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G
Properties of Natural Gas
IIT
S_
C
O
O Dr Pankaj Tiwari
M
IIT Guwahati
1
Properties of Natural Gas
Natural Gas
G
Natural gas is a complex mixture of light hydrocarbons with a minor amount of inorganic compounds: Field/Reservoir
Natural gas properties vary significantly with pressure, temperature and gas composition
IIT
Compositions of the natural gas can be found through measurements; Gas chromatography
Properties can be estimated using established correlations- Lab measurements
S_
Designing and analyzing natural gas production and processing and transportation: Changes in properties
C
O
O Unrefined Natural Gas
M
Natural gas sold to consumer is methane
IIT Guwahati
2
Properties of Natural Gas
G
Gas-specific gravity,
IIT
Pseudo-critical properties [pressure and temperature]
Viscosity
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Evaluation of Gas Reservoir and Gas Well
Density- Vapor density
Production, Prediction and Evaluation
Compressibility factor- Behavior
C
Separation and Processing
Formation and expansion volume
O
Heat of combustion – energy content
O
Measurements
M
Safety – Explosive properties- flash and fire points, volatility, flammability (5% LEL and 15% UEL)
ASTM methods
IIT Guwahati
3
Properties of Natural Gas
G
Flow in wells, need z-factor and viscosity
IIT
Pressure drop in pipelines, need density and viscosity
S_
Temperature in pipelines, need heat capacity
C
Molecular weight, need relative density (gravity)
O
Reynolds number, need density and viscosity
O
Hydrates and water, need water vapour in natural gas (diagram or PVT package)
M
IIT Guwahati
4
Properties of Natural Gas
G
Component MWi Tci, (oR) pci (psia) Mole Fraction (Example)
C1 16.04 344 673 0.775
IIT
C2 30.07 550 709 0.083
C3 44.10 666 618 0.021
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i-C4 58.12 733 530 0.006
n-C4 58.12 766 551 0.002
C
i-C5 72.15 830 482 0.003
n-C5 72.15 847 485 0.008
O
n-C6 86.18 915 434 0.001
n-C7 114.23
O 1024 361 0.001
M
N2 28.02 492 227 0.050
CO2 44.01 548 1073 0.030
H2S 34.08 1306 672 0.020
IIT Guwahati
5
Properties of Natural Gas
Gas Law
G
IIT
Ideal Gas Law PV = n RT = NKT
S_
Psc = 14.7 psi
Tsc = 520°R
C
Real Gas Law PV = Zn RT
O
O
M
A natural gas mixture under reservoir conditions is nonideal
IIT Guwahati
6
Properties of Natural Gas
Compressibility Factor
G
Hydrocarbon gases
IIT
Standing and Katz (1942)
S_
C
O
O
M
IIT Guwahati
7
Properties of Natural Gas
G
IIT
S_
C
O
O
M
IIT Guwahati
8
Properties of Natural Gas
G
Pseudocritical temperature adjustment factor, ε3
IIT
Wichert and Aziz, 1972
S_
𝑇′∝ = 𝑇𝑝𝑐 −∈3
C
𝑝𝑝𝑐 𝑇′𝑝𝑐
𝑝′𝑝𝑐 =
O
𝑇∝ +𝑦𝐻2 𝑆 1−𝑦𝐻2 𝑆 ∈3
O
M
IIT Guwahati
9
Properties of Natural Gas
Viscosity of natural gas
G
IIT
S_
C
O
O Viscosity ratio at elevated pressure( Carr et al 1954)
M
G
IIT
S_
C
O
O
M
Specific Gravity
G
Gas-specific gravity (γg): The ratio of the apparent molecular weight of a natural gas to that of air.
IIT
The molecular weight of air is usually taken as equal to 28.97 (approximately 79% nitrogen and 21% oxygen)
S_
𝑀𝑊𝑎
𝛾𝑔 =
28.97
C
yi is the mole fraction of component i,
Apparent molecular weight (MWa): MWi is the molecular weight of component i,
O
Nc is the number of components
𝑁𝑐
𝑀𝑊𝑎 = 𝑦𝑖 𝑀𝑊𝑖
O
𝑛𝑖
M
𝑖=1
𝑦𝑖 =
𝑛
For pure methane = 0.55
𝑝𝑖 = 𝑦𝑖𝑃
For rich or heavy gas = 0.9
IIT Guwahati
12
Properties of Natural Gas
G
IIT
Gas pseudo-critical pressure (ppc)
𝑁𝑐
S_
𝑝𝑝𝑐 = 𝑦𝑖 𝑝𝑐𝑖
𝑖=1
C
O
Gas pseudo-critical temperature (Tpc)
𝑁𝑐
𝑇𝑝𝑐 = 𝑦𝑖 𝑇𝑐𝑖
O
M
𝑖=1
G
Pseudo critical temperature of the gas.
Gas composition Component Mole Fraction
IIT
C1 0.775
C2 0.083
S_
C3 0.021
i-C4 0.006
C
using mixing rule
n-C4 0.002
O
i-C5 0.003
n-C5 0.008
n-C6
O 0.001
M
n-C7 0.001
N2 0.050
CO2 0.030
H2S 0.020
IIT Guwahati
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Properties of Natural Gas
Solution
Compound yi MWi Tci, (oR) pci (psia) yiMWi yipci (psia) yiTci (oR)
G
C1 0.775 16.04 344 673 12.43 521.58 266.60
C2 0.083 30.07 550 709 2.50 58.85 45.65
IIT
C3 0.021 44.10 666 618 0.93 12.98 13.99
i-C4 0.006 58.12 733 530 0.35 3.18 4.40
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n-C4 0.002 58.12 766 551 0.12 1.10 1.53
i-C5 0.003 72.15 830 482 0.22 1.45 2.49
n-C5 0.008 72.15 847 485 0.58 3.88 6.78
C
C6 0.001 86.18 915 434 0.09 0.43 0.92
O
C7+ 0.001 114.23 1024 361 0.11 0.36 1.02
N2
CO2
0.050
0.030
O 28.02
44.01
492
548
227
1073
1.40
1.32
11.35
32.19
24.60
16.44
M
H2S 0.020 34.08 1306 672 0.68 13.45 26.12
G
the pseudo-critical pressure and temperature can be determined from
various charts or correlations developed based on the charts.
IIT
S_
Gas pseudo-critical pressure 𝑝𝑝𝑐 = 709.604 − 58.718𝛾𝑔
C
O
which are valid for H2S < 3%, N2 < 5%, and total content of inorganic compounds less than 7
O
Correlations with impurity corrections for mixture pseudo-critical properties : Ahmed 1989
M
𝑝𝑝𝑐 = 678 − 50 𝛾𝑔 − 0.5 − 206.7𝑦𝑁2 + 440𝑦𝐶𝑂2 + 606.7𝑦𝐻2𝑆
𝑇𝑝𝑐 = 326 + 315.7 𝛾𝑔 − 0.5 − 240𝑦𝑁2 − 83.3𝑦𝐶𝑂2 + 133.3𝑦𝐻2 𝑆
IIT Guwahati
16
Properties of Natural Gas
G
Pseudocritical temperature adjustment factor, ε3
IIT
Wichert and Aziz, 1972
S_
𝑇′∝ = 𝑇𝑝𝑐 −∈3
𝑝𝑝𝑐 𝑇′𝑝𝑐
𝑝′𝑝𝑐 =
C
𝑇∝ +𝑦𝐻2 𝑆 1−𝑦𝐻2 𝑆 ∈3
O
O
M
IIT Guwahati
17
Properties of Natural Gas
Pseudo critical properties of natural gas Correlations
Sutton (1985)
G
ppc = 756.8 − 131.07γg − 3.6γ2g Gases rich in heptane plus with minor amount of CO2
Tpc = 169.2 − 349.5γg − 74.0γ2g and N2 and no H2S and, 0.57 < γg < 1.68
IIT
S_
Guo and Ghalambur (2005)
C
Valid for N2 <5% and no H2S < 3% and
𝑇𝑝𝑐 = 170.491 + 307.344𝛾𝑔 total content of inorganic compound less than 7%
O
Standing (1981)
O Natural gas without nonhydrocarbon gases
𝑝𝑝𝑐 = 706 − 51.7𝛾𝑔 − 11.1𝛾𝑔2
M
𝑇𝑝𝑐 = 187 − 330𝛾𝑔 − 71.5𝛾𝑔2
IIT Guwahati
18
Properties of Natural Gas
Correlations
Pseudo critical properties of Natural Gas
Elsharkawy et al. (2000)
G
IIT
Suitable for gas condensate
𝑝𝑝𝑐 = 787.06 − 147.34𝛾𝑔 − 7.916𝛾𝑔2
𝑇𝑝𝑐 = 149.18 − 358.14𝛾𝑔 − 66.976𝛾𝑔2
S_
Ahmed (1989)
C
𝑝𝑝𝑐 = 678 − 50 𝛾𝑔 − 0.5 − 206.7𝛾𝑔2 + 440𝛾𝐶𝑂2 + 606.7𝛾𝐻2 𝑆 Applicable for mixture with
O
impurities such as N2, CO2, H2S
𝑇𝑝𝑐 = 326 + 315.7 𝛾𝑔 − 0.5 − 240𝛾𝑔2 − 83.3𝛾𝐶𝑂2 + 133.3𝛾𝐻2 𝑆
O
M
IIT Guwahati
19
Properties of Natural Gas
G
IIT
pseudo-reduced pressure
S_
𝑝
𝑝𝑝𝑟 =
𝑝𝑠𝑐
C
pseudo-reduced temperature
O
𝑇
O
M
𝑇𝑝𝑟 =
𝑇𝑠𝑐
IIT Guwahati
20
Properties of Natural Gas
𝑀𝑊𝑎
Gas-specific gravity 𝛾𝑔 =
28.97 𝑁𝑐
G
𝑖=1 𝑁𝑐
IIT
Gas pseudo-critical pressure 𝑝𝑝𝑐 = 𝑦𝑖 𝑝𝑐𝑖
𝑖=1 𝑁𝑐
Gas pseudo-critical temperature 𝑇𝑝𝑐 = 𝑦𝑖 𝑇𝑐𝑖
S_
𝑝𝑝𝑐 = 709.604 − 58.718𝛾𝑔 𝑖=1
C
Correlations with impurity corrections
O
𝑝𝑝𝑐 = 678 − 50 𝛾𝑔 − 0.5 − 206.7𝑦𝑁2 + 440𝑦𝐶𝑂2 + 606.7𝑦𝐻2 𝑆
O
𝑇𝑝𝑐 = 326 + 315.7 𝛾𝑔 − 0.5 − 240𝑦𝑁2 − 83.3𝑦𝐶𝑂2 + 133.3𝑦𝐻2𝑆
M
Pseudo-reduced pressure and temperature
𝑝 𝑇
𝑝𝑝𝑟 = 𝑇𝑝𝑟 =
𝑝𝑠𝑐 𝑇𝑠𝑐
IIT Guwahati
21