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Yu1
& ARCHITECTS'
GUIDE:
HOT DIP GALVANIZING
Galvanizers Association provides
RIBA CPD assessed material:
Literature
The Engineers & Architects' Guide:
Hot Dip Galvanizing
The Engineers & Architects' Guide
to Nuts and Bolts
Seminar
"Corrosion protection of steel
by Hot Dip Galvanizing"
For further information contact
Nicky Smith on 0121 355 8838
or email n.smith@hdg.org.uk
Front Cover: Bellmouth Passage Footbridge, Techniker & Patel Taylor, Peter Cook / View
THE ENGINEERS
& ARCHITECTS' GUIDE:
STEEL IS A STRONG, VERSATILE AND INEXPENSIVE Hot dip galvanizing has many benefits Our technical team is on hand to give an
MATERIAL WITH USES IN MANY DIFFERENT as a method of corrosion protection. immediate answer to all your queries about
Importantly, it will: galvanizing. GA also monitors regulations,
INDUSTRIES. IT HAS, HOWEVER, ONE MAJOR takes a leading role in standards development
DISADVANTAGE: IT IS PRONE TO CORROSION, s¬PROVIDE¬STEEL¬WITH¬A¬COATING¬WHICH and oversees research projects to support
EVEN IN INTERIOR ENVIRONMENTS CORROSION has a long, predictable and and develop the industry.
PREVENTION IS THEREFORE ESSENTIAL IF STEEL maintenance free life.
GA can also visit your company to give a
STRUCTURES ARE TO BE ECONOMICAL. s¬BE¬HIGHLY¬COMPETITIVE¬ON¬A¬FIRST¬ presentation which is approved by RIBA for
cost basis Continuing Professional Development (CPD).
TODAY, INCREASED AWARENESS OF THE LONG-TERM GA publishes a wide range of technical
SAVINGS POSSIBLE FROM REDUCED MAINTENANCE s¬BE¬THE¬MOST¬ECONOMIC¬WAY¬ literature, surveys the market and its
to protect steel over long periods trends and improves communications
COSTS HAVE HIGHLIGHTED THE NEED FOR DURABLE about galvanizing.
PROTECTIVE SYSTEMS FOR STEEL. THIS GUIDE s¬BE¬A¬SUSTAINABLE¬SOLUTION
HAS BEEN PRODUCED TO ASSIST DESIGNERS,
SPECIFIERS, FABRICATORS AND USERS OF This Guide is published by Galvanizers
Association, which represents the hot dip
STEELWORK TO DEVELOP THE MOST EFFECTIVE, galvanizing industry of the UK and Ireland.
PRACTICAL AND ECONOMIC SOLUTIONS. It contains the essential information needed
by architects, consulting engineers and others
in selecting a corrosion protection system.
04
E&A INTRODUCTION
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING CONTENT
ONE - Galvanizing and the environment - Zinc - natural & essential for health 06
GALVANIZING & SUSTAINABLE - Recycling & the environment
CONSTRUCTION - GalvAction 21 - taking the galvanizing
industry forward
05
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION ONE GALVANIZING AND
SUSTAINABLE CONSTRUCTION
SECTION
ONE
_
TITLE
GALVANIZING AND
SUSTAINABLE CONSTRUCTION
_
FUTURE TECHNOLOGIES WILL BE LOW ENERGY
LOW WASTE. GALVANIZING IS A RECYCLABLE
SOLUTION THAT REDUCES THE ENERGY DEMAND
OF STRUCTURES.
The pressures on global industry to accept environmental responsibility GALVANIZING AND In the galvanizing process, iron or steel
for its actions is wholly justified, given society’s quest for sustainability. articles are dipped into a bath containing
THE ENVIRONMENT
_ molten zinc just above its melting point.
The philosophy of sustainability is quite simple and is concerned with Any zinc that does not form a coating on the
ensuring a better quality of life for everyone - now and, importantly, Galvanizing, the coating of iron or steel metal remains in the bath for further re-use.
for generations to come. The concept is common sense based on with zinc, is probably the most Galvanizing residues are recovered and zinc
substantial criteria and principles. It sets out to meet four objectives: environmentally friendly process available recycled for further use.
to prevent corrosion. It is estimated that
s¬3OCIAL¬PROGRESS¬WHICH¬RECOGNISES¬THE¬NEEDS¬OF¬EVERYONE corrosion costs around 4% of GDP in As well as zinc recovered from these
the USA. Effective corrosion protection residues, recycled zinc from other sources,
s¬-AINTENANCE¬OF¬HIGH¬AND¬STABLE¬LEVELS¬OF¬ECONOMIC¬GROWTH¬ is a vital means of reducing the energy such as zinc scrap, is often used in
and employment demands of buildings and structures. galvanizing. Galvanized steel can be recycled
easily with other steel scrap in the steel
s¬%FFICIENT¬PROTECTION¬OF¬THE¬ENVIRONMENT Every 90 seconds, across the world, one production process.
tonne of steel turns to rust; of every two
s¬0RUDENT¬USE¬OF¬NATURAL¬RESOURCES tonnes of steel made, one is to replace rust. Improvements in gas burner technology have
also greatly improved energy efficiency in
In respect of efficient protection of the environment and prudent use Use of hot dip galvanizing to prevent rust heating the galvanizing bath. Exhaust heat is
of natural resources, the hot dip galvanizing process stands up to means that for every one tonne of steel not wasted and is used to heat pre-treatment
scrutiny and can be considered as a major contributor towards protected we conserve enough energy to chemicals or dry work prior to immersion.
sustainable construction. satisfy an average family’s energy needs
for several weeks. The galvanizing industry is committed to
understanding and improving the life-cycle
Galvanizing is efficient in its use of zinc to environmental performance of its process
protect steel for very extensive periods - and products. Galvanizers Association has
saving energy and resources with minimal recently helped establish a Pan-European
impact on the environment. Galvanizing Life Cycle Inventory database for general
will protect steel structures for decades galvanizing. This LCI data will allow
and minimises maintenance. Environmental Product Declarations and
other life cycle assessments to be made
Zinc, the natural element responsible for this on structures involving galvanized steel.
corrosion resistance, is indispensable for
humans, animals and plants.
06
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION ONE GALVANIZING AND
SUSTAINABLE CONSTRUCTION
Process emissions
07
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION ONE GALVANIZING AND
SUSTAINABLE CONSTRUCTION
Total Scrap
Primary Zinc
smelter
Production of
materials and
Fig. 1. products
The recycling process
for zinc in galvanized steel
RECYCLING Other examples of uses and markets ZINC - NATURAL AND The natural concentrations of zinc in different
_ for recycled zinc: environments are referred to as background
ESSENTIAL FOR HEALTH levels and can vary considerably between
Zinc is the principal raw material AND THE ENVIRONMENT
s¬:INC¬OXIDES¬
¬PHARMACEUTICALS¬FOOD¬ _ locations. The animal and plant species
in galvanizing.
fertilisers and for curing rubber. within a particular area have evolved to take
Zinc is essential to life. It is a natural element up zinc from their environment and use it
Zinc is an inherently recyclable non-ferrous
s¬:INC¬DUST¬
¬PAINTS¬CHEMICALS¬LUBRICANTS found in all plants and animals and plays a for specific functions in their metabolism.
metal. It can be recycled indefinitely without
batteries and in gold recovery. crucial part in the health of our skin, teeth, Consequently, all organisms are conditioned
any loss of physical or chemical properties.
bones, hair, nails, muscles, nerves and brain to the bio-available zinc concentrations in
This is a major advantage for the hot dip
s¬!LLOYED¬WITH¬OTHER¬METALS¬
¬CAST¬INTO¬ function. Zinc and its chemistry is found in their environment which are not constant but
galvanizing process ensuring its environmental
precision parts for appliances, over 200 enzymes and hormones in man. subject to seasonal variations. Organisms
sustainability and its cost effectiveness.
hardware, electronics and toys. have mechanisms to regulate their internal
Zinc deficiency is a recognised health problem. zinc levels. If uptake levels drop too low,
About 30% (2 million tonnes) of the world’s
Hot dip galvanizing is very efficient in its The Recommended Daily Allowance (RDA) of deficiency can occur and adverse effects
zinc consumption is from recycled sources.
use of zinc, as any of the molten metal not zinc is 15mg for a male adult, a figure that is may be observed.
A figure which is rising with increased
forming a coating on the steel will run back easily met by a balanced diet containing meat
environmental awareness and improvements
into the galvanizing bath. and vegetables. However, certain people
in recycling technology.
require more zinc than others, pregnant and
Three residual products are formed during lactating women for example, may need as
Estimates suggest that 80% of zinc available
the process; a zinc/iron mix called dross, much as 19mg a day. The elderly may be
for recycling is in fact recycled (with today's
zinc ash and flux skimmings. All of these zinc deficient because of reduced food
tecnology). This means that much of the zinc
contain valuable zinc and are recovered and consumption, especially of proteins, and so
in use today has probably been used before.
recycled by specialist firms and the recycled they may need to take a zinc supplement.
zinc is often returned to the galvanizer. Zinc
The presence of a zinc coating on steel does
oxide is recovered from galvanizers’ ashes Zinc is the 17th most common element in
not restrict its recyclability. Galvanized steel
and used in pharmaceutical/beauty products. THE¬EARTHS¬CRUST¬-OST¬ROCKS¬CONTAIN¬ZINC¬IN¬
is recycled with other steel scrap in the steel
varying amounts and zinc exists naturally in
production process; it volatilises early in the
air, water and soil. Due to natural weathering
process and is collected for reprocessing.
and erosion of rocks, soils and sediments
together with volcanic eruptions and forest
fires, a small but significant fraction of natural
zinc is continuously being mobilised and
transported in the environment.
08
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION ONE GALVANIZING AND
SUSTAINABLE CONSTRUCTION
09
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TWO AN INTRODUCTION
TO HOT DIP GALVANIZING
SECTION
TWO
_
TITLE
AN INTRODUCTION TO HOT DIP GALVANIZING
_
HOT DIP GALVANIZING, HAS GROWN ALMOST
CONTINUOUSLY SINCE IT WAS FIRST USED TO
PROTECT CORRUGATED IRON SHEETS 150 YEARS
AGO. ITS ABILITY TO GROW IN THE FACE OF
SOPHISTICATED COMPETITION IS THE RESULT OF
THE SIMPLICITY OF THE PROCESS AND THE UNIQUE
ADVANTAGES OF THE COATING.
10
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TWO AN INTRODUCTION
TO HOT DIP GALVANIZING
11
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TWO AN INTRODUCTION
TO HOT DIP GALVANIZING
THE GALVANIZING PROCESS THE COATING Centrifuged galvanized coatings Galvanizing reactive steels
_ _
This involves a process covered in BS EN ISO A thicker zinc coating will be obtained if the
When the clean iron or steel component When the reaction between iron and zinc
1461 and is used for galvanizing threaded article to be galvanized is manufactured from
is dipped into the molten zinc (which is has virtually ceased the article is taken out of
components and other small parts. The parts, a reactive steel. The constituents in steel that
commonly at around 450°C) a series of zinc- the galvanizing bath complete with its outer after preparation, are dipped in the molten have the greatest influence on the iron/zinc
iron alloy layers are formed by a metallurgical coating of free zinc, the process is complete. zinc in a perforated basket. After the coating reaction are silicon, which is frequently added
reaction between the iron and zinc. A microsection of the galvanized coating has formed this is centrifuged or spun at high to steel as a deoxidant during its production,
The rate of reaction between the steel and will look like the picture above (Fig 2). speed, to throw off the surplus zinc to ensure and phosphorous. Silicon changes the
the zinc is normally parabolic with time and In reality there is no demarcation between A¬CLEAN¬PROFILE¬-INIMUM¬AVERAGE¬COATING¬ composition of the zinc-iron alloy layers so
so the initial rate of reaction is very rapid and steel and zinc but a gradual transition through weights for centrifuged work are identified in that they continue to grow with time and the
considerable agitation can be seen in the zinc
the series of alloy layers which provide the BS EN ISO 1461 and in BS 7371 Part 6. rate of growth does not slow down as the
bath. The main thickness of coating is formed
metallurgical bond. layer becomes thicker (Figs 4 & 5). To a lesser
during this period. Subsequently the reaction
Thicker coatings may be produced by one of degree phosphorus exerts a similar influence
slows down and the coating thickness is not
COATING THICKNESS the following: on the formation of the coating.
increased significantly even if the article is in _
the bath for a longer period of time.
Thicker coatings by surface roughening When an article fabricated from a reactive
A typical time of immersion is about four The coating thicknesses’ are normally
steel is removed from the zinc bath, a zinc
or five minutes but it can be longer for determined by the steel thickness and are This is the most common method of layer adheres to the alloy layer as with any
heavy articles that have high thermal inertia set out in BS EN ISO 1461 (see Section 7). achieving thicker coatings. other steel article. However, the reaction
or where the zinc is required to penetrate There are three exceptions to this rule, rate in these steels can be so high that this
internal spaces. Upon withdrawal from the the first produces a slightly thinner coating, Grit blasting, to Sa 2½ (ISO 7079), the steel pure zinc layer is transformed completely
galvanizing bath a layer of molten zinc will be the other two increase it. surface prior to immersion, using chilled to zinc-iron alloy before the article has had
taken out on top of the alloy layer. Often this
angular iron grit of size G24, roughens and time to cool. The result is a coating of equal
cools to exhibit the bright shiny appearance
increases the surface area of steel in contact or increased thickness which can be much
associated with galvanized products.
with the molten zinc. This generally increases darker in appearance as is described in
the weight per unit area of a hot dip Section 9. The change in appearance
Post galvanizing treatment can include
galvanized coating by up to 50% (Fig. 3). does not alter the corrosion resistance
quenching into water or air cooling.
Any steel article can be treated in this way, of the coating.
providing it is thick enough to withstand
Conditions in the galvanizing plant such as
blasting. It may not be possible to grit
temperature, humidity and air quality do not
blast the inside surface of hollow sections
affect the quality of the galvanized coating.
and fabrications, but these are almost
By contrast, these are critically important for
always the areas least prone to corrosion.
good quality painting.
Thicker coatings than those required by
BS EN ISO 1461 should only be specified
following consultation with the galvanizer
or Galvanizers Association
(see also Section 7).
12
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TWO AN INTRODUCTION
TO HOT DIP GALVANIZING
Fig. 5.
Approximate thickness of the zinc coating in relation
to the silicon (Si) content of the steel.
(This is a schematic representation, please contact
Galvanizers Association for detailed information)
13
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION THREE 0(93)#!,¬0%2&/2-!.#%
SECTION
THREE
_
TITLE
PHYSICAL PERFORMANCE
_
THE UNIQUE NATURE OF THE GALVANIZING PROCESS
PROVIDES A TOUGH AND ABRASION RESISTANT
COATING WHICH MEANS LESS SITE DAMAGE
AND SPEEDY ERECTION OF STRUCTURES.
COHESION TOUGHNESS
_ _
Unlike most protective coatings, which rely Resistance to mechanical damage of
solely on the preparation of the steel to protective coatings during handling, storage,
obtain adequate adhesion, hot dip galvanizing transport and erection is very important if
produces a coating which is bonded the cost of ‘touching up’ on site is to be
metallurgically to the steel. In other words, avoided. The outer layer of pure zinc is
the iron and the zinc react together to form relatively soft and absorbs much of the shock
a series of alloys which make the coating of an initial impact during handling. The alloy
an integral part of the steel surface with layers beneath are much harder, sometimes
excellent cohesion. even harder than the base steel itself. This
combination provides a tough and abrasion
resistant coating. (Fig 6)
Zn
Zn
+
Fe
Fe
Fig. 6.
-ICRO¬SECTION¬OF¬HOT¬DIP¬GALVANIZED¬COATING¬
showing variations in hardness through the
coating. The zinc-iron alloys are harder than
the base steel.
14
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION THREE 0(93)#!,¬0%2&/2-!.#%
15
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION FOUR #/22/3)/.¬0%2&/2-!.#%
SECTION
FOUR
_
TITLE
CORROSION PERFORMANCE
_
70
corrosion depends on a protective film which protective systems in different environments.
11 zinc corrosion rate g/m2/yr forms on the surface of the zinc. When the BS 5493 ‘Code of Practice for Protection of
60
steel is withdrawn from the galvanizing bath, Iron and Steel Against Corrosion’ provided
SO2 μg/m3 of air
the zinc has a clean bright, shiny surface. some information but its guidance on the
50
09 With time this changes to a dull grey patina lifetime of galvanized coatings is now
40
as the surface reacts with oxygen, water out-of-date.
and carbon dioxide in the atmosphere.
SO2 μg/m3 of air A complex but tough, stable, protective layer
07 30 Since BS 5493 was published in 1977,
is formed which is tightly adherent to the zinc. atmospheric sulphur dioxide levels (SO2)
20 Contaminants in the atmosphere affect the have reduced considerably. A direct
05 nature of this protective film. relationship exists between the corrosion
10 rate of zinc and airborne SO2 levels (Fig 7).
The most important contaminant for zinc is Therefore, the life of galvanized coatings
03 03 sulphur dioxide (SO2) and it is the presence has increased significantly since the
of SO2 which largely controls the atmospheric 1970’s and it is important to use
corrosion of zinc. up-to-date information in assessments
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
16
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION FOUR #/22/3)/.¬0%2&/2-!.#%
The environments in most corrosion guides Comparison of data obtained from The Zinc Table 1.
are necessarily general. Specific corrosivity -ILLENNIUM¬-AP¬PAGE¬
¬WITH¬RESULTS¬ Indicative zinc corrosion rates for different environments Source: BS EN ISO 14713
values in the UK have been mapped by the from previous maps (1982 and 1991) show (Corrosivity categories from ISO 9223)
Agricultural Development Advisory Service a clear, and very significant, drop in the
(ADAS). The information was based on data corrosion rate for zinc for most atmospheric
obtained from exposure of zinc reference exposures across the UK and the Republic average annual zinc
samples at National Grid Reference points of Ireland. corrosivity category corrosion rate (μm/year)
in a large number of 10km square reference
areas of the UK. In particular, urban locations which, in the C1 interior: dry <0.1
past may have been considered aggressive
The results indicated varying rates of C2 interior: occasional condensation
for zinc, will yield significantly enhanced
corrosion for zinc in exterior locations. exterior: rural 0.1 to 0.7
lives for galvanized coatings. In more remote
Galvanizers Association sponsored the
revision of the map, to provide specifiers locations these downward trends in SO2 C3 interior: high humidity, some air
with the very latest information on zinc levels are not so pronounced and the pollution exterior: urban inland
corrosion. For the first time the survey was (already low) corrosion rates for zinc would or mild coastal 0.7 to 2
extended to the Republic of Ireland. The not be anticipated to be further reduced to
same experts that were involved in the any significant extent. C4 interior: swimming pools, chemical
development of previous corrosivity maps plants exterior: industrial inland
were contracted to co-ordinate the project. A brief inspection of Table 1 and Figure 8 or urban coastal 2 to 4
confirms that for most exterior applications
of galvanizing the corrosion categories across C5 exterior: industrial with
large areas of the UK and the Republic of high humidity or high
Ireland are C2 / C3 ie 0.1μm/yr - 2μm/yr. salinity coastal 4 to 8
4HE¬:INC¬-ILLENNIUM¬-AP¬RESULTS¬SHOW¬THAT¬A¬
standard 85μm galvanized coating may now
achieve a coating life of 50 years in most
environments. Similarly, a thicker 140μm
galvanized coating, often produced on
structural steel, may achieve a coating
life of over 100 years.
17
18
Fig. 8
s¬,OCATE¬YOUR¬PROJECT¬ON¬THE¬MAP
s¬-ATCH¬THE¬COLOUR¬OF¬THE¬SQUARE¬TO¬THE¬KEY
SECTION FOUR
s¬2EAD¬OFF¬THE¬AVERAGE¬BACKGROUND¬CORROSION¬
rate in μm per annum
s¬)DENTIFY¬THE¬MINIMUM¬AVERAGE¬GALVANIZED¬¬
coating thickness for steelwork in μm
(see section 7)
s¬$IVIDE¬THE¬COATING¬THICKNESS¬BY¬THE¬
corrosion rate to obtain the expected
minimum life of the galvanized coating
#/22/3)/.¬0%2&/2-!.#%
Acknowledgements
PERFORMANCE IN Where this situation could arise, sacrificial In contact with wood High temperature
protection can be assured by installing a
OTHER ENVIRONMENTS
_ magnesium anode as ‘back-up’ Very acidic woods such as oak, sweet Galvanized coatings will withstand continuous
to the zinc coating. chestnut, western red cedar and douglas exposure to temperatures of approximately
Interior environments fir can be used in conjunction with 200°C and occasional excursions up to 275°C
Immersed: Sea water galvanized steel, provided they are isolated without any effect on the coating. Above
A common misconception is that corrosion from direct contact. these temperatures there is a tendency for
may not be a problem for interior steelwork Sea water is more aggressive than freshwater. the outer zinc layer to separate, but the
which is protected from the elements. For UK waters the corrosion rate normally In contact with other metals alloy-layer, which comprises the majority
If there is frequent condensation on its lies in the range 10 - 15μm/yr for continuous of the coating, remains intact. Adequate
surface, corrosion of inadequately protected immersion. Tidal immersion, regular sea spray There is only slight additional corrosion of protection may often, therefore, be provided
steel will be significant. Under these or immersion in warm tropical sea water can zinc as a result of contact with the majority up to the melting point of the alloy layer
conditions, hot dip galvanizing may give more lead to an increased corrosion rate. of metals in most atmospheric conditions. (around 530°C).
than 40 years life. Hot dip galvanizing has Bimetallic corrosion can occur in immersed
also been used extensively to protect interior Underground conditions or in locations where rainwater In contact with building materials
steelwork in harsh environments such as is unable to drain easily or dry out at the
swimming pools and breweries. Corrosion The life of a buried galvanized coating can contact surfaces. Guidance is given in BSI’s Damp mortar, cement and plaster have
may also arise on exposed ungalvanized vary depending on, for example, the type PD6484: ‘Commentary on corrosion at a slight etching action upon galvanized
steelwork intended for interior environments if of soil - its acidity and whether it has been bimetallic contacts and its alleviation’. coatings whilst drying or setting.
there is a delay in assembly or construction. disturbed, (contact Galvanizers Association This effect ceases once the action
for further advice). A pH range of 5.5 to 12.5, In contact with chemicals has finished.
Immersed: Cold water ie. weakly acid to alkaline, is favourable.
Soils containing ashes and clinkers are Contact with chemicals requires special
-OST¬WATERS¬CONTAIN¬SCALE
FORMING¬SALTS¬ especially harmful. In many cases, the consideration. A wide range of chemicals are
which can form a protective layer on the application of a bituminous solution (to compatible with galvanized steel. Prolonged
inside surfaces of galvanized water BS3416 Type 1) over the zinc coating is or frequent contact with acids and strong
distribution systems, hence coatings can beneficial - particularly where galvanized steel alkalis is not advisable.
have their lives enhanced usually to greater is buried in the ground or at the point where it
than 40 years. If these salts are not present, emerges from concrete. Galvanized steel can
as is often the case in soft waters, longer life be safely embedded into concrete. For even
can be obtained by applying two coats of greater protection in soils, thicker galvanized
bituminous solution (to BS3416 Type II coatings can be specified (see Section 7).
for drinking water).
20
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION FOUR #/22/3)/.¬0%2&/2-!.#%
21
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION FIVE HOW GALVANIZING PROTECTS STEEL
SECTION
FIVE
_
TITLE
HOW GALVANIZING PROTECTS STEEL
_
BARRIER PROTECTION
_
Galvanizing provides a barrier between all
internal and external steel surfaces and their
environment. Galvanizing is a term often
wrongly used to describe zinc coatings in
general. Fig. 9. illustrates how the different
types of zinc coatings vary in terms of coating
thickness. The life expectancy of a zinc coating thickness: μm measured from steel surface
coating is largely determined by its thickness. 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140
Thicker coatings give longer life. Hot dip 85
galvanizing provides fabricated iron or steel steel surface coating weight: g/m2 610
products with maximum protection through
a continuous, tough, metallurgically bonded steel of > 6mm section
coating of much greater thickness. hot dip galvanized to EN ISO 1461
Fig. 9.
Zinc coatings compared in terms of coating thickness
22
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION FIVE HOW GALVANIZING PROTECTS STEEL
PROTECTION BY
SACRIFICIAL ACTION
_ Fig. 10.
Schematic to illustrate the consequence of damage to
Zinc corrodes in preference to steel and different types of coating offering corrosion protection.
sacrifices itself to protect the steel, hence
hot dip galvanizing will provide this sacrifical
action Fig 10. The corrosion products from
the zinc are deposited on the steel resealing Anodic
it from the atmosphere and therefore stopping (electronegative) end - more active metals
corrosion. With paint coatings, additional
protection would have to be applied -AGNESIUM
immediately after the damage occurred or the Zinc
Aluminium
steel would rust with eventual break down of
Cadmium
Zinc protects steel
the whole coating as rust crept underneath Steel
the paint film. Lead
Tin
Nickel
Brass
Copper
Cathodic
hot dip paint coating coating of more (electropositive) end - less active metals
galvanized coating electro-positive
The steel rusts metals than steel
Zinc’s position in the Galvanic Series
A galvanic cell is where the paint film
formed. The zinc has been damaged. Nickel, chromium,
around the point of Rust creeps under and copper - give
damage corrodes. the paint film, which rise to more rapid
Corrosion products is lifted up from corrosion at the
precipitate on the the steel surface. point of damage
steel surface and Corrosion continues than if the steel
protect it. The steel until the damage had been uncoated.
is also protected has been repaired. The corrosion often
because it is takes the form of
cathodic in relation pitting, which can
to the zinc coating. even go through
the steel.
23
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION SIX #/34¬!.$¬%#/./-)#3
SECTION
SIX
_
TITLE
COST AND ECONOMICS
_
24
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION SIX #/34¬!.$¬%#/./-)#3
25
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION SIX #/34¬!.$¬%#/./-)#3
WHOLE-LIFE COST
_
Design Build Operate Dispose Total 2,500
The whole-life cost of a building can be
defined as:
Run/Maintain
“The cost of acquiring, operating and £ - 40% 2,000
maintaining a building over its whole life
through to disposal” 100%
£ £ Repair £ Cost
1,500
Whole-life costing can be characterised as 3% 17% £ - 30% ?% of
a system that quantifies financial values for Ownership
buildings from inception and throughout the Cost
building’s life. It is an approach that balances Periodic £
Replacement/Refurbish 1,000
capital with revenue costs to achieve an
optimum solution over a building’s whole life. £ - 10%
Sep 06
Sep 08
Sep 10
Sep 12
Sep 14
Sep 16
Sep 18
Sep 20
Sep 22
Sep 24
Sep 26
Sep 28
Sep 30
Sep 32
Sep 34
Sep 36
Sep 38
Sep 40
It is estimated that up to 80% of a building’s
whole-life cost can be attributed to
running, maintenance and refurbishment
costs. Consequently, there are spikes in Fig. 12a.
expenditure at 10 years and every five Smoothing the Expenditure
years after that (see Fig. 12a). Life cycle expenditure tends to inherently produce
“spiky” profiles with large peaks at 10, 15, 20, 25 years.
The initial choice of materials and the way
that they are protected obviously plays
an important role within the maintenance
and refurbishment costs of a building
over its lifetime. They therefore have a
very large influence on the whole-life
cost profile of the project.
27
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION SEVEN SPECIFYING HOT DIP GALVANIZING
SECTION
SEVEN
_
TITLE
SPECIFYING HOT DIP GALVANIZING
_
coatings on iron and steel articles is defined hot dip galvanizing throughout the National
by a single standard, BS EN ISO 1461 Building Specification (NBS) system, the
200
‘Hot dip galvanized coatings on iron and steel main location being G10 - Structural steel
articles - specifications and test methods’. framing. General guidance on corrosion
protection is also given.
The galvanizer acts as a specialist
subcontractor to a steel fabricator and, In the unlikely event of being unable to
100 identify the correct clause for a particular
as such, his contractual relationship is with
the fabricator, not with the ultimate user. galvanizing application, please contact
80
It is important, therefore, that the user’s Galvanizers Association for specific advice.
requirements for galvanizing are made clear
60
to the fabricator and that all communications
concerning galvanizing are channelled
through the fabricator. To ensure the best
quality and technical back-up service, it 40
should be stated that the work be ‘processed
by a member of Galvanizers Association’. 30
Fig. 13.
Relationship between steel thickness
and surface area/tonne
28
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION SEVEN SPECIFYING HOT DIP GALVANIZING
29
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
SECTION
EIGHT
_
TITLE
DESIGNING ARTICLES FOR GALVANIZING
_
EARLY CONSULTATION BETWEEN GALVANIZER, FABRICATOR AND
DESIGNER IS THE KEY TO OBTAINING THE BEST RESULTS FROM THE
GALVANIZING PROCESS. DESIGN FEATURES, WHICH AID THE ACCESS
AND DRAINAGE OF MOLTEN ZINC, WILL IMPROVE THE QUALITY AND
APPERANCE OF THE COATING.
FILLING, VENTING General principles size of hollow minimum diameter Where venting of a hollow section is required,
AND DRAINAGE section (mm) of hole (mm) for a longer section (e.g. > 3 m) there may
_ 1. Holes for venting and draining should be a need for additional or larger vent holes
be as large as possible. The minimum hole < 25 10 to help achieve the best possible surface
Good design requires:
diameters are given in Table 5. finish and advice should be sought from
≥ 25-50 12 the galvanizer.
s¬MEANS¬FOR¬THE¬ACCESS¬AND¬DRAINAGE¬
2. Holes for venting and draining should be
of molten zinc
diagonally opposite to one another at the high > 50 - 100 16 Holes that have been drilled for venting can
point and low point of the fabrication as it is be plugged, but this is mainly necessary for
s¬MEANS¬FOR¬ESCAPE¬OF¬GASES¬FROM¬INTERNAL¬
suspended for galvanizing. Very long hollow > 100 - 150 20 aesthetic reasons, because a galvanized
compartments (venting)
sections may require additional vent holes coating covers all surfaces. If required,
to aid drainage and to help produce a better > 150 consult galvanizer tapered aluminium or plastic plugs are
It is important to bear in mind that the
surface finish. available and will prevent undesirable
steelwork is immersed into a bath of molten
ingress of water.
zinc at a temperature of 450°C. Thus any
3. With hollow sections sealed at the ends,
features which aid the access and drainage
holes should be provided, again diagonally Detailed design advice is available from
of molten zinc will improve the quality of the Table 5.
opposite one another, as near as possible Galvanizers Association or directly from the
coating and reduce costs. Suitable sizes of vent holes in
to the ends. In some cases it may be more galvanizer. Some points to bear in mind for
economical to provide V or U shaped notches tubular structures venting and draining are illustrated in the
With certain fabrications, holes which are
in the ends, or to grind corners off rectangular diagrams on pages 34 - 38.
present for other purposes may fulfil the
hollow sections - these procedures provide
requirements for venting and draining;
ideal locations for venting and draining.
in other cases it may be necessary to
provide extra holes for this purpose.
4. Where holes are provided in end plates
or capping pieces, they should be placed
For complete protection, molten zinc
diagonally opposite one another, off centre
must be able to flow freely to all surfaces of
and as near as possible to the wall of the
a fabrication. With hollow sections or where
member to which the end plate is connected.
there are internal compartments,
the galvanizing of the internal surfaces
5. Internal and external stiffeners, baffles,
eliminates any danger of hidden corrosion
diaphragms, gussets etc., should have
during service.
the corners cropped to aid the flow of
molten zinc.
30
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
Cold Rolled 10% Cold Rolled 40% With Punched Holes Welded Steel
EN 10025-2 Tensile strength (Pa) 453 461 563 560 741 706
S275
0.5% proof stress (Pa) 294 281 550 502 732 659
EN 10025-2 Tensile strength (Pa) 531 522 644 635 811 784
S355
0.5% proof stress (Pa) 367 362 634 587 807 746
+
Elongation (%) 41 43 16 20 8 15 15 16 25 33
EN 10028-3 Tensile strength (Pa) 585 597 714 734 905 860
P460
0.5% proof stress (Pa) 451 446 692 683 896 842
Elongation (%) 36 34 21 21 10 13 ^6 5 29 30
key
* As Received
+ 10 % Cold Rolled
^ 40% Cold Rolled
Table 6.
Tensile properties of structural steel tests on plates 12.7mm thick (source: ILZRO, 2006)
32
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
33
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
34
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
Extenal stiffeners, welded gussets Cropping the corners of these brackets will Angle bracings should, if possible, be On structural hollow sections, provision
and webs on columns and beams, aid access and drainage of molten zinc and stopped short of the main boom flange. must be made for venting and draining.
and gussets in channel sections a cleaner coating will be obtained. This will allow the free flow of molten zinc With vertical members, drilled holes or V
should have their corners cropped. across the surface of the flange, enhancing notches should be provided, diagonally
drainage from the structure. This will assist opposite each other, at top and bottom.
the development of a smoother galvanized
coating, reduce the potential for retention of
ash on the surface of the flange and help to
avoid air traps within the structure, which
could lead to uncoated areas.
35
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
Good venting of these sections will aid Every sealed section of a fabrication must Overlapping or contacting surfaces are
access and drainage of molten zinc and be vented for reasons of safety and to allow potentially dangerous as pretreatment
a cleaner coating will be obtained. access and drainage of molten zinc. solutions trapped between surfaces
Holes diagonally opposite each other should are converted to superheated steam
be as close as possible to the sealed end. in the galvanizing bath and can lead to
an explosion.
36
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
If this is not possible, then welding should Internal diaphragms in large box sections External stiffeners for beams or channels Alternative designs for venting sections
be intermittent: in service there may be some should have cropped corners and a should have the corners cropped. fixed to base plates.
weeping of trapped pretreatment solutions ‘manhole’. Internal diaphragms on small
from between the plates leading to brown box sections should have cropped corners.
staining, but this will not be detrimental to Where any hollow section is vented internally,
the protection given by the coating. It will not it is essential for safety reasons, that the
generally be necessary to make any provision galvanizer is able to view such venting.
if the enclosed area is less than about 100
cm2 (e.g.10 cm x 10 cm).
37
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
Examples of how
weldments should
be designed in order
to avoid acid traps
(narrow crevices).
Welded joints should be continuous if they are To minimise the risk of distortion, flat panels Large open top tanks should be stayed to Vents should be diametrically opposite and
not enclosing an otherwise unvented surface. should be braced, e.g. dished or ribbed. minimise distortion. Where angles are used at least 50mm in diameter. Internal baffles
Bolted joints are best made after galvanizing. Openings should be provided in the corners. to rim the tank, appertures must be provided should be cropped top and bottom. Lifting
in the corners. Angles or flats used as stays lugs are required as indicated. It should be
should be as close as possible to the tank possible to view the baffles through either
wall thickness. the vent holes or an inspection hole - the
placement of the inspection hole should be
discussed with the galvanizer.
38
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION EIGHT DESIGNING ARTICLES FOR GALVANIZING
39
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION NINE QUALITY AND INSPECTION
SECTION
NINE
_
TITLE
QUALITY AND INSPECTION
_
COATING FINISH
_
Table 7.
Table 6 summarises variations in finish which Summary of variations in
may be observed. The variations are often galvanized finish (illustrated on pages 41- 43).
caused by surface features of the steel itself,
and the acceptability of a coating should
usually be judged primarily on its long-term
performance and corrosion resistance.
40
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION NINE QUALITY AND INSPECTION
DULL GREY OR Staining and discolouration by rust To avoid rust staining, all parts of a structure General roughness
DARK GREY COATING should receive comparable effective corrosion
_ Sound galvanized steel with many years protection where possible. Nuts and bolts BS EN ISO 1461 demands that a galvanized
of corrosion-free life still remaining, can and other fasteners should also be hot dip coating shall be ‘smooth’, but points out
Silicon is sometimes added to steel as a
sometimes be rust stained or discoloured. galvanized (see Section 10). Welds should be that smoothness is a relative term and that
deoxidant during production and this speeds
This may give an incorrect impression that the continuous wherever possible to minimise the coatings on fabricated articles should not
up the reaction between the steel and the
coating has failed and may occasionally be retention of cleaning residues and should also be judged by the same standards as those
molten zinc. When the galvanized article is
visually unacceptable. It may be the result of be slag-free. Structures should be designed applied to mechanically wiped products,
removed from the bath, but still remains hot,
one or more of the following factors: to avoid run-off water from other metals such as galvanized sheet, tube and wire.
the reaction may continue and convert all or
onto galvanized steel. Where welding after
part of the surface zinc layers to zinc-iron
s¬ $IRECT¬CONTACT¬OF¬GALVANIZED¬ galvanizing is necessary, welded areas should An uneven coating is usually due to excessive
alloys. These are dark grey compared with the
articles with unprotected or be thoroughly cleaned and the zinc coating or uneven growth of the alloy layers, because
light grey of pure zinc, although after a period
inadequately protected steel restored (see page 43). of the composition or surface condition of
of exposure the difference in grey colour
(e.g., galvanized steel sections the steel. An uneven coating is often thicker
becomes less pronounced.
fastened with unprotected, Discolouration and staining from most than a conventional coating and therefore,
electroplated or painted external sources have no effect on the life of has a longer life, but on rare occasions it may
Zinc-iron alloy coatings on reactive steel
steel bolts). the coating. However, affected areas may be be unsatisfactory or it may interfere with the
are thicker and hence longer lasting, than
cleaned to improve the appearance of the intended use of the article.
those on rimmed or aluminium-killed steels.
s¬ $EPOSITS¬OF¬IRON¬AND¬STEEL¬DUST¬AND¬¬ structure. Generally, wire brushing or the use
Corrosion resistance, thickness for thickness,
swarf from other operations or of a scouring powder will remove the stain
is at least as good as unalloyed zinc and may
sources on the galvanized surface. and leave a sound galvanized coating.
be better in acidic industrial atmospheres.
Zinc-iron alloys are more abrasion resistant
s¬ 7ATER¬DRAINING¬FROM¬UNPROTECTED¬
than zinc, but thick coatings have a greater
or poorly protected steelwork,
tendency to flake if handled roughly and
e.g. from damaged areas on
appropriate care must be taken.
painted steelwork.
The dark grey coating surface may develop
s¬ &ROM¬CLEANING¬RESIDUES¬IN¬WELDS¬
staining after a relatively short period of
During cleaning, acid may
exposure, even in mild, damp conditions. This
penetrate into the weld area via pin
is only a surface effect and does not indicate
holes or other gaps in the welding.
serious deterioration of the coating: the
galvanized coating remains and continues to
s¬ 2USTING¬OF¬AREAS¬WELDED¬AFTER¬
protect the steel.
galvanizing and subsequently
left unprotected or
inadequately protected.
s¬ 7ATER¬RUNNING¬OFF¬OTHER¬MATERIALS¬
notably metals such as copper
and certain hardwoods (e.g. oak).
This effect may occur whenever
water can dissolve materials from
one surface and deposit them on
the galvanized steel.
41
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION NINE QUALITY AND INSPECTION
Lumpiness and runs Pimples Wet storage stain Flux and dirt staining
Lumps and runs caused by uneven drainage Pimples are caused by inclusions of dross Wet storage stain is the white corrosion Where flux is used during the dipping
of zinc from an article when it is removed (a pasty zinc/iron alloy residual that forms products and dark stains, which may be seen process, flux residues may adhere to the
from the bath may occur due to shape or in the galvanizing bath) in the coating. on the surfaces of newly galvanized articles surface after immersion and pick up moisture
thinness of the component and are not These may arise from iron salts carried over when they have been closely stacked and to form white corrosion products. Although
harmful to the life of the coating. Sharp points on the work from the cleaning tank and stored, or transported under damp or wet this is a surface effect, flux stains may be
of excess solidified zinc are not acceptable as unable to escape from the surface of the conditions. Where wet storage stain has detrimental to the life of the coating and
they may present a hazard during handling. coating. Contamination may also arise from formed, the coating beneath may be stained should be removed.
Fabrications with areas where spikes have agitation of the dross layer at the bottom of dark grey or black.
been knocked off, exposing bare steel, the bath. Dross has a similar corrosion rate to Dirt may be picked up on the surface of
require remedial repair of the coating, that of zinc and its presence in the coating as To prevent wet storage stain, zinc coated the coating from the site, truck beds or
which is explained overleaf. finely dispersed particles, is not objectionable. articles must be transported and stored under from contact with other articles. These are
But, major dross inclusions tend to embrittle dry and well ventilated conditions. If stored readily washed off to reveal a sound coating
the coating and the galvanizer will avoid this. outdoors, the surfaces should not be in close underneath and are not, therefore, harmful.
contact: free circulation of air is necessary
to prevent condensation and retention of
moisture. Nesting or close packing must be
avoided as capillary action can attract water
into closely contacting surfaces. Articles
should not be stored in direct contact with
the ground.
42
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION NINE QUALITY AND INSPECTION
Bare spots RENOVATING DAMAGED s¬ 4HOROUGHLY¬WIRE¬BRUSH¬THE¬AFFECTED¬AREA Zinc rich paint is much the simplest to apply,
COATINGS and apply sufficient coats of zinc rich especially on site. Thermal zinc spraying
Due to the sacrificial action of zinc, small _ paint (by brush or aerosol spray) to give is usually only economic when applied in
localised flaws up to 5mm maximum width a coating thickness in accordance with the workshop.
Small areas of the coating may be damaged
are usually self-healing and have little effect the supply standard e.g. EN ISO 1461
by operations such as cutting or welding
on the life of coating. Articles with uncoated BS EN ISO 1461 requires that the coating
after galvanizing and although a galvanized
areas due to faulty processing will be s¬ 4HOROUGHLY¬WIRE¬BRUSH¬THE¬AFFECTED¬AREA¬ thickness on renovated areas shall normally
coating has excellent resistance to rough
detected by the galvanizer on inspection and heat it with a blow torch to 300°C and be 30μm more than the local coating
treatment, small areas of damage may
retreated but, occasionally bare spots can apply a special zinc alloy rod or powder thickness requirement for the galvanized
occasionally occur in transport and erection.
also be caused by rolling defects in the steel to obtain required repair coating coating. An exception to this may be
Due to the sacrificial action of zinc, small
such as laps and folds, laminations and thickness. This may, however, be difficult when the coating is to be overcoated and
localised flaws do not reduce protection.
non-metallic impurities rolled into the surface. or too time-consuming to carry out on the renovated area then requires an
Nevertheless, it is often aesthetically
erected steelwork, or on awkward, or equivalent thickness.
desirable to renew the coating even over
inaccessible areas.
such small areas.
Care should be taken in applying heat by Purchasers and applicators of subsequent
a blowtorch as excessive heat may coatings should ensure that the applied
Adequate corrosion resistance will be
damage the surrounding galvanized system is compatible with the method
achieved at any damaged area if a weight
coating, especially on the heavier coatings and materials used for renovation.
of zinc is deposited equivalent to the weight
resulting from reactive steels.
of the undamaged coating. The following
techniques are acceptable according to
s¬ 'RIT¬BLAST¬THE¬AFFECTED¬AREA¬AND¬THERMAL¬
BS EN ISO 1461:
zinc spray. A 100μm thermally sprayed
zinc coating confers corrosion protection
equivalent to an 85μm galvanized coating.
43
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TEN JOINING GALVANIZED STEEL
SECTION
TEN
_
TITLE
JOINING GALVANIZED STEEL
_
THERE IS NO REASON WHY STRUCTURES SHOULD HAVE
THEIR LIFE EXPECTANCIES REDUCED BY THE SERVICE LIFE
OF THE THREADED FASTENERS USED IN ASSEMBLY, SINCE
THEY TOO CAN BE HOT DIP GALVANIZED.
HOT DIP GALVANIZED Surface finish and appearance Specification of hot dip Friction grip connections
THREADED FASTENERS galvanized fasteners
_ Galvanized fasteners usually have a bright Initially, the coefficient of friction with
light grey appearance, but with certain grades Selected zinc-based protective coatings on galvanized contact surfaces is low - an
Sizes
of high yield and high tensile bolts, the threaded fasteners have been listed in average of about 0.19. As slip commences
coating may be matt grey, because the higher Table 8. One difficulty arises because however, friction rapidly builds up and
As a general rule, nuts, bolts and washers
silicon content of the steel makes them more electroplating is often known - misleadingly ‘lock-up’ occurs, due to cold welding
down to 8mm diameter can be galvanized
reactive towards the molten zinc. Fasteners - as electrogalvanizing. It is not, therefore, between the coated surfaces. If a small
and a wide range of threaded components
hot dip galvanized at high temperature, enough merely to specify ‘galvanizing’ if a amount of slip can be tolerated it is therefore
can now be processed using special
(around 550°C) tend to take on a uniform, long life is required. The fastener specification unnecessary to treat the surfaces, but if
equipment. For ISO metric fasteners,
matt grey appearance due to the structure should clearly state ‘that the fastener coating all slip must be avoided, the coefficient of
the galvanizing of one thread either internal
of the coating formed when the component should conform to BS 7371: Part 6: 1998’ friction can be raised by roughening the
or external requires an extra clearance of four
is cooled. and the addition of a clause ‘to be galvanized surface of the galvanized coating.
times the coating thickness. In practice, it is
by a member of the Galvanizers Association’ Wire brushing will raise it to 0.35 and a
normal for standard bolts from stock to be
Storage will ensure the high quality provided by its figure of 0.5 can be achieved by a light grit
fully galvanized, but for nuts to be galvanized
member companies and the technical blasting, or by roughening with a pneumatic
as blanks and then tapped up to 0.4mm
Galvanized fasteners should be stored under back-up service of GA. chisel hammer, or needle gun. In the United
oversize with the threads then lightly oiled.
dry well ventilated conditions to minimise States, galvanizing is one of the few coatings
When assembled, the nut thread is protected
the occurrence of wet storage stain Relative costs permitted on the contact surfaces in the
by contact with the coating on the bolt. Even
(see Section 9). specification for friction grip joints. This
after many years of service, galvanized nuts
The initial cost of hot dip galvanizing threaded is approved by the Research Council for
can readily be unfastened even though the
Table 8. fasteners is generally a little higher than Riveted and Bolted Structural Joints of the
threads have never been galvanized. Further
zinc plating to BS3382: Part 2. However, Engineering Foundation.
details of the dimensions, processing and
type coating thickness in terms of cost per year of rust-free life,
performance of hot dip galvanized nuts and
hot dip galvanizing is by far the most The ‘lock-up’ effect described above can
bolts is given in ‘The Engineers & Architects'
zinc electroplated 5 - 12 μm economical coating. cause galling in the threads of galvanized
Guide to Hot Dip Galvanized Nuts and Bolts’,
(typical) fasteners used in friction grip connections
published by Galvanizers Association.
High strength bolts and lubrication may be required in order that
sherardized class I 30 μm the required clamping force is developed.
Coating uniformity.
General grade high strength bolts (ISO grade Beeswax has been found to be a most
sherardized class II 15 μm ¬TO¬"3¬¬0ART¬¬EQUIVALENT¬TO¬!34-¬ effective lubricant and molybdenum
Whilst there is some tendency for hot dip
A325) can be galvanized without difficulty. disulphide, or tallow, have also been
galvanizing to be thicker in thread roots, a
hot dip galvanized 43 μm (min) ISO Grade 10.9 bolts (BS4395: Part 2 or specified for this purpose.
near uniform coating can be obtained with
BS 7371: !34-¬! ¬ARE¬GALVANIZED¬IN¬THE¬5+¬*APAN¬
modern equipment. Any thickening that does
part 6: 1998 Italy, France and Germany but may require
occur can be accommodated in the normal
blast-cleaning as an alternative treatment
truncation on the thread of the nut.
prior to hot dip galvanizing. Grade 12.9 bolts
and higher strength fasteners should not
be galvanized.
44
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TEN JOINING GALVANIZED STEEL
s¬ 3LIGHTLY¬WIDER¬GAPS¬ARE¬RECOMMENDED¬
in butt joints to give complete penetration.
s¬ !¬SHORT¬ARC¬LENGTH¬GIVES¬BETTER¬CONTROL¬
of the weld pool and helps to prevent
either intermittent excess penetration,
or undercut.
s¬ "OTH¬BASIC¬AND¬RUTILE¬COATED¬ELECTRODES¬
can be used but, simple procedural
tests should be made before undertaking
production welding.
45
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION ELEVEN PAINTING AND POWDER COATING
OF GALVANIZED STEEL
SECTION
ELEVEN
_
TITLE
PAINTING AND POWDER COATING OF GALVANIZED STEEL
_
HOT DIP GALVANIZING BY ITSELF IS A LONG LASTING AND COST EFFECTIVE
MEANS OF CORROSION PROTECTION. WHEN ORGANIC COATINGS SUCH
AS PAINT OR POWDER COATINGS ARE APPLIED OVER GALVANIZED STEEL,
THE RESULTING COMBINATION IS KNOWN AS A DUPLEX COATING.
THESE COATINGS ARE USED TO:
Add colour for aesthetic, The reasons for the need for effective surface GUIDELINES: PRE-TREATMENT T-Wash (or its proprietary equivalent)
camouflage, or safety purposes preparation in most cases are quite straight FOR PAINTING
forward. When the steel is withdrawn from the _ Despite the fact that this preparation process
Increase the economic life of a structure galvanizing bath it has a clean, bright, shiny has been available for some considerable
Guidelines for the pre-treatment of galvanized
surface. With time this changes to a dull time, T-Wash is still generally considered to
surfaces have been drawn up as a result
Provide additional protection in grey patina as the surface zinc reacts with be the best pre-treatment method for painting
of (i) a study carried out by an independent
aggressive environments oxygen, water and carbon dioxide in the galvanized steel. T-Wash is a modified zinc
research centre and a leading UK paint
atmosphere to form a complex, but tough, phosphate solution, which contains a small
manufacturer into the performance of
Paint coatings may be applied soon after stable, protective layer, which is tightly amount of copper salts. When applied, a
commercially available pre-treatment and
galvanizing, or later in the lifetime of the adherent to the zinc. The patina takes time to dark grey or black discolouration of the
paint systems and the parameters affecting
structure when the galvanized coating develop and the exact time depends upon the zinc surface will result. T-Wash must not be
their performance on hot dip galvanized
has weathered, or later still when further climate around the galvanizing. Typically, the allowed to pool on horizontal surfaces, or this
coatings, and (ii) many years experience
protection is essential to maintain protection. time can vary from six months to two years will prevent maximum paint adhesion.
with duplex coatings.
or more. During this transition of the zinc Any excess should be removed by water.
When paint is to be used to further extend outer layer into its final state, simple oxides T-wash is most suitable for application to
Although pre-treatment of galvanized
the life of a galvanized structure, it is often and carbonates form, which do not adhere new galvanizing and should not be used
components is best carried out immediately
most economic to defer painting until a long strongly to the surface. As most duplex on weathered galvanizing
after galvanizing, before the surface has
maintenance-free life has been achieved from coatings are applied whilst the galvanizing is (see etch primers below)
become contaminated in any way, this is
the galvanized coating. in this condition, the surface layer must be
not always practical. Pre-treatment can be
modified by chemical or mechanical means. The constituents of T-Wash are phosphoric
carried out later, but it is vital that the surface
PREPARATION OF Coatings may be applied directly to the acid (9.0%), ethyl cellusolve (16.5%),
is adequately cleaned to remove all traces of
initial pure zinc surface, or to the weathered methylated spirit (16.5%), water (57.0%) and
GALVANIZED STEEL contaminants such as oil, grease and dirt.
_ surface, but the results are not always
The cleaning operation must leave no
copper carbonate (1.0%). Variations to this
consistent and “taking a chance” composition may exist and so it is wise to
As with all protective treatments of steelwork, residues on the cleaned surface and any wet
is not recommended. consult the supplier if a successful result is
it is of great importance that preparation of storage staining should be removed using a
to be achieved.
the galvanized surface is carried out in a stiff brush. Washing down the coating with
Where the aesthetic requirements for a
thorough and considered manner. water will help to remove soluble salts.
duplex system are particularly high, a degree Sufficient time must be allowed for the
In particular, failure to degrease the of surface finishing or fettling may be required T-Wash to react and dry thoroughly before
galvanized steel surface properly is a There are four recognised methods of surface
on galvanized coatings, as small surface the first coat of paint is applied.
common source of failure of duplex coatings. pre-treatment that produce a sound substrate
projections may become more obvious after (Suppliers’ information will give recommended
for paint coating:
the application of an organic coating. time intervals). While research has shown
As with many other substrates, organic This is particularly the case for powder that T-Washed surfaces can be left for up
coatings can not usually be applied directly coating systems. Care must be taken when to 30 days before painting and good paint
onto galvanized steel. However, simple smoothing a galvanized coating, because the adhesion can still result, it is advisable to
direct application paint systems, designed zinc coating may be damaged by heavy or minimise the time between pretreatment
specifically to adhere to non-ferrous metals excessive grinding. and paint application. Any white salt formed
such as zinc, are becoming more popular and by the exposure of the T-Washed surface
are available in a full range of colours. to moisture must be removed before painting
using a stiff brush. If the T-Washed surface
has become contaminated, it must be
cleaned in accordance with the
suppliers’ recommendations.
46
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION ELEVEN PAINTING AND POWDER COATING
OF GALVANIZED STEEL
Etch primers Weathering Two-pack polyurethane and acrylic urethanes However, the pre-treatment of the galvanized
are commonly used as top coats and surface will depend upon which of the
Etch primers have also been used This process only becomes fully effective offer good durability and colour retention. many powder types such as polyester,
successfully. Their major disadvantage is after a galvanized surface has been exposed Alternatives include acrylic epoxies and epoxy, or hybrid is being used. This usually
the absence of any visible colour change to the atmosphere for a period of at least six polysiloxanes, the latter offering increased includes a form of chemical pretreatment
in contrast to T-Wash. Therefore, there months. The surface is prepared using either abrasion resistance along with good gloss such as chromating or phosphating, gentle
can never be complete confidence that all abrasive pads, or a stiff brush, to remove all and colour retention. heat treatment, followed by application of
surfaces have reacted with the primer. loose adherent materials and making sure the powder. The successful application of
Etch primers are most suited to application that the bright zinc surface is not restored. At present, high-build epoxies are widely used a powder coating to any metallic surface
on older, weathered galvanizing although water-based products, including requires the multistep instructions provided
This is followed by a hot detergent wash and polyurethanes, are now being specified. by the powder manufacturer to be respected
Sweep blasting rinsing with fresh clean water. The surface They are less tolerant of poor pre-treatment, in every detail. For this reason an experienced
must be fully dry before any paint is applied. but their use could to grow as the Solvent or approved applicator should be asked to
A mechanical method of pretreatment is Weathering should not be used as a method Emissions Directive becomes more stringent. do the work. As with wet painting, a full range
sweep blasting using fine copper slag, J blast of surface preparation in marine environments of colours is available. Powder coating of
or carborundum powder with a blast pressure with high chloride levels. GUIDELINES: galvanized steel for architectural applications
of no greater than 40psi (2.7 bar). This will POWDER COATING is covered at present by BS EN 13438.
ensure that only the minimum amount of GUIDELINES: PAINTING _
oxide is removed and the zinc surface is left _ It is important that the galvanizer is advised
Powder Coating is a fast growing method of
in a slightly roughened condition. Care should All paint systems should be specifically that work is to be subsequently powder
adding colour to metal surfaces.
be taken when carrying out sweep blasting formulated for use on galvanized steel coated and post-galvanizing treatments
Like galvanizing it is carried out under
on very thick galvanized coatings to avoid and applied in accordance with the paint agreed with the powder coater.
carefully controlled conditions in a factory.
damage to the coating. The optimum nozzle- manufacturer’s recommendations. For this reason the maximum size of the
to-work piece distance and angle of blasting A limited number of direct application
steel fabrication to be powder coated will be
needs to be identified for all surfaces on the The choice of paint system will depend upon products are now available for use on
limited, but powder coatings can be applied
galvanized steel work, if optimum results both the application and service environment. galvanized steel work. Given adequate
successfully to hot dip galvanized surfaces.
are to be achieved. Angular iron blasting grit With the decline in the use of chlorinated preparation work, the use of a direct
must not be used under any circumstances. rubber and alkyd paints, high- build epoxy application paint negates the need for
The thermal characteristics of galvanized
Sweep blasting is often used in addition to products and vinyl/vinyl co-polymer systems any chemical or mechanical pre-treatment
steel are almost identical to those of
the chemical preparation stage. are increasingly utilised with glass reinforced to be conducted. These products are
un-galvanized steel for powder coating
epoxy being an option for more severe known to have been used in a variety
purposes and there are many examples
environments. In multi-coat systems the use of applications.
of steel which has been galvanized and
OF¬A¬MICACEOUS¬IRON¬OXIDE¬-)/ ¬PRIMER¬HAS¬ then powder coated.
been shown to give improved adhesion.
47
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TWELVE RELEVANT STANDARDS
SECTION
TWELVE
_
TITLE
RELEVANT STANDARDS
_
BRITISH AND EUROPEAN Other zinc coating standards Other useful British Standards BS EN 23270: 1991
STANDARDS Specification for temperature and
_ BS EN 12329: 2000 BS 7361: Part 1: 1991 humidities for conditioning and
Corrosion protection of metals. Cathodic protection. testing paints, varnishes and their
BS EN ISO 1461: 1999
Electrodeposited coating of zinc with raw materials.
Hot dip galvanized coatings on fabricated
iron and steel articles – specifications supplementary treatment on iron or steel. BS EN 13636: 2004
Cathodic properties of buried metallic tanks BS 4395: Parts 1 & 2: 1969
and test methods.
BS EN ISO 2063: 2005 and related piping. High strength friction grip bolts.
BS EN ISO 14713: 1999 Sprayed aluminium and zinc coatings.
BS 7773: 1995 BS EN 14399: Parts 1-6: 2005
Protection against corrosion of iron
BS 3382: Part 2: 1961 Cleaning and preparation of metal surfaces. High strength structural bolting
and steel in structures – Zinc and aluminium
Electroplated zinc on threaded components. assemblies for preloading.
coatings – Guidelines.
PD 6484: 1979
BS 4921: 1988 Corrosion at bimetallic contacts. BS EN ISO 1460: 1995
BS 7371: Part 6: 1998
Sheradized coatings on iron Determination of hot dip galvanizing
Coatings on metal fasteners – specification
and steel articles. BS 7079: 1994 coating mass: gravimetric method.
for hot dip galvanized coatings.
Surface preparation of steel substrates
before application of coatings. BS EN ISO 1463: 2004
BS EN 10244: Part 2: 2001
-EASUREMENT¬OF¬COATING¬THICKNESS¬
Steel Wire & Wire Products – Non ferrous
BS EN ISO 2178: 1995 microscopic method.
metallic coatings on steel wire.
-EASUREMENT¬OF¬COATING¬THICKNESS¬
magnetic method. BS EN ISO 2064: 2000
BS EN 10326/10327: 2004
Definition and convention concerning
Hot dip zinc coatings on steel sheet.
BS EN ISO 9001: 2000 coating thickness measurement.
BS 3083: 1988 Quality management systems.
BS EN ISO 12944: 1998
Hot dip coated corrugated sheet
BS EN ISO 11124: Parts 3 & 4 Paints and varnises - corrosion
for general purpose.
Chilled iron shot and grit for grit blasting. protection of steel structures by
protective paint systems.
BS EN 971-1: 1996
Paints and varnishes terms and definitions
for coating materials. General terms.
48
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION TWELVE RELEVANT STANDARDS
A780 – 01
Repair of damaged hot dip galvanizing.
49
THE ENGINEERS & ARCHITECTS' GUIDE HOT DIP GALVANIZING SECTION THIRTEEN ADVISORY SERVICES
SECTION
THIRTEEN
_
TITLE
ADVISORY SERVICE
_
UNITED KINGDOM AND REPUBLIC OF IRELAND
GALVANIZERS ASSOCIATION
_
så !PPLICATIONSå
så /RGANICåCOATINGSå
on galvanizing
så &ASTENERS
så $ESIGNåIMPLICATIONSå
for galvanizing
så 7ELDING
så 0ERFORMANCEåINFORMATION
så 3USTAINABILITY
så #ASEåHISTORIES
50
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PLEASE NOTE ACKNOWLEDGEMENTS
WITH THANKS TO
_ _
Care has been taken to ensure that the Page 6 Eden Project
contents of this publication are accurate, Nicholas Grimshaw & Partners
but Galvanizers Association does not accept Paul Armiger
responsibility for errors or for information which
is found to be misleading. Suggestions for, Page 7 Eden Project
or the end use or application of, galvanized Nicholas Grimshaw & Partners
products are for information only and Peter Cook / View
Galvanizers Association accepts no liability in
respect thereof. Before having products hot Page 9 The Pump House
dip galvanized, the customer should satisfy Jaqueline Demaus,
themselves of their suitability. Tenbury Wells
printed 10/07
Telephone: +44 (0)121 355 8838
Fax: +44 (0)121 355 8727
e-mail: ga@hdg.org.uk
www.galvanizing.org.uk