About the AuthorJOE GREENSLADE See eee Toe super are, a ‘toe “eo anactve memeer of ne Anca Soca of Mechta sie, ve "tgs An anol Faster (NRPDA anda reniet fe Boar veto os Arn aesooaton tors ‘cleat (AL. Fetes omer maroar of nus stnes inst) Hse "acre nde oo ao ‘Arveean Sosy for ‘marbor ofthe Futon Guat At Tat Fore epresaning ne, ‘tanee onthe Sew Tread improvement ak Fuca worn wh ‘rorove soroopace ated ond openers ena eas ear a cael rors Assos Ics precoees Here Is What a Hydrogen Embrittlement Failure Really Looks Like he picture of the broken zine plated socket ness (cap crow in thie artela fe a gteal examle of vit ypial hydrogen emrtlement faire ook Ike. nought nis is would bs a good example to share wih readers because the discussion of hydrogen Crtitlement cores up so olen, bul most people In Inaustry do not know what'@ real hydrogen ‘ombritlemestfabure locks ke “Thote are several classic n- Gicators of a real hyarogen fembitlement fare. I any ot these factors are missing, then the falure must be atrbutable {o something her than ysro- "These fv 1 The fare must be & DELAYED faire. The de Jay is generally rom one fo 24 ous flr istlabon. Ite faiure occurs during instalation, is deitely [NOT caused by hysrogen embritlemert. the delay isa week o alr after installation, the causa ‘tees corosion and not rysrogen ‘mbitiement The falure modes and metalurgial ‘Sppearancee are lgotcal in sess corrosion faluros ang hydrogen embitiement fares, The primary ind= ton of stroee corrosion is that the delay fs longer {han 24 to 48 noure ater mstaabon. More dete on ‘055 corsion wil be dealt wih it aller ate, 2.'the fasteners must be hardened to at least ‘Rosie C27 Unardonedfastnore never sulle fom hyarogen embvitiement. Fasteners that have a hare ‘ess of Rockwal G26 ot less are extremely uly to (ver suffer trom hyerogen erbritiement (636, na groater the chance that to part wal exper nce @ fare strbutabe to hydrogen embitlment Inch socket Head cap sorews, -8 bots, metre prop- try clase 12.0 corane and bolts, and spring tee) ‘washers and fl prs are the common fasteners which fate most suscepibe io hydrogen embrilement fai- ‘tes because of tet high hardness. 83. The faiod pars must bo elocte-pated. The cre- ton of the hydrogen i Ove metal fastener is cause By the leaning processes where acds aro used and ot by the actual appllalion of he plating. Ihave ere ‘tmany eases where non-clectropated parts wore cus pected of yogen em-bitlemnt, but am not aware Gt any thal were confirmed to have falls from Myso- (en embitlement. 1. The appearance must be thal of an negra” fate: Look csely a the surface of te broken areas In the photograph inthis ancl. The surface of the fare looks rlabvely smooth wih a texture thal ook lke the suace of emery cloth I you look at it under ‘magnification, you see tat the surface has a aya le appearance wth many shar aces or facets. Some Secaribe the appearance ae Uoing smiar To broken ‘eck candy, ' bol or screw fare caused by excessive torque cortenalle stesses procuces a faire surface that has Peaks and valleys in it which is referred to as "sim- pling” This sas technically reered to as a “dutle™ fale as opposed to a “bile falure which Is charac- tc of @ Ryrogen embritiement fale If you look the faire srase of bot or ecw falure eure ‘hat has peaks and valleys andor a suiting appear- ance, The flue is highly unlkaly to be altibuable to hyarogen embettement 5: The fale loation is ear where the fstane’s head cannocs othe body or in na threads wathin two ‘tread pices above where the bots tread engages ‘he mating thread Inthe ass of head to shank failures, i frequent, looks lee someone used an ies cream scoop to scoop | the shank out o the underside of he heads, as Is the "he greater the fastner's hardness above Rockwell | casein Me cured part.1 the hygragen locaton is somewhere other han ‘one of these wo lcalons, thon Pyarogen embrten enti probalynothe cup. Hycrogen emoetiemen engagement ve falco always occurs where the siess concentrations {5s the grates ite boi ably aright when {ightered the falurea wil ganeraly be whore the fas. tener Read Joins the body. If tere Salghiess or bonding acton the aepleaton the fale wil moat tly Tain the tread laos the Seas See cerns Best surance agaist eve expetlencing a hy z regen erértlomont allure is to avo the actor that ‘make rysrogen embriierent fares posse by do- ing to fl 1 Do rot lero pat inch socket hoad oa sero, bol of metre property class 12.9 bolts or screws. 2 Ineuclomars init on using elect pato bate and scone, suggest they consider ushg 2 Grade 8 of property etse 109 par ofa sigh larger cameter Ista of using te socket Read cap sow oF prop” ny cass 123 part "site customer inate on using an electroplated sockat ed cap serow or property cess 12.9 part Spoaly that te pare must be baked st 375-400 do. (goes F within one nour ar plain for atleast four Fours “at temperature" ‘seo. conduct ane of the recagnized hydrogen ‘embrtlment tests ‘on every ot of pars wo provige you the opportunty f0 catch rydrogen embrileent before iis existed inthe users spplestion you must elect pate ay ype of apping stew, speaty to te heal ele thal Me core hardness Of ‘ie ezrewe must not exceed Rockwel 69. you wl adhere toe preceding suggestions, you wal greatly improve your ogee of rever hav To ler {p tis arte to som f your customers fare tok ene ptr inthe afte ‘For mre information onthe subject o¢ aay ether fastener quay aesuranes, gaging, o alain ra ‘er conse te suhor at 800-495-2047 by pane o By femal at grensiadeandcomparyesbogoba el. ‘eprom Disribes ik Maine, Spring 2005INDUSTRIAL FASTENERS INSTITUTE 18363 Oak Tree Boulevard «Independence, Ohio 44134 USA, wwrwindiast. org Identifying Hydrogen Embrittiement Failures ‘verte pathy yar, have become sae of many suapedtd cases hysrogen emblem n seus ad bots Empotone fas shown tht many of ese suspected nyrogen embtlament feires wee venti- ‘iy powen to have causes compe ureatedtomysregenemortmor. fs krgrtat fastener suppers intr om to gusty determine wheter ornata reported fare aul beatbutale hydrogen enbrileent, “Tue Fares Have Common Characteristics My undeondng ana exprene rested conte cases of hyrogenembstement ates in fasteners be te Tre pars ost neve on 1) Thefalres must secur some tne afrintataten usualy botaeen one ad tent fur hous { Ptemost toe a noporos en (ual ectosaiag), Tho most comma fesh asscoated wih Mycogen ‘Snorerent sires arews ar basi elected ne. ‘Fre pare must under sees hen flute coo Irany ofthese acre rot pesent the chanes ofthe ire Beng canimed a hysrogen enbtement se unk Unharere fasieners or those of Grade or Property Css 8 rover de NOT fal due to hyéegon mittee Paseners wt ghospale and ald NOT fa due tofysrogen onetrent Pars ha ae deanes [frmecharical rocasos instead of ss are hgh ult fake a hydrogen ember Fates tat coat tho pas are Ging stated ar NOT do hytagenembromen. Head to Body Junctions Most Common Faure Hydrogen embriternert ui ccou where theses nthe stow obo is mosthighy concentrated ‘ateninsalos me appecaton, The st common ocaen ot hyregen embrionen fatres np wher he adjoins the boy fe stew or bon. Frequnty tks be mani has boon scooped et ofthe undead of Theta The scone mos contro lure boston ls messy sbove wha th enor fred w engaged wth Ihe lrcral raed te ppicaton I laure somewhere os onthe pat, the couse proba something ‘the than nyarogen ambient Hydrogen Emtrited Pars Exe lergranular allure Metals fro hytogenenbrtament fae as narra it fluros as oppoee to ducsla ‘eaves, My undesandng oh at when prs fal fom hyarogen enbilemet the comecions between the ‘patrats ana tg vary ono rom one acter wen toy are ut nde tess. Tey eave sh edse= on {he sacs oft tacure win on appearance uc Ika Ys candy. Theres sunly ho evdenoe of any wana 3c- ttonon te ute stn tacure and he faces te teably sbaght aco the ar ansvrs os ana This = ‘Secon orn fares tat ok ke art ha ula pate ly where Ura = sore reking down bor ttl {thre ous Whon a fod surlace look pled ortwstes Ais clea duce aur seas of bile er nigra a FI [ aocmes utes | Identifying Hydrogen Embrittlement Failures | __rsses« [erasers sao Rap 2507 [smabponence OF so oes we ay Tan a a aay Reef pnemn ty ymin ae ane cates een beat Teionearenstete icone:INDUSTRIAL FASTENERS INSTITUTE 66363 Oak Tree Boulevard «Independence, Ohio 44131 USA, wiewindfast.org (re conpcaig ectrinconeming hyogen eminent lures that ot al be sno terran Jar faures re ryeregenenbriereent Sei appeangfalures eoroiy coe fom Rareened pars being sie ‘eadedta the pant wher they break teed of bord, nergfanlrfalues ae ake cee in pas tat are exposed ‘o-eniroents thw intl tat rode hyrogen nthe pai ale! Ny aren pace. The ype o alee ‘stsrad saves cores’ ands equentyeontres win ysropenembement Wineneves deny are SStepated,poiealry when the fale more hans week frst, the epson shail be mvestgated ‘ory toroighiy Ifthe prs ae aes ha amp enironment mere te secon) component are ofa ferent ‘tera then he aston endothe assambly rouportes components of afetent pes ema, Sees caoson stead ofhyeropen ebritlmetis very hey art with Core Hardness of Rockwell or Below are Less Lika o Fall rom Embritement In recent years nave been consuted on arumber of suspected hydrogen embsilemert ares. have ‘made an obsenaton Ibeeve set apical eoldng hysrogenembiemet ateners at inthe eval thysrogenemartemort whens corned n unused pars My experience has nda very sven hat hyarogen emtritements igh uk oeceurineny pata i Reel C26 oc blowin fs coe hardness theta tis eace hardened a In ltotnecoseeothydrogen embitarant nave Been nied wh hat were utimatay cone, the ersharenes te ahs bear Rehr CMe nb nts ware ie pat er aa, ‘hey have ben i of hysrogen by leg the coe hardnes fo Roce G36 or alow Aker having onal Fredpsndenty und tena ene h SAE a3 Mecha! ng Golly Regatomenis Taping Some, Pat provies ths ume sugpeston Secton 45 sis, “Core Hardness Aer Terperng «Sal be Rosewel C289. ete tat he and ofthe sanded ies, "Hardness shal nat excaed manu shaw and prefer shaud be no Nghe’ hen Raceaet C36 to sure aga aire ase ara seen ‘Al loys hex socket proauce ae above Race C38 making then he comme headed fasten that are ha moa auecaptele to hytogenembritrent whan ey at losroplatd, contend ha ay tel hex socket produc should never be eloped Ife custome! wanls cores reastance, phosphate ano can Previse es muah carsion ost, ss anc ar ler ar rear yllon seomate wou cng hydrogen "mbitement Ihe customer cesressver screws for appesane eesons susgestsuplying Me stows th SNer Dart heads 2s opposed o 2 pated sews, "New ASTM Spoc Helps Pltors Detect Embritied Pars Quickly After Processing Alot fof connie ogpino te prevention and detection of hyerapen emit. A gaat aaverce Innyirogen erbetiomertdaecien fac been te daveopmt of ASTM F1040 99 hal poudes 2 means manso- ing para prooessosodetarmie I hiyarogen enelenent is Seing reste in he parts bang pated This procnss ‘orion standard ond ts dasa esi ue staring ob scenes by member ofthe ing nt butwideacceptance an uses expect ine fare The edpton ois standard by ples willbe mae lp ‘orwaré inthe eimsnatn at ue hydrogen embuitlement ales infaeers, ost plain baking shoud alway be permed on lacaplae pars having a cre harness of Rockvel ‘032 or above. The most wide auggeste big procedure rhe pars to be Baked fore annun of ur Mars ‘1400 to 425 (206°C to 218°C) wn one our arte patna proces. Rie ea he pars arena ony inthe unce or four hours, buthet they ate ae age lmpettire to fourhours Fr ‘Technical Bulletin IF [psec nd esos tl [inaependene, OF Identifying Hydrogen Embrittlement Failures Page 204 esoed August, 2007 ‘Sethe roc wt ateopna a lee am camage ghee. mformang ne approve sane pees, iF Ra et edness toroner spon oy put sitet snes sar cedomon ROTA ERS RTINDUSTRIAL FASTENERS INSTITUTE 6363 Oak Tree Boulevard + Independence, Ohio 44131 USA, www indfast.org Gather Samples & Facts Immediately When a Suspected Embritdement Failure is Reported Fastener supers should ake precautions to ao hydiogen emiterent ales by encouraging plates to adhere to AST F040, by equtg boking afer elecropatn, aha by lesing lof lctoplted screws and bats tht nave a core hauness of Rocko C26 or above bythe time-delay torus tet Wen a customer reports 3 Sispedes nyrogen embitonent ale supple shoud nat pane. Ak many Queslons ard get samples DOD {ated and unused pas fom te amet: evaluation. Koop in mind that fhe pars do nethave car hardness of Rocke C36 o above hey are at electoplate andthe fate aoc dng te assembly proses of ve than @ wes af nstalsion, righ wel he ales associated wih narogenembriioment Disclaimer: Alien provided inthis document ardor presentatons bated on data he Indust Fasteners Insite belies tbe relble and accurate Such intumatan sanded fuse by persone 2 the on Graton ‘ad isk The infaraton hee ins basod on inst standards and recognized pracices, The inal Faionars Insitute and te represntzives prong he metal aseene no responsi forte content ae IFI pene | Identifying Hydrogen Embrittlement Failures | Paseo fname Tce Raga 257 tinier on Kara eleaiaie Sania ba ane ann NER RR eepsn abet ais dct a eine wenn es Schone cay. ee” eel foe Ipaogsn ‘tence cca Hyon ton Wa ee ‘Seon sree coi rr iy Be ited 1S icuia were hig or a eon Te ‘Rs of ge ei iy a res “he wk pest ce sh wee pst tale Tate Scant ecu ome ase cece ater wie wang fale) (Gal faa) stow ssa gute low te pect pootseo “Te cus ccd a he 6 sk stn of ‘Peel ule toe eg THe ‘towing nnd atoruicn we pie fo fare ns Popups omg witha face oie nde cel aac en tet {sere pd be cs 109 (8098: Din Sead 1g fGen wo acre as Pliny vin geste fhe fcr ts owed acetic were set an he rp Db ‘aumed “ampcnty wiht nek ae Tora Faraz ane Manuela Ore, eft in he wan one betes hed and sa {fer atm gon dain abr cnn, (cope ufc ne gute set and sora Se ‘ico ft oped cep fre os Pt ‘png the df ae, {cure ee oe al vin al wc he Ces escalate, wb Sea nang Soorwceoened ‘The flloving ts nero Frctgnghic. examination of beak tts. face {Grice low mapas (2 20 tne) ah Sricr suconireoqe ued abo a her Sein ti SE 5 i Mentone amin eel icon of thecal fo mesma gtal ‘Sm one Rodan tk pt mars 0 ‘adit igh btn ste a 2 RESULTS ‘SLpactocean - ‘seas tow mafouve 2) some tt ace shanti were slr in bat ae Indtng nt ue as eve eso ye sane — fe crs woe snot pare th cos set ta occured ost no once wf Sorte Ce ‘Sharm nt here ufo wor siya wih eel ek ‘con ones all sand ieee su ‘igi were sg lr eve er ‘Epc rn nen at fue re copending his it ge ‘apt shel he mest ste 2 Siandaer et edd pope wove he et, a ttre mtb ie. inl pr scared vet er ad sowed» Sears Co faces score no stn ar ‘Skinned nee A a co