Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Journal Technology
of Chemical and Metallurgy,
Technology 52, 3,52,
and Metallurgy, 2017, 526-531
3, 2017
ABSTRACT
The reaction studied is found a first order one with respect to malachite green, sugar and hydroxyl ion concentrations.
However, the reaction is independent of the solution ionic strength and shows no salt effect dependence. This provides to
imply an outer sphere mechanism. No polymerization of the reaction mixture with acrylonitrile is observed, which indicates
an absence of radicals’ formation in the course of the reaction. The Michaelis-Menten plot suggests the participation of
a reaction intermediate in the rate determining step. The activation parameters of the reaction are calculated, while the
products are identified by FTIR spectroscopy. A reaction stoichiometry of 1:1 is found. A mechanism consistent with the
facts pointed above is advanced.
Keywords: Malachite green(MG), sodium hydroxide, glucose, fructose, xylose.
CH3 CH3
fading of dyes in general [8]. Hitherto, there has been no H3C H3C
of alkaline malachite green fading in alcohols and in the The reactions were performed under pseudo-first
presence of surfactants [9,10]. Pressure and temperature order conditions by maintaining a large excess (x10 or
526
Latona Dayo Felix
527
Journal of Chemical Technology and Metallurgy, 52, 3, 2017
Fig. 2. A plot of 1/ k obs vs. 1/ [S] : ( Fructose , Glu- Fig. 3. Plot of lnKobs vs. 10 l1/2.
cose, Xylose.
of 1/kobs vs 1/[s] has an intercept, revealing the presence equal to 6.00x10-2 M. The ionic strength I ranges between
of an intermediate complex as shown in Fig. 2. The 0.10 M and 0.90 M, while T = 298 K. The reaction rate is
second order rate constants are 0.152 M-1s-1(Glucose), independent of the ionic strength of the solution. A plot
0.138 M-1s-1 (Fructose), 0.125M-1s-1 (Xylose). of lnkobs vs I1/2 gives a straight line of a slope equal to
zero as shown in Fig. 3. This implies a neutral molecule
Effect of hydroxyl ion concentration on the rate participation in the rate determining step.
constant observed
The effect of hydroxyl ion concentration on the rate Salt effect on the rate constant observed
constant observed is determined studying reaction mixtures The salt effect on the observed rate constants observed
containing [MG] of 1.00 ь 10-3 M, [sugar] of 2.00 x 10-2M, is determined studying reaction mixtures containing [MG]
and [OH-] ranging from 1.00 x 10-2 to 6.00 x 10-2 M. The of 1.00x10-3, [sugar] of 2.00x10-2 M, [OH-] of 6.00x10-2 M,
ionic strength is equal to 0.25 M, while T = 298 K. The [salt] ranging from 0.002 M to 0.2 M. The ionic strength is
increase of [OH-] results in increase of the reaction rate as equal to 0.25 M, while T = 298 K. The addition of KCl and
shown in Table 2. The slope of a plot of ln kobs vs ln[OH-] NaNO3 do not affect the reaction rate as illustrated in Fig.
indicates that the reaction is a first order one. 4. This implies an outer sphere mechanism for the reaction.
Effect of the ionic strength on the rate constant Effect of temperature and determination of
observed activation parameters
The effect of the ionic strength on the rate constants The temperature effect on the rate constants ob-
observed is determined studying reaction mixtures of served is determined varying the temperature within
[MG] equal to1.00x10-3, [S] equal to 2.00x10-2 M, [OH-] the range from 298 K to 308 K in case [MG] is equal
Table 2. Effect of hydroxyl ion concentration on the rate constant observed.
102[OH-]/M 103kobs/s-1
Glucose Fructose Xylose
1.00 1.98 1.81 2.20
2.00 3.14 2.30 3.00
3.00 4.22 3.82 4.21
4.00 5.05 4.85 5.30
5.00 6.70 6.25 6.00
6.00 8.10 7.41 6.91
-3
-3M [S] 2.00 X 10-2-2M I = 0.25 M T = 298 K
[MG] 1.00 X 10
[MG] 1.00 x 10 M [S] 2.00 x 10 M I = 0.25 M T = 298 K
528
Latona Dayo Felix
𝑘𝑘 /
ln � � = 23.76
ℎ
529
Journal of Chemical Technology and Metallurgy, 52, 3, 2017
Acknowledgements
(5) I appreciate the technical support given by the tech-
nical staff of the Central Science Laboratory, Obafemi
Awolowo University, Ile-Ife, Nigeria.
REFERENCE
7. D. Zhang, X. Pan, Removal of malachite green from 11. T. David, Y. Chen, K.J. Laidler, Pressure and
waste by Firmiana Simplex wood fibre. Electronic Temperature effects on the kinetics of the alkaline
Journal of Biotechnology, 12, 4, 2009, 1-10. fading of organic dyes in aqueous solution, Can. J.
8. R.Kuramoto, L. Lachman, J. Cooper, A study of the effect Chem, 37, 1959, 599-612.
of certain pharmaceutical materials on color stability, 12. A. Raducan, M. Pius, D. Oancea, The influence
Journal of Amer. Pharma. Ass., XLVII, 3, 1958, 175-180. of selective salvation on the kinetics of reaction
9. A. Raducan, A. Olteanu , M. Pius, D. Oancea, Influence between malachite green and hydroxide ion, Analele
of surfactants on the fading of malachite green, Central univeristatii din Bucuresti-Chimie, XVI, 2007, 31-36.
European Journal of Chemistry, 6, 1, 2008, 89-92. 13. D.F. Latona, Kinetics and mechanism of sugar
10. B. Samiey, A.R. Toosi, Kinetic study of malachite green oxidation by KMnO4 in NaOH medium, The
fading in the presence of TX-100, DTAB and SDS, Bull Pacific Journal of Science and Technolgy, 17, 1,
Korean Chem. Soc., 30, 9, 2009, 2051-2056. 2016, 177-182.
531