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Article history: The natural gas flow fields and particles separation characteristics were numerically calculated with the
Received 4 August 2010 RNG k e turbulence model and Discrete Particle Method (DPM) in the supersonic swirling separator. An
Received in revised form 14 February 2011 experimental system was set up for testing the separation efficiency of three new designed separators
Accepted 18 February 2011
with wet air. The numerical results showed that the new annular nozzle not only expanded the natural
Available online 4 March 2011
gas to supersonic velocity with resulting in low temperature (72 °C), but also strengthened the swirling
flow with the centrifugal field of 640 000g (g is the acceleration of gravity), both of which created good
Keywords:
conditions for natural gas dehydration. Under the strong swirling flow field, most particles collided with
Natural gas dehydration
Supersonic swirling separator
the walls or entered into the liquid-collection space directly, while only few particles escaped together
Separation efficiency with the gas flow. The separation efficiency reached over 95%, when the length of the cyclone separation
Discrete Particle Method (DPM) section was about 10 times of the diameter of the wall at throat. The experimental results indicated that
the water can be efficiently removed from the wet air. The numerical results were in good agreements
with the experimental findings, which demonstrated that the Discrete Particle Method (DPM) was accu-
rate and stable enough to evaluate the dehydration characteristics of the supersonic swirling separator.
Ó 2011 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder
Technology Japan. All rights reserved.
1. Introduction temperature, flow rate and pressure loss ratio on the dehydration
characteristics were analyzed. The key components of Twister sep-
The demand for natural gas has motivated the oil and gas indus- arator and hydrocarbon recovery were investigated by Betting and
try to discover natural gas reservoirs in remote areas. However, in Epsom [7]. Jiang et al. [8] developed a mathematical model to
the process of producing and transporting natural gas, the presence investigate the one-dimensional transonic flow of two-component
of water in natural gas can cause corrosion, excessive pressure gas mixture with spontaneous condensation. The mixing flow field
drop, hydrate, the decrease of its heating value and the reduction of the nitrogen and water vapor is numerical simulated in a super-
in gas transmission efficiency. The possibility of pipeline obstruc- sonic separator.
tion due to the formation of hydrate is one of the most serious The computational fluid dynamics technique was used to study
problems in the gas industry. Therefore, it is important to assure the behavior of high-pressure natural gas in supersonic nozzles by
that water is removed as the gas is transported from the wellhead Jassim et al. [9,10]. The effects of real gas and nozzle geometry on
to a processing facility. the natural gas flow behavior in the nozzle were discussed. The
Supersonic swirling separators have been introduced to treat influences of vorticity on the performance of the nozzles and shock
the problems in natural gas for offshore applications [1,2]. Alferov wave positions were studied. Shock wave with reasonable strength
et al. [3] and Betting et al. [4] proposed a method and apparatus for was beneficial to the particles separation. Selective dehydration of
the separation and liquefaction of the gas mixtures, respectively. high-pressure natural gas through supersonic nozzles was investi-
Alferov et al. [5] introduced a technological process for supersonic gated by Karimi and Abdi [11]. A computational model linked to
separator and compared the effectiveness of the 3-S separator, MATLAB and HYSYS package was presented to predict the effect
Joule–Thomson valve, and turbo-expander in extracting C3+ from of different parameters such as the inlet pressure, inlet
natural gas. Liu et al. [6] described a supersonic swirling temperature and flow rate on the behavior of the working fluid.
dehydration system for natural gas and the indoor experiment However, few researchers focused on the characteristics and
was carried out to test the unit performance. The effects of the separation efficiency of the liquid particles in the supersonic
swirling separator.
⇑ Corresponding author. In the two-phase flow models, the governing equations of
E-mail address: caoxw@upc.edu.cn (X. Cao). continuous phase are generally written in Eulerian form, whereas,
0921-8831/$ - see front matter Ó 2011 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
doi:10.1016/j.apt.2011.02.012
C. Wen et al. / Advanced Powder Technology 23 (2012) 228–233 229
swirling flows in the separator. The time step was 1e-6 in the numer- 4. Results and discussion
ical simulation. The convergence criterion is 106 for energy equa-
tion and 103 for all other equations. 4.1. Natural gas flow field
3.4. Particle size distribution The natural gas flow field was numerical simulated in the
supersonic swirling separator based on the above mentioned
Gas expands in the supersonic swirling separator to supersonic numerical methods. The average static temperature and tangential
velocities with resulting in lower temperatures, which leads to velocity of cross section was analyzed along the axis. Numerical re-
the nucleation and condensation of the water. The typical size sults are presented in Fig. 3.
of the liquid particle is 0.1–4 lm. In the calculation, the In the supersonic swirling separator, natural gas expands in the
Rosin–Rammler model [21] is used to describe the distribution annular Laval nozzle to supersonic velocities with resulting in low-
of the liquid particle size. If the size distribution is of the er temperatures. The static temperature decreases slowly in the
Rosin–Rammler type, the mass fraction of droplets of diameter convergent section of the nozzle, while gas expansion induces a ra-
greater than d is given by: pid decrease in the divergent part. The average static temperature
is about 72 °C at the nozzle exit. The swirling motion is generated
n
Y d ¼ eðd=dÞ ð1Þ by the vanes at the entrance of the nozzle. The swirl strength in-
creases strongly, due to the contraction in the annular nozzle and
where Yd is the mass fraction of droplets; d is the droplet diameter; the second convergence of the central body, resulting in a centrif-
is the size constant and n is the size distribution parameter. In our
d ugal field of about 640 000g (g is the acceleration of gravity).
simulation, the particle size constant d is 1.4 lm; the size distribu-
As a result of the low temperature and the strong centrifugal
tion parameter n is 1.62. field, the nucleation and condensation of water will occur, and
the liquid droplets can be centrifuged onto the walls with creating
3.5. Initial and boundary conditions a liquid film. Then the gas liquid mixture passes through the cy-
clone separation section, in which the static temperature increases
The Discrete Particle Method (DPM) contains the assumption and tangential velocity decreases slowly because of the wall fric-
that the second phase is sufficiently dilute that particle–particle tion. The liquid particles enter into the liquid-collection space for
interactions and the effects of the particle volume fraction on the removal. The dry gas moves across the diffuser where a shock wave
gas phase are negligible. In the numerical simulation, the liquid occurs. The remaining kinetic energy in the gas flows is trans-
particles were injected along with the gas phase. It was supposed formed to increase the static pressure.
that the particles speed were equal to the gas velocity calculated
by the simulation results. Variable numbers of the liquid particles 4.2. Liquid particle trajectory
(10,000, 40,000 and 100,000) were used to predict the particle tra-
jectories and separation efficiency. The results were in reasonable As above-mentioned the water will be condensed from natural
agreement with each other. Therefore, the number of 10,000 liquid gas mixtures duo to the low temperature in the supersonic separa-
particles was utilized for our simulations. tor. In this section, the Discrete Particle Method (DPM) was em-
Pressure boundary conditions are imposed for the inlet and out- ployed to predict the flow characteristics of the liquid particles,
let of the supersonic swirling separator. Total pressure (absolute with the following assumption:
pressure) and total temperature at the nozzle inlet are set to be
4 MPa and 303 K, respectively. The static pressure and stagnation (1) It is assumed here that the particle is a sphere, and the evap-
temperature are chosen for outlet boundary conditions, which oration process of the liquid particles could be ignored.
are 2.68 MPa and 290 K, respectively. Turbulence intensity and vis- (2) The initial velocity of the liquid particles is equal to the gas
cosity ratio are assigned as turbulence parameters. No-slip and adi- speed, obtained by the numerical calculation.
abatic boundary conditions are specified for the walls. (3) Thermal equilibrium exists between gaseous and liquid
In addition, for the discrete phase, the escape boundary condi- particles.
tions are assigned for the inlet and dry gas outlet. That is, the par- (4) The liquid particles are removed as soon as they are cap-
ticles will not return the computational domain, if they reach the tured on the wall.
inlet due to the backflow. The trap boundary conditions are used
for the liquid outlet and the walls of the cyclone separation section
and the liquid-collection space. We appoint the reflect boundary
conditions for all other walls.
In this paper, it is assumed that the gas obeys the model equa-
tion of state which enables one to take into account the effect of
super-compressibility in Eq. 2.
PV ¼ mRTZ ð2Þ
The liquids particles are released and tracked at the nozzle out- maximum gas residence time less than 2 ms. Therefore, the length
let. Fig. 4 shows the predicted liquid particle trajectories in the of the cyclone separation section greatly affects the gas/liquid sep-
supersonic separator. Obviously, the liquid particles move in circu- aration performance. Fig. 6 shows the effects of the length of the
lar motion under the combined effects of the drag force, the ther- cyclone separation section on the separation efficiency. The dimen-
mophoretic force and the centrifugal force. Fig. 4 demonstrates sionless parameter l represents the various lengths, which is the
that most of the droplets enter into the liquid-collection space ratio of the length of the cyclone separation section to the diameter
and then are removed from natural gas mixtures, while only few of the wall at throat. For a given design condition, the dimensions
liquid particles pass through the diffuser with the dry gas. of the throat in the supersonic separator is determined. Therefore,
Fig. 5 presents a single particle trajectory. It can be seen that the the dimensions of the throat can be chosen as a characteristic
particles have three representative moving states, which are: (a) parameter.
the particle colliding with the wall, (b) the particle entering into The separation efficiency g for the liquid particles is calculated
the liquid-collection space and (c) the particle passing through according to:
the diffuser. For the first kind trajectory in Fig. 5(a), the particle mtrap
is centrifuged onto the walls, creating a thin liquid film, which gets g¼ 100% ð3Þ
mtrap þ mescape
into the liquid-collection space along the wall. Some particles enter
into the liquid-collection space directly without collision with the where mtrap and mescape are the mass flow of the liquid particles pass-
wall. For other few particles, the drag force plays a much more sig- ing through the liquid-outlet and dry-gas outlet, respectively.
nificant role than other forces, as shown in Fig. 5(c). Therefore, It can be seen that the separation efficiency is significant im-
these particles pass through the diffuser together with the gas proved with the increase of the cyclone section length. When the
flow, which cause the gas phase entraining few liquids. In addition, ratio of the length to the diameter l is 10, the separation efficiency
some slip-gas flows through the liquid-outlet. reaches over 95%. This is because the increasing length not only in-
creases the wall surface area for particles collision, but also extends
4.3. Separation efficiency the particles residence time for gas/liquids separation. However,
the gas/liquid temperature will increase slowly due to the presence
The flow velocity is supersonic at the nozzle outlet in the super- of the friction loss, in the cyclone separation section. As a result of
sonic separator. The gas speed is so high that it results in a the rise of the static temperature, the liquid particles, condensed
Fig. 5. Single particle trajectory. (a) Particle colliding with the wall. (b) Particle entering into the liquid-collection space. (c) Particle passing through the diffuser.
232 C. Wen et al. / Advanced Powder Technology 23 (2012) 228–233
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