also increase. The six carbon compound hexane has as
many as:
A. 10 isomers B. 3 isomers
C. 5 isomers ✓ D. 6 isomers
Q.255 Eleven elements made part of earth mass:
A. 97.5% B. 98.5%
✓ C. 99.5% D. 100%
Q.256 Transforma on is a cyclic process in which used plac c is
A. Remelted and styrene is added ✓ B. Converted into low quality substance
C. Converted back into original components D. None of these
_______________________________________________________________________________________
Q.257 Which is property of CO?
✓ A. Soluble in water B. Insoluble in water
C. No toxic D. Pole coloured
Q.258 The pH range of acid rain is?
A. 7-6.5 B. 6.5-6
C. 6-5.6 ✓ D. Less than 5
Q.259 Heat balance of earth is maintained by sphere:
A. Hydrosphere ✓ B. atmosphers
C. lithosphere D. biosphere
Q.260 Major cause of SO2 on global scale is
✓ A. Volcanoes B. Electric sparks
C. Combustion D. All
Q.261 Which gases are produced from landfills?
A. NH3 B. H 2S
C. N2 ✓ D. All of these
Q.262 Newspapers can be recycled again and again by how many mes
✓ A. 5 B. 2
C. 4 D. 3
Q.263 Water is purified by:
A. Filtra on B. aera on
C. coaguala on ✓ D. All of these
Q.264 One of the environmental problem is the forma on of oil slicks when oil is spilled form tankers in sea water. Which
treatment is suitable to remove oil slicks
A. Blow air ✓ B. Add Na2CO3
C. Use a specially made sorbent having fluorine D. Use a sorbent having Al2O3trapped in it
trapped in it
Q.265 Nitrogen percentage in atmosphere is:
A. 76% B. 77%
✓ C. 78% D. 79%
Q.266 Which of following is primary pollutants
A. N 2O B. PAN
C. H2SO4 ✓ D. None of these
Q.267 Agriculture consumes part of fresh water:
A. 1% B. 2%
✓ C. 69% D. 23%
Q.268 Biochemical oxygen demand is the capacity of organic ma er in natural water to consume oxygen
A. 2 days ✓ B. 5 days
C. 6 days D. 7 days
Q.269 How much quan ty of water is in the domes c use
✓ A. 0.08% B. 16%
C. 24% D. 90%
Q.270 Coagula on in the purifica on of water is carried out by
✓ A. Alum B. NiSO4
C. BaSO4 D. CuSO4
Q.271 Water bodies are included in:
A. Atmosphere ✓ B. Hydrosphere
C. Lithosphere D. All of these
Q.272 Chemicals used to kill herbs are:
✓ A. Herbicides B. Insec cides
C. Pes cides D. Fungicides
Q.273 Polar ice caps and glaciers consists total earth water:
_______________________________________________________________________________________
A. 1% ✓ B. 2%
C. 3% D. 4%
Q.274 Insoluble ferric oxide is produced in the pH range:
A. 1 to 8 B. 6 to 9
✓ C. 3 to 13 D. 8 to 13
Q.275 When chlorofluoro carbon are subjected to U.V they form
A. Ca ons B. Aninons
✓ C. Free radicals D. None of these
Q.276 Chemicals used to kill pests are:
✓ C. Pes cides D. fungicides
Q.277 Factors affec ng quality of water:
A. D.O B. BOD
C. COD ✓ D. a,b,c
Q.278 The layer of gases around the earth are called?
C. Lithosphere D. All of these
Q.279 Electroposi ve character increases down the groups due to:
A. Increase in atomic size of the elements B. Decrease in ioniza on poten al
C. Decreases in electromagne cally of the ✓ D. All the above
element
Q.280 What is component of environment?
C. Lithosphere ✓ D. All of these
Q.281 The ozone deple on in the stratophere is mainly due to the reac on of ozone with
A. Freons B. CFCs
✓ C. Both A and B D. None
Q.282 Carbon Monoxide is:
A. colouriess B. orderless
C. high toxic ✓ D. All of these
Q.283 0.1M HCI having pH =1.0 it is about 100 me stronger than ace c acid what will be the pH of ace c acid:
A. 0.1 B. 1.3
C. 2 ✓ D. 3
Q.284 Which of the following is not the required condi on for the forma on of smog
A. Sufficient NO B. Sunlight
C. Less movement of air ✓ D. Winds
Q.285 Acidifica on of soil can leach metal:
A. Al B. Hg
C. Pb ✓ D. Ca
Q.286 The amount of Si in the lithosphere is about
✓ A. 27.72% B. 30.35%
C. 35.30% D. 40.21%
Q.287 Alkali metals react viotlently with halogens:
✓ A. Halides B. Anhydrides
C. Hydrides D. None of the above
Q.288 The range of UV-B is:
A. 320 to 400 nm B. 200 to 280 nm
C. 280 to 320 nm ✓ D. 50 to 400 nm
Q.289 One of the environment problem is the forma on of oil slicks when oil is spilled from tankers in sea water.
Which treatment is suitable to remove oil slicks
A. blow air B. add Na2CO3
_______________________________________________________________________________________
✓ C. use a specially made sorbent having fluorine D. Use a sorbent having Al2O3trapped in it
trapped in it
Q.290 Contamina on of water of tanning industries is due to:
A. Cr(III) ✓ B. Cr(VI)
C. Mn(III) D. Mn(VII)
Q.291 Commonly used coagulants are ions of:
A. Ferrous B. Al
C. Cr ✓ D. Ferric
Q.292 Synthe c organic pes cides formulated nowadays are more then:
A. One thousand ✓ B. Ten thousand
C. Two thousands D. Twenty thousand
Q.293 Value of chemical oxygen demand (COD) is a measure of chemically oxidizable ma er in water. Which value of COD
will indicate more polluted water
A. low value ✓ B. higher value
C. both values D. none of these
Q.294 The normal amount of overhead ozone is about in DU:
A. 150 B. 250
✓ C. 350 D. 450
Q.295 Ozone is produced in regions:
✓ A. tropical B. Polor
C. antaric D. equator
Q.296 Which of the following does not contribute towards the forma on of photochemical smog?
A. NO ✓ B. SO2
C. O3 D. Hydrocarbons
Q.297 The 95.5% mass of Lithoshone is made of 11 elements i,e O2, Si, Al, Fe, Ca, Na, K, Mg, Ti, H2and P. Which element is
present in trace amount
A. iodine B. bromine
C. lead ✓ D. carbon
Q.298 Natural water is
A. Pure ✓ B. Impure
C. Acts as solute D. Dis lled
Q.299 Requirement of macronutrient per acre of the land is
✓ A. 5 to 200 kg B. 20-200 kg
C. 200-400 kg D. 30-400 kg
Q.300 Polycyclic aroma c hydrocarbons are taught to be
A. Disinfectant ✓ B. Carcinogenic
C. Helpful D. Reac ve
Q.301 Water which forms scum with soap is called
✓ A. Hard water B. So water
C. Dis lled water D. Un dis lled water
Q.302 Which one of the following is an organic compound?
A. Calcium carbide B. Calcium cyanide
C. Carbon disulphide ✓ D. None of these
Q.303 Which one of the following is not a component of environment
A. Biosphere ✓ B. Stratosphere
C. Hydrosphere D. Lithosphere
Q.304 Organic pollutants in water are measured by
A. DO ✓ B. COD
C. Water logging D. PH
Q.305 How many mes a newspaper can be recycled
_______________________________________________________________________________________
A. 02 ✓ B. 05
C. 08 D. 10
Q.306 Lithosphere has amount of silicon
A. 35.30% ✓ B. 27.72%
C. 40.01% D. 21.13%
Q.307 During incinera on temperature range of non-rota ng chamber is
A. 900-1000C° B. 650-1100C°
✓ C. 950-1300C° D. 700-900C°
Q.308 Oceans cove ____________ percent of the surface of the earth
A. 60 B. 70
C. 80 ✓ D. 97
Q.309 Part of fresh water consumed in domes c purpose:
A. 1% B. 2%
C. 69% ✓ D. 8%
Q.310 Ozone layer is present in
A. Troposphere ✓ B. Stratosphere
C. Mesosphere D. Ionosphere
Q.311 The morality of the solu on containing x grams ammonium sulfate in 500cm3 of the solu on is 0.6 what is x?
✓ A. 39.6 B. 40.5
C. 42.7 D. 45.1
Q.312 Peroxyacetylnitrate (PAN) is an irritant to human beings and it affects:
✓ A. Eyes B. Ears
C. Stomach D. Nose
Q.313 Rigid rocky crust earth upto a depth of 100 km is called:
✓ C. Lithosphere D. All of these
Q.314 SO2 produced by volcanoes is about
A. 75% ✓ B. 67%
C. 69% D. 70%
Q.315 a hole used to dump the municipal wastes is called:
✓ A. landfill B. effluents
C. leachate D. inclnera on
Q.316 For incinera on temperature range is (in oC)
A. 700-800 B. 800-900
✓ C. 900-1000 D. 1000-1100
Q.317 In addi on to many pollutants present in ground water, a successful study was conducted to remove a highly Toxic
chemical.What chemical is this
A. Cobalt B. Nickel
✓ C. Arsenic D. Sulphur
Q.318 An excellent source of energy without causing pollu on is
A. Fossil fuel ✓ B. Sun
C. Petroleum D. Nuclear reactor
Q.319 Main cause of reducing map is:
✓ A. Combus on of coal B. NO and NO2
C. Un-burnt hydrocarbons D. All of these
Q.320 Which factor is helping to reduce the environmental pollu on
A. Urbaniza on B. Industrializa on
✓ C. Increase of planta on D. Rapid growth of popula on
Q.321 Property due to which water acts as a universal solvent is
A. Polarity B. It's ability to make hydrogen bond
_______________________________________________________________________________________
✓ C. Both A and B D. Strong dipole dipole interac on
Q.322 Ozone gas has boiling point:
✓ A. Low B. High
C. Medium D. Highest
Q.323 Which of the following human ac vi es are contamina ng surface and ground waters?
A. pes cides B. sep c ranks
C. petroleum and natural gas produc on ✓ D. all of these
_______________________________________________________________________________________

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C. The number of neutrons is one atom of this D. 201

Q.327 The number of molecule in one gram molecules is called as

Q.432 A complete analysis of a compound generally involves

C. Avogadro's law D. Dalton's law

C. high vapour pressures ✓ D. solubility in polar solvents

✓ C. petrol molecules do not have D. petrol molecules have greater size

Q.446 Freshly cut metals have a shining surface because

Q.1 A reac on in which heat is given out is:

Q.1 The normality of solu on containing 4g NaOH in 10ml of solu on is:

C. C – l < C – Br < C – F < C – Cl D. C – F < C – Cl < C – Br < C – I

Q.1 For an endothermic reac on the value ofΔE is denoted by

A. 1307 k cal ✓ B. 27.4 k cal

✓ A. -196 KJ mol-1 B. 146 KJ mol-1

A. 13.7 k. Cal ✓ B. 27.4 K. Cal

A. Enthalpy of atomiza on B. Enthalpy of neutraliza on

A. H+1/H2O ✓ B. OH-1/ H2O

A. Cr°(s)under goes in reduc on B. Cr°(s)under as oxidizing agent

Q.167 Which statement is incorrect for fuel cells:

A. Call reac on B. Electrode po en al

Q.1 Kavalue (the ioniza on constant) of HF acid is 6.7 x 10-5the acid is a

A. Total pressure B. Catalyst

In order to classify the elements, Newland gave the idea of:

A. atomic mass B. atomic volume

A. mol dm-1 B. mol-1dm3

A. Increase 2 mes B. Decrease to half

A. High pressure B. Low pressure

A. Rela vely strong base B. Rela vely weak bass

Q.1 Plaster of Paris is a hydrate of

A. r = k[NO]2[ Br2] ✓ B. r = k [ No][Br2]

Q.158 Slaked lime reacts with chlorine to form

✓ A. A ﬁrst order reac on B. A second order reac on

______ mole dm-3sec-1

A. sulphurous acid B. suphuric acid

✓ C. γ-sulphur D. None of these

✓ C. Ini al concentra on of the compound D. All of above

Q.585 Choose the compound which decomposes on hea ng similar to LiNO3

Q.322 Alkenes are also called:

Q.1 Spectrum of helium is expected to be similar to that of

Q.58 Which is not true with respect to cathode rays?

A. oxida on number B. compound number

12 Nitrogen and Sulphur

Q.1 Choose the correct statement:

Q.72 Which element belongs to group V-A?

Q.1 Isomers have same proper es:

Q.95 Alkenes give

Q.289 Which is the most reac ve?

Q.1 CH4 react with CI2 in direct sunlight and is obtained

Q.194 Calculated heat of hydrogena on of benzene is

A. Circumference of the circle. ✓ B. Radius of the circle.

✓ A. Alkyl halides B. Aryl halides

A. Oxonium Ion B. Carbon ion

Ethene adds a molecule of HI to form?

✓ A. SN reaction B. SN1 reaction

A. Angular Distance. ✓ B. Angular Displacement.

A. Curve trajectory ✓ B. High trajectory

A. Carbon atom is partially negatively ✓ B. Halogen atom is partially negatively

✓ A. Projectile motion B. Circular motion

✓ A. Nuelophile B. Electro philes

A. Alkyl sodium halide B. Alkyl potassium halide

A. Constant vertical component of velocity ✓ B. Constant horizontal component of

✓ A. 0.01745 rad B. 0.1745 rad

A. both S1N B. both SN2