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Material Safety Data Sheet Acetone Version 2.1 Effective Date: 28.05.2012 1. IDENTIFICATION OF THE SUBSTANCE/

Material Safety Data Sheet

Acetone

Version 2.1

Effective Date: 28.05.2012

1. IDENTIFICATION OF THE SUBSTANCE/ PREPARATION AND COMPANY/ UNDERTAKING

Material Name

: Acetone

Uses

: Industrial solvent.

Product Code

: S1212, U8903, S1260

Supplier

: Chemisol Inc. 3/F Johnson Bldg. #5 D. Muñoz St. Tandang Sora, Quezon City Philippines

Telephone

: (632) 9385388

Fax

: (632) 9383818

Emergency

: (632) 9385388

Number

2. HAZARDS IDENTIFICATION

GHS Classification

GHS Label Elements Symbol(s)

Signal Words GHS Hazards Statements

GHS Precautionary statements Prevention

: Flammable Liquids: Category no. 2 Serious Eye Damage/Eye Irritation: Category 2A Specific Target Organ Toxicity (single exposure): Category no. 3 Narcotic effects. Aspiration Hazard: Category no. 2

:

no. 3 Narcotic effects. Aspiration Hazard: Category no. 2 : : Warning : PHYSICAL HAZARDS: H225:

: Warning : PHYSICAL HAZARDS:

H225: Highly flammable liquid and vapor. HEALTH HAZARDS:

H320: Causes eye irritation. H336: May cause drowsiness or dizziness. H305: May be harmful if swallowed and enters airways. ENVIRONMENTAL HAZARDS:

Not classified as an environmental hazard under GHS criteria.

: P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P242: Use only non-sparking tools.

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Response

P243: Take precautionary measures against static discharge. P261: Avoid breathing dust/fume/gas/mist/vapors/spray. P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection. P235: Keep cool. : P301+P310: IF SWALLOWED: Immediately call a POISON

Storage

CENTER or doctor/physician. P331: Do NOT induce vomiting. P303+P361+P353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P370+P378: In case of fire: Use for extinction. P370+P379: In case of fire: Use foam, water spray or fog for extinction. P312: Call a POISON CENTER or doctor/physician if you feel unwell. : P403+P233: Store in a well-ventilated place. Keep container tightly closed. P235: Keep cool. P405: Store locked up.

Disposal

: P501: Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations.

Other Hazards which do not result in classification

: Exposure may enhance the toxicity of other materials. Repeated exposure may cause skin dryness or cracking. Slightly irritating to respiratory system.

Aggravated Medical Condition

: Pre-existing medical conditions of the following organ(s) or organ system(s) may be aggravated by exposure to this material : Eyes. Respiratory. Skin.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Material Formal Name Synonyms CAS No. INDEX No. EINECS No.

: Propan-2-one : Dimethyl Ketone : 67-64-1 : 606-001-00-8 : 200-662-2

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Classification of Components according to GHS

Chemical Name

Synonyms

CAS No.

Hazard Class Category

Hazard Statements

Conc.

Acetone

 

67-64-1

Flam. Liq., 2; Eye Irrit., 2; STOT SE, 3;

H225;H319;

100.00%

H336;

Additional Information

: Refer to Chapter 16 for full text of EC R-phrases.

4. FIRST AID MEASURES

Inhalation

: Remove to fresh air. If rapid recovery does not occur, transport to the nearest

Skin Contact

medical facility for additional treatment. : Remove contaminated clothing. Flush exposed area with water and follow by

Eye Contact

washing with soap if available. : Immediately flush eyes with large amounts of water for 15 minutes while

Ingestion

holding the eyelids open. Transport to the nearest medical facility for additional treatment. : If swallowed, do not induce vomiting: transport to the nearest medical facility

Advice to Physician

for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. : Potential for chemical pneumonitis. Consider: gastric lavage with protected airway, administration of activated charcoal.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards

Extinguishing Media

Protective Equipment for Firefighters

Additional Advice

: Containers exposed to intense heat from fires should be cooled with large quantity of water. The vapour is heavier than air, spreads along the ground and distant ignition is possible. : Alcohol- resistant foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. : Wear full protective clothing and self contained breathing apparatus. Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. : All storage areas should be provided with adequate fire fighting facilities. Keep adjacent containers cool by spraying with water.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. Immediately remove all contaminated clothing. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. For guidance on disposal of spilled material see Chapter 13of this Material Safety Data Sheet. Observe all relevant local and international regulations.

Protective Measures

: Avoid contact with spilled or released material. Immediately remove all contaminated clothing. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this Material Safety Data Sheet. Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area, use appropriate containment (of product and

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Clean Up Methods

fire fighting water) to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Attempt to disperse the vapour or to direct its flow to a safe location for example by using fog spray. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Monitor area with combustible gas indicator. : For large liquid spills (> 1 drum), transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. For small liquid spills (<1 drum), transfer by mechanical means to a labeled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

Additional Advice

: See Chapter 13 for information on disposal. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur

7. HANDLING STORAGE

General Precautions

: Avoid breathing of or contact with material. Only use in well ventilated areas.

Handling

Wash thoroughly after handling. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. : Avoid inhaling vapour and/or mists. Avoid contact with skin, eyes and

Storage

clothing. Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<= 10 m/sec). Avoid splash filling. Do NOT use compressed air for filling, discharge, or handling operations. Handling Temperature: Ambient. : Keep container tightly closed. Must be stored in a diked (bunded) well-

Product Transfer

ventilated area, away from sunlight, ignition sources and other sources of heat. Must be kept inhibited during storage and shipment as material can polymerise. Vapours from tanks should not be released to atmosphere. Breathing losses during storage should be controlled by a suitable vapour treatment system, storage Temperature: Ambient. : Keep containers closed when not in use. Do not use compressed air for filling,

Recommended Materials Unsuitable Materials Container Advice

discharging or handling. : For containers, or container linings use mild steel, stainless steel. : Aluminum. Most plastics. Natural, butyl, neoprene or nitrile rubbers. : Containers, even those that have been emptied, can contain explosive vapours.

Additional Information

Do not cut, drill, grind, weld or perform similar operations on or near containers. : Use the information in this data sheet as input to risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Ensure that all local regulations regarding handling and storage facilities are followed.

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Material

Source

Type

Ppm

mg/m3

Notation

 

Acetone

ACGIH

TWA

500

ppm

   
 

ACGIH

STEL

750

ppm

   

Material

Sources

Hazard Designation

Acetone

ACGIH

Not classified as a human carcinogen.

Exposure Controls

: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Provide adequate ventilation in storage areas. Use sealed systems as far as possible. Adequate explosion-proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Eye washes and showers for emergency use. : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. : If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with the respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for organic gases and vapours [boiling point <65 ºC (149 ºF)] meeting EN371. Where air-filtering respirators are unsuitable (e.g., airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g Europe: EN374, may provide suitable chemical protection: Longer term protection: Nitrile rubber gloves Incidental contact/Splash protection: PVC or neoprene rubber gloves. Personal hygiene is a key element of effective hand care. Gloves must be only worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. : Monogoggles(EN166) : Chemical resistant gloves/gauntlets, boots, and apron. Skin protection not ordinarily required beyond standard issue work clothes. : Monitoring of the concentration of the substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure control. For some substances biological monitoring may also be appropriate. Examples of sources of recommended air monitoring methods are given below or contact supplier. Further National methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods, http://www.cdc.gov/ niosh/nmam/nmammenu.html.

Personal Protective Equipment

Respiratory Protection

Hand Protection

Eye Protection Protective Clothing

Monitoring Methods

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Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods, http://www.osha-slc.gov/dts/sltc/methods/toc.html. health and Safety Executive (HSE), UK: Methods for the determination of hazardous Substances, http://www.hsl.gov.uk/search.htm. Berufsgenossenschaftliches Institut fűr Arbeitssicherheit (BIA), Germany http:/www.hvbg.de/d/bia/index.html. L’Institut National de Recherche et de Securité, (INRS), Francehttp://www.inrs.fr/securite/hygiene_securite_travail. html.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Odour pH Boiling point Flash point Explosion/ Flammability

Surface tension

: Clear Liquid : Characteristic : Not applicable : 56 ºC / 133 ºF : -18 ºC/ 0 ºF (IP 170) : ca. 2.1- 13 % (V)

Limits in air Auto-ignition temperature Vapour pressure Density Water solubility n-octanol/water partition

: 540 ºC/1,004 ºF (ASTM D-2155) : 24.7 kPa at 20 ºC/ 68ºF : 790-792 kg/m3 at 20 ºC/ 68 ºF (ASTM D-4052) : at 20ºC/ 68ºF completely miscible. : 0.2

coefficient (log Pow) Dynamic viscosity Vapour density (air=1) Coefficient of expansion Dielectric constant Heat of vapourisation Refractive index Specific heat Saturated vapour

: 0.33 mPa.s at 20 ºC/ 68 ºF : 2 at 20 ºC/ 68 ºF : 0.0014 ºC : 21.4 at 20 ºC/ 68 ºF : 525 kJ/kg ºC : 1.359 at ºC/ 68 ºF (ASTM D-1218) : 2.14 kJ/kg ºC at 20 ºC/ 68 ºF : 590 g/m3 at 20 ºC/ 68 ºF [estimated value(s)]

Concentration (in air) Thermal conductivity Evaporation rate (nBuAc=1)

: 0.16 W/m ºC at 20 ºC/ 68 ºF : 5.6 (ASTM D 3539, nBuAc=1) 2 (DIN 53170, di-ethyl ether=1) : 22.8 mN/m at 20 ºC/ 68 ºF

Molecular weight

: 58.08 g/mol

10. STABILITY AND REACTIVITY

Stability Conditions to Avoid Materials to Avoid Hazardous Decomposition Products

: Stable under normal conditions of use. : Avoid heat, sparks, open flames and other ignition sources. : Strong oxidizing agents. : None expected under normal use conditions.

11. TOXICOLOGICAL INFORMATION

Basis for Assessment Acute Oral Toxicity

: Information given is based on product testing. : Low toxicity: LD50 >2000 mg/kg, Rat

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Acute Dermal Toxicity Acute Inhalation Toxicity

Skin Irritation

Eye Irritation Respiratory Irritation Sensitization Repeated Dose Toxicity Mutagenicity Carcinogenicity Reproductive and Developmental Toxicity Additional Information

Acetone

Version 2.1

Effective Date: 28.05.2012

Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which can be fatal. : Low toxicity: LD50 >2000 mg/kg, Rabbit : Low toxicity: LC50 >2-20mg/l/ 4 hours, Rat High concentrations may cause central nervous system depression resulting in headache, dizziness and nausea; continued inhalation may result in unconsciousness and/or death. : Not irritating to skin. Prolonged/ repeated contact may cause defatting of the skin which can lead to dermatitis. : Irritating to eyes. : Inhalation of vapours or mists may cause irritation to the respiratory system. : Not a skin sensitizer. : Low systemic toxicity on repeated exposure. : Not mutagenic. : Not expected to be carcinogenic. : Not expected to impair fertility. : Causes slight foetotoxicity. Effects where seen at high doses only. : Exposure may enhance the toxicity of other materials. May potentiate the peripheral neurotoxicity of n-hexane, and the liver and kidney toxicity of some chlorinated hydrocarbons such as carbon tetrachloride.

12. ECOLOGICAL INFORMATION

Acute Toxicity Fish Aquatic Invertebrates Algae Microorganisms Mobility

Persistence/degradability

Bioaccumulation

: Low toxicity: LC/EC/IC50 > 1000 mg/l : Low toxicity: LC/EC/IC50 > 1000 mg/l : Low toxicity: LC/EC/IC50 > 1000 mg/l : Low toxicity: LC/EC/IC50 > 1000 mg/l : If product enters soil, it will be mobile and may contaminate groundwater. Dissolves in water. : Readily biodegradable. : Not expected to bioaccumulate significantly.

13. DISPOSAL CONSIDERATIONS

Material Disposal

Container Disposal

Local Legislation

: Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. : Drain container thoroughly. After draining, vent in a safe place away from sparks and fire. Residues may cause an explosion hazard. Do not puncture, cut or weld uncleaned drums. Send to drum recoverer or metal reclaimer. : Local regulations may be more stringent than regional or national requirements and must be complied with.

14. TRANSPORT INFORMATION

Land transport ADR/RID Class

3

Classification code

F1

Packaging group

ll

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Hazard id no.

339

Label

3

UN number

1301

Technical name

Vinyl acetate, stabilized

Marine transport IMDG Class

3

Packaging group

ll

UN number

1301

Proper shipping name EmS MARPOL

Vinyl acetate, stabilized F-E, S-D -

Label

3

Air transport ICAO/IATA Class

3

Packaging group

ll

UN number

1301

Proper shipping name

Vinyl acetate, stabilized

Label

3

Acetone

Version 2.1

Effective Date: 28.05.2012

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.

EC Label Name EC Label/ EC Number EC Classification EC Annex I Number EC Symbols

: ACETONE : 200-662-2 : Highly flammable. Irritant. : 606-001-00-8 : F Highly flammable

EC Risk Phrases

Xi Irritant : R11 Highly flammable.

EC Safety Phrase

R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. : S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition- No smoking. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

AICS

: Listed.

DSL

: Listed.

INV (CN)

: Listed.

ENCS (JP)

: Listed.

(2)-542

TSCA

: Listed.

EINECS

: Listed.

200-662-2

KECI (KR)

: Listed.

KE-29367

PICCS (PH)

: Listed.

Hazardous Substance Act. BE2535

16. OTHER INFORMATION

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R-phrase(s)

R11

Highly flammable.

R36

Irritating to eyes.

R66

Repeated exposure may cause skin dryness or cracking.

R67

Vapours may cause drowsiness and dizziness.

Acetone

Version 2.1

Effective Date: 28.05.2012

MSDS Version Number

: 2.1

MSDS Effective Date

: 28.05.2012

MSDS Revisions

: A vertical bar (׀) in the left margin indicates an amendment from the previous version.

MSDS Regulation

: The content and format of this safety data sheet is in accordance with Commission Directive 2001/58/EC of 27 July 2001, amending for the second time Commission Directive 91/155/EEC.

Uses and Restrictions

: Industrial Solvent. Restricted to professional users.

MSDS Distribution

: The information in this document should be made available to all who may handle the product.

Disclaimer

: This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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