ASPIRE GROUP OF COLLEGES

Paper: Chemistry Send up Examination 2018 Class: Inter-I(Regular)

Marks: 17 OBJECTIVE TYPE Time: 20 Minutes
Name: _______________________ Group-I Paper Code 6 0 4 8

Q.1: Four possible answers A, B, C and D to each question are given. The choice which you think is
correct, fill that circle in front of that question with marker or pen ink in the answer book. Cutting or
filling two or more circles will result in zero mark in that question.
i. The number of moles of CO2 which contain 8.0g of oxygen:
(a) 0.25 (b) 0.50 (c) 1.0 (d) 1.50

ii. 27g of Al will react completely with how much mass of O2 to produce AL2O3:
(a) 8g of oxygen (b) 16g of oxygen (c) 32g of oxygen (d) 24g of oxygen

iii. The volume occupied by 1.4g of N2 at S.T.P is:

(a) 2.24dm3 (b) 22.4dm3 (c) 1.12dm3 (d) 112cm3

iv. The molar volume of the CO2 is maximum at:

(a) STP (b) 1270C and 1atm (c) 0oC and 2atm (d) 273oC and 2atm

v. The deviation of a gas from ideal behavior is maximum at:

(a)-10oC and 5atm (b) ) -10oC and 2atm (c) ) 100oC and 2atm (d) 0oC and 2atm

vi. Geometry of diamond is:

(a) Tetragonal (b) Cubic (c) Rhombohedral (d) None of these

vii. The molecules of CO2 in dry ice form the :

(a) Ionic crystals (b) Covalent crystals (c) Molecular crystals (d) Any type of crystals

viii. Which of the following is a pseudo solid?:

(a)CaF2 (b) Glass (c) NaCl (d) All

ix. The nature of the positive rays depends on:

(a) The nature of the electrode (b) The nature of discharge tube
(c) The nature of the residual gas (d) All of the above
 x. Splitting of spectral lines when atoms are subjected to strong electric field is called:
(a) Stark affect (b) Zeeman effect
(c) Photoelectric effect (d) Compton Effect

xi. When 6d orbital is completed, the entering electron goes into:

(a) 7f (b) 7s (c) 7d (d) 7p

xii. Solvent extraction is an equilibrium process and it is controlled by:

(a) Law of mass action (b) The amount of solvent used
(c) Distribution law (d) The amount of solute

xiii. The comparative rates at which the solutes move in paper chromatography depend on:
(a) The size of paper (b) Rf values of solutes
(c) Temperature of the experiment (d) Size of chromatographic tank

xiv. A real gas obeying van der Waals equation will resemble ideal gas if:
(a) Both ‘a’ and ‘b’ are large (b) Both ‘a’ and ‘b’ are small
(c) ‘a’ is small and ‘b’ is large (d) ‘a’ is large and ‘b’ is small

xv. Acetone and chloroform are soluble in each other due to:
(a) Intermolecular hydrogen bonding (b) Ion dipole interaction
(c) Instantaneous dipole (d) All of these

xvi. When water freezes at 0oC its density decreases due to:
(a) Cubic structure of ice (b) Empty spaces present in the structure
(c) Change of bond length (d) Change of bond angles

xvii. Ionic solids are characterized by:

(a) Low melting points. (b) Good conductivity in solid state
(c) High vapor pressure (d) Solubility in polar solvent
 ASPIRE GROUP OF COLLEGES
Paper: CHEMISTRY Send up Examination 2018 Class: Inter-I(Regular)
Marks: 68 SUBJECTIVE TYPE GROUP-I Time: 2:40Mint
Name: ____________________ Roll #:_______________ SECTION:__________

SECTION-1
Q.No.2: Write short answers to any EIGHT (8) questions: (8×2=16)
i. Define molecular ion. How it is formed?
ii. N2 and CO have same number of electrons, protons and neutrons. Justify.
iii. What are isotopes? Give example.
iv. Mg atom is twice heavier then carbon atom. Justify.
v. What is retardation factor (Rf)?
vi. State distribution law.
vii. What is chromatography? Give uses of chromatography?
viii. Derive the units for gas constant R in general gas equation when pressure is in Nm-2
and volume in m3.
ix. How does kinetic molecular theory of gases explain Avogadro’s law?
x. What are the physical significances of van der Waals constant ‘a’ and ‘b’?
xi. Define critical temperature.
xii. What is Joule Thomsan effect?

Q. No 3: Write short answers to any EIGHT (8) questions. (8×2=16)

i. 23g of sodium and 238g of uranium have equal number of atom in them.
ii. What is stoichiometry? Give its assumptions.
iii. What is neutrino?
iv. Calculate percentage of nitrogen in NH3.
v. What is Sublimation?
vi. Calculate the moles of O atom in 9.00g of Mg(NO3)2.
vii. Difference between Gooch crucible and sintered crucible.
viii. Give three properties of gases.
ix. What is Charles’s law?
x. Water and ethanol are mix easily and in all proportions. Why?
xi. Water vapors do not behave ideally at 273K.
xii. What is Boyle’s law of gases?

Q. No 4: Write short answers to any SIX (6) questions. (6×2=12)

i. Evaporation causes cooling. Give reason.

ii. Earthen vessels keep water cool. Reason?
iii. In a very cold winter the fish in garden ponds owe their lives to hydrogen bonding.
iv. Sodium is softer then copper but both are very good electrical conductors.
 v. Diamond is harder and an electrical insulator. Why?
vi. What is difference between polymorphism and anisotropy?
vii. What are covalent solids? Give its two properties.
viii. What is Heisenberg uncertainty principle?
ix. What are the defects of Rutherford atomic model?
x. What is spectrum? Difference between continuous spectrum and line spectrum?

SECTION-II
Note: Attempt any three questions. (8 x 3=24)
Q. No 5:
a. Drive the van der Waal’s equation for real gases.
b. Ethylene glycol is used as automobile antifreeze. It has 38.7% carbon, 9.7% hydrogen and
51.6% oxygen. Its molar mass is 62.1g/mol. Determine its empirical formula.

Q. No 6:

a. Describe yield. How do you calculate the percentage yield of chemical reaction.
b. Serotenin (Molar mass= 176g/mol) is a compound that conducts nerve impulse in brain
and muscles. It contains 68.2% C, 6.86% H, 15.09%N, and 9.08% O. what is its molecular
formula?

Q. No 7:

a. What is difference between isomorphism and polymorphism. Give examples.

b. Explain liquid crystals. Write the uses of liquid crystals.

Q. No 8:

a. Explain manometric method to measure the vapor pressure.

b. Write 5 properties of hydrogen bonding.

Q. No 9:

a. Drive the radius of revolving electron in nth orbit?

b. What are quantum numbers? Explain the azimuthal quantum number.