Sei sulla pagina 1di 16

इंटरनेट मानक

Disclosure to Promote the Right To Information


Whereas the Parliament of India has set out to provide a practical regime of right to
information for citizens to secure access to information under the control of public authorities,
in order to promote transparency and accountability in the working of every public authority,
and whereas the attached publication of the Bureau of Indian Standards is of particular interest
to the public, particularly disadvantaged communities and those engaged in the pursuit of
education and knowledge, the attached public safety standard is made available to promote the
timely dissemination of this information in an accurate manner to the public.

“जान1 का अ+धकार, जी1 का अ+धकार” “प0रा1 को छोड न' 5 तरफ”


Mazdoor Kisan Shakti Sangathan Jawaharlal Nehru
“The Right to Information, The Right to Live” “Step Out From the Old to the New”

IS 3025 (Part 49) (1994, Reaffirmed 2009): Method of


Sampling and Test (Physical and Chemical) for Water and
Wastewater, Part 49: Zinc (First Revision). ICS 13.060.50

“!ान $ एक न' भारत का +नम-ण”


Satyanarayan Gangaram Pitroda
“Invent a New India Using Knowledge”

“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता ह”


है”

Bhartṛhari—Nītiśatakam
“Knowledge is such a treasure which cannot be stolen”
(Reaffirmed 2009)

IS 3025 ( Part 49 ) : 1994


( Reaffi rmed 2003 )

\fIC1 3tR 3i q ~ Ite \JlC1 ( '+i~ fa Cfj ~ '< Iff III ~ 4> )
~ ~ ~ (f~ ll"frafUT
~49~

( qi}cll ~erur )

Indian Standard
METHODS OF SAMPLING AND TEST
( PHYSICAL AND CHEMICAL) FOR WATER
AND WASTEWATER
PAAT49 ZINC

( First Revision)
Third Reprint SEPTEMBER 2()()~

UDC 628.1.032: 628.3 : 543.3 [546.47]

C BIS 1994

BUREAU OF INDIAN STANDARDS


MANAK SHAVAN, 9 BAHADUR SHAH ZAFAR MARG
NEW DELHI II 0002

June 1994 Pri« Group 4


AMENDMENT NO. 1 OCTOBER 2000
TO
IS 3025 ( PART 49) : 1994 METHODS OF SAMPLiNG
AND TEST (PHYSICAL AND CHEMICAL) FOR WATER
AND WASTEWATER
PART 49 ZINC
( First R~tlisio,. )

( Page 1, c1mlJe 1 ) - Insert tbe following new clau~e atlbe end of 1 and
renumtlcr subsequent clauses:

2.1 n.e Indian Standards listed below conlltin provisions which tbrough
reference in tbis text. con~tjlule provision o( tbis standard. Al tbe time of
publication, tbe editions indicated were vlllid. AU siandards are subject to
revision and parties to 8grcem~nts based on tbis standards are encouraged to
invc~liga.e the possibility or applying tbe most recent editions of the standards
indicated below:
IS No. Title
3025 (Part 1) : 1986 Methods of sampling lind lest (pbysicaland chemical) for
water and w8slewa1er : Part 1 Sampling (first revision)
7022 (Part 1) : 1973 GI~sary or l~rms relating to waler, sewage and industrial
effiuents: Part 1
7022 (Part 2) : 1979 Glossary of tern}! relating to water, sewage and industrial
emUcnL4t: Part II'
( P"ge 2, clause 4.4.3 ) - In..'~ert the following 'Note' It tbe end of this
clause:
'NOlE - POlassium cyanide i •• deadly roi!lOo. Avoid slUn C'Onlact or inh.alalion or
vapours. Do nol pipelle by moulb or brinl in conlac:t with acids.,'

( Page 2, clause 4.4.4 ) - Substitute the following for the existing:


•4.4.4 eyclollan none Solm ion
Dissolve 1 ml of purified cyclobc:xanone in 50 nll of water:
I
Amend No. 1 to IS JOZ! ( Part 4' ) : 1994

( PQ~ 2, cltllU~ 4..5.1, liM 13 ) - Subatitule •cyclobeu none' fOl


•cblorobcxaoone 9 •
( Pose 2, cI(,,"~ 4.5.1, linf! 14) - Delcte tbe following:
'(see 4.4.4 Note)'

(CHD 12)

Pnntod at New india Pnntma Pre... Khu1)., lndtl


2
Environmental Protection Sectional Committe'!, CHD 012

FOREWORD
This Indian Standard ( First Revision) was adopted by the Bureau of Indian Standards. after the
draft finalized by the Environmental Protection Sectional Committee had been approved by the
Chemical Division Council.
Zinc is an essential and beneficial element in body growth. Concentration above 5 mg/1 may
cause a bitter astringent taste and opalescence in alkaline water. Zinc most commonly enters
the domestic water supply from deterioration of galvanized iron and dezincification of brass.
Zinc in water may also come from industrial water pollution. In the preparation of this standard
considerable assistance has been derived from American Standard Test Methods ( ASTM Annual
Book Section 11. 1933) and Analytica Chimica Acta. 164 ( 1984) pp 1-21. The assistance so
derived is thankfully acknowledged. This standard supersedes 17 of lS 2488 (Part 2 ) : 1968
and 39 of IS 3025 : 1964.
In reporting the result of a test or analysis made in accordance with this standard. if the final
value. observed or calcuhted, is to be rounded off. it shall be done in accorJance with IS 2 : 1960
'Rules for rounding off numerical values ( revised)'.
The composition of the technical committee responsible for the formulation of this Indian
Standard is given in Annex A.
IS 3Cn5 ( Part 49 ) : 1994

Indian Standard
METHODS OF SAMPLING AND TEST
( PHYSICAL AND CHEMICAL) FOR WATER
AND WASTEWATER
PART 49 ZINC

( First Revision)
1 SCOPE .. ZINCON METHOD
This standard prescribes following four methods 4.1 PriDelple
for determination of zinc:
Zinc ( II) forms a soluble blue complex with
a) Zincon Method, 2.. carboxy-2-bydroxy..S-sulfoform-azyl benzene
b) Atomic Absorption Method ( Direct ), ( zincon) at pH 9'0. The coloured comp1ex
obeys Beer's Jaw and is suitable for spectropho-
c) Atomic Absorption Method (Chelation tometric measurements.
and Extraction ), and
This method is applicable in the range from
d) Differential Pulse Anodic Stripping 0·02 -S mg/1 of zinc.
VoJtammetry (DPASV).
Depending upon the concentration range and
".2 lotedereaca
interference levels, choice of the method is Though many heavy metals react with zincon
made. When the concentration levels are below and interfere in the analysis, treatment of the
200 p.1/l, preconcentration is carried out either sample as given in 4.5.1 with cyanide and chloro-
by chelation and extraction prior to atomic hexanone masks many of the interfering metal
absorption spectrophotometer (AAS) or by ions. The following ions interfere beyond the
deposition on a mercury drop electrode as in concentrations given against each:
DPASV method. For dissolved zinc content,
filtration through 0'45 J.&m membrane filter is Sl No. Ion Concentration, mgjl
reqUired. i) Cdl+ 1
2 SAMPLING AND PRESERVATION ii) All'" S
iii) Mn'+ 5
The sampling bottles shall be cleaned thoroughly
with dilute Ilitric acid ( 6 N ) prior to the final iv) Fe ll + 7
rinsing with water. The water samples should v) Fe l + 9
be collected and stored preferably in polypro- l 10
pylene or chemically resistant glals containers. vi) Cr '"
For preservation, the samples should be a~idi­ vii) Ni l + 20
fled with concentrated nitric acid ( 2 ml of AR viii) Cu·'" 30
grade of nitric acid in 1 litre just to bring down
the pH below 2). Unacidified samples should ix) COl'" 30
be analysed tho same day while the acidified x) CrO' SO
samples can be stored for a few days ( S days )
in a refrigerator. 4.3 Apparata.
3 PUIlITY or THE REAGENTS 4.3.1 Spec,rophotometer - for use at 620 nm
with 1 cm cells.
3.1 Unless otherwise indicated, only AR/GR
Irade chemicals should be used for all the tests. 4.4 Reageate
3.2 Double distilled water, with a specific con- 4.4.1 Sodium Hydroxide Solution - 40 Ill.
ductivity of less than 1-0 J.&mbo/cm should be
used for preparing the standards and reagent Dissolve 40 g or
sodium hydroxide (NaOH)
solutions. in SOO ml of water and make up to 1 litre.
IS 3025 ( Part 4' ) : J.994

4.4.2 Sodium Hydroxide Solution - 240.1 J • 4.5.2 Measure the optical density of the sample
solution at 620 om against the reagcnt blank
Dissolve 24 g of sodium hydroxide ( NaOH ) in containing added zinc and prepared in the
25 ml of water. Dilute to 100 ml with water. same way except for the addition of 3 ml oC
4.4.3 PotQSslum Cyanide Solution chloral hydrate.
Dissolve 1 g of potassium cyanide ( KeN) in 4.5.3 Calibration
50 ml of water and di1ute to 100 mI. Treat SO ml portions of standard solutions COD ..
4.4.4 Chlorohexanone Solution - purified. taining 0'02, 0·05. 0'1, 0'5,1-0, and '·0 mgll
of zinc and treat as above and measure the
Dissolve 10 g of chlorohexanone CCt.(OH), absorbance. Plot absorbance versus milligram
in 100 ml of water. of zinc for the standards to get a calibration
NOTE _ As the reagents 4.4.3 and 4.4." are poiso- graph. Read the concentration of zinc in the
nOUI, they Ihould b~ prepared in a fume hood and sample from the cali bration graph.
handled with safety pipettes.
4.6 CalcalatloD
4.4.S Zlncon Solution
Dissolve 0·325 g of zincon reagent in 1~ rot of
Zinc, mg/l= ~ x 1000
. methanol by heating gently. Cool. D1lute to where
25() ml with methanol in a 250 ml standard
flask. Store the reagent in a brown colourec1 M = mass of zinc present in ml in the
sample, and
bottle.
V = volume of sample in ml.
4.4.6 Sodium Ascorbate
5 ATOMIC ABSORPTION METHOD
Needed only when manganese content is more ( DIREt..,. )
than 0-2 ppm.
5.1 Principle
4.4.7 Borate Buffer Solution
The zinc content 9f the sample is determined
Dilute 213 mt of 1M NaOH solution to 500 ml by atomic 'absorption sp!ctrophotometry. For
with water and dissove 37·3 g of potassium dissolved zinc, the filtered sample is directly
chloride and 31 8 of boric acid. Make up to aspirated to the atomizer. For total recovera·
1 litre in a standard ftask. ble zinc, an acid digestion procedure is done
4.4.8 Hydrochloric Acid - Concentrated.
prior to aspiration of the sample.
This method is applicable in the range from
4.4.9 Zinc ( ll) SQlutions 0-01 to 2-0 mg/l. However t tho concenSration
Dissolve 0'2745 g of zinc sulphate (ZnSO'·7 H•O ) range will vary with the sensitivity of the
in 200 ro1 of water and dilute to 1 litre. 1 ml -== instrument used.
0·1 mg of Zn.
5.2 I.terferellce.
4.5 Proeeclure Cadmium, lead, copper, nickel, cobalt and
4.S. t For dissolved zinc, filter the sample chromium up to 10 mg/l do not interfere.
through 0-45 I'm membrane filter paper. For Alkali and alkaline earth metals can be tolera-
total zinc, add J ml of concentrated hydrochlo .. ted up to 4000 mg/l. fron interferes at concent-
ric acid to 50 mt of sample and boil for 5 rations of SO mgt! and above by suppressio, tho
minutes. Cool the solution and adjust the pH zinc absorpt ion.
to 7 with sodium hydroxide solution (4.4.2).
Make up the solution to 50 ml in a standard 5.3 Apparatulll
flask. Take 10 ml of this solution or the filtrate 5.3.1 Atomic Ab30rptlon Spectrophotometer with
( in the case of dissolved zinc) in an Erlen.. A.ir-Acetylene Flame
meyer flask. Add 0·5 g of sodium ascorbate,
1 rnl of ci'anide solution, 5 ml of buffer solu- 5.3.2 Multi-element hollow-cathode lamps or
tion, 3 ml of zincon lolution and 1 m1 of electrodeless discharge lamps for use at
chlorohexanone solution in the above order 213-8 nm.
with sufficient precaution (lee 4.4." Note).
Make up the solution to 500 mi. Prepare a 5.4 Reapatl
reagent blank by treating SO m.l 'of double 5.4.1 Hydrochloric A.cld - Concentrated.
distilled water in the same way as described
above. 5.4.2 Nitric Add - Concentrated.

2
IS 3025 ( Part 49 ) : 1994

5A.3 Nitric Acid - Diluted ( 1 : 499 ). Non - Tho lower raDIO 01 determination to tho
extent of 0,001 mill may be obtaiocd by paphito
5.4.4 Zinc ( II) Solutlom .yatem.
5•.4A.l Stock zinc ( II) solutloll 6.2 InterfereDcn - Same al in 5.1.
Dissolve 1 g of acid washed and rinsed zinc ' ..3 Apparatus - Same as in 5.3.
granules or 1,245 I of zinc oxide (ZnO) in
20 ml of 1 : 1 nitric acid. Dilute to 1 : 1 with 6.4 Reagents
water. 1 ml == 1·0 rna of Zo. 6.4.1 Hydrochloric A.cid - Concentrated.
5.4.4..2 StatUla,d zinc ( II) ,olution 6.4.2 Hye/Tochlorlc Acid - Diluted ( 1 : 2 ).
Dilute 100 m! of zinc stock solution and 1 ml 6.4.3 Hydrochloric A.cid - Diluted ( 1 : 49 ).
of nitric acid to I litre with water.
6.4.4 Nitric Acid - Concentrated.
5,5 Procedure
6.4.5 Pyrrolidine Dithio Carbamic Ac id - Chlo-
5.5.1 Add 0-5 ml of nitric acid to 100 ml of roform reagent:
the sample (filtered or unfiltered). If total
recoverable zinc is to be determined, add 5 ml 36 ml of pyrrolidinc is mixed with I litre of
of concentrated hydrochloric acid and filter the chloroform. The solution is cooled and 30 ml
sample through acid washed filter paper. Make of carbon disulphide is added in small fractions
up to 100 ml in a volumetric flask, aspirate the with continuous stirring. Dilute with I litre ot
solution and measure tbe absorbance at 213,8 chloroform and store in a cool and dark place.
nm. Aspirate nitric acid ( 1 : 499) prior to The reagent is stable for at least six months.
sample aspiration. NOTE - AI component. of this mixturo arc hiShl,
5.5.2 Prepare a reagent blank and sufficient toxic and flammable, propare and ute in a fume
hood.
standards containing 0'01, 0'05, 0'1, 0'5. 1'0
and 2,0 mgll of zinc by diluting suitable volume 6.4.6 Sodium Hydroxide Solution
of the standard solution with nitric acid
( 1 : 499) and repeat as above. Aspirate the Dissolve 100 S of sodium hydroxide in water and
solutions and measure the absorbance. dilute to I litre with water.
5.6 C.lcal.tioD 6.4.7 Chlor%rm
5.'.1 Construct a standard calibration graph by 6.4.8 Bromophenol Blue Indicator Solution
plotting the absorbance versus standard con-
centration for each standard. Read the con- Dissolve 0'1 g of bromophenol blue in 100 ml of
centration of the samples from the graph. 50 percent ethanol or isopropanol.

Zinc, mgft.=~
y
x 1 000 6...., Stock Zinc ( 11 ) Solution
Dissolve 1 g of acid washed and rinsed zinc
where grallules or 1'245 I of zinc oxide ( ZnO) in
M == mass of zinc present in mg in the 20 ml of 1 : I HNO.. Dilute to 1 litre with
sample, and water. 1 m) - 1·0 mg of zinc.
Y :III volume of sample in mi.
6.4.10 InterrMtllDte Zinc Solution
, ATOMIC ABSORPTION MEmOD
( CHELATION - EXTRACTION) DiJutc 100 ml of zinc stock solution and 1 ml
of nitric acid to I Jitre with water.
6.1 Secpe a.4 Ap,lIeatiu
Zinc is chela ted with pyrrolidine dithio carba- '.4.11 Standard Zinc Solution
mic acid and extracted with chloroform. The Dilute 10 ml of zinc intermediate solution and
extract is treated with hot nitric acid after 1 ml of nitric acid to 1 litre with water. This
eyapor~tjng to d~yaess, d,issolved in hydrochlo- solution should be prepared just before usc.
riC aCid and diluted With water. An aliquot
is aspirated into the air..acetylene flame of the 6.5 Procedure
spectrophotometer. For total recoverable zinc
an acid digestion proceduro i. done prior to 6.5.1 For dissolved zinc, filter 100 ml of the
aspiration of the sample. sample through 0·45 I'm membrane filter paper.
For total zinc, add 5 ml of concentrated nitric
This method is applicable for the concentration acid and evaporate the solution to 15 to 20 mi.
rUle from 1-200 "gIl. Cool and filter the sample througb acid washed

3
IS 3025 (Put 49 ) : 1994

filter paper. Make up to 100 mt in a volumetric 7.2 Interferences


fta,k. Add to this solution or the filtrate ( in
calc of dissolved zinc) 2 drops of bromophenol Selenium interferes when it is present in excell
blue indicator solution and mix. Adjust the of 50 I':g/1.. This. can be overcome by adding
pH by adding sodium hydroxide solution till a ascor,ble aCid Which reduces selenium ( IV ) to
blue colour persists. Add. diluted hydrochloric selemum metal. Iron (Ill) interferes when
pr~sent at levels greater than zinc. However
acid ( 1 : SO ) drop by dr('p until the colour just
disappears; then add 2'S ml in excess to bring thIS can be overcome by warming the solution
the pH to 2·3-2-S. Add 10 ml ot' pyrroline with hyd.roxylan:'ine. .AI~o, the presen.ce ot any
dithio carbamic acid - chloroform reagent and other nelghhounng stflpplng peaks which is less
shake well. After the pbases separate out, concet than 100 mV flom that of the zinc will interfere.
the chloroform pbase by taking care to avoid 7.3 Apparatul
any trace of water in a Bask. Repeat the extrac·
tion till the chloroform layer becomes colourless
7.3.1 Po/arogrtljJhtc Instrumentation Ctlpabl. 0/
with fresh 10 ml portions of chloroform and
Plr/orming Differential Pulse Work
combine the extracts. Evaporate the solution 7.l.Z Hanging Mercury Drop Electrode
just to dryness and dissolve the residue by
dropwile addition of 2 ml of concentrated 7.3.3 Platinum Counter Electrode
nitric acid by holding the beaker at an angle. 7.3.4 Saturated Calomel Reference Electrode
Again evaporate to dryness and add 2 ml of
hydrochloric acid ( 1 : 2 ) and heat for 1 minute. 7.3.5 Magnetic Stirrer Control Unit, Stirring Bar
Cool and make up the solution in a lO ml 7.4 Reagents
standard flask. Aspirate tb~ sample and
measure the absorbance; 7.4.1 Hydrochloric Acid - Concentrated.
6.S.1 Prepare a reagent blank and sufficient
standards containing 10, 20, SO, 100 and 200 7.4.2 Nitric Acid - Concentrated.
"gIl of zinc by diluting a suitable volume of the 7.4.3 Nitric Acid - Diluted ( 1 : 1).
standard solution with tOO ml of water and
repeat 1.4) above. Aspirate the solution and 7.4.4 Zinc Solutions
measure the absorbance. 7.4.4. t Stock zinc solution - Prepare as in 6.4.9.
6.6 Calculation
6.6.1 Construct It standard calibration graph by
7.4.4.2 Intermediate zinc solution - Prepare as
in 6.4.10.
plotting the absorbance versus the micrograms
of zinc. Read the concentrat ion of the samples 7.4.4.3 Zinc standard solution - Prepare a.
from the curve. in 6.4.11.

Zinc, 1'1/1 == -~- X 1 000 7..4.5 A.malgamated Zinc


where Cover 10 g of granular zinc with water and add
2 drops of concentrated hydrochloric acid.
AI :!III mass of zinc present in the sample Then add S~8 drops of mercury with continuous
( in J'g). and shaking.
V = volume of sample in mi.
7.4.6 Purified Nitrogen
7 DIFFERENTIAL PULSE ANODIC Boil 2 I of ammonium meta vanadate with 25 ml
STRIPPING VOLTAMMETllY ( DP ASV ) of concentrated hydrochloric acid. Dilute to
7.1 Principle 250 ml and transfer to the scrubber. Add 10.. IS g
Zinc is deposited on a hanging mercury drop at of amalgamated zinc. Pass nitrogen gal through
a negative potential of - 1·2 V VI saturated the scrubber for removal of traces of oxygen
calomel electrode (SeE). Then the zinc is and through distillt:d water for washin, any
stripped back into the solution by applying a traces of scrubber chemicals ( Pig. 1 ).
+ v.e p'!tential sca~. The anod~c current peak 7.5 Proeetlure
whtch IS measured IS representative of the zinc
con cent ration in the sample. Por total dissolved 7.5.1. Clean all the glassware. and the voltam-
zinc the sample ia filtered through a 0·45 I'm metrlc cells by soaking them overnight in
mem brane filter paper prior to acidification concentrated nitric acid and rinshig them
and analysis. . thoroughly with distilled water. If total disaol..
ved zinc alone is to be determined, the sample
Thil method is applicable In the concentration ahowd be filtered through 0·45 ,um membrane
raDIO 1·0-100 1'1/1 or zinc. filter paper. For total recoverable zinc. digeat
IS 3U5 ( Part 49) : 19H

the sample. with 3 mJ each of concentrated Measure the current peak height ( 11)' Add
hydrochloric acid and nitric acid. Evaporate the 20 "I of standard 1-inc solution and deaerate for
loJution to 15·20 mI. Cool and make up to S minutes. Repeat as above. Measure the
100 ml in a volumetric flask. Take 10 ml of the current peak height ( 1. ).
sample in the polarographic cell and deaerate
for IS minutes. Th(" cell should be covered with '.6 CalculaUoa
nitrosen gas during the experiment ( Fi,- 2 ). C /1 11 V Cstd X 1 000
8IUDP~ mg s=: 1• ., + ( 1.-11 ) V·
Generate a new droplet of mercury and put the
stirrer on. Connect the cell and depoait at where
-1·2 V versus SCE for 3 mjnutes. Stop the 11 == current
peale height for the
stirrer and wait for 30 seconds. Start the anodic: sample,
Ican with the followins settinss; I, .. current peak height for the
Initial potential -1'2VvsSCB sample + standard,
Scan rate 5 mV/s ., _ volume of standard added
Scan direction +ve ( 20 ~) ).
Modulation amplitude 2SmV Y _ volume ofthc sample solution,
Current ranse 1.. 10 I'A
Drop time 0·5 s Caw == concentration of the standard
Display direction -\Ie solution added, and
Low pass filter Off position
Mode Differential pulse CAmPI. _ concentration of zinc in the
ScaD raDge -1·2 to -0·6 V sample.

WATER

A.... ALGAMATED
ZINC

FlO. 1 ScRUBSD AssEM8LY POll NmtOGIN PuRlftCATION

s
Pt COUNTER
£ltCTROO£

HMOE.WOltKIMQ
ELECTROOE
STIRRER BAR

Flo. 2 VOLTAMMBTRIC CBLL ASSIMBLY


IS 3025 ( Part 49 ) : 1994

ANNEX A
( Foreword )
COMMIITEE COMPOSITION
Environmental Protection Sectional Committee, CHD 012
Cllalrman Representlnll
hop D. K. Bmw AI Central PoJiution Control Board, Delhi
M,mbe"
DR K. R. R~NOANATHAN (AII,rna" to
Prof D. K. Biswas )
ADvlSEa (PHB) Ministry of' Rural Development
ADDL ADVISER ( PHE ) ( Allernat_ )
SUI S. B. C. AOARWALA Bharat Heav)' Electrical. Ltd. Hyderabad
Smu S. BALAOURUNATHAN ( AI,,,,,al, I)
SH1U A. K. GUPTA ( Alttrnat~ 11 )
DR A. L. AOOAIlWAL National Environmental EnSineerin& Relearch Inuit ute ( CSIR),
NalPur
Da T. CH.U:RAIAIlTl ( Alternate)
DR. A. ALA,.. Indian Council ot Aaricultuul Relearcb, New Delbi
SHRIS.C.AHLUWAUA National Council for Cement &. Buildinl Materials, New Delhi
SHR. A. D. AONIHOTIU ( Allerna'e )
SHRI R. K. BANERJEB Shriram Institute for Industrial Research, Delhi
SHRI p. K. MAIR ( Alternate)
8HRI B. BASU National Thermal Power Corporation Ltd, New Dolhi
DR S. MUXH!RJ!E ( Alternau )
SHRIV.S.BHATNAOAR Central Scientific [nltruments Orpnizatjon ( CSIR). Chandigarh
DR M. S. N· SRINIVAS ( Allernat, )
5HRI S. CHAKRAVORTI Directorato General Factory Advice Service & Labour rnltitutcI,
Bombay
DR M. H. FULECAR ( A/ttr"al, )
SUR' S. DAS Indian Petrochomical. Corporation Ltd. Vadodara
SRRI M. K. PRABHUDBSA. ( Alurnat, )
Da V. S. GUPTA National Tnt HoUle. Calcutta
SRRI D. N. P. SINOH ( A/terna', )
DR HARI5H CHANDaA Indultrial Toxicolo,y Research Centre ( CSIR. ), Lucknow
SHRI B. K. JAIN Tho Fertiliur AlSoc:iation of India, New Delhi
DR ( Ms ) B. SW~MINA.THAN ( A/'erlla/' )
SaRlO. K. GUIll!JA Thc:rmax Ltd. Punt
DR A. K. W AOLB ( Alt.rnal, )
SRllI A. LAHJRI Hindultan Lover Ltd. Bombay
SHRI B. B. DAVI (A/terMl' )
Da W. MADRAVAJUlPHNA Central Leathor Research Institute ( CSIR.), Madras
SRR. S. R,uAMANI ( Allt/rnat.)
8aa. S. K. MAntA Fiakt Iodia Ud, Calcutta
SHRI A. SAKA (A/tlrMI.)
SaRI R.. K· MALHOTRA Indian Oil Corporation Ltd ( R " D Contro ). Faridabad
SHRI S. K. lAIN ( Alttr",,', )
SSIl! A.. N. KAu Municipal Corporation or Greater Bombay
Smu V. S. MAflAJAN ( A/lerna/I)
DJ, p. K. MATHUR Bhabha Atomic RNearch Contre ( (GCAR ). Kalpakkam ( TN)
Da P. M. MODAle Indian Institute of Techno)olY. Bombay
ho, H. VIIIIRAMANI ( A/lernal')
Sal K. p. NVATI National Productivity Council, New Delhi
SRRI L. PANeBRSI!L VAM ( A.ltlrMt, )
PRO. B. PADMANABRAMURTHY lawaharlal Nehru Univoreity. Now Delhi
0. T. S. P.TEL National Institute of Occupational Health (leMR). Ahmadabad
SUI C. V. R.UYANI (AI'"IIIII.)
DJ, V.V. R.o Dbarmti Morarji Chemical Co Ltd, Bombay
Da M. ATeH.YY" (AI,,,nllu)
( CDnd,..~tI OR pap 8 )

1
18 3025 ( Part ..9 ) : 1994

( Ctlnllmwd from ,tl8e 7 )


Member, R,pr'8,,,tllrg
SIIIU P. S. llAMI\NATBAN Pettfcidea Asaociatlon or India, Now Deihl
Smu D. N. V. RAo Tata Chemicals Ltd. Bombay
SHR I R. J. BUCR ( A/terMt, )
DR S. RoUTH National Tett Houlo, Calcutta
DR J. C. NUHAWAN ( A./terRat,)
SHill P. R. S.ucADDAR Central Mechanical Bnl. Research lnstituto ( CSIR), Durlapur
SHRI P. K. 58N ( A./terMle )
5HIl. 5. C. SHAIlMA India Meteorololical Department. New Delhi
SHR) R. N. GUPTA ( A/terRale)
Saar M. P. SINOR Directorate General of TC(ihDical Development, Now Dolbi
SHRJ N. C. TIWARI ( A.lltrMt,)
SHRI M. SUB.A RAO Ministry or Environment & Poreltl
DR T. CHANDINI ( Alur,",I,)
SHRI R. M. SUNDARAM National Malaria Eradication Proarammo ( DOKS ), Delbi
SRRI C. KRISHNA. RAO ( Alternate)
SHill SURBNDIIl KUMAa Indian Chemical Manufacturers Association, New Delhi
SHRI R. PARTHASA.THY (Altel'lUlte)
SUPa.INTBNOINQ BNOINED Panchay-at Raj Department, Oovcmment of Andbra Pradclb,
Hyderabad
, EXECUTIVI! BNOINOR ( AlltrlUd, )
SRRI J. M. TULI Engineers India Ltd, New Delhi
SRRI S. N. CHAJtaABARTJ ( AllerMle )
DR R. K.. S'NOH, Director General. lUS ( Ex-officio M,mb,r)
Director ( Chern )
M~mber $«retary
S8R. T. RANOAIAMY
Ioint Director ( Chem). BIS

Water Environment Subcommittee, CHD 012 : 01


CO",.R.'
DR Y. P. KAItAR Ministry or Bnvironment at Forest.
Memberl
SHRr S. B. C. AOARWALA Dharat Heavy Electricals Ltd, Hyderabad
SRR I A. K.. OuPTA ( Alle"",'e )
SHRI A. BASu Thermax Ltd. Pune
A. K. JINDAL ( Alternat. )
SHRI
S8RI M. S. DRINoaA Shriram Institute for Industrial Reteareh. Delhi
SHill V. G. K.. NAJa ( Alterna', )
DR E. IC. JAYANARAYANAN Mohan Meakin Ltd, Mohan Nasar
SRIU K. K. Manu (
SHRI S. llLAM
AI,.,."",. ) Central Pulp and Paper Researeh Institute, Sabaranpur
SHIn F. LAL KANSAL Punjab Pollution Control Board, Patiala
SHaI S. S. SANOHA ( A/lerM'. )
SRIlI D. D. KUMTA Tata Chemical. Ltd, Bombay
DR K. e. PATHAK ( AlterMte)
PaoP K. 1. NATH All India Institute of Hysiene &: Public Healtb, Calcutta
hop A. K.. ADHY A ( AlterMI, )
Oil It. NATH Banaral Hindu University. Valanasi
DR S. RATAN ( AI'.".III, )
Da S. R. PANDI National Environment Bnsineerin, Research IIIIUtuto (ClIR ).
Na,pur
DR M. V. NANOT) (Alterllal.)
DI. P. M. PRIUS National Environment Bnlineerinl RCflearcb In.mute (eIIR).
NIIPur
DIl S. R. JOIHI ( AII"-,,all )
SRal S. PaAJCAlIf Delbi Water Supply & Sewase Disposal UndertakiDi. Now DeUU
SHIH S. S. RAMRAltaYANI ( Alt6rMt. )
SaRI R. V. RAo Central Water Commission, Now Delhi
SHRI D. K . .iCAUIHJIIt ( A,lterruJI. )
RIP. IBSINTATIV. Ministry of Rural Developmcnt
RURUBNTATIVI U. p. lai Nilam, Lucknow
DR 8. SINOU'TA Contra. Pollution Control Board, Del hi
Da It. C. TRIVIDI ( AII.'IIa" )
SUI'IUUNTlNDINO BNOINID Paneha),at Raj Dcpartmont, Government of Andhra Prad.... ,
Hyuraba4
EXICUTIVI BNOINII& ( Alt.,ul. )
Simi S. 1l. T ANTA Central Oroun4 Water Board. New Delhi
SRa. K. R.uAOO'AUN ( Alterut, )
DR P. N. VI8WAN4TftAN Industrial ToxicololY !losearch Centre ( CSI .. ), LuokDow

8
Burenu of Indian Standards

BIS is a statutory institution established under the Bureau of Indian StandarJs ".Iet, 1986 to promote
harmonious development of the activities of standardization, marking and quality certification of goods and
attending to connected matters in the country.

Copyright

BIS has the copyright orall its publications. No part of these publications may be reproduced in any form
without the prior permission in writing of8IS. This does not preclude the free lise, in the course ofimpiementing
the standard, of necessary details. such as symbols and sizes, type Ot' grade designations. Enquiries n:lating
to copyright be addressed to the Director (Publications), BIS.

Review of Indian Standards

Amendments are issued to standards as the need arises on the basis OfCOIllJll\!l1tS. Standards arc also reviewed
periodically; a standard along with amendments is reaffirmed when such review indicates that no changes Clrc
needed; if the review indicates that changes are needed, it is taken up for revision. Users of Indian Standards
should ascertain that they are in possession of the latest amendments or edition by referring to the latest issue
of 'BIS Catalogue' and 'Standards: Monthly Additions'.

This Indian Stal1d~lrd has been developed from Doc: No. CHD012( 112)

Amendments Issued Since Publication

Amend No. Date of Issue T\!xt Affected

8l)REAU OF INDIAN STANDARDS


Headqua rters:
Manak Bhavan, 9 Bahadur Shah Zafar Marg. New Delhi 110002
Telephones: 2323 0131,23233375.23239402 Website: www.bis.org.in
Regional Offices: Telephones
Central : Manak Shavan, 9 Bahadur Shah Zafar Marg 23237617
NEW DELHI J 10002 { 23233841

Eastern : 1/14 C.l. T. Scheme VII M, V. I. P. Road, Kankurgachi 23378499,23378561


KOLKA T A 700 054 { 23378626,23379120
Northern: SC0335-336, Scctor34-A, CHANDIGARH 160022 2603843
{ 2609285

Southern: C. I. T. Campus,1V Cross Road, CHENNAI600 113 2254 1216,2254 1442


{ 22542519.225423l5
Western: Manakalaya, E9 MIDC, Marol, Andheri (East) 28329295,28327858
MUMBAI400093 { 28327891,28327892

Branches: AHMEDABAD. BANGALORE. BHOPAL. BHUBANESHWAR. COIMBATORE.


FARIDABAD. GHAZIABAD. GUWAHATJ. HYDERABAD. JAII)UR. KANPUR.
LUCKNOW. NAGPUR. NALAGARH. PATNA. PUNE. RAJKOT. THIRUVANANTHAPURAM.
VISAKHAPATNAM.
Printed ot New Ind:n Printing Press, KhurJa. India

Potrebbero piacerti anche