Benceno

Temperatura (K) Presión(MPa) Presión (kPa) Volumen (m3/kg)

337.23 0.060175 60.175 0.58319
348.47 0.087282 87.282 0.4125
359.71 0.1232 123.2 0.29909
370.95 0.16971 169.71 0.22165
382.19 0.22873 228.73 0.16745
393.43 0.3023 302.3 0.12866
404.68 0.39255 392.55 0.10033
415.92 0.50171 501.71 0.07926
427.16 0.63209 632.09 0.063324
438.4 0.78608 786.08 0.051084
449.64 0.96617 966.17 0.041547
460.88 1.1750 1175 0.034017
472.12 1.4151 1415.1 0.027996
483.36 1.6895 1689.5 0.023123
494.6 2.0012 2001.2 0.01913
505.84 2.3536 2353.6 0.015816
517.09 2.7503 2750.3 0.013025
528.33 3.1957 3195.7 0.01063
539.57 3.6954 3695.4 0.0085113
550.81 4.2573 4257.3 0.0065066
562.05 4.9012 4901.2 0.0032362

Tamaño de paso
h 11.24

Benceno

Temperatura (K) Presión(MPa) Presión (kPa) Volumen (m3/kg)

355.05 0.041486 41.486 0.75567
366.89 0.061175 61.175 0.52584
378.73 0.087679 87.679 0.37553
390.57 0.12251 122.51 0.27437
402.41 0.16733 167.33 0.20453
414.25 0.22392 223.92 0.15518
426.09 0.2942 294.2 0.11956
437.93 0.38018 380.18 0.093374
449.77 0.48398 483.98 0.073773
461.61 0.60785 607.85 0.058868
473.45 0.75413 754.13 0.047365
485.29 0.92531 925.31 0.038363
497.13 1.1240 1124 0.031226
508.97 1.3530 1353 0.025497
520.81 1.6155 1615.5 0.020839
532.65 1.9147 1914.7 0.017004
544.49 2.2546 2254.6 0.013801
556.33 2.6397 2639.7 0.011079
568.17 3.0756 3075.6 0.0087079
580.01 3.5693 3569.3 0.0065342

Tamaño de paso
h 11.84
Entalpia (kJ/kg)
376.35
389.15
402.21
415.49
428.96
442.57
456.3
470.1
483.93
497.73
511.46
525.03
538.36
551.32
563.76
575.44
585.99
594.79
600.6
600
547.34

Entalpia (kJ/kg)
322.93
338.28
353.97
369.94
386.17
402.63
419.26
436.04
452.89
469.77
486.61
503.32
519.8
535.9
551.45
566.17
579.68
591.33
599.93
602.57
 Parámetros de en
No. Sustancia Tc (K) Pc (kPa)
1 Benceno 562.05 4895

Estado 1
T(K) 550.81
P(kPa) 4274.820153276

Solución de la EoS (Dete

Parámetros de la EoS
k Tr a ac (kJ-m3/kmol2)
0.6870397718 0.9800 1.0139 2039.6573694742
Coeficientes polinomio Z Cálculo del discriminante ( R )
a2 a1 a0 p
-0.9306740314 0.2684592611 -0.0240836619 -0.0202587898
Tres raíces
m theta Z1 Z2
0.1643524252 0.3635626679 0.4638343459 0.2840344849

Cálculo Fugacidad Vapor Cálculo Fugacidad Liquído

Lnφ -0.4057718695 Lnφ
φ 0.6664621905 φ

Con Solver
φL-φV -2.19069207E-12

Parámetros de en
No. Sustancia Tc (K) Pc (kPa)
1 Metilbenceno 591.75 4108

Estado 1
T(K) 580.01
P(kPa) 3572.955
 Solución de la EoS (Dete

Parámetros de la EoS
k Tr a ac (kJ-m3/kmol2)
0.7629982931 0.9802 1.0153 2694.0528366211
Coeficientes polinomio Z Cálculo del discriminante ( R )
a2 a1 a0 p
-0.9309668724 0.2679034562 -0.0239177509 -0.0209963163
Tres raíces
m theta Z1 Z2
0.1673173286 0.3608289656 0.4668651328 0.2832081791

Cálculo Fugacidad Vapor Cálculo Fugacidad Liquído

Lnφ -0.4044900224 Lnφ
φ 0.6673170409 φ

Con Solver
φ -φ
L V -7.34301508E-13
 Parámetros de entrada
Omega Bures 1 Bures 2 Bures 3 R(kJ/kmol-K)
0.2103 70 182.84 1835.891 8.314

Solución de la EoS (Determinación Z)

ámetros de la EoS Psat (DIPPR)

a (kJ-m /kmol )
3 2
b(m3/kmol) A B A
2067.9201514932 0.0742659831 0.4215294682 0.0693259686 B
Cálculo del discriminante ( R ) C
# raíces reales
q R D
-0.0005126171 -2.4225347E-07 3 E
Una raíz Psat (Pa)
Z3 Z Z elegido 0.4638343459 Psat (kPa)
0.1828052006 Err:502 Estado de agregación

álculo Fugacidad Liquído Volumen Especifico

-0.4057718695 V (m /Kmol)
3
0.4968861509
0.6664621905 V(m3/Kg) 0.0063610384

Parámetros de entrada
Omega Bures 1 Bures 2 Bures 3 R(kJ/kmol-K)
0.26401 91.29 223.89 1886.711 8.314
 Solución de la EoS (Determinación Z)

ámetros de la EoS Psat (DIPPR)

a (kJ-m3/kmol2) b(m3/kmol) A B A
2735.1941718921 0.0931698745 0.4202664294 0.0690331276 B
Cálculo del discriminante ( R ) C
# raíces reales
q R D
-0.0005493628 -2.6736965E-07 3 E
Una raíz Psat (Pa)
Z3 Z Z elegido 0.4668651328 Psat (kPa)
0.1808935606 Err:502 Estado de agregación

álculo Fugacidad Liquído Volumen Especifico

-0.4044900224 V (m /Kmol)
3
0.6300998861
0.6673170409 V(m3/Kg) 0.0068384312
 Mw
78.114

Psat (DIPPR)
83.107
-6486.2
-9.2194
6.9844E-06
2
4252561.188
4252.561188
Líquido

Mw
92.141
Psat (DIPPR)
76.945
-6729.8
-8.179
5.3017E-06
2
3549446.0505
3549.44605
Líquido
 Benceno
Presión con
Temperatura (K) Volumen Molar (m3/kmol)
Isofugacidad (Kpa)
337.23 61.358 44.783
348.47 88.262 31.955
359.71 123.775 23.33
370.95 169.667 17.381
382.19 227.86 13.18
393.43 300.43 10.152
404.68 389.65 7.926
415.92 497.70 6.263
427.16 627.10 5
438.4 780.39 4.027
449.64 960.26 3.268
460.88 1169.47 2.667
472.12 1410.93 2.187
483.36 1687.63 1.798
494.6 2002.74 1.48
505.84 2359.50 1.217
517.09 2761.73 0.9974
528.33 3212.30 0.8101
539.57 3715.33 0.6468
550.81 4274.82 0.4968

Tolueno
Presión con
Temperatura (K) Volumen Molar (m3/kmol)
Isofugacidad (Kpa)
355.05 41.680 69.637
366.89 61.240 48.688
378.73 87.540 34.899
390.57 122.110 25.57
402.41 166.62 19.1
414.25 222.99 14.511
426.09 292.89 11.19
437.93 378.72 8.741
449.77 482.58 6.905
461.61 606.82 5.508
473.45 753.88 4.429
485.29 926.37 3.584
497.13 1126.94 2.915
508.97 1358.43 2.379
520.81 1623.80 1.945
532.65 1926.13 1.589
544.49 2268.68 1.293
556.33 2654.88 1.043
568.17 3088.35 0.826
580.01 3572.96 0.63
Volumen Molar (m3/kg)

0.5733
0.409
0.2986
0.2225
0.1687
0.1299
0.1014
0.0801
0.064
0.0515
0.0418
0.0341
0.0279
0.023
0.0189
0.0155
0.0127
0.0103
0.0082
0.0063

Volumen Molar (m3/kg)

0.755
0.528
0.378
0.277
0.207
0.157
0.121
0.094
0.074
0.059
0.048
0.038
0.031
0.025
0.021
0.017
0.014
0.011
0.0089
0.0068
 Temperatura (K) Presión(MPa) Presión (kPa) Volumen (m3/kg)

337.23 0.060175 60.175 0.58319

348.47 0.087282 87.282 0.4125
359.71 0.1232 123.2 0.29909
370.95 0.16971 169.71 0.22165
382.19 0.22873 228.73 0.16745
393.43 0.3023 302.3 0.12866
404.68 0.39255 392.55 0.10033
415.92 0.50171 501.71 0.07926
427.16 0.63209 632.09 0.063324
438.4 0.78608 786.08 0.051084
449.64 0.96617 966.17 0.041547
460.88 1.1750 1175 0.034017
472.12 1.4151 1415.1 0.027996
483.36 1.6895 1689.5 0.023123
494.6 2.0012 2001.2 0.01913
505.84 2.3536 2353.6 0.015816
517.09 2.7503 2750.3 0.013025
528.33 3.1957 3195.7 0.01063
539.57 3.6954 3695.4 0.0085113
550.81 4.2573 4257.3 0.0065066

Psat vs T
4500.000
4000.000
3500.000
3000.000
Psat (KPa)

2500.000
2000.000
Datos con
1500.000 Is ofugaci da
d
1000.000
datos NIST
500.000
0.000
300 350 400 450 500 550 600
T (K)
Temperatura (K)
Presión(MPa) Presión (kPa) Volumen (m3/kg)
355.05 0.041486 41.486 0.75567
366.89 0.061175 61.175 0.52584
378.73 0.087679 87.679 0.37553
390.57 0.12251 122.51 0.27437
402.41 0.16733 167.33 0.20453
414.25 0.22392 223.92 0.15518
426.09 0.2942 294.2 0.11956
437.93 0.38018 380.18 0.093374
449.77 0.48398 483.98 0.073773
461.61 0.60785 607.85 0.058868
473.45 0.75413 754.13 0.047365
485.29 0.92531 925.31 0.038363
497.13 1.1240 1124 0.031226
508.97 1.3530 1353 0.025497
520.81 1.6155 1615.5 0.020839
532.65 1.9147 1914.7 0.017004
544.49 2.2546 2254.6 0.013801
556.33 2.6397 2639.7 0.011079
568.17 3.0756 3075.6 0.0087079
580.01 3.5693 3569.3 0.0065342

Psat vs T
4000.000

3500.000

3000.000

2500.000
Psat (KPa)

2000.000

1500.000 Datos con

Is ofugacida
1000.000
Datos NIST
500.000

0.000
300 350 400 450 500 550 600
T (K)
 2000.000

Psat (
1500.000 Datos con
Is ofugacida
1000.000
Datos NIST
500.000

0.000
300 350 400 450 500 550 600
T (K)
 Benceno
Presión con
Presión con DIPPR (Kpa) Volumen Molar (m3/kmol)
Isofugacidad (Kpa)

45.55530366 60.088 61.358 44.783

32.222025 87.161 88.262 31.955
23.36311626 123.014 123.775 23.33
17.3139681 169.416 169.667 17.381
13.0801893 228.23 227.86 13.18
10.05014724 301.58 300.43 10.152
7.83717762 391.56 389.65 7.926
6.19131564 500.26 497.70 6.263
4.946490936 630.06 627.10 5
3.990375576 783.38 780.39 4.027
3.245402358 962.74 960.26 3.268
2.657203938 1170.79 1169.47 2.667
2.186879544 1410.35 1410.93 2.187
1.806230022 1684.39 1687.63 1.798
1.49432082 1996.10 2002.74 1.48
1.235451024 2348.95 2359.50 1.217
1.01743485 2747.03 2761.73 0.9974
0.83035182 3193.76 3212.30 0.8101
0.6648516882 3693.94 3715.33 0.6468
0.5082565524 4252.56 4274.82 0.4968

V vs T
0.7

0.6

0.5

0.4
V (m3/Kg)

Datos con 0.3

Datos con
Is ofugaci da Robi ns on
d 0.2
Datos NIST
datos NIST 0.1

0
600 300 350 400 450 500 550 600
T (K)
 Tolueno
Presión con
Presión con DIPPR (Kpa) Volumen Molar (m3/kmol)
Entalpia (kJ/kg) Isofugacidad (Kpa)
322.93 41.341 41.680 69.637
338.28 60.980 61.240 48.688
353.97 87.447 87.540 34.899
369.94 122.268 122.110 25.57
386.17 167.119 166.62 19.1
402.63 223.81 222.99 14.511
419.26 294.26 292.89 11.19
436.04 380.53 378.72 8.741
452.89 484.74 482.58 6.905
469.77 609.17 606.82 5.508
486.61 756.15 753.88 4.429
503.32 928.15 926.37 3.584
519.8 1127.76 1126.94 2.915
535.9 1357.70 1358.43 2.379
551.45 1620.84 1623.80 1.945
566.17 1920.23 1926.13 1.589
579.68 2259.14 2268.68 1.293
591.33 2641.07 2654.88 1.043
599.93 3069.81 3088.35 0.826
602.57 3549.44 3572.96 0.63

V vs T
0.8

0.7

0.6

0.5
V (m3/Kg)

0.4
Datos con 0.3 Datos co
Is ofugacidad Robi nso
0.2
Datos NIST Datos NI
0.1

0
550 600 300 350 400 450 500 550 600
T (K)
 0.4

V (m3
Datos con 0.3 Datos co
Is ofugacidad Robi nso
0.2
Datos NIST Datos NI
0.1

0
550 600 300 350 400 450 500 550 600
T (K)
 Volumen Molar (m3/kg)

0.5733
0.409
0.2986
0.2225
0.1687
0.1299
0.1014
0.0801
0.064
0.0515
0.0418
0.0341
0.0279
0.023
0.0189
0.0155
0.0127
0.0103
0.0082
0.0063

Datos con Peng

Robi ns on

Datos NIST

500 550 600

 Volumen Molar (m3/kg)

0.755
0.528
0.378
0.277
0.207
0.157
0.121
0.094
0.074
0.059
0.048
0.038
0.031
0.025
0.021
0.017
0.014
0.011
0.0089
0.0068

Datos con Peng

Robi nson

Datos NIST

500 550 600

 Datos con Peng
Robi nson

Datos NIST

500 550 600