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4. Calculate the final temperature of a sample of CO2 of mass 16.0g that is expanded
reversibly and adiabatically from 500.0mL at 298K to 2.00L.
3. A sample consisting of 1.00 mol of a monatomic perfect gas with Cvm = 3/2 R is heated
from 0o C to 100o C at constant pressure. Calculate S for the system.
4. Calculate S for the system when the state of 3.00 mol of a monatomic perfect gas, for
which Cp,m = 5/2 R, is changed from 25o C and 1.00 atm to 125o C and 5.00 atm.
Rationalize the sign of S.
6. Calculate the change in the entropies of the system and the surroundings and the total
change in entropy, when the volume of a sample of nitrogen gas of mass 14 g at 298K
and 1.0 bar doubles its volume in an
a) isothermal reversible expansion
b) isothermal Irreversible expansion against Pex = 0.
c) adiabatic reversible expansion
7. Calculate the change in entropy when a monatomic perfect gas is compressed to half
its volume of 2.00L and simultaneously heated to twice its initial temperature of 300K.
Assume Cvm = 3/2R.