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Jimma University Community School Chemistry Work Sheet for Grade 12

Solutions

1. The alcohol, HOCH2(CH2)6CH2OH, with two OH groups is only slightly soluble in water. A similar alcohol of
the form, CH3(CH2)6CH2OH, with only one OH group would be expected to:

A. Have the same solubility in water as alcohol with two OH groups.


B. Be less soluble in water than the alcohol with two OH groups.
C. Be more soluble in water than the alcohol with two OH groups.
D. Be less soluble in a nonpolar solvent such as dichloroethane.

2. What is the mole fraction of water in a solution containing 36 g of water (MM = 18 g/mol) and 60 g of acetic
acid (MM = 60 g/mol).
3. Calculate the molar concentration of acetic acid in a solution containing 55% acetic acid (MM = 60.0 g/mol) in
water assuming the solution has a density of 1.07 g/ml.
4. The vapor pressure of pure water at 25oC is 24 torr and the vapor pressure of ethyl alcohol at this temperature is
60 torr. What is the total vapor pressure (in torr) over a solution containing 1.0 mole of water and 4.0 mole of
ethyl alcohol?
5. Assume that incremental amounts of a volatile solute are added to a solvent so that the mole fraction of solute
varies from 0 to 1. A plot of the partial pressure of the solute vs. mole fraction of solute will:

A. Be linear with slope equal to the vapor pressure of the pure solute.
B. Be linear with slope equal to the vapor pressure of the pure solvent.
C. Be linear with slope equal to the sum of the vapor pressures of pure solvent and pure solute.
D. Vary exponentially with the mole fraction of the solute.

6. If a solution containing 2.5 x 10-5 mol/L of the blue dye in a mouth wash preparation has a percent transmittance
of 43%T, what is the molar concentration of the blue dye in a mouth wash solution that has a percent
transmittance of 73%T at the same wavelength?
7. If the water molecule had a linear rather than a bent structure, we would expect that:

A. Both the boiling and freezing temperatures would be higher.


B. The boiling temperature would be higher but the freezing temperature would be lower.
C. Both the boiling and freezing temperatures would be lower.
D. Salts such as sodium chloride would be even more soluble in the linear structure than the bent
structure.

8. What is the mole fraction of water in a solution prepared by mixing 180 g of water (MM = 18 g/mol) and 42 g
of ethyl alcohol (MM = 42 g/mol).
9. Given a solution with a density of 1.05 g/mL containing 45% water and the remainder being an organic
compound with a molecular mass of 42 g/mol. What is the molar concentration of the organic compound in the
solution?
10. When 0.534 g of a solute is dissolved in 15 g of water (MM = 18 g/mol) the freezing point of water is reduced
from 0oC to -1.57oC. The freezing-point depression constant for water is 1.85 oC kg/mol. What is the molal
concentration of the solute in this solution?
11. What is the molecular mass of the solute in the solution described in the preceding question?
12. The molecular mass of glucose is 180 g/mol and that of sucrose is 342 g/mol. Assuming ideal behavior, a plot
of freezing point vs. molal concentration of sucrose would:

A. Be linear with a slope equal to that for a similar plot for glucose.
B. Be linear with a slope equal to twice that for a similar plot for glucose.

Work sheet Community school Feb 2012


C. Be linear with a slope equal to one half that for a similar plot for glucose.
D. Be nonlinear with rate of curvature twice that for a similar plot for glucose.

13. Which of the following best explains why it takes LONGER to cook an egg in Denver, Colorado (atmospheric
pressure = 720 mm Hg) than in West Lafayette, Indiana (atmospheric pressure = 755 mm Hg)?

A. The boiling point of water is lower in Denver than in West Lafayette.


B. The boiling point of water is higher in Denver than in West Lafayette.
C. There is less hydrogen bonding between water molecules in Denver than in West Lafayette.
D. The molecular weight of water in Denver is higher than in West Lafayette.
E. The shape of water molecules in Denver is different than in West Lafayette.

14. In recitation, you constructed a microscopic representation of a solute dissolved in a solvent. Which of the
following diagrams provides a microscopic representation for a volatile liquid solute dissolved in a volatile
liquid solvent?

15. Calculate the mole fraction of acetone in the vapor above a solution prepared by dissolving 0.25 moles of
acetone (Po = 345 torr) in 1.00 mole of ethanol (Po= 59.8 torr) at 25oC.
16. Dilute solutions of hydrogen peroxide, H2O2, can be used to disinfect wounds (because H2O2 is quite effective
at killing bacteria). If the H2O2 solution that you can buy at the drugstore contains 3.0% BY MASS of H2O2 in
water, and has a density of 1.01 g/mL, calculate the molality of H2O2 in this solution.
17. Carboxylic acids are compounds that contain a "CO2H" group. Which of the following carboxylic acids will be
the LEAST SOLUBLE in water?

18. Solid, elemental iodine, I2, is much more soluble in a non-polar solvent than a polar solvent. Which of the
following best explains this behavior?

Work sheet Community school Feb 2012


A. I2 has no permanent net dipole which makes it a non-polar molecule.
B. I2 has a permanent net dipole, but it is quite small.
C. I2 ionizes to produce I+ and I- ions in non-polar solvents.
D. I2 is not soluble in water because it has a very low vapor pressure.
E. None of these statements explains the observed behavior.

19. Select the response below that is correct.

A. Freezing point, boiling point, and transmittance are all colligative properties.
B. The freezing point, boiling point, and vapor pressure all decrease when a solute is dissolved in a solvent.
C. The solubility of a gas in a liquid is inversely proportional to the vapor pressure of the gas over the
solution.
D. Plots of freezing point vs. molal concentration for ethyl alcohol, propyl alcohol and butyl alcohol
dissolved in water will all be linear with different slopes.
E. No response above is correct.

20. At 26oC, the vapor pressure of pure benzene (MM = 78) is 100 torr and the vapor pressure of pure camphor is
0.00 torr. What is the vapor pressure of benzene over a solution containing 0.30 mol of camphor in 78 grams of
benzene?
21. Polar solutes tend to be more soluble in polar solvents than nonpolar solvents because:

A. These solutes do not disrupt attractive forces between the polar solvent molecules.
B. The attractive forces between polar solvent and solute molecules tend to compensate for disrupted
attractions between solvent molecules.
C. Polar molecules tend to be arranged exclusively in completely ordered (nonrandom) structures.
D. Nonpolar solvents have much stronger intermolecular attractions than polar solvents.

22. Would the alcohol, CH3(CH2)nCH2OH, be expected to be more or less soluble in water than the alcohol
CH2OH(CH2)nCH2OH?
a. Less soluble because there is less chance for hydrogen bonding with the first than the second.
b. More soluble because the extra -OH group on the second alcohol interferes with the attractive
forces between the alcohol and water.
c. More soluble because addition of the second -OH group decreases the polarity of the molecule.
d. Neither because the addition of the second -OH group has no effect on attractive forces between
the alcohol and water.
23. Assuming ideal behavior, the freezing point depression constants for methyl, ethyl and propyl alcohols would:

A. All is different in water.


B. Be independent of the nature of the solvent.
C. Would be the same for the different alcohols in water.
D. Would be the same for each alcohol in different solvents.

24. Assuming ideal behavior, a linear-coordinate plot of the solubility of a gas in a solvent would:

A. Increase exponentially with the vapor pressure of the gas over the solvent.
B. Decrease exponentially with the vapor pressure of the gas over the solvent.
C. Increase linearly with the total vapor pressure over the solvent.
D. Decrease linearly with the vapor pressure of the gas over the solvent.
E. Increase linearly with the vapor pressure of the gas over the solvent.

25. Calculate the molal concentration of ethyl alcohol in a solution that contains 4.6 grams of ethyl alcohol (MM =
46 g/mol) and 500 grams of water (MM = 18 g/mol).
26. When 0.795 grams of a nonvolatile solute is added to 13 grams of water, the freezing point of water is reduced
by 1.89oC. Calculate the molecular mass of the solute. (For water: kf = 1.86 oC/m.)

Work sheet Community school Feb 2012


27. Which of the following correctly shows the hydrogen bonding between three methyl amine (CH3NH2)
molecules? Note: the hydrogen bonds are represented as dashed lines.

28. When gaseous ammonia, NH3 (g), is dissolved in water, the resulting solution does not obey Henry's Law (i.e.,
it is not an ideal solution). Which of the following best explains why this solution does not obey Henry's Law?

A. All of the NH3 that initially dissolves in the water rapidly escapes from the solution because NH3 is a gas
at room temperature.
B. NH3 reacts with the solvent to produce ammonium and hydroxide ions.
C. NH3 is not soluble in water because it is a non-polar molecule.
D. The hydrogen bonding between ammonia molecules is so strong that NH3 cannot be dissolved in water.
E. The hydrogen bonding between water molecules is so strong that NH3 cannot be dissolved in water.

29. Which of the following aqueous solutions will boil at the highest temperature? Note: all of the salts listed below
are completely soluble in water.

A. A 0.10 m solution of NaCl.


B. A 0.10 m solution of Na2SO4.
C. A 0.10 m solution of Na3PO4.
D. A 0.10 m solution of KNO3.
E. A 0.10 m solution of K2SO4.

30. "Sulfamethoxazole" is an antibiotic (i.e., a sulfa drug) that is used to treat urinary tract infections. When a
patient takes sulfamethoxazole, it is necessary that he/she drink large amounts of water to prevent the
sulfamethoxazole from crystallizing in the urinary tract. The structure of sulfamethoxazole is shown below.

Which of the following is TRUE?

A. Sulfamethoxazole contains groups that can form hydrogen bonds with water.
B. Sulfamethoxazole does not contain any groups that can form hydrogen bonds with water.
C. Sulfamethoxazole is a polar molecule whereas water is a non-polar molecule.

Work sheet Community school Feb 2012


D. All of the covalent bonds in sulfamethoxazole are non-polar because the difference in
electronegativity between each pair of bonded atoms is very small.
E. None of the above are TRUE.

31. Calculate the vapor pressure (in torr) of benzene over a solution that contains 0.500 moles of benzene and 1.500
moles of camphor if the vapor pressure of pure benzene is 100 torr. You may assume that the solution is an
ideal solution.
32. In large quantities, the nicotine in tobacco is a deadly poison. Calculate the molecular weight of nicotine if a
solution containing 3.62 g of nicotine in 73.4 g of water (kf = 1.85 oC/m) gives a freezing point 0.563oC below
the freezing point of pure water.
33. Which of the following pairs of properties are both colligative properties?

A. freezing point, density


B. freezing point, vapor pressure
C. boiling point, color
D. vapor pressure, molality
E. boiling point, ionic strength

34. Which of the following concentration units changes with temperature?

A. Molality C. Molarity
B. Mole fraction D. Mass percent

35. The solubility of a gas in a solvent with which it does not react is:

A. Proportional to the partial pressure of the gas.


B. Inversely proportional to the partial pressure of the gas.
C. Independent of the partial pressure of the gas.
D. Proportional to the partial pressure of the solvent.
E. Inversely proportional to the partial pressure of the solvent.

36. Calculate the vapor pressure of benzene over a solution that contains 1.00 moles of benzene and 2.00 mole of
camphor if the vapor pressure of pure benzene is 100 torr.
37. A solution containing 4.50 g of an unknown compound in 25.0 g of benzene (kf = 5.12) gives a freezing point
2.16oC below the freezing point of pure benzene. What is the molecular mass of the unknown compound?
38. Iodine, I2, does not have a permanent dipole and is therefore a non-polar molecule. Briefly explain why I2 does
not have a permanent dipole.
39. Acetic acid (CH3COOH, the active ingredient in vinegar) is much more soluble in water than ethyl acetate
(CH3CO2CH2CH3, a common organic solvent found in some nail polish removers). Briefly explain why acetic
acid is more soluble in water than ethyl acetate.
40. Which freezes at a LOWER temperature, hard water or soft water? Briefly explain your reasoning.
41. Calculate the total vapor pressure of a solution prepared by dissolving 0.45 moles of pentane (C5H12, MW=72.2
g/mol) in 0.95 moles of hexane (C6H14, MW=86.2 g/mol) if the vapor pressures for pure pentane and hexane are
511 torr and 150 torr, respectively. You may assume that this is an ideal solution.
42. Which of the following species would be MOST soluble in a nonpolar solvent such as carbon tetrachloride?

A. sodium chloride
B. water
C. molecular iodine (I2)
D. triodide ion (I3-)
E. KMnO4

43. Acetic acid, CH3COOH, is an organic acid found in vinegar. In general, organic acids can be represented with
the formula, CH3(CH2)nCOOH (where n = 0 for acetic acid). The solubility of organic acids in water:

Work sheet Community school Feb 2012


A. Is directly proportional to the value of n.
B. Does not depend on temperature.
C. Is independent of n because solubility is a colligative property.
D. Will increase as n increases.
E. Will decrease as n increases.

44. In the experiment on Colligative Properties, it can be determined the molal freezing point depression constants
for a single solvent and several solutes. Assuming ideal behavior, it would be expected that the constants would:

A. Increase with increasing molecular weights of the solutes.


B. Be proportional to the molal concentrations of the different solutes.
C. Be different for all solutes.
D. Be the same for all solutes.
E. Have different units for all solutes.

45. Commercial, topical solutions of hydrogen peroxide (H2O2, MW = 34 g/mol) are used for disinfecting wounds
because H2O2 is a good oxidizing agent (which kills bacteria). What is the MOLARITY of such a solution if it
contains 3.0% by mass of H2O2 in water? The density of the solution is 1.00 g/mL.

A. 0.088 M
B. 0.30 M
C. 0.88 M
D. 1.0 M
E. 1.3 M

46. What is the vapor pressure of water over a solution prepared by dissolving 100 g of sucrose (MW = 342 g/mol)
in 225 g of water (MW = 18.0 g/mol) at 90oC? The vapor pressure of pure water at 90oC is 526 torr.

A. 0.079 torr
B. 514 torr
C. 539 torr
D. 1,184 torr

a. 2,368 torr
47. Which of the following aqueous solutions would have the HIGHEST freezing point? Note that all of these salts
are completely soluble in water.

A. a 0.10 molal solution of sodium chloride (NaCl)


B. a 0.10 molal solution of magnesium chloride (MgCl2)
C. a 0.10 molal solution of iron chloride (FeCl3)
D. a 0.10 molal solution of sodium sulfate (Na2SO4)
E. a 0.10 molal solution of ammonium phosphate ((NH4)3PO4)

48. Potassium iodide reacts with iodine in aqueous solution to form the triiodide ion:

KI(aq) + I2(aq) --> KI3(aq)

What would happen if we added CCl4 (nonpolar) to this reaction?

A. The KI would tend to dissolve in the CCl4 layer.


B. The I2 would tend to dissolve in the CCl4 layer.
C. Both KI and I2 would dissolve in the CCl4 layer.
D. Neither KI nor I2 would dissolve in the CCl4 layer.
E. Because CCl4 and water are miscible, no distinct CCl4 layer would form.
Work sheet Community school Feb 2012
49. An alcohol is a compound with the formula CH3(CH2)nOH in which the CH2(CH2)n group is nonpolar and the
OH group is polar. As "n" increases for different alcohols, we would expect the solubilities of the alcohol to:

A. Increase in both polar and nonpolar solvents.


B. Increase in polar solvents and decrease in nonpolar solvents.
C. Decrease in both polar and nonpolar solvents.
D. Decrease in polar solvents and increase in nonpolar solvents.

50. The average concentration of cholesterol (C27H46O, MW = 386) in human serum is 0.195 g per 100 mL. What is
the average molar concentration of cholesterol in human serum?

A. 5.05 x 10-2 B. 5.05 x 10-3 C. 4.51 x 10-3 D. 5.05 x 10-4

51. If the density of human serum were 1.12 g/mL, what would be the average molal concentration of cholesterol in
serum?

A. 4.78 x 10-2 B. 5.81 x 10-3 C. 4.51 x 10-3 D. 5.05 x 10-4

52. For a nonvolatile solute dissolved in a volatile solvent, the vapor pressure, freezing point, and boiling point:

A. Are all higher for the solution than for the pure solvent.
B. Are all lower for the solution than for the pure solvent.
C. Change differently, with vapor pressure increasing and boiling and freezing points decreasing.
D. Change differently, with boiling point increasing and vapor pressure and freezing point decreasing.

53. Raoult's law predicts that the vapor pressure of solvent over a solution of a nonvolatile solute:

A. Increases with increasing mole fraction of solvent.


B. Increases with increasing mole fraction of solute.
C. Is independent of the solute concentration.
D. Decreases with increasing temperature.

54. The melting point of pure benzene is 278.70 K and the molal freezing point depression constant is 4.90
K/molal. When 4.20 g of an unknown solute is added to 100 g of benzene, the freezing point of the solution is
277.60 K. What is the molecular weight of the unknown?

A. 226 g/mol C. 187 g/mol E. 128 g/mol


B. 18.7 g/mol D. 12.7 g/mol

55. 0.400 mole of CCl4 and 0.600 mole of CHCl3 are mixed at 43oC. The vapor pressure of pure CCl4 at this
temperature is 0.354 atm and the vapor pressure of pure CHCl3 at this temperature is 0.526 atm. What is the
vapor pressure of the solution?

A. 0.285 atm C. 0.423 atm E. 0.457 atm


B. 0.526 atm D. 0.880 atm

56. Calculate the freezing point (in oC) of a solution prepared by dissolving 1.00 g of caffeine (molar mass = 212.2
g/mol) in 45.6 g of water. For water, kf = 1.853oC/m.
57. Which of the following compounds would be the MOST SOLUBLE in water?

A. CH3OH C. I2 E. CH3(CH2)6OH
B. CH3(CH2)6CH3 D. CH3(CH2)4OH

58. Which of the following statements about a "hydrogen bond" is TRUE?


Work sheet Community school Feb 2012
A. A hydrogen bond is a covalent bond between a hydrogen atom and an electronegative atom such
as O, N or F.
B. A hydrogen bond is an ionic bond between a hydrogen atom and an electronegative atom such as
O, N or F.
C. A hydrogen bond is an attractive electrostatic force between a hydrogen atom and an
electronegative atom such as O, N or F.
D. A hydrogen bond is a coordinate covalent bond between a hydrogen atom and an electronegative
atom such as O, N or F.
E. A hydrogen bond can only be formed between two ions.

59. Calculate the mole fraction of ethanol in a solution prepared by dissolving 0.50 moles of acetone (Po = 345 torr)
in 1.25 moles of ethanol (Po = 59.8 torr) at 25oC.
60. In lecture, you observed that solid, potassium permanganate, KMnO4, is much more soluble in water than in
CH2Cl2 (a non-polar solvent). Which of the following intermolecular forces is primarily responsible for the
greater solubility of KMnO4 in water than in CH2Cl2?

A. dipole-dipole forces
B. London dispersion forces
C. hydrogen bonding
D. ion-dipole forces

61. Which of the following molecules is MOST soluble in water?

A. methane : CH4
B. ethane : CH3CH3
C. octane : CH3(CH2)6CH3
D. ethanol : CH3CH2OH
E. octanol : CH3(CH2)6CH2OH

62. Calculate the PERCENT BY MASS of a 9.21 M solution of HCl (molar mass = 36.5 g/mol) in water. The
density of the solution is 1.12 g/mL.
63. Organic compounds that contain an NH2 group are called amines. Which of the following amines is the MOST
SOLUBLE in water?

A. CH3(CH2)8NH2 D. CH3(CH2)6NH2
B. CH3(CH2)4NH2 E. CH3CH2NH2
C. There is insufficient information provided to answer the question.

64. Calculate the molecular weight of sucrose if a solution containing 4.9 g of sucrose in 175 g of water has a
freezing point equal to -0.15oC. For water, kf = 1.853 oC/m.
65. When liquid water is heated, the formation of bubbles can be observed as the temperature of the liquid
increases. Which of the following is the MAJOR species inside the bubbles when the temperature of the water
is close to the boiling point of water?

A. H2(g) and O2(g) C. H2O(l) D. H2O(g) E. N2(g)


B. N2(g) and O2(g)

Work sheet Community school Feb 2012


66. Given a solution with a density of 1.05 g/mL containing 45.0% (by mass) water and the remainder being an
organic compound with a molecular mass of 42.0 g/mol, what is the molar concentration of the organic
compound in the solution?
67. At 26oC, the vapor pressure of pure benzene (MM = 78) is 100 torr and the vapor pressure of pure camphor is
0.00 torr. What is the vapor pressure (in torr) of benzene over a solution containing 0.30 mol of camphor in 78
grams of benzene?
68. A solution that contains 23.0 g of ethyl alcohol (MM = 46 g/mol) and 32.0 g of methyl alcohol (MM = 32
g/mol) has a density of 0.97 g/mL. What is the mole fraction of methyl alcohol in the solution?
69. Which of the following correctly lists the three alcohols in order of INCREASING solubility in water?

A. CH3(CH2)2CH2OH < CH3(CH2)7CH2OH < CH3(CH2)5CH2OH


B. CH3(CH2)7CH2OH < CH3(CH2)5CH2OH < CH3(CH2)2CH2OH
C. CH3(CH2)5CH2OH < CH3(CH2)7CH2OH < CH3(CH2)2CH2OH
D. CH3(CH2)2CH2OH < CH3(CH2)5CH2OH < CH3(CH2)7CH2OH
E. None of the above responses is correct.

70. Given two solutions, one containing 0.10 molal ethyl alcohol (MM = 46) in water and the other containing 0.10
molal propyl alcohol (MM = 60) in water, it is expected that the freezing point of the ethyl alcohol solution will
be:

A. Less than the freezing point of the propyl alcohol solution.


B. Greater than the freezing point of the propyl alcohol solution.
C. The same as the freezing point of the propyl alcohol solution.
D. The same as the freezing point of pure water.
E. The same as the freezing point of pure ethyl alcohol.

71. When a solution is prepared from two volatile liquids with different vapor pressures, the vapor pressure of the
solution will be:

A. Greater than the vapor pressure of each of the pure liquids.


B. Less than the vapor pressures of each of the pure liquids.
C. The same as the vapor pressure of the more volatile liquid.
D. The sum of the vapor pressure of the two pure liquids.
E. Somewhere between the vapor pressures of the pure liquids.

72. Ethylene glycol, CH2(OH)CH2(OH), an important ingredient in automobile antifreeze, is much more soluble in
water than octyl alcohol, CH3(CH2)6CH2OH, because:

A. Ethylene glycol has much less non-polar character than has octyl alcohol.
B. Hydrogen bonding is weaker in ethylene glycol than in octyl alcohol.
C. Octyl alcohol ionizes completely whereas ethylene glycol does not.
D. Ethylene glycol can form hydrogen bonds with water but octyl alcohol cannot.

73. The quantity of a gas that will dissolve in a liquid is:

A. Directly proportional to temperature.


B. Directly proportional to pressure.
C. Inversely proportional to pressure.
D. Independent of both temperature and pressure.
E. None of the above.

74. Reserpine is a substance that is used as a tranquilizer and sedative. Calculate the molecular weight of reserpine
if a solution containing 1.00 g of reserpine in 25.0 g of camphor (kf = 40.0 oC/m) gives a freezing point 2.63oC
below the freezing point of pure camphor.

Work sheet Community school Feb 2012


75. ALL colligative properties:

A. Increase with increasing solute concentration.


B. Decrease with decreasing solute concentration.
C. Are dependent on the type of solvent and independent of the type of solute.
D. Are independent of the type of solvent and dependent on the type of solute.
E. Involve temperature changes.

76. The vapor pressure of a volatile solute over a solution is:

A. Proportional to the vapor pressure of the pure solute and the mole fraction of solute in the solution.
B. Proportional to the vapor pressure of the pure solute and inversely proportional to the mole
fraction of the solute.
C. Inversely proportional to both the vapor pressure of the pure solute and the mole fraction of the
solute.
D. Dependent only on the temperature of the solution.
E. The same for all concentrations of the solute.

77. A 12.0 g sample of a nonelectrolyte is dissolved in 80.0 g of water. If pure water freezes at 0.00oC and the
solution freezes at -1.94oC, calculate the molecular weight of the nonelectrolyte. For water, kf = 1.86 oC/m.
78. A 7.00 g sample of a nonelectrolyte is dissolved in 45.0 g of water. If pure water freezes at 0.00oC and the
solution freezes at -2.56oC, calculate the molecular weight of the nonelectrolyte. For water, kf = 1.86 oC/m.
79. Calculate the mole fraction of toluene in a solution having a density of 0.876 g/mL formed by mixing 10.00 g of
toluene, C7H8 (MW = 92.15 g/mol) in 195.0 g of benzene, C6H6 (MW = 78.12 g/mol).
80. Which of the following statements about colligative properties is TRUE?

A. Both vapor pressure and freezing point INCREASE when a non- volatile solute is added to a
solvent.
B. Both freezing point and boiling point INCREASE when a non- volatile solute is added to a
solvent.
C. Both vapor pressure and boiling point DECREASE when a non- volatile solute is added to a
solvent.
D. Colligative properties depend only upon the NUMBER of solute particles in a solution and not
upon their identity.
E. None of the above statements is true.

81. Calculate the PERCENT BY MASS of hydrogen peroxide (H2O2, MW = 34.0 g/mole) in a 5.88 M solution of
H2O2 in water. The density of the solution is 1.00 g/mL.
82. Calculate the mole fraction of toluene in a solution having a density of 0.876 g/mL formed by mixing 5.00 g of
toluene, C7H8 (MW = 92.15 g/mol) in 225.0 g of benzene, C6H6 (MW = 78.12 g/mol).
83. Commercial concentrated aqueous ammonia is 28% NH3 by mass and has a density of 0.90 g/mL. Calculate the
mole fraction of NH3 in this solution.

Work sheet Community school Feb 2012

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