DELTA JUNIOR COLLEGE

2nd YEAR IIT-JEE ADVANCED CHEMISTRY PAPER-II

(Topic: Named Reactions and Identification of
Functional Groups)
Date: 21 /08/2019 Max. Marks: 80

Section –I

Single Correct Choice Type

I. This section contains 8 multiple choice questions. Each question has 4
choices (1), (2), (3) and (4), out of which ONLY ONE is correct.
(3, -1) 8 × 3= 24

1. Which of the test can be used to distinguish p-chloro aniline

and anilinium chloride
(A)LUCAS reagent (B) Carbylamine test
(C) Iodoform Test (D) None of these
2. If CH3 – Br can react with nucleophile to give nucleophilic
substitution product, then the correct order of reactivity of
nucelophiles is

(A)

(B)

(C)

(D)
3. Which can not be the possible product of the given reaction:

(A)CH3 – CH2 - Br (B)

(C) CH3 – CH2 – CH2 – CH3 (D) CH3 – CH2 – CH3
4.
 If p and q are the major products, then

(A) (B)

(C) (D)

5. An aromatic compound A (C8H10O) gives following tests with

the given reagents.

6.

In this reaction, the end product C is :

(A) salicyfaldehyde (B) salicyclic acid
(C) phenyl acetate (D) aspirin
Conc . H 2SO 4
7. Phenol + Phthalic anhydride 
fusion
→B
B gives which of the following colour in alkaline medium?
(A) Yellow (B) Colourless (C) Pink (D) Violet
8. Nitrobenzene on heating with a mixture of conc. HNO3 and
conc. H2SO4 at 1000C produces.
(A) p-dinitrobenzene (B) m-dinitrobenzene
(C) o-diritrobenzene (D) benzene suphonic acid

Section –II
Multiple Correct Answers Type
This section contains 4 multiple choice questions. Each question has 4 choices (1),
(2), (3) and (4) for its answer, out of which ONE OR MORE is/are correct.
(4, 0) 4 ×4 = 16
9.

The possible products of the above reaction are as follows :

(A) (B) (C) (D)

10.

The products formed from the above reaction are

(A) (B) (C) (D)

11.

12. Periodic oxidation of anthracene gives

 Section –III
Integer Answer Type
This section contains 6 questions. The answer to each of the questions is a single digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the following:
X Y Z W

0 0 0 0

1 1 1 1

2 2 2 2

3 3 3 3

4 4 4 4

5 5 5 5

6 6 6 6

7 7 7 7

8 8 8 8

9 9 9 9
(4, 0) 6 ×4= 24

13. How many groups are o, p directing but deactivating.

14. How many of the following compounds are more reactive than
chlorobenzene towards nitration?
15. The number of reagents among the following which can be
used to correct benzene to iodobenzene is
(a) I2/Fe (b) I2/HIO3 (c) ICl/ZnCl2 (d) I2/HNO3
16. Examine the structural formulas shown below and find out
how many compounds can not give Friedel Crafts reaction.

17. Total number of isomers formed in the following allylic

bromination reaction with NBS are (X+4), ‘X” can be

18.

How many monocholro derivatives will be obtained in this

reaction? (including stereo isomer)

Section –IV
Matrix Match Type

This section contrains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column I are labeled P, Q,
R and S, while the statements in Column II are labeled 1, 2, 3, 4. Any given
statement in Column I can have correct matching with ONE OR MORE statement(s)
in Column II. The appropriate bubbles corresponding to the answers to these
questions have to be darkened as illustrated in the following example:

If the correct matches are P-1,3 and 4; Q -2, and 3 and R-1 and 2; and S-2 and 4;
then the correct darkening of bubbles will look like the following.
You will be awarded 2 marks for each row in which you have to darken All the
bobbles corresponding to the correct answer only and zero marks otherwise.
 1 2 3 4
P 1 2 3 4
Q 1 2 3 4
R 1 2 3 4
S 1 2 3 4

(2, 0) 2 × 8 = 16

19.

20. Match the following :

Column – I Column – II
A NaNO2 + 2HCl
β − Naphthol  → p Yellow colour
B NaNO2 + 2 HCl
20 A min e  → q Red colour
C NaNO2 + 2 HCl
Phenol  → r Green colour
D 0 NaNO2 + 2HCl
1 A min e 
→ s Colourless