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1. 352 mL of chlorine under a pressure of 680.

mm Hg are placed in a container


under a pressure of 1210 mm Hg. The temperature remains constant at 296 K.
What is the volume of the container in liters?
P1 = 680. mm P2 = 1210 mm
V1 = 352 mL V2 = ?
P1V1 = P2V2
V2 = P1V1/P2
V2 = 198 mL Cl2
2. A sample of neon occupies a volume of 461 mL at STP. What will be the
volume of the neon when the pressure is reduced to 93.3 kPa?
P1 = 101.3 kPa P2 = 93.3 kPa
V1 = 461 mL V2 = ?
P1V1 = P2V2
V2 = P1V1/P2
V2 = 501 mL Ne
3. A balloon contains 7.2 L of He. The pressure is reduced to 2.00 atm and the
balloon expands to occupy a volume of 25.1 L. What was the initial pressure
exerted on the balloon?
P1 = ? P2 = 2.00 atm
V1 = 7.2 L V2 = 25.1 L
P1V1 = P2V2
P1 = P2V2/V1
P1 = 7.0 atm
4. A gas tank holds 2785 L of propane, C3H8, at 830. mm Hg. What is the
volume of the propane at standard pressure?
P1 = 830. mm Hg P2 = 760 mm Hg
V1 = 2785 L V2 = ?
P1V1 = P2V2
V2 = P1V1/P2
V2 = 3040 L C3H8
5. A container holds 500. mL of CO2 at 20.° C and 742 torr. What will be the
volume of the CO2 if the pressure is increased to 795 torr?
P1 = 742 torr P2 = 795 torr
V1 = 500. mL V2 = ?
T1 = 20.° C + 273 = 293 K T2 = 20.° C + 273 = 293 K
V2 = 467 mL CO2
6. 2.00 L of a gas is at 740.0 mmHg pressure. What is its volume at standard
pressure?
Use this equation:
P1V1 = P2V2
(740.0 mmHg) (2.00 L) = (760.0 mmHg) (x)
x = 1.95 L
7. 5.00 L of a gas is at 1.08 atm. What pressure is obtained when the
volume is 10.0 L?
(1.08 atm) (5.00 L) = (x) (10.0 L)
x = 0.540 L
8. 9.48 L of a gas was at an unknown pressure. However, at standard pressure,
its volume was measured to be 8.00 L. What was the unknown pressure?
(x) (9.48 L) = (101.325 kPa) (8.00 L)
x = 85.5 kPa
9. If we have 6.00 cm3 of gas at a pressure of 10.0 N/cm2 and we increase the
pressure to 20.0 N/cm2, what volume will the gas occupy?
(10.0) (6.00) = (20.0) (x)
x = 3.00 cm3
10. What pressure is required to compress 196.0 liters of air at 1.00 atmosphere
into a cylinder whose volume is 26.0 liters?
(1.00 atm) (196.0 L) = (x) (26.0 L)
x = 7.54 atm
11. An evacuated flask A, which has a volume of 30 mL, is attached to a second
flask B containing an ideal gas at a pressure of 5 atm. When the two flasks
are connected the pressure in the system drops to 2 atm. Calculate the
volume of flask B.
5x = 2x + 60
3x = 60
x = 20 mL
12. Three bulbs are connected by tubing, and the tubing is evacuated. The
volume of the tubing is 39.0 mL. The first bulb has a volume of 56.0 mL and
contains 5.92 atm of argon, the second bulb has a volume of 250.0 mL and
contains 1.28 atm of neon, and the third bulb has a volume of 37.0 mL and
contains 8.50 atm of hydrogen. If the stopcocks (valves) that isolate all three
bulbs are opened, what is the final pressure of the whole system in atm?
39.0 + 56.0 + 250.0 + 37.0 = 382 mL
argon ---> (5.92 atm) (56.0 mL) = (x) (382.0 mL) ---> x = 0.8678534 atm
neon ---> (1.28 atm) (250.0 mL) = (y) (382.0 mL) ---> y = 0.8376963 atm
hydrogen ---> (8.50 atm) (37.0 mL) = (z) (382.0 mL) ---> z = 0.8232984 atm
=2.53 atm
13. In order to measure the volume of a piece of apparatus, a chemist filled a
750. mL flask with 46.65 kPa pressure of gas, then expanded it into the
apparatus. The final pressure was 14.95 kPa. Calculate the total volume
occupied by the gas.
P1 = 46.65 kPa
V1 = 750. mL
P2 = 14.95 kPa
V2 = x + 750. mL
(46.65 kPa) (750. mL) = (14.95 kPa) (x + 750. mL)
34987.5 = 14.95x + 11212.5
14.95x = 23775
x = 1590 mL

14. A gas occupies 12.3 liters at a pressure of 40.0 mmHg. What is the volume
when the pressure is increased to 60.0 mmHg?
(40.0 mmHg) (12.3 liters) = (60.0 mmHg) (x)
x = 8.20 L
15. If a gas at 25.0 °C occupies 3.60 liters at a pressure of 1.00 atm, what will be
its volume at a pressure of 2.50 atm?
(1.00 atm) ( 3.60 liters) = (2.50 atm) (x)
x = 1.44 L
16. To what pressure must a gas be compressed in order to get into a 3.00 cubic
foot tank the entire weight of a gas that occupies 400.0 cu. ft. at standard
pressure?
(400.0 cu. ft) (1.00 atm) = (x) (3.00 cubic foot)
x = 133 atm
17. A gas occupies 1.56 L at 1.00 atm. What will be the volume of this gas if the
pressure becomes 3.00 atm?
(1.56 L) (1.00 atm) = (3.00 atm) (x)
0.520 L
18. A gas occupies 11.2 liters at 0.860 atm. What is the pressure if the volume
becomes 15.0 L?
(11.2 liters) (0.860 atm) = (x) (15.0 L)
x = 0.642 atm
19. 500.0 mL of a gas is collected at 745.0 mmHg. What will the volume be at
standard pressure?
(745.0 mmHg) (500.0 mL) = (760.0 mmHg) (x)
x = 490.1 mL
20. A gas occupies 4.31 liters at a pressure of 0.755 atm. Determine the volume if
the pressure is increased to 1.25 atm.
(0.755 atm) (4.31 liters) = (1.25 atm) (x)
21. 600.0 mL of a gas is at a pressure of 8.00 atm. What is the volume of the gas
at 2.00 atm?
(8.00 atm) (600.0 mL) = (2.00 atm) (x)
22. 00.0 mL of a gas are under a pressure of 800.0 torr. What would the volume of
the gas be at a pressure of 1000.0 torr?
(800.0 torr) (400.0 mL) = (1000.0 torr) (x)
23. A particular balloon is designed by its manufacturer to be inflated to a
volume of no more than 2.5 liters. If the balloon is filled with 2.0 liters of helium
at sea level (101.3 kPa), and rises to an altitude at which the boiling
temperature of water is only 88 degrees Celsius, will the balloon burst?
100 °C is to 101.3 kPa as 88 °C is to x
x = 89.144 kPa
P1V1 = P2V2
(101.3) (2.0) = (88.144) (x)
x = 2.27 L
The balloon will not burst.
24. 4.00 L of a gas are under a pressure of 6.00 atm What is the volume of the gas
at 2.00 atm?
(6.00 atm) (4.00 L) = (2.00 atm) (x)
25. A gas occupies 25.3 mL at a pressure of 790.5 mmHg. Determine the volume
if the pressure is reduced to 0.804 atm
(790.5 mmHg / 760.0 mmHg/atm) (25.3 mL) = ( 0.804 atm) (x)
26. A sample of gas has a volume of 12.0 L and a pressure of 1.00 atm If the
pressure of gas is increased to 2.00 atm, what is the new volume of the gas?
(1.00 atm) (12.0 L) = (2.00 atm) (x)
27. A container of oxygen has a volume of 30.0 mL and a pressure of 4.00 atm If
the pressure of the oxygen gas is reduced to 2.00 atm and the temperature is
kept constant, what is the new volume of the oxygen gas?
(4.00 atm) (30.0 mL) = (2.00 atm) (x)
28. A tank of nitrogen has a volume of 14.0 L and a pressure of 760.0 mmHg. Find
the volume of the nitrogen when its pressure is changed to 400.0 mmHg while
the temperature is held constant.
(760.0 mmHg) (14.0 L) = (400.0 mmHg) (x)
29. A 40.0 L tank of ammonia has a pressure of 8.00 atm Calculate the volume of
the ammonia if its pressure is changed to 12.0 atm while its temperature
remains constant.
(8.00 atm) (40.0 L ) = (12.0 atm) (x)
30. Two hundred liters of helium at 2.00 atm and 28.0 °C is placed into a tank
with an internal pressure of 600.0 kPa. Find the volume of the helium after it is
compressed into the tank when the temperature of the tank remains 28.0 °C.
(2.00 atm x 101.325 kPa/atm) (200.0 L) = (600.0 kPa) (x)
(2.00 atm) (200.0 L) = (600.0 kPa / 101.325 kPa/atm) (x)

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