Combined Aipmt Reexam

CAREER POINT [ CODE – A ]
CAREER POINT
AIPMT Exam 2015 (Paper & Solution)
Code – A Date : 25-07-2015
Q.1 2,3-Dimethyl-2-butene can be prepared by Ans. [1]

heating which of the following compounds Sol. Students may find same question in CP
with a strong acid? Exercise Sheet: [Chapter : Periodic Table,
(1) (CH3)2C=CH–CH2–CH3 Ex.3A, Q.No.15, Page no. 187]
(2) (CH3)2CH–CH2–CH=CH2 64Gd ⇒ [Xe] 4f75d16s2

54
(3) (CH3)2CH–CH–CH=CH2
Half filled 'f' subshell is more stable
CH3
(4) (CH3)3C–CH=CH2
Q.3 The formation of the oxide ion, O2– (g),
Ans. [4] from oxygen atom requires first an
Sol. Students may find similar question in CP exothermic and then an endothermic step as
Class notes: [Chapter : GOC-II] shown below :
CH3 CH3 O(g) + e– → O–(g), ∆fHΘ = –141 kJ mol–1

H⊕ ⊕
CH3–C–CH=CH2 CH3–C – CH – CH2 O–(g) + e– → O2–(g) ; ∆fHΘ = +780 kJ mol–1
CH3 CH3 Thus process of formation of O2– in gas

phase is unfavourable even though O2– is
Θ
–H⊕ ⊕ ~CH3 isoelectronic with neon. It is due to the fact
CH3–C=C–CH3 CH3–C–CH–CH3
Rearrangement
that :
H3C CH3 H3C CH3
(1) oxygen is more electronegative
(2,3-Dimethyl-2-butene)
(2) addition of electron in oxygen results in
larger size of the ion
Q.2 Gadolinium belongs to 4f series. It's atomic (3) electron repulsion outweighs the
number is 64. Which of the following is the stability gained by achieving noble gas
correct electronic configuration of configuration
gadolinium? (4) O– ion has comparatively smaller size
(1) [Xe] 4f75d16s2 (2) [Xe] 4f65d26s2 than oxygen atom
(3) [Xe] 4f86d2 (4) [Xe] 4f95s1 Ans. [3]
Kota H.O. : Career Point Ltd., CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744‐5151200 www.careerpoint.ac.in 1
Sol. Students may find same question in CP Sol. Students may find similar question in CP
Exercise Sheet: [Chapter : Periodic Table, Exercise Sheet: [Chapter : Chemical
Ex.3B, Q.No.76, Page no. 194]
equilibrium, Ex.3(A), Q.No.1, Page no. 120]
Second electron gain enthalpy is positive
If equilibrium constant for following
(energy absorbed) because incoming
reaction is
electron realise more repulsion when enter
in uninegative anion N 2 + O2 2NO ; K
then
Q.4 The number of structural isomers possible
1 1
from the molecular formula C3H9N is : N2 + O2 NO ; K' = K
2 2
(1) 2 (2) 3 (3) 4 (4) 5
Ans. [3]
Q.6 Which one of the following pairs of
Sol. Students may find similar question in CP
Exercise Sheet: [Chapter : GOC-I solution is not an acidic buffer?
(Isomerism), Ex.(7B), Q.No.23, Page no. 79]

(1) H2CO3 and Na2CO3
Given molecular formula = C3H9N
(2) H3PO4 and Na3PO4
1°-amine ⇒ CH3–CH2–CH2–NH2 & CH3–CH–NH2
(3) HClO4 and NaClO4
CH3
2°-amine ⇒ CH3–NH–CH2CH3 (4) CH3COOH and CH3COONa
3°-amine ⇒ CH3–N–CH3
Ans. [3]
CH3
Total 4 structural isomers are possible.
Exercise Sheet: [Chapter : Ionic
equilibrium, Ex.3A, Q.No.30, Page no. 156]
Q.5 If the equilibrium constant for
Weak acid and its conjugate salt with
N2(g) + O2(g) 2NO(g) is K, strong base is an acidic buffer but
the equilibrium constant for according to option Ans is (3), HClO4 is a
strong acid
1 1
N2(g) + O2(g) NO(g) will be :
2 2 ∴ HClO4 + NaClO4 is not an acidic buffer
1
(1) K (2) K2 (3) K1/2 (4) K
2
Ans. [3]
Q.7 Aqueous solution of which of the following Q.9 On heating which of the following releases
compounds is the best conductor of electric CO2 most easily ?
current ? (1) MgCO3 (2) CaCO3
(1) Ammonia, NH3 (3) K2CO3 (4) Na2CO3
Ans. [1]
(2) Fructose, C6H12O6
(3) Acetic acid, C2H4O2 Exercise Sheet: [Chapter : s-block,
Q.No.117, Page no. 28]
(4) Hydrochloric acid, HCl
1
Ans. [4] Thermal stability ∝
Ionic potential(φ)
Charg e
φ=
Exercise Sheet: [Chapter : Electro Size
Chemistry, Ex.1, Q.No.4, Page no. 14] Thermal stability :
Anhydrous HCl is non conducting but in K2CO3 > Na2CO3 > CaCO3 > MgCO3
aqueous medium conducting as it provide ∆
Na2CO3 → ×
+ –
ions HCl + H2O → H3O + Cl
∆
K2CO3 → ×
∆
MgCO3 → MgO + CO2
Q.8 Caprolactam is used for the manufacture of:
∆
CaCO3 → CaO + CO2
(1) Terylene (2) Nylon-6, 6
(3) Nylon - 6 (4) Teflon

Q.10 Strong reducing behaviour of H3PO2 is due
Ans. [3] to :
Sol. Students may find similar question in CP (1) High oxidation state of phosphorus
Exercise Sheet: [Chapter : Polymers, (2) Presence of two –OH groups and one
Page no. 194] P–H bond
NH (3) Presence of one –OH group and two

CH2 C=O O P–H bonds
H2O
C–(CH2)5–NH
CH2 CH2 ∆ (4) High electron gain enthalpy of
n
CH2–CH2 phosphorus
Caprolactum Nylon-6 Ans. [3]
Sol. Students may find same question in CP Stability O +2 > O2 > O −2 > O 2−2
Exercise Sheet: [Chapter : p-block Bond order 2.5 2 1.5 1.0
(Pnicogen family), Ex.1, Q.No.28, Page no. 4] Bond order↑
Bond dissociation energy↑
O Stability↑
H3PO2 ⇒ P
HO
H H
Q.12 The number of water molecules is
H3PO2 is monobasic acid and act reducing maximum in :
agent due to presence of two P–H bond
(1) 18 gram of water
H3PO2 + 2Ag2O → H3PO4 + 4Ag (2) 18 moles of water
(3) 18 molecules of water
Q.11 Decreasing order of stability of O 2 , O −2 , O +2 (4) 1.8 gram of water
Ans. [2]
and O 22 − is :
(1) O 2 > O 2+ > O 22− > O −2 Exercise Sheet: [Chapter : Atom,
molecules and Chemical Arithmetic, Ex.1,
(2) O 2− > O 22− > O 2+ > O 2 Q.No.61, Page no. 67]
18 g H2O is 1 mol H2O

(3) O +2 > O 2 > O −2 > O 22−
∴ no. of H2O molecules are 6.02 × 1023
(4) O 22− > O −2 > O 2 > O +2
18 mol H2O has 18 × 6.02 × 1023 molecules
Ans. [3] of H2O
1.8 g H2O has 0.1 mol H2O

Exercise Sheet: [Chapter : Chemical ∴ no. of molecules = 0.1 × 6.02 × 1023
Bonding, Ex.1, Q.No.114, Page no. 219] = 6.02 × 1022
Stability ∝ bond order
Q.13 In which of the following pairs, both the

O2 ⇒ σ1s 2 σ* 1s 2 σ2s2 σ*2s2 σ2p 2z species are not isostructural?
( π2px 2 = π2py 2 ) (π∗2px1 = π*2py1) (1) NH3, PH3
(2) XeF4, XeO4

N − Na
Bond order = b
2 (3) SiCl4, PCl +4
6−4 (4) diamond, silicon carbide

Bond order = =2
2
Ans. [2]
Sol. Students may find same question in Class Q.15 Assuming complete ionization, same moles
notes: [Chapter : Chemical Bonding] of which of the following compounds will
XeF4 XeO4 require the least amount of acidified

KMnO4 for complete oxidation?
sp3d2 sp3
(1) FeC2O4 (2) Fe(NO2)2
F O
F
Xe (3) FeSO4 (4) FeSO3
Xe
F F O Ans. [3]
O O
Square planar tetrahedral Sol. Students may find similar question in CP

Exercise Sheet: [Chapter : Oxidation
Reduction, Ex.2, Q.No.25, Page no. 93]
Q.14 In the reaction with HCl, an alkene reacts
KMnO4 + FeC2O4 → Mn+2 + Fe+3 + CO2
in accordance with the Markovnikov's
rule, to give a product 1-chloro-1- v.f = 5 v.f. = 3
methylcyclohexane. The possible alkene is : let number of reacting moles of FeC2O4 = x
CH2 CH3 3x
∴ n KMnO 4 =
5
(1) (A) (2) (B)
KMnO4 + Fe(NO2)2 → Mn+2 + Fe+3 + NO 3−
CH3 v.f = 5 v.f = 5
similarity if moles of Fe(NO2)2 is x
(3) (A) and (B) (4)
5x
n KMnO 4 = =x
5
Ans. [3]
KMnO4 + FeSO4 → Mn+2 + Fe+3
v.f = 5 v.f = 1
Class notes: [Chapter : GOC-II]
and also the moles of FeSO4 is x
CH2 CH3 H3 C Cl
⊕
ClΘ
x
H⊕ n KMnO 4 =
(HCl) 5
(A) KMnO4 + FeSO3 → Mn+2 + SO 24 − + Fe+3
v.f = 5 v.f = 3
CH3 CH3 H3C Cl
⊕
and also the moles of FeSO4 is x
H⊕ ClΘ
(HCl)
3x
n KMnO 4 =
5
Q.16 Reaction of phenol with chloroform in (3) Cl2O7 is an anhydride of perchloric acid
presence of dilute sodium hydroxide finally
(4) O3 molecule is bent
introduces which one of the following
Ans. [2]
functional group ?
Sol. Students may find similar question in Class
(1) –CHCl2 (2) –CHO
notes]
(3) –CH2Cl (4) –COOH
OF2 is fluoride of oxygen because F is more
Ans. [2] electronegative than oxygen
Sol. Students may find similar question in CP Cl2O7 H

2O
 → 2HClO4
Exercise Sheet: [Chapter : Oxygen
O3 ⇒ O sp2, bent
Compounds, Ex.6, Q.No.31] O O
OH OH ONF and O2N– are isoelectronic because both

CHO
CHCl3 + KOH contain 24 electron.
(Phenol) (Salicylaldehyde)
Q.19 The name of complex ion, [Fe(CN)6]3– is :
(1) Tricyanoferrate (III) ion

Q.17 The vacant space in bcc lattice unit cell is :
(2) Hexacyanidoferrate (III) ion
(1) 23% (2) 32% (3) 26% (4) 48%
(3) Hexacyanoiron (III) ion
Ans. [2]
(4) Hexacyanitoferrate (III) ion
Exercise Sheet: [Chapter : Solid state, Ans. [2]
Ex.1, Q.No.28, Page no. 116]
Sol. Students may find same question in CP
Packing efficiency of bcc unit cell = 68% Exercise Sheet: [Chapter : Coordination
Chemistry, Ex.11(A), Page no. 65]
vacant space = 100 – 68 = 32%
[Fe(CN)6]3–
Q.18 Which of the statements given below is x – 6 = –3
incorrect ? x = +6 – 3
x = +3
(1) ONF is isoelectronic with O2N–
Hexa cyanido ferrate (III) ion.
(2) OF2 is an oxide of fluorine
Q.20 If Avogadro number NA, is changed from Sol. Students may find similar question in CP
23 –1 20 –1
6.022 × 10 mol to 6.022 × 10 mol , Exercise Sheet: [Chapter : GOC-II,
this would change : Page no. 99]
(1) the ratio of chemical species to each Nucleophile are e– rich species
other in a balanced equation
∴ It is Lewis Base.
(2) the ratio of elements to each other in a
compound
Q.22 A gas such as carbon monoxide would be
(3) the definition of mass in units of grams
most likely to obey the ideal gas law at :
(4) the mass of one mole of carbon
(1) high temperatures and high pressures
Ans. [3]
Sol. Students may find similar question in CP (2) low temperatures and low pressures
Exercise Sheet: [Chapter Atom, molecules
(3) high temperatures and low pressures
and Chemical Arithemic, Ex.1, Q.No.65,
Page no. 68] (4) low temperatures and high pressures
1 Ans. [3]
1 amu = × mass of 1 atom of C – 12 isotope
12
1 Exercise Sheet: [Chapter : Gaseous state,
1 amu = gm = 1.66 × 10–24 gm
6.023
If Avogadro number is change then the
For real gases
definition of mass in unit of gm is changed
 an 2 
P +  (V – nb) = nRT ….(1)
 V 2 

Q.21 Which of the following statements is not
correct for a nucleophile? At high temperature intramolecular attractive
an 2
(1) Nucleophiles attack low e– density sites forces are neglected i.e. term is
V2
(2) Nucleophiles are not electron seeking neglected. At low pressure volume is high
(3) Nucleophile is a Lewis acid So nb term is neglected.
(4) Ammonia is a nucleophile Hence from equation (1) PV = nRT
Ans. [3]
Q.23 Hybridization involved in complex the C + O2 → CO2 ; ∆H = – 393.3 kJ/mol

2–
[Ni(CN)4] is : (At. No. Ni = 28)
44 g CO2 then heat evolved is 393.5 kJ when
2 2 2 3
(1) d sp (2) d sp 393.5
35.2 g then heat evolved is × 35.2
44
(3) dsp2 (4) sp3
= – 315 kJ
Ans. [3]

Exercise Sheet: 11A [Chapter : Coordination Q.25 20.0 g of magnesium carbonate sample
chemistry, Q.No.41, Page no.63] decomposes on hating to give carbon dioxide
and 8.0 g magnesium oxide. What will be the
[Ni(CN)4]2– percentage purity of magnesium carbonate in
x–4=–2 the sample ?
x = + 4 –2 (1) 60 (2) 84
x = +2 (3) 75 (4) 96
28Ni = [Ar] 3d84s2 Ans. [2]
Ni+2 =[Ar] 3d8 Sol. Students may find similar question in CP

Exercise Sheet: 2 [Chapter : Atom
molecule, Q.No. 29, Page no. 73]
3d ∆
MgCO3 → MgO + CO2
CN– is strong ligand so pairing possible
40g MgO obtained from 84 g MgCO3
84
Then 8g obtained from ×8
3d 4s 4p 40
2
dsp complex = 16.8 g MgCO3
16.8
∴ % purity = × 100 = 84%
Q.24 The heat of combustion of carbon to CO2 is 20
–393.5kJ/mol. The heat released upon
formation of 35.2g of CO2 from carbon and
Q.26 What is the mole fraction of the solute in a
oxygen gas is -
1.00 m aqueous solution ?
(1) –630 kJ (2) –3.15 kJ
(1) 0.0354 (2) 0.0177
(3) –315 kJ (4) + 315 kJ (3)0.177 (4) 1.770
Ans. [3] Ans. [2]
Sol. Students may find similar question in CP Sol. Students may find similar question in CP
Exercise Sheet: 1 [Chapter : Chemical Exercise Sheet: 3A [Chapter : Solution
thermodynamics, Q.No.112, Page no. 144] Volumetric Analysis, Q.No.10, Page no. 51]
XA 1000 Q.29 Two possible stero-structuers of

m= ×
XB MB
CH3CHOH.COOH, which are optically
XA 1000
1= × active, are called :
(1 – X A ) 18
(1) Enantiomers (2) Mesomers

1 – XA = 55.5 XA
56.5 XA = 1 (3) Diastereomers (4) Atropisomers
1 Ans. [1]
XA =
56.5
Sol.
∴ XA = 0.0177
COOH COOH
Q.27 The correct statement regarding defects in H * OH & HO * H

crystalline solids is
CH3 CH3
(1) Frenkel defect is a dislocation defect
[R] [S]
(2) Frenkel defect is found in the halides of
alkaline metals Both are optically active and Enantiomers.
(3) Schottky defects have no effect on the

density of crystalline solids
Q.30 The following reaction
(4) Frenkel defects decrease the density of
crystalline solids NH2
+ Cl
Ans. [1]
O
NaOH
H
Exercise Sheet: 1 [Chapter : Solid State, N
Q.No. 63, 64, Page no. 118]
O
Frenkel defect it is a dislocation defect
is known by the name -
Q.28 The stability of +1 oxidation state among Al, (1) Acetylation reaction
Ga, In and Tl in creases in the sequence -

(2) Schotten-Baumen reaction
(1) Tl < In < Ga < Al (2) In < Tl < Ga < Al
(3) Friedel-Craft's reaction
(3) Ga < In < Al < Tl (4) Al < Ga < In < Tl
(4) Perkin's reaction
Ans. [3]
Sol. Students may find similar question in CP Ans. [2]

Exercise Sheet: Class Notes]
Sol. Benzoylatino of aniline is called schotten- Q.32 Reaction of a carbonyl compound with one of
Baumen's reaction. the following reagents involves nucleophilic
addition followed by elimination of water.
NaOH
NH2 + Cl–C (–HCl) The reagent is -
O
(1) hydrocyanic acid
NH–C (2) sodium hydrogen sulphite

O (3) a Grignard reagent
(4) hydrazine in presence of feebly acidic

Q.31 The sum of coordination number and solution
oxidation number of the metal M in the
Ans. [4]
complex [M(en)2(C2O4)]Cl (where en is
ethylenediamine) is - Sol.
(1) 7 (2) 8
+δ – δ
NH2
(3) 9 (4) 6 R R N
H–NH–NH2
C=O C H
Ans. [3] H⊕
R/H (Nucleophilic R/H OH
Addition)
(–H2O) H⊕
Exercise Sheet: 11B [Chapter : Coordination
chemistry, Q.No.116, Page no. 77] R
C=N–NH2
[M (en)2(C2O4)]Cl R/H
(Elimination
x+0–2–2–1=0 reaction)
x=+2+1
x = +3 Q.33 Which one of the following esters gets
–2
en, and C2O4 are bidentate ligand. hydrolysed most easily under alkaline
conditions -
O
– OCOCH3
CH2–NH2 C–O
m – m
CH2–NH2 C–O (1)
O OCOCH3
N
(2) Cl
N O
OCOCH3
N
N O (3) O2N
OCOCH3
N
Coordination No = 6 (4) H3CO
sum of coordination no and oxidation no. Ans. [3]
6+3=9
O Q.35 The rate constant of the reaction A → B is

Sol. CH3–C–O NO2 is having best 0.6 × 10–3 mole per second. If the concentration
of A is 5 M, then concentration of B after
leaving group (due to –M effect of nitro
20 minutes is -
gruop) so it is most reactivge towards alkaline
(1) 0.36 M (2) 0.72 M
hydrolysis.
(3) 1.08 M (4) 3.60 M
Ans. [2]
Q.34 In an SN1 reaction on chiral centres, there Sol. Students may find similar question in CP
Exercise Sheet: 2 [Chapter : Chemical
is -
Kinetics, Q.No. 29, Page no. 194]
(1) 100% retention Zero order reaction
(2) 100% inversion x = kt
x = 0.6 × 10–3 × 20 × 60
(3) 100% racemization
= 72 × 10–2
(4) inversion more than retention leading to
x = 0.72 M
partial racemization
A → B
Ans. [4] Initial case 5 0
Sol. Not 100% recemisation After 20 min. 5 – x x
So [B] = x = 0.72M
R2 R2
* SN1 NuΘ
R1 Cl ⊕
Q.36 What is the pH of the resulting solution when
R1 R3
equal volumes of 0.1 M NaOH and 0.01 M
R3 HCl are mixed ?
(1) 7.0 (2) 1.04

R2 R2
(3) 12.65 (4) 2.0
R1 * Nu + Nu * R1 Ans. [3]

R3 R3
Exercise Sheet: 1B [Chapter : Ionic
equilibrium, Q.No. 22, Page no. 145]
Let volume of each solution is V. Cl
Acid Base
en Co en
Eq. of HCl = 0.01 × V Equivalent of NaOH = 0.1 ×V
Net Equivalent = 0.1V – 0.01V

Cl
= V [0.1 – 0.01]
Trans
= 0.09V
Cl Cl
∴ N × 2V = 0.09V (Basic)
N Cl Cl N
0.09
[OH]Θ N = = 4.5 × 10–2 Co Co
2 N N
N N
pOH = 2 – log 4.5 N N
= 2 – 0.65
d & l of Cis from
= 1.35
∴ pH = 14 – 1.35 = 12.65
Q.38 The variation of the boiling points of the
hydrogen halides is in the order HF > HI >
Q.37 Number of possible isomers for the complex HBr > HCl. What explains the higher boiling
[Co(en)2Cl2]Cl will be : (en = ethylene point of hydrogen fluoride ?
diamine)
(1) The bond energy of HF molecules is
(1) 3 (2) 4 greater than in other hydrogen halides
(3) 2 (4) 1 (2) The effect of nuclear shielding is much
Ans. [1] reduced in fluorine which polarizes the
Sol. Students may find similar question in CP HF molecule

Exercise Sheet: 5 [Chapter : Coordination (3) The electro negativity of fluorine is much
chemistry, Q.No.30, Page no. 54]
higher than for other elements in the
(i) tota isomer = 3 group
[CO(en)2Cl2]Cl (4) there is strong hydrogen bonding between
HF molecules
Cis trans Ans. [4]
⇓
d& l Sol. Students may find similar question in CP
Exercise Sheet: Class Notes [Chapter :
trans form is optically inactive due to plane of
Chemical Bonding]
symmetry
Q.40 The oxidation of benzene by V2O5 in the

HF mass ↑
HCl Vanderwall force↑ presence of air produces -
HBr Bpt↑
HI
(1) benzoic acid
Boiling point of HF is maximum because HF (2) benzaldehyde

molecules associated by hydrogen bond
(3) benzoic anhydride
δ+ δ– δ+ δ– δ– δ–
(4) maleic anhydride
H–––––F--------H–––––F--------H–––––F
Bpt. HF > HI > HBr > HCl Ans. [4]
Sol.
Q.39 What is the mass of the precipitate formed
when 50 mL of 16.9% solution of AgNO3 is O O
OH
mixed with 50 mL of 5.8% NaCl solution ? V2O5 ∆
∆
O
–H2O
OH
(Ag = 107.3, N = 14, O = 16, Na = 23, Cl = 35.5)
O O
(1) 7g (2) 14g (Benzene) (Maleic Acid) (Maleic anhydride)
(3) 28g (4) 3.5 g
Ans. [1] Q.41 Which of the following is not the product of

Exercise Sheet: 1 [Chapter : Atom
OH
Molecule, Q.No.76, Page no. 65] dehydration of ?
16.9 × 10
Molarity (M) of AgNO3 = = 1.0 M
169.3
(1) (2)
5.8
Molarity (M) of NaCl = × 10 = 0.9914M
58.5
AgNO3 + NaCl →AgCl↓ + NaNO3

(3) (4)
0.99M × 50 0.99 × 50 Ans. [4]

Moles n =
1000 1000
Sol. ⊕
~
− 0.05 ~
− 0.05 stable carbocation
∴ moles of AgCl formed = 0.05

No rearrangement occur.
Mass of AgCl = 0.05 × 142.5 = 7 g
Q.42 Method by which Aniline cannot be prepared Sol. Luca's reagent can be used for [HCl + ZnCl2]
is - 1º/2º/3º-alcohol But if ZnCl2 is absent than
(1) reduction of nitrobenzene with H2/Pd in only 3ºalcohol can be used because it is most
ethanol reactive due to 3º carbocation.
(2) potassium salt of phthalimide treated with
chlorobenzene followed by hydrolysis Q.44 Which is the correct order of increasing
with aqueous NaOH solution energy of the listed orbitals in the atom of
(3) hydrolysis of phenyisocyanide with titanium ?
acidic solution (At. no. Z = 22)
(4) degradation of benzamide with bromine in (1) 3s 3p 3d 4s (2) 3s 3p 4s 3d
alkaline solution (3) 3s 4s 3p 3d (4) 4s 3s 3p 3d
Ans. [2] Ans. [1]
Sol. Sol. Students may find similar question in CP

Exercise Sheet: 3B [Chapter : Atomic
H2/Pd
NO2 NH2 Structure, Q.No. 163, Page no. 43]
O Ti [22], [Ar] 3d24s2

C Θ⊕ Cl NaOH
NK X X When electron will fill in 3d then it's energy
Inert halide due H2O
C to resonance
will becomes less than 4s. So electron will
O
(2) H2O/H⊕ emit from 4s not from 3d. So energy of 3d
N C NH2 + HCOOH
will be less then 4s.
Br2+ KOH
C–NH2 ∆ NH2
O Q.45 In the extraction of copper from its sulphide
ore, the metal is finally obtained by the
reduction of cuprous oxide with -
Q.43 Which of the following reaction(s) can be
(1) copper (I) sulphide (2) sulphur dioxide
used for the preparation of alkyl halides ?
(3) iron(II) sulphide (4) carbon monoxide
(I) CH3CH2OH + HCl anh
. ZnCl 2
→
Ans. [1]
(II) CH3CH2OH + HCl →
(III) (CH3)3COH + HCl → Sol. Students may find similar question in CP
Exercise Sheet: [Chapter : Metallurgy,
(IV) (CH3)2CHOH + HCl anh
. ZnCl2
→
(1) (IV) only
(2) (III) and (IV) only Copper is extracted by self reduction process
(3) (I), (III) and (IV) only 2Cu2O + Cu2S → 6Cu +SO2
(4) (I) and (II) only
Ans. [3]
Q.46 Root pressure develops due to - (1) Plasma membrane
(1) Increase in transpiration (2) Nuclear envelope
(2) Active absorption (3) Ribosome
(3) Low osmotic potential in soil (4) Mesosome
(4) Passive absorption Ans. [2]
Ans. [2] Sol. Students may find it in CP Sheet:

[Chapter: Cell biology, Page no. 3]
Exercise Sheet: Plant physiology [Chapter: Nuclear membrane is absent in prokaryotes.
Plant water relation, Q.No 258, Ex. # 1]
Root pressure is developed in herbaceous Q.49 Which one of the following animals has
plants due to osmotic active water absorption.
two separate circulatory pathways?
(1) Shark (2) Frog

Q.47 Which one is a wrong statement?
(3) Lizard (4) Whale
(1) Brown algae have chlorophyll a and c,
Ans. [4]
and fucoxanthin
Sol. Students may find it in CP Sheet: Animal
(2) Archegonia are found in Bryophyta,
diversity, Page no. 132
Pteridophyta and Gymnosperms
Whale have double circulation which consist
(3) Mucor has biflagellate zoospores
of
(4) Haploid endosperm is typical feature of
(a) Pulmonary circulation
gymnosperms
(b) Systemic circulation
Ans. [3]
Q.50 Most animals that live in deep oceanic
Sol. Students may find this in CP Sheet:
waters are -
[Chapter : Plant diversity, Page no. 81]
(1) detritivores
Mucor is member of zygomycetes and form
aplanospores (Aflagellate spores). (2) primary consumers
(3) secondary consumers

Q.48 Which of the following structures is not
(4) tertiary consumers
found in a prokaryotic cell?
Ans. [1] Q.53 Axile placentation is present in -

Sol. In deep oceanic water generally detrivore's
(1) Argemone (2) Dianthus
are found.
(3) Lemon (4) Pea
Q.51 An association of individuals of different
Ans. [3]
species living in the same habitat and
having functional interactions is - Sol. Students may find it in CP Sheet:
(1) Population [Chapter: Structural organization in plant,
(2) Ecological niche Page no. 104]
(3) Biotic community
Argemone : Parietal
(4) Ecosystem Dianthus : Free central
Ans. [3] Lemon : Axile
Sol. Students may find similar question in CP Pea : Marginal
Sheet: Ecology [Chapter : Population and
community, Page no. 52]
Q.54 In which of the following both pairs have
Community is group of interacting
correct combination?
populations of different species occupying
same habitat.
Gaseous nutrient Sulphur and
(1) cycle Phosphorus
Sedimentary nutrient Carbon and Nitrogen
Q.52 The oxygen evolved during photosynthesis
cycle
comes from water molecules. Which one of
the following pairs of elements is involved Gaseous nutrient Carbon and Nitrogen
in this reaction? (2) cycle
Sedimentary nutrient Sulphur and
(1) Magnesium and Chlorine cycle Phosphorus
(2) Manganese and Chlorine Gaseous nutrient Carbon and Sulphur
(3) cycle
(3) Manganese and Potassium
Sedimentary nutrient Nitrogen and
(4) Magnesium and Molybdenum cycle Phosphorus
Ans. [2] Gaseous nutrient Nitrogen and Sulphur

(4) cycle
Sedimentary nutrient Carbon and
Exercise Sheet: Plant physiology [Chapter cycle Phosphorus
: Photosynthesis, Q.No.158, Ex. # 1] Ans. [2]
Photolysis of water helped by minerals of Sol. Students may find similar question in CP
oxygen evolving complex (OEC) which Exercise Sheet: Ecology [Chapter :

involves Mangnese and Chlorine. Ecosystem, Q.No.78, Ex.# 2]
Carbon and nitrogen cycles are gaseous Ans. [4]

cycles as their reservoir lies in hydrosphere
and atmosphere respectively while sulphur
and phosphorus cycles are sedimentory cycles
as their reservoir lies in rocks or sediment. Morels and truffles are edible member of
ascomycetes.
Q.55 In mammalian eye, the 'fovea' is the center

of the visual field, where - Q.57 Which of the following are not membrane-
bound?
(1) more rods than cones are found
(1) Mesosomes (2) Vacuoles
(2) high density of cones occur, but has no
rods (3) Ribosomes (4) Lysosomes
(3) the optic nerve leaves the eye Ans. [3]
(4) only rods are present Sol. Students may find it in CP Sheet:
Ans. [2]
Ribosomes are membrane less cell organelle.
physiology-II, Page no. 271
Q.58 In which of the following interactions both
Fovea centralis have only cone cell so act as
centre of visual field. partners are adversely affected?
(1) Mutualism (2) Competition
Q.56 Choose the wrong statement - (3) Predation (4) Parasitism
(1) Yeast is unicellular and useful in Ans. [2]

fermentation
Sol. Students may find theory in CP Sheet:
(2) Penicillium is multicellular and Ecology [Chapter : Community &
produces antibiotics population theory, Page no. 64]
(3) Neurospora is used in the study of Competition is the interaction where fitness
of both interacting species decrease ( – / – )
biochemical genetics
(4) Morels and truffles are poisonous

mushrooms
Q.59 A colour blind man marries a woman with Implantation of embryo of site other then
normal sight who has no history of colour uterus is called Ectopic pregnancy or Tubal
pregnancy
blindness in her family. What is the
probability of their grandson being colour
blind? Q.61 Cellular organelles with membranes are -
(1) 0.25 (2) 0.5 (1) lysosomes, Golgi apparatus and

mitochondria
(3) 1 (4) Nil
(2) nuclei, ribosomes and mitochondria
Ans. [4]
(3) chromosomes, ribosomes and
endoplasmic reticulum
Exercise Sheet: Genetic, Page no. 20
Nil (4) endoplasmic reticulum, ribosomes and

C
X Y nuclei
C
X X X XY
Ans. [1]
C
X X X XY
Sol. Students may find it in CP Sheet:
Son is not affected so grand son will also not [Chapter: Cell biology]
affected.
Lysosome : single membrane bound,
Golgi body and endoplasmic reticulam :

Q.60 Ectopic pregnancies are referred to as-
Membranous, mitochondria and nucleus
(1) Pregnancies terminated due to double membrane, ribosome membrane less.
hormonal imbalance
(2) pregnancies with genetic abnormality Q.62 Cell wall is absent in -
(3) Implantation of embryo at site other (1) Nostoc (2) Aspergillus
than uterus (3) Funaria (4) Mycoplasma
(4) Implantation of defective embryo in the Ans. [4]

uterus
Ans. [3] [Chapter : Plant diversity, Page no. 44]
Sol. Students may find this in class notes Cell wall is not present in mycoplasma.
[Chapter : Reproductive system]
Q.63 The term "linkage" was coined by - Sol. Students may find it in CP Sheet: Animal
physiology-I, Page no. 133
(1) W. Sutton (2) T.H. Morgan
Premolar teeth are absent in human
(3) T. Boveri (4) G. Mendel
childhood (milk teeth dentition). Pre molar
Ans. [2] teeth are monophyodont.

Exercise Sheet: Genetic, Page no. 15 Q.66 A protoplast is a cell -
T.H. Morgan
(1) without cell wall
(2) without plasma membrane

Q.64 Which of the following biomolecules does
(3) without nucleus
have a phosphodiester bond?
(4) undergoing division
(1) Nucleic acids in a nucleotide
Ans. [1]
(2) Fatty acids in a diglyceride
Sol. Students may find it in CP Sheet: [Chapter
(3) Monosaccharides in a polysaccharide
: Cell biology, Page no. 6]
(4) Amino acids in a polyptide
Protoplasm = cell wall less cell
Ans. [1]
= cell – cell wall
[Chapter: Protoplasm, Page no. 18] Q.67 In which group of organisms the cell walls
Phosphodiester bond is present between two form two thin overlapping shells which fit
nucleotide of a nucleic acid. together?
(1) Slime moulds (2) Chrysophytes

Q.65 The primary dentition in human differs
(3) Euglenoids (4) Dinoflagellates
from permanent dentition in not having one
Ans. [2]
of the following type of teeth -
(1) Incisors (2) Canine
(3) Premolars (4) Molars
Overlapping shells are present in Diatoms
Ans. [3] member of Chrysophytes.
Q.68 The DNA molecule to which the gene of Ans. [3]
interest is integrated for cloning is called - Sol. Students may find this in CP Sheet:
(1) Carrier (2) Transformer [Chapter : Reproduction in flowering

plants, Page no. 32]
(3) Vector (4) Template
Coconut water consist of free nuclear
Ans. [3]
endosperm with each nucleus been triploid in
Sol. Students may find similar question in CP nature.
Exercise Sheet: Genetic Page no. 44
Vector. Q.71 The species confined to a particular region

and not found elsewhere is termed as -
Q.69 Male gametophyte in angiosperms produces (1) Rate (2) Keystone
(1) Three sperms (3) Alien (4) Endemic
(2) Two sperms and a vegetative cell Ans. [4]
(3) Single sperm and a vegetative cell Sol. Students may find similar question in CP
Sheet: Ecology [Chapter : Biodiversity,
(4) Single sperm and two vegetative cell
Theory, Page no. 134]
Ans. [2]
Species finds only in a particular region are
Sol. Students may find this in CP Sheet: called as endemic species.
[Chapter : Reproduction in flowering
Q.72 Metagenesis refers to -
Sperm
Generative cell (1) Presence of a segmented body and
Pollen grain Sperm
Vegetative cell (male parthenogenetic mode of reproduction
gamete)
(2) Presence of different morphic forms
Q.70 Coconut water from a tender coconut is - (3) Alternation of generation between
(1) Degenerated nucellus asexual and sexual phases of an
(2) Immature embryo organism
(3) Free nuclear endosperm (4) Occurrence of a drastic change in form
(4) Innermost layers of the seed coat during post-embryonic development
Ans. [3] Eutrophication cause increase in Biochemical

Oxygen Demand (BOD) and decrease
Dissolve Oxygen (D.O.), leads to death of
fishes.
Metagenesis is alternation of generation
between asexual polyp form and sexual
Q.75 The function of the gap junction is to -
medusa form of some coelentrates like obelia.
(1) stop substance from leaking across a
tissue
Q.73 The enzyme that is not present in succus
entericus is - (2) performing cementing to keep
neighbouring cells together
(1) lipase (2) maltase
(3) facilitate communication between
(3) nucleases (4) nucleosidase
adjoining cells by connecting the
Ans. [3]
cytoplasm for rapid transfer of ions,
Sol. Students may find it in CP Sheet: Animal small molecules and some large
physiology-I, Page no. 150
molecules.
Lipase, maltase, nucleosidase enzymes are
(4) separate two cells from ach other
found in succus entericus (intestinal juice)
while Nuclease enzyme in found in pancreatic Ans. [3]
juice.
physiology-I, Page no. 5, (NCERT-XI
Q.74 Eutrophication of water bodies leading to (Eng.) Page No. 102)
killing of fishes is mainly due to non-

availability of -
Function of gap junction is to facilitate
(1) oxygen (2) food communication between adjoining cell by
(3) light (4) essential minerals connecting the cytoplasm for rapid transfer of
Ans. [1] ions, small molecule and some large
molecules.
Exercise Sheet: Ecology [Chapter :
Environmental issue, Q.No.28, Ex. # 2]
Q.76 Match the following list of microbes and Q.77 Arrange the following events of meiosis in
their importance - correct sequence -
Sacharomyces Production of (a) Crossing over

(1) cerevisiae (i) immunosuppressive
agents (b) Synapsis
(ii) Ripening of Swiss
(2) Monascus
cheese (c) Terminalisation of chiasmata
purpureus
(3) Trichoderma (iii) Commercial
(d) Disappearance of nucleolus
polysporum production of ethanol
Propioni- (iv) Production of blood (1) (b), (c), (d), (a) (2) (b), (a), (d), (c)
(4) bacterium cholesterol lowering
agents (3) (b), (a), (c), (d) (4) (a), (b), (c), (d)
sharmanii
(a) (b) (c) (d) Ans. [3]
(1) (iii) (i) (iv) (ii) Sol. Students may it in CP Sheet: [Chapter :
Cell division, Page no. 54]
(2) (iii) (iv) (i) (ii)
(a) Crossing over : Pachytene
(3) (iv) (iii) (ii) (i)
(b) Synapsis : Zygotene
(4) (iv) (ii) (i) (iii)
(c) Terminalization of chiasma : Dikinesis
Ans. [2]
(d) Disappearance of nucelolus : end of
Sol. Students may find this in CP Sheet: Dikinesis
[Chapter : Economic zoology, Page no. 113 They are different events of prophase-I of
& 117] Meiosis.
(a) Saccharomyces cerevisiae →

Fermentation → Ethanol production
Q.78 The cutting of DNA at specific locations
(b) Monoscus purpureus → statins → blood
became possible with the discovery of -
cholesterol lowering agents
(c) Trichoderma polysporum → cyclosporin (1) Ligases
A → Production of immuno suppressive
(2) Restriction enzymes
agent
(d) Propionibacterium shormanii → Ri (3) Probes
penning of swiss cheese
(4) Selectable markers
Ans. [2]
Sol. Students may find similar question in CP Q.81 The body cell in cockroach discharge their
Exercise Sheet: Genetic Page no. 42 nitrogenous waste in the haemolymph
mainly in the form of -
Q.79 During biological nitrogen fixation, (1) Calcium carbonate
inactivation of nitrogenase by oxygen (2) Ammonia

poisoning is prevented by -
(3) Potassium urate
(1) Cytochrome (2) Leghaemoglobin
(4) Urea
(3) Xanthophyll (4) Carotene
Ans. [3]
Ans. [2]
Sol. Students may find it in CP Sheet: Lower
Sol. Students may find similar question in CP animal, Page no. 89-90
Exercise Sheet: Plant Physiology [Chapter
Body cells in cockroach discharges their
: Plant water relation, Q.No. 345, Ex. # 1]
nitrogenous waste in form potassium urate in
Leghaemoglobin acts as O2 scavenger as it the haemolymph from where it comes into
combined with O2 to form malpighian tubule.
oxyleghaemoglobin and regulates O2
concentration in root nodules of leguminous
Q.82 Filiform apparatus is characteristic feature
plants.
of -
Q.80 Grafted kidney may be rejected in a patient (1) Synergids

due to -
(2) Generative cell
(1) Innate immune response
(3) Nucellar embryo
(2) Humoral immune response
(4) Aleurone cell
(3) Cell-mediated immune response
Ans. [1]
(4) Passive immune response
Ans. [3]
Exercise Sheet: Immunity and disease
Synergid of embryo sac consist of filiform
Page no. 124
apparatus.
Cell mediated immune response.
Q.83 Acid rain is caused by increase in the Ans. [3]
atmospheric concentration of - Sol. Students may find it in CP Sheet:
(1) O3 and dust (2) SO2 and NO2 [Chapter: Structural organization of plant,
Page no. 98]
(3) SO3 and CO (4) CO2 and CO
Superior ovary or hypogynous flower is
Ans. [2]
present in china rose, mustard, brinzal, potato,
Sol. Students may find similar question in CP onion and tulip.
Environmental issue]
Q.86 Which of the following is not a function of
Acid rain have H2SO4 and HNO3 in the ratio
the skeletal system?
of 7 : 3 due to high concentration of oxides of
sulphur & nitrogen. (1) Locomotion
(2) Production of erythrocytes

Q.84 The wheat grain has an embryo with one
(3) Storage of minerals
large, shield-shaped cotyledon known as -
(4) Production of body heat
(1) Coleoptile (2) Epiblast
Ans. [4]
(3) Coleorrhiza (4) Scutellum
Sol. Students may find this in class notes
Ans. [4] [Chapter : Skeletal system]
Sol. Students may find this in CP Sheet: Function of skeletal system are –
[Chapter : Reproduction in flowering Locomotion, production of erythrocyte (By
plants, Page no. 36] bone marrow) and storage of minerals.
Scutellum is the single cotyledon present in

monocot.
Q.87 Golden rice is a genetically modified crop
plant where the incorporated gene is meant
Q.85 Among china rose, mustard, brinjal, potato, for biosynthesis of -
guava, cucumber, onion and tulip, how
(1) Vitamin A (2) Vitamin B
many plants have superior ovary?
(3) Vitamin C (4) Omega 3
(1) Four (2) Five
Ans. [1]
(3) Six (4) Three
Sol. Students may find similar question in CP Q.90 A pleiotropic gene -

Exercise Sheet: Genetics, Page no. 50
(1) Controls multiple traits in an individual
Vitamin-A
(2) is expressed only in primitive plants
(3) is a gene evolved during Pliocene

Q.88 Chromatophores take part in -
(4) controls a trait only in combination
(1) Respiration (2) Photosynthesis
with anther gene
(3) Growth (4) Movement
Ans. [1]
Ans. [2]
Sol. Students may find it in CP Sheet: Exercise Sheet: Genetics Page no. 23
Control multiple trait in a individual.
Chromatophore are membraneous structure
and have photosynthetic pigments. These
pigments are involved in photosynthesis. Q.91 Human urine is usually acidic because -
(1) hydrogen ions are actively secreted into
Q.89 Select the wrong statement - the filtrate
(1) Mosaic disease in tobacco and AIDS in (2) the sodium transporter exchanges one
human being are caused by viruses hydrogen ion for each sodium ion, in
peritubular capillaries
(2) The viroids were discovered by D.J.
Ivanowski (3) excreted plasma proteins are acidic
(3) W.M. Stanley showed that viruses (4) Potassium and sodium exchange
could be crystallized generates acidity
(4) The term 'contagium vivum fluidum' Ans. [1]
was coined by M.W. Beijerinek Sol. Students may it in CP Sheet: Animal

Ans. [2]

Hydrogen ion are actively secreted into the
[Chapter : Plant diversity – Virus, Page no.
filtrate so urine become acidic in nature.
189]
Viroids were discovered by T.O. Diener.

Q.92 Auxin can be bioassayed by - Q.94 Body having meshwork of cells, internal
cavities lined with food filtering flagellated
(1) Lettuce hypocotyl elongation
cells and indirect development are the
(2) Avena coleoptile curvature
characteristics of phylum :
(3) Hydroponics
(1) Protozoa (2) Coelenterata
(4) Potometer
(3) Porifera (4) Mollusca
Ans. [2]
Ans. [3]
Exercise Sheet: Plant physiology [Chapter:
Plant growth, Q.No.3, Ex. # 1]
In porifera body having meshwork of cells
Avena coleoptile curvature test is the
internal cavities lined with food filtering
bioassay of auxin. flagellated cells 'Choanocyte' indirect
development with larva like parenchymata
and amphiblastula.
Q.93 Which of the following events is not
associated with ovulation in human female?
Q.95 Which one of the following hormones is
(1) LH surge
not involved in sugar metabolism?
(2) Decrease in estradiol
(1) Glucagon (2) Cortisone
(3) Full development of Graafian follicle
(3) Aldosterone (4) Insulin
(4) Release of secondary oocyte Ans. [3]
Ans. [2] Sol. Students may find it in CP Sheet: Animal
Sol. Students may find it in CP Sheet: Animal physiology-II, Page no. 163, (NCERT-XI
physiology-II, Page no. 149, (NCERT-XI (Eng.) Page No. 335-336)
(Eng.) Page No. 332) Aldosterone produced by adrenal cortex is
Decrease in levels of estradiol is not involved in regulating the amount of minerals
associated with ovulation in human female, is our body fluid, while glucagon, cortisone &
where as LH surge, full development of insulin are involved in sugar metabolism.
Grafian follicle and release of secondary

oocyte is associated with ovulation.
Q.96 Which of the following diseases is caused Q.98 A childless couple can be assisted to have a
by a protozoan? child through a technique called GIFT. The
full form of this technique is :
(1) Blastomycosis (2) Syphilis
(1) Germ cell internal fallopian transfer
(3) Influenza (4) Babesiosis
(2) Gamete inseminated fallopian transfer
Ans. [4]
(3) Gamete intra fallopian transfer
Sol. Students may find it in Class notes
(4) Gamete internal fertilization and
[Chapter : Animal diversity
transfer
Babesiosis also called Red fever caused by Ans. [3]
Babesia sp member of class sporozoa of
phylum protozoa.
Reproductive system, Page no. 92
GIFT = Gamete Intra Falopian Transfer

Q.97 Outbreeding is an important strategy of
animal husbandry because it :
Q.99 A jawless fish, which lays eggs in fresh
(1) exposes harmful recessive genes that water and whose ammocoetes larvae after
are eliminated by selection. metamorphosis return to the ocean is :
(2) helps in accumulation of superior genes. (1) Petromyzon (2) Eptatretus
(3) is useful in producing purelines of (3) Myxine (4) Neomyxine

animals.
Ans. [1]
(4) is useful in overcoming inbreeding
depression.
Ans. [4] Petromyzon is jawless marine fish which lays

Sol. Students may find this in class notes egg in fresh water and whose ammocoetes
[Chapter : Economic zoology], (NCERT- larva after metamorphosis return to the ocean.
XI, Page No. 167)
Outbreeding is cross between different breads Q.100 The structures that help some bacteria to
& useful in overcoming inbreeding attach to rocks and / or host tissues are :
depression.
(1) Holdfast (2) Rhizoids
(3) Fimbriae (4) Mesosomes
Ans. [3] Sol. Students may find it in CP Sheet:

Reproductive system, Page no. 51
[Chapter : Plant diversity, Page no. 29] In human female meiosis-II completed after
fertilization.
Bacterial surface consist of fimbriae that help
in attachment of substratum.
Q.103 Which of the following layers in an antral
follicle is acellular ?
Q.101 If you suspect major deficiency of
antibodies in a person, to which of the (1) Zona pellucida
following would you look for confirmatory (2) Granulosa

evidence ?
(3) Theca interna
(1) Serum globulins
(4) Stroma
(2) Fibrinogin in plasma
Ans. [1]
(3) Serum albumins
(4) Haemocytes Reproductive system, Page no. 16
Ans. [1] Zona pellucida = Acellular layer between

follicular cell and oocyte.
Exercise Sheet: Immunity and disease,
Page no. 125
Q.104 In his classic experiments on pea plants,
Serum globulins.
Mendel did not use :
(1) Flower position (2) Seed colour

Q.102 In human females, meiosis-II is not
(3) Pod length (4) Seed shape
completed until?
Ans. [3]
(1) birth
(2) puberty
(3) fertilization
Pod length.
(4) uterine implantation
Ans. [3]
Q.105 Which one of the following fruits is (2) one allele dominant on the other
parthenocarpic?
(3) alleles tightly linked on the same
(1) Banana (2) Brinjal chromosome
(3) Apple (4) Jackfruit (4) alleles that are recessive to each other
Ans. [1] Ans. [1]
Sol. Students may find it in CP Sheet: Sol. Students may find similar question in CP
[Chapter: Structural organization of plant, Exercise Sheet: Genetics, Page no. 14
Page no. 105]
Parthenocarpy : Formation of fruit without

fertilization e.g. Banana.
Q.108 The chitinous exoskeleton of arthropods is
formed by the polymerization of :
Q.106 In angiosperms, microsporogenesis and
(1) lipoglycans
megasporogenesis :
(2) keratin sulphate and chondroitin
(1) occur in ovule
sulphate
(2) occur in anther
(3) D – glucosamine
(3) form gametes without further divisions
(4) N – acetyl glucosamine
(4) Involve meiosis
Ans. [4]
Ans. [4]
Sol. Students may find this in CP Sheet: [Chapter: Protoplasm, Page no. 106]
Chitin is a polymer of N-acteyl glucosamine.
plants, Page no. 4]
Microspore and megaspore are formed by Q.109 The imperfect fungi which are decomposers
meiosis .
of litter and help in mineral cycling belong
to :
Q.107 A gene showing codominance has :
(1) Ascomycetes (2) Deuteromycetes
(1) both alleles independently expressed in
(3) Basidiomycetes (4) Phycomycetes
the heterozygote
Ans. [2]
Sol. Students may find this in CP Sheet: Sol. Students may find it in CP Sheet:
[Chapter : Plant diversity, Page no. 92] [Chapter: Structural organization of plant,
Page no. 156]
Deuteromycetes lack sexual reproduction and
so are termed fungi imperfectii. Unisexual flower either have androecium or
gyanoecium only.
Q.110 The wings of a bird and the wings of an Unisexual flowers are present in cucumber.
insect are :
(1) homologous structures and represent Q.112 Increase in concentration of the toxicant at
convergent evolution successive trophic levels is known as :
(2) homologous structures and represent (1) Biogeochemical cycling
divergent evolution (2) Biomagnification
(3) analogous structures and represent (3) Biodeterioration

convergent evolution
(4) Biotransformation
(4) phylogenetic structures and represent
Ans. [2]
divergent evolution
Ans. [3]
Sol. Students may find it in CP Sheet: Origin Environmental issues, Ex. 2, Q.No. 6]
and Evolution of life, Page no. 16
Increased concentration of non biodegradable
Wings of birds and the wings of an insect are pollutants at successive trophic levels of food
similar in function but differ in origin so they chain is known of Biomagnification.
are analogous structure & analogy shows
convergent evolution.
Q.113 Destruction of the anterior horn cells of the
spinal cord would result in loss of :
Q.111 Flowers are unisexual in :
(1) integrating impulses
(1) Onion (2) Pea
(2) sensory impulses
(3) Cucumber (4) China rose
(3) voluntary motor impulses
Ans. [3]
(4) commissural impulses
Ans. [2]
Sol. Students may find it in CP Sheet: Animal Ans. [3]

Nerves arises from dorsal or anterior root [Chapter: Cell biology]
ganglia of spinal cord are sensory in nature.
Q.114 Roots play insignificant role in absorption Q.116 Identify the correct order of organisation of
of water in : genetic material from largest to smallest :
(1) Wheat (2) Sunflower (1) Chromosome, genome, nucleotide,

gene
(3) Pistia (4) Pea
(2) Chromosome, gene, genome, nucleotide
Ans. [3]
(3) Genome, chromosome, nucleotide,
Sol. Pistia is an aquatic plant and root is generally
gene
not involved in water absorption in aquatic
plant. (4) Genome, chromosome, gene, nucleotide
Ans. [4]
Q.115 Match the columns and identify the correct Sol. Students may find it in class notes
option. Protoplasm.
Column I Column II Genome > Chromosome > Gene > Nucleotide
(a) Thylakoids (i) Disc-shaped sacs in Golgi

apparatus
Q.117 Which one of the following hormones
(b) Cristae (ii) Condensed structure of DNA
though synthesised elsewhere, is stored and
(c) Cisternae (iii) Flat membranous sacs in released by the master gland ?
stroma
(1) Melanocyte stimulating hormone
(d) Chromatin (iv) Infoldings in mitochondria
(2) Antidiuretic hormone
(a) (b) (c) (d)
(3) Luteinizing hormone
(1) (iii) (iv) (ii) (i)
(4) Prolactin
(2) (iv) (iii) (i) (ii)
Ans. [2]
(3) (iii) (iv) (i) (ii)
(4) (iii) (i) (iv) (ii)

Sol. Students may find it in CP Sheet: Animal Q.119 Which of the following joints would allow
physiology-II, Page no. 152, (NCERT-XI no movement?
(Eng.) Page No. 332)
(1) Ball and Socket joint
Antidiuretic hormone (Vasopressin) is
synthesized by hypothalamic nuclei. It is (2) Fibrous joint
stored and released by neurohypophysis
(posterior lobe of pituitary gland). (3) Cartilaginous joint
(4) Synovial joint

Q.118 Read the different components from (a) to
Ans. [2]
(d) in the list given below and tell the
correct order of the components with Sol. Students may find it in CP Sheet: Animal
reference to their arrangement from outer physiology-I, Page no. 112

side to inner side in a woody dicot stem :
Fibrous joint do not allow movement.
(1) Secondary cortex
(2) Wood
Q.120 Which one of the following is not
(3) Secondary phoem
applicable to RNA?
(4) Phellem
(1) Chargaff's rule
The correct order is :
(2) Complementary base pairing
(1) (d), (c), (a), (b)
(3) 5' phosphoryl and 3' hydroxyl ends
(2) (c), (d), (b), (a)
(3) (a), (b), (d), (c) (4) Heterocyclic nitrogenous bases
(4) (d), (a), (c), (b) Ans. [1]
Ans. [4] Sol. Students may find it in class notes
Sol. Students may find similar question in CP [Chapter : Protoplasm]
Exercise Sheet: [Chapter : Structural

Chargaff's principle is not applicable for RNA
organization of plant, Q.No. 137, Page no. 66]
as purine is not equal to pyrimidine.
Q.121 Doctors use stethoscope to hear the sounds Ans. [2]

produced during each cardiac cycle. The
second sound is heard when :
(1) AV node receives signal from SA node Population & Community, Ex. 1, Q.No. 78]
(2) AV valves open up
Succession is gradual & Predictable change in
(3) Ventricular walls vibrate due to species composition occurs in a area.
gushing in of blood from atria
(4) Semilunar valves close down after the Q.123 In the following human pedigree, the filled
blood flows into vessels from ventricles symbols represent the affected individuals.
Identify the type of given pedigree.
Ans. [4]
(I)
physiology-II, Page no. 104 (II)
Closure of Bicuspid & tricuspid valve (III)

produces first heart sound (lubb) while of
semilunar valve produces second heart sound (IV)
(Dup).
(1) X-linked dominant
(2) Autosomal dominant

Q.122 During ecological succession :
(3) X-linked recessive
(1) the changes lead to a ommunity that is
in near equilibrium with the (4) Autosomal recessive
environment and is called pioneer
Ans. [4]
community
(2) the gradual and predictable change in
Exercise Sheet: Genetics, Page no. 63]
species composition occurs in a given
area Autosomal recessive.
Offspring is affected but parent are not
(3) the establishment of a new biotic affected is characteristic of autosomal
community is very fast in its primary recessive.
phase.
(4) the numbers and types of animals

remain constant.
Q.124 Balbiani rings are sites of : Q.126 Which of the following are most suitable
indicators of SO2 pollution in the
(1) RNA and protein synthesis
environment?
(2) Lipid synthesis
(1) Fungi (2) Lichens
(3) Nucleotide synthesis
(3) Conifers (4) Algae
(4) Polysaccharide synthesis
Ans. [2]
Ans. [1]
Sol. Students may find it in CP Sheet: [Chapter
: Cell biology, Page no. 43]
Environmental issues, Ex. 1, Q.No. 19]
Balbiani ring are present in polytene
Lichens are SO2 Pollution indicators or they
chromosome & it is the site of RNA &
do not grow in SO2 Polluted habitat.
protein synthesis.
Q.127 Satellite DNA is important because it :

Q.125 Name the pulmonary disease in which
(1) codes for enzymes needed for DNA
alveolar surface area involvedin gas
replication.
exchange is drastically reduced due to
damage in the alveolar walls. (2) codes for proteins needed in cell cycle.
(1) Asthma (3) Shows high degree of polymorphism in

population and also the same degree of
(2) Pleurisy
polymorphism in an individual, which
(3) Emphysema
is heritable from parents to children.
(4) Pneumonia
(4) does not code for proteins and is same
Ans. [3] in all members of the population.
Sol. Students may find it in CP Sheet: Animal Ans. [3]

Emphysema is pulmonary disease caused by
air pollutant causes break down of alveolar
wall so reduces surface area of gaseous V.N.T.R. or satellite DNA show high degree
exchange. of polymorphism is basis of DNA test.
Q.128 Industrial melanism is an example of - Q.130 The introduction of t-DNA into plants
involves -
(1) Neo Lamarckism
(1) Allowing the plant roots to stand in
(2) Neo Darwinism
water
(3) Natural selection
(2) Infection of the plant by Agrobacterium
(4) Mutation
tumefaciens
Ans. [3]
(3) Altering the pH of the soil, then heat-
Sol. Students may find it in CP Sheet: Origin & shocking the plants
Evolution of life, Page no. 32
(4) Exposing the plants to cold for a brief
Industrial melanism shows natural selection.
period
Ans. [2]
Q.129 A column of water within xylem vessels of
tall trees does not break under its weight
Sheet: Genetics, Page no. 47
because of -
Agrobacterium tumefaciens bacteria contain
(1) Positive root pressure
t-DNA (transfer DNA)
(2) Dissolved sugars in water In its Ti plasmid (Tumor inducing plasmid)
(3) Tensile strength of water This bacterium transfers this t-DNA fragment
into host plant nuclear genome during
(4) Lignification of xylem vessels
infection.
Ans. [3]
Sol. Students may find similar question in CP Q.131 Pick up the wrong statement :
Exercise Sheet: Plant Physiology [Chapter
(1) Nuclear membrane is present in
: Plant water relation theory, Page no. 196]
Monera
High Tensile strength of water, helps in
(2) Cell wall is absent in Animalia
prevention of breakage of water column
within xylem vessels of high tree. (3) Protista have photosynthetic and
heterophic modes of nutrition
(4) Some fungi are edible
Ans. [1]
Sol. Students may find this in CP Sheet: Q.134 Which of the following pairs is not
[Chapter : Plant diversity, Page no. 23] correctly matched?
Monera (Prokaryotes) do not have well Mode of reproduction Example

defined nucleus as they lack nuclear
(1) Conidia Penicillium
membrane and nucleolus.
(2) Offset Water hyacinth
Q.132 In photosynthesis, the light-independent (3) Rhizome Banana

reactions take place at :
(4) Binary fission Sargassum
(1) Stromal matrix (2) Thylakoid lumen
Ans. [4]
(3) Photosystem I (4) Photosystem II Sol. Students may find this in CP Sheet:
Ans. [1] [Chapter : Plant diversity, Page no. 102]
Sol. Students may find similar question in CP Binary fission occurs in unicellular organisms
Exercise Sheet: Plant Physiology [Chapter whereas sargassum is multicellular brown

algae.
: Photosynthesis theory, Page no. 16]
The light independent reaction or dark

reaction occurs in stromal matrix of Q.135 The UN conference of Parties on climate
chloroplast. change in the year 2012 was held at :
(1) Warsaw
Q.133 Which of the following immunoglobulins
(2) Durban
does constitute the largest percentage in
(3) Doha
human milk?
(4) Lima
(1) IgG (2) IgD
Ans. [3]
(3) IgM (4) IgA
Sol. UN Conference of Parties (COP) 2012 was
Ans. [4]
held at Qatar, Doha.
Exercise Sheet: Immunity and disease,
Page no. 125
IgA.

Q.136 In the spectrum of hydrogen, the ratio of the Sol. Students may find similar question in CP
longest wavelength in the Lyman series to the Exercise Sheet: [Chapter : Photo electric
longest wavelength in the Balmer series is : effect, Ex-2, Q.No. 28, Page no. 78]
E = 15 keV = 15 × 103 eV
5 4
(1) (2) 12400
27 9 Q E= eVÅ
λ
12400
9 27 λ= eVÅ
(3) (4) E
4 5
12400
λ = eV Å
Ans. [1] 15 × 103 eV
λ = .826 Å (λ < 0.01 Å)
Sol. Students may find similar question in : It is part of X-rays
[Chapter : Atomic structure, similar
question in CP minor test paper ]
Q.138 An electron moves on a straight line path
1 ⎛ 1 1 ⎞⎟
⎜ XY as shown. The abcd is a coil adjacent to
λ
= Rz2 ⎜ n2 − n2 ⎟
⎝ 1 2 ⎠
the path of electron. What will be the
Lyman series : n1 = 1, n2 = 2
1 ⎛1 1 ⎞ direction of current, if any, induced in the
= Rz2 ⎜ 2 − 2 ⎟ ...(1)
λ1 ⎝1 2 ⎠ coil ?
Balmer series :
n1 = 2, n2 = 3 a
1 ⎛ 1 1 ⎞
= Rz2 ⎜ 2 − 2 ⎟ ...(2) b d
λ2 ⎝ 2 3 ⎠
⎛1 1⎞ 5 c
Rz 2 ⎜ − ⎟
eq n (2) λ ⎝ 4 9 ⎠ = 36
⇒ 1 = X electron Y
n
eq (1) λ2 2⎛ 1⎞ 3
Rz ⎜1 − ⎟
⎝ 4⎠ 4 (1) No current induced
5 4 5
= × =
36 3 27 (2) abcd
(3) adcb
Q.137 The energy of the em waves is of the order of
(4) The current will reverse its direction as
15 keV. To which part of the spectrum does it
the electron goes past the coil
belong ?
Ans. [4]
(1) γ-rays (2) X-rays
(3) Infra - red rays (4) Ultraviolet rays Exercise Sheet: [Chapter : EMI,
Ans. [2] Ex-3B, Q.No. 47, Page no. 183]

When e– is coming towards the loop magnetic the same level, then the weights added to the
flux of one type increased and when going steel and brass wires must be in the ratio
away same magnetic flux decreased so of :
induced current opposite to each other.
(1) 1 :1 (2) 1 :2
(3) 2 :1 (4) 4 :1
Q.139 The cylindrical tube of a spray pump has
radius R, one end of which has n fine holes, Ans. [3]
each of radius r. If the speed of the liquid in Sol. Students may find similar question in CP
the tube is V, the speed of the ejection of the Exercise Sheet: [Chapter : Elasticity,
liquid through the holes is :
Ex-1B, Q.No. 42, Page no. 180]
V 2R VR 2 Ysteel = 2 Ybrass
(1) (2)
nr n 2r 2
Ls = Lb
VR 2 VR 2 As = Ab
(3) (4)
nr 2 n 3r 2 ΔLs = ΔLb
Ans. [3] F
stress WL
Y= = A =
Sol. Students may find similar question in CP : strain ΔL AΔL
[Class room notes] L
YAΔL
W= ∝Y
L
n.r
2R Ws Y
= s =2:1
Wb Yb
A1V1 = A2V2
Q.141 A potentiometer wire of length L and a
A1V1 πR 2 × V
⇒ V2 = =
A2 n (πr 2 ) resistance r are connected in series with a
battery of e.m.f. E0 and a resistance r1. An
R2
= 2 V
nr unknown e.m.f. E is balanced at a length l of
the potentiometer wire. The e.m.f. E will be

given by :
Q.140 The Young’s modulus of steel is twice that of
brass. Two wires of same length and of same LE 0 r LE 0 r
(1) (2)
(r + r1 )l lr1
area of cross section, one of steel and another
of brass are suspended from the same roof. If E0r l E 0l
(3) (4)
we want the lower ends of the wires to be at (r + r1 ) L L

Ans. [3] Maximum velocity

β = Aω ....(2)
Sol. Students may find similar question in CP n
Eq (1) α α 2π
⇒ =ω ⇒ =
Exercise Sheet: [Chapter : Current Eq n (2) β β T
electricity, Ex.-3B, Q.No. 113, Page no. β

T = 2π
α
219]
E0 r1 r
Q.143 If vectors A = cos ωt î + sinωt ĵ and
r ωt ωt
l P r B = cos î + sin ĵ are functions of
A 2 2
B
time, then the value of t at which they are
E orthogonal to each other is :
E0
Current in wire AB =
r1 + r π
(1) t = 0 (2) t =
⎛ E ⎞ r 4ω
Potential gradient = ⎜⎜ 0 ⎟⎟ .
⎝ r1 + r ⎠ L
π π
(3) t = (4) t =
⎛ E ⎞ r 2ω ω
∴ E = ⎜⎜ 0 ⎟⎟ ×l
⎝ r1 + r ⎠ L
Ans. [4]

Q.142 A particle is executing a simple harmonic
[CP Minor test paper ]
motion. Its maximum acceleration is α and
For perpendicular vectors
maximum velocity is β. Then, its time period → →
A . B=0
of vibration will be: ⎡ ωt ωt ⎤
⇒ [cos ωt î + sin ωt ĵ ] . ⎢cos î + sin ĵ = 0
⎣ 2 2 ⎥⎦
2πβ β2 ωt ωt
(1) (2) cos ωt cos + sin ωt sin =0
α α2 2 2
{Q cos A cos B + sin A sin B = cos (A – B)}
α β2 ⎛ ωt ⎞
(3) (4) ∴ cos ⎜ ωt − ⎟ = 0
β α
⎝ 2 ⎠
ωt
Ans. [1] ⇒ cos =0
2
ωt π
Sol. Students may find similar question in CP ⇒ =
2 2
Exercise Sheet: [Chapter : SHM, Ex-1,
π
⇒ t=
Q.No. 25, Page no. 242] ω
Maximum acceleration
α = Aω2 ....(1)

Q.144 A source of sound S emitting waves of ⎛ 330 ⎞

= 100 ⎜ ⎟
frequency 100 Hz and an observer O are ⎝ 330 − 9.7 ⎠
located at some distance from each other. The ⎛ 330 ⎞

= 100 ⎜ ⎟
⎝ 320.3 ⎠
source is moving with a speed of 19.4 ms–1 at
an angle of 60° with the source observer line = 103.02 Hz
as shown in the figure. The observer is at rest.
The apparent frequency observed by the

Q.145 An automobile moves on a road with a speed
observer (velocity of sound in air 330 ms–1),
of 54 km h–1. The radius of its wheels is 0.45
is :
m and the moment of inertia of the wheel
vs about its axis of rotation is 3 kg m2. If the
vehicle is brought to rest in 15s, the

60°
S O magnitude of average torque transmitted by
its brakes to the wheel is :

(1) 97 Hz (2) 100 Hz
(1) 2.86 kg m2 s–2 (2) 6.66 kg m2 s–2
(3) 103 Hz (4) 106 Hz
(3) 8.58 kg m2 s–2 (4) 10.86 kg m2 s–2
Ans. [3]
Ans. [2]
[Chapter : Doppler Effect, CP Classroom
Exercise Sheet: [Chapter : Rotation ,
notes]
Ex- 1, Q.No. 41, Page no. 141]
km
Vs sin 60º V = 54 = 15 m/s
Vs h
v 15 rad
ω0 = = , ω=0
60º r .45 s
S O
Vs cos 60º Doppler
ω = ω0 + αt
line
15
⎛ v ⎞ 0= + α15
n' = n ⎜⎜ ⎟
⎟
.45
⎝ v − v s cos 60º ⎠
15 1 rad
α=– =–
⎛ ⎞ .45 × 15 .45 s 2
⎜ 330 ⎟
= 100 ⎜ ⎟
⎜ 330 − 19.4 × 1 ⎟ 3 300
⎜ ⎟ τ = Iα = – =– = –6.66 kgm2/s2
⎝ 2⎠ .45 45

Q.146 A rectangular coil of length 0.12 m and width C2V 2 C2V 2

(1) (2)
0.1 m having 50 turns of wire is suspended 2d 2 2d
vertically in a uniform magnetic field of

CV 2 CV 2
(3) (4)
strength 0.2 Weber/m2. The coil carries a 2d d
current of 2A. If the plane of the coil is
Ans. [3]
inclined at an angle of 30° with the direction
Sol. Students may find similar question in CP:
of the field, the torque required to keep the
[Chapter : Capacitance, Classroom notes]
coil in stable equilibrium will be :
Force between plates
(1) 0.12 Nm (2) 0.15 Nm of capacitor
F = qE
(3) 0.20 Nm (4) 0.24 Nm ⎛ q ⎞
= q⎜⎜ ⎟
⎟
Ans. [3] ⎝ 2A ∈0 ⎠
q2
F=
Sol. Students may find similar question in CP 2A ∈0
∴ q = CV
Exercise Sheet: [Chapter : Magnetic field,
C2V 2
F=
Ex. -1, Q.No. 117, Page no. 70] 2A ∈0
⎛ A ∈0 ⎞ 2
⎜ ⎟CV
B F= ⎝ d ⎠
2A ∈0
30º CV 2
60º A F=
2d
τ = NAIB sin θ Q.148 Two vessels separately contain two ideal

= 50 × .012 × 2 × 0.2 × sin 60º
gases A and B at the same temperature, the
= 0.20 Nm
pressure of A being twice that of B. Under
such conditions, the density of A is found to
Q.147 A parallel plate air capacitor has capacity ‘C’, be 1.5 times the density of B. The ratio of
distance of separation between plates is ‘d’ molecular weight of A and B is :
and potential difference ‘V’ is applied
1 2
(1) (2)
between the plates. Force of attraction 2 3
between the plates of the parallel plate air
3
capacitor is : (3) (4) 2
4
Ans. [3]

[Chapter : KTG, Classroom notes] Exercise Sheet: [Chapter : Gravitation, CP
Minor Test ]
A B
Force on satellite is only gravitational force,
which will always be towards the centre of

T T earth
PA = 2PB PB
ρA = 1.5 ρB
MA
=?
MB Q.150 In the given figure, a diode D is connected to
P RT ρRT
Q = ⇒ M0 = an external resistance R = 100 Ω and an
ρ M0 P
R, T = const. e.m.f. of 3.5 V. If the barrier potential
ρ
M0 ∝ developed across the diode is 0.5V, the
P
M ρ P
⇒ A = A× B current in the circuit will be:
M B ρ B PA
= 1.5 ×
1 D 100 Ω
2
= 0.75 = 3/4 R
Q.149 A satellite S is moving in an elliptical orbit

3.5 V
around the earth. The mass of the satellite is
very small compared to the mass of the earth. (1) 35 mA (2) 30 mA
Then, (3) 40 mA (4) 20 mA
(1) the acceleration of S is always directed Ans. [2]

towards the centre of the earth.
(2) the angular momentum of S about the Exercise Sheet: [Chapter : Electronics,
centre of the earth changes in direction,
Solved Example, Page no. 179]
but its magnitude remains constant.
Vnet 3.5 − 0.5
i= =
(3) the total mechanical energy of S varies R net 100
periodically with time 3

= Amp.
100
(4) the linear momentum of S remains
= 30 mA
constant in magnitude.
Ans. [1]

Q.151 A remote – sensing satellite of earth revolves (1) Path of the particle is a circle of radius 4
in a circular orbit at a height of 0.25 × 106 m meter
above the surface of earth. If earth’s radius is r
(2) Acceleration vector is along – R .
6.38 × 106 m and g = 9.8 ms–2, then the
orbital speed of the satellite is : v2
(3) Magnitude of acceleration vector is ,
R
(1) 6.67 km s–1 (2) 7.76 km s–1
where v is the velocity of particle
(3) 8.56 km s–1 (4) 9.13 km s–1
(4) Magnitude of the velocity of particle is
Ans. [2] 8 meter/ second
Sol. Students may find similar question in CP Ans. [4]
Exercise Sheet: [Chapter : Gravitation ,

Ex-2, Q.No. 6, Page no. 208]
[Chapter : Motion in plane, Class room
notes]
r
GMm mv 2 R = 4 sin(2πt )î + 4 cos(2πt ) ĵ
= r=R+h
r2 r
x = 4 sin 2πt ….(1)
GM GMR 2 g
v= = = R
r R 2r r y = 4 cos 2πt …(2)
⎛ 9.8 ⎞
v= ⎜ ⎟ × 6.38 × 10 6 (1) x2 + y2 = 42 (sin2 2πt + cos2 2πt)
⎜ 6 ⎟
.25 × 10 + 6.38 × 10 ⎠
6
⎝
x2 + y2 = 42 equation of circle and radius 4m
1.47
= × 6.38 × 10 6
10 6 .
3
= 7.76 × 10 m/s = 7.76 km/s r V2
(2) a = (−R̂ )
r R
Q.152 The position vector of a particle R as a
function of time is given by : V2
(3) a =
R
r
R = 4 sin(2πt) î + 4cos(2πt) ĵ (4) Vx = + 4(cos 2πt) (2π)
and Vy = – 4(sin 2πt) (2π)

Where R is in meters, t is in seconds and î
Vx2 + Vx
2
V=
and ĵ denote unit vectors along x-and y-
directions, respectively. Which one of the = (8π) 2 (cos 2 2πt + sin 2 2πt )
following statements is wrong for the motion
V = 8π
of particle ?
so 4th option is incorrect.

Q.153 A string is stretched between fixed points ω0

separated by 75.0 cm. It is observed to have
resonant frequencies of 420 Hz and 315 Hz. m1 P m2
There are no other resonant frequencies x (L – x)

between these two. The lowest resonant
frequency for this string is :

m2L m1L
(1) x = (2) x =
(1) 105 Hz (2) 155 Hz m1 + m 2 m1 + m 2
(3) 205 Hz (4) 10.5 Hz m1 m2

(3) x = L (4) x = L
m2 m1
Ans. [1]
Ans. [1]
Exercise Sheet: [Chapter : Wave theory, [Chapter : Rotation, classroom notes]
Ex-1, Q.No. 98, Page no. 41] I = m1x2 + m2(L – x)2
I = m1x2 + m2L2 + m2x2 – 2m2Lx
315 : 420 = 3 : 4 dI
= 2m1x + 0 + 2xm2 – 2m2L = 0
rd
315 Hz is a 3 harmonic of wire and 420 Hz dx
x(2m1 + 2m2) = 2m2L
is a 4th harmonic.
m2L
If 315 is a 3rd harmonic then 3n fundamental = 315 x=
m1 + m 2
315
n fundamental = = 105Hz 1
3 When I is minimum, work done W = Iω02
2
will also be minimum.
Q.154 Point masses m1 and m2 are placed at the
opposite ends of a rigid rod of length L and Q.155 At the first minimum adjacent to the central
maximum of a single-slit diffraction pattern,
negligible mass. The rod is to be set rotating
the phase difference between the Huygen’s
about an axis perpendicular to it. The
wavelet from the edge of the slit and the
position of point P on this rod through which wavelet from the midpoint of the slit is :
the axis should pass so that the work required π π
(1) radian (2) radian
to set the rod rotating with angular velocity 8 4
ω0 is minimum, is given by : π
(3) radian (4) π radian
2
Ans. [4]

Sol. Students may find similar question in CP ⇒ 0 î – 12(1 + α) ĵ + 6(1 + α) k̂ = 0

[Chapter : Wave optics, Classroom notes]
–12(1 + α) = 0
α = –1
A
B λ/2
Q.157 Two particles A and B, move with constant

C Δ=λ r r
velocities v1 and v 2 . At the initial moment
r r
For first minima path difference between A their position vectors are r1 and r2
and C is λ so path difference between A and respectively. The condition for particles A
B should be λ/2 and phase difference π and B for their collision is :
r r r r
(1) r1 – r2 = v1 – v 2
r r r r r
Q.156 A force F = α î + 3 ĵ + 6k̂ is acting at a point r –r v –v
(2) r1 r2 = r 2 r1
r r1 – r2 v 2 – v1
r = 2î − 6 ĵ − 12k̂ . The value of α for which
r r r r
angular momentum about origin is conserved (3) r1 ⋅ v1 = r2 ⋅ v 2
is : r r r r
(4) r1 × v1 = r2 × v 2
(1) 1 (2) –1
Ans. [2]
(3) 2 (4) zero
Ans. [2]
[Chapter : Vector, Classroom notes]
Exercise Sheet: [Chapter : Rotation, r
v1t
Solved Example 13, Page no. 134]
r
r v2t
Angular momentum r R
r1
r
L = constant
r
r r2
⇒ Torque τ = 0
r r r r r
r r R = r1 + v1t = r2 + v 2 t
⇒ r × F =0
r r r r
r1 − r2 = ( v 2 − v1 ) t
î ĵ k̂
2 − 6 − 12 = 0 r r r r
r1 − r2 ( v 2 − v1 ) t
α 3 6 r r = r r
| r1 − r2 | | v 2 − v1 | t
r r r r
r1 − r2 v 2 − v1
⇒ (–36 + 36) î – (12 + 12α) ĵ + (6 + 6α) k̂ =0 r r = r r
| r1 − r2 | | v 2 − v1 |

σ1σ 2 2 σ1σ 2
(1) (2)
Q.158 A nucleus of uranium decays at rest into σ1 + σ 2 σ1 + σ 2
nuclei of thorium and helium. Then : σ1 + σ 2 σ1 + σ 2

(3) (4)
2 σ1σ 2 σ1σ 2
(1) The helium nucleus has less kinetic
energy than the thorium nucleus Ans. [2]
(2) The helium nucleus has more kinetic Sol. Students may find similar question in CP
energy than the thorium nucleus [Chapter : Current Electricity, Classroom
(3) The helium nucleus has less momentum notes]
than the thorium nucleus

L L
(4) The helium nucleus has more momentum A
ρ1 ρ2
than the thorium nucleus. Req = R1 + R2
2L L L
Ans. [2] ρ = ρ1 + ρ2
A A A
Sol. Students may find similar question in CP 2ρ = ρ1 + ρ2
Exercise Sheet: [Chapter : Nuclear 2 1 1
= +
Physics, Ex-2, Q.No. 158, Page no. 17] σ σ1 σ 2
238
→ 90Th234 + 2He4 2 σ1 + σ 2
92U =
σ σ1σ 2
Momentum conservation
r r
⇒ | p Th | = | p He | = p 2σ1σ 2
σ=
σ1 + σ 2
p2
Kinetic energy K =
2m
Q.160 Light of wavelength 500 nm is incident on a
1
K∝ metal with work function 2.28 eV. The de
m
Broglie wavelength of the emitted electron is
mHe < mTh
⇒ KHe > KTh :
(1) ≤ 2.8 × 10–12 m
Q.159 Two metal wires of identical dimensions are (2) < 2.8 × 10–10 m
connected in series. If σ1 and σ2 are the
(3) < 2.8 × 10–9m
conductivities of the metal wires respectively,
(4) ≥ 2.8 × 10–9m
the effective conductivity of the combination
is : Ans. [4]

Sol. Students may find similar question in CP vsound = 952 m/sec

[Chapter : P.E.E., , Classroom notes] CP = ?
1240 γPV
EPh = eV = 2.48 eV vsound =
500 M
K.Emax = EPh – W M 2 C
γ= Vsound = P
= 2.48 – 2.28 PV CV
= 0.2 eV ⎛ M⎞ 2
CP = CV ⎜ ⎟ v sound
* λe min =
12.27
Å ⎝ PV ⎠
K.E max (eV)
⎡ 4 × 10 −3 ⎤
= 5⎢ −5 −3 ⎥
(952)2
=
12.27
Å ⎣ 10 × 22 .4 × 10 ⎦
0.2
20
= 27.436 Å = × (952)2 × 10–5
22.4
= 27.436 × 10–10 m = 809, 200 × 10–5 = 8.09 J/moles k
λmin. = 2.7436 × 10 m –9
λ ≥ λmin
Q.162 A series R-C circuit is connected to an
alternating voltage source. Consider two
Q.161 4.0 g of a gas occupies 22.4 liters at NTP. situations:
The specific heat capacity of the gas at
(a) When capacitor is air filled.
constant volume is 5.0 JK–1 mol–1. If the
speed of sound in this gas at NTP is 952 ms–1, (b) When capacitor is mica filled.
then the heat capacity at constant pressure is Current through resistor is i and voltage
(Take gas constant R = 8.3 JK–1 mol–1) across capacitor is V then :
(1) 8.5 JK–1mol–1 (1) Va = Vb
(2) 8.0 JK–1 mol–1 (2) Va < Vb
(3) 7.5 JK–1 mol–1 (3) Va > Vb
(4) 7.0 JK–1 mol–1 (4) ia > ib
Ans. [1] Ans. [3]
Exercise Sheet: [Chapter : KTG, Solved [Chapter : AC, Classroom notes]
Example 9, Page no. 123]
M = 4 gm
R C
V = 22.4 litre
J
CV = 5
mole K ~
V = V0 sin ωt

1 Ans. [3]
XC =
2πfC
current in circuit
[Chapter : Friction, classroom notes]
V V
I= =
Z 1
μs = tan30º = = 0.57 ≈ 0.6
2
⎛ 1 ⎞
R2 + ⎜ ⎟ 3
⎝ 2πfC ⎠
1 2
2πfC S = ut + at
or I = ×V 2
4π 2 f 2 C 2 R 2 + 1
1
Voltage drop across capacitor 4=0+ (gsin30º – μkcos 30º)(4)2
2
VC = I × XC
1 3
2πfC × V 1 0.5 = 10 × – μk 10 ×
= × 2 2
4π 2 f 2 C 2 R 2 + 1 2πfC
5 3μ k = 4.5
V
VC =
4π 2 f 2 C 2 R 2 + 1 μk = 0.51
When mica is introduced capacitance will Q.164 Two stones of masses m and 2 m are whirled
increase, hence voltage across capacitor gets in horizontal circles, the heavier one in a
decrease. r
radius and lighter one in radius r. The
2
Q.163 A plank with a box on it at one end is
tangential speed of lighter stone is n times
gradually raised about the other end. As the
that of the value of heavier stone when they
angle of inclination with the horizontal
experience same centripetal forces. The value
reaches 30°, the box starts to slip and slides
of n is :
4.0 m down the plank in 4.0 s. The
coefficients of static and kinetic friction (1) 1 (2) 2
between the box and the plank will be, (3) 3 (4) 4
respectively :
Ans. [2]

[Chapter : Circular Motion, Minor Test]
mg
θ
v2
(1) 0.4 and 0.3 r/2
2m
(2) 0.6 and 0.6 r
m v1
(3) 0.6 and 0.5
Equal centripetal force
(4) 0.5 and 0.6

mv12 (2m) v 22 Q.166 An ideal gas is compressed to half its initial

=
r r/2 volume by means of several processes. Which
⇒ v12 = 4v 22 of the process results in the maximum work

done on the gas ?
⇒ v1 = 2v2
(1) Isothermal (2) Adiabatic
(3) Isobaric (4) Isochoric

Q.165 The coefficient of performance of a
refrigerator is 5. If the temperature inside Ans. [2]
freezer is –20°C, the temperature of the
surroundings to which it rejects heat is :
[Chapter Thermodynamics, Classroom
(1) 21°C (2) 31°C notes]
(3) 41°C (4) 11°C

V1 → V1/2
Ans. [2]

adiabatic
[Chapter : Thermodynamics, Classroom
isothermal
notes]
α=5 T2 = – 20ºC
isobaric
= – 20 + 273
T2 = 253K V1/2 V1
T1 = ? Work done = area under curve
T2
α = Wadiabatic > Wisothermal > Wisobaric
T1 − T2
Q.167 A ball is thrown vertically downwards from a
253
⇒5= height of 20 m with an initial velocity v0. It
T1 − 253
collides with the ground, loses 50 percent of
⇒ 5T1 – 1265 = 253
its energy in collision and rebounds to the
1518
T1 = = 303.6K same height. The initial velocity v0 is :
5
= 30.6ºC ≈ 31ºC (Take g = 10 ms– 2)
T1 = temp. of surrounding
(1) 10 ms–1 (2) 14 ms–1
T2 = temp. of source (inside temp.)
(3) 20 ms–1 (4) 28 ms–1
Ans. [3]

Sol. Students may find similar question in CP Using conservation of K.E

[Chapter : Work, power, energy, 2
1 1 ⎛v⎞ 1
Classroom notes] Mv2 + 0 = M ⎜ ⎟ + Mv 22
2 2 ⎝3⎠ 2
⎛ 1 ⎞
0. 5⎜ mgh + mv2 ⎟ = mgh v2
⎝ 2 ⎠ v2 = + v 22
9
0.25mv2 = 0.5mgh
v= 2gh 8v 2
v 22 =
9
= 2 × 10 × 20 = 400 = 20 m/s
2 2v
v2 =
3
Q.168 On a frictionless surface, a block of mass M
moving at speed v collides elastically with
another block of same mass M which is Q.169 If potential(in volts) in a region is expressed
initially at rest. After collision the first block as V (x, y, z) = 6xy – y + 2yz, the electric
moves at an angle θ to its initial direction field (in N/C) at point (1, 1, 0) is :
and has a speed

v
3
. The second block‘s speed (
(1) – 6î + 9 ĵ + k̂ ) (
(2) – 3î + 5 ĵ + 3k̂ )
after the collision is : (
(3) – 6î + 5 ĵ + 2k̂ ) (
(4) – 2î + 3 ĵ + k̂ )
3 2 2 Ans. [3]
(1) v (2) v
2 3
3 3
(3) v (4) v Exercise Sheet: [Chapter : Electrostatics,
4 2
Ex-3A, Q.No. 26, Page no. 56]
Ans. [2]
V = 6xy – y + 2yz
∂V ∂ V ∂V
E= − î – ĵ – k̂
Exercise Sheet: [Chapter : Work, power, ∂x ∂y ∂z
energy , Ex-3B, Q.No. 9, Page no. 101]
E = – 6 yî – (6x – 1) ĵ – 2 yk̂
v/3
M At (1, 1, 0)
M →v M → u2 = 0 ≡ θ
E = – 6î – 5 ĵ – 2k̂
M E = – (6î + 5 ĵ + 2k̂ )
v2

Q.170 Two slits in Youngs experiment have widths Sol. Students may find similar question in CP
in the ratio 1 : 25. The ratio of intensity at the Exercise Sheet: [Chapter : Fluid
maxima and minima in the interference Mechanics, Ex-1A, Q.No. 4, Page no. 215]
I max W mgh V
pattern,
I min
is : P= = = ρgh
t t t
5 × 10 −3
(1)
4
(2)
9 = × 13.6 × 103 × 10 × 150 × 10–3
9 4 60
5 × 13.6 × 150
= × 10–3
121 49 6
(3) (4)
49 121 = 1700 × 10–3
Ans. [2] P = 1.7 Watt

Exercise Sheet: [Chapter : Wave Optics , Q.172 A proton and an alpha particle both enter a
Ex-1B , Q.No. 2, Page no.89] region of uniform magnetic field B, moving
2
at right angles to the field B. If the radius of
⎛ I1 ⎞
⎜ +1 ⎟ circular orbits for both the particles is equal
I max ⎜ I ⎟
=⎜ 2 ⎟
I min and the kinetic energy acquired by proton is
⎜ I1 − 1 ⎟
⎜ I ⎟
⎝ 2 ⎠ 1MeV, the energy acquired by alpha particle
will be :
2
⎛ 1 ⎞
⎜ +1 ⎟ (1) 1 MeV
= ⎜⎜ ⎟ = 36 = 9
25
1 ⎟ 16 4 (2) 4 MeV
⎜⎜ − 1 ⎟⎟
⎝ 25 ⎠
(3) 0.5 MeV
(4) 1.5 MeV

Q.171 The heart of a man pumps 5 liters of blood
through the arteries per minute at a pressure Ans. [1]
of 150 mm of mercury. If the density of
mercury be 13.6 × 103 kg/m3 and
Exercise Sheet: [Chapter : Magnetic field,
g = 10 m/s2, then the power of heart in
Solved example 19 Page no. 35]
watt is :
Radius in magnetic field
(1) 1.50 (2) 1.70 mv 2mE
R= =
qB qB
(3) 2.35 (4) 3.0
Ans. [2]

q 2 B2 R 2 V0 = Av × VI = 300
E=
2m Vouput = 300 cos (15t + π/3 + π)
For proton Vouput = 300 cos (15t + 4π/3)
e ×B ×R
2 2 2
E1 =
2 × mp
Q.174 If dimensions of critical velocity vc of a
for α-particle
liquid flowing through a tube are expressed as
( 2e ) × B × R
2 2 2
E2 = [ηx ρy rz] , where η, ρ and r are the
2 × 4m p
coefficient of viscosity of liquid, density of
∴ E1 = E2 liquid and radius of the tube respectively,
then the values of x, y, and z are given by :
Q.173 The input signal given to a CE amplifier (1) 1, 1, 1
having a voltage gain of 150 is (2) 1, –1, –1
⎛ π⎞
Vi = 2 cos ⎜15t + ⎟ . The corresponding (3) –1, –1, 1
⎝ 3⎠
(4) –1, –1, –1
output signal will be :
⎛ 4π ⎞
(1) 300 cos ⎜15 t + ⎟ Ans. [2]
⎝ 3 ⎠
⎛ π⎞
(2) 300 cos ⎜15 t + ⎟ Exercise Sheet: [Chapter : Unit &
⎝ 3⎠
Dimensions, Ex-2, Q.No. 42, Page no. 24]
⎛ 2π ⎞
(3) 75 cos ⎜15 t + ⎟ Vc = ηxρyrz
⎝ 3 ⎠
M0L1T–1 = (M1L–1T–1)x (M1L–3)y (L1)z
⎛ 5π ⎞ M0L1T–1 = Mx+y L–x–3y +z T–x

(4) 2 cos ⎜15 t + ⎟
⎝ 6 ⎠ –x = – 1
x=1 ... (1)
Ans. [1]
x+y=0=0
Sol. Students may find similar question in CP y=–x =–1 ...... (2)
Exercise Sheet: [Chapter : Electronics, –x –3y + z = 1
Q.No. 30, Page no. 191] –1 – 3(–1) + z = 1
z=–1
Vi = 2 cos (15t + π/3)
V0
Av =
VI

Q.175 A circuit contains an ammeter, a battery of 30 Q.176 Water rises to a height ‘h’ in capillary tube. If
V and a resistance 40.8 ohm all connected in the length of capillary tube above the surface
series. If the ammeter has a coil of resistance of water is made less than ‘h’, then :
480 ohm and a shunt of
(1) Water does not rise at all.
20 ohm, the reading in the ammeter will be :
(2) water rises upto the tip of capillary tube
(1) 1 A
and then starts overflowing like a
(2) 0.5 A fountain.
(3) 0.25 A (3) water rises upto the top of capillary tube
and stays there without overflowing.
(4) 2 A
(4) water rises upto a point a little below the
Ans. [2]
top and stays there
Ans. [3]
[Chapter : Current electricity, Classroom
notes] Sol. Students may find similar question in CP
[Chapter : Surface tension, Classroom
RS =20Ω notes]
40.8 Ω Height of water column > length of tube

RA =480 Ω ⇒ so liquid will be stay there
I
30 V Q.177 In an astronomical telescope in normal

adjustment a straight black line of length L is
480 × 20
Req = 40.8 +
500 drawn on inside part of objective lens. The
= 40.8 + 19.2 eye-piece forms a real image of this line. The
= 60 Ω length of the image is I. The magnification of
30 the telescope is :
I= = 0.5 amp
60
So reading of ammeter = 0.5 amp L L
(1) (2) +1
I I
L L+I
(3) –1 (4)
I L–I
Ans. [1]

Sol. Students may find similar question in CP ρ = ρ0 (1 + YΔT)

[Chapter : Optical Instrument, Classroom
ρ – ρ0 = ρ0 Y ΔT
notes]
fractional change
fO + fe
ρ − ρ0
= YΔT = 5 × 10–4 × 40
ρ0
= 200 × 10–4 = 0.020

fe
fO
Q.179 A photoelectric surface is illuminated
For eye – piece lens
successively by monochromatic light of
f h
m= = I λ
f + u hO wavelength λ and . If the maximum
2
fe I
⇒ = kinetic energy of the emitted photoelectrons
f e + [− (f O + f e )] L
in the seconds case is 3 times that in the first
fe I
⇒– = case, the work function of the surface of the
fO L
material is :
fO L
⇒ =– = m.p. (h = Planck’s constant, c = speed of light)
fe l
hc hc
(1) (2)
(–) sign stands for inverted image 3λ 2λ
hc 2hc
(3) (4)
λ λ
Q.178 The value of coefficient of volume expansion
Ans. [2]
of glycerin is 5 × 10–4 K–1. The fractional
change in the density of glycerin for a rise of
Exercise Sheet: [Chapter : P.E.E , Ex-1,
40°C in its temperature, is : Q.No. 34, Page no. 75]
(1) 0.010 (2) 0.015 kmax = E – φ
hc
(3) 0.020 (4) 0.025 k= –φ ... (1)
λ
Ans. [3] hc
3k = –φ .... (2)
( λ / 2)
[Chapter : Thermal Expansion, CP Major On solving
Paper] hc
φ=
2λ

Q.180 A beam of light consisting of red, green and Hence green and Blue colour will
blue colors is incident on a right angled
not emerge out
prism. The refractive index of the material of
the prism for the above red, green and blue
wavelengths are 1.39, 1.44 and 1.47,
respectively.
Blue
Green
Red
B 45° C
The prism will :
(1) separate the red colour part from the

green and blue colours
(2) separate the blue colour part from the red

and green colours
(3) separate all the three colours from one

another
(4) not separate the three colours at all
Ans. [1]

[Chapter : Ray Optics, Classrooms Notes]
i = 45°
∴ for no emergence
i>C
sin i > sin C
1
sin i >
µ
1 1
>
2 µ
µ> 2

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CAREER POINT [ CODE – A ]

Q.1 2,3-Dimethyl-2-butene can be prepared by Ans. [1]

(2) (CH3)2CH–CH2–CH=CH2 64Gd ⇒ [Xe] 4f75d16s2

CH3 CH3 O(g) + e– → O–(g), ∆fHΘ = –141 kJ mol–1

CH3 CH3 Thus process of formation of O2– in gas

(3) [Xe] 4f86d2 (4) [Xe] 4f95s1 Ans. [3]

(Isomerism), Ex.(7B), Q.No.23, Page no. 79]

current ? (1) MgCO3 (2) CaCO3

(1) Ammonia, NH3 (3) K2CO3 (4) Na2CO3

(3) Nylon - 6 (4) Teflon

NH (3) Presence of one –OH group and two

Caprolactum Nylon-6 Ans. [3]

(3) 18 molecules of water

Q.11 Decreasing order of stability of O 2 , O −2 , O +2 (4) 1.8 gram of water

18 g H2O is 1 mol H2O

1.8 g H2O has 0.1 mol H2O

Stability ∝ bond order

Q.13 In which of the following pairs, both the

( π2px 2 = π2py 2 ) (π∗2px1 = π*2py1) (1) NH3, PH3

(2) XeF4, XeO4

6−4 (4) diamond, silicon carbide

XeF4 XeO4 require the least amount of acidified

Square planar tetrahedral Sol. Students may find similar question in CP

methylcyclohexane. The possible alkene is : let number of reacting moles of FeC2O4 = x

Sol. Students may find similar question in CP Cl2O7 H

OH OH ONF and O2N– are isoelectronic because both

(1) Tricyanoferrate (III) ion

Q.18 Which of the statements given below is x – 6 = –3

(3) Nucleophile is a Lewis acid So nb term is neglected.

(4) Ammonia is a nucleophile Hence from equation (1) PV = nRT

Q.23 Hybridization involved in complex the C + O2 → CO2 ; ∆H = – 393.3 kJ/mol

Sol. Students may find similar question in CP

28Ni = [Ar] 3d84s2 Ans. [2]

Ni+2 =[Ar] 3d8 Sol. Students may find similar question in CP

XA 1000 Q.29 Two possible stero-structuers of

(1) Enantiomers (2) Mesomers

56.5 XA = 1 (3) Diastereomers (4) Atropisomers

Q.27 The correct statement regarding defects in H * OH & HO * H

(3) Schottky defects have no effect on the

Ga, In and Tl in creases in the sequence -

Sol. Students may find similar question in CP Ans. [2]

NH–C (2) sodium hydrogen sulphite

(4) hydrazine in presence of feebly acidic

O Q.35 The rate constant of the reaction A → B is

(1) 100% retention Zero order reaction

(2) 100% inversion x = kt

Sol. Not 100% recemisation After 20 min. 5 – x x

(1) 7.0 (2) 1.04

Sol. Students may find similar question in CP

Let volume of each solution is V. Cl

Net Equivalent = 0.1V – 0.01V

Sol. Students may find similar question in CP HF molecule

Q.40 The oxidation of benzene by V2O5 in the

Boiling point of HF is maximum because HF (2) benzaldehyde

Bpt. HF > HI > HBr > HCl Ans. [4]

(3) 28g (4) 3.5 g

Ans. [1] Q.41 Which of the following is not the product of

AgNO3 + NaCl →AgCl↓ + NaNO3

0.99M × 50 0.99 × 50 Ans. [4]

∴ moles of AgCl formed = 0.05

Ans. [2] Ans. [1]

Sol. Sol. Students may find similar question in CP

O Ti [22], [Ar] 3d24s2